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USGS1960

Minor element content of coal from Illinois beds 5 and 6 and their correlatives in Indiana and western Kentucky

Spectrographic analyses for 15 elements of 249 block samples of coal are reported here. These samples represent 28 localities of beds 5 and 6 of Illinois and their correlatives in Indiana and western Kentucky. Comparison with the coals of the Northern Great Plains province shows a similarity in the total amount of these elements in the coal, however, individual elements differ considerably. The degree of association with the organic or inorganic matter of coal is determined by the separation of thirteen samples into float and sink fractions. Be, B, Ti, V, Ga, and Ge are essentially associated with the organic matter of coal. Zn, Sn and La are invariably found to be associated with the inorganic matter. Cr, Co, Ni, Cu, Mo and Y have intermediate degrees of association.

Illinois, Indiana, Kentucky↗

USGS1979

The concentration and mobility of elements in subalpine forest soils in Colorado and Idaho

Leaching studies of subalpine forest soils collected at seven sites in Colorado and Idaho show that copper, cobalt, chromium, magnesium, barium, tin, strontium, and yttrium are highly mobile elements in these soils; that zirconium, lanthanum, nickel, and scandium are moderately mobile; and that titanium is rather immobile. Furthermore, the results of the studies indicate that elements are most highly concentrated in the ash of the mull (02) horizon. In these soils, the mull horizon is a more favorable zone for the accumulation of metals and other elements than are the mineral (A,B,C) soil horizons.

Colorado, Idaho↗

USGS1982

Effects of processed oil shale on the element content of Atriplex cancescens

Samples of four-wing saltbush were collected from the Colorado State University Intensive Oil Shale Revegetation Study Site test plots in the Piceance basin, Colorado. The test plots were constructed to evaluate the effects of processed oil shale geochemistry on plant growth using various thicknesses of soil cover over the processed shale and/or over a gravel barrier between the shale and soil. Generally, the thicker the soil cover, the less the influence of the shale geochemistry on the element concentrations in the plants. Concentrations of 20 elements were larger in the ash of four-wing saltbush growing on the plot with the gravel barrier (between the soil and processed shale) when compared to the sample from the control plot. A greater water content in the soil in this plot has been reported, and the interaction between the increased, percolating water and shale may have increased the availability of these elements for plant uptake. Concentrations of boron, copper, fluorine, lithium, molybdenum, selenium, silicon, and zinc were larger in the samples grown over processed shale, compared to those from the control plot, and concentrations for barium, calcium, lanthanum, niobium, phosphorus, and strontium were smaller. Concentrations for arsenic, boron, fluorine, molybdenum, and selenium-- considered to be potential toxic contaminants--were similar to results reported in the literature for vegetation from the test plots. The copper-to-molybdenum ratios in three of the four samples of four-wing saltbush growing over the processed shale were below the ratio of 2:1, which is judged detrimental to ruminants, particularly cattle. Boron concentrations averaged 140 ppm, well above the phytotoxicity level for most plant species. Arsenic, fluorine, and selenium concentrations were below toxic levels, and thus should not present any problem for revegetation or forage use at this time.

Open-File Report↗

USGS1994

Guidelines for collecting and processing samples of stream bed sediment for analysis of trace elements and organic contaminants for the National Water-Quality Assessment Program

A major component of the U.S. Geological Survey's National Water-Quality Assessment program is to assess the occurrence and distribution of trace elements and organic contaminants in streams. The first phase of the strategy for the assessment is to analyze samples of bed sediments from depositional zones. Fine-grained particles deposited in these zones are natural accumulators of trace elements and hydrophobic organic compounds. For the information to be comparable among studies in many different parts of the Nation, strategies for selecting stream sites and depositional zones are critical. Fine-grained surficial sediments are obtained from several depositional zones within a stream reach and composited to yield a sample representing average conditions. Sample collection and processing must be done consistently and by procedures specifically designed to separate the fine material into fractions that yield uncontaminated samples for trace-level analytes in the laboratory. Special coring samplers and other instruments made of Teflon are used for collection. Samples are processed through a 2.0-millimeter stainless-steel mesh sieve for organic contaminate analysis and a 63-micrometer nylon-cloth sieve for trace-element analysis. Quality assurance is maintained by strict collection and processing procedures, duplicate samplings, and a rigid cleaning procedure.

Open-File Report↗

USGS1996

Nutrient and trace-element enrichment of Coeur d'Alene Lake, Idaho

The limnological characteristics and geochemistry of lakebed sediments in Coeur d'Alene Lake, a 129-square-kilometer, natural lake in northern Idaho, were assessed during 1991-92 because of the possible interaction of nutrient enrichment with the highly enriched trace-element concentrations stored in the lakebed. The lake was classified as oligotrophic during 1991-92 on the basis of annual geometric mean concentrations, in micrograms per liter, of total phosphorus (4.1), total nitrogen (247), and chlorophyll-a (0.54). Despite its oligotrophy, the lake developed a substantial hypolimnetic dissolved-oxygen deficit in both years during the later stage of thermal stratification. The lake's current trophic state of oligotrophic differs from the mesotrophic ranking it received in 1975 during the National Eutrophication Survey. The shift in trophic state was consistent with nutrient-load reductions that have occurred within the lake's 9,690-square-kilometer drainage basin since the early 1970's. Approximately 85 percent of the lakebed's surface area was highly enriched in antimony, arsenic, cadmium, lead, mercury, silver, and zinc. Mean total concentrations, in milligrams per kilogram, for cadmium, lead, and zinc in the enriched lakebed sediments were, respectively, 62, 1,900, and 3,600. In contrast, the concentrations of cadmium, lead, and zinc in unenriched lakebed sediments in the lake's southern end were, respec- tively, 2.8, 24, and 110 milligrams per kilogram. The vast majority of the trace elements in the surficial and subsurface sediments were associated with ferric oxides, not sulfides as previously postulated. Under reducing conditions, such as within as anoxic hypolimnon, the ferric oxide- associated trace elements would be readily soluble and available for release into the overlying water column. (USGS)

Idaho↗

USGS1996

Concentrations and loads of selected trace elements and other constituents in the Rio Grande in the vicinity of Albuquerque, New Mexico, 1994

The Pueblo of Isleta and the New Mexico Environment Department have established water-quality standards for the Rio Grande, which flows through Albuquerque, New Mexico. Trace-element concentrations historically have been greater than maximum permissible concentrations allowed by these standards. It is not known if these concentrations are due to sources from the Albuquerque metropolitan area or are from natural or other sources outside Albuquerque. Accurate water-quality data with lower reporting limits than have been previously available were collected, and instantaneous concentrations and loads were calculated for trace elements and other constituents in the Rio Grande during high-flow and low- flow conditions. Seven sampling sites were selected upstream from, in, and downstream from metropolitan Albuquerque. Concurrent streamflow measurements were made at the time of sampling to determine suspended-sediment loads. Samples were analyzed separately for trace elements dissolved in water (less than 0.4 micrometer in diameter) and for those contained in suspended sediment (greater than 0.1 micrometer in diameter). Sample collection and processing, analytical methods, and quality control are discussed.

New Mexico↗

USGS1996

Water-quality assessment of the Albemarle-Pamlico drainage basin, North Carolina and Virginia; trace elements in Asiatic clam (Corbicula fluminea) soft tissues and redbreast sunfish (Lepomis auritus) livers, 1992-93

The analysis of potential contaminants in biological tissues is an important part of many water-quality assessment programs, including the National Water-Quality Assessment (NAWQA) Program. Tissue analyses often are used to provide information about (1) direct threats to ecosystem integrity, and (2) the occurrence and distribution of potential contaminants in the environment. During 1992-93, trace elements in Asiatic clam (Corbicula fluminea) soft tissues and redbreast sunfish (Lepomis auritus) livers were analyzed to obtain information about the occurrence and distribution of trace element contaminants in the Albemarle-Pamlico Drainage Basin of North Carolina and Virginia. The investigation was conducted as part of the NAWQA Program. All but 3 of the 22 trace elements that were analyzed were detected. Although all 10 of the U.S. Environmental Protection Agency (U.S. EPA) priority pollutants were detected in the tissues sampled, they were present in relatively low concentrations. Concentrations of U.S. EPA priority pollutants in Asiatic clams collected in the Albemarle-Pamlico Drainage Basin are similar to concentrations observed in other NAWQA study units in the southeastern United States. Mercury (a U.S. EPA priority pollutant) was widely detected, being present in 29 of 30 tissue samples, but concentrations did not exceed the FDA action level for mercury of a risk-based screening value for the general public. Mercury concentrations in Asiatic clams were similar to concentrations in other NAWQA study areas in the Southeast.

North Carolina, Virginia↗

USGS1997

Concentrations of platinum group elements in 122 U.S. coal samples

Analysis of more than 13,000 coal samples by semi-quantitative optical emission spectroscopy (OES) indicates that concentrations of the platinum group elements (iridium, palladium, platinum, osmium, rhodium, and ruthenium) are less than 1 ppm in the ash, the limit of detection for this method of analysis. In order to accurately determine the concentration of the platinum group elements (PGE) in coal, additional data were obtained by inductively coupled plasma mass spectroscopy, an analytical method having part-per-billion (ppb) detection limits for these elements. These data indicate that the PGE in coal occur in concentrations on the order of 1 ppb or less.

Open-File Report↗

USGS1997

Concentrations of selected trace elements and other constituents in the Rio Grande and in fish tissue in the vicinity of Albuquerque, New Mexico

The State of New Mexico and the Pueblo of Isleta have established surface-water standards for trace elements to control discharges of these contaminants. Before these standards can be meaningfully applied, however, ambient concentrations and loads of trace elements, principally arsenic, need to be determined in the Rio Grande and inflow sources. Arsenic concentrations also need to be determined in the edible portion of fish tissue because the Pueblo of Isleta standard for arsenic is based on fish consumption. Eighteen surface-water sampling sites on a reach of the Rio Grande from the Pueblo of San Felipe to Los Lunas, New Mexico, were sampled quarterly from October 1994 to August 1996. The sites include eight Rio Grande sites, one Jemez River site, five riverside drain sites, and four wastewater- treatment plant outfalls. Trace-element protocol was used to collect and process the samples. Field and laboratory quality-control samples were analyzed, and the results are included in this report. Fish-tissue samples were collected from four of the Rio Grande sites and the Albuquerque Riverside Drain, the Atrisco Riverside Drain, and three lakes at a recreational fishing area on the Isleta Indian Reservation. Arsenic in the Rio Grande is nearly all in the dissolved phase. There was little temporal change in arsenic concentration at the Rio Grande sites. The mean dissolved-arsenic concentration in the Rio Grande increased downstream from 1.8 micrograms per liter at the Pueblo of San Felipe to 3.6 micrograms per liter at Los Lunas. Mean dissolved-arsenic concentrations in the riverside drains were slightly higher (2.8 to 4.5 micrograms per liter) than those in the Rio Grande and were higher still in the wastewater-treatment plant outfalls (7.9 to 16.2 micrograms per liter) and the Jemez River (18.2 micrograms per liter). The mean total-arsenic concentration in fish-tissue samples from the Rio Grande and Albuquerque Riverside Drain was 14.53 micrograms per kilogram.

Open-File Report↗

USGS1981

Alkalic rocks and resources of thorium and associated elements in the Powderhorn District, Gunnison County, Colorado

Alkalic igneous rocks and related concentrations of thorium, niobium, rare-earth elements, titanium, and other elements have long been known in the Powderhorn mining district and have been explored intermittently for several decades. The deposits formed chiefly about 570 m.y. (million years) ago in latest Precambrian or Early Cambrian time. They were emplaced in lower Proterozoic (Proterozoic X) metasedimentary, metavolcanic, and plutonic rocks. The complex of alkalic rocks of Iron Hill occupies 31 km 2 (square kilometers) and is composed of pyroxenite, uncompahgrite, ijolite, nepheline syenite, and carbonatite, in order of generally decreasing age. Fenite occurs in a zone, in places more than 0.6 km (kilometer) wide, around a large part of the margin of the complex and adjacent to alkalic dikes intruding Precambrian host rock. The alkalic rocks have a radioactivity, chiefly due to thorium, greater than that of the surrounding Powderhorn Granite (Proterozoic X) and metamorphic rocks. The pyroxenite, uncompahgrite, ijolite, and nepheline syenite, which form more than 80 percent of the complex, have fairly uniform radioactivity. Radioactivity in the carbonatite stock, carbonatite dikes, and the carbonatite-pyroxenite mixed rock zone, however, generally exceeds that in the other rocks of the complex. The thorium concentrations in the Powderhorn district occur in six types of deposits: thorite veins, a large massive carbonatite body, carbonatite dikes, trachyte dikes, magnetite-ilmeniteperovskite dikes or segregations, and disseminations in small, anomalously radioactive plutons chiefly of granite or quartz syenite that are older than rocks of the alkalic complex. The highest grade thorium concentrations in the district are in veins that commonly occur in steeply dipping, crosscutting shear or breccia zones in the Precambrian rocks. They range in thickness from a centimeter or less to 5 m (meters) and are as much as 1 km long. The thorite veins are composed chiefly of potassic feldspar, white to smoky quartz, calcite, barite, goethite, and hematite, and also contain thorite, jasper, magnetite, pyrite, galena, chalcopyrite, sphalerite, synchysite, apatite, fluorite, biotite, sodic amphibole, rutile, monazite, bastnaesite, and vanadinite. The Th0 2 content of the thorite veins ranges from less than 0.01 percent to as much as 4.9 percent in high-grade samples. The Th0 2 content is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins examined in the district. Samples of the dolomitic carbonatite of Iron Hill mostly range from 3 to 145 ppm (parts per million) thorium. Thirty samples of the carbonatite dikes, the most radioactive rocks within the complex of Iron Hill, contain about 30 to 3,200 ppm thorium and a trace to about 1.5 percent rare-earth oxides. The magnetite-ilmenite-perovskite rocks have a radioactivity of 2 to 12 times the background of Precambrian granite that is attributable chiefly to thorium substitution for calcium in the perovskite. In two analyses the perovskite contains 0.12 and 0.15 percent Th0 2 . Trachyte dikes as much as 25 m thick cut the Precambrian rocks; their radioactivity is generally about two to four times the background of typical Precambrian granite, is locally higher, but is low relative to other types of thorium concentrations. A finegrained granite that is anomalously radioactive occurs in thick, dikelike plutons as much as 1.2 km wide, or more. The thorium content varies widely within the granite bodies. Eight samples of the granite contain 32 to 281 ppm thorium (averaging 115 ppm). The economic potential of thorium in the Powderhorn district is related in part to other elements such as niobium, titanium, iron, and rare earths. The proportions of niobium and rare earths to thorium vary in different parts of the district. Within the carbonatite body of Iron Hill, the Nb 2 0 5 content greatly exceeds Th0 2 , but the Th0 2 -Nb 2 0 5

Professional Paper↗

USGS1988

Geology and resources of thorium and associated elements in the Wet Mountains area, Fremont and Custer counties, Colorado

Thorium in potentially economic amounts occurs in three types of deposits in the Wet Mountains area of Colorado: (1) quartz-baritethorite veins and fracture zones, (2) carbonatite dikes, and (3) red syenite dikes. The quartz-barite-thorite veins and fracture zones contain the largest resources of thorium; they cut all Precambrian and Paleozoic rock types in the area and tend to strike normal to the foliation in the Proterozoic metasedimentary and metavolcanic rocks. The veins and fracture zones are end products of the episode of Cambrian alkaline magmatism that also produced rocks of the McClure Mountain Complex, the Gem Park Complex, the complex at Democrat Creek, and associated dikes of carbonatite, lamprophyre, and red syenite. The veins and fracture zones contain an average of 0.46 percent ThO2, 0.21 percent SLREE (total light rare-earth elements), 0.14 percent SHREE (total heavy rare-earth elements), and 0.012 percent Nb2O5; They contain reserves of 64,200 tons ThO2, 29,300 tons SLREE, 19,540 tons SHREE, 1,675 tons Nb2O5; they contain probable potential resources of 160,500 tons ThO2, 73,270 tons SLREE, 48,850 tons SHREE, and 4,185 tons Nb2O5. The carbonatite dikes form two distinct groups: replacement carbonatites and primary magmatic carbonatites. The latter group appears to be the better source of potentially economic commodities. The primary magmatic carbonatites contain an average of 0.17 percent ThO2, 0.0097 percent Nb2O5, 0.0031 percent U3O5, and 2.15 percent total rare-earth oxides. The seven largest dikes contain reserves of 131 tons ThO2, 40 tons Nb2O5, 17 tons U3O5, and 2,500 tons SRE203 (total rare-earth oxides), and probable potential resources of 753 tons ThO2, 228 tons Nb2O5, 105 tons U3O5, and 14,300 tons SRE2O3. The red syenite dikes contain anomalous amounts of thorium, uranium, niobium, and rare-earth elements. Although reserves and probable potential resources have not been calculated, they are likely to be small.

Professional Paper↗

USGS2023

Survey of chromium and selected element concentrations in rock, alluvium, and core material

Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from the Pacific Gas and Electric Company (PG&E) compressor station in Hinkley, California, in the western Mojave Desert 80 miles northeast of Los Angeles, California. In 2015, the extent of anthropogenic Cr(VI) in groundwater in Hinkley and Water Valleys was uncertain, and some Cr(VI) in groundwater may be naturally occurring from rock and aquifer material. On the basis of more than 1,500 portable (handheld) X-ray fluorescence (pXRF) measurements on more than 250 samples of rock, surficial alluvium, and core material from selected wells in Hinkley and Water Valleys, chromium concentrations are commonly low compared to the average bulk continental abundance of 185 milligrams per kilogram (mg/kg). However, chromium concentrations are as high as 530 mg/kg in mafic hornblende diorite that crops out along the western margin of Hinkley Valley in Iron Mountain. Other chromium-containing rocks in the area are either (1) not consistently high in chromium, (2) have limited areal extent, or (3) in the case of basalt, are present only in Water Valley. Chromium concentrations in core material adjacent to the screened intervals of wells sampled for water chemistry and isotopic composition as part of the U.S. Geological Survey Cr(VI) background study ranged from less than the study reporting level (SRL) of 5 mg/kg to 410 mg/kg, with a median concentration of 23 mg/kg. Chromium concentrations in core material were lower in the eastern subarea and higher in the western and the northern subareas of Hinkley Valley and in Water Valley. The highest chromium concentration in core material was in weathered hornblende diorite bedrock. Chromium concentrations in core material adjacent to the screened interval of sampled wells were log-normally distributed below a threshold of 85 mg/kg, and 3 percent of chromium concentrations were greater than 85 mg/kg. Manganese can oxidize trivalent chromium, Cr(III), to Cr(VI). Similar to chromium, manganese concentrations in core material also were log-normally distributed below a threshold of 970 mg/kg, and 5 percent of manganese concentrations were greater than 970 mg/kg. Both chromium and manganese concentrations were higher in fine-textured core material and in visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains. High concentrations of chromium and manganese in core material commonly co-occurred. Fine-textured core material, chromium concentrations greater than 85 mg/kg, and manganese concentrations greater than 970 mg/kg in core material adjacent to the screened interval of sampled wells were selected for use as metrics (threshold values) within a summative-scale analysis (SSA) developed to identify natural and anthropogenic Cr(VI) in water from wells later within this professional paper (chapter G). Principal component analysis (PCA) of 18 elements within surficial alluvium, rock, and core material measured using pXRF shows distinct elemental assemblages associated with (1) older and more recent “Mojave-type” deposits, including alluvium and lake-margin (beach) deposits sourced from the Mojave River, (2) alluvium eroded from mafic rock, including hornblende diorite that crops out on Iron Mountain, (3) alluvium eroded from felsic volcanic and hydrothermal rock that crops out on Mount General along the eastern margin of Hinkley Valley, (4) playa/mudflat and other fine-textured deposits, and (5) material with visually abundant iron- and manganese-oxide coatings. Most wells sampled as part of this study were completed in Mojave-type deposits. Portable (handheld) X-ray fluorescence data measured on core material from those wells do not appear to be different or unusual compared to the magnitude and range of data from the larger Mojave River groundwater basin, and the core material has a low-chromium, felsic composition consistent with a Mojave River origin. In general, the elemental composition of core material from wells was not measurably altered by admixtures with local mafic, felsic volcanic, or hydrothermal source materials; although, where present, admixtures with basalt may contribute chromium to core material.

California↗

USGS2008

Occurrence of organic compounds and trace elements in the upper Passaic and Elizabeth Rivers and their tributaries in New Jersey, July 2003 to February 2004: Phase II of the New Jersey toxics reduction workplan for New York-New Jersey Harbor

Samples of surface water and suspended sediment were collected from the Passaic and Elizabeth Rivers and their tributaries in New Jersey from July 2003 to February 2004 to determine the concentrations of selected chlorinated organic and inorganic constituents. This sampling and analysis was conducted as Phase II of the New York-New Jersey Harbor Estuary Workplan—Contaminant Assessment and Reduction Program (CARP), which is overseen by the New Jersey Department of Environmental Protection. Phase II of the New Jersey Workplan was conducted to define upstream tributary and point sources of contaminants in those rivers sampled during Phase I work, with special emphasis on the Passaic and Elizabeth Rivers. Samples were collected from three groups of tributaries: (1) the Second, Third, and Saddle Rivers; (2) the Pompton and upper Passaic Rivers; and (3) the West Branch and main stem of the Elizabeth River. The Second, Third, and Saddle Rivers were sampled near their confluence with the tidal Passaic River, but at locations not affected by tidal flooding. The Pompton and upper Passaic Rivers were sampled immediately upstream from their confluence at Two Bridges, N.J. The West Branch and the main stem of the Elizabeth River were sampled just upstream from their confluence at Hillside, N.J. All tributaries were sampled during low-flow discharge conditions using the protocols and analytical methods for organic constituents used in low-flow sampling in Phase I. Grab samples of streamflow also were collected at each site and were analyzed for trace elements (mercury, methylmercury, cadmium, and lead) and for suspended sediment, particulate organic carbon, and dissolved organic carbon. The measured concentrations and available historical suspended-sediment and stream-discharge data (where available) were used to estimate average annual loads of suspended sediment and organic compounds in these rivers. Total suspended-sediment loads for 1975–2000 were estimated using rating curves developed from historical U.S. Geological Survey (USGS) suspended-sediment and discharge data, where available. Average annual loads of suspended sediment, in millions of kilograms per year (Mkg/yr), were estimated to be 0.190 for the Second River, 0.23 for the Third River, 1.00 for the Saddle River, 1.76 for the Pompton River, and 7.40 for the upper Passaic River. On the basis of the available discharge records, the upper Passaic River was estimated to provide approximately 60 percent of the water and 80 percent of the total suspended-sediment load at the Passaic River head-of-tide, whereas the Pompton River provided roughly 20 percent of the total suspended-sediment load estimated at the head-of-tide. The combined suspended-sediment loads of the upper Passaic and Pompton Rivers (9.2 Mkg/yr), however, represent only 40 percent of the average annual suspended-sediment load estimated for the head-of-tide (23 Mkg/yr) at Little Falls, N.J. The difference between the combined suspended-sediment loads of the tributaries and the estimated load at Little Falls represents either sediment trapped upriver from the dam at Little Falls, additional inputs of suspended sediment downstream from the tributary confluence, or uncertainty in the suspended-sediment and discharge data that were used. The concentrations of total suspended sediment-bound polychlorinated biphenyls (PCBs) in the tributaries to the Passaic River were 194 ng/g (nanograms per gram) in the Second River, 575 ng/g in the Third River, 2,320 ng/g in the Saddle River, 200 ng/g in the Pompton River, and 87 ng/g in the upper Passic River. The dissolved PCB concentrations in the tributaries were 563 pg/L (picograms per liter) in the Second River, 2,510 pg/L in the Third River, 2,270 pg/L in the Saddle River, 887 pg/L in the Pompton River, and 1,000 pg/L in the upper Passaic River. Combined with the sediment loads and discharge, these concentrations resulted in annual loads of suspended sediment-bound PCBs, in grams per year (g/yr), of 37 in the Second River; 132 in the Third River; 2,320 in the Saddle River; 352 in the Pompton River; and 644 in the upper Passaic River. Annual loads of dissolved PCBs, in grams per year, are 9.2 in the Second River; 47 in the Third River; 212 in the Saddle River; 349 in the Pompton River; and 549 in the upper Passaic River. Concentrations of total suspended sediment-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-difurans (PCDD/PCDFs) were 6,000 pg/g (picograms per gram) in the Second River; 11,300 pg/g in the Third River; 37,700 pg/g in the Saddle River; 7,140 pg/g in the Pompton River; and 9,640 pg/g in the upper Passaic River. Total toxic equivalence quotients (TEQs), which included PCDD/PCDFs and coplanar PCBs, ranged from 2.7 pg/g in the Second River to 132 pg/g (as 2,3,7,8-TCDD) in the Saddle River. Average annual loads of PCDD/PCDFs were from 1.1 g/yr in the Second River to 71 g/yr in the upper Passaic River. The load of TEQs (as 2,3,7,8-TCDD) from PCDD/PCDFs and coplanar PCBs in the tributaries were 0.5 mg/yr (milligrams per year) in the Second River, 5.8 mg/yr in the Third River, 130 mg/yr in the Saddle River, 46 mg/yr in the Pompton River, and 100 mg/yr in the upper Passaic River. These loads represent an addition to the TEQ load estimated to cross the head-of-tide of 0.1 percent by the Second River, 0.7 percent by the Third River, and 15 percent by the Saddle River. Loads of sediment-bound trace elements mercury, methylmercury, lead, and cadmium were calculated using concentrations obtained from grab samples, which were assumed to represent average annual concentrations in these rivers. Loads of sediment-bound mercury were estimated to be 1,200 g/yr in the Second River; 130 g/yr in the Third River; 4,200 g/yr in the Saddle River; 3,400 g/yr in the Pompton River; and 6,500 g/yr in the upper Passaic River. Loads of sediment-bound lead were estimated to be 56 kg/yr (kilograms per year) in the Second River; 89 kg/yr in the Third River; 1,140 kg/yr in the Saddle River; 310 kg/yr in the Pompton River; and 1,040 kg/yr in the upper Passaic River. Loads of sediment-bound cadmium were estimated to be 1 kg/yr in the Second River; 0.59 kg/yr in the Third River; 60 kg/yr in the Saddle River; 16 kg/yr in the Pompton River; and 11 kg/yr in the upper Passaic River. These loads indicate the importance of the sediment-bound contributions of organic compounds and trace elements to the upper Passaic and Saddle Rivers. Concentrations of suspended sediment-bound PCBs in the main stem and the West Branch of the Elizabeth River were 806 ng/g and 3,100 ng/g, respectively, representing loads of 40 g/yr and 1,150 g/yr, respectively. These loads were estimated using assumed discharge conditions. Concentrations of suspended sediment-bound PCDD/PCDFs were 7,270 pg/g and 9,980 pg/g in the main stem and West Branch, respectively, representing average annual loads of 0.36 g/yr and 3.7 g/yr, respectively. Total TEQ loads (sum of PCDD/PCDFs and PCBs) were 2.1 mg/yr (as 2,3,7,8-TCDD) in the main stem and 34 mg/yr in the West Branch, respectively. These load estimates, however, were directly related to the assumed annual discharge for the two branches. Long-term measurement of stream discharge and suspended-sediment concentrations would be needed to verify these loads. On the basis of the concentrations measured in this work, it appears that the West Branch is the principal source of PCBs, PCDD/PCDFs, total TEQs, and metals to the main stem of the Elizabeth River. Additional sources of these constituents may exist between the confluence and the head-of-tide.

New Jersey, New York↗

USGS2014

Assessment of metal and trace element contamination in water, sediment, plants, macroinvertebrates, and fish in Tavasci Marsh, Tuzigoot National Monument, Arizona

Tavasci Marsh is a large freshwater marsh within the Tuzigoot National Monument in central Arizona. It is the largest freshwater marsh in Arizona that is unconnected to the Colorado River and is designated as an Important Bird Area by the Audubon Society. The marsh has been altered significantly by previous land use and the monument’s managers are evaluating the restoration of the marsh. In light of historical mining activities located near the marsh from the first half of the 20th century, evaluations of water, sediment, plant, and aquatic biota in the marsh were conducted. The evaluations were focused on nine metals and trace elements commonly associated with mining and other anthropogenic activities (As, Cd, Cr, Cu, Hg, Ni, Pb, Se, and Zn) together with isotopic analyses to understand the presence, sources and timing of water and sediment contaminants to the marsh and the occurrence in aquatic plants, dragonfly larvae, and fish. Results of water analyses indicate that there were two distinct sources of water contributing to the marsh during the study: one from older high elevation recharge entering the marsh at Shea Spring (as well as a number of unnamed seeps and springs on the northeastern edge of the marsh) and the other from younger low elevation recharge or from Pecks Lake. Water concentrations for arsenic exceeded the U.S. Environmental Protection Agency primary drinking water standard of 10 μg/L at all sampling sites. Surface waters at Tavasci Marsh may contain conditions favorable for methylmercury production. All surficial and core sediment samples exceeded or were within sample concentration variability of at least one threshold sediment quality guideline for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn. Several sediment sites were also above or were within sample concentration variability of severe or probable effect sediment quality guidelines for As, Cd, and Cu. Three sediment cores collected in the marsh have greater metal and trace element concentrations at depth for Bi, Cd, Cu, Hg, In, Pb, Sb, Sn, Te, and Zn. Radioisotope dating indicates that the elevated metal and trace element concentrations are associated with sediments deposited before 1963. Arsenic concentration was greater in cattail roots compared with surrounding sediment at Tavasci Marsh. Concentrations of As, Ni, and Se from yellow bullhead catfish (Ameiurus natalis) in Tavasci Marsh exceeded the 75th percentile of several other regional studies. Mercury concentration in dragonfly larvae and fish from Tavasci Marsh were similar to or greater than in Tavasci Marsh sediment. Future work includes a biologic risk assessment utilizing the data collected in this study to provide the monument management with additional information for their restoration plan.

Arizona↗

USGS2002

Trace elements and organic compounds in streambed sediment and fish tissue of coastal New England streams, 1998-99

Streambed sediment and fish tissue were collected at 14 river sites in eastern New England during low-flow conditions in 1998 and 1999 as part of the New England Coastal Basins (NECB) study of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. Sampling sites were selected over a range of urban settings. Population densities at selected sites ranged from 26 to 3,585 people per square mile, and urban land use ranged from 1 to 68 percent. The streambed sediment samples were analyzed for a total of 141 contaminants, including 45 trace elements, 32 organochlorine compounds, and 64 semi-volatile organic compounds. The fish tissue samples were analyzed for 22 trace elements and 28 organochlorine compounds. Concentrations of selected contaminants in both streambed sediment and fish tissue correlated more strongly with population density than with other watershed characteristics. Cadmium, copper, lead, mercury, zinc, total polycyclic aromatic hydrocarbons (PAHs), total polychlorinated biphenyls (PCBs), dichloro diphenyl trichloroethane and metabolites (DDTM), and total chlordane in streambed sediment all showed strong positive correlations with population density (rho = 0.71 to 0.85, p value = 0.005 to <0.001). Correlations between population density and selected contaminants in fish tissue were less significant than with streambed sediment (rho = 0.62 to 0.72, p value = 0.03 to 0.008). Organic carbon concentrations were correlated with concentrations of arsenic, selenium, total PAHs, total PCBs, and DDTM in streambed sediment. The relation between concentrations of contaminants in streambed sediment and fish tissue was stronger for organochlorine compounds (rho = 0.75 to 0.55, p = 0.005 to 0.065) than for trace elements (rho = 0.63 to 0.53, p = 0.029 to 0.069). The NECB study area had the highest median concentrations of lead, mercury, total PAHs, total PCBs, and DDTM in streambed sediment and the highest median concentration of PCBs in fish tissue compared to 45 other NAWQA study units across the Nation. Concentrations of many of these constituents in streambed sediment also were frequently above the consensus-based Sediment-Quality Guidelines for the protection of wildlife, suggesting they are a threat to the health of aquatic biota in New England.

Water-Resources Investigations Report↗

USGS2003

Spatial distribution and trends in trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls in Lake Worth sediment, Fort Worth, Texas

In spring 2000, the Texas Department of Health issued a fish consumption advisory for Lake Worth in Fort Worth, Texas, because of elevated concentrations of polychlorinated biphenyls (PCBs) in fish. In response to the advisory and in cooperation with the U.S. Air Force, the U.S. Geological Survey collected 21 surficial sediment samples and three gravity core sediment samples to assess the spatial distribution and historical trends of selected hydrophobic contaminants, including PCBs, and to determine, to the extent possible, sources of hydrophobic contaminants to Lake Worth. Compared to reference (background) concentrations in the upper lake, elevated PCB concentrations were detected in the surficial sediment samples collected in Woods Inlet, which receives surface runoff from Air Force facilities and urban areas. Gravity cores from Woods Inlet and from the main part of the lake near the dam indicate that the concentrations of PCBs were three to five times higher in the 1960s than in 2000. A regression method was used to normalize sediment concentrations of trace elements for natural variations and to distinguish natural and anthropogenic contributions to sediments. Concentrations of several trace elements—cadmium, chromium, copper, lead, and zinc—were elevated in sediments in Woods Inlet, along the shoreline of Air Force facilities, and in the main lake near the dam. Concentrations of these five trace elements have decreased since 1970. Polycyclic aromatic hydrocarbons also were elevated in the same areas of the lake. Concentrations of total polycyclic aromatic hydrocarbons, normalized with organic carbon, were mostly stable in the upper lake but steadily increased near the dam, except for small decreases since 1980. The Woods Inlet gravity core showed the largest increase of the three core sites beginning about 1940; total polycyclic aromatic hydrocarbon concentrations in post-1940 sediments from the core showed three apparent peaks about 1960, 1984, and 2000. The concentrations of organochlorine pesticides were low relative to consensus-based sediment-quality guidelines and either decreased or remained constant since 1970. The two likely sources of hydrophobic contaminants to the lake are urban areas around the lake and the drainage area of Meandering Road Creek that contributes runoff to Woods Inlet and includes Air Force facilities.

Texas↗

USGS1977

The use of Galerkin finite-element methods to solve mass-transport equations

The partial differential equation that describes the transport and reaction of chemical solutes in porous media was solved using the Galerkin finite-element technique. These finite elements were superimposed over finite-difference cells used to solve the flow equation. Both convection and flow due to hydraulic dispersion were considered. Linear and Hermite cubic approximations (basis functions) provided satisfactory results: however, the linear functions were computationally more efficient for two-dimensional problems. Successive over relaxation (SOR) and iteration techniques using Tchebyschef polynomials were used to solve the sparce matrices generated using the linear and Hermite cubic functions, respectively. Comparisons of the finite-element methods to the finite-difference methods, and to analytical results, indicated that a high degree of accuracy may be obtained using the method outlined. The technique was applied to a field problem involving an aquifer contaminated with chloride, tritium, and strontium-90. (Woodard-USGS)

Water-Resources Investigations Report↗

USGS1982

Reconnaissance for determining effects of land use and surficial geology on concentrations of selected elements on streambed materials from the coal-mining region, southwestern Indiana, October 1979 to March 1980

Streambed materials were collected in October 1979 from 69 watersheds in Southwest Indiana having predominantly forested, agricultural, reclaimed, and unreclaimed mined land use to determine whether concentrations of sorbed and acid-soluble metals and trace elements were affected by land use and surficial geology. Analysis of variance indicated that 10% or more of the total variation in aluminum, arsenic, cobalt, iron, nickel, selenium, and zinc concentrations on streambed materials was accounted for by differences in land use. Concentrations of aluminum, cobalt, iron, nickel, selenium, and zinc on streambed materials smaller than 0.062-millimeter from mined watersheds were significantly greater than the concentrations of these elements on streambed materials from agricultural and forested watersheds. The greater concentrations of these elements on streambed materials are due to (1) their concentrations in mine drainage and their subsequent absorption and (or) copecipitation with the oxides and hydroxides of aluminum and iron and (2) their concentrations in coal and pyritic material in streambed materials.

Indiana↗