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USGS2000

Deformation across the forearc of the Cascadia subduction zone at Cape Blanco, Oregon

Over the interval 1992-1999 the U.S. Geological Survey measured the deformation of a geodetic array extending N880°E (approximate direction of plate convergence) from Cape Blanco on the Oregon coast to the volcanic arc near Newberry Crater (55 and 350 km, respectively, from the deformation front). Within about 150 km from the deformation front, the forearc is being compressed arcward (N80°E) by coupling to the subducting Juan de Fuca plate. Dislocation modeling of the observed N80°E compression suggests that the main thrust zone (the locked portion of the Juan de Fuca-forearc interface) is about 40 km wide in the downdip direction. The transverse (N10°W) velocity component of the forearc measured with respect to the fixed interior of North America decreases with distance from the deformation front at a rate of about 0.03 mm yr -1 km -1 . That gradient appears to be a consequence of rigid rotation of the forearc block relative to fixed interior North America (Euler vector of 43.4°±0.1° N, 120.0°±0.4° W, and -1.67±0.17° (m.y.) -1 ; quoted uncertainties are standard deviations). The rotation rate is similar to the paleomagnetically measured rotation rate (-1.0±0.2° (m.y.) -1 ) of the 15 Ma lava flows along the Columbia River 250 km farther north. The back arc does not appear to participate in this rotation but rather is migrating at a rate of about 3.6 mm yr -1 northward with respect to fixed North America. That migration could be partly an artifact of an imperfect tie of our reference coordinate system to the interior of North America.

Journal of Geophysical Research B: Solid Earth↗

USGS2000

A crustal model of the ultrahigh-pressure Dabie Shan orogenic belt, China, derived from deep seismic refraction profiling

We present a new crustal cross section through the east-west trending ultrahigh-pressure (UHP) Dabie Shan orogenic belt, east central China, based on a 400-km-long seismic refraction profile. Data from our profile reveal that the cratonal blocks north and south of the orogen are composed of 35-km-thick crust consisting of three layers (upper, middle, and lower crust) with average seismic velocities of 6.0±0.2 km/s, 6.5±0.1 km/s, and 6.8±0.1 km/s. The crust reaches a maximum thickness of 41.5 km beneath the northern margin of the orogen, and thus the present-day root beneath the orogen is only 6.5 km thick. The upper mantle velocity is 8.0±0.1 km/s. Modeling of shear wave data indicate that Poisson's ratio increases from 0.24±0.02 in the upper crust to 0.27±0.03 in the lower crust. This result is consistent with a dominantly felsic upper crustal composition and a mafic lower crustal composition within the amphibolite or granulite metamorphic facies. Our seismic model indicates that eclogite, which is abundant in surface exposures within the orogen, is not a volumetrically significant component in the middle or lower crust. Much of the Triassic structure associated with the formation of the UHP rocks of the Dabie Shan has been obscured by post-Triassic igneous activity, extension and large-offset strike-slip faulting. Nevertheless, we can identify a high-velocity (6.3 km/s) zone in the upper (<5 km depth) crustal core of the orogen which we interpret as a zone of ultrahigh-pressure rocks, a north dipping suture, and an apparent Moho offset that marks a likely active strike-slip fault.

Journal of Geophysical Research B: Solid Earth↗

USGS2000

Alternating seismic uplift and subsidence in the late Holocene at Madang, Papua New Guinea: Evidence from raised reefs

Well-preserved mid-late Holocene coral reefs are exposed in low coastal cliffs in the vicinity of the Madang lagoon on the north coast of Papua New Guinea. Results from U/Th and 14 C dating of corals, surveying, and field mapping indicate several major changes in relative sea level over this period. Specifically, there is evidence for a relative sea level fall of ≥4.5 m about 3000 calendar years B.P., followed by relative sea level rises of ∼1.5 m about 2400 calendar years B.P. and ≥0.5 m about 1200 calendar years B.P. and a subsequent relative sea level fall of ≥3 m some time in the past 1000 years. Since regional eustatic sea levels are believed to have been dropping gradually over this time frame, these observed changes in relative sea level are interpreted as reflecting alternating tectonic uplift and subsidence. Furthermore, the detailed structure and age relationships of the coral deposits indicate that both uplift and subsidence occurred rapidly, most probably as coseismic events with vertical displacements of 0.5 to 4.5 m. These events may be related to rupture on NW-SE trending reverse faults which have been mapped in the nearby Adelbert Range and possibly on NE trending cross faults which have been inferred from seismicity. This interpretation implies a much greater degree of tectonic instability and potential seismic hazard in the region than previously recognized, although the inferred coseismic vertical displacements are shown to be consistent with present-day local seismicity. In a broader context, the study illustrates how detailed analysis of vertical changes in coral reef structure and assemblages may be used as a sensitive indicator of changing relative sea level, capable of resolving century timescale events and reversals.

Madang↗

USGS2000

Crustal deformation associated with glacial fluctuations in the eastern Chugach Mountains, Alaska

The changes of the solid Earth in south central Alaska in response to two major glacial fluctuations on different temporal and spatial scales have been estimated and we evaluated their influence on the stress state and ongoing tectonic deformation of the region. During the recent (1993–1995) Bering Glacier surge, a large transfer of ice from the Bagley Ice Field to the Bering Glacier terminus region occurred. We estimated the elastic displacement of the solid Earth due to ice mass redistribution from Global Positioning System (GPS) measurements at sites near the surging glacier. We can account for these displacements by transfer of an ice volume of about 14 km 3 from the surge reservoir area to the terminus region. We examined the background seismicity (M L ≥ 2.5) before, during, and after the surge. We found that the occurrence of small earthquakes (M L ≤ 4.0) in the surge reservoir region increased during the surge time interval possibly in response to a decrease in ice mass. This suggests that a small decrease in the vertical stress, σ 3 , could be enough to modulate the occurrence of small, shallow earthquakes in this dominantly thrust fault setting. During this century the southern Alaska coastal glaciers have been undergoing an overall decrease in volume. Based on our compilation of changes in the extent and thickness of the coastal glaciers between the Malaspina and Bering, we calculated surface displacements due to the Earth's viscoelastic response to annual thinning and to the cumulative retreat over the last 100 years. The uplift of the region due to an average annual thinning rate of 1–6 m/yr in the ablation region is 1–12 mm/yr. For our reference model with a viscosity of 5×10 19 Pa s for depths between ≈ 40 and 200 km the total viscoelastic response due to the retreat over the last century may be as much as a couple of meters within the coastal ablation zone near Icy Bay. The maximum decrease in σv between 0 and 10 km was ≈ 1.0 MPa, which is significant in relation to the stress drops in recent earthquakes (≈ 2 to 10 MPa) but small in relation to the estimated tectonic stress magnitude. Therefore the occurrence of an earthquake such as the St. Elias (1979, M S = 7.2) may have been advanced in time; however, most of the ongoing stress accumulation would be primarily due to tectonic forces.

Journal of Geophysical Research B: Solid Earth↗

USGS2000

On rate-state and Coulomb failure models

We examine the predictions of Coulomb failure stress and rate-state frictional models. We study the change in failure time (clock advance) Δt due to stress step perturbations (i.e., coseismic static stress increases) added to "background" stressing at a constant rate (i.e., tectonic loading) at time t 0 . The predictability of Δt implies a predictable change in seismicity rate r(t)/r 0 , testable using earthquake catalogs, where r 0 is the constant rate resulting from tectonic stressing. Models of r(t)/r 0 , consistent with general properties of aftershock sequences, must predict an Omori law seismicity decay rate, a sequence duration that is less than a few percent of the mainshock cycle time and a return directly to the background rate. A Coulomb model requires that a fault remains locked during loading, that failure occur instantaneously, and that Δt is independent of t 0 . These characteristics imply an instantaneous infinite seismicity rate increase of zero duration. Numerical calculations of r(t)/r 0 for different state evolution laws show that aftershocks occur on faults extremely close to failure at the mainshock origin time, that these faults must be "Coulomb-like," and that the slip evolution law can be precluded. Real aftershock population characteristics also may constrain rate-state constitutive parameters; a may be lower than laboratory values, the stiffness may be high, and/or normal stress may be lower than lithostatic. We also compare Coulomb and rate-state models theoretically. Rate-state model fault behavior becomes more Coulomb-like as constitutive parameter a decreases relative to parameter b. This is because the slip initially decelerates, representing an initial healing of fault contacts. The deceleration is more pronounced for smaller a, more closely simulating a locked fault. Even when the rate-state Δt has Coulomb characteristics, its magnitude may differ by some constant dependent on b. In this case, a rate-state model behaves like a modified Coulomb failure model in which the failure stress threshold is lowered due to weakening, increasing the clock advance. The deviation from a non-Coulomb response also depends on the loading rate, elastic stiffness, initial conditions, and assumptions about how state evolves.

Journal of Geophysical Research B: Solid Earth↗

USGS2000

Estimation of wave phase speed and nearshore bathymetry from video imagery

A new remote sensing technique based on video image processing has been developed for the estimation of nearshore bathymetry. The shoreward propagation of waves is measured using pixel intensity time series collected at a cross-shore array of locations using remotely operated video cameras. The incident band is identified, and the cross-spectral matrix is calculated for this band. The cross-shore component of wavenumber is found as the gradient in phase of the first complex empirical orthogonal function of this matrix. Water depth is then inferred from linear wave theory's dispersion relationship. Full bathymetry maps may be measured by collecting data in a large array composed of both cross-shore and longshore lines. Data are collected hourly throughout the day, and a stable, daily estimate of bathymetry is calculated from the median of the hourly estimates. The technique was tested using 30 days of hourly data collected at the SandyDuck experiment in Duck, North Carolina, in October 1997. Errors calculated as the difference between estimated depth and ground truth data show a mean bias of −35 cm (rms error = 91 cm). Expressed as a fraction of the true water depth, the mean percent error was 13% (rms error = 34%). Excluding the region of known wave nonlinearities over the bar crest, the accuracy of the technique improved, and the mean (rms) error was −20 cm (75 cm). Additionally, under low-amplitude swells (wave height H ≤ 1 m), the performance of the technique across the entire profile improved to 6% (29%) of the true water depth with a mean (rms) error of −12 cm (71 cm).

North Carolina↗

USGS2001

Sources of global warming in upper ocean temperature during El Niño

Global average sea surface temperature (SST) from 40°S to 60°N fluctuates ±0.3°C on interannual period scales, with global warming (cooling) during El Niño (La Niña). About 90% of the global warming during El Niño occurs in the tropical global ocean from 20°S to 20°N, half because of large SST anomalies in the tropical Pacific associated with El Niño and the other half because of warm SST anomalies occurring over &sim;80% of the tropical global ocean. From examination of National Centers for Environmental Prediction [ Kalnay et al. , 1996] and Comprehensive Ocean-Atmosphere Data Set [ Woodruff et al. , 1993] reanalyses, tropical global warming during El Niño is associated with higher troposphere moisture content and cloud cover, with reduced trade wind intensity occurring during the onset phase of El Niño. During this onset phase the tropical global average diabatic heat storage tendency in the layer above the main pycnocline is 1–3 W m −2 above normal. Its principal source is a reduction in the poleward Ekman heat flux out of the tropical ocean of 2–5 W m −2 . Subsequently, peak tropical global warming during El Niño is dissipated by an increase in the flux of latent heat to the troposphere of 2–5 W m −2 , with reduced shortwave and longwave radiative fluxes in response to increased cloud cover tending to cancel each other. In the extratropical global ocean the reduction in poleward Ekman heat flux out of the tropics during the onset of El Niño tends to be balanced by reduction in the flux of latent heat to the troposphere. Thus global warming and cooling during Earth's internal mode of interannual climate variability arise from fluctuations in the global hydrological balance, not the global radiation balance. Since it occurs in the absence of extraterrestrial and anthropogenic forcing, global warming on decadal, interdecadal, and centennial period scales may also occur in association with Earth's internal modes of climate variability on those scales.

Journal of Geophysical Research C: Oceans↗

USGS2000

Time-averaged fluxes of lead and fallout radionuclides to sediments in Florida Bay

Recent, unmixed sediments from mud banks of central Florida Bay were dated using 210 Pb/ 226 Ra, and chronologies were verified by comparing sediment lead temporal records with Pb/Ca ratios in annual layers of coral ( Montastrea annularis ) located on the ocean side of the Florida Keys. Dates of sediment lead peaks (1978±2) accord with prior observations of a 6 year lag between the occurrence of maximum atmospheric lead in 1972 and peak coral lead in 1978. Smaller lags of 1–2 years occur between the maximum atmospheric radionuclide fallout and peaks in sediment temporal records of 137 Cs and Pu. Such lags are consequences of system time averaging (STA) in which atmospherically delivered particle-associated constituents accumulate and mix in a (sedimentary?) reservoir before transferring to permanent sediments and coral. STA model calculations, using time-dependent atmospheric inputs, produced optimized profiles in excellent accord with measured sediment 137 Cs, Pu, lead, and coral lead distributions. Derived residence times of these particle tracers (16±1, 15.7±0.7, 19±3, and 16±2 years, respectively) are comparable despite differences in sampling locations, in accumulating media, and in element loading histories and geochemical properties. For a 16 year weighted mean residence time, STA generates the observed 6 year lead peak lag. Evidently, significant levels of nondegradable, particle-associated contaminants can persist in Florida Bay for many decades following elimination of external inputs. Present results, in combination with STA model analysis of previously reported radionuclide profiles, suggest that decade-scale time averaging may occur widely in recent coastal marine sedimentary environments.

Florida↗

USGS1999

Spatially averaged flow over a wavy boundary revisited

Vertical profiles of streamwise velocity measured over bed forms are commonly used to deduce boundary shear stress for the purpose of estimating sediment transport. These profiles may be derived locally or from some sort of spatial average. Arguments for using the latter procedure are based on the assumption that spatial averaging of the momentum equation effectively removes local accelerations from the problem. Using analogies based on steady, uniform flows, it has been argued that the spatially averaged velocity profiles are approximately logarithmic and can be used to infer values of boundary shear stress. This technique of using logarithmic profiles is investigated using detailed laboratory measurements of flow structure and boundary shear stress over fixed two-dimensional bed forms. Spatial averages over the length of the bed form of mean velocity measurements at constant distances from the mean bed elevation yield vertical profiles that are highly logarithmic even though the effect of the bottom topography is observed throughout the water column. However, logarithmic fits of these averaged profiles do not yield accurate estimates of the measured total boundary shear stress.

Journal of Geophysical Research C: Oceans↗

USGS1999

Precipitation structure in the Sierra Nevada of California during winter

Influences of upper air characteristics along the coast of California upon winter-time (November-April) precipitation in the Sierra Nevada are investigated. Precipitation events in the Sierra Nevada region occur mostly during wintertime, irrespective of station location (leeside or windside) and elevation. Most precipitation episodes in the region are associated with moist southwesterly winds (coming from the southwest direction) and also tend to occur when the 700-mbar temperature at the upwind direction is close to −2°C. This favored wind direction and temperature signify the importance of both moisture transport and orographic lifting in augmenting precipitation in the region. By utilizing the observed dependency of the precipitation upon the upper air conditions, a linear model is formulated to quantify the precipitation observed at different sites as a function of moisture transport. The skill of the model increases with timescale of aggregation, reaching more than 50% variance explained at an aggregation period of 5–7 days. This indicates that upstream air moisture transport can be used to estimate the precipitation totals in the Sierra Nevada region.

Journal of Geophysical Research D: Atmospheres↗

USGS1999

Potential impacts on Colorado Rocky Mountain weather due to land use changes on the adjacent Great Plains

Evidence from both meteorological stations and vegetational successional studies suggests that summer temperatures are decreasing in the mountain-plain system in northeast Colorado, particularly since the early 1980s. These trends are coincident with large changes in regional land cover. Trends in global, Northern Hemisphere and continental surface temperatures over the same period are insignificant. These observations suggest that changes in the climate of this mountain-plain system may be, in some part, a result of localized forcing mechanisms. In this study the effects of land use change on the northern Colorado plains, where large regions of grasslands have been transformed into both dry and irrigated agricultural lands, on regional weather is examined in an effort to understand this local deviation from larger-scale trends. We find with high-resolution numerical simulations of a 3-day summer period using a regional atmospheric-land surface model that replacing grasslands with irrigated and dry farmland can have impacts on regional weather and therefore climate which are not limited to regions of direct forcing. Higher elevations remote from regions of land use change are affected as well. Specifically, cases with altered landcover had cooler, moister boundary layers, and diminished low-level upslope winds over portions of the plains. At higher elevations, temperatures also were lower as was low-level convergence. Precipitation and cloud cover were substantially affected in mountain regions. We advance the hypothesis that observed land use changes may have already had a role in explaining part of the observed climate record in the northern Colorado mountain-plain system.

Journal of Geophysical Research D: Atmospheres↗

USGS1999

Nevada STORMS project: Measurement of mercury emissions from naturally enriched surfaces

Diffuse anthropogenic and naturally mercury-enriched areas represent long-lived sources of elemental mercury to the atmosphere. The Nevada Study and Tests of the Release of Mercury From Soils (STORMS) project focused on the measurement of mercury emissions from a naturally enriched area. During the project, concurrent measurements of mercury fluxes from naturally mercury-enriched substrate were made September 1–4, 1997, using four micrometeorological methods and seven field flux chambers. Ambient air mercury concentrations ranged from 2 to nearly 200 ng m −3 indicating that the field site is a source of atmospheric mercury. The mean daytime mercury fluxes, during conditions of no precipitation, measured with field chambers were 50 to 360 ng m −2 h −1 , and with the micrometeorological methods were 230 to 600 ng m −2 h −1 . This wide range in mercury emission rates reflects differences in method experimental designs and local source strengths. Mercury fluxes measured by many field chambers were significantly different ( p <0.05) but linearly correlated. This indicates that field chambers responded similarly to environmental conditions, but differences in experimental design and site heterogeneity had a significant influence on the magnitude of mercury fluxes. Data developed during the field study demonstrated that field flux chambers are ideal for assessment of the physicochemical processes driving mercury flux and development of an understanding of the magnitude of the influence of individual factors on flux. In general, mean mercury fluxes measured with micrometeorological methods during daytime periods were nearly 3 times higher than mean fluxes measured with field flux chambers. Micrometeorological methods allow for derivation of a representative mercury flux occurring from an unconstrained system and provide an assessment of the actual magnitude and variability of fluxes occurring from an area.

Journal of Geophysical Research D: Atmospheres↗

USGS2000

Chamber measurement of surface-atmosphere trace gas exchange: Numerical evaluation of dependence on soil interfacial layer, and source/sink products

We employed a three-dimensional finite difference gas diffusion model to simulate the performance of chambers used to measure surface-atmosphere tace gas exchange. We found that systematic errors often result from conventional chamber design and deployment protocols, as well as key assumptions behind the estimation of trace gas exchange rates from observed concentration data. Specifically, our simulationshowed that (1) when a chamber significantly alters atmospheric mixing processes operating near the soil surface, it also nearly instantaneously enhances or suppresses the postdeployment gas exchange rate, (2) any change resulting in greater soil gas diffusivity, or greater partitioning of the diffusing gas to solid or liquid soil fractions, increases the potential for chamber-induced measurement error, and (3) all such errors are independent of the magnitude, kinetics, and/or distribution of trace gas sources, but greater for trace gas sinks with the same initial absolute flux. Finally, and most importantly, we found that our results apply to steady state as well as non-steady-state chambers, because the slow rate of gas diffusion in soil inhibits recovery of the former from their initial non-steady-state condition. Over a range of representative conditions, the error in steady state chamber estimates of the trace gas flux varied from -30 to +32%, while estimates computed by linear regression from non-steadystate chamber concentrations were 2 to 31% too small. Although such errors are relatively small in comparison to the temporal and spatial variability characteristic of trace gas exchange, they bias the summary statistics for each experiment as well as larger scale trace gas flux estimates based on them.

Journal of Geophysical Research D: Atmospheres↗

USGS1999

Retention of an atmosphere on early Mars

The presence of valley networks and indications of high erosion rates in ancient terrains on Mars suggest that Mars was warm and wet during heavy bombardment. Various processes that could occur on early Mars were integrated into a self-consistent model to determine what circumstances might lead to warm temperatures during and at the end of heavy bombardment. Included were weathering and burial of CO 2 as carbonates, impact erosion, sputtering, and recycling of CO 2 back into the atmosphere by burial and heating. The models suggest that despite losses from the atmosphere by weathering and impact erosion, Mars could retain a 0.5 to 1 bar atmosphere at the end of heavy bombardment partly because weathering temporarily sequesters CO 2 in the ground and protects it from impact erosion while the impact rate is declining and impact erosion is becoming less effective. Because of the low output of the early Sun, surface temperatures can be above freezing only for a very efficient greenhouse, such as that suggested by Forget and Pierrehumbert [1997]. With weak greenhouse models, temperatures are below freezing throughout heavy bombardment, and such a large amount of CO 2 is left in the atmosphere at the end of heavy bombardment that it is difficult to eliminate subsequently to arrive at the present surface inventory. With strong greenhouse models, temperatures are well above freezing during heavy bombardment and drop to close to freezing at the end of heavy bombardment, at which time the atmosphere contains 0.5 to 1 bar of CO 2 . This can be largely eliminated subsequently by sputtering and low-temperature weathering. Such a model is consistent with the change in erosion rate and the declining rate of valley formation at the end of heavy bombardment. Conditions that favor warm temperatures at the end of heavy bombardment are an efficient greenhouse, low weathering rates, low impact erosion rates, and a smaller fraction of heat lost by conduction as opposed to transport of lava to the surface.

Journal of Geophysical Research E: Planets↗

USGS2000

Mineralogic and compositional properties of Martian soil and dust: results from Mars Pathfinder

Mars Pathfinder obtained multispectral, elemental, magnetic, and physical measurements of soil and dust at the Sagan Memorial Station during the course of its 83 sol mission. We describe initial results from these measurements, concentrating on multispectral and elemental data, and use these data, along with previous Viking, SNC meteorite, and telescopic results, to help constrain the origin and evolution of Martian soil and dust. We find that soils and dust can be divided into at least eight distinct spectral units, based on parameterization of Imager for Mars Pathfinder (IMP) 400 to 1000 nm multispectral images. The most distinctive spectral parameters for soils and dust are the reflectivity in the red, the red/blue reflectivity ratio, the near-IR spectral slope, and the strength of the 800 to 1000 nm absorption feature. Most of the Pathfinder spectra are consistent with the presence of poorly crystalline or nanophase ferric oxide(s), sometimes mixed with small but varying degrees of well-crystalline ferric and ferrous phases. Darker soil units appear to be coarser-grained, compacted, and/or mixed with a larger amount of dark ferrous materials relative to bright soils. Nanophase goethite, akaganeite, schwertmannite, and maghemite are leading candidates for the origin of the absorption centered near 900 nm in IMP spectra. The ferrous component in the soil cannot be well-constrained based on IMP data. Alpha proton X-ray spectrometer (APXS) measurements of six soil units show little variability within the landing site and show remarkable overall similarity to the average Viking-derived soil elemental composition. Differences exist between Viking and Pathfinder soils, however, including significantly higher S and Cl abundances and lower Si abundances in Viking soils and the lack of a correlation between Ti and Fe in Pathfinder soils. No significant linear correlations were observed between IMP spectral properties and APXS elemental chemistry. Attempts at constraining the mineralogy of soils and dust using normative calculations involving mixtures of smectites and silicate and oxide minerals did not yield physically acceptable solutions. We attempted to use the Pathfinder results to constrain a number of putative soil and dust formation scenarios, including palagonitization and acid-fog weathering. While the Pathfinder soils cannot be chemically linked to the Pathfinder rocks by palagonitization, this study and McSween et al. [1999] suggest that palagonitic alteration of a Martian basaltic rock, plus mixture with a minor component of locally derived andesitic rock fragments, could be consistent with the observed soil APXS and IMP properties.

Journal of Geophysical Research E: Planets↗

USGS2000

Compositional analyses of small lunar pyroclastic deposits using Clementine multispectral data

Clementine ultraviolet-visible (UVVIS) data are used to examine the compositions of 18 pyroclastic deposits (15 small, three large) at 13 sites on the Moon. Compositional variations among pyroclastic deposits largely result from differing amounts of new basaltic (or juvenile) material and reworked local material entrained in their ejecta upon eruption. Characterization of pyroclastic deposit compositions allows us to understand the mechanisms of lunar explosive volcanism. Evidence for compositional differences between small pyroclastic deposits at a single site is observed at Atlas crater. At all sites, compositional variation among the small pyroclastic deposits is consistent with earlier classification based on Earth-based spectra: three compositional groups can be observed, and the trend of increasing mafic absorption band strength from Group 1 to Group 2 to Group 3 is noted. As redefined here, Group 1 deposits include those of Alphonsus West, Alphonsus Southeast, Alphonsus Northeast 2, Atlas South, Crüger, Franklin, Grimaldi, Lavoisier, Oppenheimer, Orientale, and Riccioli. Group 1 deposits resemble lunar highlands, with weak mafic bands and relatively high UV/VIS ratios. Group 2 deposits include those of Alphonsus Northeast 1, Atlas North, Eastern Frigoris East and West, and Aristarchus Plateau; Group 2 deposits are similar to mature lunar maria, with moderate mafic band depths and intermediate UV/VIS ratios. The single Group 3 deposit, J. Herschel, has a relatively strong mafic band and a low UV/VIS ratio, and olivine is a likely juvenile component. Two of the deposits in these groups, Orientale and Aristarchus, are large pyroclastic deposits. The third large pyroclastic deposit, Apollo 17/Taurus Littrow, has a very weak mafic band and a high UV/VIS ratio and it does not belong to any of the compositional groups for small pyroclastic deposits. The observed compositional variations indicate that highland and mare materials are also present in many large and small pyroclastic deposits, and they suggest that volcanic glasses or spheres may not be dominant juvenile components in all large pyroclastic deposits.

Journal of Geophysical Research E: Planets↗

USGS2000

The thermal inertia of Mars from the Mars Global Surveyor Thermal Emission Spectrometer

We have used Mars Global Surveyor (MGS) Thermal Emission Spectrometer thermal emission measurements to derive the thermal inertia of the Martian surface at the ∼100-km spatial scale. We have validated the use of nighttime-only measurements to derive thermal inertia as well as the use of a single wavelength band versus bolometric thermal emission measurements. We have also reanalyzed the Viking Infrared Thermal Mapper data set in a similar manner in order to allow a direct comparison between the two. Within the uncertainties of the fit of the data to the model, and the uncertainties inherent in the model, the thermal inertia has not changed substantially in the 21 years between the Viking and the MGS measurements. Although some differences are seen, they are most likely due to changes in albedo during the intervening years or to residual effects of airborne dust that are not fully accounted for in the thermal models. The thermal inertia values that we derive, between about 24 and 800 J m -2 s -1/2 K -1 , are thought to better represent the actual thermal inertia of the Martian surface than previous estimates.

Journal of Geophysical Research E: Planets↗

USGS2000

Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets↗