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At least 379 records · Page 21Linked to original sources

Submarine ground-water discharge and its role in coastal processes and ecosystems

Submarine ground-water discharge (SGD) has recently been recognized as a phenomenon that can strongly influence coastal water and geochemical budgets and drive ecosystem change. For example, the discharge of nutrient-enriched ground water into coastal waters may contribute significantly to eutrophication and blooms of harmful algae. Similarly, the quantity of SGD can also directly affect the availability of fresh water to coastal communities, impact fragile coastal ecosystems such as estuaries and coral reefs, and influence geomorphology of shoreline features. Moore raised awareness of the global importance of SGD and much effort has been devoted to developing new tracer techniques and methods for the identification and quantification of SGD. Because the discharge of coastal ground water commonly occurs as diffuse seepage rather than focused discharge through identifiable springs, assessing SGD has remained difficult for both oceanographers and hydrologists. Through national and international research programs, Burnett, Moore, Charette, and others have developed a rigorous, systematic approach for quantifying SGD using a wide assortment of tracers and methods. Intercalibration experiments, such as those conducted in coastal waters off Australia, Brazil, and Long Island, NY, demonstrate that careful measurements can accurately quantify SGD, confirm some of the driving mechanisms (e.g. climatic and tidal forcing), and constrain the spatial and temporal scales at which these mechanisms operate. Now that approaches for rigorously quantifying SGD are becoming better established, scientists can now begin to investigate the wide variety of coastal processes affected by SGD.

Open-File Report

Geochemistry of dissolved inorganic carbon in a Coastal Plain aquifer. 2. Modeling carbon sources, sinks, and δ13C evolution

Stable isotope data for dissolved inorganic carbon (DIC), carbonate shell material and cements, and microbial CO 2 were combined with organic and inorganic chemical data from aquifer and confining-bed pore waters to construct geochemical reaction models along a flowpath in the Black Creek aquifer of South Carolina. Carbon-isotope fractionation between DIC and precipitating cements was treated as a Rayleigh distillation process. Organic matter oxidation was coupled to microbial fermentation and sulfate reduction. All reaction models reproduced the observed chemical and isotopic compositions of final waters. However, model 1, in which all sources of carbon and electron-acceptors were assumed to be internal to the aquifer, was invalidated owing to the large ratio of fermentation CO 2 to respiration CO 2 predicted by the model (5–49) compared with measured ratios (two or less). In model 2, this ratio was reduced by assuming that confining beds adjacent to the aquifer act as sources of dissolved organic carbon and sulfate. This assumption was based on measured high concentrations of dissolved organic acids and sulfate in confining-bed pore waters (60–100 μM and 100–380 μM, respectively) relative to aquifer pore waters (from less than 30 μM and 2–80 μM, respectively). Sodium was chosen as the companion ion to organic-acid and sulfate transport from confining beds because it is the predominant cation in confining-bed pore waters. As a result, excessive amounts of Na-for-Ca ion exchange and calcite precipitation (three to four times more cement than observed in the aquifer) were required by model 2 to achieve mass and isotope balance of final water. For this reason, model 2 was invalidated. Agreement between model-predicted and measured amounts of carbonate cement and ratios of fermentation CO 2 to respiration CO 2 were obtained in a reaction model that assumed confining beds act as sources of DIC, as well as organic acids and sulfate. This assumption was supported by measured high concentrations of DIC in confining beds (2.6–2.7 mM). Results from this study show that geochemical models of confined aquifer systems must incorporate the effects of adjacent confining beds to reproduce observed groundwater chemistry accurately.

South Carolina

Areas contributing ground water to the Peconic Estuary, and ground-water budgets for the north and south forks and Shelter Island, eastern Suffolk County, New York

The Peconic Estuary, at the eastern end of Long Island, has been plagued by a recurrent algal bloom, locally referred to as ?Brown Tide,? that has caused the severe decline of local marine resources. Although the factors that trigger Brown Tide blooms remain uncertain, groundwater discharge has previously been shown to affect surface-water quality in the western part of the estuary. A U.S. Geological Survey groundwater- flow model of the main body of Long Island indicates that a total of about 7.5 x 106 ft3/d (cubic feet per day) of freshwater discharges to the western part of the estuary, but the model does not include the ground-water flow systems on the North and South Forks and Shelter Island, which contribute significant amounts of freshwater to the central and eastern parts of the estuary. The need for information on freshwater discharge to the entire estuary prompted the U.S. Geological Survey to evaluate ground-water discharge from the North and South Forks and Shelter Island. Source areas that contribute ground water to the Peconic Estuary were delineated, and groundwater budgets for these areas were developed, to evaluate the distribution and magnitude of ground-water discharge to the central and eastern parts of the estuary. Contributing-area boundaries that were delineated coincide with the hydraulic boundaries of the fresh ground-water-flow systems of the North and South Forks and Shelter Island; these boundaries are of two types? external (saltwater bodies) and internal (groundwater divides). Hydrologic components that were evaluated include recharge from precipitation, public-supply withdrawal and return flow, and agricultural withdrawal. Values for each of these components were calculated or estimated for the individual freshwater flow subsystems that form each ground-water-budget area, then summed to obtain the total discharge of fresh ground water to tidewater. Ground-water discharge to the Peconic Estuary is about 3.8 x 106 ft3/d from the North Fork, 11 x 106 ft3/d from the South Fork, and 1.7 x 106 ft3/d from Shelter Island. The total contribution to the estuary from these areas is about 16 x 106 ft3/d?roughly twice the total contribution from the main body of Long Island. In contrast to the freshwater contribution from the main body of Long Island, which is concentrated near the head of the estuary, the contributions from the North and South Forks and Shelter Island are distributed along the east-west length of the estuary. Changes in water-table altitude and the resulting changes in total discharge to the Peconic Estuary were estimated from the relative changes in annual mean water level at observation wells. The 1985-95 interval included 7 years (1985-88, 1991- 92, 1995) of generally below-average water-table altitudes that presumably caused similar decreases in ground-water discharge to the estuary; intense Brown Tide blooms coincided with six of these years (1985-88, 1991, 1995), and localized blooms coincided with the remaining year (1992). Watertable altitudes in the remaining 4 years of the 1985-95 interval (1989-90, 1993-94) were nearly average or above average, and presumably produced comparably near-average or increased amounts of ground-water discharge to the estuary; none of these years saw any widespread Brown Tide blooms. Fluctuations in the amounts of ground-water discharge to the estuary appear to affect the occurrence of Brown Tide blooms, although the factors that trigger the blooms have not been determined.

Water-Resources Investigations Report

Can mercury in fish be reduced by water level management? Evaluating the effects of water level fluctuation on mercury accumulation in yellow perch ( Perca flavescens )

Mercury (Hg) contamination of fisheries is a major concern for resource managers of many temperate lakes. Anthropogenic Hg contamination is largely derived from atmospheric deposition within a lake’s watershed, but its incorporation into the food web is facilitated by bacterial activity in sediments. Temporal variation in Hg content of fish (young-of-year yellow perch) in the regulated lakes of the Rainy–Namakan complex (on the border of the United States and Canada) has been linked to water level (WL) fluctuations, presumably through variation in sediment inundation. As a result, Hg contamination of fish has been linked to international regulations of WL fluctuation. Here we assess the relationship between WL fluctuations and fish Hg content using a 10-year dataset covering six lakes. Within-year WL rise did not appear in strongly supported models of fish Hg, but year-to-year variation in maximum water levels (∆maxWL) was positively associated with fish Hg content. This WL effect varied in magnitude among lakes: In Crane Lake, a 1 m increase in ∆maxWL from the previous year was associated with a 108 ng increase in fish Hg content (per gram wet weight), while the same WL change in Kabetogama was associated with only a 5 ng increase in fish Hg content. In half the lakes sampled here, effect sizes could not be distinguished from zero. Given the persistent and wide-ranging extent of Hg contamination and the large number of regulated waterways, future research is needed to identify the conditions in which WL fluctuations influence fish Hg content.

Ecotoxicology

Formation of vertical columnar seismic structures and seafloor depressions by groundwater discharge in the drowned Miami Terrace platform and overlying deep-water carbonates, southeastern Florida

The presence of vertical cross-formational fluid migration passageways within sedimentary basins can profoundly impact aquifer and reservoir fluid-flow and their identification is fundamental to informing management of subsurface fluid resources (groundwater, oil, gas). In an onshore and offshore southeastern part of Florida, 2D/3D seismic-reflection and bathymetry data document ∼153 vertical columnar structures composed of reflection disruptions up to 790 m in the height and averaging 360 m in diameter, and ∼219 subcircular to circular seafloor depressions up to 1334 m wide. Our study focuses on these features found within the offshore shallow-marine carbonate Miami Terrace platform, which drowned approximately at the end of the middle Miocene, and within overlying Plio-Quaternary deep-water carbonate slope and drift deposits. Most columnar structures are rooted in stratiform aquifers of the Miami Terrace platform and associated with faults or fault intersections produced by Eocene and circa late Miocene tectonics. The columns commonly terminate within the platform or as subcircular depressions along an amalgamated karstic and drowning unconformity at the platform top. The columns typically stretch upwards from a zone of deep karst cavity collapse through the Miami Terrace platform with upward decreasing sag on internal reflections. Following drowning and Plio-Quaternary partial burial of the Miami Terrace platform by deep-water deposits, the subcircular depressions and faults along the platform top were points of origin for a second phase of column growth upward into the deep-water deposits. The continuation of deep platform cavity collapse and column evolution produced pockmarks along paleo-seafloors within the deep-water deposits and at the present-day sea floor. The Plio-Quaternary pockmarks formed at water depths too deep to suggest an origin related to meteoric karst above or near sea level, but rather their formation is suggested to be related to cyclic sea level falls that drove increased groundwater head and density gradients, and seafloor discharge of offshore freshened groundwater sourced from the underlying platform. Plausibly, mixing of freshened groundwater and seawater at the seafloor discharge sites drove dissolution of the host deep-water deposits, which together with erosion by groundwater venting and current scouring formed the pockmarks. Seaward of the Plio-Quaternary seafloor pockmarks, at the late-middle Miocene upper slope of the Miami Terrace platform and along the regional karst/drowning unconformity is a slope-parallel band of ∼189 densely distributed subcircular seafloor depressions with diameters up to 1334 m at water depths up to ∼660 m. It is plausible that along the upper slope, faults and fractures produced by gravity-driven slope instability and possibly tectonics formed a dense network of fluid passageways that promoted upward artesian freshened groundwater flow to sites of discharge where mixing with seawater generated limestone dissolution and the depressions. But tectonic uplift may have forced emersion and initial meteoric sinkhole formation circa late Miocene with later enhancement by freshened groundwater discharge and bottom current erosion.

Florida

Ground-water supplies in shale and sandstone in Fairfax, Loudoun, and Prince William Counties, Virginia

The Triassic rocks of northern Virginia may be a potential source of moderately large supplies of ground water for municipal end industrial use if the performance of two deep wells drilled at the site of the new Dulles International Airport is a criterion. These two wells produced 327 and 600 gpm (gallons per minute) from depths of 860-and 955 feet in sedimentary rocks in an immediate area where the previous maximum depth reported was 180 feet and the maximum yield 12 gpm. Chemical analyses of the water indicates that it is extremely hard--533 and 500 ppm (parts per million) in the two wells--and would require treatment to be satisfactory for domestic and some industrial uses. However, water of better quality may be present at greater depths, and it may be possible to case off the more highly mineralized water. Further exploration and sampling of water from various depths will be necessary for efficient development of the Triassic groundwater reservoir.

Circular

Hydrogeologic Framework and Ground Water in Basin-Fill Deposits of the Diamond Valley Flow System, Central Nevada

The Diamond Valley flow system, an area of about 3,120 square miles in central Nevada, consists of five hydrographic areas: Monitor, Antelope, Kobeh, and Diamond Valleys and Stevens Basin. Although these five areas are in a remote part of Nevada, local government officials and citizens are concerned that the water resources of the flow system eventually could be further developed for irrigation or mining purposes or potentially for municipal use outside the study area. In order to better understand the flow system, the U.S. Geological Survey in cooperation with Eureka, Lander, and Nye Counties and the Nevada Division of Water Resources, is conducting a multi-phase study of the flow system. The principal aquifers of the Diamond Valley flow system are in basin-fill deposits that occupy structural basins comprised of carbonate rocks, siliciclastic sedimentary rocks, igneous intrusive rocks, and volcanic rocks. Carbonate rocks also function as aquifers, but their extent and interconnections with basin-fill aquifers are poorly understood. Ground-water flow in southern Monitor Valley is from the valley margins toward the valley axis and then northward to a large area of discharge by evapotranspiration (ET) that is formed south of a group of unnamed hills near the center of the valley. Ground-water flow from northern Monitor Valley, Antelope Valley, and northern and western parts of Kobeh Valley converges to an area of ground-water discharge by ET in central and eastern Kobeh Valley. Prior to irrigation development in the 1960s, ground-water flow in Diamond Valley was from valley margins toward the valley axis and then northward to a large discharge area at the north end of the valley. Stevens Basin is a small upland basin with internal drainage and is not connected with other parts of the flow system. After 40 years of irrigation pumping, a large area of ground-water decline has developed in southern Diamond Valley around the irrigated area. In this part of Diamond Valley, flow is from valley margins toward the irrigated area. In northern Diamond Valley, flow appears to remain generally northward to the large discharge area. Subsurface flow through mountain ranges has been identified from Garden Valley (outside the study area) through the Sulphur Springs Range to Diamond Valley and from southeastern Antelope Valley through the Fish Creek Range to Little Smoky Valley (outside the study area). In both cases, the flow is probably through carbonate rocks. Ground-water levels in the Diamond Valley flow system have changed during the past 40 years. These changes are the result of pumpage for irrigation, municipal, domestic, and mining uses, mostly in southern Diamond Valley, and annual and longer-term variations in precipitation in undeveloped parts of the study area. A large area of ground-water decline that underlies an area about 10 miles wide and 20 miles long has developed in the basin-fill aquifer of southern Diamond Valley. Water levels beneath the main part of the irrigated area have declined as much as 90 feet. In undeveloped parts of the study area, annual water-level fluctuations generally have been no more than a few feet.

Scientific Investigations Report

Effects of two stormwater management methods on the quality of water in the upper Biscayne aquifer at two commercial areas in Dade County, Florida

This study is part of a continued effort to assess the effects of urban stormwater recharge on the water quality of the Biscayne aquifer in southeast Florida. In this report, the water-quality effects on shallow ground water resulting from stormwater disposal by exfiltration trench and grassy swale were investigated at two small commercial areas in Dade County, Florida. One study area (airport) was located near the Miami International Airport and had a drainage area of about 10 acres overlying a sandy soil; the other study area (free zone) was located at the Miami International Free Trade Zone and had a drainage area of about 20 acres overlying limestone. The monitoring design for each study area consisted of seven sites and included water-quality sampling of the stormwater in the catch basin of the exfiltration trench, ground water from two wells 1 foot from the trench (trench wells), two wells 20 feet from the trench, and ground water from two wells at the swale from April 1985 through May 1986. Eleven water-quality variables (target variables) commonly found in high levels in urban stormwater runoff were used as tracers to estimate possible changes in ground-water quality that may have been caused by stormwater recharge. Comparison of the distribution of target variables indicated that the concentrations tended to be greater in the stormwater in the exfiltration trench than in water from the two wells 1 foot from the trench at both study areas. The concentration difference for several target variables was statistically significant at the 5-percent level. Lead, for example, had median concentrations of 23 and 4 micrograms per liter, respectively, in stormwater and water from the two trench wells at the airport study area, and 38 and 2 micrograms per liter, respectively, in stormwater and groundwater at the free zone. Similar reductions in concentrations between stormwater and water from the two trench wells were indicated for zinc at both study areas and also for nitrogen, phosphorus, and organic content at the free zone. This trend suggested that the exfiltration trench at both study areas may function as a partial trap for some chemical substances present in stormwater. A comparison of the distribution of the 11 target variables and major ionic composition in water from the two trench wells and the two wells 20 feet from the trench did not indicate a notable horizontal stratification at either study area. A vertical difference between 10 and 15 feet, however, was indicated at the free zone with major ions in greater concentrations at 15 feet. The vertical variability in groundwater near the trench at the free zone may have been the result of stormwater dilution in the upper (10-foot) zone. The ground-water quality at the swale was quite dissimilar to that near the exfiltration trench at both the airport and free zone study areas. Data indicated that the groundwater environment at both sales was anaerobic as evidenced by abundant ammonia nitrogen and iron and trace levels of sulfate. Anaerobic conditions at the swale may have been the result of poor drainage and high organic content of soils. Significant biochemical cycling in the ground water at the swales precluded any assessment of quality effects that may result from storm-water infiltration.

Florida

Paleontological analysis of a lacustrine carbonaceous uranium deposit at the Anderson mine, Date Creek basin, west-central Arizona (U.S.A.)

The Tertiary sedimentary sequence of the Date Creek basin area of Arizona is composed principally of intertonguing alluvial-fan and lacustrine deposits. The lacustrine rocks contain large intermediate- to, locally, high-grade uranium deposits that form one of the largest uranium resources in the United States (an estimated 670,000 tons of U 3 O 8 at an average grade of 0.023% is indicated by drilling to date). At the Anderson mine, about 50,000 tons of U 3 O 8 occurs in lacustrine carbonaceous siltstones and mudstones (using a cutoff grade of 0.01%). The Anderson mine constitutes a new class of ore deposit, a lacustrine carbonaceous uranium deposit. Floral and faunal remains at the Anderson mine played a critical role in creating and documenting conditions necessary for uranium mineralization. Organic-rich, uraniferous rocks at the Anderson mine contain plant remains and ostracodes having remarkably detailed preservation of internal features because of infilling by opaline silica. This preservation suggests that the alkaline lake waters in the mine area contained high concentrations of dissolved silica and that silicification occurred rapidly, before compaction or cementation of the enclosing sediment. Uranium coprecipitated with the silica. Thinly laminated, dark-colored, siliceous beds contain centric diatoms preserved with carbonaceous material suggesting that lake waters at the mine were locally deep and anoxic. These alkaline, silica-charged waters and a stagnant, anoxic environment in parts of the lake were necessary conditions for the precipitation of large amounts of uranium in the lake-bottom sediments. Sediments at the Anderson mine contain plant remains and pollen that were derived from diverse vegetative zones suggesting about 1500 m of relief in the area at the time of deposition. The pollen suggests that the valley floor was semiarid and subtropical, whereas nearby mountains supported temperate deciduous forests.

Nevada

Identifying a base network of federally funded streamgaging stations

The U.S. Geological Survey (USGS) has completed a preliminary analysis to identify streamgaging stations needed in a base network that would satisfy five primary Federal goals for collecting streamflow information. The five goals are (1) determining streamflow at interstate and international borders and at locations mandated by court decrees, (2) determining the streamflow component of water budgets for the major river basins of the Nation, (3) providing real-time streamflow information to the U.S. National Weather Service to support flood-forecasting activities, (4) providing streamflow information at locations of monitoring stations included in USGS national water-quality networks, and (5) providing streamflow information necessary for regionalization of streamflow characteristics and assessing potential long-term trends in streamflow associated with changes in climate. The analysis was done using a Geographic Information System. USGS headquarters staff made initial selections of stations that satisfied at least one of the five goals, and then staff in each of the 48 USGS district offices reviewed the selections, making suggestions for additions or changes based on detailed local knowledge of the streams in the area. The analysis indicated that 4,242 streamgaging stations are needed in the base network to meet the 5 Federal goals for streamflow information. Of these, 2,692 stations (63.5 percent) are currently operated by the USGS, 277 stations (6.5 percent) are currently operated by other agencies, 865 (20.4 percent) are discontinued USGS stations that need to be reactivated, and 408 (9.6 percent) are locations where new stations are needed. Copyright ASCE 2004.

Conference Paper

An occurrence of metastable cristobalite in high-pressure garnet Granulite

High-pressure (0.8 gigapascals) granulite facies garnet from Gore Mountain, New York, hosts multiple solid inclusions containing the low- pressure silica polymorph cristobalite along with albite and minor ilmenite. Identification of cristobalite is based on Raman spectra, electron microprobe analysis, and microthermometric measurements on the ??/?? phase transformation. The cristobalite plus albite inclusions may have originated as small, trapped samples of hydrous sodium-aluminum-siliceous melt. Diffusive loss of water from these inclusions under isothermal, isochoric conditions may have resulted in a large enough internal pressure decrease to promote the metastable crystallization of cristobalite.

Science

Informing ASR treatment practices in a Florida aquifer through a human health risk approach

Aquifer storage and recovery (ASR) can augment water supplies and hydrologic flows under varying climatic conditions. However, imposing drinking water regulations on ASR practices, including pre-treatment before injection into the aquifer, remains arguable. Microbial inactivation data— Escherichia coli , Pseudomonas aeruginosa , poliovirus type 1 and Cryptosporidium parvum —were used in a human health risk assessment to identify how the storage time of recharged water in the Floridan Aquifer enhances pathogen inactivation, thereby mitigating the human health risks associated with ingestion. We used a quantitative microbial risk assessment to evaluate the risks for a gastrointestinal infection (GI) and the associated disability-adjusted life years (DALYs) per person per year. The risk of developing a GI infection for drinking water no longer exceeded the suggested annual risk threshold (1 × 10 −4 ) by days 31, 1, 52 and 80 for each pathogen, respectively. DALYs per person per year no longer exceeded the World Health Organization threshold (1 × 10 −6 ) by days 27, <1, 43 and 72. In summary, storage time in the aquifer yields a significant reduction in health risk. The findings emphasize that considering microbial inactivation, caused by storage time and geochemical conditions within ASR storage zones, is critical for recharge water treatment processes.

Florida

Land subsidence in the San Joaquin Valley, California, USA, 2007-14

Rapid land subsidence was recently measured using multiple methods in two areas of the San Joaquin Valley (SJV): between Merced and Fresno (El Nido), and between Fresno and Bakersfield (Pixley). Recent land-use changes and diminished surface-water availability have led to increased groundwater pumping, groundwater-level declines, and land subsidence. Differential land subsidence has reduced the flow capacity of water-conveyance systems in these areas, exacerbating flood hazards and affecting the delivery of irrigation water. Vertical land-surface changes during 2007–2014 were determined by using Interferometric Synthetic Aperture Radar (InSAR), Continuous Global Positioning System (CGPS), and extensometer data. Results of the InSAR analysis indicate that about 7600 km 2 subsided 50–540 mm during 2008–2010; CGPS and extensometer data indicate that these rates continued or accelerated through December 2014. The maximum InSAR-measured rate of 270 mm yr −1 occurred in the El Nido area, and is among the largest rates ever measured in the SJV. In the Pixley area, the maximum InSAR-measured rate during 2008–2010 was 90 mm yr −1 . Groundwater was an important part of the water supply in both areas, and pumping increased when land use changed or when surface water was less available. This increased pumping caused groundwater-level declines to near or below historical lows during the drought periods 2007–2009 and 2012–present. Long-term groundwater-level and land-subsidence monitoring in the SJV is critical for understanding the interconnection of land use, groundwater levels, and subsidence, and evaluating management strategies that help mitigate subsidence hazards to infrastructure while optimizing water supplies.

California

The natural history of Caroline Atoll, Southern Line Islands. Part II. Seabirds, other terrestrial animals, and conservation

conclusion: Lushly wooded Caroline Atoll, with the majority of its 39 islets (399 ha of land) either in near-pristine condition or having recovered remarkably from past disturbance, is one of the least spoiled atolls in the Pacific. Uninhabited, it harbors plant ecosystems and breeding seabirds (Pt. II) of national and international importance. Its marine and terrestrial ecosystems are prime outdoor ecological laboratories for research on geological processes including ground water, sea level changes, the dynamics of motu formation, fish poisoning, and numerous facets of ecology including plant succession and Pisonia growth rates. Caroline boasts prime coral reefs thickly studded with Tridacna clams, substantial numbers of coconut crabs, breeding sites for green turtles, wintering grounds for shorebirds including the rare Bristle-thighed Curlew, ancient Tuamotuan marae, and a crystalline, unpolluted lagoon. The variety, abundance, and quality of its flora and fauna qualify it for status as an officially recognized international preserve (Pt. II, Sect. G). Efforts toward its conservation have thus far been unsuccessful: in 1992 it was leased to a private French businessman who is currently fishing the reefs for commercial profit, as well as disturbing seabird, turtle and coconut crab populations.

Atoll Research Bulletin

The natural history of Caroline Atoll, Southern Line Islands. Part I. History, physiography, botany, and isle descriptions

conclusion: Lushly wooded Caroline Atoll, with the majority of its 39 islets (399 ha of land) either in near-pristine condition or having recovered remarkably from past disturbance, is one of the least spoiled atolls in the Pacific. Uninhabited, it harbors plant ecosystems and breeding seabirds (Pt. II) of national and international importance. Its marine and terrestrial ecosystems are prime outdoor ecological laboratories for research on geological processes including ground water, sea level changes, the dynamics of motu formation, fish poisoning, and numerous facets of ecology including plant succession and Pisonia growth rates. Caroline boasts prime coral reefs thickly studded with Tridacna clams, substantial numbers of coconut crabs, breeding sites for green turtles, wintering grounds for shorebirds including the rare Bristle-thighed Curlew, ancient Tuamotuan marae, and a crystalline, unpolluted lagoon. The variety, abundance, and quality of its flora and fauna qualify it for status as an officially recognized international preserve (Pt. II, Sect. G). Efforts toward its conservation have thus far been unsuccessful: in 1992 it was leased to a private French businessman who is currently fishing the reefs for commercial profit, as well as disturbing seabird, turtle and coconut crab populations.

Atoll Research Bulletin

Hydrology of the Helena area bedrock, west-central Montana, 1993-98

The Generalized Bedrock Geologic Map of the Helena Area, West-Central Montana (plate 1 in the report) provides an intermediate-scale overview of bedrock in the Helena area. The geologic map has been compiled at a scale of 1:100,000 from the most widely available sources of geologic map information (see index to geologic mapping on pl. 1). That information has been updated by M.W. Reynolds for this report with more recent geologic mapping and field revision of published maps. All well locations and all bedrock units penetrated during drilling have been confirmed on geologic maps at the largest scale available. Source geologic maps are all at scales larger than 1:100,000 scale. Care has been taken to ensure accurate representation of the original geology at the compilation scale. However, positional accuracy of some features might be somewhat diminished at the smaller scale of the base map when compared with the original data source. Also, line thicknesses for contacts and faults necessarily assume a greater width, relative to the real geologic feature, at the scale of the generalized map than on any original map. The map is not intended for large-scale, site-specific detailed planning. Bedrock units throughout the Helena area are generally covered by young surficial deposits such as alluvium, colluvium, glacial debris, or windblown sediment. Thickness of such deposits varies from veneers through which the underlying bedrock is clearly discernible to major thicknesses that conceal all underlying bedrock and structure. Boundaries of major accumulations of surficial deposits are attributed separately from bedrock contacts. These boundaries should not be considered precise at the map scale or at larger scales. Boundaries shown may be less accurate positionally than bedrock contacts and faults because (1) surficial deposits commonly thin to a knife edge; (2) different mappers will interpret the edge differently when drawing a boundary; or (3) the original geologic map maker was concerned principally with bedrock units and structure and thus overlooked, or did not originally map as consistently, some surficial deposits. Veneers of surficial sediment, when saturated, can be local sources of recharge to underlying bedrock. Use of the generalized map to define their distribution does not substitute for site specific mapping of such deposits. Specific knowledge is needed to determine the water-bearing properties of the geologic units at and surrounding a site because the units, including the igneous and metamorphic rocks, have internal differences in stratigraphy, composition, mineralogy and grain size or crystallinity. These differences, together with structural imprints such as faults, folds, and the spacing, orientation, degree of openness of fractures, and extent and type of mineral filling in fractures and faults, all affect the ability of rocks to store and transmit water.

Montana

Investigation of drivers and sources of potential harmful algal blooms in Lake Anna, Virginia, 2023-24

Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.

EarthArXiv

Counting at low concentrations: the statistical challenges of verifying ballast water discharge standards

Discharge from the ballast tanks of ships is one of the primary vectors of nonindigenous species in marine environments. To mitigate this environmental and economic threat, international, national, and state entities are establishing regulations to limit the concentration of living organisms that may be discharged from the ballast tanks of ships. The proposed discharge standards have ranged from zero detectable organisms to <10 organisms/m 3 . If standard sampling methods are used, verifying whether ballast discharge complies with these stringent standards will be challenging due to the inherent stochasticity of sampling. Furthermore, at low concentrations, very large volumes of water must be sampled to find enough organisms to accurately estimate concentration. Despite these challenges, adequate sampling protocols comprise a critical aspect of establishing standards because they help define the actual risk level associated with a standard. A standard that appears very stringent may be effectively lax if it is paired with an inadequate sampling protocol. We describe some of the statistical issues associated with sampling at low concentrations to help regulators understand the uncertainties of sampling as well as to inform the development of sampling protocols that ensure discharge standards are adequately implemented.

Ecological Applications