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At least 379 records · Page 21Linked to original sources

Multiple source components in gas manifestations from north-central Italy

Gas manifestations in north-central Italy consist of CO2-rich gases with minor N2-rich emissions and discharge either along with thermal springs or into cold and stagnant waters. 'Cold' gases are prevalently CO2-dominated (> 90%) while gases related to the thermal waters have variable composition: from CO2 > 99.5% to N2 > 90%. The variable composition of 'thermal' gases is caused by differences in the thermal regime and lithology of the ascent paths, where there is mixing of gases from multiple sources, such as N2-rich atmospheric and deep CO2-rich metamorphic end-members. Elevated concentrations of CH4 and H2 in these gases are generally related to the presence of active geothermal systems at shallow depth, such as the Larderello-Travale field in Tuscany. The ??13C values between coexisting CH4 and CO2 in all samples analyzed suggest that CH4 originates abiogenically in 200-400??C hydrothermal systems. Far from geothermal areas, where the thermal gradient is lower or the water/gas ratio is high because of large inflow of meteoric waters, H2 and CH4 are usually lower. In some cases, they can be scrubbed or oxidized (especially H2), while the residual rising gas becomes indirectly enriched in N2 and CO2. Carbon dioxide is also enriched in some discharged gases because it is produced at shallow depth in lower temperature conditions (< 150??C). Heavy ??15N values for N2 to near +7.0??? suggest that, for some gas samples that contain excess nitrogen (e.g. where N2/Ar ??? 83), this component probably derives from ammonia-rich feldspars and micas within the Palaeozoic schist basement rocks. However, other samples show evidence of a shallow component of CH4 and N2 from Neogene basin sediments. The areal distribution of the 3He/4He ratio points to a general prevalence of atmospheric and crustal 4He in the gas discharges in central Italy. A significant component of mantle 3He is only found in the geothermal areas of Larderello where the large regional thermal anomaly suggests the presence of a deep magmatic body. ?? 1997 Elsevier Science B.V.

Chemical Geology↗

Speciation and isotopic composition of sedimentary sulfur in the Everglades, Florida, USA

We have studied the sulfur speciation and isotopic composition of two peat cores from Water Conservation Area 2A (WCA 2A) in the Florida Everglades. Core site E1 is affected by agricultural runoff from the Hillsboro Canal which drains the Everglades Agricultural Area; Core site U3 is distant from the canal and relatively unaffected by agricultural runoff. Depth profiles of the total sulfur content of both cores show fairly constant levels (??0.7 wt.%) below about 25-30 cm depth in Core E1 and below 40-45 cm in Core U3. Above these depths, total sulfur increases to as much as 1.52 wt.% in Core E1 and 1.74 wt.% in Core U3, suggesting that more sulfur has entered the sediments and/or that more sulfur is being retained in recent times at both sampling sites. These changes in total sulfur content with depth in Core E1 correlate with changes in total phosphorus that have been observed in other studies at core sites near the Hillsboro Canal. This correlation of total sulfur with phosphorus with depth is not seen in Core U3 located away from the canal, possibly because phosphorus is more effectively retained than sulfur in the organic sediment near the canal. Organic-sulfur (OS) concentrations are at least twice as high as the dusulfide-sulfur (DS) concentrations in the upper parts of both cores suggesting that iron is presently limiting the amount of dusulfide minerals formed in these sediments. The degree of pyritization (DOP) in the upper parts of the cores suggest that sulfide mineralization is limited by the availability of highly reactive iron during the earliest stages of diagenesis. Positive ??34S values for reduced sulfur forms in both cores indicate a relatively restricted sulfate reservoir, consistent with nearly complete reduction of the sulfate available in the sediment at any given time. Differences between the two core appear in the ??34S values for the near-surface sediments. The DS ??34S values in the upper 10.0 cm of sediment are more posotive at site E1, with a mean ??34S value of +12.9???, than at site U3, with a mean ??34S value of +2.9???. These reuslts may indicate that increased rates of organic deposition due to nutrient loading near the canal have increased the rate of sulfate reduction at the E1 site in recent times. Acid-volatile-sulfide (AVS) concentrations are lower than DS and OS concentrations by at least a factor of 10. Increasing ??34S values for AVS with increasing depth in both cores suggests ongoing reduction of a limited porewater sulfate reservoir after deposition. The disulfide and organic-sulfur ??34S values diverge from the ??34S values for AVS with depth, suggesting that most of the transformation of AVS into disulfide minerals or incorporation of sulfur into orgnaic matter occurs in the near-surface sediments. A comparison of organic-sulfur ??34S values in the dominant flora at the U3 site (sawgrass leaves and periphyton) with organic-sulfur ??34S values at the top of the U3 core indicates that there was early incorporation of an isotopically light sulfide species into the orgnaic matter.

Chemical Geology↗

Carbon isotopic comparisons of oil products used in the developmental history of Alaska

Studies of the fate of oil released into Prince William Sound, AK, as a result of the 1989 Exxon Valdez oil spill, have led to an unexpected discovery. In addition to oil-like residues attributed to the spill, the ubiquitous presence of flattened tar balls, the carbon isotopic compositions of which fall within a surprisingly narrow range [??13C(PDB) = -23.7 ?? 0.3??? (n = 65)], were observed on the shorelines of the northern and western parts of the sound. These compositions are similar to those of some oil products [-23.7 ?? 0.7??? (n = 35)] that were shipped from California and used in Alaska for fuel, lubrication, construction, and paving before ~ 1970. These products include fuel oil, asphalt, and lubricants [-23.8 ?? 0.5??? (n = 11)], caulking, sealants, and roofing tar [-23.7 ?? 0.7??? (n = 16)], and road pavements and airport runways [-23.5 ?? 0.9??? (n = 8)]. Fuel oil and asphalt [-23.5 ?? 0.1??? (n = 3)], stored at the old Valdez town site and spilled during the 1964 Alaskan earthquake, appear to be the source of most of the beached tar balls. Oil products with lighter carbon isotopic compositions, between -25 and -30??? (n = 18), appear to have been used more recently in Alaska, that is, after ~ 1970. The source of some of the products used for modern pavement and runways [-29.3 ?? 0.2??? (n = 6)] is likely Alaskan North Slope crude oil, an example of which was spilled in the 1989 oil spill [-29.2??? (n = 1)].

Chemical Geology↗

Comparison of two stable hydrogen isotope-ratio measurement techniques on Antarctic surface-water and ice samples

A comparison of the new hydrogen isotope-ratio technique of Vaughn et al. ([Vaughn, B.H., White, J.W.C., Delmotte, M., Trolier, M., Cattani, O., Stievenard, M., 1998. An automated system for hydrogen isotope analysis of water. Chem. Geol. (Isot. Geosci. Sect.), 152, 309-319]; the article immediately preceding this article) for the analysis of water samples utilizing automated on-line reduction by elemental uranium showed that 94% of 165 samples of Antarctic snow, ice, and stream water agreed with the ??2H values determined by H2-H2O platinum equilibration, exhibiting a bias of +0.5??? and a 2 - ?? variation of 1.9???. The isotopic results of 10 reduction technique samples, however, gave ??2H values that differed by 3.5??? or more, and were too negative by as much as 5.4??? and too positive by as much as 4.9??? with respect to those determined using the platinum equilibration technique.

Chemical Geology↗

Organic carbon accumulation and preservation in surface sediments on the Peru margin

Concentrations and characteristics of organic matter in surface sediments deposited under an intense oxygen-minimum zone on the Peru margin were studied in samples from deck-deployed box cores and push cores acquired by submersible on two transects spanning depths of 75 to 1000 m at 12??and 13.5??S. The source of organic matter to the seafloor in these areas is almost entirely marine material as confirmed by the narrow range of ??13C of organic carbon obtained in the present study (-20.3 to -21.6???; PDB) and the lack of any relationship between pyrolysis hydrogen index and carbon isotope composition. Organic carbon contents are highest (up to 16%) on the slope at depths between 75 and 350 m in sediments deposited under intermediate water masses with low dissolved oxygen concentrations (< 5 ??mol/kg). Even at these low concentrations of dissolved oxygen, however, the surface sediments that were recovered from these depths are dominantly unlaminated. Strong currents (up to 30 cm/s) associated with the poleward-flowing Peru Undercurrent were measured at depths between 160 and 300 m on both transects. The seafloor in this range of water depths is characterized by bedforms stabilized by bacterial mats, extensive authigenic mineral crusts, and (or) thick organic flocs. Constant advection of dissolved oxygen, although in low concentrations, active resuspension of surficial organic matter, activity of organisms, and transport of fine-grained sediment to and from more oxygenated zones all contribute to greater degradation and poorer initial preservation of organic matter than might be expected under oxygen-deficient conditions. Dissolved-oxygen concentrations ultimately may be the dominant affect on organic matter characteristics, but reworking of fine-grained sediment and organic matter by strong bottom currents and redeposition on the seafloor in areas of lower energy also exert important controls on organic carbon concentration and degree of oxidation in this region.

Chemical Geology↗

A new technique for surface and shallow subsurface paleobarometry using fluid inclusions: An example from the Upper Ordovician Viola Formation, Kansas, USA

This research illustrates a new approach for paleobarometry employing heterogeneously entrapped fluid inclusions to determine timing and depth of diagenesis. Heterogeneously entrapped fluid inclusions (gas + water) in vug-filling quartz from the Upper Ordovician Viola Formation in the Midcontinent of the United States were analyzed for their internal pressure with a fluid-inclusion crushing stage. The free gas in fluid inclusions was entrapped at near-surface temperature, as indicated by the presence of all-liquid fluid inclusions and fluid inclusions with low homogenization temperatures ( <40??C). Crushing the crystal and measuring the change in bubble size determines the pressure of entrapment directly. Heterogeneous trapping is indicated by widely varying L:V ratios, from all-liquid to vapor-rich. Gas bubbles in most fluid inclusions analyzed expanded upon release to atmospheric pressure, but some collapsed. A mode of 1.5 to 2.0 atm internal pressure was indicated by the crushing runs, but pressures up to 42.9 atm were recorded. Quartz precipitation and associated fluid-inclusion entrapment therefore occurred over a wide depth-range, but principally at depths of approximately 10 m. Crushing runs done in kerosene confirmed the presence of hydrocarbon gases in most of these inclusions, and bulk analyses of gases in the quartz by quadrupole mass spectrometer revealed methane, ethane, and atmospheric gases. The hydrocarbon gases may have originated in deeper thermogenically mature sedimentary strata, and then leaked to the near-surface where they were entrapped in the precipitating quartz cement. Freezing data indicate an event of quartz precipitation from fluids of marine-fresh water intermediate salinity and other events of precipitation from more saline fluids. Considering the determined pressures, the precipitating fluids probably originated at surfaces of subaerial exposure (unconformities) and surfaces of evaporite precipitation in the overlying Silurian strata. Thus, saline inclusions most likely originated from sinking of saline surface waters during Silurian time. Lower-salinity fluids record fluxes of meteoric water during development of unconformities in the Silurian. This type of paleobarometric study may have application in many other sedimentary systems, provided low-temperature and heterogeneous entrapment of an immiscible gas phase can be demonstrated for the fluid-inclusion assemblages studied.

Chemical Geology↗

Permian paleoclimate data from fluid inclusions in halite

This study has yielded surface water paleotemperatures from primary fluid inclusions in mid Permian Nippewalla Group halite from western Kansas. A 'cooling nucleation' method is used to generate vapor bubbles in originally all-liquid primary inclusions. Then, surface water paleotemperatures are obtained by measuring temperatures of homogenization to liquid. Homogenization temperatures ranged from 21??C to 50??C and are consistent along individual fluid inclusion assemblages, indicating that the fluid inclusions have not been altered by thermal reequilibration. Homogenization temperatures show a range of up to 26??C from base to top of individual cloudy chevron growth bands. Petrographic and fluid inclusion evidence indicate that no significant pressure correction is needed for the homogenization temperature data. We interpret these homogenization temperatures to represent shallow surface water paleotemperatures. The range in temperatures from base to top of single chevron bands may reflect daily temperatures variations. These Permian surface water temperatures fall within the same range as some modern evaporative surface waters, suggesting that this Permian environment may have been relatively similar to its modern counterparts. Shallow surface water temperatures in evaporative settings correspond closely to local air temperatures. Therefore, the Permian surface water temperatures determined in this study may be considered proxies for local Permian air temperatures.

Chemical Geology↗

Evaluation of the sulfur isotopic composition and homogeneity of the Soufre de Lacq reference material

Sulfur isotopic analysis of the elemental sulfur reference material Soufre de Lacq, prepared as silver sulfide by chromous chloride reduction and as copper sulfide by sealed-tube synthesis, indicates that Soufre de Lacq is isotopically homogeneous across different size fractions to within analytical uncertainty (??0.15???). The sulfur isotopic composition of aliquots of Soufre de Lacq prepared by these two techniques are identical to within analytical uncertainty. The mean sulfur isotopic composition for Soufre de Lacq prepared as silver sulfide and copper sulfide (relative to VCDT) is +16.20 ?? 0.15??? (1??).

Chemical Geology↗

Fractionation of aquatic natural organic matter upon sorption to goethite and kaolinite

Natural organic matter (NOM) consists of a complex mixture of organic molecules; previous studies have suggested that preferential sorption of higher molecular weight, more hydrophobic, and more aromatic components may lead to fractionation of the NOM pool upon passage through porous media. Our work expands upon previous studies by quantifying the change in solution-phase weight average molecular weight (M(w)) upon sorption of bulk (rather than isolated) surface water NOM from the Suwannee River (SR) and the Great Dismal Swamp (GDS) to goethite and kaolinite at different sorption densities and at pH 4, 22??C. High pressure size exclusion chromatography (HPSEC) was used to quantify changes in M(w) upon sorption, and molar absorptivities at ?? = 280 nm were used to approximate changes in solution NOM aromaticity. Two SR water samples were used, with M(w) = 2320 and 2200 Da; a single GDS sample was used, with M(w) = 1890 Da. The SR NOM was slightly more hydrophobic and aromatic. These differences were reflected in greater sorption of SR NOM than GDS NOM. Both surface water NOMs showed a much greater affinity for goethite than for kaolinite. HPSEC analysis of the NOM remaining in solution after 24 h reaction time with geothite revealed that the largest changes in solution phase M(w)s (decreases by 900-1700 Da) occurred at relatively low equilibrium sorbate concentrations (approximately 5-20 mg C 1-1); the decrease in solution M(w) suggested that reactive surface sites were occupied disproportionately by large and intermediate size NOM moieties. At higher equilibrium NOM concentrations (>20 mg C 1-1), as percent adsorption decreased, M(w) in solution was similar to original samples. A smaller decrease in solution NOM M(w) (300-500 Da at 10-20 mg C 1-1 ~ 100 Da at > 20 mg) also occurred upon sorption to kaolinite. Overall, our results showed that factors (as related to NOM composition, clay mineral surface properties, and position along the sorption isotherm) which promote a higher percent sorption lead to the most pronounced decreases in solution M(w).

Chemical Geology↗

Consequences of slow growth for 230Th/U dating of Quaternary opals, Yucca Mountain, NV, USA

Thermal ionization mass-spectrometry 234U/238U and 230Th/238U data are reported for uranium-rich opals coating fractures and cavities within the silicic tuffs forming Yucca Mountain, NV, the potential site of a high-level radioactive waste repository. High uranium concentrations (up to 207 ppm) and extremely high 230Th/232Th activity ratios (up to about 106) make microsamples of these opals suitable for precise 230Th/U dating. Conventional 230Th/U ages range from 40 to greater than 600 ka, and initial 234U/238U activity ratios between 1.03 and 8.2. Isotopic evidence indicates that the opals have not experienced uranium mobility; however, wide variations in apparent ages and initial 234U/238U ratios for separate subsamples of the same outermost mineral surfaces, positive correlation between ages and sample weights, and negative correlation between 230Th/U ages and calculated initial 234U/238U are inconsistent with the assumption that all minerals in a given subsample was deposited instantaneously. The data are more consistent with a conceptual model of continuous deposition where secondary mineral growth has occurred at a constant, slow rate up to the present. This model assumes that individual subsamples represent mixtures of older and younger material, and that calculations using the resulting isotope ratios reflect an average age. Ages calculated using the continuous-deposition model for opals imply average mineral growth rates of less than 5 mm/m.y. The model of continuous deposition also predicts discordance between ages obtained using different radiometric methods for the same subsample. Differences in half-lives will result in younger apparent ages for the shorter-lived isotope due to the greater influence of younger materials continuously added to mineral surfaces. Discordant 14C, 230Th/U and U-Pb ages obtained from outermost mineral surfaces at Yucca Mountain support this model. (C) 2000 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

REE speciation in low-temperature acidic waters and the competitive effects of aluminum

The effect of simultaneous competitive speciation of dissolved rare earth elements (REEs) in acidic waters (pH 3.3 to 5.2) has been evaluated by applying the PHREEQE code to the speciation of water analyses from Spain, Brazil, USA, and Canada. The main ions that might affect REE are Al3+, F-, SO42-, and PO43-. Fluoride, normally a significant complexer of REEs, is strongly associated with Al3+ in acid waters and consequently has little influence on REEs. The inclusion of aluminum concentrations in speciation calculations for acidic waters is essential for reliable speciation of REEs. Phosphate concentrations are too low (10-4 to 10-7 m) to affect REE speciation. Consequently, SO42- is the only important complexing ligand for REEs under these conditions. According to Millero [Millero, F.J., 1992. Stability constants for the formation of rare earth inorganic complexes as a function of ionic strength. Geochim. Cosmochim. Acta, 56, 3123-3132], the lanthanide sulfate stability constants are nearly constant with increasing atomic number so that no REE fractionation would be anticipated from aqueous complexation in acidic waters. Hence, REE enrichments or depletions must arise from mass transfer reactions.

Chemical Geology↗

Mobilization of major inorganic ions during experimental diagenesis of characterized peats

Laboratory experiments were undertaken to study changes in concentrations of major inorganic ions during simulated burial of peats to about 1.5 km. Cladium, Rhizophora, and Cyrilla peats were first analyzed to determine cation distributions among fractions of the initial materials and minerals in residues from wet oxidation. Subsamples of the peats (80 g) were then subjected to increasing temperatures and pressures in steps of 5??C and 300 psi at 2-day intervals and produced solutions collected. After six steps, starting from 30??C and 300 psi, a final temperature of 60??C and a final pressure of 2100 psi were achieved. The system was then allowed to stand for an additional 2 weeks at 60??C and 2100 psi. Treatments resulted in highly altered organic solids resembling lignite and expelled solutions of systematically varying compositions. Solutions from each step were analyzed for Na+, Ca2+, Mg2+, total dissolved Si (Si(T)), Cl-, SO42-, and organic acids and anions (OAAs). Some data on total dissolved Al (Al(T)) were also collected. Mobilization of major ions from peats during these experiments is controlled by at least three processes: (1) loss of dissolved ions in original porewater expelled during compaction, (2) loss of adsorbed cations as adsorption sites are lost during modification of organic solids, and (3) increased dissolution of inorganic phases at later steps due to increased temperatures (Si(T)) and increased complexing by OAAs (Al(T)). In general, results provide insight into early post-burial inorganic changes occurring during maturation of terrestrial organic matter. (C) 2000 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

An evaluation of effects of groundwater exchange on nearshore habitats and water quality of western Lake Erie

Historically, the high potentiometric surface of groundwater in the Silurian/Devonian carbonate aquifer in Monroe County, MI resulted in discharge of highly mineralized, SO 4 -rich groundwater to the Lake Erie shoreline near both Erie State Game Area (ESGA) and Pointe Mouillee State Game Area (PMSGA). Recently, regional groundwater levels near PMSGA have been drawn down as much as 45 m below lake level in apparent response to quarry dewatering. From August to November of 2003, we conducted preliminary studies of groundwater flow dynamics and chemistry, shallow lake water chemistry, and fish and invertebrate communities at both sites. Consistent with regional observations, groundwater flow direction in the nearshore at ESGA was upward, or toward Lake Erie, and shallow nearshore groundwater chemistry was influenced by regional groundwater chemistry. In contrast, at PMSGA, the groundwater flow potential was downward and lake water, influenced by quarry discharge seeping downward into nearshore sediments, produced a different lake and shallow groundwater chemistry than at ESGA. Although the invertebrate and young fish community was similar at the two sites, taxonomic groups tolerant of degraded water quality were more prevalent at PMSGA. Sensitive taxa were more prevalent at ESGA. We propose a conceptual model, based on well-described models of groundwater/seawater interaction along coastal margins, to describe the interconnection among geologic, hydrologic, chemical, and biological processes in the different nearshore habitats of Lake Erie, and we identify processes that warrant further detailed study in the Great Lakes.

Lake Erie↗

Analysis options for estimating status and trends in long-term monitoring

This chapter describes methods for estimating long-term trends in ecological parameters. Other chapters in this volume discuss more advanced methods for analyzing monitoring data, but these methods may be relatively inaccessible to some readers. Therefore, this chapter provides an introduction to trend analysis for managers and biologists while also discussing general issues relevant to trend assessment in any long-term monitoring program. For simplicity, we focus on temporal trends in population size across years. We refer to the survey results for each year as the “annual means” (e.g. mean per transect, per plot, per time period). The methods apply with little or no modification, however, to formal estimates of population size, other temporal units (e.g. a month), to spatial or other dimensions such as elevation or a north–south gradient, and to other quantities such as chemical or geological parameters. The chapter primarily discusses methods for estimating population-wide parameters rather than studying variation in trend within the population, which can be examined using methods presented in other chapters (e.g. Chapters 7, 12, 20). We begin by reviewing key concepts related to trend analysis. We then describe how to evaluate potential bias in trend estimates. An overview of the statistical models used to quantify trends is then presented. We conclude by showing ways to estimate trends using simple methods that can be implemented with spreadsheets.

Book chapter↗

Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review

This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O 2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors.

Chemical Geology↗

Groundwater data for selected wells within the Eastern San Joaquin Groundwater Subbasin, California, 2003-8

Data were collected by the U.S. Geological Survey from 2003 through 2008 in the Eastern San Joaquin Groundwater Subbasin, 80 miles east of San Francisco, California, as part of a study of the increasing chloride concentrations in groundwater processes. Data collected include geologic, geophysical, chemical, and hydrologic data collected during and after the installation of five multiple-well monitoring sites, from three existing multiple-well sites, and from 79 selected public-supply, irrigation, and domestic wells. Each multiple-well monitoring site installed as part of this study contained three to five 2-inch diameter polyvinyl chloride (PVC)-cased wells ranging in depth from 68 to 880 feet below land surface. Continuous water-level data were collected from the 19 wells installed at these 5 sites and from 10 existing monitoring wells at 3 additional multiple-well sites in the study area. Thirty-one electromagnetic logs were collected seasonally from the deepest PVC-cased monitoring well at seven multiple-well sites. About 200 water samples were collected from 79 wells in the study area. Coupled well-bore flow data and depth-dependent water-quality data were collected from 12 production wells under pumped conditions, and well-bore flow data were collected from 10 additional wells under unpumped conditions.

California↗

U.S. Geological Survey (USGS), Western Region: Coastal ecosystem responses to influences from land and sea, Coastal and Ocean Science

Sea otters and the nearshore ecosystems they inhabit-from highly urbanized California to relatively pristine Alaska-are the focus of a new multidisciplinary study by scientists with the U.S. Geological Survey (USGS) and a suite of international, academic and government collaborators. The Coastal Ecosystem Responses to Influences from Land and Sea project will investigate the many interacting variables that influence the health of coastal ecosystems along the Northeast Pacific shore. These ecosystems face unprecedented challenges, with threats arising from the adjacent oceans and lands. From the ocean, challenges include acidification, sea level rise, and warming. From the land, challenges include elevated biological, geological and chemical pollutants associated with burgeoning human populations along coastlines. The implications of these challenges for biological systems are only beginning to be explored. Comparing sea otter population status indicators from around the northeastern Pacific Rim, will begin the process of defining factors of coastal ecosystem health in this broad region.

Fact Sheet↗

Science for maintaining riverine ecosystems: Actions for the USGS identified in the workshop "Analysis of Flow and Habitat for Aquatic Communities"

Federal and state agencies need improved scientific analysis to support riverine ecosystem management. The ability of the USGS to integrate geologic, hydrologic, chemical, geographic, and biological data into new tools and models provides unparalleled opportunities to translate the best riverine science into useful approaches and usable information to address issues faced by river managers. In addition to this capability to provide integrated science, the USGS has a long history of providing long-term and nationwide information about natural resources. The USGS is now in a position to advance its ability to provide the scientific support for the management of riverine ecosystems. To address this need, the USGS held a listening session in Fort Collins, Colorado in April 2006. Goals of the workshop were to: 1) learn about the key resource issues facing DOI, other Federal, and state resource management agencies; 2) discuss new approaches and information needs for addressing these issues; and 3) outline a strategy for the USGS role in supporting riverine ecosystem management. Workshop discussions focused on key components of a USGS strategy: Communications, Synthesis, and Research. The workshop identified 3 priority actions the USGS can initiate now to advance its capabilities to support integrated science for resource managers in partner government agencies and non-governmental organizations: 1) Synthesize the existing science of riverine ecosystem processes to produce broadly applicable conceptual models, 2) Enhance selected ongoing instream flow projects with complementary interdisciplinary studies, and 3) Design a long-term, watershed-scale research program that will substantively reinvent riverine ecosystem science. In addition, topical discussion groups on hydrology, geomorphology, aquatic habitat and populations, and socio-economic analysis and negotiation identified eleven important complementary actions required to advance the state of the science and to develop the tools for supporting decisions on riverine ecosystem management. These eleven actions lie within the continuum of Communications, Synthesis, and Research.

Open-File Report↗