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Gas and hydrogen isotopic analyses of volcanic eruption clouds in Guatemala sampled by aircraft

Gas samples were collected by aircraft entering volcanic eruption clouds of three Guatemalan volcanoes. Gas chromatographic analyses show higher H2 and S gas contents in ash eruption clouds and lower H2 and S gases in vaporous gas plumes. H isotopic data demonstrate lighter isotopic distribution of water vapor in ash eruption clouds than in vaporous gas plumes. Most of the H2O in the vaporous plumes is probably meteoric. The data are the first direct gas analyses of explosive eruptive clouds, and demonstrate that, in spite of atmospheric admixture, useful compositional information on eruptive gases can be obtained using aircraft. ?? 1980.

Journal of Volcanology and Geothermal Research↗

Geophysical observations of Kilauea Volcano, Hawaii, 2. Constraints on the magma supply during November 1975-September 1977

Following a 22-month hiatus in eruptive activity, Kilauea volcano extruded roughly 35 ?? 106 m3 of tholeiitic basalt from vents along its middle east rift zone during 13 September-1 October, 1977. The lengthy prelude to this eruption began with a magnitude 7.2 earthquake on 29 November, 1975, and included rapid summit deflation episodes in June, July, and August 1976 and February 1977. Synthesis of seismic, geodetic, gravimetric, and electrical self-potential observations suggests the following model for this atypical Kilauea eruptive cycle. Rapid summit deflation initiated by the November 1975 earthquake reflected substantial migration of magma from beneath the summit region of Kilauea into the east and southwest rift zones. Simultaneous leveling and microgravity observations suggest that 40-90 ?? 106 m3 of void space was created within the summit magma chamber as a result of the earthquake. If this volume was filled by magma from depth before the east rift zone intrusive event of June 1976, the average rate of supply was 6-13 ?? 106 m3/month, a rate that is consistent with the value of 9 ?? 106 m3/month suggested from observations of long-duration Kilauea eruptions. Essentially zero net vertical change was recorded at the summit during the 15-month period beginning with the June 1976 intrusion and ending with the September 1977 eruption. This fact suggests that most magma supplied from depth during this interval was eventually delivered to the east rift zone, at least in part during four rapid summit deflation episodes. Microearthquake epicenters migrated downrift to the middle east rift zone for the first time during the later stages of the February 1977 intrusion, an occurrence presumably reflecting movement of magma into the eventual eruptive zone. This observation was confirmed by tilt surveys in May 1977 that revealed a major inflation center roughly 30 km east of the summit in an area of anomalous steaming and forest kill first noted in March 1976. ?? 1980.

Journal of Volcanology and Geothermal Research↗

Submarine volcanic features west of Kealakekua Bay, Hawaii

Visual observations of submarine volcanic vents were made from the submersible vehicle DSV "Sea Cliff" in water depths between 1310 and 690 m, west of Kealakekua Bay, Hawaii. Glass-rich, shelly submarine lavas surround circular 1- to 3-m-diameter volcanic vents between 1050 and 690 m depth in an area west-northwest of the southernpoint (Keei Pt.) of Kealakekua Bay. Eye-witness accounts indicate that this area was the site of a submarine eruption on February 24, 1877. Chemical analyses of lavas from these possible seafloor vent areas indicate that the eruptive products are very similar in composition to volcanic rocks produced by historic eruptions of Mauna Loa volcano. ?? 1980.

Journal of Volcanology and Geothermal Research↗

The 1977 eruption of Kilauea volcano, Hawaii

Kilauea volcano began to erupt on September 13, 1977, after a 21.5-month period of quiescence. Harmonic tremor in the upper and central east rift zone and rapid deflation of the summit area occurred for 22 hours before the outbreak of surface activity. On the first night, spatter ramparts formed along a discontinuous, en-echelon, 5.5-km-long fissure system that trends N70??E between two prehistoric cones, Kalalua and Puu Kauka. Activity soon became concentrated at a central vent that erupted sporadically until September 23 and extruded flows that moved a maximum distance of 2.5 km to the east. On September 18, new spatter ramparts began forming west of Kalalua, extending to 7 km the length of the new vent system. A vent near the center of this latest fissure became the locus of sustained fountaining and continued to extrude spatter and short flows intermittently until September 20. The most voluminous phase of the eruption began late on September 25. A discontinuous spatter rampart formed along a 700-m segment near the center of the new, 7-km-long fissure system; within 24 hours activity became concentrated at the east end of this segment. One flow from the 35-m-high cone that formed at this site moved rapidly southeast and eventually reached an area 10 km from the vent and 700 m from the nearest house in the evacuated village of Kalapana. We estimate the total volume of material produced during this 18-day eruption to be 35 ?? 106 m3. Samples from active vents and flows are differentiated quartz-normative tholeiitic basalt, similar in composition to lavas erupted from Kilauea in 1955 and 1962. Plagioclase is the only significant phenocryst; augite, minor olivine, and rare orthopyroxene and opaque oxides accompany it as microphenocrysts. Sulfide globules occur in fresh glass and as inclusions in phenocrysts in early 1977 lavas; their absence in chemically-similar basalt from the later phases of the eruption suggests that more extensive intratelluric degassing occurred as the eruption proceeded. Bulk composition of lavas varied somewhat during the eruption, but the last basalt produced also is differentiated, suggesting that the magma withdrawn from the summit reservoir during the rapid deflation has not yet been erupted. ?? 1980.

Journal of Volcanology and Geothermal Research↗

Applications of the VLF induction method for studying some volcanic processes of Kilauea volcano, Hawaii

The very low-frequency (VLF) induction method has found exceptional utility in studying various volcanic processes of Kilauea volcano, Hawaii because: (1) significant anomalies result exclusively from ionically conductive magma or still-hot intrusions (> 800??C) and the attendant electrolytically conductive hot groundwater; (2) basalt flows forming the bulk of Kilauea have very high resistivities at shallow depths that result in low geologic noise levels and relatively deep depths of investigation (???100 m); and (3) the azimuths to two of the usable transmitters (NLK and NPM) are aligned favorably with most of the principal geologic features. Measurements of the tilt angle and ellipticity of the polarization ellipse of the magnetic field, using a simple, hand-held receiver, have been used to: (1) delineate the lateral extent of shallow, partially solidified lava lakes, active lava tubes, and recent intrusive dikes; (2) obtain an indication of the attitude of some recent dikes; (3) show that many eruptive fissures cool faster than their intrusive counterparts; (4) show that some fumarolic areas are underlain by shallow, highly altered, and conductive zones; and (5) provide control information for interpreting data obtained with other electrical techniques. Complementary measurements of scalar apparent resistivity and surface impedance phase, using a new attachment for the VLF receiver, have substantially increased the utility of VLF studies in Kilauea. They provide better lateral resolution of conductors and reduce the ambiguity in interpretation. Notwithstanding recent advances in theoretical modeling techniques, the excellent quality of some of the data warrants extension of interpretive techniques, particularly for quantitatively characterizing the configuration and conductivity of small-dimension bodies. These VLF induction methods should have wide application to studies of active volcanic regions in other parts of the world and could provide some insights into the workings of larger-scaled geothermal systems. ?? 1978.

Journal of Volcanology and Geothermal Research↗

A large submarine sand-rubble flow on kilauea volcano, hawaii

Papa'u seamount on the south submarine slope of Kilauea volcano is a large landslide about 19 km long, 6 km wide, and up to 1 km thick with a volume of about 39 km3. Dredge hauls, remote camera photographs, and submersible observations indicate that it is composed primarily of unconsolidated angular glassy basalt sand with scattered basalt blocks up to 1 m in size; no lava flows were seen. Sulfur contents of basalt glass from several places on the sand-rubble flow and nearby areas are low (< 240 ppm), indicating that the clastic basaltic material was all erupted on land. The Papa'u sandrubble flow was emplaced during a single flow event fed from a large near-shore bank of clastic basaltic material which in turn was formed as lava flows from the summit area of Kilauea volcano disintegrated when they entered the sea. The current eruptive output of the volcano suggests that the material in the submarine sand-rubble flow represents about 6000 years of accumulation, and that the flow event occurred several thousand years ago. ?? 1979.

Journal of Volcanology and Geothermal Research↗

Geochemical and hydrologic considerations and the use of enthalpy-chloride diagrams in the prediction of underground conditions in hot-spring systems

Thermal water ascending in a hot-spring system may cool by conduction of heat to the surrounding rock, by boiling, by mixing with cooler water, or by a combination of these processes. Complete or partial chemical reequilibration may occur as a result of this cooling. In spite of these complexities, in many places chemical compositions of hot-spring waters may be used to estimate underground conditions. A plot of enthalpy versus chloride is particularly useful for determining underground temperatures, salinities, and boiling and mixing relations. The utility of this approach is illustrated using hot-spring composition data from Cerro Prieto, Mexico, Orakeikorako, New Zealand, and Yellowstone National Park, Wyoming. ?? 1979.

Journal of Volcanology and Geothermal Research↗

Chemical and isotopic prediction of aquifer temperatures in the geothermal system at Long Valley, California

Temperatures of aquifers feeding thermal springs and wells in Long Valley, California, estimated using silica and Na-K-Ca geothermometers and warm spring mixing models, range from 160/dg to about 220??C. This information was used to construct a diagram showing enthalpy-chloride relations for the various thermal waters in the Long Valley region. The enthalpy-chloride information suggests that a 282 ?? 10??C aquifer with water containing about 375 mg chloride per kilogram of water is present somewhere deep in the system. That deep water would be related to ??? 220??C Casa Diablo water by mixing with cold water, and to Hot Creek water by first boiling with steam loss and then mixing with cold water. Oxygen and deuterium isotopic data are consistent with that interpretation. An aquifer at 282??C with 375 mg/kg chloride implies a convective heat flow in Long Valley of 6.6 ?? 107 cal/s. ?? 1979.

Journal of Volcanology and Geothermal Research↗

Minerals produced during cooling and hydrothermal alteration of ash flow tuff from Yellowstone drill hole Y-5

A rhyolitic ash-flow tuff in a hydrothermally active area within the Yellowstone caldera was drilled in 1967, and cores were studied to determine the nature and distribution of primary and secondary mineral phases. The rocks have undergone a complex history of crystallization and hydrothermal alteration since their emplacement 600,000 years ago. During cooling from magmatic temperatures, the glassy groundmass underwent either devitrification to alkali feldspar + ??-cristobalite ?? tridymite or granophyric crystallization to alkali feldspar + quartz. Associated with the zones of granophyric crystallization are prismatic quartz crystals in cavities similar to those termed miarolitic in plutonic rocks. Vapor-phase alkali feldspar, tridymite, magnetite, and sporadic ??-cristobalite were deposited in cavities and in void spaces of pumice fragments. Subsequently, some of the vapor-phase alkali feldspar crystals were replaced by microcrystalline quartz, and the vapor-phase minerals were frosted by a coating of saccharoidal quartz. Hydrothermal minerals occur primarily as linings and fillings of cavities and fractures and as altered mafic phenocrysts. Chalcedony is the dominant mineral related to the present hydrothermal regime and occurs as microcrystalline material mixed with various amounts of hematite and goethite. The chalcedony displays intricate layering and was apparently deposited as opal from silica-rich water. Hematite and goethite also replace both mafic phenocrysts and vapor-phase magnetite. Other conspicuous hydrothermal minerals include montmorillonite, pyrite, mordenite, calcite, and fluorite. Clinoptilolite, erionite, illite, kaolinite, and manganese oxides are sporadic. The hydrothermal minerals show little correlation with temperature, but bladed calcite is restricted to a zone of boiling in the tuff and clearly was deposited when CO2 was lost during boiling. Fractures and breccias filled with chalcedony are common throughout Y-5 and may have been produced by rapid disruption of rock caused by sudden decrease of fluid pressure in fractures, most likely a result of fracturing during resurgent doming in this part of the Yellowstone caldera. The chalcedony probably was deposited as opal or ??-cristobalite from a pre-existing silica floc that moved rapidly into the fractures and breccias immediately after the sudden pressure drop. ?? 1978.

Journal of Volcanology and Geothermal Research↗

A geophysical and geological study of Laguna de Ayarza, a Guatemalan caldera lake

Geologic and geophysical data from Laguna de Ayarza, a figure-8-shaped doublecaldera lake in the Guatemalan highlands, show no evidence of postcaldera eruptive tectonic activity. The bathymetry of the lake has evolved as a result of sedimentary infilling. The western caldera is steep-sided and contains a large flat-floored central basin 240 m deep. The smaller, older, eastern caldera is mostly filled by coalescing delta fans and is connected with the larger caldera by means of a deep channel. Seismicreflection data indicate that at least 170 m of flat-lying unfaulted sediments partly fill the central basin and that the strata of the pre-eruption edifice have collapsed partly along inward-dipping ring faults and partly by more chaotic collapses. These sediments have accumulated in the last 23,000 years at a minimum average sedimentation rate of 7 m/103 yr. The upper 9 m of these sediments is composed of > 50% turbidites, interbedded with laminated clayey silts containing separate diatom and ash layers. The bottom sediments have >1% organic material, an average of 4% pyrite, and abundant biogenic gas, all of which demonstrate that the bottom sediments are anoxic. Although thin (<0.5 cm) ash horizons are common, only one thick (7-16 cm) primary ash horizon could be identified in piston cores. Alterations in the mineralogy and variations in the diatom assemblage suggest magnesium-rich hydrothermal activity. ?? 1985.

Journal of Volcanology and Geothermal Research↗

Chemistry of thermal and nonthermal springs in the vicinity of Lassen Volcanic National Park

Meaningful applications of water geothermometry to thermal springs in and around Lassen Volcanic National Park (LVNP) are limited to Growler Hot Spring and Morgan Hot Springs. Most hot springs located within LVNP are low-chloride, acid-sulfate waters associated with nearby steam vents. This type of hot-spring activity is characteristically found above vapor-dominated hydrothermal systems. These acid-sulfate waters are not generally useful for liquid chemical geothermometry, however, because their chemical compositions result from water-rock interaction at relatively shallow depths. Thermal waters at Drakesbad and in Little Hot Springs Valley have neutral-pH, low-Cl concentrations and have estimated Na-K-Ca and Na-Li geothermometer temperatures close to measured spring temperatures of 65 to 95??C. Hot-spring waters located south of LVNP at Growler Hot Spring, Morgan Hot Springs, and in the south-central part of LVNP in the Walker "O" No. 1 well at Terminal Geyser are rich in chloride and yield calculated geothermometer temperatures between 220 and 230??C. These thermal waters probably originate within a zone of upflow of high-enthalpy fluid inside LVNP and cool conductively during lateral flow to the south and southeast. ?? 1985.

Journal of Volcanology and Geothermal Research↗

Variations in tilt rate and harmonic tremor amplitude during the January-August 1983 east rift eruptions of Kilauea Volcano, Hawaii

During January-August 1983, a network of telemetered tiltmeters and seismometers recorded detailed temporal changes associated with seven major eruptive phases along the east rift of Kilauea Volcano, Hawaii. Each eruptive phase was accompanied by subsidence of the summit region and followed by reinflation of the summit to approximately the same level before renewal of eruptive activity. The cyclic summit tilt pattern and the absence of measurable tilt changes near the eruptive site suggest that conditions in the summit region controlled the timing of the last six eruptive phases. The rate of summit subsidence progressively increased from one eruptive phase to the next during the last six phases; the amplitude of harmonic tremor increased during the last four phases. The increases in subsidence rate and in tremor amplitude suggest that frequent periods of magma movement have reduced the flow resistance of the conduit system between the summit and the rift zone. ?? 1985.

Journal of Volcanology and Geothermal Research↗

Chloride flux out of Yellowstone National Park

Monitoring of the chloride concentration, electrical conductivity, and discharge was carried out for the four major rivers of Yellowstone National Park from September 1982 to January 1984. Chloride flux out of the Park was determined from the measured values of chloride concentration and discharge. The annual chloride flux from the Park was 5.86 ?? 1010 g. Of this amount 45% was from the Madison River drainage basin, 32% from the Yellowstone River basin, 12% from the Snake River basin, and 11% from the Falls River basin. Of the annual chloride flux from the Yellowstone River drainage basin 36% was attributed to the Yellowstone Lake drainage basin. The geothermal contribution to the chloride flux was determined by subtracting the chloride contribution from rock weathering and atmospheric precipitation and is 94% of the total chloride flux. Calculations of the geothermal chloride flux for each river are given and the implications of an additional chloride flux out of the western Park boundary discussed. An anomalous increase in chloride flux out of the Park was observed for several weeks prior to the Mt. Borah earthquake in Central Idaho on October 28, 1983, reaching a peak value shortly thereafter. It is suggested that the rise in flux was a precursor of the earthquake. The information in this paper provides baseline data against which future changes in the hydrothermal systems can be measured. It also provides measurements related to the thermal contributions from the different drainage basins of the Park. ?? 1985.

Journal of Volcanology and Geothermal Research↗

A reconnaissance of the major Holocene tephra deposits in the upper Cook Inlet region, Alaska

The upper Cook Inlet region of southcentral Alaska would be significantly impacted by a major tephrafall, owing to a widespread population and heavily travelled transportation corridors. To evaluate the likelihood of such an occurrence, the tephra deposits of the region have been inventoried. Approximately 90 deposits of Holocene age are sufficiently thick to have been preserved for sampling; the frequency of such major tephrafalls ranges from 1 every 200 years near sources on the west side of upper Cook Inlet, to 1 every 1000 years on the more populated east side. The volcanoes located on the west side of upper Cook Inlet are, from north to south, Hayes, Spurr, Redoubt, and Iliamna. Hayes volcano produced the most extensive set of 6 to perhaps 8 tephra layers in the region about 3650 yr B.P. and produced one other, less extensive tephra layer during Holocene time. Spurr and Redoubt volcanoes have produced, respectively, approximately 35 and 30 Holocene layers which were dispersed eastward toward population centers. No Holocene tephra layers of Iliamna have been recognized with certainty; consequently, several tephra layers which originated to the south of the region must have a source at Augustine Volcano, or some more distant volcano. Tephra layers of Hayes volcano are calc-alkaline dacites. Most of the Spurr deposits are tholeiitic, basaltic andesites whereas those of Redoubt Volcano are calc-alkaline andesites and dacites. ?? 1985.

Journal of Volcanology and Geothermal Research↗

Vp/Vs ratios in the Yellowstone National Park region, Wyoming

In this paper we study the variation of Vp/Vs and Poisson's ratio (??) in the Yellowstone National Park region, using earthquakes which were well recorded by a local seismic network. We find that the average Vp/Vs value within the geothermally active Yellowstone caldera is about 7% lower than in the area outside the caldera. Within the caldera itself there may be a further 2-7% reduction of Vp/Vs in the hydrothermally active Norris Geyser Basin, the Upper and Lower Geyser Basins, and the Yellowstone Lake and Mud Volcano regions. After considering various possible causes for Vp/Vs changes, such as geologic and structural differences, thermal effects, partial melting, and hydrothermal activity, we conclude that the most plausible explanation for the observed Vp/Vs reduction is the presence of hot-water at temperatures and pore-pressures near the water steam transition in the caldera geothermal reservoirs. ?? 1985.

Journal of Volcanology and Geothermal Research↗

The eruption of Mount Pagan volcano, Mariana Islands, 15 May 1981

A major explosive eruption occurred 15 May 1981 at Mount Pagan Volcano, the larger of two historic eruptive centers on Pagan Island, Mariana Islands. The eruption was preceded by increased numbers of locally felt earthquakes beginning in late March or early April and by new ground cracks, new sublimates, and increased gas emissions. A swarm of felt earthquakes began at 0745h (local time = UCT+10 hours) 15 May, and at 0915 h, closely following a loud sonic boom, a strong plinian column issued from the volcano. The high-altitude ash cloud (at least 13.5 km) travelled south-southeast, but ash and scoria deposits were thickest (> 2 m) in the NW sector of the island because of the prevailing low-altitude southeasterly winds. The early activity of 15 May probably involved magmatic eruption along a fissure system oriented about N10??E. However, the eruption became hydromagmatic, possibly within minutes, and was largely restricted to three long-lived vents. The northernmost of these built a substantial new scoria-ash cinder cone. Flows and air-fall deposits, consisting almost entirely of juvenile material, exceeded 105 ?? 106 m3 in volume (75 ?? 106 m3 of magma) on land and at least 70-100 ?? 606 m3 at sea. An unknown volume was carried away by stratospheric winds. Lithic blocks and juvenile bombs as large as 1 m in diameter were thrown more than 2 km from the summit, and evidence for base-surge was observed in restricted corridors as low as 200 m elevation on the north and south slopes of the volcano. Neither of these events resulted in serious injuries to the 54 residents of the island, nor did the eruption produce serious chemical hazards in their water supply. Weak eruptions occurred during the ensuing month, and some of these were monitored by ground observations, seismic monitoring, and deformation studies. Precursory seismicity and possibly deformation occurred with some of the observed eruptions. More vigorous eruptions were reported by visiting residents in late 1981 and early 1982, but these were of lesser magnitude than the 15 May 1981 event. The 15 May lava is predominantly aa and ranges from 3 to > 30 m in thickness. In composition, it is a high-alumina basalt with small (< 1 mm long) phenocrysts of plagioclase and clinopyroxene (7%) that is more or less typical of basalt of the northern Marianas volcanoes. It contains slightly more SiO2 (52%), K2O, TiO2, and less Al2O3 and CaO than does the basalt of the last eruptive event of Mount Pagan Volcano in 1925. Gas analyses indicate that a large portion of air was introduced into the vent system through the porous volcanic edifice and that the carbon gases were not in equilibrium with the magma or each other. ?? 1984.

Journal of Volcanology and Geothermal Research↗

Evidence for magma mixing within the Laacher See magma chamber (East Eifel, Germany)

The final pyroclastic products of the late Quaternary phonolitic Laacher See volcano (East Eifel, W.-Germany) range from feldspar-rich gray phonolite to dark olivine-bearing rocks with variable amounts of feldspar and Al-augite megacrysts. Petrographically and chemically homogeneous clasts occur along with composite lapilli spanning the compositional range from phonolite (MgO 0.9%) to mafic hybrid rock (MgO 7.0%) for all major and trace elements. Both a basanitic and a phonolitic phenocryst paragenesis occur within individual clasts. The phonolite-derived phenocrysts are characterized by glass inclusions of evolved composition, rare inverse zoning and strong resorption indicating disequilibrium with the mafic hybrid matrix. Basanitic (magnesian) clinopyroxene and olivine, in contrast, show skeletal (normally zoned) overgrowths indicative of post-mixing crystallization. In accord with petrographical and other chemical evidence, mass balance calculations suggest mixing of an evolved Laacher See phonolite containing variable amounts of mineral cumulates and a megacryst-bearing basanite magma. Magma mixing occurred just prior to eruption (hours) of the lowermost magma layer of the Laacher See magma chamber but did not trigger the volcanic activity. ?? 1984.

Journal of Volcanology and Geothermal Research↗

Volatiles of Mount St. Helens and their origins

Analyses have been made of gases in clouds apparently emanating from Mount St. Helens. Despite appearances, most of the water in these clouds does not issue from the volcano. Even directly above a large fumarole ??D and ?? 18O data indicate that only half the water can come from the volcano. Isotopic and chemical evidence also shows the steam in the volcano (-33.0 per mol ??D) from which a condensate of 0.2 N HCI was obtained is not a major cause of the explosions. The steam in the volcano is derived from a metamorphic brine in the underlying Tertiary meta andesite. The gas that caused the explosive eruptions is carbon dioxide. ?? 1984.

Journal of Volcanology and Geothermal Research↗