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At least 415 records · Page 23Linked to original sources
USGS2000

Revelations from a single strong-motion record retreived during the 27 June 1998 Adana (Turkey) earthquake

During the 27 June 1998 Adana (Turkey) earthquake, only one strong-motion record was retrieved in the region where the most damage occurred. This single record from the station in Ceyhan, approximately 15 km from the epicenter of that earthquake, exhibits characteristics that are related to the dominant frequencies of the ground and structures. The purpose of this paper is to explain the causes of the damage as inferred from both field observations and the characteristics of a single strong-motion record retrieved from the immediate epicentral area. In the town of Ceyhan there was considerable but selective damage to a significant number of mid-rise (7-12 stories high) buildings. The strong-motion record exhibits dominant frequencies that are typically similar for the mid-rise building structures. This is further supported by spectral ratios derived using Nakamura's method [QR of RTRI, 30 (1989) 25] that facilitates computation of a spectral ratio from a single tri-axial record as the ratio of amplitude spectrum of horizontal component to that of the vertical component [R = H(f)/V(f)]. The correlation between the damage and the characteristics exhibited from the single strong-motion record is remarkable. Although deficient construction practices played a significant role in the extent of damage to the mid-rise buildings, it is clear that site resonance also contributed to the detrimental fate of most of the mid-rise buildings. Therefore, even a single record can be useful to explain the effect of site resonance on building response and performance. Such information can be very useful for developing zonation criteria in similar alluvial valleys. Published by Elsevier Science Ltd.

Soil Dynamics and Earthquake Engineering↗
USGS2010

Analogues to features and processes of a high-level radioactive waste repository proposed for Yucca Mountain, Nevada

Natural analogues are defined for this report as naturally occurring or anthropogenic systems in which processes similar to those expected to occur in a nuclear waste repository are thought to have taken place over time periods of decades to millennia and on spatial scales as much as tens of kilometers. Analogues provide an important temporal and spatial dimension that cannot be tested by laboratory or field-scale experiments. Analogues provide one of the multiple lines of evidence intended to increase confidence in the safe geologic disposal of high-level radioactive waste. Although the work in this report was completed specifically for Yucca Mountain, Nevada, as the proposed geologic repository for high-level radioactive waste under the U.S. Nuclear Waste Policy Act, the applicability of the science, analyses, and interpretations is not limited to a specific site. Natural and anthropogenic analogues have provided and can continue to provide value in understanding features and processes of importance across a wide variety of topics in addressing the challenges of geologic isolation of radioactive waste and also as a contribution to scientific investigations unrelated to waste disposal. Isolation of radioactive waste at a mined geologic repository would be through a combination of natural features and engineered barriers. In this report we examine analogues to many of the various components of the Yucca Mountain system, including the preservation of materials in unsaturated environments, flow of water through unsaturated volcanic tuff, seepage into repository drifts, repository drift stability, stability and alteration of waste forms and components of the engineered barrier system, and transport of radionuclides through unsaturated and saturated rock zones.

Professional Paper↗
USGS2012

Expansion of urban area and wastewater irrigated rice area in Hyderabad, India

The goal of this study was to investigate land use changes in urban and peri-urban Hyderabad and their influence on wastewater irrigated rice using Landsat ETM + data and spectral matching techniques. The main source of irrigation water is the Musi River, which collects a large volume of wastewater and stormwater while running through the city. From 1989 to 2002, the wastewater irrigated area along the Musi River increased from 5,213 to 8,939 ha with concurrent expansion of the city boundaries from 22,690 to 42,813 ha and also decreased barren lands and range lands from 86,899 to 66,616 ha. Opportunistic shifts in land use, especially related to wastewater irrigated agriculture, were seen as a response to the demand for fresh vegetables and easy access to markets, exploited mainly by migrant populations. While wastewater irrigated agriculture contributes to income security of marginal groups, it also supplements the food basket of many city dwellers. Landsat ETM + data and advanced methods such as spectral matching techniques are ideal for quantifying urban expansion and associated land use changes, and are useful for urban planners and decision makers alike. ?? 2011 Springer Science+Business Media B.V.

Irrigation and Drainage Systems↗
USGS2004

Tracing the history of submarine hydrothermal inputs and the significance of hydrothermal hafnium for the seawater budget - A combined Pb-Hf-Nd isotope approach

Secular variations in the Pb isotopic composition of a mixed hydrogenous-hydrothermal ferromanganese crust from the Bauer Basin in the eastern Equatorial Pacific provide clear evidence for changes in hydrothermal contributions during the past 7 Myr. The nearby Galapagos Rise spreading center provided a strong hydrothermal flux prior to 6.5 Ma. After 6.5 Ma, the Pb became stepwise more radiogenic and more similar to Equatorial Pacific seawater, reflecting the westward shift of spreading to the presently active East Pacific Rise (EPR). A second, previously unrecognized enhanced hydrothermal period occurred between 4.4 and 2.9 Ma, which reflects either off-axis hydrothermal activity in the Bauer Basin or a late-stage pulse of hydrothermal Pb from the then active, but waning Galapagos Rise spreading center. Hafnium isotope time-series of the same mixed hydrogenous-hydrothermal crust show invariant values over the past 7 Myr. Hafnium isotope ratios, as well as Nd isotope ratios obtained for this crust, are identical to that of hydrogenous Equatorial Pacific deep water crusts and clearly indicate that hydrothermal Hf, similar to Nd, does not travel far from submarine vents. Therefore, we suggest that hydrothermal Hf fluxes do not contribute significantly to the global marine Hf budget. ?? 2004 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2016

Final Laurentide ice-sheet deglaciation and Holocene climate-sea level change

Despite elevated summer insolation forcing during the early Holocene, global ice sheets retained nearly half of their volume from the Last Glacial Maximum, as indicated by deglacial records of global mean sea level (GMSL). Partitioning the GMSL rise among potential sources requires accurate dating of ice-sheet extent to estimate ice-sheet volume. Here, we date the final retreat of the Laurentide Ice Sheet with 10 Be surface exposure ages for the Labrador Dome, the largest of the remnant Laurentide ice domes during the Holocene. We show that the Labrador Dome deposited moraines during North Atlantic cold events at ∼10.3 ka, 9.3 ka and 8.2 ka, suggesting that these regional climate events helped stabilize the retreating Labrador Dome in the early Holocene. After Hudson Bay became seasonally ice free at ∼8.2 ka, the majority of Laurentide ice-sheet melted abruptly within a few centuries. We demonstrate through high-resolution regional climate model simulations that the thermal properties of a seasonally ice-free Hudson Bay would have increased Laurentide ice-sheet ablation and thus contributed to the subsequent rapid Labrador Dome retreat. Finally, our new 10 Be chronology indicates full Laurentide ice-sheet had completely deglaciated by 6.7 ± 0.4 ka, which re quires that Antarctic ice sheets contributed 3.6–6.5 m to GMSL rise since 6.3–7.1 ka.

Quaternary Science Reviews↗
USGS2017

Windows of susceptibility and consequences of early life exposures to 17β–estradiol on medaka (Oryzias latipes) reproductive success

Estrogens and estrogen mimics are commonly found in surface waters and are associated with deleterious effects in fish populations. Impaired fertility and fecundity in fish following chronic exposures to estrogens and estrogen mimics during critical windows in development are well documented. However, information regarding differential reproductive effects of exposure within defined developmental stages remains sparse. In this study, reproductive capacity was assessed in Japanese medaka ( Oryzias latipes ) after exposure to two concentrations of 17β–estradiol (E2β; 2 ng/L and 50 ng/L) during four distinct stages of development: gonad development, gonad differentiation, development of secondary sex characteristics (SSC) and gametogenesis. Exposure to E2β did not adversely impact survival, hatch success, growth, or genotypic ratios. In contrast, exposure to 50 ng/L E2β during SSC development altered phenotypic ratios and SSC. Exposure to both E2β treatments reduced reproductive capacity (fertility, fecundity) by 7.3–57.4% in adult medaka breeding pairs, with hindrance of SSC development resulting in the largest disruption in breeding capacity (51.6–57.4% decrease) in the high concentration. This study documents differential effects among four critical stages of development and provides insight into factors (window of exposure, exposure concentration and duration of exposure period) contributing to reproductive disruption in fish.

Environmental Science & Technology↗
USGS1995

Brown trout avoidance of metals in water characteristic of the Clark Fork River, Montana

The avoidance response of brown trout ( Salmo trutta ) to mixtures of cadmium, copper, lead, and zinc was determined in water simulating the Clark Fork River, Montana. Effects of acidification on the avoidance response were also evaluated. Tests were conducted in a cylindrical chamber that received reference water at one end and metal-contaminated water at the other; a distinct boundary formed at the center where the chamber drained. A 1 × mixture of the four metals (Cd, 1.1 μg/L; Cu, 12 μg/L; Pb, 3.2 μg/L; and Zn, 55 μg/L) that was representative of the ambient metals concentrations of the Clark Fork River resulted in avoidance by brown trout. Brown trout also avoided 0.5×, 2×, 4×, and 10× mixtures but not a 0.1 × mixture. A reduction in pH from 8.0 to either 7.0, 6.0, or 5.0 resulted in significant avoidance. Avoidance reactions to metals, similar to those observed in our laboratory experiments, may contribute to the depression of brown trout populations in the Clark Fork River.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2019

Spatial distribution of water level impact to back-barrier bays

Water level in semi-enclosed bays, landward of barrier islands, is mainly driven by offshore sea level fluctuations that are modulated by bay geometry and bathymetry, causing spatial variability in the ensuing response (transfer). Local wind setup can have a secondary role that depends on wind speed, fetch, and relative orientation of the wind direction and the bay. Inlet geometry and bathymetry primarily regulate the magnitude of the transfer between open ocean and bay. Tides and short-period offshore oscillations are more damped in the bays than longer-lasting offshore fluctuations, such as storm surge and sea level rise. We compare observed and modeled water levels at stations in a mid-Atlantic bay (Barnegat Bay) with offshore water level proxies. Observed water levels in Barnegat Bay are compared and combined with model results from the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) modeling system to evaluate the spatial structure of the water level transfer. Analytical models based on the dimensional characteristics of the bay are used to combine the observed data and the numerical model results in a physically consistent approach. Model water level transfers match observed values at locations inside the Bay in the storm frequency band (transfers ranging from 70-100%) and tidal frequencies (10-55%). The contribution of frequency-dependent local setup caused by wind acting along the bay is also considered. The approach provides transfer estimates for locations inside the Bay where observations were not available resulting in a complete spatial characterization. The approach allows for the study of the Bay response to alternative forcing scenarios (landscape changes, future storms, and rising sea level). Detailed spatial estimates of water level transfer can inform decisions on inlet management and contribute to the assessment of current and future flooding hazard in back-barrier bays and along mainland shorelines.

Natural Hazards and Earth System Sciences↗
USGS2006

Progress made in groundwater flow and transport modeling

A special session, “Automated Parameter Identification and Sensitivity Analysis in Groundwater Flow and Transport,” was held at the Spring AGU meeting last May to explore recent scientific and technological developments in this expanding research area. The problems and approaches discussed are crucial to any field of Earth science in which models are used to represent physical processes and simulated values are compared with measured quantities. Although methods for automated parameter identification and sensitivity analysis were first developed at about the same time as numerical groundwater models, they are rarely used. Presentations at this special session clearly demonstrated the potential contributions of these methods for more insightful groundwater model development and calibration.

Eos, Transactions, American Geophysical Union↗
USGS2006

Sedimentary deposits of the 26 December 2004 tsunami on the northwest coast of Aceh, Indonesia

The 2004 Sumatra-Andaman tsunami flooded coastal northern Sumatra to a depth of over 20 m, deposited a discontinuous sheet of sand up to 80 cm thick, and left mud up to 5 km inland. In most places the sand sheet is normally graded, and in some it contains complex internal stratigraphy. Structures within the sand sheet may record the passage of up to 3 individual waves. We studied the 2004 tsunami deposits in detail along a flow-parallel transect about 400 m long, 16 km southwest of Banda Aceh. Near the shore along this transect, the deposit is thin or absent. Between 50 and 400 m inland it ranges in thickness from 5 to 20 cm. The main trend in thickness is a tendency to thicken by filling low spots, most dramatically at pre-existing stream channels. Deposition generally attended inundation - along the transect, the tsunami deposited sand to within about 40 m of the inundation limit. Although the tsunami deposit contains primarily material indistinguishable from material found on the beach one month after the event, it also contains grain sizes and compositions unavailable on the current beach. Along the transect we studied, these grains become increasingly dominant both landward and upward in the deposit; possibly some landward source of sediment was exposed and exploited by the passage of the waves. The deposit also contains the unabraded shells of subtidal marine organisms, suggesting that at least part of the deposit came from offshore. Grain sizes within the deposit tend to fine upward and landward, although individual units within the deposit appear massive, or show reverse grading. Sorting becomes better landward, although the most landward sites generally become poorly sorted from the inclusion of soil clasts. These sites commonly show interlayering of sandy units and soil clast units. Deposits from the 2004 tsunami in Sumatra demonstrate the complex nature of the deposits of large tsunamis. Unlike the deposits of smaller tsunamis, internal stratigraphy is complex, and will require some effort to understand. The Sumatra deposits also show the contribution of multiple sediment sources, each of which has its own composition and grain size. Such complexity may allow more accurate modeling of flow depth and flow velocity for paleotsunamis, if an understanding of how tsunami hydraulics affect sedimentation can be established. Copyright ?? The Society of Geomagnetism and Earth, Planetary and Space Sciences (SGEPSS); The Seismological Society of Japan; The Volcanological Society of Japan; The Geodetic Society of Japan; The Japanese Society for Planetary Sciences; TERRAPUB.

Earth, Planets and Space↗
USGS2023

Integrated rangeland fire management strategy actionable science plan completion assessment: Restoration topic, 2015–20

Loss and degradation of sagebrush rangelands due to an accelerated invasive annual grass-wildfire cycle and other stressors are substantial management, conservation, and economic issues in the western United States. These sagebrush rangelands comprise a unique biome spanning 11 states, support over 350 wildlife species, and provide important ecosystem services that include stabilizing the economies of western communities. Impacts to sagebrush ecosystem processes over large areas due to the annual grass-wildfire cycle necessitated the development of a coordinated, science-based strategy for improving efforts to achieve long-term protection, conservation, and restoration of sagebrush rangelands, which was framed in 2015 under the Integrated Rangeland Fire Management Strategy (IRFMS). Central to this effort was the development of an Actionable Science Plan (Plan) that identified 37 priority science needs (Needs) for informing the actions proposed under the 5 topics (Fire, Invasives, Restoration, Sagebrush and Sage-Grouse, Climate and Weather) that were part of the collective focus of the IRFMS. Notable keys to this effort were identification of the Needs co-produced by managers and researchers, and a focus on resulting science being “actionable.” Substantial investments aimed at fulfilling the Needs identified in the Plan have been made since its release in 2016. While the state of the science has advanced considerably, the extent to which knowledge gaps remain relative to identified Needs is relatively unknown. Moreover, new Needs have likely emerged since the original strategy as results from actionable science reveal new questions, and possible (yet untested) solutions. A quantifiable assessment of the progress made on the original science Needs can identify unresolved gaps and new information that can help inform prioritization of future research efforts. This report details a systematic literature review that evaluated how well peer-reviewed journal articles and formal technical reports published between January 1, 2015, and December 31, 2020, addressed 10 needs (hereinafter “Needs”) identified under the Restoration topic in the Plan. The topic outlined research Needs for improving restoration success in degraded sagebrush rangelands. We established the level of progress towards addressing each Need following a standardized set of criteria, and developed summaries detailing how research objectives nested within Needs identified in the Plan (“Next Steps”) were either addressed well, partially addressed or remain outstanding (that is, addressed poorly) in the literature through 2020. Our searches resulted in the inclusion of 371 science products that at least partially addressed a Need identified in the Restoration topic. The Needs that were well and partially addressed included: the development of methods to improve seeding success of native plants after fire; evaluation of short- and long-term plant responses relative to biotic and abiotic factors following restoration treatments; assessments of long-term effects on ecosystem processes following conifer removal treatments and development of decision support tools to aid in conifer management; determination of the costs of restoration treatments relative to the benefits to sage-grouse occupancy, survival, and populations; and assessments of the factors which contribute to soil degradation and development of soil enhancement methods that enhance seed germination and seedling survival while resisting nonnative plants. Needs that were not addressed well included: the development of methods for the rapid recovery of sagebrush and native herbaceous plants following wildfire and determination of whether treatments benefit sage-grouse and mitigate impacts from fires; determination of thresholds for successful restoration across a range of environmental conditions and development of decision support tools to assist with restoration effectiveness monitoring; and development and evaluation of the utility of seed transfer zones. The information provided in this assessment will assist updating the Plan along with other science strategies.

western United States↗
USGS1996

Chemical and isotopic characteristics of fluids along the cameroon volcanic line, cameroon

Results of the chemical and isotopic analysis of the water and gases discharged from volcanic crater lakes and soda springs located along the Cameroon Volcanic Line were used to characterize and infer their genetic relationships. Variations in the solute compositions of the waters indicate the dominant influence of silicate hydrolysis. Na+ (40-95%) constitutes the major cation in the springs while Fe2+ + Mg2+ (70%) dominate in the CO2-rich lakes. The principal anion is HCO3 (>90%), except in the coastal springs where Cl predominates. Lakes Nyos and Monoun have Fe-Mg-Ca-HCO3 type signatures; the soda springs are essentially Na-HCO3 type, while all other lakes show similar ionic compositions to dilute surface waters. Dissolved gases show essentially CO2 (>90%), with small amounts of Ar and N2, while CH4 constitutes the principal component in the non-gassy lakes. Active volcanic gases are generally absent, except in the Lobe spring with detectable H2S. Stable isotope ratio evidence indicates that the bicarbonate waters are essentially of meteoric origin. CO2 (??13C = -2 to -8???) and He (3He/4He = 1 to 5.6Ra) infer a mantle contribution to the total CO2. CH4 has a biogenic source, while Ar and N2 are essentially atmospheric in origin, but mixing is quite common.

Journal of African Earth Sciences↗
USGS2020

Oil-source rock correlation studies in the unconventional Upper Cretaceous Tuscaloosa marine shale (TMS) petroleum system, Mississippi and Louisiana, USA

The U.S. Geological Survey assessed undiscovered unconventional hydrocarbon resources reservoired in the Upper Cretaceous Tuscaloosa marine shale (TMS) of southern Mississippi and adjacent Louisiana in 2018. As part of the assessment, oil-source rock correlations were examined in the TMS play area where operators produce light (38–45° API), sweet oil from horizontal, hydraulically-fractured wells in an overpressured ‘high-resistivity’ (>5 Ω-m) zone at the base of the TMS. Geochemical data from 39 oil samples and 17 source rock solvent extracts collected from the TMS play area indicate close correspondence for Tuscaloosa Group oils [from lower Tuscaloosa, middle Tuscaloosa (the TMS) and upper Tuscaloosa reservoirs] in thermal maturity (computed from MPI), SARA proportions, n- alkane distributions, isoprenoid and DBT/P ratios, monoaromatic steroids, and δ 13 C isotopic compositions (from whole oils, saturate and aromatic fractions). Other parameters (normal steranes, extended homohopanes, C 31 R/C 30 hopane, norhopane/hopane and tricyclic terpane ratios, gammacerane/hopane) show most oil samples have similar values, suggesting all Tuscaloosa Group oils are from a common mixed marine-terrigenous source rock. Tighter distributions for triaromatic steroid (TAS) and δ 13 C isotopic composition for conventional oils in lower and upper Tuscaloosa reservoirs may indicate charge occurred in a single or shorter pulse relative to TMS oils which show broader TAS and δ 13 C properties, possibly from their generation over an extended period of burial maturation. Dissimilarity in geochemical properties between lower Tuscaloosa source rock solvent extracts and Tuscaloosa Group oils indicates lower Tuscaloosa source rocks did not contribute significantly to conventional and unconventional Tuscaloosa Group hydrocarbon accumulations. Whereas, TMS solvent extracts are similar to Tuscaloosa Group oils, suggesting an oil-source rock correlation. Excluding the possibility for long-distance lateral migration from a similar source downdip (which is unnecessary given thermal maturity considerations), the observations indicate 1. the TMS is a self-sourced reservoir, 2. the TMS is the source of oils accumulated in nearby conventional Tuscaloosa Group reservoirs, and 3. thin organic-rich shales in the lower Tuscaloosa did not contribute substantially to any oil accumulations in the Tuscaloosa Group.

Louisiana, Mississippi↗
USGS2014

Toxicity and accumulation of silver nanoparticles during development of the marine polychaete Platynereis dumerilii

Pollutants affecting species at the population level generate ecological instability in natural systems. The success of early life stages, such as those of aquatic invertebrates, is highly affected by adverse environmental conditions. Silver released into the environment from emerging nanotechnology represents such a threat. Sediments are sinks for numerous pollutants, which aggregate and/or associate with depositing suspended particles. Deposit feeder such as the annelid Platynereis dumerilii, which has a large associated literature on its development, is an excellent model organism for exposure studies in coastal environments. We exposed eggs, larvae, juveniles and adults of P. dumerilii to various concentrations of citrate (cit-Ag NPs) or humic acid (HA-Ag NPs) capped silver nanoparticles (Ag NPs) as well to dissolved Ag (added as AgNO3). We showed that mortality and abnormal development rate increased with younger life stages. While adults and juvenile were the most tolerant life stages, fertilized eggs were highly sensitive to AgNO3, cit-Ag NPs and HA-Ag NPs. Exposures to HA-Ag NPs triggered the highest cute toxicity responses in P. dumerilii and in most cases both Ag NPs were more toxic than AgNO3. Uptake rate of HA-Ag NPs in adult worms was also higher than from other Ag forms, consistent with toxicity to other life stages. The early stages of the life cycle of marine coastal organisms are more affected by Ag NPs than the juvenile or adult life stages, indicating that exposure experiments at the larval level contribute to realistic eco-toxicological studies in aquatic environments.

Science of the Total Environment↗
USGS2000

16-year trends in elements of lichens at Theodore Roosevelt National Park, ND

An epiphytic lichen and a soil lichen in two very closely related genera (Parmelia sulcata and Xanthoparmelia chlorochroa, respectively) were sampled 16 years apart at Theodore Roosevelt National Park in North Dakota and measured for their elemental content. Mercury and cadmium decreased approximately 30% over the time period in both species. Sulfur decreased 8% in the epiphytic species, but increased 20% in the soil lichen. Factor analysis revealed that soil elements were higher in the soil lichen, indicating there was some soil contamination in that species. A relationship between iron and titanium was found only in the soil lichen. Sulfur and mercury were highly enriched in both species relative to the soil, which suggests that the atmosphere is a contributing source of these elements. New baseline values were calculated, 22 elements for both species, although it is not recommended that the soil lichen be sampled in the future.

North Dakota↗
USGS2002

Spatial and temporal variability of trace element concentrations in an urban subtropical watershed, Honolulu, Hawaii

Trace metal concentrations in soils and in stream and estuarine sediments from a subtropical urban watershed in Hawaii are presented. The results are placed in the context of historical studies of environmental quality (water, soils, and sediment) in Hawaii to elucidate sources of trace elements and the processes responsible for their distribution. This work builds on earlier studies on sediments of Ala Wai Canal of urban Honolulu by examining spatial and temporal variations in the trace elements throughout the watershed. Natural processes and anthropogenic activity in urban Honolulu contribute to spatial and temporal variations of trace element concentrations throughout the watershed. Enrichment of trace elements in watershed soils result, in some cases, from contributions attributed to the weathering of volcanic rocks, as well as to a more variable anthropogenic input that reflects changes in land use in Honolulu. Varying concentrations of As, Cd, Cu, Pb and Zn in sediments reflect about 60 a of anthropogenic activity in Honolulu. Land use has a strong impact on the spatial distribution and abundance of selected trace elements in soils and stream sediments. As noted in continental US settings, the phasing out of Pb-alkyl fuel additives has decreased Pb inputs to recently deposited estuarine sediments. Yet, a substantial historical anthropogenic Pb inventory remains in soils of the watershed and erosion of surface soils continues to contribute to its enrichment in estuarine sediments. Concentrations of other elements (e.g., Cu, Zn, Cd), however, have not decreased with time, suggesting continued active inputs. Concentrations of Ba, Co, Cr, Ni, V and U, although elevated in some cases, typically reflect greater proportions attributed to natural sources rather than anthropogenic input. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗
USGS2017

Salish Kootenai College and U.S. Geological Survey partnership—Enhancing student opportunities and professional development

Salish Kootenai College (SKC), in the Flathead Reservation in the northwestern corner of Montana, is the largest of the seven Tribal colleges in the State. In 2011, U.S. Geological Survey (USGS) National Tribal Liaison Monique Fordham from the Office of Tribal Relations/Office of Science Quality and Integrity began discussions with SKC faculty to examine ways the USGS could assist with classes taught as part of the new hydrology program at the college. With funding provided by the USGS Office of Tribal Relations, Roy Sando from the Wyoming-Montana Water Science Center began collaborating with SKC. From 2012 to 2017, Sando and others have developed and taught eight educational workshops at SKC. Topics of the workshops have included classifying land cover using remote sensing, characterizing stream channel migration, estimating actual evapotranspiration, modeling groundwater contamination plumes, and building custom geographic information system tools. By contributing to the educational training of SKC students and establishing this high level of collaboration with a Tribal college, the USGS is demonstrating its commitment to helping build the next generation of Tribal scientists.

Fact Sheet↗
USGS2013

Sources and characteristics of organic matter in the Clackamas River, Oregon, related to the formation of disinfection by-products in treated drinking water

This study characterized the amount and quality of organic matter in the Clackamas River, Oregon, to gain an understanding of sources that contribute to the formation of chlorinated and brominated disinfection by-products (DBPs), focusing on regulated DBPs in treated drinking water from two direct-filtration treatment plants that together serve approximately 100,000 customers. The central hypothesis guiding this study was that natural organic matter leaching out of the forested watershed, in-stream growth of benthic algae, and phytoplankton blooms in the reservoirs contribute different and varying proportions of organic carbon to the river. Differences in the amount and composition of carbon derived from each source affects the types and concentrations of DBP precursors entering the treatment plants and, as a result, yield varying DBP concentrations and species in finished water. The two classes of DBPs analyzed in this study-trihalomethanes (THMs) and haloacetic acids (HAAs)-form from precursors within the dissolved and particulate pools of organic matter present in source water. The five principal objectives of the study were to (1) describe the seasonal quantity and character of organic matter in the Clackamas River; (2) relate the amount and composition of organic matter to the formation of DBPs; (3) evaluate sources of DBP precursors in the watershed; (4) assess the use of optical measurements, including in-situ fluorescence, for estimating dissolved organic carbon (DOC) concentrations and DBP formation; and (5) assess the removal of DBP precursors during treatment by conducting treatability "jar-test" experiments at one of the treatment plants. Data collection consisted of (1) monthly sampling of source and finished water at two drinking-water treatment plants; (2) event-based sampling in the mainstem, tributaries, and North Fork Reservoir; and (3) in-situ continuous monitoring of fluorescent dissolved organic matter (FDOM), turbidity, chlorophyll- a , and other constituents to continuously track source-water conditions in near real-time. Treatability tests were conducted during the four event-based surveys to determine the effectiveness of coagulant and powdered activated carbon (PAC) on the removal of DBP precursors. Sample analyses included DOC, total particulate carbon (TPC), total and dissolved nutrients, absorbance and fluorescence spectroscopy, and, for regulated DBPs, concentrations of THMs and HAAs in finished water and laboratory-based THM and HAA formation potentials (THMFP and HAAFP, respectively) for source water and selected locations throughout the watershed. The results of this study may not be typical given the record and near record amounts of precipitation that occurred during spring that produced streamflow much higher than average in 2010-11. Although there were algal blooms, lower concentrations of chlorophyll- a were observed in the water column during the study period compared to historical data. Concentrations of DBPs in finished (treated) water averaged 0.024 milligrams per liter (mg/L) for THMs and 0.022 mg/L for HAAs; maximum values were about 0.040 mg/L for both classes of DBPs. Although DBP concentrations were somewhat higher within the distribution system, none of the samples collected for this study or for the quarterly compliance monitoring by the water utilities exceeded levels permissible under existing U.S. Environmental Protection Agency (USEPA) regulations: 0.080 mg/L for THMs and 0.060 mg/L for HAAs. DOC concentrations were generally low in the Clackamas River, typically about 1.0-1.5 mg/L. Concentrations in the mainstem occasionally increased to nearly 2.5 mg/L during storms; DOC concentrations in tributaries were sometimes much higher (up to 7.8 mg/L). The continuous in-situ FDOM measurements indicated sharp rises in DOC concentrations in the mainstem following rainfall events; concentrations were relatively stable during summer base flow. Even though the first autumn storm mobilized appreciable quantities of carbon, higher concentrations of DBPs in finished water were observed 3-weeks later, after the ground was saturated from additional rainfall. The majority of the DOC in the lower Clackamas River appears to originate from the upper basin, suggesting terrestrial carbon was commonly the dominant source. Lower-basin tributaries typically contained the highest concentrations of DOC and DBP precursors and contributed substantially to the overall loads in the mainstem during storms. During low-flow periods, tributaries were not major sources of DOC or DBP precursors to the Clackamas River. Although the dissolved fraction of organic carbon contributed the majority of DBP precursors, at times the particulate fraction (inorganic sediment and organic particles including detritus and algal material) contributed a substantial fraction of DBP precursors. Considering just the main-stem sites, on average, 10 percent of THMFP and 32 percent of HAAFP were attributed to particulate carbon. This finding suggests water-treatment methods that remove particles prior to chlorination would reduce finished-water DBP concentrations to some degree. Overall, concentrations of THM and HAA precursors were closely linked to DOC concentrations; laboratory DBP formation potentials (DBPFPs) clearly showed that THMFP and HAAFP were greatest in the downstream tributaries that contained elevated carbon concentrations. However, carbon-normalized "specific" formation potentials for THMs and HAAs (STHMFP and SHAAFP, respectively) revealed changes in carbon character over time that affected the two types of DBP classes differently. HAA precursors were elevated in waters containing aromatic-rich soil-derived material arising from forested areas. In contrast, THM precursors were associated with carbon having a lower aromatic content; highest STHMFP occurred in autumn 2011 in the mainstem from North Fork Reservoir downstream to LO DWTP. This pattern suggests the potential for a link between THM precursors and algal-derived carbon. The highest STHMFP value was measured within North Fork Reservoir, indicating reservoir derived carbon may be important for this class of DBPs. Weak correlations between STHMFP and SHAAFP emphasize that precursor sources for these types of DBPs may be different. This highlights not only that different locations within the watershed produce carbon with different reactivity (specific DBPFP), but also that different management approaches for each class of DBP precursors could be required for control. Treatability tests conducted on source water during four basin-wide surveys demonstrated that an average of about 40 percent of DOC can be removed by coagulation. While the decrease in THMFP following coagulation was similar to DOC, the decrease in HAAFP was much greater (approximately 70 percent), indicating coagulation is particularly effective at removing HAA precursors'likely because of the aromatic nature of the carbon associated with HAA precursors. Several findings from this study have direct implications for managing drinking-water resources and for providing useful information that may help improve treatment-plant operations. For example, the use of in-situ fluorometers that measure FDOM provided an excellent proxy for DOC concentration in this system and revealed short-term, rapid changes in DOC concentration during storm events. In addition, the strong correlation between FDOM values measured in-situ and HAA5 concentrations in finished water may permit estimation of continuous HAA concentrations, as was done here. As part of this study, multiple in-situ FDOM sensors were deployed continuously and in real-time to characterize the composition of dissolved organic matter. Although the initial results were promising, additional research and engineering developments will be needed to demonstrate the full utility of these sensors for this purpose. In conclusion, although DBPFPs were strongly correlated to DOC concentration, some DBPs formed from particulate carbon, including terrestrial leaf material and algal material such as planktonic species of blue-green algae and sloughed filaments, stalks, and cells of benthic algae. Different precursor sources in the watershed were evident from the data, suggesting specific actions may be available to address some of these sources. In-situ measurements of FDOM proved to be an excellent proxy for DOC concentration as well as HAA formation during treatment, which suggests further development and refinement of these sensors have the potential to provide real-time information about complex watershed processes to operators at the drinking-water treatment plants. Follow-up studies could examine the relative roles that terrestrial and algal sources have on the DBP precursor pool to better understand how watershed-management activities may be affecting the transport of these compounds to Clackamas River drinking-water intakes. Given the low concentrations of algae in the water column during this study, additional surveys during more typical river conditions could provide a more complete understanding of how algae contribute DBP precursors. Further development of FDOM-sensor technology can improve our understanding of carbon dynamics in the river and how concentrations may be trending over time. This study was conducted in collaboration with Clackamas River Water and the City of Lake Oswego water utilities. Other research partners included Oregon Health and Science University in Hillsboro, Oregon, Alexin Laboratory in Tigard, Oregon, U.S. Geological Survey National Research Program Laboratory in Denver, Colorado, and the U.S. Geological Survey Water Science Centers in Portland, Oregon, and Sacramento, California. This project was supported with funding from Clackamas River Water, City of Lake Oswego, the U.S. Geological Survey, and the Water Research Foundation.

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