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At least 379 records · Page 21Linked to original sources

Potential interaction of groundwater and surface water including autonomous underwater vehicle reconnaissance at Nolin River Lake, Kentucky, 2016

The U.S. Geological Survey collaborated with the U.S. Army Corps of Engineers, Louisville District, on a synoptic study of water quality at Nolin River Lake during August 2016. The purpose of the study was to develop a better understanding of the potential for interaction between groundwater and surface water at Nolin River Lake, Kentucky. Groundwater can have properties that are measurably different from those in adjacent surface water, and inflows and outflows can be an important component of water quality and quantity. An improved understanding of potential interaction of groundwater and surface water at Nolin River Lake may be used to refine lake-management strategies. This study (1) compiled and interpreted existing information to characterize the hydrogeological setting and implications for potential interaction of groundwater and surface water in the Nolin River Lake watershed; (2) collected transects of onsite water-quality parameters using an autonomous underwater vehicle (AUV) in areas with potential for interaction of groundwater and surface water, including five sites on Nolin River Lake and one site on the Nolin River; and (3) collected discrete water-quality and phytoplankton community data at the same six sites. A review of existing hydrogeologic information did not indicate the presence of karst features adjacent to or beneath Nolin River Lake that would facilitate groundwater interaction with the reservoir. Observations leading to this conclusion include (1) limestone that is adjacent to the shoreline and perhaps beneath the lake, is overlain with siliciclastic rocks and fine-grained sediment that inhibits infiltration and development of karst features that encourage rapid groundwater flow; (2) the geologic deposits surrounding the reservoir are described as having limited or no potential for development of karst features, some exceptions may exist in tributary valleys; (3) very few karst features were mapped within 1 mile of the reservoir or in the area currently occupied by the reservoir; and (4) faults that intersect the reservoir but may not possess hydraulic properties that cause the faults to be conduits for groundwater flow. Groundwater interaction with reservoir tributaries is likely more common in areas of the watershed upstream from Nolin River Lake where karst hydrogeology is prevalent. Results of water-quality surveys using an AUV from August 15 to 19, 2016, did not identify areas of anomalous values that might indicate groundwater inflows through preferential flow zones. Spatial distributions of water-quality parameters were generally uniform within each constant-depth layer. The constant-depth layers were selected to be above, within, and below the thermocline and ranged from the water surface to 25 feet. Surveys near the bottom of the reservoir that might have been more sensitive to groundwater inflows were not done because presurvey data were not available to indicate locations of obstacles that could ensnare the AUV. Water-quality data collected with the AUV did identify water-quality anomalies where stream tributaries were discharging to the reservoir. The discrete water-quality samples indicated uniformity among the five reservoir sites. The riverine site that is immediately upstream from Nolin River Lake, however, had some unique water-quality characteristics relative to sites on the reservoir. The highest concentrations of nitrate plus nitrite as nitrogen (0.145 milligrams per liter [mg/L]), total phosphorous (0.07 mg/L), chlorophyll a (36.1 micrograms per liter), and pheophytin a (10.2 micrograms per liter) were measured at the Nolin River Lake riverine site (site 2NRR20034). The concentrations of nutrients and chlorophyll a at the riverine site did exceed the 25th percentile of median concentrations measured by the U.S. Environmental Protection Agency (EPA) at other lakes and reservoirs in EPA level IV ecoregion 71a. Concentrations of most nutrients and chlorophyll a at the five reservoir sites also exceeded the 25th percentile of median concentrations in EPA level IV ecoregion 72h. The exception was the concentrations of total phosphorus as phosphorus at the reservoir sites that were at or below the 25th percentile of median concentrations measured by EPA (0.03 mg/L). Concentrations of orthophosphate as phosphorus were less than the method detection limit of 0.004 mg/L at all sites. The phytoplankton community in Nolin River Lake was almost exclusively (greater than 90 percent of total phytoplankton abundance) cyanobacteria, also known as blue-green algae. A species of Cylindrospermopsis dominated the cyanobacterial community at the five reservoir sites, while Chroococcus microscopicus was most abundant at the riverine site. Cyanobacterial cell densities ranged from 10,000 to 198,067,460 cells per liter in five areas in the reservoir and from 4,800 to 73,751,253 cells per liter at the riverine site. Multiple potential sources of water to Nolin River Lake include direct precipitation, overland flow, interflow, groundwater, and surface water. Understanding the exact contribution of each of these components to the water budget at Nolin River Lake may help the U.S. Army Corps of Engineers manage the water quality, water quantity, and biological communities in the reservoir. Additional hydrogeologic and water-quality data that builds on the results of this study may refine the inferences of this study; for example, deeper AUV surveys that target the largest fault zones might further the understanding of the potential for groundwater flow through those features. A complete understanding of the reservoir hydrology, however, may require the use of scientific methods intended for water bodies as large as Nolin River Lake, such as aerial infrared photography and imagery; water mass, chemical, and isotopic balance studies; geophysical measurements; and numerical simulations.

Kentucky↗

Simulation of groundwater flow and chloride transport in the “1,500-foot” sand, “2,400-foot” sand, and “2,800-foot” sand of the Baton Rouge area, Louisiana

Groundwater withdrawals since the 1940s have lowered water levels, altered groundwater-flow directions, and caused saltwater to intrude within some freshwater-containing sands of the fluvial-deltaic Southern Hills regional aquifer system beneath Baton Rouge, Louisiana. New interpretations of stratigraphic correlations amongst geophysical well logs were utilized to revise a hydrogeologic framework that delineates the depth and thickness variations of aquifers and confining units in the Southern Hills regional aquifer system. A groundwater-flow and chloride-transport model incorporating the revised framework was constructed to assess the effects of groundwater withdrawals on the rate and pathways of saltwater migration in the “1,500-foot” sand, “2,400-foot” sand, and the “2,800-foot” sand. Groundwater withdrawals reported since 1940 were compiled to specify annual average withdrawal rates through 2016 for 722 wells. Regional groundwater flow throughout the Southern Hills regional aquifer system was first simulated with MODFLOW, and flow-model parameters were calibrated to 8,810 water levels observed through 2016 by using the parameter-estimation code PEST++. Saltwater transport was subsequently simulated for the “1,500-foot” sand, “2,400-foot” sand, and the “2,800-foot” sand by using the variable-density code, SEAWAT. Chloride-concentration measurements were used as a proxy for saltwater to formulate the concentration initial conditions and calibrate the transport-model parameters. Three groundwater-management scenarios were simulated to evaluate the effects of different groundwater withdrawals on future groundwater levels and saltwater concentrations in the “1,500-foot” sand, “2,400-foot” sand, and “2,800-foot” sand. All three scenarios simulated the period from 2017 through 2112 (96 years), and the water levels and concentrations simulated for 2047 and 2112 were compared among the scenarios. The first scenario simulated a continuation of groundwater withdrawals at 2016 rates and represents the “status quo” of groundwater withdrawals. The second scenario simulated the effects of discontinuing 10,620 gallons per minute (gal/min) of withdrawals from the “2,800-foot” sand, and the third scenario simulated reallocating 2,000 gal/min of withdrawals from the “1,500-foot” sand to the “2,800-foot” sand. Continuation of the “status quo” withdrawals results in lower water levels by 2047 around groundwater-withdrawal locations in the “1,500-foot” sand, “2,400-foot” sand, and “2,800-foot” sand. By 2112, water levels recover to higher levels as flow in the aquifer approaches equilibrium. Saltwater within the “1,500-foot” sand would continue migrating toward public-supply wells located 2.4 miles (mi) north of the Baton Rouge Fault, but a “scavenger well” that removes relatively concentrated water from the base of the “1,500-foot” sand attenuates chloride concentrations at the public-supply wells. Saltwater within the “2,400-foot” sand would continue to encroach on a well with large withdrawals and farther east within an area about 1 mi north of the Baton Rouge Fault. Saltwater within the “2,800-foot” sand would migrate northward toward withdrawal wells located about 3 mi north of the industrial district. Cessation of 10,620 gal/min of industrial withdrawals from the “2,800-foot” sand about 12 mi northwest of the industrial district (scenario 2) would cause a substantial water-level recovery in the “2,800-foot” sand in the area of discontinued withdrawals. Groundwater levels 3 mi north of the industrial district would be 25–30 feet higher in 2047 than predicted for the “status quo” withdrawals. Saltwater encroachment toward wells north of the industrial district would be slowed because of the decreased hydraulic gradient. Reallocating 2,000 gal/min of withdrawals from the “1,500-foot” sand to the “2,800-foot” sand 12 mi northwest of the industrial district (scenario 3) would have a negligible effect on water levels and chloride concentrations in the “1,500-foot” sand 15 mi to the south-southeast where saltwater is encroaching toward wells in the “1,500-foot” sand. Within the “2,800-foot” sand, the area of saltwater encroachment is only 3 mi from increased withdrawals in the “2,800-foot” sand, and water levels would be about 5 feet lower in 2047 than for the “status quo” scenario. A larger hydraulic gradient would cause slightly faster saltwater transport and higher chloride concentrations within this area of the “2,800-foot” sand.

Louisiana↗

Groundwater quality in relation to drinking water health standards and geochemical characteristics for 54 domestic wells in Clinton County, Pennsylvania, 2017

Despite the reliance on groundwater by approximately 2.4 million rural Pennsylvania residents, publicly available data to characterize the quality of private well water are limited. As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, samples from 54 domestic wells in Clinton County were collected and analyzed in 2017. The samples were evaluated for a wide range of constituents and compared to drinking-water health standards and geochemical characteristics. The sampled wells were completed to depths ranging from 46 to 500 feet in bedrock that was of predominantly sandstone, shale, or carbonate lithology. Results of this study show that the sampled groundwater quality in Clinton County generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded drinking-water maximum contaminant levels (MCLs) for total coliform bacteria (57.4 percent), Escherichia coli ( E. coli ) (25.9 percent), nitrate (1.9 percent), and arsenic (1.9 percent); and secondary maximum contaminant levels (SMCLs) for pH (31.5 percent), manganese (29.6 percent), iron (13 percent), total dissolved solids (7.4 percent), aluminum (1.9 percent), and chloride (1.9 percent). Sodium concentrations exceeded the U.S. Environmental Protection Agency drinking-water advisory recommendation in 16.7 percent of the samples. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter (pCi/L) in 59.3 percent of the samples. The only volatile organic compounds (VOCs) detected were acetone and methyl ethyl ketone in two separate samples; neither constituent exceeded drinking-water standards. Higher median nitrate concentrations were found in the carbonate (3.26 milligrams per liter [mg/L]) versus shale (less than 0.04 mg/L) and sandstone (0.27 mg/L) aquifer subsets. Most of the elevated nitrate concentrations were associated with E. coli detections in the carbonate aquifers, where transmissive bedrock can facilitate groundwater contamination by human activities at the land surface. The median pH of groundwater from the sandstone aquifers (6.53) was less than those for the shale aquifers (7.31) and carbonate aquifers (7.43). Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH outside this range. Many samples from the shale or sandstone aquifers, particularly those with pH less than 6.5, were identified as having serious potential corrosivity based on the combination of the calcite saturation index and the chloride to sulfate mass ratio; however, none of the samples from the carbonate aquifers was identified as seriously corrosive. Groundwater from 3.7 percent of the wells had concentrations of methane greater than the Pennsylvania action level of 7 mg/L, and 48 of the 54 wells (88.9 percent) had detectable concentrations of methane greater than the 0.0002 mg/L detection limit. Greater methane concentrations were found more frequently in groundwater sampled from the shale aquifers than the carbonate or sandstone aquifers in the study area. Most of the samples containing elevated methane (greater than 0.2 mg/L) were located outside the area of the Appalachian Plateaus. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH and were correlated with concentrations of iron, manganese, ammonia, sodium, lithium, barium, fluoride, and boron. The stable carbon and hydrogen isotopic compositions of methane in two of four samples analyzed for isotopes were consistent with compositions reported for mud-gas logging samples from gas-bearing geologic units (thermogenic gas) in the Appalachian Plateaus region, whereas two others were consistent with methane of microbial origin or a mixture of microbial and thermogenic gas. Forty-two percent of samples had chloride concentrations greater than 20 mg/L with variable bromide concentrations. Corresponding chloride/bromide ratios are consistent with low-bromide sources such as road-deicing salt and septic effluent or animal waste, or, in a few cases, high-bromide brine. Brines characterized by relatively high bromide are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. One of the four groundwater samples with methane concentrations greater than 4 mg/L had chloride and bromide concentrations and a chloride/bromide ratio that indicates mixing with a salinity source such as road-deicing salt, whereas the chloride and bromide concentrations and ratios for the other three high-methane samples indicate mixing with a small amount of brine (0.03 percent or less). In two other eastern Pennsylvania county studies where gas drilling is absent, groundwater with comparable chloride/bromide ratios, bromide, and chloride concentrations plus other element associations have been reported. Additional sampling and analysis, such as isotopic analysis of the dissolved gas, fracture analysis, and more detailed evaluation of surrounding land uses, may be warranted to better understand the origin of the methane and brine constituents in groundwater at specific locations.

Pennsylvania↗

Hydrology of Haskell Lake and investigation of a groundwater contamination plume, Lac du Flambeau Reservation, Wisconsin

Haskell Lake is a shallow, 89-acre drainage lake in the headwaters of the Squirrel River, on the Lac du Flambeau Reservation in northern Wisconsin. The lake has long been valued by the Lac du Flambeau Band of Lake Superior Chippewa Indians (LDF Tribe) for abundant wild rice and game fish. In recent decades, however, wild rice has mostly disappeared from the lake and the fishery has declined. A petroleum contamination plume discovered in the 1990s in the shallow aquifer upgradient from the northern end of the lake poses a threat to the ecological health of the lake and the aquifer, which is the sole drinking water source for nearby residents and businesses. Understanding of the lake’s hydrology is important to the LDF Tribe as they seek to restore wild rice and maintain the ecological health of the Haskell Lake/Tower Creek watershed. An improved understanding of lithology in the area of the contamination plume, documentation of a contamination pathway from groundwater in the plume source area to Haskell Lake, and an understanding of the plume extent beneath the lake are needed to advance remediation efforts. Evaluation of the fraction of groundwater discharge that is contaminated relative to the overall lake water budget is desired as a first step towards determining the extent of ecological effects from the plume. A cooperative study between the U.S. Geological Survey and the LDF Tribe was initiated to quantify the lake water budget and the sources of water to the lake, to provide a rough estimate of the maximum quantity of groundwater discharge to the lake that may be contaminated, and to improve the conceptual understanding of the plume extent and subsurface materials in the area of contamination. The results of this study can help inform natural resource management of the Haskell Lake/Tower Creek watershed, including planned wild rice restoration and cleanup of the contaminant plume. During 2016–17, field data on lake and groundwater levels, gradients, fluxes, and subsurface lithology were collected using a variety of techniques that ranged from basic measurement of water levels and streamflows to distributed temperature sensing, vertical temperature profiling, and several shallow geophysical methods. The data were used to inform a MODFLOW–NWT model that simulated the contributing groundwatershed, including the water budget for Haskell Lake and Tower Creek using the Lake, Streamflow-Routing, and Unsaturated Zone-Flow Packages. Particle tracking with the MODFLOW solution (using MODPATH 6) was used to improve understanding of the downgradient extent of the contamination plume, estimate groundwater flux through the plume area, and delineate the groundwater contributing area (groundwatershed) for the lake/creek system. Linear uncertainty estimates for model results were computed during model parameter estimation using the software package PEST++. Results indicate groundwater discharge along the perimeter of Haskell Lake, with groundwater accounting for about 22 (± 11.5) percent of the lake water budget. Field data and particle tracking results indicate discharge of the entire contamination plume to Haskell Lake. Although the exact locations where contaminated groundwater enters the lake are unknown, the downgradient extent of the plume beneath Haskell Lake is likely limited to within about 700 feet from the shore. Groundwater flux through the plume accounts for at most about 1.4 percent of total groundwater discharge to Haskell Lake, or about 0.3 percent of the lake water budget. Most groundwater discharging to Haskell Lake and Tower Creek originates as terrestrial recharge. A lesser amount originates in or passes through neighboring lakes, including Buckskin, Crawling Stone, Broken Bow, Tippecanoe, and Jerms Lakes, as well as several unnamed kettles. The average age of simulated groundwater discharge to the lake is about 20 years.

Wisconsin↗

Water Quality of groundwater used for public supply in principal aquifers of the western United States

Groundwater provides nearly half of the Nation’s drinking water. As the Nation’s population grows, the importance of (and need for) high-quality drinking-water supplies increases. As part of a national-scale effort to assess groundwater quality in principal aquifers (PAs) that supply most of the groundwater used for public supply, the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Project staff sampled six principal aquifers in the western United States between 2013 and 2017: (1) the Basin and Range carbonate-rock aquifers, (2) Basin and Range basin-fill aquifers, (3) Rio Grande aquifer system, (4) High Plains aquifer, (5) Colorado Plateaus aquifers, and (6) Columbia Plateau basaltic-rock aquifers. These six PAs supply a large part of the Nation’s drinking water and cover a large geographic extent of the western conterminous United States. Groundwater samples were analyzed for a large suite of water-quality constituents including major ions, nutrients, trace elements, volatile organic compounds (VOCs), pesticide compounds, radioactive constituents, age tracers, and, in selected PAs, perchlorate. Two types of assessments were made: (1) a status assessment that describes the quality of the groundwater resource at time of collection and (2) an understanding assessment that evaluates relations between groundwater quality and potential explanatory factors that represent characteristics of the aquifer system. The assessments characterize untreated groundwater quality, which might be different than the quality of drinking water delivered to consumers. The assessments are based on water-quality data collected from 352 wells and 6 springs using an equal-area grid sampling design. This sampling approach allows for the estimation of the proportion of high, moderate, or low concentrations relative to federal water-quality benchmarks of selected constituents in the area of each PA. Results were compared to established benchmarks for drinking-water quality to provide context for evaluating the quality of untreated groundwater: Federal regulatory benchmarks for protecting human health, non-regulatory human-health benchmarks, and non-regulatory benchmarks for nuisance chemicals. Not all constituents that were analyzed have benchmarks and thus were not considered for assessments. Concentrations are characterized as high if they are greater than their benchmark. Concentrations are considered moderate if they are greater than one-half their benchmark (for inorganic constituents), or greater than one-tenth their benchmark (for organic constituents). Concentrations are considered low if they are less than moderate or the constituent was not detected. Status assessment results indicated that inorganic constituents more commonly occurred at high and moderate concentrations in the six PAs than organic constituents, and organic constituents predominately occurred at low concentrations. Inorganic constituents that exceeded health-based benchmarks (high concentrations) were present in all six PAs; aquifer-scale proportion were 30 percent in the Rio Grande aquifer system, 22 percent in the Basin and Range basin-fill aquifers, 20 percent in the Basin and Range carbonate-rock aquifers, 19 percent in the High Plains aquifer, 16 percent in the Colorado Plateaus aquifers, and 8 percent in the Columbia Plateau basaltic-rock aquifers. Arsenic, fluoride, manganese, and total dissolved solids were the constituents most commonly present at high concentrations. Organic constituents with human-health benchmarks (pesticide compounds and VOCs) did not occur at high concentrations and moderate concentrations were infrequent; aquifer-scale proportions ranged from 0 to 5 percent. Detections of organic compounds at low concentrations, however, occurred in all six PAs, with detection frequencies ranging from 10 to 26 percent for pesticide compounds and from 10 to 46 percent for VOCs. Specific organic constituents with detection frequencies greater than 10 percent were four herbicides (atrazine, didealkylatrazine, bromoform, and propazine), one insecticide (propoxur), and two VOCs (the trihalomethanes chloroform and bromodichloromethane). Where collected—in the Rio Grande aquifer system and High Plains aquifer—perchlorate did not occur at high concentrations; moderate aquifer-scale proportions were 3 and 11 percent, respectively. The understanding assessment included statistical tests to evaluate relations between constituent concentrations and potential explanatory factors to identify natural and human factors that affect groundwater quality. Potential explanatory factors included depth to bottom of well perforation, groundwater age category, land use, aquifer lithology, hydrologic conditions, and geochemical conditions. Higher concentrations of trace elements, radioactive constituents, and constituents with non-health-based benchmarks generally were associated with unconsolidated sand and gravel aquifer lithologies, premodern groundwater age, greater aridity, and more alkaline pH. Organic constituents with detection frequencies greater than 10 percent generally were associated with urban land use, shallower well depths, and higher total dissolved solids concentrations. The results for the six western PAs provide important insights into the quality of groundwater that is used for drinking water in the western United States, as well as natural and human factors that affect groundwater quality in this region.

Arizona, California, Colorado, Idaho, Kansas, Mont↗

Use of real-time sensors to temporally characterize water quality in groundwater and surface water in Mason County, Illinois, 2017–19

The persistence of high nitrate concentrations in shallow groundwater has been well documented in the shallow glacial aquifer of Mason County, Illinois. Nitrates in groundwater can be a concern when concentrations exceed 10 milligrams per liter in drinking water. Additionally, nitrate in groundwater can contribute to surface water nitrogen loads that can cause increased algal growth. Algal growth increases oxygen consumption causing anoxic conditions as observed in the Gulf of Mexico Hypoxic Zone. From March 8, 2017, to March 31, 2019, groundwater level, continuous nitrate, dissolved oxygen, specific conductance, water temperature, and pH data were collected in a monitoring well to temporally assess changes in water quality using high frequency data. During this same period, instantaneous field measurements of water quality and groundwater levels were made in surface water and groundwater in and near Quiver Creek in the presumed groundwater flow path about 0.6 mile from the continuous monitoring well. Groundwater nitrate concentrations continuously measured in the aquifer during this time ranged from 14.7 to 23.2 milligrams per liter, whereas instantaneously measured nitrate concentrations in Quiver Creek ranged from 0.9 to 6.4 milligrams per liter. Nitrate concentrations measured by piezometer varied laterally and vertically in the Quiver Creek floodplain and beneath the stream. Irrigation and fertigation for agriculture is widely practiced in Mason County. This may seasonally affect the groundwater flow and movement as well as the persistence of nitrate in this area. Continuously and instantaneously measured nitrate concentrations and groundwater levels indicate that during the irrigation season, discharge to Quiver Creek from the shallow groundwater system may be limited. During and following periods when estimated irrigation use is highest, the low-nitrate deeper groundwater may be the dominant contributor to the Quiver Creek surface water, whereas during recharge events and when the system is not under the stress of irrigation, there is more contribution from the local and higher-nitrate shallow groundwater.

Illinois↗

Nitrogen and phosphorus loads from groundwater to Lake Spokane, Spokane, Washington, October 2016–October 2019

Shallow nearshore groundwater and estimates of groundwater seepage were collected at 21 locations along the north and south shores of Lake Spokane beginning in October 2016 and ending in October 2019. Nitrate plus nitrite concentrations in nearshore groundwater ranged from <0.04 to 7.60 milligrams of nitrogen per liter. Nearshore groundwater orthophosphate concentrations ranged from <0.004 to 0.381 milligrams of phosphorus per liter, and, overall, there were no consistent seasonal differences in nearshore groundwater nutrients during this study. Nitrate plus nitrite concentrations were highest at sites located adjacent to nearshore development and similar to concentrations in water collected from nearby drinking water wells. Similarly, samples from locations adjacent to nearshore development were statistically greater than samples collected from other locations for orthophosphate concentrations. Dissolved boron concentrations, elevated values of which are an indicator of household-detergent use, were elevated in spring and summer at some locations, indicating that residential wastewater was reaching the lake. Stable isotope ratios of nitrate ( 15 N and 18 O), which were used to identify the source nitrate in sampled groundwater, showed that most data indicated a mix of soil nitrogen and nitrogen sources from human or animal waste. Generally, median groundwater discharge to the lake was low across all sites and seasons, with most values smaller than 1 centimeter per day (cm/d). Similar to the nutrient-concentration data, seasonal patterns in seepage flux were weak, and, where there were seasonal increases in flux, the increased groundwater discharge did not carry increased nutrients. Localized estimates of groundwater seepage flux were scaled up to the entire length of the lakeshore. The median groundwater flux of 0.34 cm/d scaled to 1.9 cubic feet per second (ft 3 /s) and the maximum recorded seepage flux of 17.6 cm/d was equivalent to 97 ft 3 /s. These estimates of groundwater inputs are orders of magnitude less than surface water inputs to the lake. Nutrient loads were determined from the product of groundwater flow and a representative nutrient concentration. Using the median seepage flux of 1.9 ft 3 /s, the orthophosphate load ranged from 0.7 to 3.8 pounds of phosphorus per day based on the median and maximum orthophosphate concentrations, respectively. For nitrate plus nitrite, loads ranged from 5.8 to 76.6 pounds of nitrogen per day. Using the maximum value of seepage flux, maximum orthophosphate loads ranged from 35 to 198 pounds of phosphorus per day, and maximum nitrate plus nitrite loads ranged from 296 to 3,943 pound of nitrogen per day. Overall, groundwater nutrient loads are small compared to other sources to the lake. Continued monitoring of future nutrient loads would aid decisions by resource managers as infrastructure within the neighboring residential communities continues to age around Lake Spokane.

Washington↗

Development of a groundwater-simulation model in the Los Angeles Coastal Plain, Los Angeles County, California

Executive Summary The Los Angeles Coastal Plain (LACP) covers about 580 square miles and is the largest coastal plain of semiarid southern California. The LACP is heavily developed with mostly residential, commercial, and industrial land uses that rely heavily on groundwater for water supply. In 2010, the LACP was home to about 14 percent of California’s population, or about 5.4 million residents. The LACP is also a major commercial and industrial hub with industries including manufacturing, aerospace, entertainment, and tourism. There has been a heavy reliance on groundwater from the LACP for many years. An average of 305,000 acre-feet per year (acre-ft/yr) of groundwater was used annually from the LACP from 1971 to 2015. The need to replenish the groundwater basins within the LACP was recognized as far back as the 1930s, when spreading grounds were first used to replenish groundwater basins and store water underground during times of water surplus to meet demands in times of shortage. Seawater intrusion resulting from freshwater pumping was first observed in the 1940s. As a result, injection of imported water through wells at what is now the West Coast Basin Barrier Project began on an experimental basis in 1951. Managed aquifer recharge from the spreading grounds and barrier wells is now a substantial component of the LACP’s groundwater supply. The average annual recharge from water spreading from 1971 to 2015 was about 120,000 acre-ft/yr, and the average annual injection into the barrier wells was about 33,000 acre-ft/yr. Other inflows include areal recharge, underflow from San Gabriel and San Fernando Valleys, and onshore flow from the ocean. The average annual recharge from these sources was 100,000 acre-feet (acre-ft) from 1971 to 2015. Additionally, cross-boundary flow from Orange County into the western Orange County subareas of the LACP was simulated as 48,000 acre-ft from 1971 to 2015. This study, conducted in cooperation with the Water Replenishment District of Southern California (WRD), involved an assessment of the historical and present status of groundwater resources in the LACP and the development of tools to better understand the groundwater system. These efforts were built upon results from previous studies and incorporate new information and developments in modeling capabilities to provide a more detailed analysis of the aquifer systems. This study includes a comprehensive compilation of geologic and hydrologic data (Chapter A), development of a chronostratigraphic model that provides a detailed description of the LACP aquifer systems (Chapter B), characterization of the groundwater hydrology of the LACP, including a down-hole analysis of grain size using lithologic and geophysical logs (Chapter C), and development and application of the Los Angeles Coastal Plain Groundwater-flow Model (LACPGM) to simulate past groundwater conditions, estimate groundwater-budget components and flow paths, and approximate future groundwater conditions under different scenarios (Chapter D).

California↗

Groundwater availability, geochemistry, and flow pathways to public-supply wells in the Atlantic Coastal Plain and bedrock aquifers, Aiken County and part of Lexington County, South Carolina, 2015–2019

Between 2015 and 2019, the U.S. Geological Survey (USGS) studied concerns related to projected increases in demand for groundwater, in collaboration with municipal water providers and county managers within the study area, Aiken County and part of Lexington County, South Carolina. A three-dimensional (3D), numerical groundwater-flow model of the Atlantic Coastal Plain (ACP) aquifers, confining units, and the underlying bedrock aquifer in the study area was constructed using the USGS software program MODFLOW–NWT in conjunction with a groundwater-recharge model using the Soil-Water-Balance (SWB) model. Water budgets for dry (2012) and wet (2015) year conditions, future (2017–2065) groundwater-demand scenarios based on general circulation models (GCMs) of future climates, and future agricultural irrigation demands were simulated. Overall, the GCMs projected increased recharge rates. Simulation of projected increased demand on groundwater by agriculture irrigation indicated little drawdown in the study area. Groundwater-quality samples were collected from representative public-supply wells (PSWs) and analyzed in the field and laboratory. In general, the groundwater in the ACP aquifers is acidic, dilute, and oxic. Conversely, groundwater in the bedrock aquifer was of neutral pH, mineralized, and anoxic. Total-radium concentrations across all PSWs ranged from 0.55 to 6.69 picocuries per liter (pCi/L). Groundwater from some PSWs contained detectable but low concentrations of commonly and historically used volatile organic compounds, such as chloroform, methyl tert -butyl ether (MTBE), cis -1,2-dichloroethylene ( cis -1,2-DCE), 1,1-dichloroethane (1,1-DCA), and 1,1-dichloroethylene (1,1-DCE). The stable isotopes of groundwater sampled from all wells indicate the possibility that groundwater from the bedrock aquifer may discharge into the ACP. Finally, groundwater age-dating results and MODPATH simulations indicate recharge between the 1950s and 1980s for PSWs in the ACP and recharge between the 1940s and 1950s for PSWs in bedrock. Maximum groundwater-flow pathways ranged from 270 to 7,470 feet, with the longest simulated-flow pathway for wells pumped at higher rates.

South Carolina↗

Interaction of a legacy groundwater contaminant plume with the Little Wind River from 2015 through 2017, Riverton Processing site, Wyoming

The Riverton Processing site was a uranium mill 4 kilometers southwest of Riverton, Wyoming, that prepared uranium ore for nuclear reactors and weapons from 1958 to 1963. The U.S. Department of Energy completed surface remediation of the uranium tailings in 1989; however, groundwater below and downgradient from the tailings site and nearby Little Wind River was not remediated. Beginning in 2010, a series of floods along the Little Wind River began to mobilize contaminants in the unsaturated zone, resulting in substantial increases of uranium and other contaminants of concern in monitoring wells completed inside the contaminant plume. In 2011, the U.S. Department of Energy started a series of university and Government agency retrospective and field investigations to understand the processes controlling contaminant increases in the groundwater plume. The goals of the field investigations described in this report were to (1) identify and quantify the contaminant flux and potential associated biological effects from groundwater associated with the legacy plume as it enters a perennial stream reach, and (2) assess chemical exposure and potential effects to biological receptors from the interaction of the contaminant plume and the river. Field investigations along the Little Wind River were completed by the U.S. Geological Survey during 2015–17 in cooperation with the U.S. Department of Energy Office of Legacy Management to characterize: (1) seepage areas and seepage rates; (2) pore-water and bed sediment chemistry and hyporheic exchange and reactive loss; and (3) exposure pathways and biological receptors. All data collected during the study are contained in two U.S. Geological Survey data releases, available at https://doi.org/10.5066/F7BR8QX4 and https://doi.org/10.5066/P9J9VJBR . A variety of tools and methods were used during the field characterizations. Streambed temperature mapping, electrical resistivity tomography, electromagnetic induction, fiber-optic distributed temperature sensing, tube seepage meters, vertical thermal sensor arrays, and an environmental tracer (radon) were used to identify areas of groundwater seepage and associated seepage rates along specific sections of the study reach of the river. Drive points, minipiezometers, diffusive equilibrium in thin-film/diffusive gradients in thin-film probes, bed-sediment samples, and equal discharge increment sampling methods were used to characterize pore-water chemistry, estimate hyporheic exchange and reactive loss of selected chemical constituents, and quantify contaminant loadings entering the study reach. Sampling and analysis of surface sediments, filamentous algae, periphytic algae, and macroinvertebrates were used to characterize biological exposure pathways, metal uptake, and receptors. Areas of focused groundwater discharge identified by the fiber-optic distributed temperature sensing surveys corresponded closely with areas of elevated electrical conductivity identified by the electromagnetic induction survey results in the top 5 meters of sediment. During three monitoring periods in 2016, the mean vertical seepage rate measured with tube seepage meters was 0.45 meter per day, ranging from −0.02 to 1.55 meters per day. Five of the 11 locations where vertical thermal profile data were collected along the study reach during August 2017 indicated mean upwelling values ranging from 0.11 to 0.23 meter per day. Radon data collected from the Little Wind River during June, July, and August 2016 indicated a consistent inflow of groundwater to the central part of the study reach, in the area congruous with the center of the previously mapped groundwater plume discharge zone. During August 2017, the greatest attenuation of uranium from reactive loss in pore-water samples was observed at three locations along the study reach, at depths between 6 and 15 centimeters, and similar trends in molybdenum attenuation were also observed. Bed-sediment concentration profiles collected during 2017 also indicated attenuation of uranium and molybdenum from groundwater during hyporheic mixing of surface water with the legacy plume during groundwater upwelling into the river. Streamflow measurements combined with equal discharge increment water sampling along the study reach indicated an increase in dissolved uranium concentrations in the downstream direction during 2016 and 2017. Net uranium load entering the Little Wind River study reach was about 290 and 435 grams per day during 2016 and 2017, respectively. Biological samples indicated that low levels of uranium and molybdenum exposure were confined to the benthos in the Little Wind River within and immediately downstream from the perimeter of the groundwater plume. Concentrations of molybdenum and uranium in filamentous algae were consistently low at all sites in the study reach with no indication of increased exposure of dissolved bioavailable molybdenum or uranium at sites next to or downstream from the groundwater plume. Comparison of the August 2017 results from electromagnetic induction, tube seepage meters, vertical thermal profiling, and pore-water chemistry surveys were in general agreement in identifying areas with upwelling groundwater conditions along the study reach. However, the electroconductivity values measured with electromagnetic induction in the top 100 centimeters of sediment did not agree with sodium concentrations measured in pore-water samples collected at similar streambed depths. Differences and similarities between multiple methods can result in additional insights into hydrologic and biogeochemical processes that may be occurring along a reach of a river system interacting with shallow groundwater inputs. It may be advantageous to apply a variety of geophysical, geochemical, hydrologic, and biological tools at other Uranium Mill Tailings Remedial Action ( https://www.energy.gov/sites/prod/files/2014/10/f19/UMTRCA.pdf ) sites during the investigation of legacy contaminant plume interactions with surface-water systems.

Wyoming↗

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia↗

Nutrient chemistry in the Elizabeth Lake subwatershed—Effects of onsite wastewater treatment systems on groundwater and lake water quality, Los Angeles County, California

Nutrient (nitrogen [N] and phosphorus [P] chemistry) downgradient from onsite wastewater treatment system (OWTS) was evaluated with a groundwater study in the area surrounding Elizabeth Lake, the largest of three sag lakes within the Santa Clara River watershed of Los Angeles County, California. Elizabeth Lake is listed on the “303 (d) Impaired Waters List” for excess nutrients and is downgradient from more than 600 OWTS. The primary objective of this study was to develop a conceptual hydrogeological model to determine if discharge from OWTS is transported into shallow groundwater within the Elizabeth Lake subwatershed and contributes nutrients to Elizabeth Lake in excess of the total maximum daily load limit. An analysis of historical data and data collected for this study provided estimates of aquifer properties, such as hydraulic gradients and other parameters necessary to estimate boundary conditions. Electrical resistivity tomography (ERT) surveys were done to determine the best monitoring well locations and to estimate depth to groundwater. During 4 separate sampling events, 11 wells, 2 imported water tanks, 1 spring (sampled on March 17, 2019), and Elizabeth Lake were sampled, which occurred during February–September 2020. ERT transects and borehole geophysical measurements indicated that there were low to high resistivity materials in the subsurface and potential perched fresh water. Most of the aquifer material was characterized as sandy silt, occasionally with mixed clays and medium gravels, and was estimated to have a hydraulic conductivity from 3.28x10 −3 to 16.4 feet per day, a porosity from 0.34 to 0.42, and a hydraulic gradient from 0.01 to 0.03. Although bedrock was not obvious in ERT transects, all well depths were terminated at depths of an impassible confining layer observed to be a highly consolidated blue-gray clay. Depths to granitic bedrock, based on road outcrops and lithologic driller logs, varied throughout the study area. Depth to the bedrock was estimated to be shallow on the north side of Elizabeth Lake at approximately 30 feet below land surface (ft bls). Depth to bedrock is at 50 ft bls toward the east of the Elizabeth Lake subwatershed, which is at topographic ground surface to the north and south of the residential development. Groundwater levels ranged from approximately 0 to 12 ft bls during this study. Historical water levels ranged from 8 to 16 ft bls in the lower elevation of the study area and increased to depths of as much as 80 ft bls at higher elevations on the north and south boundaries of the Elizabeth Lake subwatershed. Water-quality samples were analyzed for major ions, nutrients, dissolved organic carbon, stable isotopes, and age-dating tracers. A principal component analysis was completed to determine organic matter sources. The proportion of recharge from imported waters, used for domestic consumption, was calculated using stable water isotopes, deuterium (δD) and oxygen (δ 18 O). Recharge from imported waters accounted for approximately 15–71 percent of the total recharge to groundwater within the study area. Total nitrogen concentrations ranged from 0.17 to 30.9 milligrams per liter (mg/L) as N, and phosphorus, measured in the soluble form as orthophosphate, ranged from 0.03 to 0.35 mg/L as P. Nitrate concentrations in groundwater samples ranged from less than the detection limit (0.01 mg/L as N) to approximately 24 mg/L as N. Nitrate was not detected in 3 of the 12 sites sampled during the study (2 wells and Elizabeth Lake). Dissolved organic carbon concentrations ranged from 0.4 to 27 mg/L in groundwater and from 9.9 to 100 mg/L in Elizabeth Lake. Ammonium and orthophosphate concentrations generally were low in groundwater. However, elevated concentrations of ammonium in Elizabeth Lake were assumed to be due to avian waste products or biological nitrogen fixation. Groundwater ages were mostly modern (recharged since 1952), with a median recharge temperature of 13 degrees Celsius. Redox conditions in groundwater indicated the likely occurrence of nitrate attenuation by denitrification downgradient from the wells to the south of Elizabeth Lake before groundwater discharges to the lake. Undetectable nitrate in Elizabeth Lake at the time of sampling was likely due to algal uptake. Most wells contained stable isotopes of nitrogen and oxygen in nitrate (δ 15 N-NO 3 and δ 18 O-NO 3 ) molecules with values consistent with denitrification. However, one monitoring well on the north of Elizabeth Lake (ELLA-8) had no evidence of denitrification, based on elevated concentrations of nitrate and a sufficient amount of dissolved oxygen such that the water was oxic and not favorable for the denitrification reaction. Consequently, this nitrate could be delivered to Elizabeth Lake through groundwater discharge if nitrate is not removed from the system by denitrifying bacteria downgradient from the well before the groundwater discharges into Elizabeth Lake. The principal component analysis demonstrated that dissolved organic matter optical properties track different sources of dissolved organic matter from decayed plants, animals, and animal-derived wastes. Two wells contained strong indicators of OWTS water presence, although geochemical evidence indicated other wells may also be affected by OWTS discharge.

California↗

Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii↗

Simulation of groundwater flow in Wake County, North Carolina, 2000 through 2070

In 2019, the U.S. Geological Survey and Wake County Environmental Services began a collaborative study to evaluate groundwater resources and long-term groundwater availability in the county’s fractured-rock groundwater system. Wake County, in central North Carolina, is experiencing rapid population growth, associated land development, and changing water use. Hydrogeologic data including groundwater levels, aquifer testing, borehole fracture flow measurements, water-quality samples, and groundwater age-dating tracers were collected, along with findings from previous investigations, to help inform a conceptual model of the flow system used to develop a modular three-dimensional finite-difference groundwater-flow model (MODFLOW) for simulating historical and future groundwater conditions from 2000 to 2070. Hydraulic conductivity and transmissivity ranges were estimated from 17 slug tests and 21 borehole-flow measurements. Groundwater-quality analytical results from 19 sampling sites indicate that oxidation-reduction (redox) conditions varied within the regolith and bedrock and that minimal evaporation occurred before recharge entered the groundwater system. Age dating revealed mixtures of older and younger water, ranging from the 1940s to the 1990s—indicating variable flow pathways of recharge within permeable bedrock fracture zones. To simplify the complex fractured-rock groundwater system, two layers representing the regolith and the fractured bedrock were used in the MODFLOW model. Model calibration included parameter estimation and provided a reasonable fit to observed groundwater levels and estimated stream base flows. The model forecast scenarios incorporated future climate-model data for two emissions scenarios with land cover change projections to simulate potential impacts to future groundwater levels, recharge, and base flows. Recharge and base flow projections were largely within historical ranges, with no apparent long-term trends, but did indicate a slight downward shift in median values—likely, in part, because of differences in spatial resolution of input climate datasets. Seasonal patterns were consistent with historical data, with projections of possible increases in future winter recharge. Model limitations are discussed, and additional monitoring and model refinement needs are highlighted to support decision making for local groundwater management.

North Carolina↗

Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California↗

Mapping groundwater recharge potential and an assessment of available hydrogeologic data within five selected focus areas in eastern Nebraska

Groundwater recharge potential was mapped using airborne electromagnetic survey data collected over the previously glaciated part of eastern Nebraska. To evaluate the appropriate resolution at which airborne electromagnetic data should be interpolated (or represented), we compared a 500-​meter ​cell ​raster​ and​ a​ filled ​contour​ shapefile​ to ​known​ geologic features, point estimates of groundwater recharge, and selected water-quality data. The median groundwater recharge rate for the estimates collected in areas mapped as having high groundwater recharge potential were higher compared to the groundwater recharge rate estimates collected in areas mapped as having moderate and low recharge potential. Selected water-quality data were examined to determine​ the ​influence of​ near-​surface​ geology​ on​ water​ quality, groundwater geochemistry, and groundwater age. The strongest statistical correlations were produced when examining ​specific​ conductance​ values ​measured​ from​ wells​ in areas mapped as high, moderate, and low groundwater recharge potential. Within till-covered areas, statistically significant​ differences​ existed​ in ​nitrate,​ dissolved ​oxygen,​ manganese, and iron concentrations sampled from wells mapped in high, moderate, and low groundwater recharge potential areas. Boxplots indicate that till-covered areas mapped as low groundwater recharge potential generally have lower concentrations of nitrate and dissolved oxygen, but higher concentrations of manganese and iron. The Eastern Nebraska Water Resources Assessment project​ sponsors ​have​ identified ​five ​focus​ areas ​as​ locations facing unique and important groundwater resource management issues. These focus areas are experiencing the emergence of groundwater resource issues that include increased groundwater development, nitrate contamination, and the potential expansion of rural water districts. Hydrogeologic assessments were completed for the Dorchester-Sterling paleovalley aquifer, Dodge County, Knox County, Burt County, and the Fremont-Arlington-Leshara focus areas. Potential future studies to address data gaps were identified​ and​ discussed.

Nebraska↗

Multi‐constrained catchment scale optimization of groundwater abstraction using linear programming

Due to increasing water demands globally, freshwater ecosystems are under constant pressure. Groundwater resources, as the main source of accessible freshwater, are crucially important for irrigation worldwide. Over‐abstraction of groundwater leads to declines in groundwater levels; consequently, the groundwater inflow to streams decreases. The reduction in base flow and alteration of the stream flow regime can potentially have an adverse impact on groundwater‐dependent ecosystems. A spatially distributed, coupled groundwater‐surface water model can simulate the impacts of groundwater abstraction on aquatic ecosystems. A constrained optimization algorithm and a simulation model in combination can provide an objective tool for the water practitioner to evaluate the interplay between economic benefits of groundwater abstractions and requirements to environmental flow. In this study, a holistic catchment‐scale groundwater abstraction optimization framework has been developed that allows for a spatially explicit optimization of groundwater abstraction, while fulfilling a pre‐defined maximum allowed reduction of stream flow (base flow (Q95) or median flow (Q50)) as constraint criteria for 1484 stream locations across the catchment. A balanced K‐Means clustering method was implemented to reduce the computational burden of the optimization. The model parameters and observation uncertainties calculated based on Bayesian linear theory allow for a risk assessment on the optimized groundwater abstraction values. The results from different optimization scenarios indicated that using the linear programming optimization algorithm in conjunction with integrated models provides valuable information for guiding the water practitioners in designing an effective groundwater abstraction plan with the consideration of environmental flow criteria important for the ecological status of the entire system.

Groundwater↗

Use of geochemical, isotopic, and age tracer data to develop models of groundwater flow for the purpose of water management, northern High Plains aquifer, USA

A prolonged drought in the High Plains of Nebraska prompted the use of groundwater for cooling at the largest coal-fired power plant in the State. Prior to the drought, groundwater was used primarily for irrigation and the power plant relied exclusively on surface water stored in a nearby reservoir for cooling. Seepage from the reservoir system during the past ∼75 a has resulted in the buildup of a large mound of water in the underlying unconfined aquifer. A well field was installed during the drought for the purpose of tapping the groundwater mound as a supplemental source of water for cooling. Concentrations of dissolved Cl − and SO 4 2 - "> SO 4 2- indicate 65–100% of shallow groundwater and 0–100% of deep groundwater (saturated thickness ∼115 m) in the immediate vicinity of the reservoir was from seepage out of the reservoir system. Hydrogen and O isotopic data indicate most surface-water seepage occurred in the late spring and early summer when reservoir stage was at its highest level. Tritium/ 3 He apparent groundwater ages imply horizontal flow velocities from the reservoir were on the order of 60–600 m/a. These diverse data provided information regarding the spatial distribution, timing, and rate of seepage from the reservoir that could not have been obtained from the available geologic, hydraulic head, and conductivity data. In particular, mixing fractions of surface water and regional groundwater in the aquifer could not have been determined using hydraulic information. Mixing fractions were of special interest in this study because of the management objective to maximize the capture of surface-water seepage in the cooling water wells. Groundwater-flow models developed as well-field management tools were calibrated using inverse modeling techniques and observations of groundwater age, surface-water flow, reservoir stage, and groundwater levels. The age data only accounted for 6 of the 2574 field observations used to calibrate the groundwater-flow models, yet they were among the most influential for refining estimates of hydraulic conductivity, recharge, and seepage from the reservoir. Results from this study demonstrate the benefits of using geochemical, isotopic, and age tracer data to develop conceptual and numerical models of groundwater flow for the purpose of water management.

Nebraska↗