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At least 379 records · Page 21Linked to original sources

Weathering of the meade peak phosphatic shale member, phosphoria formation: Observations based on uranium and its decay products

Variably weathered outcrop samples of the Meade Peak Phosphatic Shale Member of the Phosphoria Formation have 5-10% of the contained uranium (U) in a form readily extractable by 0.1 M sodium bicarbonate. Fission track radiography of outcrop samples and other less-weathered channel and core samples indicate that this mobile fraction of U is likely hosted by organic matter, secondary iron oxides and clay minerals, trace uraninite, and very fine-grained apatite cement. During weathering, this extractable U fraction is especially susceptible to redistribution, which produces small but measurable departures (1-15%) from radioactive (secular) equilibrium in the 238 U decay-series. The most weath- ered samples show the strongest isotopic evidence for redistribution of U during the last 350 ka, but sequestration of U by alteration products limits open-system losses of U at the whole-rock scale. In less-weathered samples, isotopic evidence for minor U loss (or gain) over longer time periods (1 Ma) is consistent with relatively non-aggressive attack of phosphatic rock during weathering. Comparative extractability of selenium (Se) suggests that a larger fraction of Se (19%) is readily available for mobilization during the earliest stages of weathering.

Book chapter↗

Late Quaternary loess and soils on uplands in the Canyonlands and Mesa Verde areas, Utah and Colorado

Thin loess deposits on the uplands of the southeastern Colorado Plateau have previously not been well studied. We sampled deposits and soils from trenches on Hatch Point (HP) mesa near Canyonlands National Park, Utah, and from two outcrops in Mesa Verde National Park, Colorado. At HP, the oldest buried unit yielded 2 optically stimulated luminescence (OSL) ages of 10,370 and 7555 yr; the middle unit yielded 10 OSL ages from 6220 to 1385 yr; and the youngest unit had a single age of 1740 yr. At Mesa Verde (MV), three loess units are preserved in the two outcrops we examined; 6 OSL ages range from 51 to 17 ka. At least one buried soil is present between two units with ages of about 50 and 40 ka. The ages of the loess units in both study areas correspond well with OSL-dated dune sands in Canyonlands National Park and with dune sands on Black Mesa, Arizona. Particle-size distribution combined with chemical and magnetic data indicate that HP loess was derived mostly from nearby sandstone sources with a small component of far-traveled atmospheric dust, whereas MV loess was sourced both from the nearby sandstone and the San Juan River and its tributaries.

Colorado, Utah↗

Seismic mapping of shallow fault zones in the San Gabriel Mountains from the Los Angeles Region Seismic Experiment, southern California

During the Los Angeles Region Seismic Experiment (LARSE), a reflection/refraction survey was conducted along a profile (line 1) extending from Seal Beach, California, northeastward to the Mojave Desert and crossing the Los Angeles and San Gabriel Valley basins and San Gabriel Mountains. In most shot gathers from the southern and central San Gabriel Mountains, clear secondary arrivals are seen that merge, or appear to merge, with first arrivals at three locations, including the location of the Vincent thrust fault, an exposed late Mesozoic/early Cenozoic megathrust. These secondary arrivals are interpretable as reflections in the shallow crust (<5 km depth) from a concave-upward interface that projects to the surface in the north near the Vincent thrust fault, is offset in its central part at the San Gabriel fault (an old branch of the San Andreas fault), and terminates in the south at 1 to 2 km depth at the southern mountain front. The velocity structure above and below this interface strongly suggests it is the Vincent thrust fault: intermediate velocities (6.2 km/s), consistent with mylonites overlying the Vincent thrust fault, are observed above it; lower velocities (5.8 km/s), consistent with the Pelona Schist underlying the Vincent thrust fault, are observed below it. Problems arise, however, in attempting to match this reflector to the exposed Vincent thrust fault, which is seen in outcrops east of line 1. The Vincent thrust fault is shallower than the reflector in most places. An unmapped structure (steep fault, monocline, or thrust fault) is required between line 1 and the outcrops that either drops the Vincent thrust fault down to the depths of the reflector or repeats the Vincent thrust fault beneath line 1 in the footwall of another thrust fault. An alternative interpretation of the reflector is a deep greenstone horizon within the Pelona Schist, although this alternative is not favored by the velocity structure. Copyright 2001 by the American Geophysical Union.

California↗

Remotely sensed geology from lander-based to orbital perspectives: Results of FIDO rover May 2000 field tests

Blind field tests of the Field Integration Design and Operations (FIDO) prototype Mars rover were carried out 7-16 May 2000. A Core Operations Team (COT), sequestered at the Jet Propulsion Laboratory without knowledge of test site location, prepared command sequences and interpreted data acquired by the rover. Instrument sensors included a stereo panoramic camera, navigational and hazard-avoidance cameras, a color microscopic imager, an infrared point spectrometer, and a rock coring drill. The COT designed command sequences, which were relayed by satellite uplink to the rover, and evaluated instrument data. Using aerial photos and Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data, and information from the rover sensors, the COT inferred the geology of the landing site during the 18 sol mission, including lithologic diversity, stratigraphic relationships, environments of deposition, and weathering characteristics. Prominent lithologic units were interpreted to be dolomite-bearing rocks, kaolinite-bearing altered felsic volcanic materials, and basalt. The color panoramic camera revealed sedimentary layering and rock textures, and geologic relationships seen in rock exposures. The infrared point spectrometer permitted identification of prominent carbonate and kaolinite spectral features and permitted correlations to outcrops that could not be reached by the rover. The color microscopic imager revealed fine-scale rock textures, soil components, and results of coring experiments. Test results show that close-up interrogation of rocks is essential to investigations of geologic environments and that observations must include scales ranging from individual boulders and outcrops (microscopic, macroscopic) to orbital remote sensing, with sufficient intermediate steps (descent images) to connect in situ and remote observations.

Journal of Geophysical Research E: Planets↗

Evidence of phyllosilicates in Wooly Patch, an altered rock encountered at West Spur, Columbia Hills, by the Spirit rover in Gusev crater, Mars

On its traverse to Columbia Hills, the Mars Exploration Rover Spirit investigated an outcrop designated “Wooly Patch” that exhibited morphological, mineralogical, and geochemical characteristics at the extreme ends of ranges observed among rocks studied at West Spur, a westward projecting salient near the foot of the Columbia Hills, Gusev crater. The major‐element composition and Fe‐mineralogy, as determined by the Alpha‐Particle X‐ray Spectrometer and Mössbauer Spectrometer, are inconsistent with any reasonable assemblage of basaltic minerals in that there is an excess of Si and Al. The combined data are best explained by the presence of 14–17% phyllosilicate minerals. Phyllosilicates that account for the composition and cation ratios include members of the kaolinite, serpentine, chlorite, and septechlorite groups. The potential existence of kaolinite‐type Al‐rich phyllosilicates within the Wooly Patch outcrop suggests a mildly acidic environment (pH 4–6) in the past and an open hydrologic system with good drainage conditions in the environment where these rocks were altered.

Journal of Geophysical Research E: Planets↗

Nature and origin of the hematite-bearing plains of Terra Meridiani based on analyses of orbital and Mars Exploration rover data sets

The ∼5 km of traverses and observations completed by the Opportunity rover from Endurance crater to the Fruitbasket outcrop show that the Meridiani plains consist of sulfate‐rich sedimentary rocks that are largely covered by poorly‐sorted basaltic aeolian sands and a lag of granule‐sized hematitic concretions. Orbital reflectance spectra obtained by Mars Express OMEGA over this region are dominated by pyroxene, plagioclase feldspar, crystalline hematite (i.e., concretions), and nano‐phase iron oxide dust signatures, consistent with Pancam and Mini‐TES observations. Mössbauer Spectrometer observations indicate more olivine than observed with the other instruments, consistent with preferential optical obscuration of olivine features in mixtures with pyroxene and dust. Orbital data covering bright plains located several kilometers to the south of the landing site expose a smaller areal abundance of hematite, more dust, and a larger areal extent of outcrop compared to plains proximal to the landing site. Low‐albedo, low‐thermal‐inertia, windswept plains located several hundred kilometers to the south of the landing site are predicted from OMEGA data to have more hematite and fine‐grained olivine grains exposed as compared to the landing site. Low calcium pyroxene dominates spectral signatures from the cratered highlands to the south of Opportunity. A regional‐scale model is presented for the formation of the plains explored by Opportunity, based on a rising ground water table late in the Noachian Era that trapped and altered local materials and aeolian basaltic sands. Cessation of this aqueous process led to dominance of aeolian processes and formation of the current configuration of the plains.

Journal of Geophysical Research E: Planets↗

Controls on the variability of net infiltration to desert sandstone

As populations grow in arid climates and desert bedrock aquifers are increasingly targeted for future development, understanding and quantifying the spatial variability of net infiltration becomes critically important for accurately inventorying water resources and mapping contamination vulnerability. This paper presents a conceptual model of net infiltration to desert sandstone and then develops an empirical equation for its spatial quantification at the watershed scale using linear least squares inversion methods for evaluating controlling parameters (independent variables) based on estimated net infiltration rates (dependent variables). Net infiltration rates used for this regression analysis were calculated from environmental tracers in boreholes and more than 3000 linear meters of vadose zone excavations in an upland basin in southwestern Utah underlain by Navajo sandstone. Soil coarseness, distance to upgradient outcrop, and topographic slope were shown to be the primary physical parameters controlling the spatial variability of net infiltration. Although the method should be transferable to other desert sandstone settings for determining the relative spatial distribution of net infiltration, further study is needed to evaluate the effects of other potential parameters such as slope aspect, outcrop parameters, and climate on absolute net infiltration rates.

Water Resources Research↗

Hematite spherules at Meridiani: results from MI, Mini-TES, and Pancam

We report on observations of hematite‐bearing spherules at Meridiani Planum made using the Microscopic Imager (MI), Mini‐Thermal Emission Spectrometer (Mini‐TES), and Panoramic Camera (Pancam) instruments on the Mars Exploration Rover Opportunity. Spherules were observed on soil surfaces and in outcrop rocks, both on undisturbed surfaces and in abraded surfaces ground using the Rock Abrasion Tool (RAT). Spherule size and shape change little along the 850 m eastward traverse from Eagle Crater to Endurance Crater, but spherules decrease and then slightly increase in size along the 6 km traverse from Endurance south to Victoria Crater. Local populations range from submillimeters to several millimeters in diameter. An additional small diameter (100 μ m) size population is possible. An increase in irregular shapes is found near Victoria Crater. This, combined with the size decrease south of Endurance, suggests either a changing depositional environment, or variation in the duration and timing of diagenetic events. The dominant smaller size population observed early in the mission in aeolian areas and ripple crests is observed as the primary size population in abraded outcrop farther south. This suggests that successively younger beds are exposed at the surface along the southward traverse. Stratigraphically higher units removed by erosion could be recorded by the present surface lag deposit. Coordinated systematic observations are used to determine optical and infrared hematite indices of the surface soils in Pancam and Mini‐TES. In spite of the systematic variation seen in MI, both Pancam and Mini‐TES indices are highly variable based on the local surface, and neither show systematic trends south of Endurance. The lack of a 390 cm −1 feature in Mini‐TES spectra suggests concentric or radial interior structure within the spherules at scales too fine for MI to observe. Mini‐TES does not detect any silicate component in the spherules. A bound water component in soils or in exchange with the atmosphere is observed. These spherules have been previously interpreted as concretions formed within what were once water‐saturated, diagenetically altered “dirty evaporate” sandstone sediments. Our observations support this interpretation; however, no single terrestrial analog provides a model that can account for all attributes of the spherules on Mars.

Journal of Geophysical Research↗

Compositional stratigraphy of clay-bearing layered deposits at Mawrth Vallis, Mars

Phyllosilicates have previously been detected in layered outcrops in and around the Martian outflow channel Mawrth Vallis. CRISM spectra of these outcrops exhibit features diagnostic of kaolinite, montmorillonite, and Fe/Mg-rich smectites, along with crystalline ferric oxide minerals such as hematite. These minerals occur in distinct stratigraphic horizons, implying changing environmental conditions and/or a variable sediment source for these layered deposits. Similar stratigraphic sequences occur on both sides of the outflow channel and on its floor, with Al-clay-bearing layers typically overlying Fe/Mg-clay-bearing layers. This pattern, combined with layer geometries measured using topographic data from HiRISE and HRSC, suggests that the Al-clay-bearing horizons at Mawrth Vallis postdate the outflow channel and may represent a later sedimentary or altered pyroclastic deposit that drapes the topography.

Geophysical Research Letters↗

Spirit Mars Rover Mission to the Columbia Hills, Gusev Crater: Mission overview and selected results from the Cumberland Ridge to Home Plate

This paper summarizes the Spirit rover operations in the Columbia Hills of Gusev Crater from sols 513 to 1476 and provides an overview of selected findings that focus on synergistic use of the Athena Payload and comparisons to orbital data. Results include discovery of outcrops (Voltaire) on Husband Hill that are interpreted to be altered impact melt deposits that incorporated local materials during emplacement. Evidence for extensive volcanic activity and aqueous alteration in the Inner Basin is also detailed, including discovery and characterization of accretionary lapilli and formation of sulfate, silica, and hematite‐rich deposits. Use of Spirit's data to understand the range of spectral signatures observed over the Columbia Hills by the Mars Reconnaissance Orbiter's Compact Reconnaissance Imaging Spectrometer (CRISM) hyperspectral imager (0.4–4 μ m) is summarized. We show that CRISM spectra are controlled by the proportion of ferric‐rich dust to ferrous‐bearing igneous minerals exposed in ripples and other wind‐blown deposits. The evidence for aqueous alteration derived from Spirit's data is associated with outcrops that are too small to be detected from orbital observations or with materials exposed from the shallow subsurface during rover activities. Although orbital observations show many other locations on Mars with evidence for minerals formed or altered in an aqueous environment, Spirit's data imply that the older crust of Mars has been altered even more extensively than evident from orbital data. This result greatly increases the potential that the surface or shallow subsurface was once a habitable regime.

Journal of Geophysical Research E: Planets↗

Characteristics, distribution, origin, and significance of opaline silica observed by the Spirit rover in Gusev crater, Mars

The presence of outcrops and soil (regolith) rich in opaline silica (∼65–92 wt % SiO 2 ) in association with volcanic materials adjacent to the “Home Plate” feature in Gusev crater is evidence for hydrothermal conditions. The Spirit rover has supplied a diverse set of observations that are used here to better understand the formation of silica and the activity, abundance, and fate of water in the first hydrothermal system to be explored in situ on Mars. We apply spectral, chemical, morphological, textural, and stratigraphic observations to assess whether the silica was produced by acid sulfate leaching of precursor rocks, by precipitation from silica‐rich solutions, or by some combination. The apparent lack of S enrichment and the relatively low oxidation state of the Home Plate silica‐rich materials appear inconsistent with the originally proposed Hawaiian analog for fumarolic acid sulfate leaching. The stratiform distribution of the silica‐rich outcrops and their porous and brecciated microtextures are consistent with sinter produced by silica precipitation. There is no evidence for crystalline quartz phases among the silica occurrences, an indication of the lack of diagenetic maturation following the production of the amorphous opaline phase.

Journal of Geophysical Research E: Planets↗

Evidence for a diagenetic origin of Vera Rubin Ridge, Gale Crater, Mars: Summary and synthesis of Curiosity's exploration campaign

This paper provides an overview of the Curiosity rover's exploration at Vera Rubin ridge (VRR) and summarizes the science results. VRR is a distinct geomorphic feature on lower Aeolis Mons (informally known as Mount Sharp) that was identified in orbital data based on its distinct texture, topographic expression, and association with a hematite spectral signature. Curiosity conducted extensive remote sensing observations, acquired data on dozens of contact science targets, and drilled three outcrop samples from the ridge, as well as one outcrop sample immediately below the ridge. Our observations indicate that strata composing VRR were deposited in a predominantly lacustrine setting and are part of the Murray formation. The rocks within the ridge are chemically in family with underlying Murray formation strata. Red hematite is dispersed throughout much of the VRR bedrock, and this is the source of the orbital spectral detection. Gray hematite is also present in isolated, gray‐colored patches concentrated toward the upper elevations of VRR, and these gray patches also contain small, dark Fe‐rich nodules. We propose that VRR formed when diagenetic event(s) preferentially hardened rocks, which were subsequently eroded into a ridge by wind. Diagenesis also led to enhanced crystallization and/or cementation that deepened the ferric‐related spectral absorptions on the ridge, which helped make them readily distinguishable from orbit. Results add to existing evidence of protracted aqueous environments at Gale crater and give new insight into how diagenesis shaped Mars' rock record.

Journal of Geophysical Research: Planets↗

Magnetic fabric, flow directions, and source area of the Lower Miocene Peach Springs Tuff in Arizona, California, and Nevada

We have used anisotropy of magnetic susceptibility (AMS) to define the flow fabric and possible source area of the Peach Springs Tuff, a widespread rhyolitic ash flow tuff in the Mojave Desert and Great Basin of California, Arizona, and Nevada. The tuff is an important stratigraphic marker from the Colorado Plateau to Barstow, California, a distance of 350 km; however, the location of its source caldera is unknown. Dated at 18.5 Ma by 40 Ar/ 39 Ar, the tuff erupted during the early stages of Miocene extension along the lower Colorado River. The thicker accumulations (>100 m) occur at Kingman, Arizona, and in the Piute Mountains, California, on opposite sides of the Colorado River extensional corridor. Our AMS studies produced well-defined magnetic lineations in 30 of 42 sites distributed throughout the tuff. Typical ratios of the principal AMS axes are 1.01 for the magnetic lineation ( k max / k int ) and 1.02 for the foliation ( k int / k min ); the bulk magnetic susceptibility of the Peach Springs Tuff averages 2.0×10 −3 in the SI unit system. The subhorizontal lineations, which presumably parallel the flow directions, form a pattern radiating outward from the approximate center of the outcrop area. Magnetic foliations define an imbrication that generally dips away from the distal margins and toward the center of the outcrop of the tuff. The lineation and imbrication indicate a source region near the southern tip of Nevada. Defining the best intersection of the AMS lineations required restoration of major extension, strike-slip faulting, and associated tectonic rotation in the disrupted tuff. The optimum intersection of magnetic lineations lies in the southern Black Mountains of Arizona on the eastern side of the Colorado River extensional corridor. No caldera structures are known from that area, but the area contains thick sections of the Peach Springs Tuff above a silicic volcanic center. The caldera may be buried under younger deposits in the Mohave Valley of Arizona. Tertiary granite in the Newberry Mountains may represent a deeper level of the Peach Springs Tuff vent that has been exhumed by detachment faulting.

Journal of Geophysical Research↗

Chemistry of unsaturated zone gases sampled in open boreholes at the crest of Yucca Mountain, Nevada: Data and basic concepts of chemical and physical processes in the mountain

Boreholes open to the unsaturated zone at the crest of Yucca Mountain, Nevada, were variously sampled for CO 2 (including 13 C and 14 C), CH 4 , N 2 , O 2 , Ar, CFC-11, CFC-12, and CFC-113 from 1986 to 1993. Air enters the mountain in outcrops, principally on the eastern slope, is enriched in CO 2 by mixing with soil gas, and is advected to the mountain crest, where it returns to the atmosphere. The CFC data indicate that travel times of the advecting gas in the shallow Tiva Canyon hydrogeologic unit are ≤5 years. The 14 C activities are postbomb to depths of 100 m, indicating little retardation of 14 CO 2 in the shallow flow systems. The 14 C activities from 168 to 404 m in the Topopah Spring hydrogeologic unit are 85–90 pMC at borehole USW-UZ6. The CFC data show that the drilling of USW-UZ6 in 1984 has altered the natural system by providing a conduit through the Paintbrush Nonwelded unit, allowing flow from Topopah Spring outcrops in Solitario Canyon on the west to USW-UZ6, upward in the borehole through the Paintbrush, to the shallow Tiva Canyon flow systems, and out of the mountain.

Nevada↗

Microsatellite DNA markers for the study of Allegheny woodrat (Neotoma magister) populations and cross-species amplification the genus Neotoma

The Allegheny woodrat ( Neotoma magister ) is a colony-forming murid rodent inhabiting rock outcrops, cliff and talus slopes, and caves within the Central and Southern Appalachians of North America ( Hall 1981 ). The species is currently considered threatened, endangered, or at risk throughout its range purportedly due to the direct or indirect effects of human-fragmented landscapes. Currently, Allegheny woodrat management units are arbitrarily defined as metapopulations that roughly constitute contiguous rock outcrops interconnected by forested habitat. To strengthen long-term population stability and reduce the need for further protection through the regulatory process, an effective conservation programme for this at-risk species will require unambiguous, objectively defined units of management that discern evolutionarily important lineages ( Avise 1994 ). A prerequisite in the development of management strategies that recognize and maintain significant woodrat lineages is a thorough understanding of the levels of gene exchange among geographically proximate and distal populations. However, no information exists on population structure, levels of gene flow, or relatedness among Allegheny woodrat populations or colonies. As an initial step towards addressing this research need, we have developed a suite of polymorphic microsatellite DNA markers for this species. In this paper, we describe the isolation and characterization of these markers and demonstrate their suitability in amplifying putatively homologous products in seven additional Neotoma species.

Alabama, Georgia, Kentucky, Mississippi, North Car↗

A unique Middle Ordovician K-bentonite bed succession at Röstånga, S. Sweden

An approximately 8.5 m thick sequence of upper Viruan (upper Middle Ordovician) shales, mudstones, and limestones in an outcrop at Kyrkb&auml;cken near R&ouml;st&aring;nga in W‐central Sk&aring;ne contains 19 K‐bentonite beds, several of which are as much as 40&ndash;67 cm thick. Thirteen of these beds are in the upper part of the Sularp Fm., four in the Skagen Fm., and two questionable beds in the Mossen Fm. Evidence from macrofossils, chitinozoans, and conodonts are used for biostratigraphic age assessment of the K‐bentonite succession. Regional comparison of the sequence with those at Kinnekulle (Kullatorp), Ko&auml;ngen, and Tommarp suggests that its total stratigraphie thickness is smaller than those at the two former sites but the thicknesses of several of the Kyrkbacken ash beds are greater than those in similar stratigraphic positions in the other successions. The K‐bentonites at Kyrkbacken have a similar clay mineralogy and major and trace element composition as other Ordovician K‐bentonites, and these data indicate that the parental magma was of felsic, probably rhyolitic composition. Based on amphibole geoba‐rometry, the magma chamber is interpreted to have been at a depth of 14&ndash;20 km. The relatively large number of unusually thick ash beds of Middle Ordovician age makes the easily accessible Kyrkb&auml;cken outcrop unique not only in Baltoscandia but, as far as we are aware, also on the entire northern hemisphere, and only one comparable exposure is known in the southern hemisphere, namely in the Precordillera of northern Argentina.

GFF↗

Granitic boulder erosion caused by chaparral wildfire: Implications for cosmogenic radionuclide dating of bedrock surfaces

Rock surface erosion by wildfire is significant and widespread but has not been quantified in southern California or for chaparral ecosystems. Quantifying the surface erosion of bedrock outcrops and boulders is critical for determination of age using cosmogenic radionuclide techniques, as even modest surface erosion removes the accumulation of the cosmogenic radionuclides and causes significant underestimate of age. This study documents the effects on three large granitic boulders following the Esperanza Fire of 2006 in southern California. Spalled rock fragments were quantified by measuring the removed rock volume from each measured boulder. Between 7% and 55% of the total surface area of the boulders spalled in this single fire. The volume of spalled material, when normalized across the entire surface area, represents a mean surface lowering of 0.7–12.3 mm. Spalled material was thicker on the flanks of the boulders, and the height of the fire effects significantly exceeded the height of the vegetation prior to the wildfire. Surface erosion of boulders and bedrock outcrops as a result of wildfire spalling results in fresh surfaces that appear unaffected by chemical weathering. Such surfaces may be preferentially selected by researchers for cosmogenic surface dating because of their fresh appearance, leading to an underestimate of age.

California↗

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California↗