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USGS2012

Magmatic ore deposits in layered intrusions - Descriptive model for reef-type PGE and contact-type Cu-Ni-PGE deposits

Layered, ultramafic to mafic intrusions are uncommon in the geologic record, but host magmatic ore deposits containing most of the world's economic concentrations of platinum-group elements (PGE) (figs. 1 and 2). These deposits are mined primarily for their platinum, palladium, and rhodium contents (table 1). Magmatic ore deposits are derived from accumulations of crystals of metallic oxides, or immiscible sulfide, or oxide liquids that formed during the cooling and crystallization of magma, typically with mafic to ultramafic compositions. "PGE reefs" are stratabound PGE-enriched lode mineralization in mafic to ultramafic layered intrusions. The term "reef" is derived from Australian and South African literature for this style of mineralization and used to refer to (1) the rock layer that is mineralized and has distinctive texture or mineralogy (Naldrett, 2004), or (2) the PGE-enriched sulfide mineralization that occurs within the rock layer. For example, Viljoen (1999) broadly defined the Merensky Reef as "a mineralized zone within or closely associated with an unconformity surface in the ultramafic cumulate at the base of the Merensky Cyclic Unit." In this report, we will use the term PGE reef to refer to the PGE-enriched mineralization, not the host rock layer. Within a layered igneous intrusion, reef-type mineralization is laterally persistent along strike, extending for the length of the intrusion, typically tens to hundreds of kilometers. However, the mineralized interval is thin, generally centimeters to meters thick, relative to the stratigraphic thickness of layers in an intrusion that vary from hundreds to thousands of meters. PGE-enriched sulfide mineralization is also found near the contacts or margins of layered mafic to ultramafic intrusions (Iljina and Lee, 2005). This contact-type mineralization consists of disseminated to massive concentrations of iron-copper-nickel-PGE-enriched sulfide mineral concentrations in zones that can be tens to hundreds of meters thick. The modes and textures of the igneous rocks hosting the mineralization vary irregularly on the scale of centimeters to meters; autoliths and xenoliths are common. Mineralization occurs in the igneous intrusion and in the surrounding country rocks. Mineralization can be preferentially localized along contact with country rocks that are enriched in sulfur-, iron-, or CO2-bearing lithologies. Reef-type and contact-type deposits, in particular those in the Bushveld Complex, South Africa, are the world's primary source of platinum and rhodium (tables 2 and 3; fig. 2). Reef-type PGE deposits are mined only in the Bushveld Complex (Merensky Reef and UG2), the Stillwater Complex (J-M Reef), and the Great Dyke (Main Sulphide Layer). PGE-enriched contact-type deposits are only mined in the Bushveld Complex. The other deposits in tables 2 and 3 are undeveloped; some are still under exploration.

Open-File Report↗

USGS1982

Mineral resource potential map of the Rock Pile Mountain Wilderness Study area, Madison County, Missouri

Although the Rock Pile Mountain Wilderness Study Area is within the general boundary of the Southeast Missouri mining district, it has no record of mineral production and there is no mining or prospecting activity at present. Exploratory drill holes on private land along the west side of the area encountered no economic mineralization. Neither the Precambrlan volcanic rocks nor the Cambrlan sedimentary rocks contain any detectable evidence of economic mineralization. The area has no potential for coal resources, an unfavorable potential for oil and gas, and no known potential for geothermal energy. The volcanic rocks might be suitable for use as crushed stone, but similar rocks occur abundantly in more favorable locations elsewhere.

Missouri↗

USGS2015

Celestine-bearing geodes from Wayne and Emery counties, southeastern Utah: Genesis and mineralogy

Geodes containing celestine with associated quartz, calcite, chlorite, and other minerals occur in the Jurassic Curtis Formation of Emery and Wayne counties off the east and south flanks of the San Rafael Swell in southeastern Utah. The two areas discussed in this article produce geodes to 25 cm wide containing bladed to tabular celestine crystals that are as much as 4.5 cm in length. An evaporative littoral system resulting in the formation of anhydrite nodules is proposed as the initial environment for this deposit. Subsequent silicification of the nodules and, in some cases, the formation of hollow spaces within the silicified nodules, provided a geode structure for the eventual crystallization of celestine and associated minerals.

Utah↗

USGS2014

Platinum-group elements in southern Africa: mineral inventory and an assessment of undiscovered mineral resources

The platinum-group elements, platinum, palladium, rhodium, ruthenium, iridium, and osmium, possess unique physical and chemical characteristics that make them indispensable to modern technology and industry. However, mineral deposits that are the main sources of these elements occur only in three countries in the world, raising concerns about potential disruption in mineral supply. Using information in the public domain, mineral resource and reserve information has been compiled for mafic and ultramafic rocks in South Africa and Zimbabwe that host most of the world’s platinum-group element resources. As of 2012, exploration and mining companies have delineated more than 20 billion metric tons of mineralized rock containing 42,000 metric tons of platinum, 29,000 metric tons of palladium, and 5,200 metric tons of rhodium, primarily in mafic and ultramafic intrusions of the Bushveld Complex and the Great Dyke, in southern Africa. Additional mineralized rock is likely to occur in extensions to the well-explored and characterized volumes of mineralized rock. Underexplored extensions of stratabound platinum-group element (PGE) deposits in the Bushveld Complex in South Africa may contain 65,000 metric tons of platinum, palladium, and rhodium to a depth of 3 km. Rocks enriched in PGE, which occur near the contact of the Bushveld Complex with older Transvaal Supergroup sedimentary rocks, may contain 1,100 metric tons of platinum and 1,370 metric tons of palladium (mean estimate to a depth of 1 km). A stratabound platinum-group element deposit in the Great Dyke in Zimbabwe may contain 6,900 metric tons of undiscovered platinum, palladium, and rhodium. By comparison, the global net demand for PGE in 2012 was approximately 460 metric tons. Since the 1920s, mining has recovered 7,200 and 107 metric tons of platinum-group elements from the Bushveld Complex and the Great Dyke, respectively. The large layered intrusions in southern Africa—the Bushveld Complex and the Great Dyke—are now and will continue to be a major source of the world’s supply of PGE. Mining will not deplete the identified mineral resources and reserves or potential undiscovered mineral resources for many decades; however, in the near-term, PGE supply could be affected by social, environmental, political, and economic factors.

Southern Africa↗

USGS2002

Determination of the common and rare alkalies in mineral analysis

Methods are described which afford a determination of each member of the alkali group and are successful in dealing with the quantities of the rare alkalies found in rocks and minerals. The procedures are relatively rapid and based chiefly on the use of chloroplatinic acid, absolute alcohol and ether, and ammonium sulfate. The percentages of all the alkalies found in a number of minerals are given.

Industrial And Engineering Chemistry Analytical Ed↗

USGS2013

Accumulation of atmospheric sulfur in some Costa Rican soils

Sulfur is one of the macronutrient elements whose sources to terrestrial ecosystems should shift from dominance by rock-weathering to atmospheric deposition as soils and underlying substrate undergo progressive weathering and leaching. However, the nature and timing of this transition is not well known. We investigated sources of sulfur to tropical rain forests growing on basalt-derived soils in the Osa Peninsula region of Costa Rica. Sulfur sources were examined using stable isotope ratios (δ 34 S) and compared to chemical indices of soil development. The most weathered soils, and the forests they supported, are dominated by atmospheric sulfur, while a less weathered soil type contains both rock-derived and atmospheric sulfur. Patterns of increasing δ 34 S with increasing soil sulfur concentration across the landscape suggest atmospheric sulfur is accumulating, and little rock-derived sulfur has been retained. Soil sulfur, minus adsorbed sulfate, is correlated with carbon and nitrogen, implying that sulfur accumulation occurs as plants and microbes incorporate sulfur into organic matter. Only the lower depth increments of the more weathered soils contained significant adsorbed sulfate. The evidence suggests a pattern of soil development in which sulfur-bearing minerals in rock, such as sulfides, weather early relative to other minerals, and the released sulfate is leached away. Sulfur added via atmospheric deposition is retained as organic matter accumulates in the soil profile. Adsorbed sulfate accumulates later, driven by changes in soil chemistry and mineralogy. These aspects of sulfur behavior during pedogenesis in this environment may hasten the transition to dominance by atmospheric sources.

Journal of Geophysical Research: Biogeosciences↗

USGS1992

Sr, Nd, and Pb isotopes of ultramafic xenoliths in volcanic rocks of Eastern China: Enriched components EMI and EMII in subcontinental lithosphere

The U-Th-Pb, Sm-Nd, and Rb-Sr isotopic systematics of mafic and ultramafic xenolithic rocks and associated megacrystic inclusions of aluminous augite and garnet, that occur in three alkalic volcanic suites: Kuandian in eastern Liaoning Province, Hanluoba in Hebei Province, and Minxi in western Fujian Province, China are described. In various isotopic data plots, the inclusion data invariably fall outside the isotopic ranges displayed by the host volcanic rocks, testifying to the true xenolithic nature of the inclusions. The major element partitioning data on Ca, Mg, Fe, and Al among the coexisting silicate minerals of the xenoliths establish their growth at ambient mantle temperatures of 1000–1100°C and possible depths of 70–80 km in the subcontinental lithosphere. Although the partitioning of these elements reflects equilibrium between coexisting minerals, equilibria of the Pb, Nd, and Sr isotopic systems among the minerals were not preserved. The disequilibria are most notable with respect to the 206 Pb/ 204 Pb ratios of the minerals. On a Nd-Sr isotopic diagram, the inclusion data plot in a wider area than that for oceanic basalts from a distinctly more depleted component than MORB with higher 143 Nd/ 144 Nd and a much broader range of 87 Sr/ 86 Sr values, paralleling the theoretical trajectory of a sea-water altered lithosphere in Nd-Sr space. The garnets consistently show lowerμ andκ values than the pyroxenes and pyroxenites, whereas a phlogopite shows the highestμ andκ values among all the minerals and rocks studied.

Earth and Planetary Science Letters↗

USGS1985

Origin of the Sudbury Complex by meteoritic impact: Neodymium isotopic evidence

Samarium-neodymium isotopic data on whole rocks and minerals of the Sudbury Complex in Canada gave an igneous crystallization age of 1840 ± 21 × 10 6 years. The initial epsilon neodymium values for 15 whole rocks are similar to those for average upper continental crust, falling on the crustal trend of neodymium isotopic evolution as defined by shales. The rare earth element concentration patterns of Sudbury rocks are also similar to upper crustal averages. These data suggest that the Sudbury Complex formed from melts generated in the upper crust and are consistent with a meteoritic impact.

Ontario↗

USGS1989

Airborne imaging spectrometer data of the Ruby Mountains, Montana: Mineral discrimination using relative absorption band-depth images

Airborne imaging spectrometer data collected in the near-infrared (1.2–2.4 μm) wavelength range were used to study the spectral expression of metamorphic minerals and rocks in the Ruby Mountains of southwestern Montana. The data were analyzed by using a new data enhancement procedure—the construction of relative absorption band-depth (RBD) images. RBD images, like bandratio images, are designed to detect diagnostic mineral absorption features, while minimizing reflectance variations related to topographic slope and albedo differences. To produce an RBD image, several data channels near an absorption band shoulder are summed and then divided by the sum of several channels located near the band minimum. RBD images are both highly specific and sensitive to the presence of particular mineral absorption features. Further, the technique does not distort or subdue spectral features as sometimes occurs when using other data normalization methods. By using RBD images, a number of rock and soil units were distinguished in the Ruby Mountains including weathered quartz - feldspar pegmatites, marbles of several compositions, and soils developed over poorly exposed mica schists. The RBD technique is especially well suited for detecting weak near-infrared spectral features produced by soils, which may permit improved mapping of subtle lithologic and structural details in semiarid terrains. The observation of soils rich in talc, an important industrial commodity in the study area, also indicates that RBD images may be useful for mineral exploration.

Montana↗

USGS2000

Generalized surficial geologic map of the Denver 1° x 2° quadrangle, Colorado

Thirty-nine types of surficial geologic deposits and residual materials of Quaternary age are described and mapped in the greater Denver area, in part of the Front Range, and in the piedmont and plains east of Denver, Boulder, and Castle Rock. Descriptions appear in the pamphlet that accompanies the map. Landslide deposits, colluvium, residuum, alluvium, and other deposits or materials are described in terms of predominant grain size, mineral or rock composition (e.g., gypsiferous, calcareous, granitic, andesitic), thickness of deposits, and other physical characteristics. Origins and ages of the deposits and geologic hazards related to them are noted. Many lines between geologic units on our map were placed by generalizing contacts on published maps. However, in 1997-1999 we mapped new boundaries, as well. The map was projected to the UTM projection. This large map area extends from the Continental Divide near Winter Park and Fairplay (on the west edge), eastward about 107 mi (172 km); and extends from Boulder on the north edge to Woodland Park at the south edge (68 mi; 109 km).

Colorado↗

USGS2025

Tracing fluid evolution during batholith and deposit formation: In-situ and bulk rock Mo isotopes from the Questa porphyry Mo deposit, New Mexico, USA

The Oligocene Questa porphyry Mo deposit, located in New Mexico, USA, is a well-characterized system that formed over 400 kyr, punctuating the 8 Myr formation of the Questa-Latir batholith. Detailed sampling of the intrusions and minerals associated with magmatichydrothermal mineralization, as well as bookending barren intrusions, allows for examination of the Mo isotope record of the deposit and its host batholith. Through this established chronologic framework, such data can yield insights into the metallogenesis of deposit formation and long-term magma genesis evolution for upper crustal magmatism. The Mo isotopic compositions of barren intrusions yield a younging trend towards lighter δ 98 Mo. However, intrusions associated with Mo deposit formation yield heavier δ 98 Mo relative to barren magmatism, by up to 2.0‰. This indicates that they were affected by an isotopically heavy and Mo-rich fluid. The in-situ data from molybdenite covers the range observed in mineralized bulk rocks. However, individual samples consistently yield Mo isotopic variations of 0.4‰ to 0.5‰. The consistency of the δ 98 Mo variation in in-situ analyses of molybdenite within hand samples and individual mineral grains is likely the result of MoS 2 crystallization in a closed system and reflects an almost complete precipitation of Mo.

New Mexico↗

USGS1975

Titanium deposits in alkalic igneous rocks

Many types of alkalic rocks are enriched in Ti0 2 relative to the average for the crust. Silicate minerals in these rocks may have high Ti0 2 contents, but the oxides ilmenite, rutile, brookite, and perovskite are also characteristic primary phases. These tend to be higher in niobium than are the same minerals from other rock suites. At Tapira, Brazil, titanium minerals in a carbonatite complex comprise tens of millions of tons contained Ti0 2. Anatase (as "leucoxene") is present in laterite lying over parent rocks containing perovskite, ilmenite, and rutile. In other discovered localities of alkalic rocks, production of titanium minerals is at best economically marginal.

Open-File Report↗

USGS1989

Chloritization and associated alteration at the Jabiluka unconformity-type uranium deposit, Northern Territory, Australia

Jabiluka is the largest of four known uncomformity-type uranium deposits that are hosted by brecciated and altered metasedimentary rocks in the Pine Creek geosyncline, Northern Territory, Australia. The alteration zone at Jabiluka is dominated by chlorite, but also contains white mica, tourmaline and apatite; hematite is present, but only in minor amounts. Added quartz is mainly restricted to fractures and breccias. Chlorite, which formed during episodic fluid movement, partly to totally replaced all pre-existing minerals. Chloritized rocks are enriched in Mg, and depleted in K, Ca, Na and Si. Five types of chlorite are optically and chemically distinguishable in the rocks at Jabiluka. Chloritization is proposed as a mechanism that lowered the pH of the circulating fluid, and also caused significant loss of silica from the altered rocks. The proposed constraints on alteration, and presumably on at least part of the uranium mineralization, neither require nor preclude the existence of the unconformity as necessary for the formation of ore.

Canadian Mineralogist↗

USGS1979

Major and trace element data with partition coefficients for lava flows from the San Francisco volcanic field

Major and trace element data from San Francisco Mountain (a stratovolcano), as well as major element data from representative flows of the surrounding volcanic field (figure 1), are presented in this report. Also included are conventional and normalized partition coefficients for trace elements in each of the coexisting mineral phases and mesostasis from San Francisco Mountain lavas. The San Francisco Mountain lavas are from the upper portion of the southeast slope of Humphreys Peak which is composed of three petrographically distinct types: (1) a lower series of hornblende pyroxene andesites, (2) a middle group of hypersthene dacites, and (3) an upper series of olivine andesites. The sequence of volcanic flows was measured and analyzed for the major elements and fifteen trace elements Sc, V, Cr, Cq Ni, Cu, Zn, Ga, Sr, Y, Zr, Ba, La, Ce, and Yb) in each of the coexisting mineral phases, groundmass and bulk rock. The constituent mineral phases (not all are present in every sample) are plagioclase, hypersthene, augite, hornblende, olivine, magnetite, and ilmenite/hematite.

Arizona↗

USGS2023

Natural and anthropogenic (human-made) hexavalent chromium, Cr(VI), in groundwater near a mapped plume, Hinkley, California

Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert 80 miles (mi) northeast of Los Angeles, California. Remediation began in 1992, and in 2010, site cleanup was projected to require between 10 and 95 years and was expected to cost between $36 and $176 million. A 2007 PG&E study estimated the natural Cr(VI) background in groundwater in Hinkley Valley to be 3.1 micrograms per liter (μg/L). This concentration was used for interim regulatory purposes by the Lahontan Regional Water Quality Control Board (RWQCB). In the fourth quarter (October–December) 2015, the regulatory Cr(VI) plume extended about 3.0 mi downgradient from the release location within the Hinkley compressor station, while groundwater having Cr(VI) concentrations greater than 3.1 μg/L was present more than 8 mi downgradient. Although rocks and minerals in the area are naturally low in chromium, alluvium eroded from the San Gabriel Mountains and transported to Hinkley Valley by the Mojave River, and locally small exposures of mafic rock, including hornblende diorite and basalt, may contribute Cr(VI) to groundwater. In response to limitations of the PG&E 2007 Cr(VI) background study’s methodology, uncertainty in the natural Cr(VI) background concentration, and an increase in the mapped extent of groundwater having Cr(VI) concentrations greater than the interim regulatory background of 3.1 μg/L, the Lahontan RWQCB concluded that the 2007 PG&E background Cr(VI) study should be updated. The purpose of the updated study is to estimate background Cr(VI) concentrations in groundwater within the upper aquifer upgradient, downgradient, near the margins, and within the footprint of the PG&E Cr(VI) plume in Hinkley, California. The scope of the study included eight tasks; results from those tasks are presented in the chapters within this professional paper.

California↗

USGS2023

Introduction to study area hydrogeology, chromium sources, site history, and purpose of study

California↗

USGS2010

Tectonics of the Maryland Piedmont along the Potomac River; insight since 1960 and potential transfer to the Pennsylvania Piedmont

This is a summary of a half century of research in the Mary land Piedmont and how it may or may not have implications for the Piedmont of Pennsylvania. Much of the field mapping and all of the isotopic analyses of rocks and minerals of the Maryland Piedmont have been conducted since the 1960 Field Conference of Pennsylvania Geologists “Some tectonic and structural problems of the Appalachian Piedmont along the Susquehanna River”. The Piedmont rocks of Maryland and Pennsylvania occur in a critical place within the central Appalachian Pennsylvania embayment (Thomas, 1977), which likely contributed to the distribution of lithologies and structures.

Maryl;Pennsylvania↗

USGS1987

Petrogenesis of gabbronorite at Yakobi and northwest Chichagof Islands, Alaska

On Yakobi Island and at Mirror Harbor on the northwest coast of Chichagof Island, gabbronorite occurs as irregular bodies, as much as 5.5 km in maximum dimension, mostly within a 40 to 43 m.y. composite pluton consisting largely of tonalite. The gab-bronorites are the host rocks for a magmatic nickel-copper sulfide deposit consisting predominantly of pyrrhotite, pentlandite, and chalcopyrite. The gabbronorites characteristically have more orthopyroxene than augite and have a significant amount of hornblende. Rock types mapped as gabbronorite range from hornblende pyroxenite to hornblende-pyroxene gabbronorite to quartz-bearing norite and gabbronorite. The tonalite pluton is composed of hornblende diorite, biotite-hornblende diorite, hornblende quartz diorite, biotite-hornblende tonalite, and biotite granodiorite. Contacts between types of gabbronorite are generally gradational on a scale of centimetres to metres; contacts between gabbronorite and the tonalite pluton are gradational on a scale of metres to tens of metres. Rock textures, pyroxene-hornblende relations, and rock and mineral chemistry of the gabbronorites show systematic changes as the gabbronorites grade into the tonalites. The field, petrographic, and chemical data, including trace-element abundances, of the gabbronorites and tonalite pluton rocks can best be explained by either (1) crystallization of gabbronorite from a tholeiitic magma with subsequent assimilation by tonalite that was simultaneously undergoing fractional crystallization or (2) fractional crystallization of a quartz diorite parent magma yielding the range of gabbronorites and tonalite pluton rocks.

Geological Society of America Bulletin↗