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USGS2002

Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis

“Two-line” ferrihydrite samples precipitated and then exposed to a range of aqueous Zn solutions (10 −5 to 10 −3 M), and also coprecipitated in similar Zn solutions (pH 6.5), have been examined by Zn and Fe K-edge X-ray absorption spectroscopy. Typical Zn complexes on the surface have Zn-O distances of 1.97(.02) Å and coordination numbers of about 4.0(0.5), consistent with tetrahedral oxygen coordination. This contrasts with Zn-O distances of 2.11(.02) Å and coordination numbers of 6 to 7 in the aqueous Zn solutions used in sample preparation. X-ray absorption extended fine structure spectroscopy (EXAFS) fits to the second shell of cation neighbors indicate as many as 4 Zn-Fe neighbors at 3.44(.04) Å in coprecipitated samples, and about two Zn-Fe neighbors at the same distance in adsorptionsamples. In both sets of samples, the fitted coordination number of second shell cations decreases as sorption density increases, indicating changes in the number and type of available complexing sites or the onset of competitive precipitation processes. Comparison of our results with the possible geometries for surface complexes and precipitates suggests that the Zn sorption complexes are inner sphere and at lowest adsorption densities are bidentate, sharing apical oxygens with adjacent edge-sharing Fe(O,OH) 6 octahedra. Coprecipitation samples have complexes with similar geometry, but these are polydentate, sharing apices with more than two adjacent edge-sharing Fe(O,OH) 6 polyhedra. The results are inconsistent with Zn entering the ferrihydrite structure (i.e., solid solution formation) or formation of other Zn-Fe precipitates. The fitted Zn-Fe coordination numbers drop with increasing Zn density with a minimum of about 0.8(.2) at Zn/(Zn + Fe) of 0.08 or more. This change appears to be attributable to the onset of precipitation of zinc hydroxide polymers with mainly tetrahedral Zn coordination. At the highest loadings studied, the nature of the complexes changes further, and a second type of precipitate forms. This has a structure based on a brucite layer topology, with mainly octahedral Zn coordination. Amorphous zinc hydroxide samples prepared for comparison had a closely similar local structure. Analysis of the Fe K-edge EXAFS is consistent with surface complexation reactions and surface precipitation at high Zn loadings with little or no Fe-Zn solid solution formation. The formation of Zn-containing precipitates at solution conditions two or more orders of magnitude below their solubility limit is compared with other sorption and spectroscopic studies that describe similar behavior.

Geochimica et Cosmochimica Acta↗

USGS1998

The Cascadia Subduction Zone: Two contrasting models of lithospheric structure

The Pacific margin of North America is one of the most complicated regions in the world in terms of its structure and present day geodynamic regime. The aim of this work is to develop a better understanding of lithospheric structure of the Pacific Northwest, in particular the Cascadia subduction zone of Southwest Canada and Northwest USA. The goal is to compare and contrast the lithospheric density structure along two profiles across the subduction zone and to interpet the differences in terms of active processes. The subduction of the Juan de Fuca plate beneath North America changes markedly along the length of the subduction zone, notably in the angle of subduction, distribution of earthquakes and volcanism, goelogic and seismic structure of the upper plate, and regional horizontal stress. To investigate these characteristics, we conducted detailed density modeling of the crust and mantle along two transects across the Cascadia subduction zone. One crosses Vancouver Island and the Canadian margin, the other crosses the margin of central Oregon.

Oregon, Washington, British Columbia↗

USGS2010

Structural features of a bituminous coal and their changes during low-temperature oxidation and loss of volatiles investigated by advanced solid-state NMR spectroscopy

Quantitative and advanced 13 C solid-state NMR techniques were employed to investigate (i) the chemical structure of a high volatile bituminous coal, as well as (ii) chemical structural changes of this coal after evacuation of adsorbed gases, (iii) during oxidative air exposure at room temperature, and (iv) after oxidative heating in air at 75 ??C. The solid-state NMR techniques employed in this study included quantitative direct polarization/magic angle spinning (DP/MAS) at a high spinning speed of 14 kHz, cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CH, CH 2 , and CH n selection, 13 C chemical shift anisotropy (CSA) filtering, two-dimensional (2D) 1 H- 13 C heteronuclear correlation NMR (HETCOR), and 2D HETCOR with 1 H spin diffusion. With spectral editing techniques, we identified methyl CCH 3 , rigid and mobile methylene CCH 2 C, methine CCH, quaternary C q , aromatic CH, aromatic carbons bonded to alkyls, small-sized condensed aromatic moieties, and aromatic C-O groups. With direct polarization combined with spectral-editing techniques, we quantified 11 different types of functional groups. 1 H- 13 C 2D HETCOR NMR experiments indicated spatial proximity of aromatic and alkyl moieties in cross-linked structures. The proton spin diffusion experiments indicated that the magnetization was not equilibrated at a 1 H spin diffusion time of 5 ms. Therefore, the heterogeneity in spatial distribution of different functional groups should be above 2 nm. Recoupled C-H long-range dipolar dephasing showed that the fraction of large charcoal-like clusters of polycondensed aromatic rings was relatively small. The exposure of this coal to atmospheric oxygen at room temperature for 6 months did not result in obvious chemical structural changes of the coal, whereas heating at 75 ??C in air for 10 days led to oxidation of coal and generated some COO groups. Evacuation removed most volatiles and caused a significant reduction in aliphatic signals in its DP/MAS spectrum. DP/MAS, but not CP/MAS, allowed us to detect the changes during low-temperature oxidation and loss of volatiles. These results demonstrate the applicability of advanced solid-state NMR techniques in chemical characterization of coal. ?? 2010 American Chemical Society.

Conference Paper↗

USGS2002

Crustal structure of central Lake Baikal: Insights into intracontinental rifting

The Cenozoic rift system of Baikal, located in the interior of the largest continental mass on Earth, is thought to represent a potential analog of the early stage of breakup of supercontinents. We present a detailed P wave velocity structure of the crust and sediments beneath the Central Basin, the deepest basin in the Baikal rift system. The structure is characterized by a Moho depth of 39–42.5 km; an 8-km-thick, laterally continuous high-velocity (7.05–7.4 km/s) lower crust, normal upper mantle velocity (8 km/s), a sedimentary section reaching maximum depths of 9 km, and a gradual increase of sediment velocity with depth. We interpret the high-velocity lower crust to be part of the Siberian Platform that was not thinned or altered significantly during rifting. In comparison to published results from the Siberian Platform, Moho under the basin is elevated by <3 km. On the basis of these results we propose that the basin was formed by upper crustal extension, possibly reactivating structures in an ancient fold-and-thrust belt. The extent and location of upper mantle extension are not revealed by our data, and it may be offset from the rift. We believe that the Baikal rift structure is similar in many respects to the Mesozoic Atlantic rift system, the precursor to the formation of the North Atlantic Ocean. We also propose that the Central Baikal rift evolved by episodic fault propagation and basin enlargement, rather than by two-stage rift evolution as is commonly assumed.

Lake Baikal↗

USGS2004

Crystallographic controls on the frictional behavior of dry and water-saturated sheet structure minerals

We compare the frictional strengths of 17 sheet structure mineral powders, measured under dry and water-saturated conditions, to identify the factors that cause many of them to be relatively weak. The dry coefficient of friction μ ranges upward from 0.2 for graphite, leveling off at 0.8 for margarite, clintonite, gibbsite, kaolinite, and lizardite. The values of μ (dry) correlate directly with calculated (001) interlayer bond strengths of the minerals. This correlation occurs because shear becomes localized along boundary and Riedel shears and the platy minerals in them rotate into alignment with the shear planes. For those gouges with μ (dry) < 0.8, shear occurs by breaking the interlayer bonds to form new cleavage surfaces. Where μ (dry) = 0.8, consistent with Byerlee's law, the interlayer bonds are sufficiently strong that other frictional processes dominate. The transition in dry friction mechanisms corresponds to calculated surface energies of 2–3 J/m 2 . Adding water causes μ to decrease for every mineral tested except graphite. If the minerals are separated into groups with similar crystal structures, μ (wet) increases with increasing interlayer bond strength within each group. This relationship also holds for the swelling clay montmorillonite, whose water-saturated strength is consistent with the strengths of nonswelling clays of similar crystal structure. Water in the saturated gouges forms thin, structured films between the plate surfaces. The polar water molecules are bonded to the plate surfaces in proportion to the mineral's surface energy, and μ (wet) reflects the stresses required to shear through the water films.

Journal of Geophysical Research B: Solid Earth↗

USGS2011

Drilling the central crater of the Chesapeake Bay Impact Structure: A first look

The late Eocene Chesapeake Bay impact structure is a well‐preserved example of one of Earth's largest impact craters, and its continental‐shelf setting and relatively shallow burial make it an excellent target for study. Since the discovery of the structure over a decade ago [ Edwards et al., 2004; Poag et al., 2004], test drilling by U.S. federal and state agencies has been limited to the structure's annular trough (Figure 1). In May 2004, the U.S. Geological Survey (USGS) drilled the first scientific test hole into the central crater of the Chesapeake Bay impact structure in Cape Charies,Virginia (Figure 1). This partially cored test hole, the deepest to date, penetrated postimpact sediments and impact breccias to a total depth of 823 m.

Chesapeake Bay↗

USGS2021

Exploring GPS observations of postseismic deformation following the 2012 MW7.8 Haida Gwaii and 2013 MW7.5 Craig, Alaska Earthquakes: Implications for viscoelastic Earth structure

The Queen Charlotte-Fairweather Fault (QC-FF) system off the coast of British Columbia and southeast Alaska is a highly active dextral strike-slip plate boundary that accommodates ∼50 mm/yr of relative motion between the Pacific and North America plates. Nine M W ≥ 6.7 earthquakes have occurred along the QC-FF system since 1910, including a M S (G-R) 8.1 event in 1949. Two recent earthquakes, the October 28, 2012 Haida Gwaii ( M W 7.8) and January 5, 2013 Craig, Alaska ( M W 7.5) events, produced postseismic transient deformation that was recorded in the motions of 25 nearby continuous Global Positioning System (cGPS) stations. Here, we use 5+ yr of cGPS measurements to characterize the underlying mechanisms of postseismic deformation and to constrain the viscosity structure of the upper mantle surrounding the QC-FF. We construct forward models of viscoelastic deformation driven by coseismic stress changes from these two earthquakes and explore a large set of laterally heterogeneous viscosity structures that incorporate a relatively weak back-arc domain; we then evaluate each model based on its fit to the postseismic signals in our cGPS data. In determining best-fit model structures, we additionally incorporate the effects of afterslip following the 2012 event. Our results indicate the occurrence of a combination of temporally decaying afterslip and vigorous viscoelastic relaxation of the mantle asthenosphere. In addition, our best-fit viscosity structure (transient viscosity of 1.4–2.0 × 10 18 Pa s; steady-state viscosity of 10 19 Pa s) is consistent with the range of upper mantle viscosities determined in previous studies of glacial isostatic rebound and postseismic deformation.

Alaska, British Columbia↗

USGS2023

Identifying structural priors in a hybrid differentiable model for stream water temperature modeling

Although deep learning models for stream temperature ( T s ) have recently shown exceptional accuracy, they have limited interpretability and cannot output untrained variables. With hybrid differentiable models, neural networks (NNs) can be connected to physically based equations (called structural priors) to output intermediate variables such as water source fractions (specifying what portion of water is groundwater, subsurface, and surface flow). However, it is unclear if such outputs are physically meaningful when only limited physics is imposed, and if structural priors have enough impacts to be identifiable from data. Here, we tested four alternative structural priors describing basin-scale water temperature memory and instream heat processes in a differentiable stream temperature model where NNs freely estimate the water source fractions. We evaluated models’ abilities to predict T s and baseflow ratio. The four priors exhibited noticeably different behaviors in these two metrics and their tradeoffs, with some dominating others. Therefore, the better structural priors can be identified. Moreover, testing different priors yielded valuable insights: having a separate shallow subsurface flow component better matches observations, and a recency-weighted averaging of past air temperature for calculating source water temperature resulted in better T s and baseflow prediction than traditionally employed simple averaging. However, we also highlight the limitations when insufficient physical constraints are implemented: the internal variables (water source fractions) may not be adequately constrained by a single target variable (stream temperature) alone. To ensure the physical significance of the internal fluxes, one can either employ multivariate data for model selection, or include more physical processes in the priors.

Water Resources Research↗

USGS2012

Chemical bonding in the outer core: high-pressure electronic structures of oxygen and sulfur in metallic iron

From its density the outer core is believed to be an alloy of iron and a light element such as sulfur or oxygen. The nature of the light element in the core is an important constraint for theories of the Earth's formation. In this paper the electronic structures of oxygen and sulfur impurities in metallic iron are investigated to determine if pressure, temperature, and composition-induced changes in bonding might affect phase equilibria along the Fe-FeS and Fe-FeO binaries. The electronic structure of sulfur in metallic iron is consistent with the miscibility between Fe and FeS liquids. Volume compression strengthens the Fe-S bond, and it is expected that at sufficiently high pressure, sulfur can substitute for Fe and give solid solution behavior between Fe and FeS. In contrast, the electronic structure of oxygen in metallic iron shows that oxygen cannot act as a substitutional impurity (replacing Fe). This explains the observed miscibility gap on the Fe-FeO binary at 1 atm pressure. Volume compression does not greatly change the electronic structure if oxygen substitutes for iron in bcc and fcc iron. Iron-oxygen bonding does occur, however, if oxygen occupies interstitial sites. Insofar as the molar volume of FeO incorporated as interstitial oxygen in metallic iron is smaller than that of pure FeO, the incorporation of oxygen into metallic iron may be favored under the pressures of the Earth's core.

Journal of Geophysical Research↗

USGS2012

Gravity survey of the Mount Toondina impact structure, South Australia

Gravity and seismic reflection data, together with geologic mapping, indicate that the Mount Toondina feature in South Australia is best interpreted as an eroded 4-km-diameter impact structure consisting of a ring structural depression surrounding a pronounced central uplift. Beds at the center of the structure within the central uplift have been raised as much as 200 m from depth and deformed by convergent flow. Seismic reflection data indicate that deformation extends to depths of only ≈800 m; at greater depths the reflectors are nearly flat lying, indicating little or no deformation. Gravity data show residual anomalies of +1.0 mGal coincident with the central uplift and a −0.5 Mgal low associated with the ring structural depression. Modeling of the gravity data indicates that relatively high-density material occurs within the central uplift, whereas the ring depression is filled with low-density material. The deformation at Mount Toondina is typical of a complex impact crater; the 4-km diameter is consistent with the expected threshold size for complex craters formed in weak to moderate strength sedimentary rocks.

South Australia↗

USGS2012

Seismic velocity structure and composition of the continental crust: A global view

Seismic techniques provide the highest‐resolution measurements of the structure of the crust and have been conducted on a worldwide basis. We summarize the structure of the continental crust based on the results of seismic refraction profiles and infer crustal composition as a function of depth by comparing these results with high‐pressure laboratory measurements of seismic velocity for a wide range of rocks that are commonly found in the crust. The thickness and velocity structure of the crust are well correlated with tectonic province, with extended crust showing an average thickness of 30.5 km and orogens an average of 46.3 km. Shields and platforms have an average crustal thickness nearly equal to the global average. We have corrected for the nonuniform geographical distribution of seismic refraction profiles by estimating the global area of each major crustal type. The weighted average crustal thickness based on these values is 41.1 km. This value is 10% to 20% greater than previous estimates which underrepresented shields, platforms, and orogens. The average compressional wave velocity of the crust is 6.45 km/s, and the average velocity of the uppermost mantle ( Pn velocity) is 8.09 km/s. We summarize the velocity structure of the crust at 5‐km depth intervals, both in the form of histograms and as an average velocity‐depth curve, and compare these determinations with new measurements of compressional wave velocities and densities of over 3000 igneous and metamorphic rock cores made to confining pressures of 1 GPa. On the basis of petrographic studies and chemical analyses, the rocks have been classified into 29 groups. Average velocities, densities, and standard deviations are presented for each group at 5‐km depth intervals to crustal depths of 50 km along three different geotherms. This allows us to develop a model for the composition of the continental crust. Velocities in the upper continental crust are matched by velocities of a large number of lithologies, including many low‐grade metamorphic rocks and relatively silicic gneisses of amphibolite facies grade. In midcrustal regions, velocity gradients appear to originate from an increase in metamorphic grade, as well as a decrease in silica content. Tonalitic gneiss, granitic gneiss, and amphibolite are abundant midcrustal lithologies. Anisotropy due to preferred mineral orientation is likely to be significant in upper and midcrustal regions. The bulk of the lower continental crust is chemically equivalent to gabbro, with velocities in agreement with laboratory measurements of mafic granulite. Garnet becomes increasingly abundant with depth, and mafic garnet granulite is the dominant rock type immediately above the Mohorovicic discontinuity. Average compressional wave velocities of common crustal rock types show excellent correlations with density. The mean crustal density calculated from our model is 2830 kg/m 3 , and the average SiO 2 content is 61.8%.

Journal of Geophysical Research B: Solid Earth↗

USGS1996

Three-dimensional P and S wave velocity structure of Redoubt Volcano, Alaska

The three‐dimensional P and S wave structure of Redoubt Volcano, Alaska, and the underlying crust to depths of 7–8 km is determined from 6219 P wave and 4008 S wave first‐arrival times recorded by a 30‐station seismograph network deployed on and around the volcano. First‐arrival times are calculated using a finite‐difference technique, which allows for flexible parameterization of the slowness model and easy inclusion of topography and source‐receiver geometry. The three‐dimensional P wave velocity structure and hypocenters are determined simultaneously, while the three‐dimensional S wave velocity model is determined using the relocated seismicity and an initial S wave velocity model derived from the P wave velocity model assuming an average Vp / Vs ratio of 1.78. Convergence is steady with approximately 73% and 52% reduction in P and S wave arrival time RMS, respectively, after 10 iterations. The most prominent feature observed in the three‐dimensional velocity models derived for both P and S waves is a relative low‐velocity, near‐vertical, pipelike structure approximately 1 km in diameter that extends from 1 to 6 km beneath sea level. This feature aligns axially with the bulk of seismicity and is interpreted as a highly fractured and altered zone encompassing a magma conduit. The velocity structure beneath the north flank of the volcano between depths of 1 and 6 km is characterized by large lateral velocity variations. High velocities within this region are interpreted as remnant dikes and sills and low velocities as regions along which magma migrates. No large low‐velocity body suggestive of a magma chamber is resolved in the upper 7–8 km of the crust.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Active faulting and deformation of the Coalinga anticline as interpreted from three-dimensional velocity structure and seismicity

This work gives a clear picture of the geometry of aftershock seismicity in a large thrust earthquake. Interpretation of hypocenters and fault plane solutions, from the 1983 Coalinga, Coast Range California, earthquake sequence, in combination with the three-dimensional velocity structure shows that the active faulting beneath the fold primarily consists of a set of southwest dipping thrusts uplifting blocks of higher-velocity material. Above the main listric blind thrust there is a conjugate fault, steeply northeast dipping, that provides the western limit of the aftershocks within the Coalinga Anticline and that corresponds in location and spatial extent with the adjacent Pleasant Valley syncline. The character of the seismicity varies with the degree of previous deformation on each section of the anticline. Where the previous uplift was largest, the shallow seismicity shows secondary faulting on either side of the fold with orientations that correspond to the preexisting geologic structure. Diffuse seismicity characterizes the area with the least previous deformation. The mainshock rupture terminated where the fold trend was no longer uniform but had competing north and west trending features. The upward extent of the mainshock rupture ended at the approximate boundary between Franciscan and Great Valley Sequence rocks. Above that depth the main thrust appears to splay into a steeper segment and a near-horizontal segment. Thus the extent of rupture area is limited by the area of uniform structural orientation and by the variation in the type of material. With the three-dimensional velocity model each individual hypocenter moved slightly (0–2 km) in accord with the details of the surrounding velocity structure, so that secondary features in the seismicity pattern are more detailed than with a local one-dimensional model and station corrections. The overall character of the fault plane solutions was not altered by the three-dimensional model, but the more accurate ray paths did result in distinct changes. In particular, the mainshock has a fault plane dipping 30° southwest instead of the 23° obtained with the one-dimensional model.

Journal of Geophysical Research Solid Earth↗

USGS2012

Crustal structure of the northwestern Basin and Range Province from the 1986 Program for Array Seismic Studies of the Continental Lithosphere Seismic Experiment

A portion of northwestern Nevada was imaged to determine the crustal structure and to assess reported differences between refraction versus reflection determinations of Moho depth and how the crustal composition and structure has been influenced by volcanic and extension mechanisms. Interpretation of the refraction/wide-angle reflection data suggests that the crust is fairly uniform in thickness and varies by less than 5 km over the 280 km east-west profile and 3 km over its 220 km north-south length. The velocity structure is characterized by five layers: 1) an uppermost crust, composed of sedimentary rocks and basement that has an average velocity of 5.7 km s-1; 2) a middle crust that extends to a depth of 18-22 with an average velocity of 6.1 km s-1; 3) a 10-12 km thick lower crust with an average velocity of 6.6 km s-1; 4) a 2-5 km thick transitional crust-mantle boundary defined by a 7.6 km s-1 velocity; and 5) an upper mantle with an average Pn velocity of 7.9-8.0 km s-1. A uniform upper mantle composition across the Basin and Range is suggested and the homogeneity of the velocity structure beneath the western Basin and Range argues for a youthful Moho and crust that has been reworked by province-wide late Cenozoic extension, episodic magmatism, and underplating. -from Authors

Journal of Geophysical Research↗

USGS2001

Three-dimenstional crustal velocity structure beneath the Strait of Georgia, British Columbia

The Strait of Georgia is a topographic depression straddling the boundary between the Insular and Coast belts in southwestern British Columbia. Two shallow earthquakes located within the strait ( M = 4.6 in 1997 and M = 5.0 in 1975) and felt throughout the Vancouver area illustrate the seismic potential of this region. As part of the 1998 Seismic Hazards Investigation of Puget Sound (SHIPS) experiment, seismic instruments were placed in and around the Strait of Georgia to record shots from a marine source within the strait. We apply a tomographic inversion procedure to first-arrival traveltime data to derive a minimum-structure 3-D P -wave velocity model for the upper crust to about 13 km depth. We also present a 2-D velocity model for a profile orientated across the Strait of Georgia derived using a minimum-parameter traveltime inversion approach. This paper represents the first detailed look at crustal velocity variations within the major Cretaceous to Cenozoic Georgia Basin, which underlies the Strait of Georgia. The 3-D velocity model clearly delineates the structure of the Georgia Basin. Taking the 6 km s −1 isovelocity contour to represent the top of the underlying basement, the basin thickens from between 2 and 4 km in the northwestern half of the strait to between 8 and 9 km at the southeastern end of the study region. Basin velocities in the northeastern half are 4.5–6 km s −1 and primarily represent the Upper Cretaceous Nanaimo Group. Velocities to the south are lower (3–6 km s −1 ) because of the additional presence of the overlying Tertiary Huntingdon Formation and more recent sediments, including glacial and modern Fraser River deposits. In contrast to the relatively smoothly varying velocity structure of the basin, velocities of the basement rocks, which comprise primarily Palaeozoic to Jurassic rocks of the Wrangellia Terrane and possibly Jurassic to mid-Cretaceous granitic rocks of the Coast Belt, show significantly more structure, probably an indication of the varying basement rock lithologies. The 2-D velocity model more clearly reveals the velocity layering associated with the recent sediments, Huntingdon Formation and Nanaimo Group of the southern Georgia Basin, as well as the underlying basement. We interpret lateral variation in sub-basin velocities of the 2-D model as a transition from Wrangellian to Coast Belt basement rocks. The effect of the narrow, onshore–offshore recording geometry of the seismic experiment on model resolution was tested to allow a critical assessment of the validity of the 3-D velocity model. Lateral resolution throughout the model to a depth of 3–5 km below the top of the basement is generally 10–20 km.

British Columbia↗

USGS2012

Strong Motion Instrumentation of Seismically-Strengthened Port Structures in California by CSMIP

The California Strong Motion Instrumentation Program (CSMIP) has instrumented five port structures. Instrumentation of two more port structures is underway and another one is in planning. Two of the port structures have been seismically strengthened. The primary goals of the strong motion instrumentation are to obtain strong earthquake shaking data for verifying seismic analysis procedures and strengthening schemes, and for post-earthquake evaluations of port structures. The wharves instrumented by CSMIP were recommended by the Strong Motion Instrumentation Advisory Committee, a committee of the California Seismic Safety Commission. Extensive instrumentation of a wharf is difficult and would be impossible without the cooperation of the owners and the involvement of the design engineers. The instrumentation plan for a wharf is developed through study of the retrofit plans of the wharf, and the strong-motion sensors are installed at locations where specific instrumentation objectives can be achieved and access is possible. Some sensor locations have to be planned during design; otherwise they are not possible to install after construction. This paper summarizes the two seismically-strengthened wharves and discusses the instrumentation schemes and objectives. ?? 2009 ASCE.

Conference Paper↗

USGS2003

Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions

Recently x-ray absorption fine structure (XAFS) studies of various ions in aqueous solutions showed a variation of cation-ligand bond lengths, often coupled with other structure changes, with increasing temperatures. Thus, the variations of the structure of several metal ion complexes with temperature based on observations from the X-ray absorption fine structure (XAFS) studies in the hope that it will stimulate the development of either first- principles theory or molecular dynamics simulations that might adequately describes these results are discussed.

Journal of Chemical Physics↗

USGS2005

Using chaotic forcing to detect damage in a structure

In this work we develop a numerical test for Holder continuity and apply it and another test for continuity to the difficult problem of detecting damage in structures. We subject a thin metal plate with incremental damage to the plate changes, its filtering properties, and therefore the phase space trajectories of the response chaotic excitation of various bandwidths. Damage to the plate changes its filtering properties and therefore the phase space of the response. Because the data are multivariate (the plate is instrumented with multiple sensors) we use a singular value decomposition of the set of the output time series to reduce the embedding dimension of the response time series. We use two geometric tests to compare an attractor reconstructed from data from an undamaged structure to that reconstructed from data from a damaged structure. These two tests translate to testing for both generalized and differentiable synchronization between responses. We show loss of synchronization of responses with damage to the structure.

Chaos↗