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At least 415 records · Page 23Linked to original sources

Surface-geophysical investigation of the University of Connecticut landfill, Storrs, Connecticut

A surface-geophysical investigation of the former landfill area at the University of Connecticut in Storrs, Conn. was conducted as part of a preliminary hydrogeologic assessment of the contamination of soil, surface water, and ground water at the site. Geophysical data were used to help determine the dominant direction of fracture strike; subsurface structure of the landfill; locations of possible leachate plumes, fracture zones or conductive lithologic layers; and the location and number of chemical waste-disposal pits. Azimuthal square-array direct-current (dc) resistivity, two-dimensional (2D) dc-resistivity, inductive terrain conductivity, and ground-penetrating radar (GPR) were the methods used to characterize the landfill area.The dominant strike direction of bedrock fractures interpreted from azimuthal square-array resistivity data is north, ranging from 285 to 30 degrees east of True North. These results complement local geologic maps that identify bedrock foliation and fractures that strike approximately north-south and dip 30 to 40 degrees west.The subsurface structure of the landfill was imaged with 2D dc-resistivity profiling data, which were used to interpret a landfill thickness of 10 to 15 meters. Orientation of the landfill trash disposal trenches were detected by azimuthal square-array resistivity soundings; the dimension and the orientation of the trenches were verified by aerial photographs.Inductive terrain conductivity and 2D dc-resistivity profiling detected conductive anomalies that were interpreted as possible leachate plumes near two surface-water discharge areas. The conductive anomaly to the north of the landfill is interpreted to be a shallow leachate plume and dissipates to almost background levels 45 meters north of the landfill. The anomaly to the southwest is interpreted to extend vertically through the overburden and into the shallow bedrock and laterally along the intermittent drainage to Eagleville Brook, terminating 140 meters south of the landfill. Inductive terrain conductivity and 2D dc-resistivity profiling also detected two dipping, sheet-like conductive features that extend vertically into the bedrock. These features were interpreted either as fracture zones filled with conductive fluids or conductive lithologic layers between more resistive layers. One dipping conductive feature was detected south of the landfill, and the other feature was detected to the west of the former chemical waste-disposal pits. Both anomalies strike approximately north-south and dip about 30 degrees to the west.GPR was used unsuccessfully to locate the former chemical waste-disposal pits. Although the entire overburden and the upper few meters of bedrock were imaged, no anomalous features were detected with GPR that could be correlated with the pits. It is possible that the area surveyed by GPR was entirely backfilled after the soil was removed from the site and that the outline of the former chemical waste-disposal pits no longer exists.

Connecticut↗

Understanding contaminants associated with mineral deposits

Interdisciplinary studies by the U.S. Geological Survey (USGS) have resulted in substantial progress in understanding the processes that control the release of metals and acidic water from inactive mines and mineralized areas, the transport of metals and acidic water to streams, and the fate and effect of metals and acidity on downstream ecosystems. The potential environmental effects associated with abandoned and inactive mines, resulting from the complex interaction of a variety of chemical and physical processes, is an area of study that is important to the USGS Mineral Resources Program. Understanding the processes contributing to the environmental effects of abandoned and inactive mines is also of interest to a wide range of stakeholders, including both those responsible for managing lands with historically mined areas and those responsible for anticipating environmental consequences of future mining operations. The recently completed (2007) USGS project entitled 'Process Studies of Contaminants Associated with Mineral Deposits' focused on abandoned and inactive mines and mineralized areas in the Rocky Mountains of Montana, Colorado, New Mexico, Utah, and Arizona, where there are thousands of abandoned mines. Results from these studies provide new information that advances our understanding of the physical and biogeochemical processes causing the mobilization, transport, reaction, and fate of potentially toxic elements (including aluminum, arsenic, cadmium, copper, iron, lead, and zinc) in mineralized near-surface systems and their effects on aquatic and riparian habitat. These interdisciplinary studies provide the basis for scientific decisionmaking and remedial action by local, State, and Federal agencies charged with minimizing the effects of potentially toxic elements on the environment. Current (2007) USGS research highlights the need to understand (1) the geologic sources of metals and acidity and the geochemical reactions that release them from their sources, (2) the pathways that facilitate transport from those sources, and (3) the processes that control the fate of the elements once released from the sources. Experts in the fields of economic geology, structural geology, mineralogy, geophysics, geochemistry, hydrology, ground-water modeling, microbiology, and toxicology came together for a series of studies that address these relationships on scales ranging from the microscopic to the watershed. This Circular presents results and highlights from the detailed, interdisciplinary studies that include investigations in both mining-affected areas and mineralized but unmined areas. The first section of the Circular describes laboratory and site-scale field investigations that primarily focus on mineralogic and biologic controls on the source and release of metals and acidity from mine-waste rock and hydrothermally altered areas. The second section describes a set of basin- to watershed-scale studies that not only investigate the source and release of metals and acidity but also the transport of these constituents away from the source areas. The third section is a summary of results from postremediation ecosystem monitoring. For more information on these and other project-related studies, please visit the project Web site at http://minerals.cr.usgs.gov/projects/contaminants/index.html. The Web site includes a complete bibliography and detailed descriptions of each interdisciplinary study.

Circular↗

Resolution of fault slip along the 470-km-long rupture of the great 1906 San Francisco earthquake and its implications

Data from all available triangulation networks affected by the 1906 earthquake have been combined to assess the trade-off between slip resolution and its uncertainty and to construct a conservative image of coseismic slip along the rupture. Because of varying network aperture and station density, slip resolution is very uneven. Although slip is determined within uncertainties of ??1.0 m along 60% of the fault, constraints are poor on the remaining, mostly offshore portions of the rupture. Slip decreases from maxima of 8.6 and 7.5 m at Shelter Cove and Tomales Bay to 4.5 m near Mount Tamalpais and 2.7 m at Loma Prieta. The geodetically derived slip distribution is in poor agreement with estimates based on analysis of S wave seismograms, probably because these waves register only 20-30% of the total seismic moment obtained from longer-period surface waves. Consideration of a range of fault geometries for 1906 slip near Loma Prieta indicates right-lateral motions lie between 2.3 and 3.1 m. These values are considerably greater than the 1.5 m of measured surface slip on which several assessments of high earthquake hazard for this fault segment were based. This factor, along with the absence of 1989 slippage where 1906 surface slip was used to make the forecasts, casts doubt on some claims of success in predicting the 1989 M = 6.9 Loma Prieta earthquake.

Journal of Geophysical Research B: Solid Earth↗

Return from dormancy: Rapid inflation and seismic unrest driven by transcrustal magma transfer at Mt. Edgecumbe (L’´ux Shaa) Volcano, Alaska

In April 2022, a seismic swarm near Mt. Edgecumbe in southeast Alaska suggested renewed activity at this transform fault volcano, which was last active ≈800 years ago. Previously, thin rhyolitic tephras were deposited 5 and 4 ka. Satellite radar data from 2014 to 2022 resolves line-of-sight rapid inflation up to 7.1 cm/yr beginning in August 2018. Bayesian modeling suggests a transcrustal system of a deflating (−0.528 km 3 ) dipping sill at 20 km depth recharging a magma chamber at 10 km (0.222 km 3 ). A near-vertical conduit could capture the volume difference without noticeable surface deformation. Reanalyzed seismicity, recorded 25 km away, shows increases since July 2019. Magma ascent through ductile material and brittle strain release in a stressed overburden could explain the time delay. Cloud-native open data and workflows enabled discovery and analysis of this signal within days after going unnoticed for >3 years.

Alaska↗

Extraction of near-surface properties for a lossy layered medium using the propagator matrix

Near-surface properties play an important role in advancing earthquake hazard assessment. Other areas where near-surface properties are crucial include civil engineering and detection and delineation of potable groundwater. From an exploration point of view, near-surface properties are needed for wavefield separation and correcting for the local near-receiver structure. It has been shown that these properties can be estimated for a lossless homogeneous medium using the propagator matrix. To estimate the near-surface properties, we apply deconvolution to passive borehole recordings of waves excited by an earthquake. Deconvolution of these incoherent waveforms recorded by the sensors at different depths in the borehole with the recording at the surface results in waves that propagate upwards and downwards along the array. These waves, obtained by deconvolution, can be used to estimate the P- and S-wave velocities near the surface. As opposed to waves obtained by cross-correlation that represent filtered version of the sum of causal and acausal Green's function between the two receivers, the waves obtained by deconvolution represent the elements of the propagator matrix. Finally, we show analytically the extension of the propagator matrix analysis to a lossy layered medium for a special case of normal incidence. ?? 2007 The Authors Journal compilation ?? 2007 RAS.

Geophysical Journal International↗

Upper-crustal structure beneath the strait of Georgia, Southwest British Columbia

We present a new three-dimensional (3-D) P -wave velocity model for the upper-crustal structure beneath the Strait of Georgia, southwestern British Columbia based on non-linear tomographic inversion of wide-angle seismic refraction data. Our study, part of the Georgia Basin Geohazards Initiative (GBGI) is primarily aimed at mapping the depth of the Cenozoic sedimentary basin and delineating the near-surface crustal faults associated with recent seismic activities (e.g. M = 4.6 in 1997 and M = 5.0 in 1975) in the region. Joint inversion of first-arrival traveltimes from the 1998 Seismic Hazards Investigation in Puget Sound (SHIPS) and the 2002 Georgia Basin experiment provides a high-resolution velocity model of the subsurface to a depth of ∼7 km. In the southcentral Georgia Basin, sedimentary rocks of the Cretaceous Nanaimo Group and early Tertiary rocks have seismic velocities between 3.0 and 5.5 km s −1 . The basin thickness increases from north to south with a maximum thickness of 7 (±1) km (depth to velocities of 5.5 km s −1 ) at the southeast end of the strait. The underlying basement rocks, probably representing the Wrangellia terrane, have velocities of 5.5–6.5 km s −1 with considerable lateral variation. Our tomographic model reveals that the Strait of Georgia is underlain by a fault-bounded block within the central Georgia Basin. It also shows a correlation between microearthquakes and areas of rapid change in basin thickness. The 1997/1975 earthquakes are located near a northeast-trending hinge line where the thicknesses of sedimentary rocks increase rapidly to the southeast. Given its association with instrumentally recorded, moderate sized earthquakes, we infer that the hinge region is cored by an active fault that we informally name the Gabriola Island fault. A northwest-trending, southwest dipping velocity discontinuity along the eastern side of Vancouver Island correlates spatially with the surface expression of the Outer Island fault. The Outer Island fault as mapped in our seismic tomography model is a thrust fault that projects directly into the Lummi Island fault, suggesting that they are related structures forming a fault system that is continuous for nearly 90 km. Together, these inferred thrust faults may account for at least a portion of the basement uplift at the San Juan Islands.

British Columbia↗

Hydrogeologic and Hydraulic Characterization of the Surficial Aquifer System, and Origin of High Salinity Groundwater, Palm Beach County, Florida

Previous studies of the hydrogeology of the surficial aquifer system in Palm Beach County, Florida, have focused mostly on the eastern one-half to one-third of the county in the more densely populated coastal areas. These studies have not placed the hydrogeology in a framework in which stratigraphic units in this complex aquifer system are defined and correlated between wells. Interest in the surficial aquifer system has increased because of population growth, westward expansion of urbanized areas, and increased utilization of surface-water resources in the central and western areas of the county. In 2004, the U.S. Geological Survey, in cooperation with the South Florida Water Management District, initiated an investigation to delineate the hydrogeologic framework of the surficial aquifer system in Palm Beach County, based on a lithostratigraphic framework, and to evaluate hydraulic properties and characteristics of units and permeable zones within this framework. A lithostratigraphic framework was delineated by correlating markers between all wells with data available based primarily on borehole natural gamma-ray geophysical log signatures and secondarily, lithologic characteristics. These correlation markers approximately correspond to important lithostratigraphic unit boundaries. Using the markers as guides to their boundaries, the surficial aquifer system was divided into three main permeable zones or subaquifers, which are designated, from shallowest to deepest, zones 1, 2, and 3. Zone 1 is above the Tamiami Formation in the Anastasia and Fort Thompson Formations. Zone 2 primarily is in the upper part or Pinecrest Sand Member of the Tamiami Formation, and zone 3 is in the Ochopee Limestone Member of the Tamiami Formation or its correlative equivalent. Differences in the lithologic character exist between these three zones, and these differences commonly include differences in the nature of the pore space. Zone 1 attains its greatest thickness (50 feet or more) and highest transmissivity in coastal areas. Zone 2, the most transmissive and extensive zone, is thickest (80 feet or more) and most transmissive in the inland eastern areas near Florida's Turnpike. In this area, zone 1 is absent, and the semiconfining unit above zone 2 extends to the land surface with a thickness commonly ranging from 50 to 100 feet. The thickness of zone 2 decreases to zero in most wells near the coast. Zone 3 attains its greatest thickness (100 feet or more) in the southwestern and south-central areas; zone 3 is equivalent to the gray limestone aquifer. The distribution of transmissivity was mapped by zone; however, zones 2 and 3 were commonly combined in aquifer tests. Maximum transmissivities for zone 1, zones 2 and 3, and zone 3 were 90,000, 180,000, and 70,000 ft2/d (feet-squared per day), respectively. The northern extent of the area with transmissivity greater than 50,000 ft2/d for zones 2 and 3 in the inland northeastern area along Florida's Turnpike has not been defined based on available data and could extend 5 to 10 miles farther north than mapped. Based on the thickness of zone 2 and a limited number of aquifer tests, a large area of zone 2 with transmissivity greater than 10,000 ft2/d, and possibly as much as 30,000 ft2/d, extends to the west across Water Conservation Area 1 from the inland southeastern area into the south-central area and some of the southwestern area. In contrast to the Biscayne aquifer present to the south of Palm Beach County, zones 2 and 3 are interpreted to be present principally in the Tamiami Formation and are commonly overlain by a thick semiconfining unit of moderate permeability. These zones have been referred to as the 'Turnpike' aquifer in the inland eastern areas of Palm Beach County, and the extent of greatest thickness and transmissivity follows, or is adjacent to, Florida's Turnpike. Where it is thick and transmissive, zone 1 may be considered equivalent to the Biscayne aquifer. Areas

Scientific Investigations Report↗

Results and interpretation of geophysical studies near the Picacho Fault, south-central Arizona

Earth fissuring attributed to ground-water withdrawal occurs throughout south-central Arizona. A large zone of active fissures is located near Picacho, Arizona on the eastern rim of a large subsidence bowl. The main fissure has been named the Picacho fault. During February and March 1977, approximately 6.5 km of seismic-refraction lines were run across the Picacho fault to investigate subsurface conditions down to the crystalline basement. In addition, two lines of close-spaced gravity stations were made across the fault. The gross geologic features inferred from the gravity data agree with the seismic interpretations. Six layers were interpreted from the seismic refraction data: three layers of unconsolidated alluvium, two of denser rock of varying porosity, and the basement rock. Three significant basement faults were identified. These faults appear to lie almost directly beneath the surface fissures. Abrupt slope changes in the alluvial layers and an abrupt velocity change in the denser compacted sediments seem to be related spatially to the surface fissures. In addition there are lateral velocity differences within the basement fault blocks. In the overlying sediments a facies change in a 3.0 km/sec layer is suggested by the abrupt lateral velocity increase from 3.0 km/sec to 3.7 km/sec. This apparent facies change may in fact represent a fault plane extending upwards from the westernmost basement fault. This fault plane may even extend farther into the unconsolidated overlying sediments, inferred from basinward increases in slope, subtle basinward decreases in velocity, and a basinward elevation decrease in the top of the zone of saturation.

Open-File Report↗

Numerical model of frazil ice and suspended sediment concentrations and formation of sediment laden ice in the Kara Sea

A one-dimensional (vertical) numerical model of currents, mixing, frazil ice concentration, and suspended sediment concentration has been developed and applied in the shallow southeastern Kara Sea. The objective of the calculations is to determine whether conditions suitable for turbid ice formation can occur during times of rapid cooling and wind- and wave-induced sediment resuspension. Although the model uses a simplistic approach to ice particles and neglects ice-sediment interactions, the results for low-stratification, shallow (∼20-m) freeze-up conditions indicate that the coconcentrations of frazil ice and suspended sediment in the water column are similar to observed concentrations of sediment in turbid ice. This suggests that wave-induced sediment resuspension is a viable mechanism for turbid ice formation, and enrichment mechanisms proposed to explain the high concentrations of sediment in turbid ice relative to sediment concentrations in underlying water may not be necessary in energetic conditions. However, salinity stratification found near the Ob' and Yenisey Rivers damps mixing between ice-laden surface water and sediment-laden bottom water and probably limits incorporation of resuspended sediment into turbid ice until prolonged or repeated wind events mix away the stratification. Sensitivity analyses indicate that shallow (≤20 m), unstratified waters with fine bottom sediment (settling speeds of ∼1 mm s −1 or less) and long open water fetches (>25 km) are ideal conditions for resuspension.

Kara Sea↗

Direction of unsaturated flow in a homogeneous and isotropic hillslope

The distribution of soil moisture in a homogeneous and isotropic hillslope is a transient, variably saturated physical process controlled by rainfall characteristics, hillslope geometry, and the hydrological properties of the hillslope materials. The major driving mechanisms for moisture movement are gravity and gradients in matric potential. The latter is solely controlled by gradients of moisture content. In a homogeneous and isotropic saturated hillslope, absent a gradient in moisture content and under the driving force of gravity with a constant pressure boundary at the slope surface, flow is always in the lateral downslope direction, under either transient or steady state conditions. However, under variably saturated conditions, both gravity and moisture content gradients drive fluid motion, leading to complex flow patterns. In general, the flow field near the ground surface is variably saturated and transient, and the direction of flow could be laterally downslope, laterally upslope, or vertically downward. Previous work has suggested that prevailing rainfall conditions are sufficient to completely control these flow regimes. This work, however, shows that under time-varying rainfall conditions, vertical, downslope, and upslope lateral flow can concurrently occur at different depths and locations within the hillslope. More importantly, we show that the state of wetting or drying in a hillslope defines the temporal and spatial regimes of flow and when and where laterally downslope and/or laterally upslope flow occurs.

Water Resources Research↗

Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer. Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface. A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow. Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of water-bearing zones. Aquifer-test data were analyzed with a two-dimensional, axisymmetric, radial, transient, groundwater-flow model using MODFLOW–2005. The flowmeter-survey and aquifer-test simulations provided an estimated transmissivity of about 60,000 square feet per day for the Upper Floridan aquifer and about 5,000 square feet per day for the Lower Floridan aquifer. Water in discrete-depth samples collected from the Upper Floridan aquifer, middle semiconfining unit, and Lower Floridan aquifer during the EM flowmeter survey in August 2013 was low in dissolved solids. Tested constituents were in concentrations within established U.S. Environmental Protection Agency drinking water-quality criteria. Concentrations of measured constituents in water samples from Lower Floridan aquifer well 36Q398 collected at the end of the 72-hour aquifer test in November 2013 were generally higher than in the discrete-depth samples collected during EM flowmeter testing in August 2013 but remained within established drinking water-quality criteria. Water-level data for the aquifer test were filtered for external influences such as barometric pressure, earth-tide effects, and long-term trends to enable detection of small (less than 1 ft) water-level responses to aquifer-test withdrawal. During the 72-hour aquifer test, the Lower Floridan aquifer was pumped at a rate of 750 gallons per minute resulting in a drawdown response of 35.5 ft in the pumped well; 1.6 ft in the Lower Floridan aquifer observation well located about 6,000 ft west of the pumped well; and responses of 0.7, 0.6, and 0.4 ft in the Upper Floridan aquifer observation wells located about 36 ft, 6,000 ft, and 6,800 ft from the pumped well, respectively

Georgia↗

Geophysical modeling of a possible blind geothermal system near Battle Mountain, NV

The northeastern portion of the Reese River basin in north-central Nevada is the focus of detailed geophysical and geological studies as part of the INGENIOUS project, which aims to identify new, commercially viable hidden geothermal systems in the Great Basin region of the western U.S. This location, herein referred to as Argenta Rise, occupies a broad (~15km wide) left-step between major range-front fault systems along the northwestern edge of the Shoshone Range and Argenta Rim, with numerous ENE-striking intra-basin faults presumably accommodating sinistral-normal oblique slip across the step-over. Four discrete regions have been identified within the study area that have favorable structural settings for hosting a blind hydrothermal system. However, with no definitive or extensive surface manifestations of an active hydrothermal system (e.g., geysers, steam vents, sinter, etc.), detailed geophysical studies are necessary to resolve subsurface geology and structure, and identify zones of enhanced structural complexity that may promote hydrothermal fluid flow. Hence, we collected high-resolution gravity, MT, and rock property data (density, magnetic susceptibility), and analyzed the recently acquired GeoDAWN aeromagnetic data to characterize potential geothermal resources in this region. Using the new geophysical datasets, we jointly modeled gravity and magnetic data along a series of intersecting 2D profiles that integrated information from recent, local-scale fault mapping. Rock property measurements performed on outcrops and hand samples throughout the study area constrained the models. The MT data were used to construct a 3D resistivity model that highlights the location of inferred alteration and fluids in the subsurface. Combined MT and potential field results reveal which structures may be most important for controlling hydrothermal fluid migration, as well as which geologic units may host hydrothermal fluids. Our gravity derived depth to basement surface coincides well with the base of shallow conductive anomalies, suggesting hydrothermal fluids may be confined to basin fill sediments and volcanics. This work supports our development of 3D geophysical and geologic models that are focused along the western flank of the northern Shoshone Range and aids the process of selecting sites for temperature gradient drilling.

Nevada↗

Constraints on the mechanism of long-term, steady subsidence at Medicine Lake volcano, northern California, from GPS, leveling, and InSAR

Leveling surveys across Medicine Lake volcano (MLV) have documented subsidence that is centered on the summit caldera and decays symmetrically on the flanks of the edifice. Possible mechanisms for this deformation include fluid withdrawal from a subsurface reservoir, cooling/crystallization of subsurface magma, loading by the volcano and dense intrusions, and crustal thinning due to tectonic extension (Dzurisin et al., 1991 [Dzurisin, D., Donnelly-Nolan, J.M., Evans, J.R., Walter, S.R., 1991. Crustal subsidence, seismicity, and structure near Medicine Lake Volcano, California. Journal of Geophysical Research 96, 16, 319-16, 333.]; Dzurisin et al., 2002 [Dzurisin, D., Poland, M.P., Bürgmann, R., 2002. Steady subsidence of Medicine Lake Volcano, Northern California, revealed by repeated leveling surveys. Journal of Geophysical Research 107, 2372, doi:10.1029/2001JB000893.]). InSAR data that approximate vertical displacements are similar to the leveling results; however, vertical deformation data alone are not sufficient to distinguish between source mechanisms. Horizontal displacements from GPS were collected in the Mt. Shasta/MLV region in 1996, 1999, 2000, 2003, and 2004. These results suggest that the region is part of the western Oregon block that is rotating about an Euler pole in eastern Oregon. With this rotation removed, most sites in the network have negligible velocities except for those near MLV caldera. There, measured horizontal velocities are less than predicted from ∼10 km deep point and dislocation sources of volume loss based on the leveling data; therefore volumetric losses simulated by these sources are probably not causing the observed subsidence at MLV. This result demonstrates that elastic models of subsurface volume change can provide misleading results where additional geophysical and geological constraints are unavailable, or if only vertical deformation is known. The deformation source must be capable of causing broad vertical deformation with comparatively smaller horizontal displacements. Thermoelastic contraction of a column of hot rock beneath the volcano cannot reproduce the observed ratio of vertical to horizontal surface displacements. Models that determine deformation due to loading by the volcano and dense intrusions can be made to fit the pattern of vertical displacements by assuming a weak upper crust beneath MLV, though the subsidence rates due to surface loading must be lower than the observed displacements. Tectonic extension is almost certainly occurring based on fault orientations and focal mechanisms, but does not appear to be a major contributor to the observed deformation. We favor a model that includes a combination of sources, including extension and loading of a hot weak crust with thermal contraction of a cooling mass of rock beneath MLV, which are processes that are probably occurring at MLV. Future microgravity surveys and the planned deployment of an array of continuous GPS stations as part of a Plate Boundary Observatory volcano cluster will help to refine this model.

California↗

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70-100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93-99%) in particulates (>0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560-13,000 g/kg of As and 14-35% weight/weight of Fe. As/Fe ratios (2.5-20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000-100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ 18 O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater.

Maine↗

Numerical modeling of an estuary: A comprehensive skill assessment

Numerical simulations of the Hudson River estuary using a terrain-following, three-dimensional model (Regional Ocean Modeling System (ROMS)) are compared with an extensive set of time series and spatially resolved measurements over a 43 day period with large variations in tidal forcing and river discharge. The model is particularly effective at reproducing the observed temporal variations in both the salinity and current structure, including tidal, spring neap, and river discharge-induced variability. Large observed variations in stratification between neap and spring tides are captured qualitatively and quantitatively by the model. The observed structure and variations of the longitudinal salinity gradient are also well reproduced. The most notable discrepancy between the model and the data is in the vertical salinity structure. While the surface-to-bottom salinity difference is well reproduced, the stratification in the model tends to extend all the way to the water surface, whereas the observations indicate a distinct pycnocline and a surface mixed layer. Because the southern boundary coindition is located near the mouth the estuary, the salinity within the domain is particularly sensitive to the specification of salinity at the boundary. A boundary condition for the horizontal salinity gradient, based on the local value of salinity, is developed to incorporate physical processes beyond the open boundary not resolved by the model. Model results are sensitive to the specification of the bottom roughness length and vertical stability functions, insofar as they influence the intensity of vertical mixing. The results only varied slightly between different turbulence closure methods of k-??, k-??, and k-kl. Copyright 2005 by the American Geophysical Union.

New York↗

Mg-spinel lithology: A new rock type on the lunar farside

High-resolution compositional data from Moon Mineralogy Mapper (M 3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated "OOS" since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (<5% pyroxene, olivine). All OOS surfaces are old and undisturbed since basin formation. They are effectively invisible in image data and are only recognized by their distinctive composition identified spectroscopically. The origin of these unusual lithologies appears to be linked to one or more magmatic intrusions into the lower crust, perhaps near the crust-mantle interface. Processes such as fractional crystallization and gravity settling within such intrusions may provide a mechanism for concentrating the mafic components within zones several kilometers in dimension. The OOS are embedded within highly anorthositic material from the lunar crust; they may thus be near contemporaneous with crustal products from the cooling magma ocean. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Hydrogeology and gain/loss assessment of two lakes contaminated with per- and polyfluoroalkyl substances, vicinity of Joint Base McGuire-Dix-Lakehurst, New Jersey, 2020–21

Per- and polyfluoroalkyl substances (PFAS) have been identified in two lakes near Joint Base McGuire-Dix-Lakehurst (JBMDL) in New Jersey—Little Pine Lake in Pemberton Township and Pine Lake in Manchester Township. The streams that enter these lakes begin in or near JBMDL where sources of PFAS contamination are located. The U.S. Geological Survey, in cooperation with the U.S. Air Force Civil Engineer Center, performed a study of the hydrogeology and the gaining or losing conditions associated with these lakes. Hydrogeologic characteristics in the vicinity of both lakes were assessed using qualitative vertical hydraulic profiling of the subsurface. Groundwater was pumped from test intervals at various depths below land surface, then groundwater levels were measured until they recovered to static conditions. Low permeability aquifer intervals were identified within the aquifer underlying both lakes, consistent with silty and (or) clayey subunits of the Kirkwood-Cohansey aquifer system indicated on geophysical and lithologic logs. Gaining or losing conditions between groundwater and lake surface water were assessed with continuous monitoring of water levels and temperature in the lakes and in three piezometers per lake screened at different depths in the underlying aquifer from August 2020 through May 2021. At Little Pine Lake, surface water levels were consistently lower than groundwater levels, which is indicative of a gaining condition with groundwater flowing into the lake. Gaining conditions also support the lack of diurnal temperature fluctuations observed in groundwater, but poor response of surface-water temperature prevents complete analysis. The potential for losing conditions at other locations around Little Pine Lake necessitates further assessment in regard to possible PFAS contamination of groundwater in the underlying aquifer. Temperature results were inconclusive at Pine Lake, but surface water levels were consistently higher than groundwater levels throughout the monitoring period, which indicates a losing condition with lake water flowing into the underlying aquifer. Because of the downward vertical hydraulic gradient identified at Pine Lake, there is a strong possibility that PFAS in the lake water has also contaminated groundwater in its vicinity.

New Jersey↗

Questa baseline and pre-mining ground-water quality investigation. 25. Summary of results and baseline and pre-mining ground-water geochemistry, Red River Valley, Taos County, New Mexico, 2001-2005

Active and inactive mine sites are challenging to remediate because of their complexity and scale. Regulations meant to achieve environmental restoration at mine sites are equally challenging to apply for the same reasons. The goal of environmental restoration should be to restore contaminated mine sites, as closely as possible, to pre-mining conditions. Metalliferous mine sites in the Western United States are commonly located in hydrothermally altered and mineralized terrain in which pre-mining concentrations of metals were already anomalously high. Typically, those pre-mining concentrations were not measured, but sometimes they can be reconstructed using scientific inference. Molycorp?s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The State of New Mexico requires that ground-water quality standards be met on closure unless it can be shown that potential contaminant concentrations were higher than the standards before mining. No ground water at the mine site had been chemically analyzed before mining. The aim of this investigation, in cooperation with the New Mexico Environment Department (NMED), is to infer the pre-mining ground-water quality by an examination of the geologic, hydrologic, and geochemical controls on ground-water quality in a nearby, or proximal, analog site in the Straight Creek drainage basin. Twenty-seven reports contain details of investigations on the geological, hydrological, and geochemical characteristics of the Red River Valley that are summarized in this report. These studies include mapping of surface mineralogy by Airborne Visible-Infrared Imaging Spectrometry (AVIRIS); compilations of historical surface- and ground- water quality data; synoptic/tracer studies with mass loading and temporal water-quality trends of the Red River; reaction-transport modeling of the Red River; environmental geology of the Red River Valley; lake-sediment chemistry; geomorphology and its effect on ground-water flow; geophysical studies on depth to ground-water table and depth to bedrock; bedrock fractures and their potential influence on ground-water flow; leaching studies of scars and waste-rock piles; mineralogy and mineral chemistry and their effect on ground-water quality; debris-flow hazards; hydrology and water balance for the Red River Valley; ground-water geochemistry of selected wells undisturbed by mining in the Red River Valley; and quality assurance and quality control of water analyses. Studies aimed specifically at the Straight Creek natural-analog site include electrical surveys; high-resolution seismic survey; age-dating with tritium/helium; water budget; ground-water hydrology and geochemistry; and comparison of mineralogy and lithology to that of the mine site. The highly mineralized and hydrothermally altered volcanic rocks of the Red River Valley contain several percent pyrite in the quartz-sericite-pyrite (QSP) alteration zone, which weather naturally to acid-sulfate surface and ground waters that discharge to the Red River. Weathering of waste-rock piles containing pyrite also contributes acid water that eventually discharges into the Red River. These acid discharges are neutralized by circumneutral-pH, carbonate-buffered surface and ground waters of the Red River. The buffering capacity of the Red River, however, decreases from the town of Red River to the U.S. Geological Survey (USGS) gaging station near Questa. During short, but intense, storm events, the buffering capacity is exceeded and the river becomes acid from the rapid flushing of acidic materials from natural scar areas. The lithology, mineralogy, elevation, and hydrology of the Straight Creek proximal analog site were found to closely approximate those of the mine site with the exception of the mine site?s Sulphur Gulch catchment. Sulphur Gulch contains three subcatchments?upper Sulphur Gulch, Blind Gulch, and Spring Gulc

New Mexico↗