Computer-aided estimates of concentrating-grade iron resources in the Negaunee Iron-formation, Marquette District, Michigan
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Remote sensing and measurements of the Moon from Apollo orbiting spacecraft and Earth form a basis for extrapolation of Apollo surface data to regions of the Moon where manned and unmanned spacecraft have not been and may be used to discover target regions for future lunar exploration which will produce the highest scientific yields. Orbital remote sensing and measurements discussed include (1) relative ages and inferred absolute ages, (2) gravity, (3) magnetism, (4) chemical composition, and (5) reflection of radar waves (bistatic). Earth-based remote sensing and measurements discussed include (1) reflection of sunlight, (2) reflection and scattering of radar waves, and (3) infrared eclipse temperatures. Photographs from the Apollo missions, Lunar Orbiters, and other sources provide a fundamental source of data on the geology and topography of the Moon and a basis for comparing, correlating, and testing the remote sensing and measurements. Relative ages obtained from crater statistics and then empirically correlated with absolute ages indicate that significant lunar volcanism continued to 2.5 b.y. (billion years) ago-some 600 m.y. (million years) after the youngest volcanic rocks sampled by Apollo-and that intensive bombardment of the Moon occurred in the interval of 3.84 to 3.9 b.y. ago. Estimated fluxes of crater-producing objects during the last 50 m.y. agree fairly well with fluxes measured by the Apollo passive seismic stations. Gravity measurements obtained by observing orbiting spacecraft reveal that mare basins have mass concentrations and that the volume of material ejected from the Orientale basin is near 2 to 5 million km 3 depending on whether there has or has not been isostatic compensation, little or none of which has occurred since 3.84 b.y. ago. Isostatic compensation may have occurred in some of the old large lunar basins, but more data are needed to prove it. Steady fields of remanent magnetism were detected by the Apollo 15 and 16 subsatellites, and the lunar dipole field was revised to no more than 6x 10 19 gauss. High-resolution mapping of fields of weak remanent magnetism (to 0.1 gamma) was made possible by the Apollo plasma and energetic-particle experiment. Although the causes of remanent magnetism are poorly understood, correlations with geologic units suggest the results may ultimately have farreaching significance to lunar history. Maria are much less structured by strong surface magnetic anomalies than the highlands. The strongest anomalies are associated with ejecta of farside basins, plains materials filling pre-Imbrian craters, and other old Imbrian to pre-Imbrian units. The high remanent fields could be due to cooling of ejecta units in an ancient magnetic field, lunar regolith maturity, extensive reworking and disruption of a magnetized layer, or simply surface roughness. Orbital geochemical experiments have shown that lunar high lands have larger Al: Si ratios and smaller Mg: Si ratios than maria. These two ratios are inversely related on a regional basis. With the exception of fresh craters, albedo and Al : Si ratios vary directly, showing that compositional differences as well as exposure of fresh materials are responsible for high albedos. Statistically treated data show that geologic contacts and compositional boundaries are concentric and can be roughly matched. Some craters on mare material have penetrated the mare fill, bringing highland-type materials to the surface. Natural radioactivity from thorium, potassium, and uranium is inversely correlated with elevation. Mare regions are enriched in iron, titanium, and magnesium relative to the highlands. Orbital bistatic-radar results provide estimates of surface roughness at two scale lengths (about 30 m and 250 m), which agree with visual estimates of roughness. The dielectric constant of the lunar surface, where sampled, is uniform to 13-cm radar and near 3. Slope frequency distributions measured by the radar vary and
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Alkalic igneous rocks and related concentrations of thorium, niobium, rare-earth elements, titanium, and other elements have long been known in the Powderhorn mining district and have been explored intermittently for several decades. The deposits formed chiefly about 570 m.y. (million years) ago in latest Precambrian or Early Cambrian time. They were emplaced in lower Proterozoic (Proterozoic X) metasedimentary, metavolcanic, and plutonic rocks. The complex of alkalic rocks of Iron Hill occupies 31 km 2 (square kilometers) and is composed of pyroxenite, uncompahgrite, ijolite, nepheline syenite, and carbonatite, in order of generally decreasing age. Fenite occurs in a zone, in places more than 0.6 km (kilometer) wide, around a large part of the margin of the complex and adjacent to alkalic dikes intruding Precambrian host rock. The alkalic rocks have a radioactivity, chiefly due to thorium, greater than that of the surrounding Powderhorn Granite (Proterozoic X) and metamorphic rocks. The pyroxenite, uncompahgrite, ijolite, and nepheline syenite, which form more than 80 percent of the complex, have fairly uniform radioactivity. Radioactivity in the carbonatite stock, carbonatite dikes, and the carbonatite-pyroxenite mixed rock zone, however, generally exceeds that in the other rocks of the complex. The thorium concentrations in the Powderhorn district occur in six types of deposits: thorite veins, a large massive carbonatite body, carbonatite dikes, trachyte dikes, magnetite-ilmeniteperovskite dikes or segregations, and disseminations in small, anomalously radioactive plutons chiefly of granite or quartz syenite that are older than rocks of the alkalic complex. The highest grade thorium concentrations in the district are in veins that commonly occur in steeply dipping, crosscutting shear or breccia zones in the Precambrian rocks. They range in thickness from a centimeter or less to 5 m (meters) and are as much as 1 km long. The thorite veins are composed chiefly of potassic feldspar, white to smoky quartz, calcite, barite, goethite, and hematite, and also contain thorite, jasper, magnetite, pyrite, galena, chalcopyrite, sphalerite, synchysite, apatite, fluorite, biotite, sodic amphibole, rutile, monazite, bastnaesite, and vanadinite. The Th0 2 content of the thorite veins ranges from less than 0.01 percent to as much as 4.9 percent in high-grade samples. The Th0 2 content is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins examined in the district. Samples of the dolomitic carbonatite of Iron Hill mostly range from 3 to 145 ppm (parts per million) thorium. Thirty samples of the carbonatite dikes, the most radioactive rocks within the complex of Iron Hill, contain about 30 to 3,200 ppm thorium and a trace to about 1.5 percent rare-earth oxides. The magnetite-ilmenite-perovskite rocks have a radioactivity of 2 to 12 times the background of Precambrian granite that is attributable chiefly to thorium substitution for calcium in the perovskite. In two analyses the perovskite contains 0.12 and 0.15 percent Th0 2 . Trachyte dikes as much as 25 m thick cut the Precambrian rocks; their radioactivity is generally about two to four times the background of typical Precambrian granite, is locally higher, but is low relative to other types of thorium concentrations. A finegrained granite that is anomalously radioactive occurs in thick, dikelike plutons as much as 1.2 km wide, or more. The thorium content varies widely within the granite bodies. Eight samples of the granite contain 32 to 281 ppm thorium (averaging 115 ppm). The economic potential of thorium in the Powderhorn district is related in part to other elements such as niobium, titanium, iron, and rare earths. The proportions of niobium and rare earths to thorium vary in different parts of the district. Within the carbonatite body of Iron Hill, the Nb 2 0 5 content greatly exceeds Th0 2 , but the Th0 2 -Nb 2 0 5
The Bear Lodge Mountains are a small northerly trending range approximately 16 km northwest of the Black Hills in the northeast corner of Wyoming. Thorium and rare-earth deposits occur over an area of 16 km 2 in the southern part of these mountains. These deposits occur in the core of the Bear Lodge dome in a large multiple intrusive body made up principally of trachyte and phonolite. Two types of deposits are recognized: disseminated deposits and veins. The disseminated deposits are made up of altered igneous rocks cut by numerous crisscrossing veinlets. The disseminated deposits contain thorium and rare-earth minerals in a matrix consisting principally of potassium feldspar, quartz, and iron and manganese oxides. Total rare-earth content of these deposits is about 27 times that of the thorium content. The general size and shape of the disseminated deposits were outlined by making a radiometric map using a scintillation counter of the entire Bear Lodge core, an area of approximately 30 km 2 . The most favorable part of this area, which was outlined by the 40 countJs (count-per-second) isograd on the radiometric map, was sampled in detail. A total of 341 samples were taken over an area of 10.6 km 2 and analyzed for as many as 60 elements. Rare earths and thorium are the principal commodities of interest in these deposits. Total rare-earth content of these samples ranged from 47 to 27,145 ppm (parts per million), and the thorium content from 9.3 to 990 ppm. The amount of total rare earths of individual samples shows little correlation with that of thorium. Contour maps were constructed using the analytical data for total rare earths, thorium, uranium, and potassium. The total rare-earth and thorium maps can be used to define the size of the deposits based on what cut-off grade may be needed during mining. The size is large as the 2,000 ppm total rare-earth isograd encloses several areas that total 3.22 km 2 in size, and the 200 ppm thorium isograd encloses several areas that total 1.69 km 2 . These deposits could be mined by open pit. The Bear Lodge disseminated deposits have one of the largest resources of both total rare earths and thorium in the United States, and although the grade of both commodities is lower than some other deposits, their large size and relative cheapness of mining make them an important future resource. Vein deposits in the Bear Lodge Mountains include all tabular bodies at least 5 cm thick. Twenty-six veins were noted in this area. These veins are thin and short; the longest vein was traced for only 137 m. Minerals vary greatly in the amount present. Gangue minerals are commonly potassium feldspar, quartz, or cristobalite intermixed with varying amounts of limonite, hematite, and various manganese oxides. Rare earths and thorium occur in the minerals monazite, brockite, and bastnaesite. Thorium content of 35 samples ranged from 0.01 to 1.2 percent, and the total rare-earth content of 21 samples from 0.23 to 9.8 percent. Indicated reserves were calculated to a depth of one-third the exposed length of the vein. Inferred reserves lie in a block surrounding indicated reserves. Indicated reserves of all veins are only 50 t of Th0 2 and 1,360 t of total rare-earth oxides; inferred reserves are 250 t of Th0 2 and 6,810 t of total rare-earth oxides. The Bear Lodge dome, which underlies the greater part of this area, is formed by multiple intrusive bodies of Tertiary age that dome up the surrounding sedimentary rocks. In the southern part of the core, the younger intrusive bodies surround and partly replace a granite of Precambrian age. This granite is approximately 2.6 b.y. old. The sedimentary rocks around the core are (from oldest to youngest): Deadwood Formation of Late Cambrian and Early Ordovician age, Whitewood Limestone of Late Ordovician age, Pahasapa Limestone of Early Mississippian age, Minnelusa Sandstone of Pennsylvanian and Early Permian age, Opeche Formation of Permian age, Minnek
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Thorium in potentially economic amounts occurs in three types of deposits in the Wet Mountains area of Colorado: (1) quartz-baritethorite veins and fracture zones, (2) carbonatite dikes, and (3) red syenite dikes. The quartz-barite-thorite veins and fracture zones contain the largest resources of thorium; they cut all Precambrian and Paleozoic rock types in the area and tend to strike normal to the foliation in the Proterozoic metasedimentary and metavolcanic rocks. The veins and fracture zones are end products of the episode of Cambrian alkaline magmatism that also produced rocks of the McClure Mountain Complex, the Gem Park Complex, the complex at Democrat Creek, and associated dikes of carbonatite, lamprophyre, and red syenite. The veins and fracture zones contain an average of 0.46 percent ThO2, 0.21 percent SLREE (total light rare-earth elements), 0.14 percent SHREE (total heavy rare-earth elements), and 0.012 percent Nb2O5; They contain reserves of 64,200 tons ThO2, 29,300 tons SLREE, 19,540 tons SHREE, 1,675 tons Nb2O5; they contain probable potential resources of 160,500 tons ThO2, 73,270 tons SLREE, 48,850 tons SHREE, and 4,185 tons Nb2O5. The carbonatite dikes form two distinct groups: replacement carbonatites and primary magmatic carbonatites. The latter group appears to be the better source of potentially economic commodities. The primary magmatic carbonatites contain an average of 0.17 percent ThO2, 0.0097 percent Nb2O5, 0.0031 percent U3O5, and 2.15 percent total rare-earth oxides. The seven largest dikes contain reserves of 131 tons ThO2, 40 tons Nb2O5, 17 tons U3O5, and 2,500 tons SRE203 (total rare-earth oxides), and probable potential resources of 753 tons ThO2, 228 tons Nb2O5, 105 tons U3O5, and 14,300 tons SRE2O3. The red syenite dikes contain anomalous amounts of thorium, uranium, niobium, and rare-earth elements. Although reserves and probable potential resources have not been calculated, they are likely to be small.
The vertical permeability to air of layered materials in the unsaturated zone may be determined from air pressure data obtained at depth during a period when air pressure is changing at land surface. Such data may be obtained by monitoring barometric pressure with a microbarograph or surveying altimeter and simultaneously measuring down-hole pneumatic head differences in specially constructed piezometers. These data, coupled with air-filled porosity data from other sources, may be compared with the results of electric-analog or numerical solution of the one-dimensional diffusion equation to make a trial-and-error determination of the air permeability for each layer. The permeabilities to air may in turn be converted to equivalent hydraulic conductivity values if the materials are well drained, are permeable enough that the Klinkenberg effect is small, and are structurally unaffected by wetting. The method offers potential advantages over present methods to evaluate sites for artificial recharge by spreading; to evaluate ground-water pollution hazards from feedlots, sanitary landfills , and land irrigated with sewage effluent; and to evaluate sites for temporary storage of gas in the unsaturated zone. (Woodard-USGS)
The birth of the idea that led to this publication on "Global Sand Seas" dates back to the late 1920's. At that time I was engaged in a study of the Coconino Sandstone of Arizona's Grand Canyon. Considerable controversy existed then as to whether this sandstone was a subaqueous deposit or was composed of wind-formed dunes. It became apparent that definitive literature was sparse or lacking on types of dunes, global distribution of these types, the mechanics of their development, the precise nature of their internal structure of cross-stratificiation, and the relation of wind systems to these sand forms. Especially lacking were data on criteria that could confidently be used in the recognition of ancient dunes. The common denominator in this publication is eolian sand bodies. Although the book is concerned primarily with desert sand seas, the subject matter is not restricted to deserts; it includes many references to deposits of coastal sand and to sand bodies in humid climates. Nor does the book deal exclusively with dunes, which, according to most definitions, involve mounds or hills. Many references are made to sand sheets, sand stringers, and other types of sand deposits that have no prominent topographic expression. All sand bodies accumulated by the action of wind are discussed. Chapters A-J of this publication are primarily topical. Chapters cover the grain texture, the color, and the structure of modern dunes and other eolian sands. Special treatment is given to the relation of wind data to dune interpretation, the evolution of form in current-deposited sand bodies as determined from experimental studies, and the discriminant analysis technique for differentiating between coastal and inland desert sands. This topical part of the publication also includes an analysis of criteria used in ancient deposits to interpret their eolian genesis and a consideration of economic application of the principles described, including a discussion of potentials and problems associated with eolian hydrocarbon reservoirs. The final chapters present a discussion of the morphology and distribution of dunes as determined largely from Landsat images. Chapter K of the publication is devoted to descriptions of major sand seas based largely on thematic maps derived from Landsat (ERTS) mosaics. Although inclusion herein of the actual mosaics proved to be impractical, the maps derived from them do show the distribution and abundance of various dune types and the relations of these types to certain associated features, such as bedrock, water bodies, and juxtaposed dunes. Furthermore, sand roses included with each of these maps enable the user to draw conclusions on the probable relations of wind strength and direction to dune type in a particular area. Regional studies (chapter K) were a team effort. Analysis of the Landsat (ERTS) mosaics and mapping boundaries of individual dune types were by Carol Breed. Synthesis of the rather voluminous literature and preparation of abstracts covering it was by Camilla MacCauley. Actual preparation of maps was by Franci Lennartz and later by Sarah Andrews. The gathering of data on wind, the calculation of wind roses, and the interpretation of their relations to sand bodies were by Steven Fryberger, assisted by Gary Dean.
Mathematical and laboratory models were used to observe, respectively, the hydraulic and chemical reactions that may take place during proposed injection of a highly acidic, iron-rich waste pickle liquor into a deep waste-disposal well in western New York. Field temperature and pressure conditions were simulated in the tests. Hydraulic pressure in the middle stages of the initial (1968) injection test had probably hydraulically fractured the Cambrian sandstone-dolomite formation adjacent to the borehole. Transmissivity of the formation is 13 feet squared per day. The proposed rate of injection (72,000 gallons per day) of waste pickle liquor would approach a wellhead pressure of 600 pounds per square inch in about a year. Hydraulic fracturing would reoccur at about 580 pounds per square inch. The measurable cone of influence would extend about 22 miles after injection for 1 year. Chemical reactions between acidic wastes and brine-saturated dolomite would create precipitates that would drastically reduce the permeability of the unfractured part of the dolomite. Nondolomitic sandstone permeability would not be affected by chemical reactions, but the pores might be plugged by the iron-bearing waste. The digital model can be used for qualitative predictions on a regional scale. (Woodard-USGS)