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At least 415 records · Page 23Linked to original sources

High influx of carbon in walls of agglutinated foraminifers during the Permian-Triassic transition in global oceans

The Permian – Triassic mass extinction is postulated to be related to the rapid volcanism that produced the Siberian flood basalt (Traps). Unrelated volcanic eruptions producing several episodes of ash falls synchronous with the Siberian Traps are found in South China and Australia. Such regional eruptions could have caused wildfires, burning of coal deposits, and the dispersion of coal fly ash. These eruptions introduced a major influx of carbon into the atmosphere and oceans that can be recognized in the wall structure of foraminiferal tests present in survival populations in the boundary interval strata. Analysis of free specimens of foraminifers recovered from residues of conodont samples taken at a Permian – Triassic boundary section at Lung Cam in northern Vietnam has revealed the presence of a significant amount of elemental carbon , along with oxygen and silica, in their test wall structure, but an absence of calcium carbonate . These foraminifers , identified as Rectocornuspira kalhori , Cornuspira mahajeri , and Earlandia spp. and whose tests previously were considered to be calcareous, are confirmed to be agglutinated , and are now referred to as Ammodiscus kalhori and Hyperammina deformis . Measurement of the 207 Pb/ 204 Pb ratios in pyrite clusters attached to the foraminiferal tests confirmed that these tests inherited the Pb in their outer layer from carbon -contaminated seawater. We conclude that the source of the carbon could have been either global coal fly ash or forest fire-dispersed carbon , or a combination of both, that was dispersed into the Palaeo-Tethys Ocean immediately after the end- Permian extinction event.

Ha Giang Province

Estimating carbon and showing impacts of drought using satellite data in regression-tree models

Integrating spatially explicit biogeophysical and remotely sensed data into regression-tree models enables the spatial extrapolation of training data over large geographic spaces, allowing a better understanding of broad-scale ecosystem processes. The current study presents annual gross primary production (GPP) and annual ecosystem respiration (RE) for 2000–2013 in several short-statured vegetation types using carbon flux data from towers that are located strategically across the conterminous United States (CONUS). We calculate carbon fluxes (annual net ecosystem production [NEP]) for each year in our study period, which includes 2012 when drought and higher-than-normal temperatures influence vegetation productivity in large parts of the study area. We present and analyse carbon flux dynamics in the CONUS to better understand how drought affects GPP, RE, and NEP. Model accuracy metrics show strong correlation coefficients ( r ) ( r ≥ 94%) between training and estimated data for both GPP and RE. Overall, average annual GPP, RE, and NEP are relatively constant throughout the study period except during 2012 when almost 60% less carbon is sequestered than normal. These results allow us to conclude that this modelling method effectively estimates carbon dynamics through time and allows the exploration of impacts of meteorological anomalies and vegetation types on carbon dynamics.

International Journal of Remote Sensing

A case study of carbon fluxes from land change in the Southwest Brazilian Amazon

Worldwide, land change is responsible for one-fifth of anthropogenic carbon emissions. In Brazil, three-quarters of carbon emissions originate from land change. This study represents a municipal-scale study of carbon fluxes from vegetation in Rio Branco, Brazil. Land-cover maps of pasture, forest, and secondary growth from 1993, 1996, 1999, and 2003 were produced using an unsupervised classification method (overall accuracy = 89%). Carbon fluxes from land change over the decade of imagery were estimated from transitions between land-cover categories for each time interval. This article presents new methods for estimating emissions reductions from carbon stored in the vegetation that replaces forests (e.g., pasture) and sequestration by new (>10–15 years) forests, which reduced gross emissions by 16, 15, and 22% for the period of 1993–1996, 1996–1999, and 1999–2003, respectively. The methods used in the analysis are broadly applicable and provide a comprehensive characterization of regional-scale carbon fluxes from land change.

Southwest Brazilian Amazon Rainforest

Investigating permafrost carbon dynamics in Alaska with artificial intelligence

Positive feedbacks between permafrost degradation and the release of soil carbon into the atmosphere impact land–atmosphere interactions, disrupt the global carbon cycle, and accelerate climate change. The widespread distribution of thawing permafrost is causing a cascade of geophysical and biochemical disturbances with global impacts. Currently, few earth system models account for permafrost carbon feedback (PCF) mechanisms. This research study integrates artificial intelligence (AI) tools and information derived from field-scale surveys across the tundra and boreal landscapes in Alaska. We identify and interpret the permafrost carbon cycling links and feedback sensitivities with GeoCryoAI, a hybridized multimodal deep learning (DL) architecture of stacked convolutionally layered, memory-encoded recurrent neural networks (NN). This framework integrates in-situ measurements and flux tower observations for teacher forcing and model training. Preliminary experiments to quantify, validate, and forecast permafrost degradation and carbon efflux across Alaska demonstrate the fidelity of this data-driven architecture. More specifically, GeoCryoAI logs the ecological memory and effectively learns covariate dynamics while demonstrating an aptitude to simulate and forecast PCF dynamics—active layer thickness (ALT), carbon dioxide flux (CO 2 ), and methane flux (CH 4 )—with high precision and minimal loss (i.e. ALT RMSE : 1.327 cm [1969–2022]; CO 2 RMSE : 0.697 µ molCO 2 m −2 s −1 [2003–2021]; CH 4 RMSE : 0.715 nmolCH 4 m −2 s −1 [2011–2022]). ALT variability is a sensitive harbinger of change, a unique signal characterizing the PCF, and our model is the first characterization of these dynamics across space and time.

Alaska

The response of soil organic carbon of a rich fen peatland in interior Alaska to projected climate change

It is important to understand the fate of carbon in boreal peatland soils in response to climate change because a substantial change in release of this carbon as CO 2 and CH 4 could influence the climate system. The goal of this research was to synthesize the results of a field water table manipulation experiment conducted in a boreal rich fen into a process-based model to understand how soil organic carbon (SOC) of the rich fen might respond to projected climate change. This model, the peatland version of the dynamic organic soil Terrestrial Ecosystem Model (peatland DOS-TEM), was calibrated with data collected during 2005–2011 from the control treatment of a boreal rich fen in the Alaska Peatland Experiment (APEX). The performance of the model was validated with the experimental data measured from the raised and lowered water-table treatments of APEX during the same period. The model was then applied to simulate future SOC dynamics of the rich fen control site under various CO 2 emission scenarios. The results across these emissions scenarios suggest that the rate of SOC sequestration in the rich fen will increase between year 2012 and 2061 because the effects of warming increase heterotrophic respiration less than they increase carbon inputs via production. However, after 2061, the rate of SOC sequestration will be weakened and, as a result, the rich fen will likely become a carbon source to the atmosphere between 2062 and 2099. During this period, the effects of projected warming increase respiration so that it is greater than carbon inputs via production. Although changes in precipitation alone had relatively little effect on the dynamics of SOC, changes in precipitation did interact with warming to influence SOC dynamics for some climate scenarios.

Alaska

Projected carbon stocks in the conterminous USA with land use and variable fire regimes

The dynamic global vegetation model (DGVM) MC2 was run over the conterminous USA at 30 arc sec (~800 m) to simulate the impacts of nine climate futures generated by 3GCMs (CSIRO, MIROC and CGCM3) using 3 emission scenarios (A2, A1B and B1) in the context of the LandCarbon national carbon sequestration assessment. It first simulated potential vegetation dynamics from coast to coast assuming no human impacts and naturally occurring wildfires. A moderate effect of increased atmospheric CO 2 on water use efficiency and growth enhanced carbon sequestration but did not greatly influence woody encroachment. The wildfires maintained prairie‐forest ecotones in the Great Plains. With simulated fire suppression, the number and impacts of wildfires was reduced as only catastrophic fires were allowed to escape. This greatly increased the expansion of forests and woodlands across the western USA and some of the ecotones disappeared. However, when fires did occur, their impacts (both extent and biomass consumed) were very large. We also evaluated the relative influence of human land use including forest and crop harvest by running the DGVM with land use (and fire suppression) and simple land management rules. From 2041 through 2060, carbon stocks (live biomass, soil and dead biomass) of US terrestrial ecosystems varied between 155 and 162 Pg C across the three emission scenarios when potential natural vegetation was simulated. With land use, periodic harvest of croplands and timberlands as well as the prevention of woody expansion across the West reduced carbon stocks to a range of 122–126 Pg C, while effective fire suppression reduced fire emissions by about 50%. Despite the simplicity of our approach, the differences between the size of the carbon stocks confirm other reports of the importance of land use on the carbon cycle over climate change.

Global Change Biology

The effects of sea level and palaeotopography on lithofacies distribution and geometries in heterozoan carbonates, south-eastern Spain

This study utilized three-dimensional exposures to evaluate how sea-level position and palaeotopography control the facies and geometries of heterozoan carbonates. Heterozoan carbonates were deposited on top of a Neogene volcanic substrate characterized by palaeotopographic highs, palaeovalleys, and straits that were formed by subaerial erosion, possibly original volcanic topography, and faults prior to carbonate deposition. The depositional sequence that is the focus of this study (DS1B) consists of 7-10 fining upward cycles that developed in response to relative sea-level fluctuations. A complete cycle has a basal erosion surface overlain by deposits of debrisflows and high-density turbidity currents, which formed during relative sea-level fall. Overlying tractive deposits most likely formed during the lowest relative position of sea level. Overlying these are debrites grading upward to high-density turbidites and low-density turbidites that formed during relative sea-level rise. The tops of the cycles consist of hemipelagic deposits that formed during the highest relative position of sea level. The cycles fine upward because upslope carbonate production decreased as relative sea level rose due to less surface area available for shallow-water carbonate production and partial drowning of substrates. The cycles are dominated by two end-member types of facies associations and stratal geometries that formed in response to fluctuating sea-level position over variable substrate palaeotopography. One end-member is termed 'flank flow cycle' because this type of cycle indicates dominant sediment transport down the flanks of palaeovalleys. Those cycles drape the substrate, have more debrites, high-density turbidites and erosion on palaeovalley flanks, and in general, the lithofacies fine down the palaeovalley flanks into the palaeovalley axes. The second end-member is termed 'axial flow cycle' because it indicates a dominance of sediment transport down the axes of palaeovalleys. Those cycles are characterized by debrites and high-density turbidites in palaeovalley axes, and lap out of strata against the flanks of palaeovalleys. Where and when an axial flow cycle or flank flow cycle developed appears to be related to the intersection of sea level with areas of gentle or steep substrate slopes, during an overall relative rise in sea level. Results from this study provide a model for similar systems that must combine carbonate principles for sediment production, palaeotopographic controls, and physical principles of sediment remobilization into deep water. ?? 2005 International Association of Sedimentologists.

Sedimentology

Direct and legacy effects of varying cool-season precipitation totals on ecosystem carbon flux in a semi-arid mixed grassland

In the semi-arid grasslands of the southwest United States, annual precipitation is divided between warm-season (July–September) convective precipitation and cool-season (December–March) frontal storms. While evidence suggests shifts in precipitation seasonal distribution, there is a poor understanding of the ecosystem carbon flux responses to cool-season precipitation and the potential legacy effects on subsequent warm-season carbon fluxes. Results from a two-year experiment with three cool-season precipitation treatments (dry, received 5th percentile cool-season total precipitation; normal, 50th; wet, 95th) and constant warm-season precipitation illustrate the direct and legacy effects on carbon fluxes, but in opposing ways. In wet cool-season plots, gross primary productivity (GPP) and ecosystem respiration (ER) were 103% and 127% higher than in normal cool-season plots. In dry cool-season plots, GPP and ER were 47% and 85% lower compared to normal cool-season plots. Unexpectedly, we found a positive legacy effect of the dry cool-season treatment on warm-season carbon flux, resulting in a significant increase in both GPP and ER in the subsequent warm season, compared to normal cool-season plots. Our results reveal positive legacy effects of cool-season drought on warm-season carbon fluxes and highlight the importance of the relatively under-studied cool-growing season and its direct/indirect impact on the ecosystem carbon budget.

Plant, Cell & Environment

Orbital identification of carbonate-bearing rocks on Mars

Geochemical models for Mars predict carbonate formation during aqueous alteration. Carbonate-bearing rocks had not previously been detected on Mars' surface, but Mars Reconnaissance Orbiter mapping reveals a regional rock layer with near-infrared spectral characteristics that are consistent with the presence of magnesium carbonate in the Nili Fossae region. The carbonate is closely associated with both phyllosilicate-bearing and olivine-rich rock units and probably formed during the Noachian or early Hesperian era from the alteration of olivine by either hydrothermal fluids or near-surface water. The presence of carbonate as well as accompanying clays suggests that waters were neutral to alkaline at the time of its formation and that acidic weathering, proposed to be characteristic of Hesperian Mars, did not destroy these carbonates and thus did not dominate all aqueous environments.

Science

Oxygen and carbon isotopic growth record in a reef coral from the Florida Keys and a deep-sea coral from Blake Plateau

Carbon and oxygen isotope analysis through a 30-year (1944 to 1974) growth of Montastrea annularis from Hen and Chickens Reef (Florida Keys) shows a strong yearly variation in the abundances of both carbon-13 and oxygen-18 and a broad inverse relationship between the two isotopes. Normal annual dense bands are formed during the summer and are characterized by heavy carbon and light oxygen. "Stress bands" are formed during particularly severe winters and are characterized by heavy carbon and heavy oxygen. The isotopic effect of Zooxanthellae metabolism dominates the temperature effect on the oxygen-18/oxygen-16 ratio. The isotopic results on the deep-sea solitary coral Bathypsammia tintinnabulum , where Zooxanthellae are nonexistent, indicates that the abundance of the heavy isotopes carbon-13 and oxygen-18 is inversely related to the growth rate, with both carbon and oxygen approaching equilibrium values with increasing skeletal age.

Florida

Carbon isotopes in pelites of the Precambrian Uncompahgre Formation, Needle Mountains, Colorado

Carbon isotopic ratios and weight percentages of carbon were measured in 15 samples of slate, phyllite, and schist of the approximately 1500- to 1600-m.y.-old Uncompahgre Formation of the Needle Mountains, southwestern Colorado. Rocks with less than 1 percent total carbon, all of which is reduced, have δC 13 values of −23 to −28 per mil, whereas those with 1 to 6.4 percent carbon have δC 13 from −29 to −31 per mil. In general, the slates and phyllites contain more carbon and isotopically lighter carbon than do the schists of higher metamorphic rank. Increasing loss of C 12 -enriched methane with increasing intensity of metamorphism is suggested to account for these differences.

Colroado

Lithological and hydrological influences on ground-water composition in a heterogeneous carbonate-clay aquifer system

The influence of clay units on ground-water composition was investigated in a heterogeneous carbonate aquifer system of Miocene age in southwest Florida, known as the Intermediate aquifer system. Regionally, the ground water is recharged inland, flows laterally and to greater depths in the aquifer systems, and is discharged vertically upward at the saltwater interface along the coast. A depth profile of water composition was obtained by sampling ground water from discrete intervals within the permeable carbonate units during coring and by squeezing pore water from a core of the less-permeable clay layers. A normative salt analysis of solute compositions in the water indicated a marine origin for both types of water and an evolutionary pathway for the clay water that involves clay diagenesis. The chemical composition of the ground water in the carbonate bedrock is significantly different from that of the pore water in the clay layers. Dissolution of clays and opaline silica results in high silica concentrations relative to water in other parts of the Intermediate aquifer system. Water enriched in chloride relative to the overlying and underlying ground water recharges the aquifer inland where the confining clay layer is absent, and it dissolves carbonate and silicate minerals and reacts with clays along its flow path, eventually reaching this coastal site and resulting in the high chloride and silica concentrations observed in the middle part of the Intermediate aquifer system. Reaction-path modeling suggests that the recharging surficial water mixes with sulfate-rich water upwelling from the Upper Floridan aquifer, and carbonate mineral dissolution and precipitation, weathering and exchange reactions, clay mineral diagenesis, clay and silica dissolution, organic carbon oxidation, and iron and sulfate reduction result in the observed water compositions.

Geological Society of America Bulletin

The 87Sr/86Sr ratios of lacustrine carbonates and lake-level history of the Bonneville paleolake system

Lakes in the Bonneville basin have fluctuated dramatically in response to changes in rainfall, temperature, and drainage diversion during the Quaternary. We analyzed tufas and shells from shorelines of known ages in order to develop a relation between 87Sr/86Sr ratio of carbonates and lake level, which then can be used as a basis for constraining lake level from similar analyses on carbonates in cores. Carbonates from the late Quaternary shorelines yield the following average 87Sr/86Sr ratios: 0.71173 for the Stansbury shoreline (22-20 14C ka; 1350 m), 0.71153 for the Bonneville shoreline (15.5-14.5 14C ka; 1550 m), 0.71175 for the Provo shoreline (14.4-14.0 14C ka; 1450 m), 0.71244 for the Gilbert shoreline (???10.3-10.9 14C ka; 1300 m), and 0.71469 for the modern Great Salt Lake (1280 m). These analyses show that the 87Sr/86Sr ratio of lacustrine carbonates changes substantially at low- to mid-lake levels but is invariant at mid- to high-lake levels. Sr-isotope mixing models of Great Salt Lake and the Bonneville paleolake system were constructed to explain these variations in 87Sr/86Sr ratios with change in lake level. Our model of the Bonneville system produced a 87Sr/86Sr ratio of 0.71193, very close to the observed ratios from high-shoreline tufa and shell. The model verifies that the integration of the southern Sevier and Beaver rivers with the Bear and others rivers in the north is responsible for the lower 87Sr/86Sr ratios in Lake Bonneville compared to the modern Great Salt Lake. We also modeled the 87Sr/86Sr ratio of Lake Bonneville with the upper Bear River diverted into the Snake River basin and obtained an 87Sr/86Sr ratio of 0.71414. Coincidentally, this ratio is close to the observed ratio for Great Salt Lake of 0.71469. This means that 87Sr/86Sr ratios of >0.714 for carbonate can be produced by climatically induced low-lake conditions or by diversion of the upper Bear River out of the Bonneville basin. This model result also demonstrates that the upper Bear River had to be flowing into the Bonneville basin during highstands of other late Quaternary lake cycles: carbonates from the Little Valley (130-160 ka) and Cutler Dam (59 ?? 5 ka) lake cycles returned 87Sr/86Sr ratios of 0.71166 and 0.71207, respectively, and are too low to be produced by a lake without the upper Bear River input. ?? 2004 Geological Society of America.

Geological Society of America Bulletin

Advances in carbonate exploration and reservoir analysis

Carbonate reservoirs contain an increasingly important percentage of the world’s hydrocarbon reserves. This volume presents key recent advances in carbonate exploration and reservoir analysis. As well as a comprehensive overview of the trends in carbonate over the years, the volume focuses on four key areas: (1) emerging plays and techniques with special reference to lacustrine plays in syn-rift basins and development of super-giant heavy oil plays (2) improved reservoir characterization with examples from the Middle East and Europe and case studies of how outcrop analogues can provide key data for input to geological models (3) impact of fractures and faults in carbonates contributors highlight the need for integrated structural and diagenetic approaches in order to understand how fractures evolve as fluid-flow conduits (4) advances in geomodelling of carbonate reservoirs several papers discuss the application of new and innovative geomodelling and geostatistical techniques to carbonate reservoirs.

Book

Preliminary assessment of carbon and nitrogen sequestration potential of wildfire-derived sediments stored by erosion control structures in forest ecosystems, southwest USA

The role of pyrogenic carbon (PyC) in the global carbon cycle is still incompletely characterized. Much work has been done to characterize PyC on landforms and in soils where it originates or in “terminal” reservoirs such as marine sediments. Less is known about intermediate reservoirs such as streams and rivers, and few studies have characterized hillslope and in-stream erosion control structures (ECS) designed to capture soils and sediments destabilized by wildfire. In this preliminary study, organic carbon (OC), total nitrogen (N), and stable isotope parameters, δ 13 C and δ 15 N, were compared to assess opportunities for carbon and nitrogen sequestration in postwildfire sediments (fluvents) deposited upgradient of ECS in ephemeral- and intermittent-stream channels. The variability of OC, N, δ 13 C, and δ 15 N were analyzed in conjunction with fire history, age of captured sediments, topographic position, and land cover. Comparison of samples in 2 watersheds indicates higher OC and N in ECS with more recently captured sediments located downstream of areas with higher burn severity. This is likely a consequence of (1) higher burn severity causing greater runoff, erosion, and transport of OC (organic matter) to ECS and (2) greater cumulative loss of OC and N in older sediments stored behind older ECS. In addition, C/N, δ 13 C, and δ 15 N results suggest that organic matter in sediments stored at older ECS are enriched in microbially processed biomass relative to those at newer ECS. We conservatively estimated the potential mean annual capture of OC by ECS, using values from the watershed with lower levels of OC, to be 3 to 4 metric tons, with a total potential storage of 293 to 368 metric tons in a watershed of 7.7 km 2 and total area of 2000 ECS estimated at 2.6 ha (203-255 metric tons/ha). We extrapolated the OC results to the regional level (southwest USA) to estimate the potential for carbon sequestration using these practices. We estimated a potential of 0.01 Pg, which is significant in terms of ecosystem services and regional efforts to promote carbon storage.

Arizona

Blue carbon as a tool to support coastal management and restoration: Bringing wetlands to market case study

A collaborative research approach involving substantial end user and stakeholder engagement was applied to great effect to guide broad, integrated investigation of the science, policy, and management of blue carbon and carbon markets as drivers for coastal wetland management and restoration. Expanding awareness about blue carbon concepts among local, state, and federal agencies and the public was found to be effective at stimulating interest in taking climate-change mitigation action through wetland protection and restoration, as well as increasing understanding about the overall value of coastal wetlands and the services they provide. Interest in blue carbon is high regardless of the potential for financial benefits through a carbon market. For end users such as the Massachusetts Division of Ecological Restoration and National Park Service Cape Cod National Seashore and many others, the ability to highlight the climate benefits of ecological restoration to stakeholders may have greater value than financial benefits from sale of carbon market credits.

Book chapter

Carbon sequestration and subsidence reversal in the Sacramento-San Joaquin Delta and Suisun Bay: Management opportunities for climate mitigation and adaptation

The aquatic landscapes of the Sacramento–San Joaquin Delta (hereafter, the Delta) and Suisun Bay represent both a significant past and future soil carbon stock. Historical alterations of hydrologic flows have led to depletion of soil carbon stocks via emissions of carbon dioxide (CO2), and loss of elevation as a result of subsidence. Optimizing ecosystem hydrology in the Delta and Suisun Bay could both reduce and reverse subsidence while also providing significant opportunities for climate mitigation and adaptation. Emissions of greenhouse gases (GHGs)—notably CO2, methane (CH4 ), and nitrous oxide (N2O)—contribute to global warming at different rates and intensities, requiring GHG accounting and modeling to assess the relative benefits of management options. Decades of data collection, model building, and map development suggest that past and current management actions have both caused—and can mitigate—losses of soil carbon. We review here the magnitude of potential GHG offsets, management options that may be achievable, and trade-offs of carbon storage under different land management. Using a land-use/land-cover framework to assess these management options, we describe the potential of three interventions (impoundment to reverse subsidence, agricultural management, and tidal reintroduction and/or maintained connectivity), both in acreage and radiative balance to clarify their relative influence on the region’s GHG balance today and in relation to its millennial history. From floodplains to farming to floating aquatic vegetation, we find specific scalable strategies to manage hydrology that can alter regional GHG balance. Preservation of soil carbon stocks and restoration of net atmospheric CO2 fluxes into soils are the primary route to net negative emissions in the Delta and Suisun Bay, with CH4 emission management occurring in a supporting role. Over a 40-year horizon of climate-mitigation markets, the resilience of different aquatic habitats introduces the most uncertainty, from expected and unexpected hydrologic changes associated with land, ocean, and operational water flows.

California

Removal of benzocaine from water by filtration with activated carbon

Benzocaine is a promising candidate for registration with the U.S. Food and Drug Administration for use as an anesthetic in fish culture, management, and research. A method for the removal of benzocaine from hatchery effluents could speed registration of this drug by eliminating requirements for data on its residues, tolerances, detoxification, and environmental hazards. Carbon filtration effectively removes many organic compounds from water. This study tested the effectiveness of three types of activated carbon for removing benzocaine from water by column filtration under controlled laboratory conditions. An adsorptive capacity was calculated for each type of activated carbon. Filtrasorb 400 (12 × 40 mesh; U.S. standard sieve series) showed the greatest capacity for benzocaine adsorption (76.12 mg benzocaine/g carbon); Filtrasorb 300 (8 × 30 mesh) ranked next (31.93 mg/g); and Filtrasorb 816 (8 × 16 mesh) adsorbed the least (1.0 mg/g). Increased adsorptive capacity was associated with smaller carbon particle size; however, smaller particle size also impeded column flow. Carbon filtration is a practical means for removing benzocaine from treated water.

Progressive Fish-Culturist