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At least 379 records · Page 21Linked to original sources

Rock chemistry and fluid inclusion studies as exploration tools for ore deposits in the Sila batholith, southern Italy

The Sila batholith is the focus of an extensive petrogenetic research program, which includes an assessment of its potential to host granite-related ore deposits. Univariate and multivariate statistical techniques were applied to major- and minor-element rock geochemical data. The analysis indicates that the highest potential for mineralization occurs in corundum-normative, peraluminous, unfoliated, relatively late-stage plutons. The plutons are enriched in Rb, Nb, Ta and U, but depleted in Fe, Mg and Sr. The K/Rb, Ba/Rb, Rb/Sr and Rb 3 /Ba·Sr·K indices and high R -factor scores of Si-K-Rb are typical of mineralized granitic rocks. A reconnaissance fluid inclusion study indicates that the sub-solidus rock was infiltrated by solutions of widely different temperatures (50–416°C) and variable salinities (0 to ∼26 wt.% NaCl equivalent). The higher-temperature solutions probably represent granite or magmatic-related Hercynian fluids, whereas the lower-temperature fluids may be either Hercynian or Alpine in age. Fluids with characteristics typical of mineralized “porphyry” systems have not been recognized.

Journal of Geochemical Exploration

Boron analysis by electron microprobe using MoB4C layered synthetic crystals

Preliminary electron microprobe studies of B distribution in minerals have been carried out using MoB4C-layered synthetic crystals to improve analytical sensitivity for B. Any microprobe measurements of the B contents of minerals using this crystal must include analyses for Cl to assess and correct for the interference of Cl X-rays on the BK?? peak. Microprobe analyses for B can be made routinely in tourmaline and other B-rich minerals, and minor B contents also can be determined in common rock-forming minerals. Incorporation of unusually high B contents in minerals other than borosilicates has been discovered in prograde and retrograde minerals in tourmalinites from the Broken Hill district, Australia, and may reflect high B activities produced during the metamorphism of tourmaline-rich rocks. -from Authors

American Mineralogist

Geochronology of the western and central Brooks Range, Alaska: Implications for the geologic evolution of the Anarraaq and Red Dog Zn-Pb-Ag deposits

A compilation of published geochronology of rocks and minerals from the western and central Brooks Range provides a framework for understanding the complex history of the Brooks Range and northern Alaska. A simplified timeline of events comprises (1) Devonian extension, (2) Mississippian extension and Zn-Pb-Ag mineralization, (3) a passive interval, (4) pre-Brooks Range orogeny rock-formation and thermal event, (5) inception of Brooks Range orogeny, (6) exhumation and the end of main-stage deformation, and (7) subsequent episodic deformation. This compilation is supplemented by new 40Ar/39Ar dates of white mica from the Anarraaq and Red Dog Zn-Pb-Ag (+ barite) deposits from the western Brooks Range. The deposits are hosted in black shale and carbonate rocks of the Late Mississippian-Early Pennsylvanian Kuna Formation. Quartz-pyrite-white mica grains in sedimentary rocks above the Anarraaq deposit yield an age of 195.0 ?? 2.0 Ma, and paragenetically late quartz-pyrite-white mica from the Main orebody at the Red Dog deposit has an age of 126.1 ?? 0.7 Ma. These white micas are much younger than the age of Zn-Pb-Ag mineralization at Red Dog (338 ?? 5.8 Ma Re-Os age of pyrite). The date for white mica from Anarraaq (???195 Ma) appears to be related to a large-scale thermal event in the region immediately before the inception of the Brooks Range orogeny. The white mica from the Red Dog deposit (???126 Ma) correlates with the later stages of the orogeny, a period of blueschist metamorphism, extension, and rapid exhumation, which varied with geographic location. These dates suggest that the Red Dog deposits underwent significant hydrothermal overprinting during multiple episodes of the Brooks Range orogeny. ?? 2004 by Economic Geology.

Economic Geology

Geological assessment of cores from the Great Bay National Wildlife Refuge, New Hampshire

Geological sources of metals (especially arsenic and zinc) in aquifer bedrock were evaluated for their potential to contribute elevated values of metals to ground and surface waters in and around Rockingham County, New Hampshire. Ayotte and others (1999, 2003) had proposed that arsenic concentrations in ground water flowing through bedrock aquifers in eastern New England were elevated as a result of interaction with rocks. Specifically in southeastern New Hampshire, Montgomery and others (2003) established that nearly one-fifth of private bedrock wells had arsenic concentrations that exceed the U.S. Environmental Protection Agency (EPA) maximum contamination level for public water supplies. Two wells drilled in coastal New Hampshire were sited to intersect metasedimentary and metavolcanic rocks in the Great Bay National Wildlife Refuge. Bulk chemistry, mineralogy, and mineral chemistry data were obtained on representative samples of cores extracted from the two boreholes in the Kittery and Eliot Formations. The results of this study have established that the primary geologic source of arsenic in ground waters sampled from the two well sites was iron-sulfide minerals, predominantly arsenic-bearing pyrite and lesser amounts of base-metal-sulfide and sulfosalt minerals that contain appreciable arsenic, including arsenopyrite, tetrahedrite, and cobaltite. Secondary minerals containing arsenic are apparently limited to iron-oxyhydroxide minerals. The geologic source of zinc was sphalerite, typically cadmium-bearing, which occurs with pyrite in core samples. Zinc also occurred as a secondary mineral in carbonate form. Oxidation of sulfides leading to the liberation of acid, iron, arsenic, zinc, and other metals was most prevalent in open fractures and vuggy zones in core intervals containing zones of high transmissivity in the two units. The presence of significant calcite and lesser amounts of other acid-neutralizing carbonate and silicate minerals, acting as a natural buffer to reduce acidity, forced precipitation of iron-oxyhydroxide minerals and the removal of trace elements, including arsenic and lead, from ground waters in the refuge. Zinc may have remained in solution to a greater extent because of complexing with carbonate and its solubility in near-neutral ground and surface waters. The regional link between anomalously high arsenic contents in ground water and a bedrock source as established by Ayotte and others (1999, 2003) and Montgomery and others (2003) was confirmed by the presence of some arsenic-bearing minerals in rocks of the Kittery and Eliot Formations. The relatively low amounts of arsenic and metals in wells in the Great Bay National Wildlife Refuge as reported by Ayotte and others (U.S. Geological Survey Water Resources Data, 2005) were likely controlled by local geochemical environments in partially filled fractures, fissures, and permeable zones within the bedrock formations. Carbonate and silicate gangue minerals that line fractures, fissures, and permeable zones likely limited the movement of arsenic from bedrock to ground water. Sources other than the two geologic formations might have been required to account for anomalously high arsenic contents measured in private bedrock aquifer wells of Rockingham County.

New Hampshire

Effects of interaction between ultramafic tectonite and mafic magma on Nd-Pb-Sr isotopic systems in the Neoproterozoic Chaya Massif, Baikal-Muya ophiolite belt

Sm-Nd, Rb-Sr and U-Pb isotopic systems have been studied in minerals and whole rocks of harzburgites and mafic cumulates from the Chaya Massif, Baikal-Muya ophiolite belt, eastern Siberia, in order to determine the relationship between mantle ultramafic and crustal mafic sections. Geological relations in the Chaya Massif indicate that the mafic magmas were emplaced into, and interacted with older solid peridotite. Hand picked, acid-leached, primary rock-forming and accessory minerals (olivine, orthopyroxene, clinopyroxene and plagioclase) from the two harzburgite samples show coherent behavior and yield 147 Sm/ 144 Nd- 143 Nd/ 144 Nd and 238 U/ 204 Pb- 206 Pb/ 204 Pb mineral isochrons, corresponding to ages of 640 ± 58 Ma (95% confidence level) and 620 ± 71 Ma, respectively. These values are indistinguishable from the crystallization age of the Chaya mafic units of 627 ± 25 Ma (a weighted average of internal isochron Sm-Nd ages of four mafic cumulates). The Rb-Sr and Sm-Nd isotopic systems in the harzburgite whole-rock samples were disturbed by hydrothermal alteration. These alteration-related isotopic shifts mimic the trend of variations in primary isotopic compositions in the mafic sequence, thus emphasizing that isotopic data for ultramafic rocks should be interpreted with great caution. On the basis of initial Sr and Nd values, ultramafic and mafic rocks of the Chaya Massif can be divided into two groups: (1) harzburgites and the lower mafic unit gabbronorites withε Nd = +6.6 to +7.1 andε Sr = −11 to −16; and (2) websterite of the lower unit and gabbronorites of the upper mafic unit:ε Nd = +4.6 to +6.1 andε Sr = −8 to −9. Initial Pb isotopic ratios are identical in all rocks studied, with mean values of 206 Pb/ 204 Pb= 16.994 ± 0.023 and 207 Pb/ 204 Pb= 15.363 ± 0.015. The similarity of ages and initial isotopic ratios within the first group indicates that the isotopic systems in the pre-existing depleted peridotite were reset by extensive interaction with basaltic magma during formation of the mafic crustal sequence. The isotopic data agree with a hypothesized formation of the Chaya Massif in a suprasubduction-zone environment.

Siberia

Mineral potential of felsic plutonic rocks in the north-central Arabian Shield, Kingdom of Saudi Arabia

Fourteen plutons of Late Proterozoie age potentially favorable for rare-element mineralization have been identified in a geochemical and petrographic assessment of felsic plutonic rocks in the north-central Arabian Shield (lat 23°00'-25°00' N., long 40°00'-45°00' E.). The plutons are highly fractionated, leucocratic granitoids assigned to a major magmatic pulse that spanned the later stages of the Hijaz orogeny (about 610 Ma to about 550 Ma). Most of the targeted plutons are small or not deeply eroded. Two rock types are dominant: subsolvus, muscovite-bearing monzogranite or syenogranite; and hypersolvus, mieroeline perthite granite commonly containing sodic pyriboles. Enrichment in varied suites of the granitophile elements (Sn-W-NbTa-Zr-Y-Th-U) is characteristic. The plutons occupy the central part of a broad arcuate belt of geochemically specialized plutons that conforms generally to the eastern limit of exposed Proterozoic basement. The muscovite-bearing monzogranites containing anomalous tin and tungsten in rock and (or) wadi sediment samples occur generally east of long 42°30' E. Two of these, Jabal Minya and Jabal Khinzir, are recommended for immediate follow-up studies. Of the alkali granites, most of which occur in the area west of long 42°30' E., the composite plutons of Jabal Hadb ad Dayahin and Jabal Tuqfah have the highest potential for rare-element mineralization and warrant prompt systematic investigation. Evaluation of isolated one- or two-element anomalies should be coordinated with current high-density geochemical prospecting programs of the Riofinex Geological Mission.

Open-File Report

Geology and ore deposits in the Reid Inlet area, Glacier Bay, Alaska, with added notes on a mineralized zone near Lituya Bay

A gold-bearing area of about 7 1/2 square miles, first discovered by Mr. Joseph Ibach in 1924, exists near the head of Glacier Bay between Reid and Lamplugh glaciers. The dominant rock type in the area is granodiorite which is intruded into bedded rocks that may be of Paleozoic age. The bedded rocks consist of conglomerate, limestone, and black graphitic schist. A light-colored quartz diorite younger than the granodiorite crops out south of the mapped area. Most of the ore deposits are found in fissure type quartz veins. These occur in both the granodiorite and in the older bedded rocks. The mineralizing solutions which brought in the gold have altered the country rock for as much as a few tens of feet to each side of the fissures. Locally, this altered rock is gold-bearing, but in the places sampled the gold content was found to be too low to permit profitable mining. Most of the quartz veins tend to be lenticular, both horizontally and vertically, and the gold tends to be concentrated in discrete spots along the veins. These factors tend to make the ore spotty and its location unpredictable. This has given rise to the concept that the ore in the area has a tendency not to continue below the surface. Geologically there appears to be no reason to believe that gold mineralization is confined to surface outcrop. The Leroy and Rainbow properties are the only two that have yielded significant quantities of gold within the mapped area, but the veins on the Highland Chief and probably the Rambler claims appear to be of sufficient size and grade to be potential ore producers. The LeRoy mine is the largest in the area. The ore body consisted of a fissure type quartz vein averaging between 2 and 3 feet in width with a length of about 60 feet, but in 1954, all of the ore in the main vein had been mined out above the main working level. Ore probably amounting to several hundreds of tons was mined and milled from the Rainbow vein. The results of an investigation of a mineralized area near Lituya Bay is included in this report. The mineralized material consists of hydrothermally altered rock found in volcanic rocks believed to be of Mesozoic age. The gold content is too low to permit profitable mining, although it is possible that undiscovered spots exist in which the gold concentration is sufficiently high to be of economic significance.

Alaska

Distribution of hydrothermally altered rocks in the Reko Diq, Pakistan mineralized area based on spectral analysis of ASTER data

The Reko Diq, Pakistan mineralized study area, approximately 10??km in diameter, is underlain by a central zone of hydrothermally altered rocks associated with Cu-Au mineralization. The surrounding country rocks are a variable mixture of unaltered volcanic rocks, fluvial deposits, and eolian quartz sand. Analysis of 15-band Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data of the study area, aided by laboratory spectral reflectance and spectral emittance measurements of field samples, shows that phyllically altered rocks are laterally extensive, and contain localized areas of argillically altered rocks. In the visible through shortwave-infrared (VNIR + SWIR) phyllically altered rocks are characterized by Al-OH absorption in ASTER band 6 because of molecular vibrations in muscovite, whereas argillically altered rocks have an absorption feature in band 5 resulting from alunite. Propylitically altered rocks form a peripheral zone and are present in scattered exposures within the main altered area. Chlorite and muscovite cause distinctive absorption features at 2.33 and 2.20????m, respectively, although less intense 2.33????m absorption is also present in image spectra of country rocks. Important complementary lithologic information was derived by analysis of the spectral emittance data in the 5 thermal-infrared (TIR) bands. Silicified rocks were not distinguished in the 9 VNIR + SWIR bands because of the lack of diagnostic spectral absorption features in quartz in this wavelength region. Quartz-bearing surficial deposits, as well as hydrothermally silicified rocks, were mapped in the TIR bands by using a band 13/band 12 ratio image, which is sensitive to the intensity of the quartz reststrahlen feature. Improved distinction between the quartzose surficial deposits and silicified bedrock was achieved by using matched-filter processing with TIR image spectra for reference. ?? 2006 Elsevier Inc. All rights reserved.

Remote Sensing of Environment

40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been migrating toward, and subparallel to, the northeast margin of the Colorado Plateau since the middle Miocene. Quaternary volcanism within this northern Rio Grande rift corridor is evidence that the rift is continuing to evolve.

Colorado

Scapolite in the Belt Series in the St. Joe-Clearwater Region, Idaho

S capolite is a common rock-forming mineral in parts of the Belt Series of Precambrian age in southern Shoshone County and adjoining parts of Clearwater County, Idaho. It is most abundant in moderately metamorphosed calcareous shaly layers of the Wallace Formation but occurs also in their highly metamorphosed equivalents and in the lowest part of the Prichard Formation. The mode of occurrence varies with distance from the Idaho batholith, with bulk composition, and with grade of metamorphism. In the northern part of the area where rocks were metamorphosed to the epidote-amphibolite facies, the highest concentration of scapolite is in layers rich in calcite, biotite, or hornblende and diopside. In biotite-rich layers interbedded with quartzite, scapolite is in round holoblasts; in carbonate granofels, crystals are euhedral to subhedral; and in hornblende- and diopside-bearing layers, small anhedral grains are common. In rocks metamorphosed to the amphibolite facies, such as diopside gneiss and calcium-magnesium-aluminum silicate rocks (here named “camalsite”), scapolite occurs in small anhedral grains. In diopside gneiss, scapolite is in thin layers that extend long distances parallel to the bedding. In camalsite, small masses exceptionally rich in scapolite are common. The mode of occurrence and the distribution parallel to the bedding suggest that scapolite crystallized from a sedimentary rock that contained saline minerals. The scapolite contains much Cl but only a little SO 3 , suggesting that halite was the chief source mineral. The local high concentrations of scapolite occur in a zone where elements have been redistributed, either because of metamorphism of dispersed or layered saline minerals with accompanying migration of chlorine or because of metamorphism of primary local masses of such minerals.

Idaho

In situ evidence for an ancient aqueous environment at Meridiani Planum, Mars

Sedimentary rocks at Eagle crater in Meridiani Planum are composed of fine-grained siliciclastic materials derived from weathering of basaltic rocks, sulfate minerals (including magnesium sulfate and jarosite) that constitute several tens of percent of the rock by weight, and hematite. Cross-stratification observed in rock outcrops indicates eolian and aqueous transport. Diagenetic features include hematite-rich concretions and crystal-mold vugs. We interpret the rocks to be a mixture of chemical and siliciclastic sediments with a complex diagenetic history. The environmental conditions that they record include episodic inundation by shallow surface water, evaporation, and desiccation. The geologic record at Meridiani Planum suggests that conditions were suitable for biological activity for a period of time in martian history.

Science

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington

40Ar/39Ar geochronology supporting mineral resources research at USGS Denver

The 40 Ar/ 39 Ar geochronology method is used to date potassium-bearing rocks and minerals, based on the decay of 40 K to 40 Ar, which provides important temporal constraints for geological events. The USGS Denver Argon Geochronology Laboratory dates samples from a variety of projects, mainly in the USGS Mineral Resource Program and the National Cooperative Geologic Mapping Program, facilitating in-depth research into the timing of geological events and processes. Recent applications of this method include geochronological studies in the Yellow Pine district, revealing mineralization ages that range from 51 to 70 Ma, and investigations into the Bear Lodge alkaline complex, providing insights into the timing of REE carbonatite formation. Additionally, studies at Alunite Ridge highlight the method's potential for understanding concealed mineral deposits. Ongoing projects continue to leverage 40 Ar/ 39 Ar data to enhance understanding of geologic frameworks and mineral resources, underpinning its importance in modern geochronology and mineral resource assessment.

Conference Paper

Effect of sample inhomogeneity in K Ar dating

Error in K-Ar ages is often due more to deficiencies in the splitting process, whereby portions of the sample are taken for potassium and for argon determination, than to imprecision in the analytical methods. The effect of the grain size of a sample and of the composition of a contaminating mineral can be evaluated, and this provides a useful guide in attempts to minimize error. Rocks and minerals should be prepared for age determination with the effects of contaminants and grain size in mind. The magnitude of such effects can be much larger than intuitive estimates might indicate.

Geochimica et Cosmochimica Acta

Textures of the soils and rocks at Gusev Crater from Spirit’s Microscopic Imager

The Microscopic Imager on the Spirit rover analyzed the textures of the soil and rocks at Gusev crater on Mars at a resolution of 100 micrometers. Weakly bound agglomerates of dust are present in the soil near the Columbia Memorial Station. Some of the brushed or abraded rock surfaces show igneous textures and evidence for alteration rinds, coatings, and veins consistent with secondary mineralization. The rock textures are consistent with a volcanic origin and subsequent alteration and/or weathering by impact events, wind, and possibly water.

Science

Stable isotope and chemical relations during mineralization in the Bodie mining district, Mono County, California

Stable isotope and chemical relations have been determined in a typical epithermal Au-Ag deposit located in the Bodie mining district of California. Analyses were made of altered host rocks, vein minerals, alteration clays, fluid inclusions, modern spring waters, and unaltered rocks of the area.The results indicate that a hydrothermal convection system was set up by the interaction of a cooling shallow intrusion and local meteoric water. The water traveled to depth where it picked up ore constituents and SiO 2 , K, and Rb, without significant shifts in the stable isotope ratios of the water. The altered rocks have equilibrated to various degrees with an ore fluid of constant K/Rb, O 18 /O 16 and D/H ratios. Deposition of ore took place over the approximate temperature range 215 degrees -245 degrees . From C 13 /C 12 ratios of minor calcite, a volcanic source of CO 2 is postulated. The chemical and isotope composition of the ore fluid is strikingly similar to that of modern spring waters in the area.All ore deposition at Bodie took place from essentially isotopically unaltered ground water with delta O 18 = -13ppm and delta D = -98ppm.

California

The Early Jurassic Bokan Mountain peralkaline granitic complex (southeastern Alaska): geochemistry, petrogenesis and rare-metal mineralization

The Early Jurassic (ca. 177 Ma) Bokan Mountain granitic complex, located on southern Prince of Wales Island, southernmost Alaska, cross-cuts Paleozoic igneous and metasedimentary rocks of the Alexander terrane of the North American Cordillera and was emplaced during a rifting event. The complex is a circular body (~3 km in diameter) of peralkaline granitic composition that has a core of arfvedsonite granite surrounded by aegirine granite. All the rock-forming minerals typically record a two-stage growth history and aegirine and arfvedsonite were the last major phases to crystalize from the magma. The Bokan granites and related dikes have SiO 2 from 72 to 78 wt. %, high iron (FeO (tot) ~3-4.5 wt. %) and alkali (8-10 wt.%) concentrations with high FeO (tot) /(FeO (tot) +MgO) ratios (typically >0.95) and the molar Al 2 O 3 /(Na 2 O+K 2 O) ratio <1. The granitic rocks are characterized by elevated contents of rare earth elements (REE), Th, U and high field strength elements (HFSE) and low contents of Ca, Sr, Ba and Eu, typical of peralkaline granites. The granites have high positive ε Nd values which are indicative of a mantle signature. The parent magma is inferred to be derived from an earlier metasomatized lithospheric mantle by low degrees of partial melting and generated the Bokan granitic melt through extensive fractional crystallization. The Bokan complex hosts significant rare-metal (REE, Y, U, Th, Nb) mineralization that is related to the late-stage crystallization history of the complex which involved the overlap of emplacement of felsic dikes, including pegmatite bodies, and generation of orthomagmatic fluids. The abundances of REE, HFSE, U and Th as well as Pb and Nd isotopic values of the pluton and dikes were modified by orthomagmatic hydrothermal fluids highly enriched in the strongly incompatible trace elements, which also escaped along zones of structural weakness to generate rare-metal mineralization. The latter was deposited in two stages: the first relates to the latest stage of magma emplacement and is associated with felsic dikes that intruded along the faults and shear deformations, whereas the second stage involved ingress of hydrothermal fluids that both remobilized and enriched the initial magmatic mineralization. Mineralization is mostly composed of new minerals. Fluorine complexing played a role during the transportation of REE and HFSE in hydrothermal fluids and oxygen isotopes in the granites and quartz veins negate the significant incursion of an external fluid and support a dominantly orthomagmatic hydrothermal system. Many other REE-HFSE deposits hosted by peralkaline felsic rocks (nepheline syenites, peralkaline granites and peralkaline trachytes) were formed by a similar two stage process.

Alaska