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At least 397 records · Page 22Linked to original sources
USGS2023

Dissolved organic matter transformations in a freshwater rivermouth

River-to-lake transitional areas are biogeochemically active ecosystems that can alter the amount and composition of dissolved organic matter (DOM) as it moves through the aquatic continuum. However, few studies have directly measured carbon processing and assessed the carbon budget of freshwater rivermouths. We compiled measurements of dissolved organic carbon (DOC) and DOM in several water column (light and dark) and sediment incubation experiments conducted in the mouth of the Fox river (Fox rivermouth) upstream from Green Bay, Lake Michigan. Despite variation in the direction of DOC fluxes from sediments, we found that the Fox rivermouth was a net sink of DOC where water column DOC mineralization outweighed the release of DOC from sediments at the rivermouth scale. Although we found DOM composition also changed during our experiments, alterations in DOM optical properties were largely independent of the direction of sediment DOC fluxes. We found a consistent decrease in humic-like and fulvic-like terrestrial DOM and a consistent increase in the overall microbial composition of rivermouth DOM during our incubations. Moreover, greater ambient total dissolved phosphorus concentrations were positively associated with the consumption of terrestrial humic-like, microbial protein-like, and more recently derived DOM but had no effect on bulk DOC in the water column. Unexplained variation indicates that other environmental controls and water column processes affect the processing of DOM in this rivermouth. Nonetheless, the Fox rivermouth appears capable of substantial DOM transformation with implications for the composition of DOM entering Lake Michigan.

Wisconsin↗
USGS2023

Foliar chemical composition and respiration rates of sugar maple (Acer saccharum) and American beech (Fagus grandifolia) trees across a gradient of soil acidification

Acidic deposition has been well studied for its impacts on forest soils and plants and is thought to detrimentally affect sugar maple ( Acer saccharum ) in northeastern North America. The physiological mechanism driving reduced tree growth on acid impaired sites is not well understood, but has been suggested to involve increased autotrophic respiration rates. We measured foliar respiration and leaf elemental composition on two species with contrasting acid tolerances (sugar maple and American beech, Fagus grandifolia ) across a naturally occurring soil base saturation (BS) gradient in the Adirondack Mountains of New York. Foliar chemistry varied strongly as anticipated across the BS gradient, with decreases in base cations and increases in phytotoxic metals (e.g., Mn) on sites with highly acidified soils. However, foliar respiration rates were not correlated with most measures of acidity (e.g., BS, foliar concentrations of Ca, Mg, Al content). Respiration rates did correlate with other leaf traits (N content, leaf mass per unit area) reflective of leaf morphological variation in response to variable light availability. After accounting for multivariate trait covariation, mass-based respiration rates were associated with foliar Mn content, suggesting a positive relationship between the concentration of this phytotoxic metal and foliar respiration rates. Soluble foliar Ca, Mg, and Mn were closely correlated with total foliar concentrations of these elements. Overall these results demonstrate that soil acidification and loss of base cations is largely unrelated to foliar respiration rates, although the accumulation of foliar Mn on acidified soils may contribute to the metabolic burden of both sugar maple and American beech trees.

New York↗
USGS2023

Nitrogen-bedrock interactions regulate multi-element nutrient limitation and sustainability in forests

Nutrient limitation of tree growth can intensify when nutrients are lost to forest harvest, creating challenges for forest growth and sustainability. Forest harvest accelerates nutrient loss by removing nutrient-containing biomass and by increasing nutrient leaching, shaping patterns of nutrient depletion that cause long-term shifts in nutrient limitation. Nitrogen most frequently limits tree growth, but where nitrogen is abundant, nutrient limitation often shifts to phosphorus and base cations, depending on soil mineralogy. We used the process-based biogeochemical model NutsFor to evaluate how multiple elements can limit long-term forest growth via interactions between soil nitrogen (low vs. high nitrogen) and soil mineralogy (sedimentary vs. basaltic bedrock). Simulations were run for 525 years with 40-year harvest intervals for managed Douglas-fir forests of the Oregon Coast Range. In low nitrogen sites, nutrient limitation switched after several centuries from nitrogen to phosphorus, as cycles of forest growth and harvest depleted soil organic phosphorus pools. In contrast, high nitrogen sites displayed severe base cation depletion and reduced tree growth within only one to two rotations, with sedimentary bedrock sites limited by calcium and basaltic sites by both calcium and potassium. Harvesting stimulated the largest fractional losses of nitrogen and potassium across all simulations, and additionally of calcium in high nitrogen sites. These multi-element simulations of interactions among harvesting, soil nitrogen, and bedrock type provide a set of testable predictions to guide monitoring and changes in management aimed at sustaining long-term forest productivity across a wide range of soil biogeochemical conditions.

Biogeochemistry↗
USGS2023

Storms and pH of dam releases affect downstream phosphorus cycling in an arid regulated river

Reservoirs often bury phosphorus (P), leading to seasonal or persistent reductions in P supply to downstream rivers. Here we ask if observed variation in the chemistry of dam release waters stimulates downstream sediment P release and biological activity in an arid, oligotrophic system, the Colorado River below Lake Powell, Arizona, USA. We use bottle incubations to simulate a range of observed pH (6–8.8) and oxygen (0–9.4 mg L −1 ) levels, with the hypothesis that either oxygen concentrations or pH regulates P release from sediments to the water column. We found support for pH-mediated P release from calcite across the three sites we sampled. The magnitude of this effect was lower in bottles filled with tailwater sediment, but at downriver sites low pH resulted in declining water column dissolved inorganic nitrogen:soluble reactive P (DIN:SRP) ratios, which dropped below the Redfield ratio of 16:1, increasing water column total protein production, and down-regulating alkaline phosphatase production. Additional 7-day incubations showed that tributary storm inputs can temporarily elevate riverine P availability from < 1.5 µg L −1 total dissolved P (TDP) pre-storm to 6.7 µg L −1 TDP post storm. Taken together, our lab incubation and long-term observational results highlight the importance of pH, and ultimately reservoir management and storm dynamics, in regulating P availability and biological processes both now and into the future.

Biogeochemistry↗
USGS2023

Unraveling mechnisms underlying effects of wetting–drying cycles on soil respiration in a dryland

Rewetting of dry soils usually stimulates soil carbon (C) emission, a phenomenon known as the Birch effect. Soil C cycling in drylands, which store approximately one third of terrestrial soil organic C (SOC), is strongly affected by wetting–drying cycles. However, the physical, chemical, and biological mechanisms that link rewetting cycles with dryland soil C cycling have not been comprehensively studied, nor do we understand how these mechanisms interact with each other. Here, we conducted a dryland soil incubation experiment manipulating four factors related to global change (soil moisture content, soil moisture variability, C availability, and prior warming) in a factorial design. The experiment was divided into two periods: a rewetting period consisting of six 14-d wetting–drying cycles; and a recovery period lasting 28 days during which soil moisture content was held stable, allowing for examination of the legacy effects of the wet-dry cycles. Rewetting cycles decreased soil aggregate stability under some conditions, but their effects on soil microbial biomass and fungal communities, soil enzyme activities, soil priming, and soil dissolved C were not significant. We found lower average soil respiration under the wetting–drying treatment than the stable soil moisture treatment, and Birch effects were observed, but only under some conditions. This was probably because moisture variability exacerbated soil microbial metabolic stress, which showed itself as oxygen limitation during the initial precipitation pulse and as water limitation during soil drying. Notably, respiration rates remained low even after moisture fluctuations ceased, suggesting a legacy effect of rewetting cycles on dryland microbial communities. Overall, rewetting inhibited aggregate formation (physical mechanism), and suppressed soil respiration by inducing soil microbial metabolic stress (biological mechanism), ultimately leading to lower soil C loss under rewetting. Our findings indicate that Birch effects are mediated by the magnitude of moisture variability, the availability of C, and the degree of physiological stress microbes experience.

Biogeochemistry↗
USGS2023

Elevated temperature and nutrients lead to increased N2O emissions from salt marsh soils from cold and warm climates

Salt marshes can attenuate nutrient pollution and store large amounts of ‘blue carbon’ in their soils, however, the value of sequestered carbon may be partially offset by nitrous oxide (N 2 O) emissions. Global climate and land use changes result in higher temperatures and inputs of reactive nitrogen (Nr) into coastal zones. Here, we investigated the combined effects of elevated temperature (ambient + 5℃) and Nr (double ambient concentrations) on nitrogen processing in marsh soils from two climatic regions (Quebec, Canada and Louisiana, U.S.) with two vegetation types, Sporobolus alterniflorus (= Spartina alterniflora ) and Sporobolus pumilus (= Spartina patens ), using 24-h laboratory incubation experiments. Potential N 2 O fluxes increased from minor sinks to major sources following elevated treatments across all four marsh sites. One day of potential N 2 O emissions under elevated treatments (representing either long-term sea surface warming or short-term ocean heatwaves effects on coastal marsh soil temperatures alongside pulses of N loading) offset 15–60% of the potential annual ambient N 2 O sink, depending on marsh site and vegetation type. Rates of potential denitrification were generally higher in high latitude than in low latitude marsh soils under ambient treatments, with low ratios of N 2 O:N 2 indicating complete denitrification in high latitude marsh soils. Under elevated temperature and Nr treatments, potential denitrification was lower in high latitude soil but higher in low latitude soil as compared to ambient conditions, with incomplete denitrification observed except in Louisiana S. pumilus . Overall, our findings suggest that a combined increase in temperature and Nr has the potential to reduce salt marsh greenhouse gas (GHG) sinks under future global change scenarios.

Biogeochemistry↗
USGS2024

Riverine dissolved organic matter transformations increase with watershed area, water residence time, and Damköhler numbers in nested watersheds

Quantifying the relative influence of factors and processes controlling riverine ecosystem function is essential to predicting future conditions under global change. Dissolved organic matter (DOM) is a fundamental component of riverine ecosystems that fuels microbial food webs, influences nutrient and light availability, and represents a significant carbon flux globally. The heterogeneous nature of DOM molecular composition and its propensity for interaction (i.e., functional diversity) can characterize riverine ecosystem function across spatiotemporal scales. To investigate fundamental drivers of DOM diversity, we collected seasonal water samples from 42 nested locations within five watersheds spanning multiple watershed sizes (~5 to 30,000 km2) across the United States. Patterns in DOM molecular richness, aromaticity, relative abundance of N-containing formulas, and putative biochemical transformations derived from high-resolution mass spectrometry were assessed across gradients of explanatory variables associated with watershed characteristics (e.g., watershed area, water residence time, land cover). We found that putative biochemical transformations were more strongly related to explanatory variables across watersheds than common bulk DOM parameters and that watershed area, surface water residence time and derived Damköhler numbers representing DOM reactivity timescales were strong predictors of DOM diversity. The data also indicate that catchment-specific land cover factors can significantly influence DOM diversity in diverging directions. Overall, the results highlight the importance of considering water residence time and land cover when interpreting longitudinal patterns in DOM chemistry and the continued challenge of identifying generalizable drivers that are transferable across watershed and regional scales for application in Earth system models. This work also introduces a Findable Accessible Interoperable Reusable (FAIR) dataset (>300 samples) to the community for future syntheses.

Biogeochemistry↗
USGS2024

Seasonal patterns in riverine carbon form and export from a temperate forested watershed in Southeast Alaska

Riverine export of carbon (C) is an important part of the global C cycle; however, most riverine C budgets focus on individual forms of C and fail to comprehensively measure both organic and inorganic C species in concert. To address this knowledge gap, we conducted high frequency sampling of multiple C forms, including dissolved organic C (DOC), inorganic carbon (as alkalinity), particulate organic C (POC), coarse particulate organic C (CPOC), and invertebrate biomass C across the main run-off season in a predominantly rain-fed watershed in Southeast Alaska. Streamwater concentrations were used to model daily watershed C export from May through October. Concentration and modeled yield data indicated that DOC was the primary form of riverine C export (8708 kg C/km 2 ), except during low flow periods when alkalinity (3125 kg C/km 2 ) was the dominant form of C export. Relative to DOC and alkalinity, export of particulate organic C (POC: 992 kg C/km 2 ; CPOC: 313 kg C/km 2 ) and invertebrates (40 kg C/km 2 ) was small, but these forms of organic matter could disproportionately impact downstream food webs because of their higher quality, assessed via C to nitrogen ratios. These seasonal and flow driven changes to C form and export likely provide subsidies to downstream and nearshore ecosystems such that predicted shifts in regional hydroclimate could substantially impact C transfer and incorporation into aquatic food webs.

Alaska↗
USGS2025

Mercury cycling in the Czech GEOMON network catchments recovering from acid deposition and facing climate change

We used the catchment mass balance approach to investigate mercury (Hg) cycling at the 14 forested GEOMON catchments of the Czech Geological Survey. The temperate forest catchments had variable exposure to historic high sulfur (S) and Hg emissions, and span a range of size and elevation. We monitored monthly Hg inputs (bulk precipitation, throughfall, litterfall) and outputs (stream runoff) during 2020–2022. The catchments spanned a large gradient of historic Hg deposition, but current Hg patterns more closely aligned with catchment factors like local climate, as influenced by elevation, dissolved organic carbon (DOC) concentrations, and geology. The dominant pathway of Hg input was litterfall (averaging 44.5 ± 15.7 µg m −2 yr −1 ; > 91% of total input). Two surprising findings were that GEOMON had low Hg concentrations and fluxes in general but had the highest litterfall Hg fluxes in Europe, and these increased even further in forested areas that had bark beetle infestations. Gaseous elemental mercury (GEM), measured using passive samplers, was consistently low (1.25 to 1.66 ng m −3 ) across the 14 catchments. Stream Hg output varied across catchments and averaged 1.5 ± 1.7 µg m −2 yr −1 . The average Hg retention rate at the 14 GEOMON catchments, calculated as the fraction of average Hg inputs (throughfall + litterfall) that remained in the catchment and did not run off in streamwater, was 97%. The high catchment Hg retention combined with its strong association with DOC suggests that with climate change intensification of carbon cycling, these catchments will be a Hg source for decades to come.

Biogeochemistry↗
USGS2025

Rare earth element and phosphorus mobility depend on adsorption to Al-, Fe-, and Mn-oxyhydroxides in a headwater stream in Vermont, USA

We evaluated base cations, Al, Fe, Mn, REEs, DOC, anions, and P mobilization during three discharge events (E-1, E-2, E-3) at the headwater catchment W-9, Sleepers River, Vermont, USA. Peak discharge ranged from 3.696 (E-1) to 0.073 (E-3) mm h −1 . Eight samples from each event were speciated for total (unfiltered-acidified) and dissolved (0.45 µm filtered-acidified). During E-1, total Al, Fe, and Mn increased to maxima of 376 (1790X), 161 (194X), and 38 (45X) µmol L −1 , respectively. Concurrently, total La, Ce, Pr, and Nd increased to maxima of 87 (590X), 114 (671X), 15 (375X), and 53 (408X) nmol L −1 , respectively, greatly exceeding the dissolved fraction. Totals for Er > Yb > Tm > Lu reached comparable enrichments near or at maximum discharge. Discharge ranged from 0.41 to 0.94 mm h −1 during E-2, a snowmelt event. Total Al was comparatively stable; total Fe and Mn increased 15X and 79X, remaining less than total Al. Total La, Ce, Pr, and Nd peaked with total Fe and Mn. E-3, a late summer rain, resembled E-1 but had much lower maxima for all REEs, P, Al, Fe, and Mn. Particulate, total, and dissolved REEs and P correlated with DOC and with total Al, Fe, and Mn over all discharges, with molar Al > Fe > Mn (most samples) for E-1 and E-3. Maximum total and dissolved P declined from 15.4 and 0.89 (E-1) to 0.98 and 0.27 µmol L −1 (E-3), respectively. Particulate REEs correlated strongly (R 2 = 0.95–0.96) with Al, Fe, and Mn particulates eroded from the stream bed and continuously precipitated during and after high discharge of groundwater.

Vermont↗
USGS2026

Water table rise sustains carbon release from soils in wetland-dominated landscapes: An intact soil core study

Wetland-dominated landscapes influence carbon cycling through their potential to act as both carbon sinks and sources. Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces that change seasonally with variable surface water and groundwater levels. However, few studies have directly quantified dissolved organic matter (DOM) release and greenhouse gas (CO 2 , CH 4 ) fluxes from wetland soils along terrestrial-aquatic interfaces as they are seasonally re-saturated by groundwater. To estimate groundwater-mediated soil DOM and gas fluxes, we performed laboratory simulations of vertical groundwater rise on intact soil cores collected from four Delmarva bay wetlands located in the Mid-Atlantic United States. At each wetland, one core was collected from within the wetland basin and the other from the transitional zone at the basin edge. Cores were re-saturated with groundwater over 15 days and then kept fully saturated for an additional 25 days. Source groundwater, soil porewater, and exfiltrated surface water samples were collected and analyzed for pH, ORP, DOM concentration, and DOM optical indices. In both the wetland and transition zone cores, porewater DOM concentrations increased over the wet up and were sustained during prolonged saturation. Optical indices shifted from recently produced, microbial-like signatures towards aromatic, terrestrial-like signatures. Fluxes of CO 2 decreased as the duration of soil saturation increased and soil cores switched from CH 4 sinks to sources upon full soil core saturation. Results indicate that groundwater rise sustains carbon mobilization from soils in wetland-dominated landscapes, emphasizing the need to understand how climate-driven changes to groundwater dynamics may affect carbon fluxes along terrestrial-aquatic interfaces.

Delaware, Maryland↗
USGS2024

Biocrusts modulate carbon losses under warming across global drylands: A bayesian meta-analysis

Biocrusts are critical biological components of drylands and play an important role in soil carbon (C) cycling. However, the effect of biocrusts on soil CO 2 exchange across global gradients of temperature and moisture is poorly understood. Moreover, their response to climate change remains highly uncertain. Bayesian hierarchical meta-analyses were performed on 47 published studies to quantify the impact of biocrusts on net soil exchange (NSE) of carbon- the difference between respiration and photosynthesis. Meta-analyses were also used on 23 studies to examine the effects of experimental warming on NSE in biocrusts. Meta-regressions further explored the thermal and wetness sensitivities of biocrust NSE and potential adaptation of biocrust responses to climate change. The development of biocrusts in dryland soils significantly increased NSE by 66.5 [22.2, 112.2] g C m −2 yr −1 , despite seasonal fluctuations, indicating a net loss of carbon to the atmosphere. Experimental warming, on average, increased biocrust NSE by 22.9 [-0.1, 40.8] g C m −2 yr −1 per °C. However, across the spatial climate gradient, aridity limited the effects of warming, while high temperature decreased the thermal sensitivity of biocrust NSE, thus supporting the thermal adaptation of biocrusts. These results emphasize the critical role of biocrusts in modulating soil carbon exchange in response to climate warming across drylands, with particularly high thermal sensitivity in cool and moist regions. This highlights the need to incorporate biocrusts into global carbon budgets and models for a comprehensive understanding of their impact on the carbon cycle.

Soil Biology and Biogeochemistry↗
USGS1997

Chemical characteristics of particulate, colloidal, and dissolved organic material in Loch Vale Watershed, Rocky Mountain National Park

The chemical relationships among particulate and colloidal organic material and dissolved fulvic acid were examined in an alpine and subalpine lake and two streams in Loch Vale Watershed, Rocky Mountain National Park. The alpine lake, Sky Pond, had the lowest dissolved organic carbon (DOC) (0.37 mgC/L), the highest particulate carbon (POC) (0.13 mgC/L), and high algal biomass. The watershed of Sky Pond is primarily talus slope, and DOC and POC may be autochthonous. Both Andrews Creek and Icy Brook gain DOC as they flow through wet sedge meadows. The subalpine lake, The Loch, receives additional organic material from the surrounding forest and had a higher DOC (0.66 mgC/L). Elemental analysis, stable carbon isotopic compositon, and 13C-NMR characterization showed that: 1) particulate material had relatively high inorganic contents and was heterogeneous in compositon, 2) colloidal material was primarily carbohydrate material with a low inorganic content at all sites; and 3) dissolved fulvic acid varied in compositon among sites. The low concentration and carbohydrate-rich character of the colloidal material suggests that this fraction is labile to microbial degradation and may be turning over more rapidly than particulate fractions or dissolved fulvic acid. Fulvic acid from Andrews Creek had the lowest N content and aromaticity, whereas Sky Pond fulvic acid had a higher N content and lower aromaticity than fulvic acid from The Loch. The UV-visible spectra of the fulvic acids demonstrate that variation in characteristics with sources of organic carbon can explain to some extent the observed nonlinear relationship between UV-B extinction coefficients and DOC concentrations in lakes.

Colorado↗
USGS1997

Assessment of soil calcium status in red spruce forests in the northeastern United States

Long-term changes in concentrations of available Ca in soils of red spruce forests have been documented, but remaining questions about the magnitude and regional extent of these changes have precluded an assessment of the current and future status of soil Ca. To address this problem, soil samples were collected in 1992-93 from 12 sites in New York, Vermont, New Hampshire, and Maine to provide additional data necessary to synthesize all available research results on soil Ca in red spruce forests. Sites were chosen to encompass the range of environmental conditions experienced by red spruce. Concentrations of exchangeable Ca ranged from 2.13 to 21.6 cmol(c) kg-1 in the Oa horizon, and from 0.11 to 0.68 cmol(c) kg-1 in the upper 10 cm of the B horizon. These measurements expanded the range of exchangeable Ca reported in the literature for both horizons in northeastern red spruce forests. Exchangeable Ca was the largest Ca fraction in the forest floor at most sites (92% of acid-extractable Ca), but mineral Ca was the largest fraction at the three sites that also had the highest mineral-matter concentrations. The primary factor causing variability in Ca concentrations among sites was the mineralogy of parent material, but exchangeable concentrations in the B horizon of all sites were probably reduced by acidic deposition. Because the majority of Ca in the forest floor is in a readily leachable form, and Ca inputs to the forest floor from the mineral soil and atmospheric deposition have been decreasing in recent decades, the previously documented decreases in Ca concentrations in the forest floor over previous decades may extend into the future.

Biogeochemistry↗
USGS1997

Assessing hydrogeochemical heterogeneity in natural and constructed wetlands

While 'water quality function' is cited as an important wetland function to design for and preserve, we demonstrate that the scale at which hydrochemical samples are collected can significantly influence interpretations of biogeochemical processes in wetlands. Subsurface, chemical profiles for both nutrients and major ions were determined at a site in southwestern Wisconsin that contained areas of both natural and constructed wetlands. Sampling was conducted on three different scales: (1) a large scale (3 m between sampling points), (2) an intermediate scale (0.15 m between sampling points), and (3) a small scale (1.5 cm between sampling points). In most cases, significant vertical heterogeneity was observed at the 0.15 m scale, which was much larger than previously reported for freshwater wetlands and not detected by sampling water table wells screened over the same interval. However, profiles of ammonia and total phosphorus showed tenfold changes in the upper 0.2 meters of the saturated zone when sampled at the small (1.5 cm) scale, that was not depicted by sampling at the intermediate scale. At the intermediate scale of observation, one constructed wetland site differed geochemically from the natural wetlands and the other constructed wetland site due to application of off-site salvaged marsh surface and downward infiltration of rain. While important differences in dissolved inorganic phosphorus and dissolved inorganic carbon concentrations existed between the constructed wetland and the natural wetlands, we also observed substantial differences between the natural wetland sites for these constituents. A median-polishing analysis of our data showed that temporal variations in constituent concentrations within profiles, although extensively recognized in the literature, were not as important as spatial variability.

Biogeochemistry↗
USGS1998

Peat characteristics and groundwater geochemistry of calcareous fens in the Minnesota River Basin, U.S.A

Calcareous fens in Minnesota are spring-seepage peatlands with adistinctive flora of rare calciphilic species. Peat characteristics andgroundwater geochemistry were determined for six calcareous fens in theMinnesota River Basin to better understand the physical structure andchemical processes associated with stands of rare vegetation. Onset of peataccumulation in three of the fens ranged from about 4,700 to 11,000 14 C yrs BP and probably resulted from acombination of climate change and local hydrogeologic conditions. Most peatcores had a carbonate-bearing surface zone with greater than 10%carbonates (average 27%, dry wt basis), an underlyingcarbonate-depleted zone with 10% or less carbonates (average4%), and a carbonate-bearing lower zone again with greater than10% carbonates (average 42%). This carbonate zonation washypothesized to result from the effect of water-table level on carbonateequilibria: carbonate precipitation occurs when the water table is above acritical level, and carbonate dissolution occurs when the water table islower. Other processes that changed the major ion concentrations inupwelling groundwater include dilution by rain water, sulfate reduction orsulfide oxidation, and ion adsorption or exchange. Geochemical modelingindicated that average shallow water in the calcareous fens during the studyperiod was groundwater mixed with about 6 to 13% rain water.Carbonate precipitation in the surface zone of calcareous fens could bedecreased by a number of human activities, especially those that lower thewater table. Such changes in shallow water geochemistry could alter thegrowing conditions that apparently sustain rare fen vegetation.

Minnesota↗
USGS1998

Retention of NO3/- in an upland stream environment: A mass balance approach

Models of the effects of atmospheric N deposition in forested watersheds have not adequately accounted for the effects of aquatic and near-stream processes on the concentrations and loads of NO3/- in surface waters. This study compared the relative effects of aquatic and near-stream processes with those from the terrestrial ecosystem on the retention and transport of NO3/- in two contrasting stream reaches of the Neversink River, a forested watershed in the Catskill Mountains of New York that receives among the highest load of atmospheric N deposition in the northeastern United States. Stream water samples were collected every two hours and ground-water and tributary samples were collected daily at base flow conditions during four 48-hour periods from April to October 1992, and NO3/- mass balances were calculated for each site. Results indicated diurnal variations in stream NO3/- concentrations in both reaches during all four sampling periods; this is consistent with uptake of NO3/- by photoautotrophs during daylight hours. Mass-balance results revealed significant stream reach losses of NO3/- at both sites during all sampling periods. The diurnal variations in NO3/- concentrations and the retention of NO3/- relative to terrestrial contributions to the stream reaches were greater downstream than upstream because physical factors such as the head gradients of inflowing ground water and the organic matter content of sediment are more favorable to uptake and denitrification downstream. The mass retention of NO3/- increased as the mean 48-hr stream discharge increased at each site, indicating that the responsible processes are dependent on NO3/- supply. Low stream temperatures during the April sampling period, however, probably reduced the rate of retention processes, resulting in smaller losses of NO3/- than predicted from stream discharge alone. Water samples collected from the stream, the hyporheic zone, and the alluvial ground water at sites in both reaches indicated that the net effect of hyporheic processes on downstream NO3/- transport ranged from conservative mixing to complete removal by denitrification. The relative effects of biological uptake and denitrification as retention mechanisms could not be quantified, but the results indicate that both processes are significant. These results generally confirm that aquatic and near-stream processes cause significant losses of NO3/- in the Neversink River, and that the losses by these processes at downstream locations can exceed the NO3/- contributions to the stream from the terrestrial environment during summer and fall base-flow conditions. Failure to consider these aquatic and near-stream processes in models of watershed response to atmospheric N deposition could result in underestimates of the amount of NO3/- leaching from forested ecosystems and to an inability to unequivocally relate geographic differences in NO3/- concentrations of stream waters to corresponding differences in terrestrial processes.

Biogeochemistry↗
USGS1998

Trophic transfer of methyl mercury in the northern Florida Everglades

There are spatial differences in methyl mercury (MeHg) concentrations in biota in Water Conservation Areas 2 and 3 in the Everglades, with higher concentrations generally found in the southern areas. Fish and hemipterans had the most MeHg on a wet weight basis, with levels exceeding 30 ng g-1. The magnitude of MeHg accumulation in biota varies seasonally and does not always appear to be associated with changes in water column concentration. This is exemplified by periphyton, the base of the foodweb in the Everglades, at a high nutrient sampling site. Although limited in scope, MeHg concentrations presented for biota provide insight into beginning to understand the dynamic nature of Hg transfer in the Everglades foodweb on a spatial and temporal basis.

Biogeochemistry↗