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Water-quality, bed-sediment, and biological data (October 2007 through September 2008) and statistical summaries of long-term data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in streams from Butte to near Missoula as part of a long-term monitoring program in the upper Clark Fork basin; additional water samples were collected in the Clark Fork basin from sites near Missoula downstream to near the confluence of the Clark Fork and Flathead River as part of a supplemental sampling program. The sampling programs were conducted in cooperation with the U.S. Environmental Protection Agency to characterize aquatic resources in the Clark Fork basin of western Montana, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water samples were collected periodically at 23 sites from October 2007 through September 2008. Bed-sediment and biota samples were collected once at 13 sites during August 2008. This report presents the analytical results and quality assurance data for water-quality, bed-sediment, and biota samples collected at all long-term and supplemental monitoring sites from October 2007 through September 2008. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Turbidity was analyzed for water samples collected at sites where seasonal daily values of turbidity were being determined and at Clark Fork above Missoula. Nutrients also were analyzed at all the supplemental water-quality sites, except for Clark Fork Bypass, near Bonner. Daily values of suspended-sediment concentration and suspended-sediment discharge were determined for four sites, and seasonal daily values of turbidity were determined for four sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of long-term water-quality, bed-sediment, and biological data for sites in the upper Clark Fork basin are provided for the period of record since 1985.

Montana

Ensemble methods for parameter estimation of WRF-Hydro

The WRF-Hydro hydrological model has been used in many applications in the past with some level of history matching in the majority of these studies. In this study, we use the iterative Ensemble Smoother (iES), a powerful parameter estimation methodology implemented in the open-source PEST++ software. The iES provides an ensemble solution with an uncertainty bound instead of a single best estimate which has been the common approach in the previous WRF-Hydro studies. We discuss the importance of accounting for observation noise which results in a wider spread in the model solution. We investigate the impact of constructing objective functions by differentially weighting the observations to tune the model response toward model outputs appropriate for a specific application. Results confirm the necessity of differentially weighting the observations before calculation of the objective function as the optimization algorithm struggles with calculating parameter updates with uniform weighting. We also show that we achieve better model performance in terms of verification metrics with higher emphasis on the high flow events, when the objective function is tuned toward an application where the extreme events are of importance. We then investigate the impact of estimating more parameters, in particular we estimate a larger number of snow parameters. Results show a large improvement in the model performance. In summary, our study demonstrates the efficacy of employing iES alongside differential weighting of observations, highlighting its potential to enhance hydrological model parameter estimation.

Water Resources Research

Evaluation of sockeye salmon after passage through an innovative upstream fish-passage system at Cle Elum Dam, Washington, 2017

Executive Summary The Bureau of Reclamation (Reclamation) and the Washington State Department of Ecology (Ecology), working with the Yakima River Basin Water Enhancement Project Workgroup (composed of representatives of the Yakama Nation; Federal, State, county, and city governments; environmental organizations; and irrigation districts), developed the Yakima Basin Integrated Plan (Integrated Plan). The Integrated Plan identifies a comprehensive approach to water resources and ecosystem restoration improvements in the Yakima Basin to be implemented over a 30-year period. The Integrated Plan includes seven elements: Reservoir fish passage, Structural and operational changes to existing facilities, Surface water storage, Groundwater storage, Habitat/watershed protection and enhancement, Enhanced water conservation, and Market reallocation. The first listed element, reservoir fish passage, will be expensive and take many years to accomplish. Reclamation and Ecology decided to look at new and innovative means to provide passage that could help reduce project cost and construction timing while maintaining survival rates of traditional upstream passage facilities. Reclamation contracted with the U.S. Geological Survey to do a study to evaluate the outcome of passage through one innovative fish-passage system at Cle Elum Dam, the first Integrated Plan reservoir fish-passage project being implemented.

Washington

Water-quality, bed-sediment, and biological data (October 2006 through September 2007) and statistical summaries of long-term data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in streams from Butte to below Milltown Reservoir as part of a long-term monitoring program in the upper Clark Fork basin; additional water-quality samples were collected in the Clark Fork basin from sites near Milltown Reservoir downstream to near the confluence of the Clark Fork and Flathead River as part of a supplemental sampling program. The sampling programs were conducted in cooperation with the U.S. Environmental Protection Agency to characterize aquatic resources in the Clark Fork basin of western Montana, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water-quality samples were collected periodically at 22 sites from October 2006 through September 2007. Bed-sediment and biological samples were collected once at 12 sites during August 2007. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at all long-term and supplemental monitoring sites from October 2006 through September 2007. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Turbidity was analyzed for samples collected at sites where seasonal daily values of turbidity were being determined. Nutrients also were analyzed in the supplemental water-quality samples. Daily values of suspended-sediment concentration and suspended-sediment discharge were determined for four sites, and seasonal daily values of turbidity were determined for five sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of long-term water-quality, bed-sediment, and biological data for sites in the upper Clark Fork basin are provided for the period of record since 1985.

Montana

U.S. Geological Survey National Water Census: Colorado River Basin Geographic Focus Area Study

Introduction The U.S. Geological Survey’s (USGS) concept of a national census (or accounting) of water resources has evolved over the last several decades as the Nation has experienced increasing concern over water availability for multiple competing uses. The implementation of a USGS National Water Census was described in the USGS 2007 science strategy document that identified the highest priority science topics for the decade 2007–17. In 2009, the SECURE Water Act (Public Law 111–11, subtitle F) authorized the USGS to create a Water Availability and Use Assess­ment Program for the Nation, and in 2012, the Department of the Interior WaterSMART initiative provided funding to begin implementation of the USGS National Water Census (NWC). Generally, the USGS NWC approaches water-availability assessment in terms of a “water budget.” The water-budget approach seeks to better quantify the inflows and outflows of water, as well as the change in storage volume, both nationally and at a regional scale and, by doing so, provides critical information to managers and stakeholders responsible for making water-availability decisions. The NWC has two primary components: Topical Studies and Geographic Focus Area Studies. Topical Studies do research on methods that can provide nationwide estimates of particular water-budget components at the subwatershed scale. Some examples of NWC Topical Studies include estimation of streamflow at ungaged locations; periodic quantification of evapotranspiration; and water use related to development of unconventional oil and gas. These efforts are planned to include additional topics in the future. Geographic Focus Area Studies (FASs) assess water availability and use within a defined geographic area, typically a surface-water drainage basin, to increase the understanding of factors affecting water availability in the region. In the FASs, local stakeholder input helps the USGS identify what components of the water budget are in most need of additional understanding or quantification. Focus Area Studies are planned as 3-year efforts and, typically, three FASs are ongoing in different parts of the country at any given time. The Colorado River Basin (CRB) and the Delaware and Apalachicola-Chattahoochee-Flint (ACF) River Basins were selected by the Department of the Interior for the first round of FASs because of the perceived water shortages in the basins and potential conflicts over water supply and allocations. After gathering input from numerous stakeholders in the CRB, the USGS determined that surface­-water resources in the basin were already being closely monitored and that the most important scientific contribution could be made by helping to improve estimates of four water­-budget components: evapotranspiration losses, snowpack hydrodynamics, water­-use information, and the relative importance of groundwater discharge in supporting streamflow across the basin. The purpose of this fact sheet is to provide a brief summary of the CRB FAS results as the study nears completion. Although some project results are still in the later stages of review and publication, this fact sheet provides an overall description of the work completed and cites the publications in which additional information can be found.

Arizona, California, Colorado, Nevada, New Mexico,

Brackish groundwater and its potential as a resource in the southwestern United States

Secure, reliable, and sustainable water resources are fundamental to food production, energy independence, and the health of humans and ecosystems. But the large-scale development of fresh groundwater resources has stressed aquifers in some areas, causing declines in the amount of groundwater in storage and decreases in discharge to surface-water bodies like rivers and springs (Reilly and others, 2008). In some parts of the southwestern United States, the water supply is not adequate to meet demand without substantial effects on groundwater storage or surface discharge, and severe drought intensifies the stresses affecting water resources. In support of the national census of water resources, the U.S. Geological Survey (USGS) completed the national brackish groundwater assessment to provide information about brackish groundwater as a potential resource to augment or replace freshwater supplies (Stanton and others, 2017). The objectives of the brackish groundwater assessment were to consolidate available data into a comprehensive database of brackish groundwater resources in the United States and to produce a summary report about the distribution, physical and chemical characteristics, and use of brackish groundwater. This fact sheet summarizes the occurrence of brackish groundwater and factors affecting its usability in the southwestern United States (specifically the Southwest Basins region) reported for the national study. The map below (fig. 1) summarizes the brackish zones for the five largest principal aquifers within the southwestern United States, along with groundwater resources in the remaining part of the region (Reilly and others, 2008).

Fact Sheet

Review of techniques to prevent introduction of zebra mussels (Dreissena polymorpha) during native mussel (Unionoidea) conservation activities

Because of the declines in diversity and abundance of native freshwater mussels (superfamily Unionoidea), and the potential decimation of populations of native mussels resulting from the rapid spread of the exotic zebra mussel Dreissena polymorpha, management options to eliminate or reduce the threat of the zebra mussel are needed. Relocating native mussels to refugia (artificial and natural) has been proposed to mitigate the threat of zebra mussels to native species. Relocation of native mussels to refugia such as fish hatchery facilities or natural habitats within their historic range. Which are unlikely to be infested by zebra mussels, necessitates that protocols be developed to prevent the inadvertent introduction of zebra mussels. Several recent studies have developed Such protocols, and have assessed their effectiveness on the health and survival of native mussels during subsequent relocation to various refugia. The purpose of this project is to synthesize and evaluate the current protocols and to develop a set of procedures that resource managers and researchers should consider before conducting conservation activities in zebra mussel infested waters. We found that the existing protocols have many common points of concern, such as facility modification and suitability, zebra mussel risk assessment and management procedures, and health and disease management procedures. These conservation protocols may have broad applicability to other situations and locations. A summary and evaluation of the information in these main areas, along with recommended guidelines, are presented in this article.

Journal of Shellfish Research

Water-quality, bed-sediment, and biological data (October 2008 through September 2009) and statistical summaries of long-term data for streams in the Clark Fork basin, Montana

Water, bed sediment, and biota were sampled in streams from Butte to near Missoula, Montana, as part of a long-term monitoring program in the upper Clark Fork basin; additional water samples were collected in the Clark Fork basin from sites near Missoula downstream to near the confluence of the Clark Fork and Flathead River as part of a supplemental sampling program. The sampling programs were conducted by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency to characterize aquatic resources in the Clark Fork basin of western Montana, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water samples were collected periodically at 24 sites from October 2008 through September 2009. Bed-sediment and biota samples were collected once at 13 sites during August 2009. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at all long-term and supplemental monitoring sites from October 2008 through September 2009. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Turbidity was analyzed for water samples collected at the four sites where seasonal daily values of turbidity were being determined as well as at Clark Fork above Missoula. Nutrients also were analyzed at all the supplemental water-quality sites, except for Clark Fork Bypass, near Bonner. Daily values of suspended-sediment concentration and suspended-sediment discharge were determined for four sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of long-term water-quality, bed-sediment, and biological data for sites in the upper Clark Fork basin are provided for the period of record since 1985.

Open-File Report

Environmental setting of benchmark streams in agricultural areas of eastern Wisconsin

This report describes the environmental setting of 20 benchmark streams in agricultural areas of eastern Wisconsin that are part of the Western Lake Michigan Drainages, National Water-Quality Assessment Program. Benchmark streams are defined as those that show minimal adverse effects from human activity, and they were selected on the basis of field reconnaissance and the following criteria: (1) available invertebrate or fisheries data that indicated good to excellent water quality, (2) instream habitat restoration for fisheries enhancement, and (3) land management to protect riparian vegetation. Information gathered from these benchmark sites can be used as a standard of reference to compare the health of other streams in agricultural areas on the basis of aquatic-biota communities, habitat, and water-quality characteristics. The information included in this report serves as background information that will be useful for a series of studies at these benchmark-stream sites in the Western Lake Michigan Drainages study unit as part of the National Water-Quality Assessment Program. Four relatively homogeneous units (RHU's) in agricultural areas that differed in bedrock and surficial geology were selected for study. RHU 1 (clayey surficial deposits over carbonate bedrock) and RHU 3 (sandy-till surficial deposits over carbonate bedrock) are in adjacent agricultural areas in the Southeastern Wisconsin Till Plains ecoregion. RHU 20 (sandy/sand and gravel surficial deposits over igneous and metamorphic bedrock) and RHU 26 (sandy/sand and gravel surficial deposits over sandstone bedrock) are in adjacent areas of agriculture and mixed forests in the North Central Hardwood Forests ecoregion. Differences in land use/land cover, and riparian vegetation and instream habitat characteristics are presented. Summaries of field measurements of water temperature, pH, specific conductance and concentrations of dissolved oxygen, total organic plus ammonia nitrogen, dissolved ammonium, nitrate plus nitrte as nitrogen, total phosphorus, dissolved orthophosphate, and atrazine are listed. Concentrations of dissolved oxygen for the sampled streams ranged from 6 A to 14.3 and met the standards set by the Wisconsin Department of Natural Resources (WDNR) for supporting fish and aquatic life. Specific conductance ranged from 98 to 753 u,Scm with values highest in RHU's 1 and 3, where streams are underlain by carbonate bedrock. Median pH did not vary greatly among the four RHU's and ranged from 6.7 to 8.8 also meeting the WDNR standards. Concentrations of total organic plus ammonia nitrogen, dissolved ammonium, total phosphorus, and dissolved orthophosphate show little variation between streams and are generally low, compared to concentrations measured in agriculturally-affected streams in the same RHU's during the same sampling period. Concentrations of the most commonly used pesticide in the study unit, atrazine, were low in all streams, and most concentrations were below trn 0.1 u,g/L detection limit. Riparian vegetation for the benchmark streams were characterized by lowland species of the native plant communities described by John T. Curtis in the "Vegetation of Wisconsin." Based on the environmental setting and water-quality information collected to date, these streams appear to show minimal adverse effects from human activity.

Wisconsin

Selected hydrologic data, Uinta Basin area, Utah and Colorado

The Uinta Basin area in northeastern Utah and northwestern Colorado covers an area of slightly more than 10,000 mi 2 (25,900 km 2 ). More than 95 percent of the basin is in Utah, thus most of the data in this report apply to Utah. Most of the water wells are concentrated in populated areas along the lower parts of the basin; records of only a representative number of these water sources are included in this report. This report presents consolidated listings of data selected for use in hydrologic studies in the Uinta Basin area through June 1974. The data are principally taken from three studies made during 1971-74 by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. Also incorporated in this report are data collected since 1935 by the Geological Survey and other organizations. This report is intended to make data conveniently available and to supplement interpretive reports that will be published separately. For some data sites, the volume of data is too great for complete inclusion here. For these sites, data summaries are provided, and for greater detail the reader is referred to the sources listed under Selected references.

Colorado, Utah

Summary of hydrologic testing, wellbore-flow data, and expanded water-level and water-quality data, 2011–15, Fort Irwin National Training Center, San Bernardino County, California

In view of the U.S. Army’s historical reliance and plans to increase demands on groundwater to supply its operations at Fort Irwin National Training Center (NTC), California, coupled with the continuing water-level declines in some developed groundwater basins as a result of pumping, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, evaluated the water resources, including water quality and potential groundwater supply, of undeveloped basins in the NTC. Previous work in the three developed groundwater basins—Langford, Bicycle, and Irwin—provided information to support water-resources management of those basins. During 2009–12, the USGS installed 41 wells at the NTC; 34 wells were at 14 single- or multiple-well monitoring sites, and 7 wells were long-screen test wells. The majority of the wells were installed in previously undeveloped or minimally developed groundwater basins (Cronise, Red Pass, the Central Corridor area, Superior, Goldstone, and Nelson Basins). During 2012–15, the USGS tested hydrologic properties at 32 wells in 8 basins to help characterize the aquifer system. This report presents data and analyses from core samples; slug tests and single-well aquifer tests; coupled measurements of wellbore flow, water levels, and water-quality constituents; and results from two-dimensional numerical modeling. This information provides a basis for developing and constraining basin-scale hydrogeologic framework and groundwater-flow models to further evaluate water resources in each groundwater basin. Core samples were tested for vertical saturated hydraulic conductivity, physical properties, and particle-size distribution. Vertical saturated hydraulic conductivities of the cores ranged from less than 0.00001 to 18.13 feet per day, and porosities ranged from 0.15 to 0.56. These physical properties and particle-size analyses indicate the high degree of heterogeneity of the hydrogeologic deposits penetrated by the boreholes. Horizontal hydraulic conductivities estimated from slug tests in 22 monitoring wells in 6 basins (Cronise, Central Corridor area, Goldstone, Langford, Bicycle, and Nelson Basins) ranged from less than 0.1 to 40 feet per day. Results of the aquifer tests at six test wells in the Goldstone, Nelson, and Superior Basins indicate hydraulic conductivities ranged from 0.37 to 66 feet per day; associated transmissivity values ranged from 130 to 28,000 feet squared per day. Wellbore-flow data, collected from the six test wells under unpumped and pumped conditions, generally showed downward movement of water. Flow data collected under unpumped conditions indicate groundwater entered the well through the upper part of the screened interval and exited to aquifer zones in the lower part of the screened interval at rates ranging from 1 to 3 gallons per minute. Flow data collected under pumping conditions show increased flow downward in the test wells, indicating higher yields from deeper aquifers. Water levels, measured periodically between 2011 and 2015, remained stable during this period in the majority of the wells measured since 2011, except at two monitoring sites in developed basins (Bicycle and Langford). Vertical hydraulic gradients were generally low throughout the NTC, but ranged from –0.0003 to 0.27 during the summer of 2015. Multiple-well monitoring sites in Bicycle, Central Corridor area, Cronise, Goldstone, Nelson, and Superior Basins, had downward vertical gradients. Groundwater in wells in Nelson and Superior Basins, and wells BLA5, CCT1, and GOLD2 #2, was characterized as sodium-bicarbonate water, whereas groundwater from the remaining wells in Goldstone Basin was characterized as sodium-chloride water and Cronise Basin, and well LL04 was characterized by sodium-sulfate water. Total dissolved solids (TDS) ranged from 285 to 13,400 milligrams per liter (mg/L) TDS and chloride concentrations ranged from 19 to 1,030 mg/L chloride, with lowest concentrations of each in groundwater from Superior and Nelson Basins and highest concentrations in Cronise Basin. Nitrate plus nitrite as nitrogen ranged from less than 0.040 mg/L in groundwater from Cronise and Goldstone Basins to about 20 mg/L in Nelson Basin. Groundwater from wells in Nelson Basin was isotopically light, whereas groundwater samples from wells CRTH1, CRTH2, and LL04 were isotopically heavier and plotted along an evaporative trend line. No measurable tritium was detected in groundwater from 13 wells sampled in 2015, indicating that groundwater was recharged prior to 1952. Measured carbon-14 ( 14 C) activities in groundwater from four wells sampled in 2015 ranged from about 7.9 to 23.5 percent modern carbon and had apparent (uncorrected) ages of 11,970–20,980 years. Arsenic concentrations were above the maximum contaminant level of 10 micrograms per liter in groundwater from all wells, except those in Goldstone Basin and the two deepest wells in Langford Basin (LL04); likewise, fluoride concentrations were above the California maximum contaminant level of 2 mg/L in groundwater from most wells, except those in Goldstone and Superior Basins, the middle well in Langford Basin, middle and deep wells in two locations in Cronise Basin, and two wells in Nelson Basin. Wellbore flow was simulated for each well by using an integrated-flow analysis tool, AnalyzeHOLE, to evaluate aquifer properties and heterogeneity. Horizontal layers in the model (hydrogeologic units) were defined by lithostratigraphic‐geophysical units, interpreted from lithologic and geophysical logs for each well, and were adjusted during calibration. The saturated hydraulic conductivities derived from the calibrated simulations ranged from less than 0.01 to 60 feet per day in Nelson, Goldstone, and Superior Basins.

California

Understanding the influence of nutrients on stream ecosystems in agricultural landscapes

Sustaining the quality of the Nation’s water resources and the health of our diverse ecosystems depends on the availability of sound water-resources data and information to develop effective, science-based policies. Effective management of water resources also brings more certainty and efficiency to important economic sectors. Taken together, these actions lead to immediate and long-term economic, social, and environmental benefits that make a difference to the lives of the almost 400 million people projected to live in the United States by 2050. In 1991, Congress established the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) to address where, when, why, and how the Nation’s water quality has changed, or is likely to change in the future, in response to human activities and natural factors. Since then, NAWQA has been a leading source of scientific data and knowledge used by national, regional, State, and local agencies to develop science-based policies and management strategies to improve and protect water resources used for drinking water, recreation, irrigation, energy development, and ecosystem needs ( https://water.usgs.gov/nawqa/applications/ ). Plans for the third decade of NAWQA (2013–23) address priority water-quality issues and science needs identified by NAWQA stakeholders, such as the Advisory Committee on Water Information and the National Research Council, and are designed to meet increasing challenges related to population growth, increasing needs for clean water, and changing land-use and weather patterns. Excess nutrients are a pervasive problem of streams, lakes, and coastal waters. The current report, “The Quality of Our Nation’s Waters—Understanding the Effects of Nutrients on Stream Ecosystems in Agricultural Landscapes,” presents a summary of results from USGS investigations conducted from 2003 to 2011 on processes that influence nutrients and how nutrient enrichment can alter biological components of agricultural streams. This study included collecting data from 232 sites distributed among eight study areas. This report summarizes findings on processes that influence nutrients and how nutrient enrichment can alter biological communities in agricultural streams. These findings are relevant to local, State, regional, and national decision-makers involved in efforts to (1) better understand the influence of nutrients on agricultural streams, (2) develop nutrient criteria for streams and rivers, (3) reduce nutrients to streams and downstream receiving waters, and (4) develop tools for tracking nutrient and biological conditions following nutrient reduction strategies. All NAWQA reports are available online at https://water.usgs.gov/nawqa/bib/ . We hope this publication will provide you with insights and information to meet your water-resource needs and will foster increased citizen awareness and involvement in the protection and restoration of our Nation’s waters. The information in this report is intended primarily for those interested or involved in resource management and protection, conservation, regulation, and policymaking at the regional and national levels.

Central Columbia-Yakima River Basins, Great River

Executive summary and annotated bibliography of selected references from “Microbial and viral indicators of pathogens and human health risks from recreational exposure to waters impaired by fecal contamination” with related project ideas for Gwinnett County, Georgia

This document was prepared in cooperation with Gwinnett County, Georgia, to supplement the journal article “Microbial and Viral Indicators of Pathogens and Human Health Risks from Recreational Exposure to Waters Impaired by Fecal Contamination” (published in Journal of Sustainable Water in the Built Environment ). The document includes an executive summary of the article, project ideas for Gwinnett County to enhance its bacterial monitoring program, and an annotated bibliography of selected references from the article. Although tailored to Gwinnett County, the project ideas are based on the state of the science of monitoring for fecal-associated pathogens and pathogen indicators in impaired surface waters and may be of interest to water resources divisions of other municipalities.

Georgia

Description of landscape features, summary of existing hydrologic data, and identification of data gaps for the Osage Nation, northeastern Oklahoma, 1890-2012

The Osage Nation of northeastern Oklahoma, conterminous with Osage County, is characterized by gently rolling uplands and incised stream valleys that have downcut into underlying sedimentary rock units of Pennsylvanian through Permian age. Cattle ranching and petroleum and natural-gas extraction are the principal land uses in this rural area. Freshwater resources in the Osage Nation include water flowing in the Arkansas River and several smaller streams, water stored in several lakes, and groundwater contained in unconsolidated alluvial aquifers and bedrock aquifers. The Vamoosa-Ada aquifer is the primary source of fresh groundwater in this area. Fresh groundwater is underlain by saline groundwater in aquifers underlying the Osage Nation. Because of the potential for future population increases, demands for water from neighboring areas such as the Tulsa metropolitan area, and expansion of petroleum and natural-gas extraction on water resources of this area, the U.S. Geological Survey, in cooperation with the Osage Nation, summarized existing hydrologic data and identified data gaps to provide information for planning of future development of water resources in the Osage Nation. Streamflows in the Osage Nation are substantially affected by precipitation. During the relatively wet periods from the 1970s to 2000, the annual streamflows in the Osage Nation increased by as much as a factor of 2 relative to preceding decades, with subsequent decreases in streamflow of as much as 50 percent being recorded during intermittent drier years of the early 2000s. This report summarizes hydrologic data from 3 surface-water sites and 91 wells distributed across the Osage Nation. Data collected at those sites indicate that surface water in the Osage Nation generally has sufficient dissolved oxygen for survival of both coldwater and warmwater aquatic biota. Total dissolved solids concentration exceeded the secondary drinking-water standard of 500 milligrams per liter (mg/L) in up to 75 percent of the surface-water samples, indicating limited availability of potable water at some sites. Some surface-water samples collected in the Osage Nation contained dissolved chloride concentrations exceeding the secondary drinking-water standard of 250 mg/L, with greater chloride concentrations in selected basins appearing to be associated with greater densities of petroleum well locations. Several lakes sampled in the Osage Nation from 2011–12 contained sufficient chlorophyll-a concentrations to be ranked as mesotrophic to eutrophic, indicating impairment by nutrients. Relatively large dissolved phosphorus concentrations in many surface-water samples, compared to water-quality standards, indicate that eutrophication can occur in local streams and lakes. The amount of fresh groundwater stored in alluvial aquifers and the Vamoosa-Ada bedrock aquifer is adequate for domestic and other purposes in the Osage Nation at the current rate of usage. In areas where these aquifers are absent, groundwater must be pumped from minor bedrock aquifers that produce smaller volumes of water. About 30 and 60 percent of 32 and 54 water samples collected from the alluvial and Vamoosa-Ada aquifers, respectively, contained total dissolved solids concentrations larger than the secondary drinking-water standard of 500 mg/L. Local factors, such as natural seepage of brines or leakage from petroleum and natural-gas extraction activities, may cause substantial variations in dissolved chloride concentration in groundwater in the Osage Nation. Total phosphorus concentrations measured in groundwater samples were similar to dissolved phosphorus concentrations measured in the base flow of several streams. Total fresh surface-water withdrawals (use) and fresh groundwater withdrawals in the Osage Nation were estimated to have increased from 0.75 to 16.19 million gallons per day and from 0.13 to 2.39 million gallons per day, respectively, over the period from 1890 through 2010. Estimated saline-groundwater reinjection volumes at the heavily developed Burbank Oil Field in the Osage Nation from 1950 through 2012 were many times larger than the total amounts of freshwater withdrawn in this area, with estimated increases in saline-groundwater reinjection in the 2000s probably being related to increased petroleum extraction. Estimates of freshwater resources in local streams, lakes, and freshwater aquifers and of net annual precipitation indicate that less than 1 percent of freshwater resources and net annual precipitation currently is being withdrawn annually in the Osage Nation. In addition to freshwater resources, the Osage Nation may be underlain by 45,000,000 million gallons of brines, a small portion of which are withdrawn and reinjected during petroleum and natural-gas extraction. Ongoing development of desalinization technology may lead to the ability to expand use of these saline waters in the future. Several additional studies could improve understanding of the hydrologic resources of the Osage Nation. Development of computer models (simulations) of groundwater and surface-water flow for this area could enable testing of scenarios of localized and widespread effects of future climate variations and water-use changes on streamflows, lake-water levels, and groundwater levels in the Osage Nation. Installation of additional long-term streamflow and water-quality sampling stations, some with continuous water-quality monitors, could expand and improve understanding of surface-water quality. Periodic measurement of groundwater levels and sampling of water from a network of wells could provide better information about trends of groundwater quantity and quality with time. Measurement of water withdrawals at selected sites could enable more accurate estimates of water use. Lastly, better understanding of aquifer properties and spatial distribution of saline groundwater provided by geophysical surveys could improve understanding of fresh and saline groundwater resources underlying the Osage Nation.

Oklahoma

Handbook of acute toxicity of chemicals to fish and aquatic invertebrates : summaries of toxicity tests conducted at Columbia National Fisheries Research Laboratory, 1965-78

Acute toxicity is a major subject of research at Columbia National Fisheries Research Laboratory for evaluating the impact of toxic chemicals on fishery resources. The Laboratory has played a leading role in developing research technology for toxicity testing and data interpretation. In 1965-78, more than 400 chemicals were tested against a variety of invertebrates and fish species representative of both cold- and warm-water climates. The use of acute toxicity tests for assessing the potential hazard of chemical contaminants to aquatic organisms is well documented (Boyd 1957; Henderson et al. 1960; Sanders and Cope 1966; Macek and McAllister 1970). Static acute toxicity tests provide rapid and (within limits) reproducible concentration-response curves for estimating toxic effects of chemicals on aquatic organisms. These tests provide a database for determining relative toxicity of a large number of chemicals to a variety of species and for estimating acute effects of chemical spills on natural aquatic systems; they also assist in determining priority and design of additional toxicity studies. Acute toxicity tests usually provide estimates of the exposure concentration causing 50% mortality (LC50) to test organisms during a specified period of time. For certain invertebrates, the effective concentration is based on immobilization, or some other identifiable endpoint, rather than on lethality. The application of the LC50 has gained acceptance among toxicologists and is generally the most highly rated test for assessing potential adverse effects of chemical contaminants to aquatic life (Brungs and Mount 1978; American Institute for Biological Sciences 1978 a ). The literature contains numerous papers dealing with the acute toxicity of chemicals to freshwater organisms. However, there is a tremendous need for a concise compendium of toxicity data covering a large variety of chemicals and test species. This Handbook is a compilation of a large volume of acute toxicity data from the Columbia Laboratory and its field laboratories. It presents definitive acute toxicity data on 271 chemicals tested against a variety of freshwater invertebrates and fishes. The chemicals represent all major groups of pesticides, as well as numerous industrial chemicals. This compilation should serve as a useful database for the many agencies and organizations dealing with research and management programs concerned with the impact of chemicals on aquatic resources. The Columbia Laboratory has played a major role in developing currently used standard methodology for static acute toxicity testing. The use of standardized methodology greatly reduces variation in results. The data presented here have been carefully scrutinized to eliminate tests that failed to follow acceptable procedures. Handling of test organisms and procedures for static toxicity tests followed those described by Lennon and Walker (1964) and Macek and McAllister (1970), and conform well with those recommended by Brauhn and Schoettger (1975) and the Committee on Methods for Toxicity Tests with Aquatic Organisms (1975). The species of fish and invertebrates that were tested are listed in phylogenetic order in Tables 1 and 2. Fish were obtained from Federal and State hatcheries as either eggs or fry. Original stocks of invertebrates were collected and cultured from wild populations with no known source of contamination; these populations were replenished regularly. The invertebrates were cultured in the Laboratory by methods similar to those described by Sanders and Cope (1966). Test chemicals usually consisted of technical or analytical grade samples of known purity. Formulations of the chemicals were also tested when available. When purity of test chemicals was known, all calculated concentrations were based on percent active ingredients. Stock solutions were prepared immediately before each test, with commercial grade acetone as the carrier solvent. Occasionally, ethanol or dimethyl-formamide was substituted. Solvent concentrations did not exceed 0.5 mL/L in final dilution water. Test water (dilution water) was reconstituted from deionized water of at least 10 6 ohms resistivity by the addition of appropriate reagent grade chemicals (Marking 1969). Water was buffered to maintain a pH of 7.2 to 7.5, an alkalinity of 30 to 35 mg/L, and a hardness of 40 to 50 mg/L as CaCO 3 . Test water was mixed thoroughly and aerated before transfer into test chambers. Fish were acclimated to dilution water by gradually changing the water in acclimated tanks from 100% well water to 100% reconstituted water over a 1- to 3-day period at the desired testing temperature. Invertebrates were acclimated from well water to dilution water over a 4- to 6-h period. Toxicity tests were conducted under static conditions without aeration, and the organisms were not fed during acclimation or testing. Temperature of test solutions was maintained within ± 1°C of that required for a given test. Toxicity tests with fish were conducted in 18.9-liter (5-gal) wide-mouthed jars containing 15 liters of test solution. Fingerling fish weighing 0.2 to 1.5 g were tested at each concentration. Caution was taken not to exceed 0.8 g of test organisms per liter of solution. Duplicate test chambers were used to accommodate larger fish. Test chambers varied in size for invertebrates, depending on the species used; volume of test solution ranged from 0.25 to 4 liters. At least 10 organisms were exposed to each concentration for all definitive tests. At least six concentrations were used per toxicity test. The tests began upon initial exposure to the toxicant and continued for 96 h. Immobilization tests with invertebrates were conducted for only 48 h. The number of dead or affected organisms in each test chamber were recorded and the dead organisms were removed every 24 h; general observations on the condition of test organisms were also recorded at these times. Toxicity data were analyzed by a statistical method described by Litchfield and Wilcoxon (1949) to determine LC50 (theoretical estimate of the concentration lethal to 50% of the test animals) and 95% confidence intervals. This method is recommended by the American Public Health Association (1971) and by Sprague (1969) for determining median lethal concentrations. The procedure is easily modified for computing a single LC50 when replicate tests are performed.

Resource Publication

Statistical summaries of streamflow data and characteristics of drainage basins for selected streamflow-gaging stations in Arizona through water year 1996

Statistical summaries of streamflow data are given for 142 unregulated or partly regulated continuous-record streamflow-gaging stations and 178 peak-flow partial-record stations in Arizona through water year 1996. Streamflow statistics were generated for stations with a minimum period of record of 10 years. Summaries for continuous-record stations include: (1) station description, (2) statistics of mean monthly and annual discharges, (3) magnitude and probability of annual peak discharge, (4) magnitude and probability of annual low and high flow, (5) mean daily flow duration, and (6) basin and climatic characteristics. Statistical summaries for peak-flow partial-record stations include: (1) station description, (2) magnitude and probability of annual peak discharge, and (3) basin and climatic characteristics.

Arizona

A summary of pesticides in ground-water data collected by government agencies in Indiana, December 1985 to April 1991

The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, computerized the available government agency data on the occurrence of pesticides and pesticide metabolites in Indiana ground water. Results of analyses of 725 samples were summarized for the period December 1985 through April 1991. The data had been collected during 6 statewide surveys and 15 localized studies by the Indiana Department of Environmental Management, the Indiana Department of Natural Resources, the U.S. Environmental Protection Agency, and the U.S. Geological Survey. Ground-water samples were collected from 521 sites in 81 of 92 Indiana counties, including 179 public-supply wells, 304 domestic-supply wells, 36 observation wells, and 2 springs; 41 percent of all sites were sampled more than once. Thirty wells were sampled in response to alleged groundwater contamination with pesticides. Of 87 pesticides and 10 metabolites analyzed, 18 pesticides and 5 metabolites were detected in 51 samples of ground water from 22 domestic wells, 8 community-system wells, 5 observation wells, 4 non-community-system wells, and 2 springs. Detections associated with complaints of ground-water contamination from pesticide storage, handling, or application occurred at five domestic wells. Three-fourths of all the pesticide detections were in water from wells completed in unconsolidated materials to a depth of less than 100 feet, but well depths ranged from 12 to 260 feet. The highest frequency of occurrence was observed for the most commonly used herbicides alachlor, atrazine and two atrazine metabolites (de-ethylatrazine and de-isopropylatrazine); dicamba; 2,4-D; and metolachlor. Also reported in Indiana ground water were eight insecticides whose registration had been cancelled by the U.S. Environmental Protection Agency prior to their detection in Indiana EDB, DBCP, aldrin, endrin, dieldrin, lindane, heptachlor, and DOT. More than 1 pesticide was present in 16 of the 51 samples that had detections, for a total of 90 individual pesticide detections. Concentrations of the detected pesticides ranged from 0.04 to 49 micrograms per liter, and two-thirds of the detected concentrations were less than 1 microgram per liter. In about 29 percent of all detections, the concentration of 9 pesticides alachlor, aldrin, atrazine, dieldrin, EDB, heptachlor, heptachlor epoxide, simazine, and terbufos exceeded either the U.S. Environmental Protection Agency's Maximum Contaminant Level or adult lifetime Health Advisory.

Indiana

Summary of hydrologic conditions in Kansas, water year 2014

The U.S. Geological Survey Kansas Water Science Center, in cooperation with Federal, State, and local agencies, maintains a long-term network of hydrologic monitoring gages in the State of Kansas. These include 206 real-time streamgages, 12 real-time reservoir-level monitoring stations, and 32 groundwater monitoring wells. These data and associated analyses, accumulated over time, provide a unique overview of hydrologic conditions and help improve our understanding of Kansas’s water resources. Yearly hydrologic conditions are determined by comparing statistical analyses of current and historical water year data for the period of record. These data are used in protecting life and property, and managing water resources for agricultural, industrial, public supply, ecological, and recreational purposes.

Kansas