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USGS2025

Analyzing multi-year nitrate concentration evolution in Alabama aquatic systems using a machine learning model

Rising nitrate contamination in water systems poses significant risks to public health and ecosystem stability, necessitating advanced modeling to understand nitrate dynamics more accurately. This study applies the long short-term memory (LSTM) modeling to investigate the hydrologic and environmental factors influencing nitrate concentration dynamics in rivers and aquifers across the state of Alabama in the southeast of the United States. By integrating dynamic data such as streamflow and groundwater levels with static catchment attributes, the machine learning model identifies primary drivers of nitrate fluctuations, offering detailed insights into the complex interactions affecting multi-year nitrate concentrations in natural aquatic systems. In addition, a novel LSTM-based approach utilizes synthetic surface water nitrate data to predict groundwater nitrate levels, helping to address monitoring gaps in aquifers connected to these rivers. This method reveals potential correlations between surface water and groundwater nitrate dynamics, which is particularly meaningful given the lack of water quality observations in many aquifers. Field applications further show that, while the LSTM model effectively captures seasonal trends, limitations in representing extreme nitrate events suggest areas for further refinement. These findings contribute to data-driven water quality management, enhancing understanding of nitrate behavior in interconnected water systems.

Alabama↗
USGS2026

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas↗
USGS2026

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas↗
USGS2026

A review and synthesis of post-wildfire shifts in hydrologic processes and streamflow generation mechanisms

Critical water supply watersheds in the western United States (WUS) are impacted by wildfires, with potential negative effects on water quality and quantity. Scientific understanding is currently insufficient to deliver estimates of wildfire consequences for water quantity that are regionally accurate. Regional variability in the directionality and magnitude of post-wildfire shifts in streamflow generation fuels uncertainty in estimates of wildfire effects on water supply. In this work we provide a narrative review of wildfire effects on hydrologic processes and the resulting changes in streamflow generation mechanisms with a focus on the WUS, incorporating other global regions when pertinent. A conceptual model summary of wildfire effects on streamflow generation emphasizes: (1) precipitation seasonality, (2) synchrony of precipitation and potential evapotranspiration, (3) net shifts in interception, evaporation, and transpiration relative to total annual precipitation, (4) vegetation changes, including compensatory uptake and type conversion, (5) degree of overlap in rainfall rates and infiltration, (6) fire extent and severity, (7) burn scar positioning (e.g. in headwaters or proximal to watershed outlet), (8) scale-dependent groundwater leakage, (9) near-surface water storage reduction, and (10) soil to groundwater connectivity. Ongoing gaps and challenges include separating the influences of precipitation variability, water withdrawals, and post-fire land management; compound and overlapping disturbances; and lack of pre-fire data. Notable future opportunities include: harnessing ever-improving gridded and remotely sensed precipitation and fire-effects data; linking geophysical, isotopic tracer, and geochemical signatures to diagnose hydrologic changes; leveraging physically based and data-driven model advancements; and analyzing streamflow generation recovery trajectories across diverse watersheds.

western United States↗
USGS2025

Dietary bioavailability of uranium to a model freshwater invertebrate

Uranium (U) mining increases environmental exposures. Understanding how U is taken up by organisms can aid in evaluating the potential for bioaccumulation and toxicity. Although the importance of aqueous geochemical speciation is well recognized for U bioavailability after dissolved exposures, far less is known about the processes controlling U bioavailability after dietary exposures. This study characterizes the biogeochemical drivers of dietary U uptake in the freshwater snail Lymnaea stagnalis in laboratory experiments. Solids tested included benthic diatoms pre-exposed to dissolved U(VI), soils from contaminated U mine sites, and colloidal hydrous ferric oxide (HFO) synthesized in the presence of dissolved U(VI) or with U complexed by natural organic matter (NOM). Results showed that U was bioavailable from all solids. Uranium assimilation efficiency (AE), a proxy for dietary U bioavailability, varied among solids. AE was lowest for the U-contaminated soils (25 ± 17%) and highest for the U-laden diatoms (71 ± 13%). AE varied slightly among HFO preparations, suggesting modest influences of NOM and iron on U bioavailability. Increases in dietary U exposures reduced feeding rates, and the extent of feeding inhibition appeared inversely related to U bioavailability. The high U assimilation and range of bioavailability have implications for toxicity risks inferred without considering dietary uptake.

Environmental Science and Technology↗
USGS2025

A framework for understanding the effects of subsurface agricultural drainage on downstream flows

Understanding controls on streamflow volume and magnitude is important to water resource management applications, such as critical water and transportation structure design and floodplain mapping. Changes in land use and agricultural practices, such as subsurface agricultural drainage, may be contributing to changes in streamflow characteristics. Subsurface agricultural drainage, also known as tile drainage, is the practice of installing drains in the subsurface of agricultural fields to improve productivity. Because of the complex interactions between subsurface drainage systems, precipitation, local soil conditions, and land management practices, it is difficult to determine how subsurface agricultural drainage affects downstream flow. Previously developed subsurface agricultural drainage conceptual models under dry, saturated, and winter conditions are summarized, and current literature on the effects of subsurface agricultural drainage on downstream flows, focusing on peak flow, non-event flow, and total flow to develop frameworks for discussing these systems is compiled. The effects that subsurface drainage has on hydrologic systems are expected to vary by site and are seasonally based on system design, soil type, moisture conditions, precipitation characteristics, and land conditions. Subsurface drainage can affect the magnitude of peak flow by converting surface runoff from a storm event to subsurface runoff. By increasing hydrologic connectivity of a catchment, subsurface drainage can increase non-event flow or the flow between two storm events, typically dependent on lateral flow through the subsurface and groundwater. Theoretically, by diverting water from groundwater recharge or by reducing water available for evapotranspiration, subsurface drainage may increase the total volume of flow. Precipitation changes may increase infiltration, excess overland flow, and flood risk regardless of the presence or absence of subsurface drainage.

Illinois, Iowa, Michigan, Minnesota, Missouri, Mon↗
USGS1998

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia↗
USGS2025

Integrated stratigraphic and geochemical analysis of organic-rich intervals of the Lewis Shale in the eastern Washakie Basin, Wyoming

Geological studies in the Cretaceous Western Interior Seaway (KWIS) in North America reveal highly variable sedimentological conditions on its western shore caused by rapidly changing sea level and detrital input during the seaway’s closure. Here we examine a 601-foot (183 meters) continuous core through the lower part of the Maastrichtian Lewis Shale in the eastern Washakie Basin, Wyoming, through integrating stratigraphic and geochemical analyses to better understand organic matter deposition and preservation during the final marine transgression within the seaway. The core penetrates eight organic-rich flooding intervals (F1-F8) and a regional condensed section, informally known as the Asquith marker. The lower portions of the core record sediment input from a southern source, likely the Sierra Madre/Park Ranges, while the upper part records sediment input from a northern source, likely the Granite Mountains. This provenance transition is supported by regional stratigraphic analysis and changes in bulk mineral and trace metal composition. The Asquith marker and early flooding surfaces are enriched in oil-prone, marine organic matter deposited under dysoxic to euxinic conditions, whereas younger flooding surfaces show increased terrigenous input and poorer preservation conditions. The Asquith marker is identified as a prime oil-prone source rock. Although younger flooding surfaces also exhibit favorable source-rock properties, their generative potential is reduced due to increased clastic and terrigenous organic matter deposition caused by regression. These results emphasize the importance of sediment source variability, organic matter preservation, and changing redox conditions to provide insight into the sediment provenance and petroleum potential of the Lewis Shale in the context of the final transgression within the KWIS.

Colorado, Wyoming↗
USGS2025

Combining scanning electron microscopy, X-ray diffraction, and X-ray fluorescence to characterize shear zones at the Pogo gold deposit, Alaska

This study employs a multi-method analytical approach to characterize the mineralogical, geochemical, and textural properties of fault rocks from the Pogo gold mine in the Yukon-Tanana Upland, central Alaska. Specifically, we examine cataclasites, to document the structural and geochemical evolution of shear zones and their associations with gold mineralization. To investigate the shear zone, we integrate portable X-ray fluorescence (pXRF), scanning electron microscopy-based automated mineralogy (SEM-AM), X-ray diffraction (XRD), and high-resolution micro-X-ray fluorescence (micro-XRF) mapping. These methods collectively provide insights into bulk and trace element chemistry, mineralogical composition, and deformation-related textures across multiple scales. Handheld pXRF enables rapid geochemical screening, guiding SEM-AM and XRD analyses to ensure consistent mineralogical interpretation. X-ray diffraction identifies and quantifies crystalline phases, while SEM-AM produces high-resolution mineral maps, revealing mineral abundances, grain-scale textures, and gold associations. Micro-XRF mapping further refines our understanding by showing visual trace element distributions at sub-millimetre resolution. By integrating these techniques, we improve our understanding of the nature and geochemistry of Pogo shear zones, their role in gold mineralization, and support metallurgical processing strategies. This approach enhances exploration models and resource characterization for structurally complex gold deposits.

Alaska↗
USGS2025

Annual NLCD (National Land Cover Database)—The next generation of land cover mapping

Introduction The widely used National Land Cover Database (NLCD) has long been the foundational land cover source for scientists, resource managers, and decision makers across the United States. In 2024, a reinvention as Annual NLCD added the key improvement of annual time steps to show decades of change at a higher frequency than the intervals of 2–3 years used in the legacy NLCD. Annual NLCD was derived primarily from the long Landsat satellite data record, and it includes data from other sources. The first release in 2024 of Annual NLCD provides Collection 1.0 of products encompassing land cover and land change from 1985 through 2023 for the conterminous United States (CONUS). The Annual NLCD Collection 1.0 consists of six operational products that map the unique characteristics of land cover. A map created from Annual NLCD shows 16 land cover classes for the CONUS in 2023.

conterminous United States↗
USGS1976

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta↗
USGS2026

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the effects of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study, we constructed the Strawberry Creek integrated hydrological model to increase this understanding. The Strawberry Creek integrated hydrological model is an integrated surface runoff and groundwater model, GSFLOW to simulate surface runoff and infiltration and groundwater flow. The model has 263 rows and 176 columns in each of its three layers. The model area includes the Strawberry Creek and four adjacent watersheds. The precipitation-runoff modeling system was calibrated using two streamflow gaging stations, and the groundwater and surface-water flow model was calibrated to the reported spring diversion discharge and a sparse number of groundwater-level measurements. The Strawberry Creek integrated hydrological model was run with and without diversions active, and simulated streamflow was compared, indicating that in the headwaters of Strawberry Creek, about 35 percent of the diversion flow was captured from base flow.

California↗
USGS2025

Avak Creek oil occurrence, North Slope, Alaska: Newly discovered oil seep on Native lands, near village of Utqiagvik

An unknown occurrence of oil was detected near Avak Creek on Native lands on the North Slope of Alaska. Determining the source of oil was imperative for allowing stakeholders (Federal, State, and local government agencies and the landowner, an Alaska Native corporation) to make timely and informed decisions and mount a mitigation response, if required. The regional and local geological framework of the Avak Creek site was constructed using seismic surveys, well data, and basin modeling results, to identify local petroleum systems, map structural geometry and faults, define source rock thermal maturity distributions, and infer likely oil-migration pathways. Molecular hydrocarbon fingerprints (biomarkers, diamondoids, compound-specific isotopes) of the oil were compared to those of local and regional oil seeps, exploration well tests, and produced oils. Biomarker acid distributions characterized the history and extent of petroleum biodegradation. Integrating subsurface and geochemical parameters, the oil is interpreted to be a natural seep generated locally, predominantly from the Brookian Lower Cretaceous Hue Shale/gamma-ray zone, rather than an anthropogenic source of pollution. Results highlight sophisticated analytical technologies used to characterize complex, compositionally altered hydrocarbons. Results also advance our understanding of Brookian source rock distribution, subsurface petroleum migration pathways, and Arctic Alaska petroleum systems.

Alaska↗
USGS2025

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, situated in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the impact of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study we constructed the Strawberry Creek integrated hydrological model (SCIHM) to increase this understanding. The SCIHM is an integrated surface runoff and groundwater model that uses the coupled groundwater and surface-water flow model (GSFLOW), which is based on the integration of the precipitation-runoff modeling system (PRMS) and the modular groundwater flow model commonly called MODFLOW, version MODFLOW-2005 software to simulate surface runoff and infiltration and groundwater flow. The model has three layers, 263 rows, and 176 columns. The model area includes the Strawberry Creek and four adjacent watersheds. The PRMS model was calibrated using two streamflow gaging stations and the GSFLOW model was calibrated to reported spring diversion discharge and a sparse number of groundwater-level measurements. The SCIHM was run with and without diversions active and simulated streamflow was compared, finding that in the headwaters of Strawberry Creek about 35 percent of the diversion flow was captured from base flow.

EarthArXiv↗
USGS2025

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research↗
USGS2026

USGS Geochron—A database of geochronological and thermochronological dates and data—Technical documentation

Geochronological and thermochronological data are essential for constraining the timing and rates of geological processes, supporting geologic mapping, natural hazard assessment, and resource exploration. The U.S. Geological Survey (USGS) Geochron Database is a centralized, relational database that integrates USGS and State geological survey data in accordance with the National Geologic Mapping Act of 1992 and its reauthorizations. This report documents the structure and development of the database, including its standardized schema, controlled vocabularies, and protocols for compiling legacy and newly published data. The database is designed to adhere to FAIR (Findable, Accessible, Interoperable, and Reusable) data principles and currently (2026) includes data from a wide range of geochronological and thermochronological methods. Public access is provided through the USGS Geochron Database Explorer, a browser-based geographic information system (GIS) interface, and through versioned data releases available on ScienceBase, which provide sample-level summary data and detailed analytical information. The USGS Geochron Database is structured to be extensible, supporting the inclusion of additional methods and data types as they are compiled. This format ensures long-term utility and aligns with the Mapping Act’s directive to create a national archive of geochronological information that adds interpretive value to geologic map data. Its design reflects a commitment to data transparency, scientific reproducibility, and national geoscience priorities.

Data Report↗
USGS2025

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita↗
USGS2025

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

Florida↗