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Minerals Yearbook, volume II, Area Reports — Domestic

The U.S. Geological Survey (USGS) Minerals Yearbook discusses the performance of the worldwide minerals and materials industries and provides background information to assist in interpreting that performance. Content of the individual Minerals Yearbook volumes follows: Volume I, Metals and Minerals , contains chapters about virtually all metallic and industrial mineral commodities important to the U.S. economy. Chapters on survey methods, summary statistics for domestic nonfuel minerals, and trends in mining and quarrying in the metals and industrial mineral industries in the United States are also included. Volume II, Area Reports: Domestic , contains a chapter on the mineral industry of each of the 50 States and Puerto Rico and the Administered Islands. This volume also has chapters on survey methods and summary statistics of domestic nonfuel minerals. Volume III, Area Reports: International , is published as four separate reports. These regional reports contain the latest available minerals data on more than 180 foreign countries and discuss the importance of minerals to the economies of these nations and the United States. Each report begins with an overview of the region’s mineral industries during the year. It continues with individual country chapters that examine the mining, refining, processing, and use of minerals in each country of the region and how each country’s mineral industry relates to U.S. industry. Most chapters include production tables and industry structure tables, information about Government policies and programs that affect the country’s mineral industry, and an outlook section. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the Minerals Yearbook are welcome.

Minerals Yearbook↗

Minerals Yearbook, volume III, Area Reports — International

The U.S. Geological Survey (USGS) Minerals Yearbook discusses the performance of the worldwide minerals and materials industries and provides background information to assist in interpreting that performance. Content of the individual Minerals Yearbook volumes follows: Volume I, Metals and Minerals , contains chapters about virtually all metallic and industrial mineral commodities important to the U.S. economy. Chapters on survey methods, summary statistics for domestic nonfuel minerals, and trends in mining and quarrying in the metals and industrial mineral industries in the United States are also included. Volume II, Area Reports: Domestic , contains a chapter on the mineral industry of each of the 50 States and Puerto Rico and the Administered Islands. This volume also has chapters on survey methods and summary statistics of domestic nonfuel minerals. Volume III, Area Reports: International , is published as four separate reports. These regional reports contain the latest available minerals data on more than 180 foreign countries and discuss the importance of minerals to the economies of these nations and the United States. Each report begins with an overview of the region’s mineral industries during the year. It continues with individual country chapters that examine the mining, refining, processing, and use of minerals in each country of the region and how each country’s mineral industry relates to U.S. industry. Most chapters include production tables and industry structure tables, information about Government policies and programs that affect the country’s mineral industry, and an outlook section. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the Minerals Yearbook are welcome.

Minerals Yearbook↗

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids, acidity, alkalinity, Cl - , F - and SO 4 2- found in receiving streams, rivers, and lakes are affected by all of these factors and their interactions. Remediation of mine sites is an engineering concern but to design a remediation plan without understanding the hydrogeochemical processes of contaminant mobilization can lead to ineffective and excessively costly remediation. Furthermore, remediation needs a goal commensurate with natural background conditions rather than water-quality standards that might bear little relation to conditions of a highly mineralized terrain. This paper reviews hydrogeochemical generalizations, primarily from US Geological Survey research, that enhance our understanding of the origin, transport, and fate of contaminants released from mined and mineralized areas. Mobility of potential or actual contaminants from mining and mineral processing activities depends on (1) occurrence : is the mineral source of the contaminant actually present? (2) abundance : is the mineral present in sufficient quantity to make a difference? (3) reactivity : what are the energetics, rates, and mechanisms of sorption and mineral dissolution and precipitation relative to the flow rate of the water? and (4) hydrology : what are the main flow paths for contaminated water? Estimates of relative proportions of minerals dissolved and precipitated can be made with mass-balance calculations if minerals and water compositions along a flow path are known. Combined with discharge, these mass-balance estimates quantify the actual weathering rate of pyrite mineralization in the environment and compare reasonably well with laboratory rates of pyrite oxidation except when large quantities of soluble salts and evaporated mine waters have accumulated underground. Quantitative mineralogy with trace-element compositions can substantially improve the identification of source minerals for specific trace elements through mass balances. Post-dissolution sorption and precipitation (attenuation) reactions depend on the chemical behavior of each element, solution composition and pH, aqueous speciation, temperature, and contact-time with mineral surfaces. For example, little metal attenuation occurs in waters of low pH (<3.5) and metals tend to maintain element ratios indicative of the main mineral or group of minerals from which they dissolved, except Fe, SiO 2 , and redox-sensitive oxyanions (As, Sb, Se, Mo, Cr, V). Once dissolved, metal and metalloid concentrations are strongly affected by redox conditions and pH. Iron is the most reactive because it is rapidly oxidized by bacteria and archaea and Fe(III) hydrolyzes and precipitates at low pH (1&ndash;3) which is related directly to its first hydrolysis constant, pK 1 = 2.2. Several insoluble sulfate minerals precipitate at low pH including anglesite, barite, jarosite, alunite and basaluminite. Aluminum hydrolyzes near pH 5 (pK 1 = 5.0) and provides buffering and removal of Al by mineral precipitation from pH 4&ndash;5.5. Dissolved sulfate behaves conservatively because the amount removed from solution by precipitation is usually too small relative to the high concentrations in the water column and relative to the flow rate of the water.

Applied Geochemistry↗

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation, and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka Marine Terrace Chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized [White A. F., Schulz M. S., Vivit D. V., Blum A., Stonestrom D. A. and Anderson S. P. (2008) Chemical weathering of a Marine Terrace Chronosequence, Santa Cruz, California. I: interpreting the long-term controls on chemical weathering based on spatial and temporal element and mineral distributions. Geochim. Cosmochim. Acta 72 (1), 36-68] and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisserand [Hellmann R. and Tisserand D. (2006) Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar. Geochim. Cosmochim. Acta 70 (2), 364-383] or the aluminum inhibition model proposed by Oelkers et al. [Oelkers E. H., Schott J. and Devidal J. L. (1994) The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim. Cosmochim. Acta 58 (9), 2011-2024], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site. Additionally, observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO 2 (aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws. ?? 2009 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

Western Mineral and Environmental Resources Science Center--providing comprehensive earth science for complex societal issues

Minerals in the environment and products manufactured from mineral materials are all around us and we use and come into contact with them every day. They impact our way of life and the health of all that lives. Minerals are critical to the Nation's economy and knowing where future mineral resources will come from is important for sustaining the Nation's economy and national security. The U.S. Geological Survey (USGS) Mineral Resources Program (MRP) provides scientific information for objective resource assessments and unbiased research results on mineral resource potential, production and consumption statistics, as well as environmental consequences of mining. The MRP conducts this research to provide information needed for land planners and decisionmakers about where mineral commodities are known and suspected in the earth's crust and about the environmental consequences of extracting those commodities. As part of the MRP scientists of the Western Mineral and Environmental Resources Science Center (WMERSC or 'Center' herein) coordinate the development of national, geologic, geochemical, geophysical, and mineral-resource databases and the migration of existing databases to standard models and formats that are available to both internal and external users. The unique expertise developed by Center scientists over many decades in response to mineral-resource-related issues is now in great demand to support applications such as public health research and remediation of environmental hazards that result from mining and mining-related activities. Western Mineral and Environmental Resources Science Center Results of WMERSC research provide timely and unbiased analyses of minerals and inorganic materials to (1) improve stewardship of public lands and resources; (2) support national and international economic and security policies; (3) sustain prosperity and improve our quality of life; and (4) protect and improve public health, safety, and environmental quality. The MRP supports approximately 40 USGS research specialists who utilize cooperative agreements with universities, industry, and other governmental agencies to support their collaborative research and information exchange. Scientists of the WMERSC study how and where non-fuel mineral resources form and are concentrated in the earth's crust, where mineral resources might be found in the future, and how mineral materials interact with the environment to affect human and ecosystem health. Natural systems (ecosystems) are complex - our understanding of how ecosystems operate requires collecting and synthesizing large amounts of geologic, geochemical, biologic, hydrologic, and meteorological information. Scientists in the Center strive to understand the interplay of various processes and how they affect the structure, composition, and health of ecosystems. Such understanding, which is then summarized in publicly available reports, is used to address and solve a wide variety of issues that are important to society and the economy. WMERSC scientists have extensive national and international experience in these scientific specialties and capabilities - they have collaborated with many Federal, State, and local agencies; with various private sector organizations; as well as with foreign countries and organizations. Nearly every scientific and societal challenge requires a different combination of scientific skills and capabilities. With their breadth of scientific specialties and capabilities, the scientists of the WMERSC can provide scientifically sound approaches to a wide range of societal challenges and issues. The following sections describe examples of important issues that have been addressed by scientists in the Center, the methods employed, and the relevant conclusions. New directions are inevitable as societal needs change over time. Scientists of the WMERSC have a diverse set of skills and capabilities and are proficient in the collection and integration of

Circular↗

Locatable Mineral Reports for Colorado, South Dakota, and Wyoming provided to the USDA Forest Service in Fiscal Years 2006-2009

The U.S. Geological Survey is required by Congress (under Public Law 86-509) to provide Locatable Mineral Reports to the USDA Forest Service whenever National Forest System lands are sold or exchanged. This volume is a compilation of the reports already provided to the Forest Service by the author in fiscal years 2006-2009 (October 2006-September 2009). Altogether, the reports describe the geology and locatable mineral resource potential of 57 properties offered in 10 land-exchange proposals. Approximately 41,084 acres were evaluated: 19,068 acres in Federal parcels and 22,016 acres in non-Federal parcels. The parcels are located in eight National Forests and one National Grassland in three States. Locatable Mineral Reports provide a summary of the geology and a subjective appraisal of the mineral resource potential of land parcels considered for exchange. Information in each report is based on a review of published maps and reports, unpublished data in U.S. Geological Survey files, the professional expertise of the writer, and interviews with other knowledgeable geoscientists. No visits were conducted to support the reports included in this volume. The mineral resource information provided is used in making relative comparisons of the potential future mineral value of lands being offered in an exchange and in appraising the value of the land. Future mineral potential value is subjectively expressed in qualitative terms using a three-tier nomenclature of 'high,' 'moderate,' and 'low.' In general, 'high' is applied where mineral deposits are present on the property or adjacent to it or there are other indications that the area has been mineralized. 'Moderate' is applied where mineralization is only suspected or where an area possesses some of the same geologic characteristics that are common to areas around known mineral deposits. A 'low' value is routinely applied to all remaining areas, with the understanding that the information required to prove the absence of any mineral resource potential will never be available. Copies of the reports reside in U.S. Geological Survey Mineral Resource Program and USDA Forest Service files. Ten reports are included in this volume. They are grouped by State, then alphabetically by Forest. Each starts with a cover letter and title page. Geologic descriptions of properties, their mineral potential, and references make up the main body of each report. Legal descriptions of the property locations (either verbatim or paraphrased from descriptions supplied by the Forest Service) are included as attachments designated Exhibits A and B. Also included as attachments are the report request from the USDA Forest Service and any index maps, geologic maps, or other figures or illustrations that are provided for the convenience of the Forest Service minerals examiner. Page numbers for each individual report are retained: the larger number at the bottom of each page is the pagination for this volume.

Colorado, South Dakota, Wyoming↗

Preliminary report on Tertiary volcanism and uranium mineralization in the Thomas Range and northern Drum Mountains, Juab County, Utah

The Thomas Range and northern Drum Mountains have a history of volcanism, faulting, and mineralization that began about 42 m.y. ago. Volcanic activity and mineralization in the area can be divided into three stages according to the time-related occurrence of rock types, trace element associations, and chemical nature of mineralization. Volcanic activity switched abruptly from rhyodacite-quartz latite (42-39 m.y. ago) to rhyolite (38-32 m.y. ago) to alkali rhyolite stages (21 and 6-7 m.y. ago); these stages correspond to periods of chalcophile and siderophile metal mineralization, no mineralization, and lithophile metal mineralization, respectively. Angular unconformities record episodes of cauldron collapse and block faulting between the stages of volcanic activity and mineralization. The youngest angular unconformity formed between 21 and 7 m.y. ago during basin-and-range faulting. Early rhyodacite-quartz latite volcanism from composite volcanoes and fissures produced flows, breccias, and ash-flow tuff of the Drum Mountains Rhyodacite and Mt. Laird Tuff. Eruption of the Mt. Laird Tuff about 39 m.y. ago from an area north of Joy townsite was accompanied by collapse of the Thomas caldera. Part of the roof of the magma chamber did not collapse, or the magma was resurgent, as is indicated by porphyry dikes and plugs in the Drum Mountains. Chalcophile and siderophile metal mineralization, including copper, gold, and manganese, accompanied early volcanism. The middle stage of volcanic activity was characterized by explosive eruption of rhyolitic ash-flow tuffs and collapse of the Dugway Valley cauldron. Eruption of the Joy Tuff 38 m.y. ago was accompanied by subsidence of this cauldron and followed by collapse and sliding of Paleozoic rocks from the west wall of the cauldron. Landslides in The Dell were covered by the Dell Tuff, erupted 32 m.y. ago from an unknown source to the east. An ash-flow of the Needles Range Formation was erupted 30-31 m.y. ago, probably from a distant source outside the volcanic field. The rhyolitic stage of volcanism was barren of mineralization. The last stage of volcanism was contemporaneous with basin-and-range faulting and was characterized by explosive eruption of ash and pumice, forming stratified tuff, and by quiet eruption of alkali rhyolite as viscous flows and domes. The first episode of alkali rhyolite volcanism deposited the beryllium tuff and porphyritic rhyolite members of the Spor Mountain Formation 21 m.y. ago. After a period of block faulting, the stratified tuff and alkali rhyolite of the Topaz Mountain Rhyolite were erupted 6-7 m.y. ago along faults and fault intersections. Erosion of Spor Mountain may have provided abundant dolomite detritus to the beryllium tuff member. The alkali rhyolite of both formations is fluorine-rich, as is evident from abundant topaz, and contains anomalous amounts of lithophile metals. Alkali rhyolite volcanism was accompanied by lithophile metal mineralization which deposited fluorite, beryllium, and uranium. The structure of the area is dominated by the Thomas caldera, and the younger Dugway Valley cauldron, which is nested within the Thomas caldera; the Thomas caldera is surrounded by a rim of Paleozoic rocks at Spor Mountain and Paleozoic to Precambrian rocks in the Drum Mountains. The Joy fault and Dell fault system mark the ring fracture zone of the Thomas caldera. These structural features began to form about 39 m.y. ago during eruption of the Mt. Laird Tuff and cauldon subsidence. The Dugway Valley cauldron sank along a series of step-like normal faults southeast of Topaz Mountain in response to collapse of the magma chamber of the Joy Tuff. The caldera structure was modified by block faulting between 21 and 7 m.y. ago, the time of widespread extensional faulting in the basin-and-range province. Vents erupted alkali rhyolite 6-7 m.y. ago along basin-and-range faults. Uranium mineralization was associated with the stage of alkali rhyolite volcanism, extensional basin-and-range faulting, and lithophile metal mineralization; it occurred at least 11 m.y. after the end of the caldera cycle. Uranium, derived from alkali rhyolite magma, was concentrated in trace amounts by magmatic fluids and in potentially economic amounts by hydrothermal fluids and ground water. Hydrothermal fluids deposited uraniferous fluorite as pipes in carbonate rocks of Paleozoic age on Spor Mountain and uranium-bearing disseminated deposits of fluorite and beryllium in the beryllium tuff member of the Spor Mountain Formation. Uranium of hydrothermal origin is dispersed in fluorite and opal. Uranium in fluorite may be tetravalent(?) but that in opal is probably hexavalent; no primary minerals of tetravalent uranium are known to occur. Ground waters have concentrated significant ores of hexavalent uranium minerals in the beryllium tuff member of the Spor Mountain Formation at the Yellow Chief Mine, and are probably also responsible for widespread low concentrations (0.0X percent) of uranium that occur separately from beryllium ore in the beryllium tuff member. More deposits of the Yellow Chief type may occur in down-faulted sections of beryllium tuff beneath the Thomas Range. The ground water ores show no evidence of a reducing environment; instead, precipitation of hexavalent uranium minerals occurred by evaporation, decline in concentration of complexing ions such as carbonate, or some other mechanism. Reducing environments for hydrothermal deposits must be sought around rhyolite vents and in a hypothesized pluton of alkali rhyolite composition beneath Spor Mountain; for ground-water deposits, reducing environments may occur in basin fill such as that of the Dugway Valley cauldron.

Utah↗

Global mineral resource assessment

Introduction In response to the growing demand for information on the global mineral-resource base, the U.S. Geological Survey (USGS) is conducting the Quantitative Global Mineral Resource Assessment Project (GMRAP), a cooperative international project, begun in 2002, to assess the world's undiscovered nonfuel mineral resources. Primary Objectives The USGS conducts national and global assessments of resources (mineral, energy, water, biologic) to provide science in support of decisionmaking. Mineral resource assessments provide a synthesis of available information about where mineral deposits are known and suspected in the Earth&rsquo;s crust, what commodities may be present, and estimates of amounts of resources that may be present in undiscovered deposits. The Global Mineral Resource Assessment Project started in 2002 as a cooperative international effort to assess the world&rsquo;s undiscovered nonfuel mineral resources. Primary objectives are to: Outline the regional locations and estimate the probable amounts of the world&rsquo;s undiscovered resources of copper, platinum-group elements (PGE), and potash in selected types of mineral deposits to depths of 1 to 3 kilometers below the Earth&rsquo;s surface. Provide the first globally consistent and comprehensive analysis of undiscovered nonfuel mineral resources to provide all nations with a regional and global context for evaluating their mineral resources, planning for new mineral exploration and anticipating the economic, environmental, and social impacts of mineral development, and making land use decisions. The project emphasizes the most important types of mineral deposits for world supply of copper, platinum-group elements (PGE) and nickel, and potash. Go to the Quantitative Global Mineral-Resource Assessments home page for more information.

Scientific Investigations Report↗

Systematic variation of rare-earth elements in cerium-earth minerals

In a continuation of a study reported previously, rare-earth elements and thorium have been determined in monazite, allanite, cerite, bastnaesite, and a number of miscellaneous cerium-earth minerals. A quantity called sigma (∑), which is the sum of the atomic percentages of La, Ce, and Pr, is proposed as an index of composition of all cerium-earth minerals with respect to the rare-earth elements. The value of ∑ for all of the minerals analysed falls between 58 and 92 atomic per cent. Monazites, allanites, and cerites cover the entire observed range, whereas bastnaesites are sharply restricted to the range between 80 and 92 atomic per cent. The minimum value of ∑ for a cerium-earth mineral corresponds to the smallest possible unit-cell size of the mineral. In monazite, this structurally controlled minimum value of ∑ is estimated to be around 30 atomic per cent. Neodymium, because of its abundance, and yttrium, because of its small size, have dominant roles in contraction of the structure. In the other direction, the limit of variation in composition will be reached when lanthanum becomes the sole rare-earth element in a cerium-earth mineral. Cerium-earth minerals from alkalic rocks are all characterized by values of ∑ greater than 80 atomic per cent, indicating that the processes that formed these rocks were unusually efficient in fractionating the rare-earth elements—efficient in the sense that a highly selected assemblage is produced without eliminating the bulk of these elements. Analyses of inner and outer parts of two large crystals of monazite from different deposits show no difference in ∑ in one crystal and a slightly smaller value of ∑ in the outer part of the other crystal compared to the inner part. The ∑ of monazites from pegmatites that intrude genetically related granitic rocks in North Carolina is found to be either higher or lower than the ∑ of monazites in the intruded host rock. These results indicate that the fractionation of the rare-earth elements is not a simple unidirectional process. When a cerium-earth mineral undergoes replacement, its rare-earth elements may be fractionated into two parts, one forming a new mineral with ∑ that is smaller, and the other a second new mineral with ∑ that is larger than that of the original mineral. The complete analysis of a cerium-earth mineral to determine its ∑ is time consuming. The discovery of a direct relationship between ∑ and the Ce/(Nd + Y) atomic ratio in cerium earth minerals allows a rapid determination of ∑ from spectrograms obtained in a previously described method for determining thorium in these minerals.

Geochimica et Cosmochimica Acta↗

Primary borates in playa deposits: Minerals of high hydration

The primary borate minerals in nonmarine bedded borate deposits - those of the playa type, and their deformed derivatives - are the high hydrates. Both field and laboratory data indicate that the high hydrates are the borate minerals that form stable phases at the lowest temperatures: under the surface conditions of playas. From a study of hand specimens of borate minerals from the new Turkish borate deposits, Meixner suggested that the borate minerals having the lowest specific gravity, and hence, highest water content, are the primary minerals. The role of temperature in the formation of the hydrous borates is shown by solid phases in the system Na 2 B 4 O 7 -H 2 O. As temperature increases, hydration of the solid phase decreases successively from borax (10H 2 O) through tincalconite (5H 2 O), kernite (4H 2 O), to metakernite (2H 2 O). This suggests that in the temp- erature ranges considered in the present paper - those of playas - the high hydrate (borax) is the one most likely to form as the primary mineral in nature. Studies of the Ca, Mg, and Ca-Na hydrous borate systems suggest that the same statement holds in these systems. Until recently, only borax and ulexite (Na 2 O . 2CaO . 5B 2 O 3 . 16H 2 O) have been known as primary minerals of playa deposits. However, inderite (2MgO . 3B 2 O 3 . 15H 2 O) has recently been found as a primary mineral I 5i in Argentina and primary inyoite (2CaO . 3B 2 O 3 . 13H 2 O) has been found in Peru. These 4 minerals are the high hydrates of their respective mineral series. None of the lower hydrates are known as primary minerals in nonmarine bedded deposits. On burial and deformation of the primary minerals, the changes in temperatures and pressures are almost certainly in such a direction as to encourage minerals of higher density and lower hydration to become stable phases. Field evidence bears this out; in all deformed deposits secondary minerals of low hydration are quantitatively important.

Economic Geology↗

Recent trends in the nonfuel minerals industry of Iran

Summary In response to the recent removal of international sanctions on Iran, including the lifting of &ldquo;secondary&rdquo; sanctions by the United States on investment into and trade with Iran, the U.S. Geological Survey National Minerals Information Center compiled and analyzed available information on the current state of Iran&rsquo;s nonfuel minerals industry. This Circular features a new map and table that identify existing mines and mineral-processing facilities and provide information on location, ownership, and capacity for metals and industrial minerals whose output levels may substantially change in the near future. Additionally, the report covers Iran&rsquo;s mineral resources and reserves, official mineral production targets for 2025, and current output and share of global mineral production. Recent trends and developments in individual mineral commodities are discussed, including mineral exploration and partnerships with foreign investors. The U.S. Geological Survey estimated that Iran held globally significant reserves of feldspar (2d largest in the world), barite (5th largest), gypsum (5th largest), fluorspar (8th largest), and iron ore (10th largest). The Government of Iran claimed to also have significant reserves of chromium, copper, gold, manganese, phosphate rock, and zinc. In 2014, Iran was the second-leading producer of gypsum and the sixth-leading producer of barite, with 6.1 percent and 3.6 percent of world output, respectively. Iran was also the world&rsquo;s 7th-leading producer of cement, feldspar, and fluorspar; 8th-leading producer of bentonite; 9th-leading producer of molybdenum; 11th-leading producer of iron ore; and 14th-leading producer of crude steel. The Government of Iran plans to quadruple the output of aluminum, copper cathode, direct-reduced iron, and iron ore pellets; triple that of crude steel and gold; and double that of cement, pig iron, and zinc by 2025. It also plans to double the contribution of mining and to quadruple that of mineral processing to the national economy in the next decade. In order to achieve these major goals, the construction and expansion of several mines and mineral facilities are planned or under development. Whether Iran&rsquo;s annual mineral production increases as rapidly as envisioned by the Government will depend largely on the amount of foreign investment into the minerals industry; integration of modern technology into mineral facilities; and availability of energy to aluminum, copper, and steel plants at competitive prices to international investors.

Circular↗

Focus areas for data acquisition for potential domestic resources of 13 critical minerals in the conterminous United States and Puerto Rico — Antimony, barite, beryllium, chromium, fluorspar, hafnium, helium, magnesium, manganese, potash, uranium, vanadium, and zirconium

The Earth Mapping Resources Initiative (Earth MRI) is conducted in phases to identify areas for acquiring new geologic framework data to identify potential domestic resources of the 35 mineral materials designated as critical minerals for the United States. This report describes the data sources and summary results for 13 critical minerals evaluated in the conterminous United States and Puerto Rico during phase 3 of the study (antimony, barite, beryllium, chromium, fluorspar, hafnium, helium, magnesium, manganese, potash, uranium, vanadium, and zirconium). Phases 1 and 2 of the Earth MRI addressed aluminum, cobalt, graphite, lithium, niobium, platinum-group elements (PGEs), rare earth elements (REEs), tantalum, tin, titanium, and tungsten. Critical minerals in Alaska are covered in a separate report. No focus areas for phase 3 critical minerals are delineated for Hawaii. The geologic, geochemical, topographic, and geophysical mapping provided by the Earth MRI documents geologic features that reflect the extent of individual mineral systems and provides information about critical mineral deposits that may not have been previously considered. The mineral-systems approach links critical mineral commodities to deposit types that represent the manifestations of large mineral systems. Each of the 13 critical mineral commodities for phase 3 of the Earth MRI is discussed in terms of its importance to the Nation’s economy, modes of occurrence, mineral systems, and deposit types, and is accompanied by maps and tables listing examples of focus areas in the conterminous United States and Puerto Rico. Examples of important mineral systems for this group of 13 critical minerals include basin brine path systems for barite and fluorspar, Carlin-type systems and Coeur d’Alene systems for antimony, chemical weathering and volcanogenic seafloor systems for manganese, Climax-type systems for beryllium, mafic magmatic systems for chromium, marine evaporite systems for potash and magnesium, meteoric recharge systems for uranium, petroleum systems for helium, and placer systems for zirconium and hafnium.

Open-File Report↗

Mineral Commodity Summaries 2008

Each chapter of the 2008 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production and resources. The MCS is the earliest comprehensive source of 2007 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. National reserves and reserve base information for most mineral commodities found in this report, including those for the United States, are derived from a variety of sources. The ideal source of such information would be comprehensive evaluations that apply the same criteria to deposits in different geographic areas and report the results by country. In the absence of such evaluations, national reserves and reserve base estimates compiled by countries for selected mineral commodities are a primary source of national reserves and reserve base information. Lacking national assessment information by governments, sources such as academic articles, company reports, common business practice, presentations by company representatives, and trade journal articles, or a combination of these, serve as the basis for national reserves and reserve base information reported in the mineral commodity sections of this publication. A national estimate may be assembled from the following: historically reported reserves and reserve base information carried for years without alteration because no new information is available; historically reported reserves and reserve base reduced by the amount of historical production; and company reported reserves. International minerals availability studies conducted by the U.S. Bureau of Mines, before 1996, and estimates of identified resources by an international collaborative effort (the International Strategic Minerals Inventory) are the basis for some reserves and reserve base estimates. The USGS collects information about the quantity and quality of mineral resources but does not directly measure reserves, and companies or governments do not directly report reserves or reserve base to the USGS. Reassessment of reserves and reserve base is a continuing process and the intensity of this process differs for mineral commodities, countries, and time period. Abbreviations and units of measure, and definitions of selected terms used in the report, are in Appendix A and Appendix B, respectively. A resource/reserve classification for minerals, based on USGS Circular 831 (published with the U.S. Bureau of Mines) is Appendix C, and a directory of USGS minerals information country specialists and their responsibilities is Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the MCS 2008 are welcomed.

Mineral Commodity Summaries↗

Analysis of aquifer mineralization by paleodrainage channels

Mineralization of groundwater resources is a problem in south-central Kansas, due to the penetration of saline water from Permian bedrock formations into the overlying alluvial aquifer. One of the mechanisms involved in the mineralization involves small bedrock features of high permeability located in places occupied by streams and rivers in past geological eras. These geological features are termed 'paleodrainage channels'. The permeability of the overlying aquifer can be significantly smaller than that of the channel fill material. The comparatively fast migration of saline water through these channels of high permeability is associated with the transfer of minerals into the overlying freshwater aquifer. This study applies a set of boundary layer approaches to quantify the process of mineral transfer from the channels into the aquifer. The methods used in the present study provide quick estimation and evaluation of the dilution of the channel flow, as well as mineral concentration profile changes in the mineralized zone created in the overlying aquifer. More generally, the method can also be useful for the analysis and evaluation of various types of groundwater contamination in heterogeneous aquifers. The application of the method is exemplified by a complete set of calculations characterizing the possible mineralization process at a specific channel in south central Kansas. Sensitivity analyses are performed and provide information about the importance of the various parameters that affect the mineralization process. Some possible scenarios for the aquifer mineralization phenomena are described and evaluated. It is shown that the channel mineralization may create either several stream tubes of the aquifer with high mineral concentration, or many stream tubes mineralized to a lesser extent. Characteristics of these two patterns of aquifer mineralization are quantified and discussed. ?? 2003 Published by Elsevier Science B.V.

Journal of Hydrology↗

Stratigraphic framework and heavy minerals of the continental shelf of Onslow and Long Bays, North Carolina

One hundred fourteen vibracores from the Atlantic continental shelf offshore of southeastern North Carolina were opened, described, and processed over several contract years (years 6-9) of the Minerals Management Service-Association of American State Geologists Continental Margins program. Reports for years 9 and 10 of the program compiled the results of the work and assembled the data for release as an interactive CD-ROM report, respectively. The continental shelf of Onslow and Long Bays consists predominantly of outcropping Cretaceous through late Tertiary geologic units. Nearshore these units are covered and incised by late Tertiary and Quaternary units. From oldest to youngest, formally recognized geologic units mapped as part of this study are the Late Cretaceous Peedee Formation-a muddy, fine- to medium-grained quartz sand with trace amounts of glauconite and phosphate; the Paleocene Beaufort Formation-a muddy, fine- to medium-grained glauconitic quartz sand with locally occurring turritelid-mold biosparrudite; the middle Eocene Castle Hayne Formation-a sandy bryozoan biomicrudite and biosparrudite; the Oligocene River Bend Formation-a sandy molluscan-mold biosparrudite; and the Miocene Pungo River Formation-a medium-grained, poorly sorted slightly shelly phosphatic sand. Informal units include a very widespread, unnamed fine- to very fine grained, well-sorted, dolomitic muddy quartz sand that is biostratigraphically equivalent to the Oligocene River Bend Formation; several large valley-fill lithosomes composed of biomicrudite, biomicrite, and biosparrudite of Plio/Pleistocene age; muddy, shelly sands and silty clays of Pliocene, Pleistocene, or mixed Plio/Pleistocene age; and loose, slightly shelly, medium- to coarse-grained sands assigned a Holocene age. Heavy minerals (SG > 2.96) comprise an average of 0.54 wt% (on a bulk-sample basis) of the sediments in 306 samples derived from the 114 vibracores. Heavy-mineral content ranges from <0.01 to 3.69 wt%. The economic heavy mineral content (EHM = ilmenite + zircon + rutile + aluminosilicates + leucoxene [altered ilmenite] + monazite) of the bulk samples averages 0.26 wt% in a range of <0.01-1.70 wt%. As a percentage of the heavy-mineral concentrate, the average EHM value is 45.78% in a range of 0.27-68.60%. The distribution of heavy minerals offshore of southeastern North Carolina is controlled by the lithostratigraphic framework. The unnamed Oligocene sand unit has the highest heavy-mineral content, averaging 0.86 wt% on a bulk-sample basis. The remaining geologic units and their heavy-mineral content (in decreasing order of abundance) are Beaufort (0.64%), Holocene sand (0.60%), Plio-Pleistocene muddy sand and silty clay (0.59%), Peedee (0.42%), River Bend (0.34%), Plio-Pleistocene carbonate (0.12%), and Castle Hayne (0.08%). The heavy-mineral assemblage is fairly consistent throughout the different units. Significantly smaller percentages of heavy minerals correlate with increased amounts of CaCO 3 in the sediments. The sediments analyzed in this study have significantly lower overall heavy-mineral content, as well as lower EHM content than sediments that are known to host commercially important heavy-mineral deposits in the southeastern United States. The potential for economic deposits of heavy minerals in the area of this study, therefore, appears to be limited.

Marine Georesources and Geotechnology↗

Titanium, vanadium, and niobium mineralization and alkali metasomatism from the Magnet Cove complex, Arkansas

The Christy Ti-V-Nb deposit is hosted by the Arkansas Novaculite, adjacent to the carbonatite-alkaline Magnet Cove Complex. Mineralized rock contains up to 8 wt percent Ti, 2.68 wt percent V, and 0.124 wt percent Nb. Minor amounts of Li and Mo are present, and there is evidence for the preferential concentration of the middle to heavy rare earth elements (REE) in altered clay-rich dikes. Mineralized rock consists of (1) thermally recrystallized novaculite that is partly replaced by actinolite, sodic amphibole, taeniolite (KLiMg 2 Si 4 O 10 F 2 ), pyrite,and siderite, (2) brookite-bearing amphibole- and taeniolite-rich rock that contains siderite and pyrite, (3) quartz-brookite aggregates, and (4) goethite-rich rocks that form the oxidized zone of the deposit. Unaltered rock is scarce at the Christy deposit. Comparison of mineralized lithologies from the Christy deposit with those from two other areas of mineralization associated with the Magnet Cove Complex, the Magnet Cove Titanium Corporation deposit ("Rutile deposit") and the Hardy-Walsh prospect, provides mineralogical and chemical evidence for the source of the mineralizing fluids at the Christy deposit.Massive clay-rich (kaolinite + or - smectite) dikes are in contact with the mineralized zones of the Christy deposit. The presence of relict K feldspar and pyrite in the least altered dikes and certain characteristic trace elements (e.g., Ba, Rb) suggest that the Christy dikes are related to less pervasively altered rutile-mineralized, pyrite-bearing carbonate-feldspar dikes fromthe Rutile deposit. The feldspar-carbonate dikes from the Rutile deposit may be the products of intense alkali metasomatism of alkaline igneous silicate rocks that were emplaced prior to the intrusion of the Magnet Cove carbonatite.The Christy deposit formed through a series of complex processes. The initial phase of mineralization is directly related to the infiltration of novaculite by alkali-rich fluids that were probably derived from carbonatite magma. Introduction of the metasomatic fluids preceded emplacement of massive feldspar- and pyrite-bearing dikes that were subsequently altered to the clay-rich masses Titanium, V, Nb, and Li were introduced by the alkali-rich fluids at temperatures that were, as indicated by fluid inclusion data (Willis et al., 1991), as high as 600 degrees C. During the initial stage of mineralization, V was concentrated in aegirine and sodic amphibole, Li was concentrated in taeniolite, minor amounts of Ti were concentrated in aegirine, and pyrite formed. The replacement of novaculite by the aforementioned minerals yielded excess silica, which precipitated as quartz in veins and as clear overgrowths on recrystallized, inclusion-rich (partly replaced) quartz. Niobium- and V-bearing brookite precipitated with the quartz. Minerals formed during the first stage reacted with a second fluid at temperatures of 100 degrees to 300 degrees C, as indicated by fluid inclusion data (Willis et al., 1991), and V was then concentrated in smectite and goethite. The isotopic composition of siderite [delta 18 O SMOW = 23.8-25.0ppm, delta 13 C PDB = -7.1 to -8.9ppm suggests that the second fluid was a mixture of low-temperature metasomatic fluid and ground water. Vanadium was further concentrated in clay minerals (Breit et al., 1992), in goethite, and in vug minerals as low-temperature alteration proceeded. Brookite is not totally resistant to weathering and it is at least partly replaced by other oxides in the oxidized zone.

Economic Geology↗

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗

Assessment of the geoavailability of trace elements from selected zinc minerals

This assessment focused on five zinc-bearing minerals. The minerals were subjected to a number of analyses including quantitative X-ray diffraction, optical microscopy, leaching tests, and bioaccessibility and toxicity studies. Like a previous comprehensive assessment of five copper-bearing minerals, the purpose of this assessment was to obtain structural and chemical information and to characterize the reactivity of each mineral to various simulated environmental and biological conditions. As in the copper minerals study, analyses were conducted consistent with widely accepted methods. Unless otherwise noted, analytical methods used for this study were identical to those described in the investigation of copper-bearing minerals. Two sphalerite specimens were included in the zinc-minerals set. One sphalerite was recovered from a mine in Balmat, New York; the second came from a mine in Creede, Colorado. The location and conditions of origin are significant because, as analyses confirmed, the two sphalerite specimens are quite different. For example, data acquired from a simulated gastric fluid (SGF) study indicate that the hydrothermally formed Creede sphalerite contains orders of magnitude higher arsenic, cadmium, manganese, and lead than the much older metamorphic Balmat sphalerite. The SGF and other experimental results contained in this report suggest that crystallizing conditions such as temperature, pressure, fluidization, or alteration processes significantly affect mineral properties—properties that, in turn, influence reactivity, solubility, and toxicity. The three remaining minerals analyzed for this report—smithsonite, hemimorphite, and hydrozincite—are all secondary minerals or alteration products of zinc-ore deposits. In addition, all share physical characteristics such as tenacity, density, streak, and cleavage. Similarities end there. The chemical composition, unit-cell parameters, acid-neutralizing potential, and other observable and quantifiable properties indicate very different minerals. Only one of each of these minerals was studied. Had this assessment included multiples of these minerals, geochemical and mineralogical distinctions would have emerged, similar to the results for the two sphalerite specimens.

Arizona;Chihuahua;Colorado;New York↗