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Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 12 million barrels of oil and 184 billion cubic feet of gas in the Buda Limestone of Texas.
A new quantitative mineral resource assessment for tungsten skarn was conducted for the Auminzatau and Kuldjuktau mountain ranges in Central Uzbekistan, along with qualitative assessments of orogenic gold, rare earth elements (REEs), amorphous graphite, and uranium. By integrating a variety of geological, geochemical, geophysical, and remote sensing data sets, estimates of undiscovered tungsten skarn deposits in permissive tracts are combined with grade and tonnage distributions of known deposits to generate probabilistic estimates of undiscovered resources. Undiscovered deposits in Auminzatau are estimated to contain median resources of 98 thousand metric tons (kt) of WO 3 with a 70 percent (%) probability of at least 28 kt and a 10% probability of at least 468 kt, of which 16 kt to 293 kt may be economic to extract. In Kuldjuktau, the undiscovered deposits are estimated to contain median resources of 27 kt of WO 3 with a 60% probability of at least 12 kt and a 10% probability of at least 208 kt, of which 5 kt to 132 kt may be economic to extract. Our results suggest that the Auminzatau–Kuldjuktau Mountains area is highly prospective for additional discovery of significant Au and U resources and has low prospectivity for discovery of significant REE and graphite resources.
Periodic and continual water-level data from 1963 to 1998 were compiled and quality assured for 65 observation wells on Pahute Mesa and vicinity, Nye County, Nevada. As part of the quality assurance of all water levels, ancillary data pertinent to computing hydraulic heads in wells were compiled and analyzed. Quality-assured water levels that were not necessarily in error but which did not represent static heads in the regional aquifer system, or required some other qualification, were flagged. Water levels flagged include those recovering from recent pumping or well construction, water levels affected by nuclear tests, and measurements affected by borehole deviations. A cursory examination of about 30 wells with available water-level and down-hole temperature data indicate that water levels in most wells on Pahute Mesa would not be significantly affected by temperature if corrected to 95 degrees Fahrenheit. Wells with large corrections (greater than 10 feet) are those with long water columns (greater than 1,500 feet of water above the assumed point of inflow) in combination with mean water-column temperatures exceeding 105 degrees Fahrenheit. Water-level fluctuations in wells on Pahute Mesa are caused by several factors including infiltration of precipitation, barometric pressure, Earth tides, ground-water pumpage, and seismic events caused by tectonic activity and underground nuclear testing. No observed water-level fluctuations were attributed to a naturally occurring earthquake. The magnitude and duration of changes in water levels caused by nuclear tests are affected by the test size and the distance from a well to the test. Identifying water levels that might be affected by past nuclear tests is difficult because pre-testing water-level data are sparse. Hydrologically significant trends were found in 13 of 25 wells with multiple years of water-level record. The largest change in water levels (1,029 feet in 25 years) occurred in well U-19v PS 1D as a result of the Almendro nuclear test. Likely explanations for trends in most of the wells are either changes in precipitation patterns that affect recharge rates to the ground-water system, pumping effects from water-supply well U-20 WW, or a combination of these two factors.
The U.S. Geological Survey and the Louisville Water Company, from 2000 to 2020, cooperatively investigated physical and hydrologic conditions in the Ohio River alluvial aquifer and adjacent riverbed sediments in the northeast part of Louisville, Kentucky, to increase knowledge of processes affecting water sources to collector wells during operation of a riverbank filtration system (RBF). The RBF, in 2020, included an initial collector well (CW1) completed in 1999 and a tunnel and collector well system (TCWS) composed of four collector wells (CW2–CW5) completed in late 2010 that were connected by a tunnel that routed water to a pumping station and a treatment plant. Daily mean water-withdrawal rates typically ranged from about 10.4 to 20.7 million gallons per day (Mgal/d) from 2005 to 2007, then were cyclic from 2008 to 2010 and ranged from as low as about 9 to 13 Mgal/d in winter-spring months up to about 19 to 20 Mgal/d in summer-autumn months. From 2011 through 2017, peak daily mean water-withdrawal rates from CW2–CW5 fluctuated between winter-spring lows of about 20–30 Mgal/d to summer-autumn peak rates of about 41.6 Mgal/d in 2013 to about 48.2 Mgal/d in 2012. From 2017 to 2020, TCWS peak daily mean water-withdrawal rates decreased from about 45.7 Mgal/d in 2017 to about 37.5 Mgal/d in 2020 and peak daily mean rates from CW1 ranged from about 20.7 Mgal/d in 2020 to about 21.6 Mgal/d in 2018. Periods in 2019–20 with tunnel pumping station daily mean water-withdrawal rates smaller than about 30 Mgal/d had generally stable water levels in CW2 and indicated the sustainable yield of the TCWS collector wells under the prevailing hydrologic conditions. Drawdown during July–August of 2008 and 2009 was associated with CW1, the sole operating collector well. Groundwater-flow directions outside the CW1 cone of depression during July–August of 2008 and 2009 were from areas near the alluvial valley margin toward the Ohio River and in 2009 toward Harrods Creek. Collector wells CW2 through CW5 derived water during 2011–19 surveys from surface-water infiltration, as indicated by drawdown that extended beneath the Ohio River and Harrods Creek. Increases in drawdown toward the alluvial valley margins in July–August of 2013 and 2015, compared with July 2011, indicated less available recharge from those flow directions and decreased yield of groundwater from the aquifer after progressively longer TCWS water withdrawals. Drawdown at CW2–CW5 and at observation wells between them lessened in October 2019 and indicated that onshore groundwater levels can recover when collector well withdrawals decrease. Overlapping cones of depression in 2011–15 potentiometric surfaces centered around CW2, CW3, CW4, and CW5, and drawdown along divides between those wells indicated well interference between collector wells. Well-interference effects increased during 2013 and 2015 survey periods, despite decreased water-withdrawal rates compared with July 2011, and expanded to include CW1 when its use resumed. Groundwater-level fluctuations in observation wells near the Ohio River were consistent with gradual depletion of groundwater yield during tunnel pumping station operation at river elevations of about 420 feet above the National Geodetic Vertical Datum of 1929 (NGVD 29) and enhanced recharge of the aquifer when river elevations were above flood stage of about 430 feet above NGVD 29. Groundwater-level declines in observation wells near the Ohio River were most apparent in summer and some autumn months between 2012 and 2017 during periods when tunnel pumping station mean daily water-withdrawal rates were about 35 Mgal/d or more. Periods of relatively stable groundwater levels during 2019–20 in observation wells between CW2–CW5, when tunnel pumping station water-withdrawal rates were about 30–33 Mgal/d or less, also indicated that the prevailing sustainable yield was about 30 Mgal/d or less. Wells associated with CW3 and CW4 had the largest increases in slopes of best-fit lines relating water-level difference to water-withdrawal rate between 2012 and 2020, an indication of decreased efficiencies of those wells to supply water or of changes in groundwater yield around the well. Increased slopes of best-fit lines relating water-level difference to water-withdrawal rate from 2019 to 2020, when groundwater levels were otherwise relatively stable, also indicated that the specific capacity of one or more TCWS collector wells may have declined during that period. Riverbed surface elevation, roughness, and hardness changes between hydroacoustic surveys indicated active accretion and erosion of bed sediment offshore from the riverbank filtration system in 2002–4. Riverbed hydraulic conductivity computed from 2013 to 2015 in tests at 11 sites ranged from 0.2 to 230 feet per day. Ten temporary piezometer sites with adjacent operating collector wells had drawdowns that ranged from about 4 to 11.7 feet and hammer blows greater than or equal to 49 counts, which indicated a relatively great density of alluvial sediments and the potential for diminished riverbed infiltration rates. Contributions of Ohio River infiltration to collector wells estimated from deuterium and oxygen-18 isotopic ratios in representative Ohio River and groundwater samples were considerably larger in warmer months than cooler months and ranged from 80–90 percent in CW1–CW5 in May 2020 to 100 percent in May 2019 at CW2, CW4, and CW5. Groundwater contributions to water withdrawals by collector wells increased in cooler autumn months and ranged from 40 percent at CW3 and CW5 in November 2020 to 70 percent at CW2, CW4, and CW5 in November–December 2019. November 2019 and November 2020 isotopic compositions of water from the collector wells had enriched deuterium and oxygen-18 isotopic ratios consistent with mixtures of evaporation-modified water from the Ohio River and meteoric-origin groundwater.
More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.
Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.
The stress field controls patterns of crustal deformation, including which faults are likeliest to cause earthquakes or transmit fluids. Since the 1950s, maps of maximum horizontal stress ( S Hmax ) orientations have advanced dramatically, and the style of faulting (relative principal stress magnitudes) has recently been mapped in some regions as well. This perspectives paper summarizes developments in characterizing stress orientations and (relative) magnitudes, including new seismic and borehole methods, as well as progress in identifying the causes of stress variations. Despite these advances, adding far more spatiotemporal detail would allow geoscientists to address many of today's key challenges regarding natural hazards, energy development, and geodynamics. In particular, it is critically important to characterize stress heterogeneity at multiple scales while also recognizing the coherent variability of the stress field. The second part of the paper considers how more detailed stress datasets could prove essential to addressing some of the grand questions in geoscience, including deciphering the poorly understood feedbacks between crustal dynamics and surface processes, improving earthquake and eruption forecasts, and determining the origins and shared properties of plate boundaries.
Landsliding in river valleys poses unique risks for cascading hazards and can damage infrastructure and cause fatalities. In postglacial valleys, many landslides are posited to occur in relation to lateral river erosion, but the dynamics of fluvial-hillslope interactions are not well understood. Here, we investigate a section of the Nooksack River in western Washington State where the channel is flanked by landslide-prone glacial terraces similar to those that failed in the 2014 State Route 530 “Oso” landslide. We map 216 landslides through time across 17 aerial imagery data sets (1933–2022) and analyze them in relation to river meandering and curvature. We observe dynamic feedbacks between lateral river meandering and valley-adjacent landsliding. Terrace lateral retreat rates of up to 25 m/year owing to combined fluvial erosion and slope failure occur on pinned, outer meander bends immediately downstream from peaks in river curvature (>0.0075 1/m); these locations are predisposed to both shallow and deep-seated landslides. Deep-seated landslides extending 17%–32% of the active valley width into the floodplain can displace the river away from the floodplain margin and change the channel planform. River-displacing landslides relocate meanders up- or downstream, thereby conditioning the location of subsequent landslides. This conceptual model of coupled landslide-driven meander displacement and valley-adjacent landsliding is exemplified across western Washington river systems. The distance between up- and downstream valley-adjacent landsliding scales with valley width, meander wavelength, and terrace height. Our results can advance our understanding of the river-hillslope interface in landscape evolution and can be used to inform hazard management in river corridors.
Compound flood events, the co-occurrence of multiple flood drivers, can result in flood hazard potential exceeding that of any single driver alone. To evaluate compound flooding in a semi-urbanized coastal area, historical records dating back to 1970 are used to study the co-occurrences of high precipitation, storm surge, and shallow groundwater conditions along the coastlines of New York and Connecticut. Joint return periods for coincident precipitation-surge events were computed using statistical dependence models and compared to the assumption of independence as a ratio, referred to here as a return period adjustment. Results indicate distinct seasonality where compound events in the area disproportionately occur in the cold season between October and April. Return period adjustments range from a factor of 1 to almost 9, demonstrating the range in precipitation-storm surge dependence across the study area. Across all 24 station triad locations, groundwater levels were elevated during times of precipitation- surge co-occurrence, reflecting the tendency for coastal storms and shallow groundwater conditions to co-occur seasonally. The result is a pseudo-trivariate compound flood hazard score and corresponding hazard map that integrates dependence between daily precipitation-surge events and overall monthly groundwater levels (as a precondition) into a relative compound hazard score. The location with the highest compound flood hazard score is on the south shore of Long Island, as well as locations across coastal Connecticut where groundwater levels compound the co-occurrence of heavy precipitation and storm surge.
The timing and nature of early deformation in the Rio Grande Rift remains poorly constrained. We present evidence for the earliest structural signature of rift extension in the Sangre de Cristo Range, southern Colorado, based on new geologic mapping, structural analysis, rock magnetic data, and thermochronology. These analyses focus on the ~30.0 Ma granite of Chokecherry Canyon, which hosts discrete low-angle mylonitic shear zones and a distributed, gently SW-dipping protomylonitic fabric. Incremental stretching axes, stretching lineations, and Kmax magnetic lineations plunge gently WSW. Quartz microstructures and crystallographic orientations indicate dominantly coaxial strain in the protomylonite and general shear in the discrete shear zones. Quartz c-axis opening-angle thermometry suggests deformation at ~420–540°C. Thermal modeling of ⁴⁰Ar/³⁹Ar K-feldspar data indicates rapid post magmatic cooling below the brittle–plastic transition, supporting shear-zone formation immediately after emplacement. Slow cooling from ~20–13 Ma was followed by renewed rapid cooling at ~13 Ma, interpreted as the onset of extensional exhumation along the Sangre de Cristo Fault System. These results show that extension in the northern Rio Grande Rift was active by ~30 Ma, earlier than previously recognized. We propose a two-stage model for northern Rio Grande Rift evolution: Stage I (30–23 Ma) records ENE–WSW extension localized in low-angle mylonitic shear zones associated with mid-crustal intrusions; Stage II (≤18 Ma) reflects brittle high-angle normal faulting, focused exhumation, and rift narrowing. Stage I magmatism and deformation along the western range front likely established crustal weaknesses that guided later fault development.
The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.
Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.
This paper describes a study that deployed underwater acoustic sensors (hydrophones) to detect streambed mobilization in the Wild and Scenic reach of the Rio Chama, New Mexico. Fine sediment accumulation in the gravel‑cobble bed affects brown trout spawning habitat, and understanding incipient motion thresholds is essential for planning effective environmental flushing flows released from El Vado Dam. Two hydrophone stations were operated during 2021–2022, capturing audio data during a high‑flow pulse in late 2021. Acoustic processing techniques, including spectral analysis and threshold‑based impact detection, were used to identify sediment‑generated noise associated with coarse sediment transport. Results indicate detectable sediment mobilization during the high‑flow pulse, demonstrating hydrophones’ potential as a passive monitoring tool for environmental flow planning and sediment‑management decision support.
Characterizing changes to water availability for domestic, industrial, agricultural, and other uses is essential to support water management. To better quantify these changes, the U.S. Geological Survey and National Science Foundation National Center for Atmospheric Research produced two hydrologic models simulating water budget components from 1980 to 2021 over the contiguous United States (CONUS). Both hydrologic models were driven by a common atmospheric forcing dataset and aggregated to common spatial and temporal scales, which enables a novel evaluation of congruency between the models. We present annual and seasonal trends in six water budget components (precipitation, evapotranspiration, streamflow, groundwater recharge, soil saturation, and snow water equivalent) based on the Mann–Kendall test for monotonic trend and Theil-Sen slope estimate for the water year 1983–2021 period for ~86,000 catchments in CONUS. Additional components and metrics from our analysis pipeline are available in an associated published dataset, which contains more than 46 million trend results. The water budget trends showed broad agreement with prior observational and modeling studies that indicate increasing trends in the northeast and decreasing trends in southwestern CONUS. We found the seasonal variability in water budget trends was greatest in the southern, central, and northwest CONUS. These findings support integrated trend assessments when coupled with trends in water quality and use.
Long Island, New York and near coastal areas surrounding Long Island Sound are densely populated and, like other coastal areas, are susceptible to flooding from several potential sources, including stormwater from precipitation events, tidal flooding and storm surge, and groundwater inundation or groundwater emergence flooding. The latter refers to the intersection of a rising water table with land surface or critical infrastructure. Many studies of flood drivers either neglect or only briefly discuss how shallow groundwater conditions may contribute to or exacerbate flood conditions. As part of a comprehensive study of compound flood hazards in the near coastal areas surrounding Long Island and Long Island Sound, a spatial analysis was completed, in cooperation with the Environmental Protection Agency’s Long Island Sound Study, using available regional datasets to characterize the potential hazard for groundwater emergence flooding. The approximately 3,100 square mile study area was subdivided into 11,407 900-meter by 900-meter (approximately 3,000-feet by 3,000-feet) grid cells, for the purposes of integrating the spatial datasets to calculate and map the groundwater emergence flood hazard. The depth to the water table, hydrologic soil groups, and National Land Cover Database were harmonized to the common grid. A groundwater emergence flood hazard rank was calculated for each grid cell for current average conditions following a set of rules accounting for the depth to the water table and the percent of area within each cell with slow infiltrating soils. A higher sea level position scenario was also calculated for the Long Island part of the study area. The calculated groundwater emergence flood hazard rank was reviewed in concert with the National Land Cover Data Base to identify developed areas and associated infrastructure that may be at risk to groundwater emergence flooding. Study results indicate that the groundwater emergence flood hazard is highest in coastal areas and near surface water where the water table is close to ground surface. Inland areas away from surface water bodies are not likely to be exposed to groundwater emergence flooding. For Long Island, under a scenario with higher sea level position, a greater groundwater emergence flood hazard is calculated in some locations closer to the coast and where land is submerged. Away from the coast and surface-water drainage, the groundwater emergence flood hazard is similar between the current average sea level condition and a higher sea level position scenario.
The Scituate Reservoir Basin covers about 94 square miles in north central Rhode Island and supplies more than 60 percent of the State of Rhode Island's drinking water. The basin includes the Scituate Reservoir Basin and six smaller tributary reservoirs with a combined capacity of about 40 billion gallons. Most of the basin is forested and undeveloped. However, because of its proximity to the Providence, Rhode Island, metropolitan area, the basin is subject to increasing development pressure and there is concern that this may lead to the degradation of the water supply. Selected water-quality constituent concentrations, loads, and trends in the Scituate Reservoir Basin, Rhode Island, were investigated locate parts of the basin likely responsible for exporting disproportionately large amounts of water-quality constituents to streams, rivers, and tributary reservoirs, and to determine whether water quality in the basin has been changing with time. Water-quality data collected between 1982 and 1995 by the Providence Water Supply Board PWSB) in 34 subbasins of the Scituate Reservoir Basin were analyzed. Subbasin loads and yields of total coliform bacteria, chloride, nitrate, iron, and manganese, estimated from constituent concentrations and estimated mean daily discharge records for the 1995 water year, were used to determine which subbasins contributed disproportionately large amounts of these constituents. Measurements of pH, color, turbidity, and concentrations of total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese made between 1982 and 1995 by the PWSB were evaluated for trends. To determine the potential effects of human-induced changes in drainage- basin characteristics on water quality in the basin, relations between drainage-basin characteristics and concentrations of selected water-quality constituents also were investigated. Median values for pH, turbidity, total coliform bacteria, sodium, alkalinity, chloride, nitrate, and iron were largest in subbasins with predominately residential land use. Median instantaneous loads reflected drainage-basin size. However, loads normalized by drainage area (median instantaneous yields) also were largest in residential areas where point and non-point sources are likely, and in areas of poorly drained soils. Significant trends in water-quality constituents from 1982 to 1995 in the Scituate Reservoir Basin indicate that the quality of the water resources in the basin may be slowly changing. Scituate Reservoir subbasins with large amounts of residential land use showed increasing trends in alkalinity and chloride. In contrast, subbasins distributed throughout the drainage basin showed increasing trends in pH, color, nitrate, and iron concentrations, indicating that these characteristics and constituents may be affected more by atmospheric deposition. Although changing, water-quality constituent concentrations in the Scituate Reservoir Basin only occasionally exceeded Rhode Island and USEPA water-quality guidelines and standards. Result of correlation analysis between pH, color, turbidity, and concentrations total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese and land use, geology, wetlands, slope, soil drainability, and roads indicated that the percentage of wetlands, roads, and slope appear have the greatest effect on water-quality in the Scituate Reservoir Basin. The percentage of urban, residential, and commercial land use also are important, but to a lesser degree than wetlands, roads, and slope. Finally, geology appears to have the least effect on water quality compared to other drainage-basin characteristics investigated.
Quantitative information concerning aquifer hydrologic and hydraulic characteristics is needed to manage the development of ground-water resources. These characteristics are poorly defined for the bedrock aquifers in Middle and East Tennessee where demand for water is increasing. This report presents estimates of recharge rate, storage coefficient, diffusivity, and transmissivity for representative drainage basins in Middle and East Tennessee, as determined from analyses of stream-aquifer interactions. The drainage basins have been grouped according to the underlying major aquifer, then statistical descriptions applied to each group, in order to define area1 distribution of these characteristics. Aquifer recharge rates are estimated for representative low, average, and high flow years for 63 drainage basins using hydrograph analysis techniques. Net annual recharge during average flow years for all basins ranges from 4.1 to 16.8 in/yr (inches per year), with a mean value of 7.3 in. In general, recharge rates are highest for basins underlain by the Blue Ridge aquifer (mean value11.7 in/yr) and lowest for basins underlain by the Central Basin aquifer (mean value 5.6 in/yr). Mean recharge values for the Cumberland Plateau, Highland Rim, and Valley and Ridge aquifers are 6.5, 7.4, and 6.6 in/yr, respectively. Gravity drainage characterizes ground-water flow in most surficial bedrock aquifer in Tennessee. Accordingly, a gravity yield analysis, which compares concurrent water-level and streamflow hydrographs, was used to estimate aquifer storage coefficient for nine study basins. The basin estimates range from 0.002 to 0.140; however, most estimates are within a narrow range of values, from 0.01 to 0.025. Accordingly, storage coefficient is estimated to be 0.01 for all aquifers in Middle and East Tennessee, with the exception of the aquifer in the inner part of the Central Basin, for which storage coefficient is estimated to be 0.002. Estimates of aquifer hydraulic diffusivity are derived from estimates of the streamflow recession index and drainage density for 75 drainage basins; values range from 3,300 to 130,000 ft^2/d (feet squared per day). Basin-specific and site-specific estimates of transmissivity are computed from estimates of hydraulic diffusivity and specific-capacity test data, respectively. Basin-specific, or areal, estimates of transmissivity range from 22 to 1,300 ft^2/d, with a mean of 240 ft^2/d In general, areal transmissivity is highest for basins underlain by the Cumberland Plateau aquifer (mean value 480 ft^2/d) and lowest for basins underlain by the Central Basin aquifer (mean value 79 ft^2/d). Mean transmissivity values for the Highland Rim, Valley and Ridge, and Blue Ridge aquifer are 320,140, and 120 ft^2/d respectively. Site-specific estimates of transmissivity, computed from specific-capacity data from 118 test wells in Middle and East Tennessee range from 2 to 93,000 ft^2/d with a mean of 2,600 ft^2/d Mean transmissivity values for the Cumberland Plateau, Highland Rim, Central Basin, Valley and Ridge, and Blue Ridge aquifers are 2,800,1,200, 7,800, 390, and 65Oft Id, respectively.
Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.