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Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis

Wavelet Inversion for SliP (WISP): Open-source earthquake slip modeling software

Models of the spatiotemporal evolution of earthquake slip, termed finite-fault models, are a critical component of rapid earthquake and tsunami response, earthquake forecasting, seismic ground-motion estimates, and studies of earthquake kinematics. Here, we detail a newly released finite-fault modeling software, Wavelet Inversion for SliP (WISP), in use at the U.S. Geological Survey’s National Earthquake Information Center (NEIC) and available to the public. WISP version 1.1.0 allows inversion of teleseismic body and surface waves, as well as local strong-motion, static and dynamic Global Navigation Satellite System, and satellite imagery (e.g., Interferometric Synthetic Aperture Radar) observations on single or multiple planar fault segments. The software is used in NEIC rapid response of earthquakes M w ≥ 7, generally resulting in a published model within the first few hours after the event origin time. The rupture location and dimensions are then used as inputs to downstream products to estimate earthquake shaking, predict loss, and model the likelihood of secondary hazards, namely landslides and liquefaction. WISP is also used in research studies to evaluate the characteristics of complex ruptures including multifault ruptures and earthquake doublets, among others. The WISP version 1.1.0 software release is composed of Python-wrapped FORTRAN code to accomplish the inversion procedure. A simple command line interface facilitates ease of use even for those with only a cursory knowledge of Python scripting. WISP version 1.1.0 includes a Jupyter Notebook tutorial demonstrating use of the software for modeling the 2015 M w 8.3 Illapel, Chile, earthquake. In parallel with the tutorial, we demonstrate the typical usage of the WISP software using the M w 8.3 Illapel earthquake example here.

Seismological Research Letters

Utilization of multiple geochronology techniques to constrain the age of laterization and mineralization of the world-class Mount Weld rare earth element deposit, Western Australia

Pervasive chemical weathering on stable cratons may form thick regoliths and elemental enrichment, but constraining the age of regolith formation is challenging. In this study we utilize multiple geochronological techniques on different minerals from the world-class Mount Weld rare earth element (REE) deposit, formed by lateritic weathering of a carbonatite, to constrain the age of formation and provide insight into landscape evolution. The oldest dates, ca. 100 to 38 Ma, are from Lu-Hf dating of churchite [HREE(PO 4 )·2(H 2 O)], a heavy REE phosphate mineral. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane [K(Mn 4+ ,Mn 2+ )₈O₁₆] yielded dates from ca. 40 to 27 Ma. Similarly, (U-Th)/He geochronology of goethite [FeO(OH)] yielded dates ranging from ca. 45 to 19 Ma. Integrating results into regional constraints, suggests 1) churchite formed by mineral saturation in a karst-like setting below the water table from ca. 100 to 40 Ma, 2) with minor uplift and erosion, cryptomelane and goethite formed at or near the water table between ca. 45 and 19 Ma, 3) after ca. 15 to 10 Ma chemical weathering within the profile had ended. Other studies document that the region experienced minimal uplift and a wet, warm climate from ca. 100 Ma to 15 Ma. These conditions and the high carbonate content of the carbonatite promote extensive chemical weathering, a deep weathering profile, and the preservation of the weathered section. This study highlights the use of multiple geochronological techniques utilizing different minerals to provide insight into how laterites form and to constrain the timing and history of the formation of this important mineral deposit.

Western Australia

ECCOE Landsat quarterly Calibration and Validation report—Quarter 1, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 1 (January–March), 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This quarterly report is the third to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This quarterly report is the first to not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 after being lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

ECCOE Landsat quarterly Calibration and Validation report—Quarter 2, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 2 (April–June) of 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This is the fourth quarterly report to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This is the second quarterly report that does not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 when it was lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

An unexplained tsunami: Was there megathrust slip during the 2020 Mw7.6 Sand Point, Alaska, earthquake?

On October 19, 2020, the M w 7.6 Sand Point earthquake struck south of the Shumagin Islands in Alaska. Moment tensors indicate the earthquake was primarily strike-slip, yet the event produced an enigmatic tsunami that was larger and more widespread than expected for an earthquake of that magnitude and mechanism. Using a suite of hydrodynamic, seismic, and geodetic modeling techniques, we explore plausible causes of the tsunami. We find that strike-slip models consistent with the moment tensor orientation cannot produce the observed tsunami. Hydrodynamic inversion of sea surface deformation from deep ocean and tide gauge data suggest seafloor deformation more closely matches a megathrust, rather than a strike-slip, source. Static slip inversions, using sea level and Global Navigation Satellite System data, allow for a portion of co-seismic megathrust slip that can explain tsunamigenesis. Combining all available geophysical datasets to model the kinematic rupture, we show that considerable, relatively slow, megathrust slip is allowable in the Shumagin segment, concurrent with strike-slip faulting. We hypothesize that the slow megathrust rupture does not contribute much seismic radiation allowing it to previously go unnoticed with traditional seismic monitoring.

Alaska

Summary of selenium in the lower Gunnison River Basin, Colorado—Information and data gaps

The Cretaceous Mancos Shale is a geologic source of selenium in the lower Gunnison River Basin. Natural weathering processes and human activity mobilize selenium from the Mancos Shale and derived materials, and surface water, groundwater, and sediment all affect the transport of selenium from source areas to receiving streams and biota. Selenium accumulates through the aquatic food chain, and its toxic effects can result in invertebrate mortality and mortality, decreased reproduction, and deformities to fish and birds. The Bureau of Reclamation, in cooperation with the State of Colorado and Gunnison River Basin water users, is implementing a Selenium Management Program to reduce selenium concentrations in the lower Gunnison River Basin of Colorado. Goals of the Selenium Management Program are to (1) achieve compliance with the State of Colorado chronic aquatic-life standard for dissolved selenium (4.6 micrograms per liter) in the Gunnison River near Grand Junction, Colorado; (2) sufficiently improve water-quality conditions to assist in the recovery of endangered species in the Gunnison and Colorado Rivers by reducing selenium concentrations; and (3) support continued water uses in the basin. Many previous studies have contributed to the understanding of selenium in the environment; however, monitoring and research data gaps exist in the lower Gunnison River Basin. The purpose of this report is to summarize information regarding selenium in the lower Gunnison River Basin and describe strategies for scientific research and monitoring to potentially improve understanding of selenium sources; processes affecting the mobilization, transport, and fate of selenium; and the effects of selenium-mitigation projects in the lower Gunnison River Basin. Monitoring and research data gaps discussed in this report include geologic mapping and geochemical source characterization, long-term and ongoing monitoring of the surface-water and groundwater networks, developing and refining statistical models, characterizing selenium on suspended sediment, modeling selenium in the food web, evaluating best management practices, and more.

Colorado

Profiles of gamma-ray and magnetic data for aerial surveys over parts of the Western United States from longitude 108 to 126 degrees W. and from latitude 34 to 49 degrees N.

This CD-ROM contains images generated from geophysical data, software for displaying and analyzing the images and software for displaying and examining profile data from aerial surveys flown as part of the National Uranium Resource Evaluation (NURE) Program of the U.S. Department of Energy. The images included are of gamma-ray data (uranium, thorium, and potassium channels), Bouguer gravity data, isostatic residual gravity data, aeromagnetic anomalies, topography, and topography with bathymetry. This publication contains image data for the conterminous United States and profile data for the conterminous United States within the area longitude 108 to 126 degrees W. and latitude 34 to 49 degrees N. The profile data include apparent surface concentrations of potassium, uranium, and thorium, the residual magnetic field, and the height above the ground. The images on this CD-ROM include graytone and color images of each data set, color shaded-relief images of the potential-field and topographic data, and color composite images of the gamma-ray data. The image display and analysis software can register images with geographic and geologic overlays. The profile display software permits the user to view the profiles as well as obtain data listings and export ASCII versions of data for selected flight lines.

Data Series

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Probing lower-crustal fault properties with frequency-dependent tidal tremor triggering

The way seismicity responds to periodic stress perturbations offers crucial insights into the processes that can trigger an earthquake. Laboratory and theoretical analyses have shown that the period of imposed forcing and source properties affect the sensitivity to triggering, but frequency-dependent triggering of tectonic faults is poorly understood. The rate of low-frequency earthquakes (LFEs) near Parkfield, California has been found to be strongly correlated with solid earth tides. Tidal forcing acts over multiple frequencies, and the sensitivity to tidal triggering of LFEs therefore provides a unique opportunity to probe the physics of earthquake triggering and underlying fault properties. Here, we find that the response of LFEs to solid earth tides at diurnal and semi-diurnal frequencies is highly variable but spatially coherent along the San Andreas Fault. Using rate-state friction modeling, we find that the variation of the amplitude of tidal modulation is mainly affected by the spatial variation of the background effective normal stress, whereas the spatially varied tidal modulation at diurnal and semi-diurnal frequencies is mainly affected by the fault frictional property. The spatial variations of the LFE response reveal a heterogeneous lower-crustal geologic structure and complex physical faulting processes below the rupture zone of eventual great earthquakes.

California

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Invasion of perennial sagebrush steppe by shallow-rooted exotic cheatgrass reduces stable forms of soil carbon in a warmer but not cooler ecoregion

Soil organic carbon ('SOC') in drylands comprises nearly a third of the global SOC pool and has relatively rapid turnover and thus is a key driver of variability in the global carbon cycle. SOC is also a sensitive indicator of longer-term directional change and disturbance-responses of ecosystem C storage. Biome-scale disruption of the dryland carbon cycle by exotic annual grass invasions (mainly Bromus tectorum, 'Cheatgrass') threatens carbon storage and corresponding benefits to soil hydrology and nutrient retention. Past studies on cheatgrass impacts mainly focused on total C, and of the few that evaluated SOC, none compared the very different fractions of SOC, such as relatively unstable particulate organic carbon (POC) or relatively stable, mineral-associated organic carbon (MAOC). We measured SOC and its POC and MAOC constituents in the surface soils of sites that had sagebrush canopies but differed in whether their understories had been invaded by cheatgrass or not, in both warm and relatively colder ecoregions of the western USA. MAOC stocks were 36.1% less in the 0–10 cm depth and 46.1% less in the 10–20 cm depth in the cheatgrass-invaded stands compared to the uninvaded stands of the warmer Colorado Plateau, but not in the cooler and more carbon-rich Wyoming Basin ecoregion. In plots where cheatgrass increased SOC, it was via unstable POC. These findings indicate that cheatgrass effects on the distribution of soil carbon among POC and MAOC fractions may vary among ecoregions, and that cheatgrass can reduce forms of carbon that are otherwise considered stable and 'secure', i.e. sequestered.

Environmental Research Communications

A roadmap for identifying and interpreting physical processes and national water model prediction bias associated with baseflow index regimes across the contiguous United States

Understanding how groundwater–surface water interactions shape streamflow variability is critical for diagnosing low flow behavior and prediction bias in continental scale hydrologic models. We present a process informed framework that links observed baseflow (BF) dynamics, watershed attributes, and National Water Model (NWM) performance across the contiguous United States. Using daily observed streamflow from 797 reference quality streamgages, we developed monthly baseflow index (BFI) signatures using a streamgage specific, calibrated digital filter. Hierarchical clustering of these signatures identified seven distinct BFI regimes capturing regional and seasonal variability. We evaluated NWM v3.0 retrospective streamflow performance within each regime using multiple hydrograph and flow duration curve-based metrics. Model skill varied systematically across regimes: mixed flow systems were simulated most accurately, while predominantly BF dominated and quickflow dominated regimes exhibited substantially poorer performance. Across nearly all regimes, the NWM underestimated observed BFI magnitude and frequently failed to reproduce seasonal BF patterns, indicating systematic biases in simulated low flow contributions. To relate these regimes to potential process controls, we trained a Random Forest classifier using static watershed attributes and applied Shapley Additive Explanations to identify features most strongly associated with each regime. Results highlight regionally varying influences, including the dominant role of snow fraction and seasonal runoff timing in snow dominated basins and the importance of evapotranspiration and aridity in quickflow dominated systems. Collectively, these findings demonstrate how hydrologic signatures combined with interpretable machine learning can diagnose regime specific model biases and generate process-based hypotheses about limitations in large scale hydrologic prediction systems.

contiguous United States

Predicting hydrothermal reservoir depth from chemical geothermometers using a three-dimensional temperature model in the Great Basin, USA

Recent work in the Great Basin region of the western United States has made it possible to predict the depth of hydrothermal reservoirs (i.e., the depth at which heat is accumulated prior to ascent via hydrothermal upflow) identified through geochemistry and to contextualize the spatial patterns of these reservoir depths. Chemical geothermometers use the chemical and mineral constituents of hydrothermal fluids to predict the temperature at which fluids equilibrated with the host rocks at depth. Assuming that most of the Great Basin is dominated by conductive conditions until a vertically connected hydrothermal flow path is created (e.g., by faulting), geothermometers reflect the chemical and thermal conditions at the depth interval that the fluid has conductively equilibrated over a long period before a vertical conduit allows convective upflow. By pairing geothermometer temperature estimates with our recent three-dimensional temperature model of conductive heat flow in the Great Basin, we estimate the corresponding reservoir depths and construct a map of circulation depths. The predicted depths from geothermometers have spatial patterns across the Great Basin that relate to patterns seen in other geologic and geophysical data. Deeper springs generally occur disproportionately in areas with higher strain rates and in basins. We posit that current elevated strain rates reflect patterns of historic deformation where ongoing tectonic activity maintains permeable pathways to deeper reservoirs, some of which are estimated to exceed 6 km depth. Basins, as expected, contain a disproportionate number of these deep systems, because the underlying aquifers are closer to the surface in basins, thus requiring less water pressure to reach the surface than in mountain ranges. Most springs estimated to have their source in a deep reservoir occur at places known to host a hydrothermal system; these refined depth estimates of the source reservoir can help to better constrain the source depth for many known hydrothermal systems across the Great Basin.

Arizona, California, Idaho, Nevada, Oregon, Utah

Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming

Latest Pleistocene to 19th-century earthquakes on bending-moment reverse faults of the Seattle fault zone, Washington

Fault-related folds and their associated secondary faults play a critical yet often underrecognized role in accommodating strain and generating earthquakes in active fold-and-thrust belts. In the Seattle fault zone (SFZ), Washington, USA, we present new paleoseismic, geomorphic, and geophysical evidence for late Pleistocene and Holocene earthquakes on shallow, south-dipping secondary faults—the Lytle Beach and Vasa Park faults—that lie within the hanging wall of the greater SFZ and are on trend with the primary, blind Blakely Harbor fault. Our data show that these structures have ruptured independently, producing localized uplift and deformation at the surface, with the most recent event (RH2) likely occurring in the early nineteenth century. While a temporal overlap between the late Pleistocene RH1 and VP1 earthquakes raises the possibility of a ≥35 km rupture along the Blakely Harbor fault, structural and temporal evidence instead supports independent rupture on individual faults related to folding. We interpret these faults as bending-moment reverse faults that formed within a synclinal hinge zone of the main fault, reflecting mechanical and kinematic influences of the broader fault system. Combined with prior studies, our findings indicate that faulting related to folding dominates the mode of strain release within the SFZ since the late Pleistocene with more frequent earthquake recurrence (∼350 yr) over the past ∼2500 yr.

Washington

The 3D Elevation Program—Supporting New Hampshire’s economy

Introduction The topography of New Hampshire ranges from the Coastal Lowlands to the Eastern New England Upland to the White Mountains region. High-quality statewide elevation data are useful in managing this very diverse landscape. For example, the short coastline, including the Great Bay estuary and the Hampton-Seabrook marshes, is of disproportionately high value to New Hampshire’s tourist economy. The vulnerability of the coast to the effects of sea-level rise underscores the need for accurate, high-quality nearshore topographic elevation data and offshore bathymetric data to effectively manage the coast’s valuable resources, which include important fisheries, habitat, and infrastructure. Another important use for accurate elevation data in New Hampshire is in the evaluation of flood hazards and their potential environmental and infrastructure effects. This evaluation includes mapping of inundation and sediment transport, and assessing the associated costs of flooding. Addressing this challenge requires detailed knowledge of both surface topography and inland bathymetry. Other important activities having a substantial economic element and needing accurate elevation data include geologic resource assessment and hazard mitigation, urban and regional planning, infrastructure and construction management, and cultural resources preservation and management. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional model of the Earth’s surface and aboveground features.

New Hampshire