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At least 397 records · Page 22Linked to original sources

Analysis of Water-Quality Trends for Selected Streams in the Water Chemistry Monitoring Program, Michigan, 1998-2005

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began a long-term monitoring program to evaluate the water quality of most watersheds in Michigan. Major goals of this Water-Chemistry Monitoring Program were to identify streams exceeding or not meeting State or Federal water-quality standards and to assess if constituent concentrations reflecting water quality in these streams were increasing or decreasing over time. As part of this program, water-quality data collected from 1998 to 2005 were analyzed to identify potential trends. Sixteen water-quality constituents were analyzed at 31 sites across Michigan, 28 of which had sufficient data to analyze for trends. Trend analysis on the various water-quality data was done using the uncensored Seasonal Kendall test within the computer program ESTREND. The most prevalent trend detected throughout the state was for chloride. Chloride trends were detected at 8 of the 28 sites; trends at 7 sites were increasing and the trend at 1 site was decreasing. Although no trends were detected for various nitrogen species or phosphorus, these constituents were detected at levels greater than the U.S. Environmental Protection Agency recommendations for nutrients in water. The results of the trend analysis will help to establish a baseline to evaluate future changes in water quality in Michigan streams.

Scientific Investigations Report

Hydrogeology and ground-water quality of the county road a disposal site on the Bad River Indian Reservation, Ashland County, Wisconsin: 1997-98

The County Road A disposal site, located on the Bad River Indian Reservation, Ashland County, Wisconsin, contains papermill sludge generated by a former mill in the City of Ashland. Since the time of disposal (1968-1970) the site has been the subject of investigations by the U.S. Bureau of Indian Affairs, the U.S. Environmental Protection Agency, and private consultants. During 1997- 1998, an investigation was conducted by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Natural Resources Department of the Bad River Indian Tribe, to evaluate the hydrogeology and groundwater quality of the disposal site, particularly with respect to the hydraulic connection between two ponds at the site and the shallow ground-waterflow system. Additional monitoring wells and well points were installed, and additional hydrogeologic, ground-water quality, and geophysical data were collected. The data from this and previous studies were integrated and interpreted.

Wisconsin

Arsenic in ground water in Genesee County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

Arsenic in ground water in Livingston County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

Arsenic in ground water in Shiawassee County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

Arsenic in ground water in Sanilac County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

Arsenic in ground water in Tuscola County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

Arsenic in ground water in Washtenaw County, Michigan

Previous studies of ground-water resources in Michigan by the Michigan Department of Community Health (MDCH), the Michigan Department of Environmental Quality (MDEQ), and the U.S. Geological Survey (USGS) indicate that in several counties in the southeastern part of the State the concentrations of arsenic in ground water may exceed the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 50 micrograms per liter [µg/L]. This MCL was established in 1986. The Safe Drinking Water Act, as amended in 1996, requires USEPA to revise this standard in 2000. In June 2000, the USEPA proposed a revised MCL of 5 µg/L. In 1996, the USGS, in cooperation with the MDEQ and the Health Departments of Genesee, Huron, Lapeer, Livingston, Oakland, Sanilac, Shiawassee, Tuscola and Washtenaw counties, began a study of the factors controlling arsenic occurrence and concentrations in ground water in southeastern Michigan. This study is one of four USGS Drinking Water Initiative projects throughout the United States.

Michigan

The Sun and climate

Many geologic records of climatic and environmental change based on various proxy variables exhibit distinct cyclicities that have been attributed to extraterrestrial forcing. The best known of these are the changes in Earth’s orbital geometry called Milankovitch Cycles, with periodicities of tens to hundreds of thousands of years. However, many cycles seem to have subMilankovitch periodicities, commonly on decadal and centennial scales, similar to those of known solar cycles. A direct connection between solar irradiance (solar constant) and weather and climate has been suggested for more than 100 years but generally rejected by most scientists, who assume that the effect of solar variations would be small. However, recent satellite radiometer measurements and modeling studies indicate that small changes in total solar irradiance could produce global temperature changes of the magnitude suggested for climatic events such as the Little Ice Age (A.D. 1550–1700).

Fact Sheet

Cross-sectional associations between drinking water arsenic and urinary inorganic arsenic in the US: NHANES 2003-2014

Background: Inorganic arsenic is a potent carcinogen and toxicant associated with numerous adverse health outcomes. The contribution of drinking water from private wells and regulated community water systems (CWSs) to total inorganic arsenic exposure is not clear. Objectives: To determine the association between drinking water arsenic estimates and urinary arsenic concentrations in the 2003-2014 National Health and Nutrition Examination Survey (NHANES). Methods: We evaluated 11,088 participants from the 2003-2014 NHANES cycles. For each participant, we assigned private well and CWS arsenic levels according to county of residence using estimates previously derived by the US Environmental Protection Agency and US Geological Survey. We used recalibrated urinary dimethylarsinate (rDMA) to reflect the internal dose of estimated water arsenic by applying a previously validated, residual-based method that removes the contribution of dietary arsenic sources. We compared the adjusted geometric mean ratios and corresponding percent change of urinary rDMA across tertiles of private well and CWS arsenic levels, with the lowest tertile as the reference. Comparisons were made overall and stratified by census region and race/ethnicity. Results: Overall, the geometric mean of urinary rDMA was 2.52 (2.30, 2.77) µg/L among private well users and 2.64 (2.57, 2.72) µg/L among CWS users. Urinary rDMA was highest among participants in the West and South, and among Mexican American, Other Hispanic, and Non-Hispanic Other participants. Urinary rDMA levels were 25% (95% CI: 17-34%) and 20% (95% CI: 12-29%) higher comparing the highest to the lowest tertile of CWS and private well arsenic, respectively. The strongest associations between water arsenic and urinary rDMA were observed among participants in the South, West, and among Mexican American and Non-Hispanic White and Black participants. Discussion: Both private wells and regulated CWSs are associated with inorganic arsenic internal dose as reflected in urine in the general US population.

Environmental Research

Lithologic log, lithium content, and mineralogy of sediments penetrated in test boring drilled in Eureka Valley, Inyo County, California

A test boring was drilled in a playa in Eureka Valley, Calif., by the U.S. Geological Survey in the spring of 1978. Work was done under the terms of a cooperative agreement between the U.S. Geological Survey and the U.S. Bureau of Land Management to evaluate the leasable mineral potential of various playas in the California Desert Planning area, as described in the environmental analysis (prepared by the U.S. Geological Survey, 1978). The purpose of this report is to describe the occurrence and distribution of lithium in the basin sediments as part of a program to identify additional domestic resources of nonpegmatite lithium (Vine, 1978). Interest in this playa stems from the fact that Eureka Valley is located in a region where other lithium resources have been identified. Lithium is recovered from subsurface brines at Clayton Valley, Nev., to the north and at Searles Lake, Calif., to the south. Eureka Valley is a closed topographic basin that has an arid climate, it thus provides suitable conditions for the entrapment of a brine and subsequent concentration of lithium by evaporation. Development of new energy related uses for lithium in batteries for electric vehicle propulsion and for off-peak power storage by the utility industry (Chilenskas and others, 1977) may he aided by identification of a large domestic resource of lithium.

California

Current activity on the Martian surface: A key subject for future exploration

One of the fundamental discoveries in Mars science in the last decade has been the extent and importance of current surface activity. Recent results have shifted our view of Mars from a world where the most interesting geologic events were in the distant past (similar to the Moon) to a world that undergoes active evolution and one where understanding the present is key to deciphering the planet’s history. When input was requested for the last Planetary Science Decadal Survey, some observations of surface changes had been published, but the number of detections was small and their significance not fully appreciated. Since that time, detections have proliferated, driven primarily by the long-term operation of the Mars Reconnaissance Orbiter (MRO) and the High Resolution Imaging Science Experiment (HiRISE) as well as landed observations of aeolian activity. In addition to observed changes, theory suggests that additional important surface processes are likely active but not yet observed because orbital data are limited in space and time and landed studies are rare. Understanding current Martian surface processes is a fundamental science question in itself, as it provides a test for physical and terrestrial analog-based models of specific geological processes acting under non-Earth planetary and environmental conditions. It is also an essential step for reading Mars’ geologic history and providing input to climate models: without understanding current dynamic processes, we cannot understand how they have varied during recent climate cycles, nor how they are reflected in ancient rock or modern ice records. Understanding the rates and types of current surface activity is also highly relevant to selecting geological samples, setting Planetary Protection rules, and understanding the hazards and environment that would be experienced by future human explorers.

Bulletin of the AAS

A Procedure for the supercritical fluid extraction of coal samples, with subsequent analysis of extracted hydrocarbons

Introduction: This report provides a detailed, step-by-step procedure for conducting extractions with supercritical carbon dioxide (CO2) using the ISCO SFX220 supercritical fluid extraction system. Protocols for the subsequent separation and analysis of extracted hydrocarbons are also included in this report. These procedures were developed under the auspices of the project 'Assessment of Geologic Reservoirs for Carbon Dioxide Sequestration' (see http://pubs.usgs.gov/fs/fs026-03/fs026-03.pdf) to investigate possible environmental ramifications associated with CO2 storage (sequestration) in geologic reservoirs, such as deep (~1 km below land surface) coal beds. Supercritical CO2 has been used previously to extract contaminants from geologic matrices. Pressure-temperature conditions within deep coal beds may render CO2 supercritical. In this context, the ability of supercritical CO2 to extract contaminants from geologic materials may serve to mobilize noxious compounds from coal, possibly complicating storage efforts. There currently exists little information on the physicochemical interactions between supercritical CO2 and coal in this setting. The procedures described herein were developed to improve the understanding of these interactions and provide insight into the fate of CO2 and contaminants during simulated CO2 injections.

Open-File Report

USGS national surveys and analysis projects: Preliminary compilation of integrated geological datasets for the United States

The growth in the use of Geographic nformation Systems (GS) has highlighted the need for regional and national digital geologic maps attributed with age and rock type information. Such spatial data can be conveniently used to generate derivative maps for purposes that include mineral-resource assessment, metallogenic studies, tectonic studies, human health and environmental research. n 1997, the United States Geological Survey’s Mineral Resources Program initiated an effort to develop national digital databases for use in mineral resource and environmental assessments. One primary activity of this effort was to compile a national digital geologic map database, utilizing state geologic maps, to support mineral resource studies in the range of 1:250,000- to 1:1,000,000-scale. Over the course of the past decade, state databases were prepared using a common standard for the database structure, fields, attributes, and data dictionaries. As of late 2006, standardized geological map databases for all conterminous (CONUS) states have been available on-line as USGS Open-File Reports. For Alaska and Hawaii, new state maps are being prepared, and the preliminary work for Alaska is being released as a series of 1:500,000-scale regional compilations. See below for a list of all published databases.

Conference Paper

Diversity of diatoms, benthic macroinvertebrates, and fish varies in response to different environmental correlates in Arctic rivers across North America

Climate change poses a significant threat to Arctic freshwater biodiversity, but impacts depend upon the strength of organism response to climate‐related drivers. Currently, there is insufficient knowledge about Arctic freshwater biodiversity patterns to guide assessment, prediction, and management of biodiversity change. As part of the Circumpolar Biodiversity Monitoring Program's first freshwater assessment, we evaluated diversity of diatoms, benthic macroinvertebrates, and fish in North American Arctic rivers. Alpha diversity was assessed in relation to temperature, water chemistry, bedrock geology, and glaciation history to identify important environmental correlates. Biotic composition was compared among groups to evaluate response to environmental gradients. Macroinvertebrate α‐diversity declined strongly with increasing latitude from 48°N to 82°N, whereas diatom and fish diversity peaked around 70°N without a clear latitudinal decline. Macroinvertebrate diversity was significantly positively related to air temperature. Diatom diversity was related to bedrock geology and temperature, whereas fish diversity was related to glaciation history. Fish and macroinvertebrate assemblages differed between sites in western Canada, where invertebrate composition was more variable, and Alaska, where fish composition was more variable. In sites with both diatom and macroinvertebrate data, diatom composition was distinct in Alaska, where richness was highest in former glacial refugia. Macroinvertebrate composition was distinct in lowest‐latitude eastern and high‐latitude western Canadian sites where temperature was highest. Temperature, precipitation, geology, calcium, and substrate size were important environmental correlates for diatoms and macroinvertebrates, although the relative importance of each correlate differed. Diatom taxa were most strongly associated with water chemistry, whereas benthic invertebrate composition related most strongly to precipitation and temperature. This large‐scale study provides the most substantial integration and analysis of river diatom, macroinvertebrate, and fish data from the North American Arctic to date. Findings suggest that macroinvertebrates will show the strongest response to climate‐related shifts in temperature, whereas diatoms and fish are more likely to respond to climate‐induced shifts in nutrients and hydraulic connectivity. However, significant gaps in data coverage limited our ability to reliably evaluate spatial patterns and detect change. These gaps could be reduced by improving collaborative efforts between the U.S.A. and Canada to harmonise future monitoring.

Arctic

Water quality data for national-scale aquatic research: The Water Quality Portal

Aquatic systems are critical to food, security, and society. But, water data are collected by hundreds of research groups and organizations, many of which use nonstandard or inconsistent data descriptions and dissemination, and disparities across different types of water observation systems represent a major challenge for freshwater research. To address this issue, the Water Quality Portal (WQP) was developed by the U.S. Environmental Protection Agency, the U.S. Geological Survey, and the National Water Quality Monitoring Council to be a single point of access for water quality data dating back more than a century. The WQP is the largest standardized water quality data set available at the time of this writing, with more than 290 million records from more than 2.7 million sites in groundwater, inland, and coastal waters. The number of data contributors, data consumers, and third-party application developers making use of the WQP is growing rapidly. Here we introduce the WQP, including an overview of data, the standardized data model, and data access and services; and we describe challenges and opportunities associated with using WQP data. We also demonstrate through an example the value of the WQP data by characterizing seasonal variation in lake water clarity for regions of the continental U.S. The code used to access, download, analyze, and display these WQP data as shown in the figures is included as supporting information.

Water Resources Research

Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse

Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concerns, and their commodity (e.g., lithium) potential. However, produced water geochemistry from many active petroleum plays remain poorly constrained leading to knowledge gaps associated with the origin of brine salinity and parameters (e.g., radium levels) that can impact treatment, disposal, and possible reuse. Here we evaluate the major ion geochemistry, radium concentrations, and stable water isotope composition of ~120 produced water samples collected from 17 producing unconventional petroleum wells in Weld County, Colorado from the Late Cretaceous Niobrara Formation. This sample set encompasses eight produced water time series from four new wells across production days 0 to ~365 and from four established wells across production days ~1000 to ~1700. Additionally, produced water from nine other established Niobrara Formation wells were sampled at discrete time points ranging from day 458 to day 2256, as well as hydraulic fracturing input fluids. These results expand the available Niobrara Formation produced water geochemical data, previously limited to few wells sampled within the first year of production, allowing for the heterogeneity of major ions and radium to be evaluated. Furthermore, we explore the geochemical relationships between major ion ratios and stable water isotope composition to understand the origin of salinity in Niobrara Formation brines from the Denver-Julesburg Basin. These findings are discussed with perspective toward potential treatment and reuse of Niobrara produced water prior to disposal.

Colorado, Nebraska, Wyoming

Cell-Based metabolomics for untargeted screening and prioritization of vertebrate-active stressors in streams across the United States

The U.S. Geological Survey and the U.S. Environmental Protection Agency have assessed contaminants in 38 streams across the U.S., using an extensive suite of target-chemical analysis methods along with a variety of biological effects tools. Here we report zebrafish liver (ZFL) cell-culture based NMR metabolomic analysis of these split stream samples. We used this untargeted approach to evaluate the sites according to overall impact on the ZFL metabolome and found that neither the total number of organics detected at the sites, nor their cumulative concentrations, were good predictors of these impacts. Further, we used partial-least squares regression to compare ZFL endogenous metabolite profiles to values for 455 potential stressors (organics, inorganics, and physical properties) measured in these waters and found that the profiles covaried with at most 280 of the stressors, which were subsequently ranked into quartiles based on the strength of their covariance. While contaminants of emerging concern (CECs) were well represented in the top, most strongly, covarying quartile – suggesting considerable potential for eliciting biological responses at these sites – there was even higher representation of various well-characterized legacy contaminants (e.g., PCBs). These results emphasize the importance of complementing chemical analysis with untargeted bioassays to help focus regulatory efforts on the most significant ecosystem threats.

Environmental Science & Technology