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Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia

A new groundwater energy transport model for the MODFLOW hydrologic simulator

Heat transport in the subsurface is an important aspect of research related to the effects of a warming climate on ecological services (i.e., cold-water refugia); the development of geothermal resources for energy banking schemes (i.e., aquifer thermal energy storage [ATES]); and the effects of temperature on other aspects of groundwater quality, such as nutrient cycling. Historically, simulation of heat transport using the MODFLOW groundwater simulator and related codes was performed by scaling the input parameters of a solute-transport model to emulate heat transport. However, that approach required additional pre- and post-processing of input and output and could not account for the variation in effective thermal storage and transport properties during transient, unsaturated flow, for example. True heat-transport capabilities in the context of MODFLOW were first introduced in a variant called USG-Transport. More recently, a new groundwater energy-transport (GWE) model type has been added to MODFLOW 6, the core version of the MODFLOW hydrologic simulator. GWE supports the simulation of heat transport on structured or unstructured grids as well as within and between features of advanced packages that represent streams, lakes, multi-aquifer wells, and the unsaturated zone. GWE is integrated within MODFLOW 6 and is accessible through the FloPy Python package and the MODFLOW 6 application programming interface (API). An example simulation demonstrates conduction between grid cells through both the water and the solid aquifer material, including thermal bleeding from saturated overburden cells into a groundwater flow field.

Groundwater

Self-guided decision support groundwater modelling with Python

The GMDSI tutorial notebooks repository provides learners with a comprehensive set of tutorials for self-guided training on decision-support groundwater modelling using Python-based tools. Although targeted at groundwater modelling, they are based around model-agnostic tools and readily transferable to other environmental modelling workflows. The tutorials are divided into three parts. The first covers fundamental theoretical concepts. These are intended as background reading for reference on an as-needed basis. Tutorials in the second part introduce learners to some of the core concepts parameter estimation in a groundwater modelling context, as well as providing a gentle introduction to the PEST, PEST++ and pyEMU software. Lastly, the third part demonstrates how to implement highly-parameterized applied decision-support modelling workflows. The tutorials aim to provide examples of both “how to use” the software as well as “how to think” about using the software. A key advantage to using notebooks in this context is that the workflows described run the same code as practitioners would run on a large-scale real- world application. Using a small synthetic model facilitates rapid progression through the workflow.

Journal of Open Source Education

Groundwater spatial variability within an atoll island: Assessing shallow aquifer heterogeneity with geophysical and physicochemical measurements

This study examines the spatial variability of shallow groundwater on Dhigelaabadhoo Island using electromagnetic induction surveys, groundwater monitoring, and sediment analyses. The research reveals how variations in island morphology—such as differences in elevation, reef flat width, and sediment composition—affect the spatial distribution of groundwater lenses and the overall aquifer dynamics. Saltwater intrusion is especially pronounced in low elevated areas, with narrow reef flat plate and areas where higher hydraulic conductivity—driven by the presence of coarser sediments—is observed, whereas regions characterized by finer sediments, higher elevation, and wider reef flat plates tend to support more symmetric and less saline groundwater lenses. The geophysical investigations reveal that tidal oscillations alter groundwater movement by markedly changing water levels and conductivity, thereby underscoring the critical need to account for temporal dynamics in atoll coastal aquifer systems and the importance of integrating tidal dynamics into the aquifer zone. The findings highlight the significant role of intrinsic morphological and external hydrodynamic factors in shaping groundwater distribution on atoll islands, offering critical insights for sustainable freshwater resource management.

Dhigelaabadhoo Island

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma

Base-flow sampling to enhance understanding of the groundwater flow component of nitrogen loading in small watersheds draining into Long Island Sound

Excessive nitrogen discharge is a major concern for the Long Island Sound. Programs have been implemented to reduce point sources of nitrogen to the sound, but little is known about the nonpoint sources. This study aims to better understand the current groundwater contributions of nitrogen from nonpoint sources in the Long Island Sound watershed. During the spring and summer of 2022, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected water-quality samples to analyze nutrients (nitrogen and phosphorus), chloride, and bromide at 45 stations in the Long Island Sound watershed in Connecticut, New York, and Rhode Island. The stations were in small drainage watersheds (5 to 30 square kilometers) in the southern part of the Long Island Sound watershed. During two separate synoptic sampling events, water-quality samples and instantaneous streamflow measurements were collected under base-flow conditions (where the streamflow is dominated by groundwater inputs rather than overland flow or runoff flow). One sampling event was in the nongrowing season (April 24–25, 2022), and the other was in the growing season (June 30–July 1, 2022). To calculate instantaneous nitrogen loads and yields, streamflow was measured at the time of sample collection. Nitrogen concentrations, loads, and yields varied among sampling stations and by season. Total filtered nitrogen concentrations were generally lower in the nongrowing season (from less than 0.14 to 1.9 milligrams per liter) than in the growing season (from less than 0.23 to 3.0 milligrams per liter). Nitrate plus nitrite concentrations showed little variation between the nongrowing and growing seasons. Unfiltered ammonia plus organic nitrogen concentrations were generally lower in the nongrowing season (from less than 0.07 to 0.83 milligram per liter) than in the growing season (from 0.11 to 0.98 milligram per liter). In contrast, total filtered and unfiltered nitrogen loads and yields were higher in the nongrowing season than during the growing season, likely because streamflows were higher during the nongrowing season. Total unfiltered nitrogen yields during the nongrowing season ranged from less than 0.15 to 5.0 kilograms per square kilometer per day. Total unfiltered nitrogen yields during the growing season ranged from less than 0.12 to 2.5 kilograms per square kilometer per day. Total filtered nitrogen yields during the nongrowing season ranged from less than 0.13 to 5.2 kilograms per square kilometer per day. Total filtered nitrogen yields during the growing season ranged from less than 0.06 to 2.5 kilograms per square kilometer per day.

Connecticut, New York, Rhode Island

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii

The effect of temperature, flow, density and disease on smallmouth bass (Micropterus dolomieu) early life growth rate

Individual growth rates of fish are influenced by gradually changing environmental conditions and rapid-onset events. However, there is a paucity of information on drivers of spatiotemporal variability in growth rates of fishes across large spatial extents. Using a 36-year dataset of smallmouth bass ( Micropterus dolomieu ) length-at-age data across 10 river reaches in Pennsylvania, USA ( n = 54,068 individuals), we estimated annual early life growth rates (mm year −1 ) and assessed the effects of relative abundance, summer temperature, summer streamflow rate and a disease outbreak on growth rate. We found that temperature had a positive effect on growth rate, varied spatially, and had a stronger effect in diseased reaches. There was also evidence for an impact of disease on early life growth through density-dependent mechanisms, with growth rates increasing from ∼85 to 101 mm·year −1 following disease-related decreases in abundance. This study adds to our understanding of the factors that shape early life growth, including rapid-onset events like disease which can have immediate and lasting effects on growth rate trajectory.

Pennsylvania

Preserving and increasing water resources—Natural infrastructure in dryland streams in Baja California Sur, Mexico

The Los Planes watershed of Baja California Sur, Mexico, and its underlying aquifer are experiencing groundwater decline owing to low average annual rainfall (28.1 centimeters per year) and rising water demand from population growth and agricultural activities. This decline in water availability can lead to desertification—a process that changes arable land to desert by degrading soil and vegetation—and can pose serious challenges to livelihoods that depend on the land. To address these issues, a ranch in the Los Planes watershed has installed many natural infrastructures in dryland streams (NIDS) in channels for soil and water conservation. In 2022, the U.S. Geological Survey (USGS) began working with regional researchers and land managers to investigate the effects of NIDS on natural biological, geochemical, and physical processes and determine the efficacy of NIDS for water augmentation in the Los Planes watershed. The USGS also worked with local academic institutions and nonprofit organizations to create public educational opportunities focused on the area’s hydrogeology. These and other collaborative efforts with the U.S. Water Partnership and Innovaciones Alumbra aim at enhancing water resources in the Baja California Sur region and promoting water security and safeguarding community well-being. Resume La cuenca de Los Planes, ubicada en Baja California Sur, México, y su acuífero subyacente, están sufriendo una disminución de las aguas subterráneas debido a la baja precipitación media anual (28.1 centímetros por año) y la alta demanda de agua por parte de una población creciente y la actividad agrícola. Esta disminución de la disponibilidad de agua puede conducir a la desertificación—un proceso que por medio de la degradación del suelo y la vegetación convierte a la tierra cultivable en desierto—representando un serio desafío para los medios de vida de las personas. Para abordar estos problemas, un rancho en la cuenca de Los Planes ha instalado numerosas obras de Infraestructura Natural en Arroyos de Tierras Áridas (INATS) para conservación del suelo y del agua. En 2022, el Servicio Geológico de los Estados Unidos (USGS, por sus siglas en inglés) comenzó a trabajar con investigadores regionales y gestores de tierras para estudiar los efectos de INATS en los procesos biológicos, geoquímicos y físicos, y determinar su eficacia en el aumento de los recursos hídricos en la cuenca de Los Planes. El USGS se ha asociado con instituciones académicas y organizaciones locales sin fines de lucro para crear oportunidades educativas públicas centradas en la hidrogeología de la zona. Estos y otros esfuerzos colaborativos con la Asociación del Agua de Estados Unidos (U.S. Water Partnership) e Innovaciones Alumbra, tienen como objetivo mejorar el uso de los recursos hídricos en la región de Baja California Sur, promover la seguridad hídrica y proteger el bienestar de la comunidad.

Baja California Sur

U.S. Geological Survey Earthquake Hazards Program decadal science strategy, 2024–33

Executive Summary Earthquakes represent one of our Nation’s most significant and costly natural hazards, with estimated annual loses from earthquakes close to $15 billion in 2023. Over the past two centuries, 37 U.S. States have experienced an earthquake exceeding a magnitude of 5, and 50 percent of States have a significant potential for future damaging shaking; these statistics speak to the need for nationwide interest and investment in earthquake hazard characterization and risk reduction. Authorized under the Earthquake Hazards Reduction Authorization Act, the U.S. Geological Survey (USGS) Earthquake Hazards Program (EHP) provides the scientific information, situational awareness, and knowledge necessary to reduce deaths, injuries, and economic losses from earthquakes and earthquake-induced tsunamis, landslides, and soil liquefaction. The EHP supports activities in three focused topical areas: (1) earthquake monitoring, (2) hazard assessment, and (3) applied research, using the results of each—and the coordination among them—to further support risk translation and communication in regions at risk nationwide. For earthquake monitoring, the Advanced National Seismic System (ANSS), a cooperative effort of USGS networks, university partner regional seismic networks, and real-time geodetic networks, collects and analyzes data on earthquakes; issues timely, reliable notifications of their occurrence and impacts; and provides data for earthquake research, hazard, and risk assessment as a foundation for building an earthquake-resilient Nation. The USGS-operated ShakeAlert Earthquake Early Warning system is a recent addition to EHP’s ANSS infrastructure. In the realm of earthquake hazard assessment, the EHP contributes to earthquake risk mitigation strategies by developing the National Seismic Hazard Model and maps, and other related products, that describe the likelihood and potential effects of earthquakes nationwide, especially in the urban areas of highest risk. The EHP also conducts research on the causes, characteristics, and effects of earthquakes and prioritizes work that directly increases the accuracy and precision of earthquake hazards assessments, earthquake forecasts, and earthquake monitoring and situational-awareness products and that supports the Nation’s earthquake mitigation practices. Bridging the EHP’s efforts across research, hazard assessments, and earthquake monitoring is a broad and comprehensive collection of earthquake information products, including the National Seismic Hazard Model, ShakeAlert, and other products describing impact, such as ShakeMap and PAGER (Prompt Assessment of Global Earthquakes for Response), which have been developed and integrated into EHP’s real-time monitoring systems. EHP funds external partners to carry out many important collaborative activities through an active external grants program—one of the largest in the USGS—and through cooperative agreements with other partners such as the university-operated regional seismic networks, funded as part of the ANSS. To continue its support of earthquake hazard characterization and risk reduction, the EHP aims to strengthen its foundational products and practices while positioning itself to respond to the evolving needs of the Nation and follow best practices of the scientific community. This document describes a strategy for the program to ensure it can meet these demands. The foundational priorities outlined in this strategy represent those activities that remain critical to the core functionality of the program and those that can be supported under current fiscal year 2024-level appropriations. Priorities described as aspirational are important for future growth, and to maintain the program’s position as a leading global resource in earthquake science, but would require increases in appropriated funding to be fully realized. Across the program’s portfolio of activities, several major themes have been identified as the most critical activities to advance EHP science over the coming decade. Together, these activities provide the framework necessary to integrate critical hazard characterization and risk reduction activities across the program. They provide the structure for research to advance the understanding of where, when, and why earthquakes occur and how we can use improved knowledge to drive short-term and actionable forecasts of seismic activity. They expand the usefulness of critical earthquake products and advance the sophistication of those products to keep pace with the rapidly evolving needs of an ever-expanding user base while maintaining the position of the USGS as a global leader in earthquake science. Focus on system-level science. Establish an automated earthquake-processing pipeline. Enhance the accuracy and reliability of the ShakeAlert Earthquake Early Warning system and plan for extension to other regions. Implement time-dependent earthquake forecasting. Develop physically realistic models. Expand computational capacity. This science strategy is organized into three primary sections. The first section provides an overview of the EHP and its budget, governance, and program council. Readers familiar with the program may wish to focus on the second section, which describes the core of the science strategy, including priorities across each of the EHP’s major program activities in monitoring, hazard assessment, and targeted research. The third section outlines science priorities that cut across program activities, including those involving collaborations external to the EHP.

American Samoa, Guam, Northern Marianas Islands, U

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas

USGS—An Unparalleled Scientific Asset

The U.S. Geological Survey (USGS) delivers information critical to powering our economy, managing our natural resources, and keeping Americans safe and healthy. 1 Mapping the Nation $21B Geologic maps save users an estimated 15% in annual costs: a value of between $14B and $21B. $25.6B in annual value to users of imagery from Landsat satellites, which were codeveloped by NASA and the USGS and operated through their lifespans by the USGS. $13.5B in annual benefits is generated by the USGS's 3D Elevation Program. Securing America’s Energy Independence 44% USGS-identified undiscovered geothermal energy is equal to 44% of current U.S. electricity generation. 29.4B barrels of oil and 391.6 trillion cubic feet of gas in recoverable resources are available on U.S. public lands based on USGS assessments. Protecting Americans’ Health and Safety $424B in recent wildland fire damages highlight the need for USGS fire science, which supports efforts to protect communities and reduce risk. USGS earthquake, volcano, landslide, and coastal hazard monitoring and information save lives and minimize costs; for example, $2.8M can be saved because of USGS enhanced information about a Mauna Loa eruption. $4.5B is the estimated cost of annual flooding. Through a network of over 11,885 streamgages, the USGS supports public safety and enables forecasts, early warning systems, and management actions that protect lives and property. Supporting National Security $3.1B The USGS identified a $3.1B risk to the American economy if China restricts gallium imports. This is one example underscoring the importance of the USGS mapping critical minerals, investigating supply chains, and producing the Nation’s critical minerals list. Enhancing Our Lands and Waters $21B in estimated annual costs results from invasive species. The USGS’s invasive species research informs approaches used to reduce their effects on agriculture, water infrastructure, disease transmission, fisheries, and outdoor recreation. USGS innovations support early warnings for harmful algal blooms—over $2M in yearly benefits are provided to Kansas alone. $45B USGS science informs the management of big game (such as deer and elk). The big-game hunting industry contributes $45B to the U.S. economy. Fostering American Prosperity $4.1T Mineral commodities are necessary for the $4.1T in value added to the GDP by major industries that consume processed mineral materials and employ 1 million workers. Because of this, USGS data on mineral supply, demand, and trade are highly valued. 45,000 metric tons Rare earths power the growing technology economy, including cell phones, electric vehicles, and medical devices. For over 70 years, USGS work has supported the discovery of rare earth resources in California’s Mountain Pass area, which produced 45,000 metric tons of rare earth concentrates in 2024—over 11% of the global supply. Guarding American Food Security $70.2B USGS science informs early warning systems and management strategies to mitigate disease outbreaks in agriculture—critical research on highly pathogenic avian influenza, for example, helps safeguard the $70B value in poultry and egg production. $11.8B USGS groundwater tools are vital for agriculture; for example, in the Mississippi Alluvial Plain, 65% of farming relies on groundwater to support its $11.8B annual industry. 1 Values throughout are given in billions (B), millions (M), and trillions (T) of U.S. dollars. GDP is “Gross Domestic Product.” Percentages are shown as %.

General Information Product

Computational electromagnetic geophysics for groundwater system studies: A review on established practices and recent advances

Identifying effective solutions for locating groundwater resources and ensuring the quality of drinking water is increasingly urgent, given the challenges posed by climate change and population growth. This review investigates electromagnetic geophysical imaging techniques, in both time- and frequency-domain, that can provide valuable insights for groundwater assessment. We explore computational electromagnetic methods used to evaluate electromagnetic data and several recent hydrogeophysical case studies. As open-source frameworks for modeling electromagnetic geophysical problems become available, a broader range of researchers can interpret their data with computationally advanced software. We provide an overview of documented open-source codes for evaluating electromagnetic data and analyze various hydrological targets in relation to their electromagnetic surveying technique and the computational method applied. Furthermore, we evaluate the potential of advanced computational techniques, including three-dimensional modeling, non-deterministic inversion and machine learning, to couple geophysical with numerical groundwater modeling and apply it in groundwater system studies. Despite obstacles such as complexity and resource demands, our findings indicate that the quantification and integration of predictive uncertainties from both electromagnetic and hydrological data and simulations would significantly improve the reliability of hydrogeophysical models. This can lead to a deeper understanding of groundwater systems and improved management practices.

Journal of Hydrology

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ~1,900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1,500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (~1,000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

EarthArXiv

The value of electronic tagging and tracking studies for understanding fish–hypoxia interactions

Objective Hypoxia (i.e., low dissolved oxygen availability) is a natural phenomenon but can also be induced by human activities (e.g., nutrient enrichment from runoff). Given that dissolved oxygen is essential for aquatic life, periods of hypoxia tend to have negative consequences (e.g., sublethal disturbances, mortality) for most fishes. Extensive laboratory research has documented hypoxia thresholds and physiological and behavioral outcomes for a variety of freshwater and marine fishes and there is also an extensive body of fieldwork assessing population-level responses (e.g., survival, distribution). Yet, studying how individual fish respond to hypoxia in the wild has proved challenging; electronic tagging and tracking tools (e.g., biotelemetry, biologging) have made it easier to study individual responses to hypoxia and complement other tools like hydroacoustics that tend to focus on population-level responses. Methods We review what has been learned from contemporary studies that employ electronic tagging and tracking tools to understand how fish respond to hypoxia in the wild. Topics explored include identifying and validating hypoxia thresholds, habitat compression, connectivity, mortality, physiological and bioenergetic consequences, and extreme weather conditions. We also consider what we have learned about evaluating various management plans for hypoxia and reflect on how electronic tags have also been used in aquaculture systems and in hybrid studies that combine laboratory and field research. We highlight fishes in Lake Erie as a research narrative to demonstrate how electronic tagging and tracking have markedly improved our understanding of a longstanding hypoxia issue. Results Our synthesis revealed that electronic tagging and tracking have provided critical information on how fish respond to hypoxia in the field, revealing complex trade-offs and compensatory mechanisms as well as cryptic hypoxia-induced mortality. Beyond just illuminating space use and mortality, tags equipped with various sensors are revealing how fish deal with hypoxia in real time in terms of physiology, bioenergetics, and behavior. Conclusions As electronic tagging and tracking methods experience further innovation and are increasingly applied to understand the effects of hypoxia on fish, we expect more unanticipated findings about the effects of hypoxia on fish in all aquatic ecosystems, which will strengthen our ability to manage and mitigate hypoxia. Combining tools and approaches (e.g., lab and field) is perhaps the best way to generate comprehensive understanding.

Transactions of the American Fisheries Society