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USGS2016

Documentation of a groundwater flow model developed to assess groundwater availability in the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to North Carolina

The U.S. Geological Survey developed a groundwater flow model for the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to northeastern North Carolina as part of a detailed assessment of the groundwater availability of the area and included an evaluation of how these resources have changed over time from stresses related to human uses and climate trends. The assessment was necessary because of the substantial dependency on groundwater for agricultural, industrial, and municipal needs in this area. The three-dimensional, groundwater flow model developed for this investigation used the numerical code MODFLOW–NWT to represent changes in groundwater pumping and aquifer recharge from predevelopment (before 1900) to future conditions, from 1900 to 2058. The model was constructed using existing hydrogeologic and geospatial information to represent the aquifer system geometry, boundaries, and hydraulic properties of the 19 separate regional aquifers and confining units within the Northern Atlantic Coastal Plain aquifer system and was calibrated using an inverse modeling parameter-estimation (PEST) technique. The parameter estimation process was achieved through history matching, using observations of heads and flows for both steady-state and transient conditions. A total of 8,868 annual water-level observations from 644 wells from 1986 to 2008 were combined into 29 water-level observation groups that were chosen to focus the history matching on specific hydrogeologic units in geographic areas in which distinct geologic and hydrologic conditions were observed. In addition to absolute water-level elevations, the water-level differences between individual measurements were also included in the parameter estimation process to remove the systematic bias caused by missing hydrologic stresses prior to 1986. The total average residual of –1.7 feet was normally distributed for all head groups, indicating minimal bias. The average absolute residual value of 12.3 feet is about 3 percent of the total observed water-level range throughout the aquifer system. Streamflow observation data of base flow conditions were derived for 153 sites from the U.S. Geological Survey National Hydrography Dataset Plus and National Water Information System. An average residual of about –8 cubic feet per second and an average absolute residual of about 21 cubic feet per second for a range of computed base flows of about 417 cubic feet per second were calculated for the 122 sites from the National Hydrography Dataset Plus. An average residual of about 10 cubic feet per second and an average absolute residual of about 34 cubic feet per second were calculated for the 568 flow measurements in the 31 sites obtained from the National Water Information System for a range in computed base flows of about 1,141 cubic feet per second. The numerical representation of the hydrogeologic information used in the development of this regional flow model was dependent upon how the aquifer system and simulated hydrologic stresses were discretized in space and time. Lumping hydraulic parameters in space and hydrologic stresses and time-varying observational data in time can limit the capabilities of this tool to simulate how the groundwater flow system responds to changes in hydrologic stresses, particularly at the local scale.

Delaware, Maryland, New Jersey, New York, North Ca↗

USGS2020

Groundwater quality in the Redding–Red Bluff shallow aquifer study unit of the northern Sacramento Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Private domestic and small system drinking water wells in the Redding–Red Bluff study unit primarily draw from shallow aquifers which are the target for this assessment.

California↗

USGS2010

Conceptual understanding and groundwater quality of selected basin-fill aquifers in the Southwestern United States

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey has been conducting a regional analysis of water quality in the principal aquifer systems in the southwestern United States (hereinafter, “Southwest”) since 2005. Part of the NAWQA Program, the objective of the Southwest Principal Aquifers (SWPA) study is to develop a better understanding of water quality in basin-fill aquifers in the region by synthesizing information from case studies of 15 basins into a common set of important natural and human-related factors found to affect groundwater quality. The synthesis consists of three major components: 1. Summary of current knowledge about the groundwater systems, and the status of, changes in, and influential factors affecting quality of groundwater in basin-fill aquifers in 15 basins previously studied by NAWQA (this report). 2. Development of a conceptual model of the primary natural and human-related factors commonly affecting groundwater quality, thereby building a regional understanding of the susceptibility and vulnerability of basin-fill aquifers to contaminants. 3. Development of statistical models that relate the concentration or occurrence of specific chemical constituents in groundwater to natural and human-related factors linked to the susceptibility and vulnerability of basin-fill aquifers to contamination. Basin-fill aquifers occur in about 200,000 mi 2 of the 410,000 mi 2 SWPA study area and are the primary source of groundwater supply for cities and agricultural communities. Four of the principal aquifers or aquifer systems of the United States are included in the basin-fill aquifers of the study area: (1) the Basin and Range basin-fill aquifers in California, Nevada, Utah, and Arizona; (2) the Rio Grande aquifer system in New Mexico and Colorado; (3) the California Coastal Basin aquifers; and (4) the Central Valley aquifer system in California. Because of the generally limited availability of surface-water supplies in the arid to semiarid climate, cultural and economic activities in the Southwest are particularly dependent on supplies of good-quality groundwater. Irrigation and public-supply withdrawals from basin-fill aquifers in the study area account for about one quarter of the total withdrawals from all aquifers in the United States. Many factors influence the quality of groundwater in the 15 case-study basins, but some common factors emerge from the basin summaries presented in this report. These factors include the chemical composition of the recharge water, consolidated rock geology and composition of aquifer materials derived from consolidated rock, and land and water use. The major water-quality issues in many of the developed case-study basins are increased concentrations of dissolved solids, nitrate, and VOCs in groundwater as a result of human activities. The information presented and the citations listed in this report serve as a resource for those interested in the groundwater-flow systems in the NAWQA case-study basins. The summaries of water-development history, hydrogeology, conceptual understanding of the groundwater system under both predevelopment and modern conditions, and effects of natural and human-related factors on groundwater quality presented in the sections on each basin also serve as a foundation for the synthesis and modeling phases of the SWPA regional study.

Arizona, California, Colorado, Nevada, New Mexico,↗

USGS2023

Estimating streambed hydraulic conductivity for selected streams in the Mississippi Alluvial Plain using continuous resistivity profiling methods—Delta region

Introduction The Mississippi Alluvial Plain is one of the most important agricultural regions in the United States, and crop productivity relies on groundwater irrigation from an aquifer system whose full capacity is unknown. Groundwater withdrawals from the Mississippi River Valley alluvial aquifer have resulted in substantial groundwater-level declines and reductions in base flow in streams within the Mississippi Alluvial Plain. These effects are limiting well production and threatening future water availability in the region. A comprehensive assessment of water availability in the Mississippi Alluvial Plain is critically important for making well-informed management decisions about sustainability, establishing best practices for water use, and predicting changes to water levels in the Mississippi Alluvial Plain over the next 50–100 years. The first step in the new regional modeling effort was to run the existing Mississippi Embayment Regional Aquifer Study (MERAS) model and perform data-worth and uncertainty analyses to prioritize data collection efforts to improve model forecasts. Parameter estimation indicated that streambed conductance was one of the variables that the model was most sensitive to, but little data were available to constrain those general estimates. From this characterization of the existing data, a map of the streams that the MERAS model was most sensitive to was created by the U.S. Geological Survey to guide the collection of 862 kilometers of waterborne resistivity surveys within the Delta region of Mississippi to characterize streambed lithology. This technique characterizes the streambed itself and the 15–30 meters below the streambed that control the exchange of water between the stream and the alluvial aquifer. These data can be used to map changes in the lithology of the streambed and identify areas of potential groundwater/surface-water exchange. Additionally, electrical and nuclear well logs from the study area were compared to facilitate the development of a petrophysical relation between the waterborne resistivity data and hydraulic conductivity. Resistivity values may then be used as a cost-effective way to approximate aquifer hydraulic conductivity distributions for use in regional groundwater models.

Arkansas, Louisiana, Mississippi↗

USGS2018

Groundwater-level analysis of selected wells in the Hoosic River Valley near Hoosick Falls, New York, for aquifer framework and properties

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, analyzed groundwater levels, drilling record logs, and field water-quality data from selected wells, and the surficial geology in the Hoosic River valley south of the village of Hoosick Falls, New York, to provide information about the framework and properties of a confined aquifer. The aquifer, which consists of ice-contact sand and gravel overlain by lacustrine clay and silt, was evaluated by the New York State Department of Environmental Conservation as part of their investigation of alternate water supplies for the village whose wellfield has been affected by perfluorooctanoic acid. Wells inventoried in the study area were classified as confined, water table, or transitional between the two aquifer conditions. Groundwater levels in three confined-aquifer wells and a transitional-aquifer well responded to pumping of a test production well finished in the confined aquifer. Groundwater levels in a water-table well showed no detectable water-level change in response to test-well pumping. Analysis of drawdown and recovery data from the three confined-aquifer wells and a transitional-aquifer well through the application of the Theis type-curve method provided estimates of aquifer properties. Representation of a constant-head boundary in the analysis where an unnamed pond and fluvial-terrace deposits abut the valley wall resulted in satisfactory matches of the Theis type curves with the observed water-level responses. Aquifer transmissivity estimates ranged from 1,160 to 1,370 feet squared per day. Aquifer storativity estimates ranged from 5.2×10 –5 to 1.1×10 –3 and were consistent with the inferred degree of confinement and distance from the represented recharge boundary.

New York↗

USGS2013

A combined radio- and stable-isotopic study of a California coastal aquifer system

Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na + , K + , Mg 2+ , Ca 2+ ) and anions (Cl − , SO 4 2− ), silica, alkalinity, select trace elements (Ba, B, Sr), dissolved oxygen, stable isotopes of hydrogen (δD), oxygen (δ 18 O), dissolved inorganic carbon (δ 13 C DIC ), and radioactive isotopes ( 3 H, 222 Rn and 223,224,226,228 Ra). In the study area, groundwater may consist of a complex mixture of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some wells, Cl − concentrations attained seawater-like values and in conjunction with isotopically heavier δ 18 O values, these tracers provide information on the extent of seawater intrusion and/or mixing with oil-field brines. Groundwater 3 H above 1 tritium unit (TU) was observed only in a few select wells close to the Dominguez Gap area and most other well groundwater was aged pre-1952. Based on an initial 14 C value for the study site of 90 percent modern carbon (pmc), groundwater age estimates likely extend beyond 20 kyr before present and confirm deep circulation of some native groundwater through multiple aquifers. Enriched values of groundwater δ 13 C DIC in the absence of SO 4 2− imply enhanced anaerobic microbial methanogenesis. While secular equilibrium was observed for 234 U/ 238 U (activity ratios ~1) in host matrices, strong isotopic fractionation in these groundwater samples can be used to obtain information of adsorption/desorption kinetics. Calculated Ra residence times are short, and the associated desorption rate constant is about three orders of magnitude slower than that of the adsorption rate constant. Combined stable- and radio-isotopic results provide unique insights into aquifer characteristics, such as geochemical cycling, rock/water interactions, and subsurface transport and mixing.

California↗

USGS2007

Arsenic attenuation by oxidized aquifer sediments in Bangladesh

Recognition of arsenic (As) contamination of shallow fluvio-deltaic aquifers in the Bengal Basin has resulted in increasing exploitation of groundwater from deeper aquifers that generally contain low concentrations of dissolved As. Pumping-induced infiltration of high-As groundwater could eventually cause As concentrations in these aquifers to increase. This study investigates the adsorption capacity for As of sediment from a low-As aquifer near Dhaka, Bangladesh. A shallow, chemically-reducing aquifer at this site extends to a depth of 50 m and has maximum As concentrations in groundwater of 900 μg/L. At depths greater than 50 m, geochemical conditions are more oxidizing and groundwater has < 5 μg/L As. There is no thick layer of clay at this site to inhibit vertical transport of groundwater. Arsenite [As(III)] is the dominant oxidation state in contaminated groundwater; however, data from laboratory batch experiments show that As(III) is oxidized to arsenate [As(V)] by manganese (Mn) minerals that are present in the oxidized sediment. Thus, the long-term viability of the deeper aquifers as a source of water supply is likely to depend on As(V) adsorption. The adsorption capacity of these sediments is a function of the oxidation state of As and the concentration of other solutes that compete for adsorption sites. Arsenite that was not oxidized did adsorb, but to a much lesser extent than As(V). Phosphate (P) caused a substantial decrease in As(V) adsorption. Increasing pH and concentrations of silica (Si) had lesser effects on As(V) adsorption. The effect of bicarbonate (HCO 3 ) on As(V) adsorption was negligible. Equilibrium constants for adsorption of As(V), As(III), P, Si, HCO 3 , and H were determined from the experimental data and a quantitative model developed. Oxidation of As(III) was modeled with a first-order rate constant. This model was used to successfully simulate As(V) adsorption in the presence of multiple competing solutes. Results from these experiments show that oxidized sediments have a substantial but limited capacity for removal of As from groundwater.

Dhaka↗

USGS2023

One Ranney well can make a difference: The impacts of a radial collector well on groundwater level and quality in the Cedar River alluvial aquifer

The City of Cedar Rapids, Iowa, depends on groundwater from the Cedar River alluvial aquifer for residential and industrial use. In 2020, the city completed an additional radial collector well, or Ranney well, and was concerned that pumping from the well at high rates may lower water level elevations in the aquifer, reduce yields from nearby production wells, and change the quality of produced water. During an operational test of the well's pumps, the U.S. Geological Survey and the city collected water level and water quality data to evaluate the effects of increased pumping rates on the aquifer and nearby production wells. Results indicated that a high rate of pumping from the new well caused sustained declines in water levels near the well and other nearby production wells, and, if maintained, the aquifer water level in the vicinity would continue to decline to levels observed during the 2012 drought. Aquifer specific conductance and temperature were altered and matched trends and values of the river, and river-to-well travel time was shortened from 7-17 days to about 3 days. Results may also provide insights to other municipal water resource managers when considering wellfield design, production expectations, and long-term management strategies for radial collector well production during drought, low streamflow, and times when high concentrations of nitrate-N or organic pesticide compounds in the river may limit production options.

Iowa↗

USGS1996

Kinetic and mineralogic controls on the evolution of groundwater chemistry and 87Sr/86Sr in a sandy silicate aquifer, northern Wisconsin, USA

Substantial flowpath-related variability of 87Sr/86Sr is observed in groundwaters collected from the Trout Lake watershed of northern Wisconsin. In the extensive shallow aquifer composed of sandy glacial outwash, groundwater is recharged either by seepage from lakes or by precipitation that infiltrates the inter-lake uplands. 87Sr/86Sr of groundwater derived mainly as seepage from a precipitation-dominated lake near the head of the watershed decreases with progressive water chemical evolution along its flowpath due primarily to enhanced dissolution of relatively unradiogenic plagioclase. In contrast, 87Sr/86Sr of groundwater derived mainly from precipitation that infiltrates upland areas is substantially greater than that of precipitation collected from the watershed, due to suppression of plagioclase dissolution together with preferential leaching of Sr from radiogenic phases such as K-feldspar and biotite. The results of a column experiment that simulated the effects of changing residence time of water in the aquifer sand indicate that mobile waters obtain relatively unradiogenic Sr, whereas stagnant waters obtain relatively radiogenic Sr. Nearly the entire range of strontium-isotope composition observed in groundwaters from the watershed was measured in the experimental product waters. The constant mobility of water along groundwater recharge flowpaths emanating from the lakes promotes the dissolution of relatively unradiogenic plagioclase, perhaps due to effective dispersal of clay mineral nuclei resulting from dissolution reactions. In contrast, episodic stagnation in the unsaturated zone along the upland recharge flowpaths suppresses plagioclase dissolution, perhaps due to accumulation of clay mineral nuclei on its reactive surfaces. Differences in redox conditions along these contrasting flowpaths probably enhance the observed differences in strontium isotope behavior. This study demonstrates that factors other than the calculated state of mineral saturation must be considered when attempting to simulate chemical evolution along flowpaths, and that reaction models must be able to incorporate changing contributions from reacting minerals in the calculations.

Geochimica et Cosmochimica Acta↗

USGS2017

Hydrogeology and simulation of groundwater flow and analysis of projected water use for the Canadian River alluvial aquifer, western and central Oklahoma

This report describes a study of the hydrogeology and simulation of groundwater flow for the Canadian River alluvial aquifer in western and central Oklahoma conducted by the U.S. Geological Survey in cooperation with the Oklahoma Water Resources Board. The report (1) quantifies the groundwater resources of the Canadian River alluvial aquifer by developing a conceptual model, (2) summarizes the general water quality of the Canadian River alluvial aquifer groundwater by using data collected during August and September 2013, (3) evaluates the effects of estimated equal proportionate share (EPS) on aquifer storage and streamflow for time periods of 20, 40, and 50 years into the future by using numerical groundwater-flow models, and (4) evaluates the effects of present-day groundwater pumping over a 50-year period and sustained hypothetical drought conditions over a 10-year period on stream base flow and groundwater in storage by using numerical flow models. The Canadian River alluvial aquifer is a Quaternary-age alluvial and terrace unit consisting of beds of clay, silt, sand, and fine gravel sediments unconformably overlying Tertiary-, Permian-, and Pennsylvanian-age sedimentary rocks. For groundwater-flow modeling purposes, the Canadian River was divided into Reach I, extending from the Texas border to the Canadian River at the Bridgeport, Okla., streamgage (07228500), and Reach II, extending downstream from the Canadian River at the Bridgeport, Okla., streamgage (07228500), to the confluence of the river with Eufaula Lake. The Canadian River alluvial aquifer spans multiple climate divisions, ranging from semiarid in the west to humid subtropical in the east. The average annual precipitation in the study area from 1896 to 2014 was 34.4 inches per year (in/yr). A hydrogeologic framework of the Canadian River alluvial aquifer was developed that includes the areal and vertical extent of the aquifer and the distribution, texture variability, and hydraulic properties of aquifer materials. The aquifer areal extent ranged from less than 0.2 to 8.5 miles wide. The maximum aquifer thickness was 120 feet (ft), and the average aquifer thickness was 50 ft. Average horizontal hydraulic conductivity for the Canadian River alluvial aquifer was calculated to be 39 feet per day, and the maximum horizontal hydraulic conductivity was calculated to be 100 feet per day. Recharge rates to the Canadian River alluvial aquifer were estimated by using a soil-water-balance code to estimate the spatial distribution of groundwater recharge and a water-table fluctuation method to estimate localized recharge rates. By using daily precipitation and temperature data from 39 climate stations, recharge was estimated to average 3.4 in/yr, which corresponds to 8.7 percent of precipitation as recharge for the Canadian River alluvial aquifer from 1981 to 2013. The water-table fluctuation method was used at one site where continuous water-level observation data were available to estimate the percentage of precipitation that becomes groundwater recharge. Estimated annual recharge at that site was 9.7 in/yr during 2014. Groundwater flow in the Canadian River alluvial aquifer was identified and quantified by a conceptual flow model for the period 1981–2013. Inflows to the Canadian River alluvial aquifer include recharge to the water table from precipitation, lateral flow from the surrounding bedrock, and flow from the Canadian River, whereas outflows include flow to the Canadian River (base-flow gain), evapotranspiration, and groundwater use. Total annual recharge inflows estimated by the soil-water-balance code were multiplied by the area of each reach and then averaged over the simulated period to produce an annual average of 28,919 acre-feet per year (acre-ft/yr) for Reach I and 82,006 acre-ft/yr for Reach II. Stream base flow to the Canadian River was estimated to be the largest outflow of groundwater from the aquifer, measured at four streamgages, along with evapotranspiration and groundwater use, which were relatively minor discharge components. Objectives for the numerical groundwater-flow models included simulating groundwater flow in the Canadian River alluvial aquifer from 1981 to 2013 to address groundwater use and drought scenarios, including calculation of the EPS pumping rates. The EPS for the alluvial and terrace aquifers is defined by the Oklahoma Water Resources Board as the amount of fresh water that each landowner is allowed per year per acre of owned land to maintain a saturated thickness of at least 5 ft in at least 50 percent of the overlying land of the groundwater basin for a minimum of 20 years. The groundwater-flow models were calibrated to water-table altitude observations, streamgage base flows, and base-flow gain to the Canadian River. The Reach I water-table altitude observation root-mean-square error was 6.1 ft, and 75 percent of residuals were within ±6.7 ft of observed measurements. The average simulated stream base-flow residual at the Bridgeport streamgage (07228500) was 8.8 cubic feet per second (ft 3 /s), and 75 percent of residuals were within ±30 ft 3 /s of observed measurements. Simulated base-flow gain in Reach I was 8.8 ft 3 /s lower than estimated base-flow gain. The Reach II water-table altitude observation root-mean-square error was 4 ft, and 75 percent of residuals were within ±4.3 ft of the observations. The average simulated stream base-flow residual in Reach II was between 35 and 132 ft 3 /s. The average simulated base-flow gain residual in Reach II was between 11.3 and 61.1 ft 3 /s. Several future predictive scenarios were run, including estimating the EPS pumping rate for 20-, 40-, and 50-year life of basin scenarios, determining the effects of current groundwater use over a 50-year period into the future, and evaluating the effects of a sustained drought on water availability for both reaches. The EPS pumping rate was determined to be 1.35 acre-feet per acre per year ([acre-ft/acre]/yr) in Reach I and 3.08 (acre-ft/acre)/yr in Reach II for a 20-year period. For the 40- and 50-year periods, the EPS rate was determined to be 1.34 (acre-ft/acre)/yr in Reach I and 3.08 (acre-ft/acre)/yr in Reach II. Storage changes decreased in tandem with simulated groundwater pumping and were minimal after the first 15 simulated years for Reach I and the first 8 simulated years for Reach II. Groundwater pumping at year 2013 rates for a period of 50 years resulted in a 0.2-percent decrease in groundwater-storage volumes in Reach I and a 0.6-percent decrease in the groundwater-storage volumes in Reach II. The small changes in storage are due to groundwater use by pumping, which composes a small percentage of the total groundwater-flow model budgets for Reaches I and II. A sustained drought scenario was used to evaluate the effects of a hypothetical 10-year drought on water availability. A 10-year period was chosen where the effects of drought conditions would be simulated by decreasing recharge by 75 percent. In Reach I, average simulated stream base flow at the Bridgeport streamgage (07228500) decreased by 58 percent during the hypothetical 10-year drought compared to average simulated stream base flow during the nondrought period. In Reach II, average simulated stream base flows at the Purcell streamgage (07229200) and Calvin streamgage (07231500) decreased by 64 percent and 54 percent, respectively. In Reach I, the groundwater-storage drought scenario resulted in a storage decline of 30 thousand acre-feet, or an average decline in the water table of 1.2 ft. In Reach II, the groundwater-storage drought scenario resulted in a storage decline of 71 thousand acre-feet, or an average decline in the water table of 2.0 ft.

Oklahoma↗

USGS2014

Assessing the magnitude and timing of anthropogenic warming of a shallow aquifer: example from Virginia Beach, USA

Groundwater temperature measurements in a shallow coastal aquifer in Virginia Beach, Virginia, USA, suggest groundwater warming of +4.1 °C relative to deeper geothermal gradients. Observed warming is related to timing and depth of influence of two potential thermal drivers—atmospheric temperature increases and urbanization. Results indicate that up to 30 % of groundwater warming at the water table can be attributed to atmospheric warming while up to 70 % of warming can be attributed to urbanization. Groundwater temperature readings to 30-m depth correlate positively with percentage of impervious cover and negatively with percentage of tree canopy cover; thus, these two land-use metrics explain up to 70 % of warming at the water table. Analytical and numerical modeling results indicate that an average vertical groundwater temperature profile for the study area, constructed from repeat measurement at 11 locations over 15 months, is consistent with the timing of land-use change over the past century in Virginia Beach. The magnitude of human-induced warming at the water table (+4.1 °C) is twice the current seasonal temperature variation, indicating the potential for ecological impacts on wetlands and estuaries receiving groundwater discharge from shallow aquifers.

Virginia↗

USGS2013

Geochemical, isotopic, and dissolved gas characteristics of groundwater in a fractured crystalline-rock aquifer, Savage Municipal Well Superfund site, Milford, New Hampshire, 2011

Tetrachloroethylene (PCE), a volatile organic compound, was detected in groundwater from deep (more than (>) 300 feet (ft) below land surface) fractures in monitoring wells tapping a crystalline-rock aquifer beneath operable unit 1 (OU1) of the Savage Municipal Well Superfund site (Weston, Inc., 2010). Operable units define remedial areas of contaminant concern. PCE contamination within the fractured-rock aquifer has been designated as a separate operable unit, operable unit 3 (OU3; Weston, Inc., 2010). PCE contamination was previously detected in the overlying glacial sand and gravel deposits and basal till, hereafter termed the Milford-Souhegan glacial-drift (MSGD) aquifer (Harte, 2004, 2006). Operable units 1 and 2 encompass areas within the MSGD aquifer, whereas the extent of the underlying OU3 has yet to be defined. The primary original source of contamination has been identified as a former manufacturing facility—the OK Tool manufacturing facility; hence OU1 sometimes has been referred to as the OK Tool Source Area (New Hampshire Department of Environmental Services, undated). A residential neighborhood of 30 to 40 houses is located in close proximity (one-quarter of a mile) from the PCE-contaminated monitoring wells. Each house has its own water-supply well installed in similar rocks as those of the monitoring wells, as indicated by the New Hampshire State geologic map (Lyons and others, 1997). An investigation was initiated in 2010 by the U.S. Environmental Protection Agency (USEPA) region 1, and the New Hampshire Department of Environmental Services (NHDES) to assess the potential for PCE transport from known contaminant locations (monitoring wells) to the residential wells. The U.S. Geological Survey (USGS) and the NHDES entered into a cooperative agreement in 2011 to assist in the evaluation of PCE transport in the fractured-rock aquifer. Periodic sampling over the last decade by the USEPA and NHDES has yet to detect PCE in groundwater from the residential-supply wells (as of 2012). However, part of assessing the potential for PCE transport involves understanding the origin of the groundwater in the monitoring and residential wells. One of the tools in delineating the movement of groundwater to wells, particularly in complex, highly heterogeneous fractured-rock aquifers, is the understanding of the geochemical and isotopic composition of groundwater (Lipfert and Reeve, 2004; Harte and others, 2012). This report summarizes findings from analyses of geochemical, isotopic, and dissolved gas characteristics of groundwater. Samples of groundwater were collected in 2011 from monitoring wells and nearby residential-supply wells in proximity to OU1.

New Hampshire↗

USGS2021

Time-domain electromagnetic soundings and passive-seismic measurements for delineation of saline groundwater in the Genesee Valley-fill aquifer system, western New York, 2016–17

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, used noninvasive surface geophysics in the investigation of the distribution of saline groundwater in the valley-fill aquifer system of the Genesee River Valley near the former Retsof salt mine in western New York. In 1994, the Retsof salt mine, the largest of its kind in the western hemisphere, underwent a catastrophic roof collapse that resulted in groundwater inflow from the valley-fill aquifer system and bedrock fracture zones into the mine through two bedrock-rubble chimneys and the subsequent dissolution and filling of the mine with saturated brine. Since the early 2000s, except for a period of remedial pumping in 2006 to 2013, high-salinity water has migrated upward through the rubble chimneys into the basal part the aquifer system. The extent of saline-water migration within the aquifer system had not been evaluated since the end of remedial pumping when all the monitoring wells were grouted shut and abandoned. Installation of a monitoring-well network would be expensive and difficult given the thickness and heterogeneous character of valley fill. An investigation of the current extent of saline water in the aquifer system was warranted because the basal part of the aquifer is shallow to the north and it is used for water supply. In fall 2016 and fall 2017, the U.S. Geological Survey collected time-domain electromagnetic soundings at 105 sites along 13 cross-valley transects north and south of the mine-collapse area, east of Piffard, and on the Fowlerville Moraine. The time-domain electromagnetic soundings were colocated with passive-seismic measurements to estimate the bedrock-surface elevation through use of a regression equation developed from measurements at well sites with reported bedrock depths in the study area. An integrated analysis of the time-domain electromagnetic soundings with the depth-to-bedrock estimates, well logs, and past chloride-monitoring data suggests the presence of a zone of high electrical conductivity associated with saline water in the confined lower part of the valley-fill aquifer system. This high-salinity zone delineated in the lower confined aquifer extends from the mine-collapse area northward for more than 2.5 miles (4.0 kilometers). The chloride concentration in groundwater within this high-conductivity zone may be about 20,000 milligrams per liter. Saline water flowing upward through the bedrock-rubble chimneys and mixing with northward groundwater flow in the lower confined aquifer likely is a major source of chlorides for this high-conductivity zone. The northern extent of the zone is unclear because of the presence of highly saline water zones that were delineated by time-domain electromagnetic soundings in the lower confined aquifer and uppermost bedrock and are probably associated with historic salt-solution wells in Piffard or possibly sourced from natural brine pools.

New York↗

USGS2018

Status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers, Houston-Galveston region, Texas, 2018

Since the early 1900s, most of the groundwater withdrawals in the Houston-Galveston region, Texas, have been from the three primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers. Withdrawals from these aquifers are used for municipal supply, industrial, and irrigation purposes. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2018 groundwater-level altitudes (represented by measurements made during December 2017 through March 2018) and long-term groundwater-level changes for the Chicot, Evangeline, and Jasper aquifers. In 2018, groundwater-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) to 200 ft above datum. The 1977–2018 groundwater-level-change contours for the Chicot aquifer depict a large area of decline in groundwater-level altitudes (120 ft) in northwestern Harris County. The largest rise in groundwater-level altitudes in the Chicot aquifer from 1977 to 2018 (180 ft) was in southeastern Harris County. Groundwater-level-altitude contours for the Evangeline aquifer ranged from 250 ft below datum to 200 ft above datum in 2018. The 1977–2018 groundwater-level-change contours for the Evangeline aquifer depict broad areas where groundwater-level altitudes either declined or rose. The largest decline in groundwater-level altitudes (320 ft) was in southern Montgomery County. The largest rise in groundwater-level altitudes in the Evangeline aquifer from 1977 to 2018 (240 ft) was in southeastern Harris County. In 2018, groundwater-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum to 200 ft above datum. The 2000–18 groundwater-level-change contours for the Jasper aquifer depict groundwater-level declines throughout most of the study area where groundwater-level-altitude data from the Jasper aquifer were collected, with the largest decline (200 ft) in southern Montgomery County.

Texas↗

USGS1989

Hydrology of the Oakley Fan Area, south-central Idaho

The Oakley Fan area is a broad, crescent-shaped lowland along the southern margin of the Snake River Plain in south-central Idaho. Intensive groundwater development for irrigation has resulted in rapid water-level declines and, as a consequence, designation by the State of four Critical Groundwater Areas. Principal aquifers are in limestone, rhyolite, basalt, and alluvium. Annual water-level declines range from 3 ft to about 5 ft. Recharge to the groundwater system is from infiltration of surface water used for irrigation, precipitation on the surrounding mountains, infiltration of localized runoff, and upward movement of thermal water. Groundwater pumpage during the period 1979-84 averaged 173,000 acre-ft/yr. Surface and groundwater is predominantly a calcium bicarbonate type with variable concentrations of dissolved solids. Comparisons of silica and chloride concentrations and isotopic composition of groundwater were useful in determining areal extent of aquifers and movement of groundwater. A three-dimensional mathematical model of the Oakley Fan area was developed. The aquifer system was simulated in three phases: (1) Average 1979-84 hydrologic conditions, (2) 1910 hydrologic conditions, and (3) 1910-84 hydrologic conditions. Model simulation indicated that, for the period 1945-79, subsurface outflow declined from 327,000 acre-ft/yr to 215,000 acre-ft/yr. Simulated groundwater pumpage during the period 1945-79 was 3,000,000 acre-ft; simulated change in storage was 250,000 acre-ft. Simulations with the model approximate natural conditions and probably can be used to evaluate future changes in the hydrologic system.

Idaho↗

USGS2007

U/Th series radionuclides as coastal groundwater tracers

The study of coastal groundwater has recently surfaced as an active interdisciplinary area of research, driven foremost by its importance as a poorly quantified pathway for subsurface material transport into coastal ecosystems. Key issue in coastal groundwater research include a complete geochemical characterization of the groundwater(s); quantification of the kinetics of subsurface transport, including rock-water interactions; determination of groundwater ages; tracing of groundwater discharge into coastal waters using radiochemical fingerprints; and an assessment of the potential ecological impact of such subsurface flow to a reviving water body. For such applications, the isotopic systemics of select naturally occurring radionucludes in the U/Th series has proven to be particularly useful. These radionuclides (e.g., U, Th, Ram and Rn) are ubiquitous in all groundwaters ad are represented by several isotopes with widely different half-lives and chemistries (Figure 1). As a result, varied biogeochemical processes occurring over a broad range of time scales can be studied. In source rock, most U/Th series isotopes in secular equilibrium; that is, the rate of decay of a daughter isotope is equal to that of it radiogenic parent, and so will have equal activities (in this context, the specific activity is simply a measure of the amount of radioactivity per unit amount). In contrast, these nuclides exhibit strong fractionations within the surrounding groundwaters because of their respective physiochemical differences. Disequilibria in U/Th series radionuclides can thus be used to identify distinct water masses, quantify release rates from source rocks, assess groundwater migration rates, and assess groundwater discharge rates in coastal waters., Large isotopic variations also have the potential for providing precise fingerprints for groundwaters from specific aquifers and have been explored as a means for calculating groundwater ages and estuarine water mass transit times. The highly fractionated nature of U/Th series nuclides in groundwater is illustrated by the range in some measured activities. highest activities are typically observed for 222 Rn, reflecting the inert nature of this noble gas. Groundwater 222 Rn (t 1/2 =3.8) activities are thus controlled only by rapid in situ decay (Table 1) and production within host rocks, without the added complications of reversible removal via absorption or precipitation. Uranium, which is soluble as U(VI) in oxidizing waters, is present in intermediate activities in groundwaters that are moderated by redox-initiated removal onto aquifer rocks. The alkaline earth Ra and, to a greater extent, the less soluble actinide Th are readily removed from groundwater by water -- rock interactions and so are strongly depleted. Both of these elements have very short-lived as well as longer-lived isotopes, and so isotopes compositions reflect processes over a range of time scales. Many studies have evaluated and behavior of select radionuclides in groundwater and surface water systems. Recent advances in high-=precision mass spectrometry have opted new possibilities for more subtle interpretations in select long-lived U/Th series isotopes, such as U, Ra, Pa, and Th. However, these techniques have yet to be fully developed, ahns as a consequence, such data remain largely scarce and underutilized. Although many different approaches have been developed to study radionucluide behavior in groundwater, all are based on principles of radioactive production and decay and knowledge of source terms from weathering and recoil processes, as well as removal terms from the interaction with aquifer host rock surface by sorption and precipitation. This review is structured to present first a brief description of the background, driving forces, scales, and ecological significance of submarine groundwater discharge. Following this, a description of the geochemistry and behavior of select radionuclides in groundwater will be presented, and their application to tracing submarine groundwater discharge will be discussed.

Chemical Reviews↗

USGS2019

Status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers, Houston-Galveston region, Texas, 2019

Since the early 1900s, most of the groundwater withdrawals in the Houston-Galveston region, Texas, have been from the three primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers. Withdrawals from these aquifers are used for municipal supply, commercial and industrial use, and irrigation. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2019 groundwater-level altitudes (represented by measurements made during December 2018 through March 2019) and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers. In 2019, groundwater-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) to 200 ft above datum. The 1977–2019 groundwater-level-change contours for the Chicot aquifer depict a large area of decline in groundwater-level altitudes (100 ft) in northwestern Harris County. The largest rise in groundwater-level altitudes in the Chicot aquifer from 1977 to 2019 (200 ft) was in southeastern Harris County. In 2019, groundwater-level-altitude contours for the Evangeline aquifer ranged from 300 ft below datum to 200 ft above datum. The 1977–2019 groundwater-level-change contours for the Evangeline aquifer depict broad areas where groundwater-level altitudes either declined or rose. The largest decline in groundwater-level altitudes (280 ft) was in southern Montgomery and northern Harris Counties. The largest rise in groundwater-level altitudes in the Evangeline aquifer from 1977 to 2019 (240 ft) was in southeastern Harris County. In 2019, groundwater-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum to 250 ft above datum. The 2000–19 groundwater-level-change contours for the Jasper aquifer depict groundwater-level declines throughout most of the study area where groundwater-level-altitude data from the Jasper aquifer were collected, with the largest decline (200 ft) in southern Montgomery County.

Texas↗

USGS2020

Status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers, Houston-Galveston region, Texas, 2020

Since the early 1900s, most of the groundwater withdrawals in the Houston-Galveston region, Texas, have been from the three primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers. Withdrawals from these aquifers are used for municipal supply, commercial and industrial use, and irrigation. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2020 groundwater-level altitudes (represented by measurements made during December 2019 through March 2020) and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers. In 2020, groundwater-level-altitude contours for the Chicot aquifer ranged from 150 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) to 200 ft above datum. The 1977–2020 groundwater-level-change contours for the Chicot aquifer depict a large area of decline in groundwater-level altitudes (120 ft) in northwestern Harris County. The largest rise in groundwater-level altitudes in the Chicot aquifer from 1977 to 2020 (200 ft) was in southeastern Harris County. In 2020, groundwater-level-altitude contours for the Evangeline aquifer ranged from 250 ft below datum to 200 ft above datum. The 1977–2020 groundwater-level-change contours for the Evangeline aquifer depict broad areas where groundwater-level altitudes either declined or rose. The largest decline in groundwater-level altitudes (280 ft) was in southern Montgomery and northern Harris Counties. The largest rise in groundwater-level altitudes in the Evangeline aquifer from 1977 to 2020 (240 ft) was in southeastern Harris County. In 2020, groundwater-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum to 250 ft above datum. The 2000–20 groundwater-level-change contours for the Jasper aquifer depict groundwater-level declines throughout most of the study area where groundwater-level-altitude data from the Jasper aquifer were collected, with the largest decline (220 ft) in southern Montgomery County.

Texas↗