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At least 397 records · Page 22Linked to original sources
USGS2005

Evolution of melt-vapor surface tension in silicic volcanic systems: Experiments with hydrous melts

We evaluate the melt‐vapor surface tension (σ) of natural, water‐saturated dacite melt at 200 MPa, 950–1055°C, and 4.8–5.7 wt % H 2 O. We experimentally determine the critical supersaturation pressure for bubble nucleation as a function of dissolved water and then solve for σ at those conditions using classical nucleation theory. The solutions obtained give dacite melt‐vapor surface tensions that vary inversely with dissolved water from 0.042 (±0.003) J m −2 at 5.7 wt % H 2 O to 0.060 (±0.007) J m −2 at 5.2 wt % H 2 O to 0.073 (±0.003) J m −2 at 4.8 wt % H 2 O. Combining our dacite results with data from published hydrous haplogranite and high‐silica rhyolite experiments reveals that melt‐vapor surface tension also varies inversely with the concentration of mafic melt components (e.g., CaO, FeO total , MgO). We develop a thermodynamic context for these observations in which melt‐vapor surface tension is represented by a balance of work terms controlled by melt structure. Overall, our results suggest that cooling, crystallization, and vapor exsolution cause systematic changes in σ that should be considered in dynamic modeling of magmatic processes.

Journal of Geophysical Research B: Solid Earth↗
USGS2012

Relationships between Δ 14 C and the molecular quality of dissolved organic carbon in rivers draining to the coast from the conterminous United States

Dissolved organic carbon (DOC) in natural waters possesses chemical and molecular qualities indicative of its source and age. The apportionment of DOC by age into millennial and decadal pools is necessary to understand the temporal connection between terrestrial and aquatic ecosystems in the global carbon cycle. We measured Δ 14 C-DOC and chemical composition indices (specific ultraviolet absorbance (SUVA 254 ), fluorescence index (FI), hydrophobic organic acid fraction (HPOA) content) for 15 large river basins in the conterminous United States. Across all rivers the average proportion of HPOA in DOC correlated strongly with SUVA 254 (r 2 = 0.93 p < 0.001). Individual Δ 14 C-DOC ranged from a low of −92.9‰ (726 y.b.p.) in the Colorado River to 73.4‰ (>Modern) in the Altamaha River for the year 2009. When adjusted by total discharge, these U.S. Rivers export modern carbon at between 34 and 46‰, a signal dominated by the Mississippi River. The variation in Δ 14 C correlates to indices of the aromaticity of the DOC measured by the SUVA 254 (r 2 = 0.87, p < 0.001), and FI (r 2 = 0.6; p < 0.001) as well as differences in annual river discharge (r 2 = 0.46, p < 0.006). SUVA 254 was further correlated to broad scale vegetation phenology estimated from the Enhanced Vegetation Index derived from the NASA Moderate Resolution Imaging Spectrometer (MODIS). We show that basins with high discharge, high proportions of vegetation cover, and low human population densities export DOC enriched in aromatic material that corresponds to recently fixed atmospheric CO 2 . Conversely old DOC is exported from low discharge watersheds draining arid regions, and watersheds more strongly impacted by humans. The potential influence from fossil carbon from human inputs to aquatic systems may be important and requires more research.

Global Biogeochemical Cycles↗
USGS1999

Molecular aggregation of humic substances

Humic substances (HS) form molecular aggregates in solution and on mineral surfaces. Elucidation of the mechanism of formation of these aggregates is important for an understanding of the interactions of HS in soils arid natural waters. The HS are formed mainly by enzymatic depolymerization and oxidation of plant biopolymers. These reactions transform the aromatic and lipid plant components into amphiphilic molecules, that is, molecules that consist of separate hydrophobic (nonpolar) and hydrophilic (polar) parts. The nonpolar parts of the molecules are composed of relatively unaltered segments of plant polymers and the polar parts of carboxylic acid groups. These amphiphiles form membrane-like aggregates on mineral surfaces and micelle-like aggregates in solution. The exterior surfaces of these aggregates are hydrophilic, and the interiors constitute separate hydrophobic liquid-like phases.

Soil Science↗
USGS2007

Manganese oxidation model for rivers

The presence of manganese in natural waters (>0.05 mg/L) degrades water-supply quality. A model was devised to predict the variation of manganese concentrations in river water released from an impoundment with the distance downstream. The model is one-dimensional and was calibrated using dissolved oxygen, biochemical oxygen demand, pH, manganese, and hydraulic data collected in the Duck River, Tennessee. The results indicated that the model can predict manganese levels under various conditions. The model was then applied to the Chattahoochee River, Georgia. Discrepancies between observed and predicted may be due to inadequate pH data, precipitation of sediment particles, unsteady flow conditions in the Chattahoochee River, inaccurate rate expressions for the low pH conditions, or their combinations.

Water Resources Bulletin↗
USGS2007

The impact of runoff generation mechanisms on the location of critical source areas

Identifying phosphorus (P) source areas and transport pathways is a key step in decreasing P loading to natural water systems. This study compared the effects of two modeled runoff generation processes - saturation excess and infiltration excess - on total phosphorus (TP) and soluble reactive phosphorus (SRP) concentrations in 10 catchment streams of a Catskill mountain watershed in southeastern New York. The spatial distribution of runoff from forested land and agricultural land was generated for both runoff processes; results of both distributions were consistent with Soil Conservation Service-Curve Number (SCS-CN) theory. These spatial runoff distributions were then used to simulate stream concentrations of TP and SRP through a simple equation derived from an observed relation between P concentration and land use; empirical results indicate that TP and SRP concentrations increased with increasing percentage of agricultural land. Simulated TP and SRP stream concentrations predicted for the 10 catchments were strongly affected by the assumed runoff mechanism. The modeled TP and SRP concentrations produced by saturation excess distribution averaged 31 percent higher and 42 percent higher, respectively, than those produced by the infiltration excess distribution. Misrepresenting the primary runoff mechanism could not only produce erroneous concentrations, it could fail to correctly locate critical source areas for implementation of best management practices. Thus, identification of the primary runoff mechanism is critical in selection of appropriate models in the mitigation of nonpoint source pollution. Correct representation of runoff processes is also critical in the future development of biogeochemical transport models, especially those that address nutrient fluxes.

Journal of the American Water Resources Associatio↗
USGS2002

Chromium isotopes and the fate of hexavalent chromium in the environment

Measurements of chromium (Cr) stable-isotope fractionation in laboratory experiments and natural waters show that lighter isotopes reacted preferentially during Cr(VI) reduction by magnetite and sediments. The 53 Cr/ 52 Cr ratio of the product was 3.4 ± 0.1 per mil less than that of the reactant. 53 Cr/ 52 Cr shifts in water samples indicate the extent of reduction, a critical process that renders toxic Cr(VI) in the environment immobile and less toxic.

Science↗
USGS1962

Glass electrodes sensitive to divalent cations

Glass electrodes suitable for measurement of divalent cations have been made and tested. Empirical and theoretical electrode equations have been presented to describe electrode behavior in a variety of aqueous solutions. Most electrodes show response interpretable as showing nearly ideal solid-solution behavior of the cations in the glass surface. The electrodes should be useful in the measurement of divalent-cation activities in natural waters and biological fluids, and useful in general analytical chemistry.

Science↗
USGS2004

Microbial precipitation of dolomite in methanogenic groundwater

We report low-temperature microbial precipitation of dolomite in dilute natural waters from both field and laboratory experiments. In a freshwater aquifer, microorganisms colonize basalt and nucleate nonstoichiometric dolomite on cell walls. In the laboratory, ordered dolomite formed at near-equilibrium conditions from groundwater with molar Mg:Ca ratios of <1; dolomite was absent in sterile experiments. Geochemical and microbiological data suggest that methanogens are the dominant metabolic guild in this system and are integral to dolomite precipitation. We hypothesize that the attached microbial consortium reacts with the basalt surface, releasing Mg and Ca into solution, which drives dolomite precipitation via nucleation on the cell wall. These findings provide insight into the long-standing dolomite problem and suggest a fundamental role for microbial processes in the formation of dolomite across a wide range of environmental conditions.

Geology↗
USGSDate not supplied

Characterizing the interface between wild ducks and poultry to evaluate the potential of transmission of avian pathogens

Background Characterizing the interface between wild and domestic animal populations is increasingly recognized as essential in the context of emerging infectious diseases (EIDs) that are transmitted by wildlife. More specifically, the spatial and temporal distribution of contact rates between wild and domestic hosts is a key parameter for modeling EIDs transmission dynamics. We integrated satellite telemetry, remote sensing and ground-based surveys to evaluate the spatio-temporal dynamics of indirect contacts between wild and domestic birds to estimate the risk that avian pathogens such as avian influenza and Newcastle viruses will be transmitted between wildlife to poultry. We monitored comb ducks ( Sarkidiornis melanotos melanotos ) with satellite transmitters for seven months in an extensive Afro-tropical wetland (the Inner Niger Delta) in Mali and characterise the spatial distribution of backyard poultry in villages. We modelled the spatial distribution of wild ducks using 250-meter spatial resolution and 8-days temporal resolution remotely-sensed environmental indicators based on a Maxent niche modelling method. Results Our results show a strong seasonal variation in potential contact rate between wild ducks and poultry. We found that the exposure of poultry to wild birds was greatest at the end of the dry season and the beginning of the rainy season, when comb ducks disperse from natural water bodies to irrigated areas near villages. Conclusions Our study provides at a local scale a quantitative evidence of the seasonal variability of contact rate between wild and domestic bird populations. It illustrates a GIS-based methodology for estimating epidemiological contact rates at the wildlife and livestock interface integrating high-resolution satellite telemetry and remote sensing data.

Inner Niger Delta↗
USGS2018

Characterizing drought in California: new drought indices and scenario-testing in support of resource management

Introduction California’s recent drought (2012–2016) has implications throughout the state for natural resource management and adaptation planning and has generated many discussions about drought characterization and recovery. This study characterizes drought conditions with two indices describing deficits in natural water supply and increases in landscape stress developed on the basis of water balance modeling, at a fine spatial scale to assess the variation in conditions across the entire state, and provides an in-depth evaluation for the Russian River basin in northern California to address local resource management by developing extreme drought scenarios for consideration in planning and adaptation. Methods We employed the USGS Basin Characterization Model to characterize drought on the basis of water supply (a measure of recharge plus runoff) and landscape stress (climatic water deficit). These were applied to the state and to the Russian River basin where antecedent soil moisture conditions were evaluated and extreme drought scenarios were developed and run through a water management and reservoir operations model to further explore impacts on water management. Results Drought indices indicated that as of the end of water year 2016 when reservoirs were full, additional water supply and landscape replenishment of up to three average years of precipitation in some locations was needed to return to normal conditions. Antecedent soil conditions in the Russian River were determined to contribute to very different water supply results for different years and were necessary to understand to anticipate proper watershed response to climate. Extreme drought scenarios manifested very different kinds of drought and recovery and characterization helps to guide the management response to drought. Conclusions These scenarios and indices illustrate how droughts differ with regard to water supply and landscape stress and how long warm droughts recover much more slowly than short very dry droughts due to the depletion of water in the soil and unsaturated zone that require filling before runoff can occur. Recognition of ongoing conditions and likelihood of recovery provides tools and information for a range of resource managers to cope with drought conditions.

California↗
USGS1989

Enhanced detection of infectious hematopoietic necrosis virus by pretreatment of cell monolayers with polyethylene glycol

To improve quantification of very low levels of infectious hematopoietic necrosis virus (IHNV) in samples of tissue, ovarian fluid, or natural water supplies, we tested the ability of polyethylene glycol (PEG) to enhance the sensitivity and speed of the plaque assay system. We compared 4, 7, and 10% solutions of PEG of molecular weight 6,000, 8,000, or 20,000 applied at selected volumes and for various durations. When cell monolayers of epithelioma papulosum cyprini (EPC), fathead minnow (FHM), chinook salmon embryo (CHSE-214), and bluegill fry (BF2) were pretreated with 7% PEG-20,000, they produced 4-17-fold increases in plaque assay titers of IHNV. The plaque assay titers of viral hemorrhagic septicemia virus, chum salmon reovirus, and chinook salmon paramyxovirus were also enhanced by exposure of CHSE-214 cells to PEG, but the titers of infectious pancreatic necrosis virus and Oncorhynchus masou virus were not substantially changed. Plaques formed by IHNV on PEG-treated EPC cells incubated at 15°C had a larger mean diameter at 6 d than those on control cells at 8 d; this suggests the assay could be shortened by use of PEG. Pretreatment of EPC cell monolayers with PEG enabled detection of IHNV in some samples that appeared negative with untreated cells. For example, when ovarian fluid samples from chinook salmon Oncorhynchus tshawytscha were inoculated onto untreated monolayers of EPC cells, IHNV was detected in only 11 of 51 samples; 17 of the samples were positive when PEG-treated EPC cells were used. PDF

Journal of Aquatic Animal Health↗
USGS1949

Geochemical prospecting for ores; a progress report

Methods of prospecting for mineral deposits by means of chemical studies of residual soil, alluvium, glacial moraine, vegetation, and natural water were first applied on a systematic scale in Scandinavia and Russia about 15 years ago. Since the war, work in this field has been undertaken by several independent groups in the United States and Canada, including the Geochemical Prospecting Unit of the U. S. Geological Survey.Best results have been obtained by systematic analysis of zinc in residuum, ground water, and vegetation; copper and lead in gossan and residuum; tin in residuum and alluvium; molybdenum in residuum; and cobalt, nickel, and gold in vegetation. In addition, studies of plant ecologies and toxicity symptoms in vegetation in relation to metal-rich soil appear to be promising.Rapid colorimetric and spectrographic tests for traces of metals in soil, water, and vegetation have been developed for use under field conditions.

Economic Geology↗
USGS1983

Hydrothermal alteration of graywacke and basalt by 4 m NaCl

Separate experiments at 350 degrees C and 500 bars at a rock/fluid ratio of 1/10. Illite, dolomite, and quartz amounting to 67 percent of the original graywacke, were converted to albite and smectite. The rock gained Na and released Ca, K, heavy metals, and CO 2 to solution. In sharp contrast, the reaction of 4 m NaCl with basalt produced only minor alteration. Albitization of graywacke produces H (super +) whereas albitization of basalt apparently consumes H (super +) . All experiments to date that have reacted basalt with sea water, natural brine, and fully saturated NaCl over a variety of conditions have been unsuccessful in producing a spilite alteration assemblage.

Economic Geology↗
USGS2004

Snakeheads ( Pisces, Channidae ): A biological synopsis and risk assessment

Snakeheads (family Channidae) are airbreathing freshwater fishes containing two genera, Channa with 26 species native to Asia, Malaysia, and Indonesia; and Parachanna with 3 species native to tropical Africa. Some snakeheads are small, reaching about 17 centimeters, but most are much larger, the largest reported to be 1.8 meters in length. All are considered thrust predators with most being piscivorous as adults. A few of the smaller snakeheads and colorful juveniles of some larger ones have been available to hobbyists through the aquarium fish trade. Several species are highly valued as food fishes within parts of their native ranges, especially in Asia where they are an important part of capture fisheries and aquaculture. Because of these uses by humans, introductions far beyond native ranges have occurred. One Asian snakehead has been established in Oahu, Hawaii, since before 1900. Another species was discovered established in southeastern Florida in 2000, and a third in a pond in Maryland in 2002. Others have been captured from natural waters of the United States without evidence of reproduction and likely represent released aquarium fishes. That snakeheads at or near sexual maturity were being sold alive in ethnic food markets raised fears that they could be introduced into novel waters. These concerns led to this study on the biology of snakeheads. A risk assessment is included that examines environmental and related aspects of snakehead introductions.

Circular↗
USGS2016

Urban hydrology—Science capabilities of the U.S. Geological Survey

Urbanization affects streamflow characteristics, coastal flooding, and groundwater recharge. Increasing impervious areas, streamflow diversions, and groundwater pumpage are some of the ways that the natural water cycle is affected by urbanization. Assessment of the relations among these factors and changes in land use helps water-resource managers with issues such as stormwater management and vulnerability to flood and drought. Scientists with the U.S. Geological Survey (USGS) have the expertise to monitor and model urban hydrologic systems. Streamflow and groundwater data are available in national databases, and analyses of these data, including identification of long-term streamflow trends and the efficacy of management practices, are published in USGS reports.

Fact Sheet↗
USGS2020

A review of Cattail ( Typha ) invasion in North American wetlands

Overview Cattail ( Typha ) is an iconic emergent wetland plant found worldwide. By producing an abundance of wind-dispersed seeds, cattail can colonize wetlands across great distances, and its rapid growth rate, large size, and aggressive expansion result in dense stands in a variety of aquatic ecosystems such as marshes, ponds, lakes, and riparian areas. Cattail can also quickly dominate disturbed areas with waterlogged soils such as roadside ditches, retention areas, and fringes of stormwater ponds. These dense stands impact local plant and animal life, biogeochemical cycling, and wetland hydrology, which in turn alter wetland functions. Over recent decades, the distribution and abundance of cattail in North America has increased as a result of human disturbances to natural water cycles and increased nutrient loads. In addition, highly competitive nonnative and hybrid taxa have worsened the rapid spread of cattail. Because cattail invasion and expansion often change wetlands in undesirable ways, wetland managers often respond with widespread management efforts, though these efforts may have short-lived or weak effects. Notwithstanding the negative impacts, cattail provides beneficial ecosystem services including the reduction of pollution through bioremediation and the production of biofuel material. Despite the widespread distribution and invasive characteristics of cattail, a comprehensive review and synthesis of past and current research on cattail was lacking. To address this gap, a diverse team of researchers produced a paper that details the spread and management of cattail throughout North America, summarizing 4 decades of research from more than 650 references (Bansal and others, 2019). This fact sheet highlights the primary topics covered in the paper.

Fact Sheet↗
USGS2012

Stream ecosystems change with urban development

The healthy condition of the physical living space in a natural stream—defined by unaltered hydrology (streamflow), high diversity of habitat features, and natural water chemistry—supports diverse biological communities with aquatic species that are sensitive to disturbances. In a highly degraded urban stream, the poor condition of the physical living space—streambank and tree root damage from altered hydrology, low diversity of habitat, and inputs of chemical contaminants—contributes to biological communities with low diversity and high tolerance to disturbance.

General Information Product↗