USGS ScienceSearch

SEARCH · USGS Science

Results for “Environmental Research Letters”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

504 records · Page 20Linked to original sources

Do bighorn sheep use desert tortoise burrow spoil piles as mineral licks in southern California?

In a previous study, bighorn sheep ( Ovis canadensis ) were periodically photographed by trail cameras when they visited desert tortoise ( Gopherus agassizii ) burrows in the San Bernardino Mountains near Palm Springs, California, USA. The authors suggested that bighorn sheep may utilize the excavated spoil material from burrows as a mineral lick. To test that supposition, we collected soil samples from the spoil piles and undisturbed surface soil up to 1 m away at two desert tortoise study sites with bighorn sheep at the aforementioned site and another nearby site. We hypothesized that sodium concentrations would be greater in spoil than in nearby surface soil samples. Common major cations were quantified in soil samples using inductively coupled plasma-mass spectrometry following microwave-assisted digestion to solubilize the fraction of elements that could become biologically or environmentally available. Mean sodium concentrations were greater in burrow spoil samples than in undisturbed soil samples at both sites, likely due to aqueous leaching of sodium from surface to subsurface soil horizons. Although we did not collect evidence of geophagy by bighorn sheep, the behavior is well known. However, trail camera photographs of bighorn sheep with their head next to the entrance of tortoise burrows suggests that they may periodically utilize sodium and other elements brought to the surface by desert tortoises that are otherwise unavailable to bighorn sheep on the surface.

California

Developing, testing, and communicating earthquake forecasts: Current practices and future directions

While deterministically predicting the time and location of earthquakes remains impossible, earthquake forecasting models can provide estimates of the probabilities of earthquakes occurring within some region over time. To enable informed decision-making of civil protection, governmental agencies, or the public, Operational Earthquake Forecasting (OEF) systems aim to provide authoritative earthquake forecasts based on current earthquake activity in near-real time. Establishing OEF systems involves several nontrivial choices. This review captures the current state of OEF worldwide and analyzes expert recommendations on the development, testing, and communication of earthquake forecasts. An introductory summary of OEF-related research is followed by a description of OEF systems in Italy, New Zealand, and the United States. Combined, these two parts provide an informative and transparent snapshot of today's OEF landscape. In Section 4, we analyze the results of an expert elicitation that was conducted to seek guidance for the establishment of OEF systems. The elicitation identifies consensus and dissent on OEF issues among a non-representative group of 20 international earthquake forecasting experts. While the experts agree that communication products should be developed in collaboration with the forecast user groups, they disagree on whether forecasting models and testing methods should be user-dependent. No recommendations of strict model requirements could be elicited, but benchmark comparisons, prospective testing, reproducibility, and transparency are encouraged. Section 5 gives an outlook on the future of OEF. Besides covering recent research on earthquake forecasting model development and testing, upcoming OEF initiatives are described in the context of the expert elicitation findings.

Reviews of Geophysics

Monitoring changes in Landsat thermal features in urban and non-urban interfaces from 1986 to 2023 in two international urban centers: Implications for climate and global issues

Rapid urbanization is reshaping thermal environments worldwide, with the strongest impacts occurring at the interface between urban and non-urban areas. Impervious surfaces, as key indicators of urban expansion, are critical for monitoring urban growth and assessing surface urban heat island (SUHI) effects. Land use and land cover change (LULCC) provides an essential link between urban dynamics and their environmental and societal consequences. Here, we integrated the U.S. Geological Survey (USGS) Climate Global Issues (CGI) Land Cover Product with Landsat thermal time-series to investigate SUHI evolution in two contrasting metropolitan regions: Wuhan, China, and Brasília, Brazil. Using data spanning 1986–2023, we analyzed the relationships between land cover, Landsat-based land surface temperature (LST), and SUHI intensity, and identified persistent thermal hotspots. Results demonstrate that the land cover data utilized increases the accuracy of impervious surface mapping along urban–rural gradients. Average SUHI intensities were 3.4 °C in Wuhan and 3.3 °C in Brasília, with statistically significant warming trends of 0.04 °C/year and 0.01 °C/year, respectively. Maximum temperature proved to be a robust indicator of SUHI intensification, capturing long-term upward trends. Our findings highlight the important role of urban land cover dynamics in shaping temporal SUHI variability and hotspot emergence. This prototype framework demonstrates the scientific and policy value of combining long-term land cover monitoring information with satellite thermal monitoring to quantify and track SUHI at city scale, supporting sustainable urban planning and climate adaptation strategies.

Remote Sensing

Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Dendroseismological investigation of redwood trees along the North Coast section of the San Andreas Fault

Sequoia sempervirens (coast redwood) tree rings have the potential to annually resolve late-Holocene earthquakes on the northern San Andreas Fault based on direct (e.g., physical damage) and indirect (e.g., co-seismic environmental change) impacts, but scarcity of suitable samples and challenges crossdating this long-lived species have limited progress. More precise dating of the pre-1906 (penultimate) earthquake can improve hazard assessment and understanding of rupture segmentation. We target old trees (maximum >815 yr) along the North Coast section of the fault (increment cores via rope-climbing, 11 living trees; plunge cuts, 23 stumps) and employ complementary disturbance detection methods including radial-growth averaging (tree- and series-level), cataloging anatomical indicators (e.g., traumatic resin ducts, TRD), and dating structural components (e.g., reiterated trunks, leans). Multi-centennial ring-width chronologies at Fort Ross (1569−2023) and Gualala (1397−2023) promote continued study with incomplete crossdating limiting utilization of some series. Growth pulses (reductions, releases) and TRD dispersed across the record reflect dynamic environments that obfuscate detection of earthquake signals. The 1906 earthquake did not leave strong signatures on most trees, and when it did, within-tree response varied from normal presentation to discoloration, TRD, and missing rings. Synchrony of indicators at both locations identified 1678−1680 (6 of 15 trees) and 1698−1700 (8 of 16 trees) as the strongest disturbances among dated rings in the time range of the penultimate earthquake, peaking at 1698 (15.7 % of possible growth and anatomical indicators), but the triggering mechanisms for these events are unknown.

California

Recent scientific contributions by the U.S. Geological Survey in the San Francisco Bay and Sacramento–San Joaquin Delta Estuary

Introduction The San Francisco Bay and Sacramento–San Joaquin Delta Estuary (hereafter, Bay-Delta) is the largest estuary on the West Coast of the United States. The Bay-Delta covers more than 1,600 square miles and drains a watershed of more than 75,000 square miles, which is greater than 40 percent of California. The region surrounding the Bay-Delta is home to about 10 million people, and its habitats (fig. 1) support more than 800 plant and animal species. The waterways of the Bay-Delta are the central hub of California’s extensive freshwater delivery system, supplying water to more than 27 million Californians and 4 million acres of farmland in the Central Valley. The U.S. Geological Survey (USGS) is the primary science agency of the U.S. Department of the Interior, providing a broad range of Earth, water, biological, and mapping data and expertise to inform natural resource management across the country. This fact sheet focuses on research conducted by the USGS in the Bay-Delta region, mostly within the past 5 years. The fact sheet is organized across five major themes: water flow and water quality, fish and wildlife, wetland restoration, invasive species, and hazards. In each of these areas, the USGS works closely with Federal, State, and local agencies; academia; and non-governmental organizations to provide objective, evidence-based science. The data and knowledge gained from USGS research and monitoring are publicly available and are routinely used by agencies, including the U.S. Bureau of Reclamation, U.S. Army Corps of Engineers, U.S. Fish and Wildlife Service, California Department of Water Resources, California Department of Fish and Wildlife, California State Water Resources Control Board, Delta Stewardship Council, and many additional organizations and stakeholders to inform management of the Bay-Delta region and its resources.

California

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund Site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

EarthArXiv

Analysis of nutrients in the surface waters of the Georgia–Florida Coastal Plain study unit, 1970–91

During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface-water sites between October 1, 1970, and September 30, 1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used: (1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were enerally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the Aucilla River basin had the lowest. Median concentrations of nitrate and ammonia among all major basins were below USEPA guidelines. The median total-phosphorus concentrations for the following river basins exceeded the USEPA guideline: Hillsborough, St. Johns, Suwannee, Ochlockonee, Satilla, Altamaha, and Ogeechee. Although nutrient concentrations within the study unit were low, long-term increasing trends were found in all four nutrients. All 18 study-unit wide nitrate trends had increasing slopes ranging from less than 0.01 to 0.07 (mg/L)/yr. The range in slope for the 13 ammonia trends was -0.03 to 0.01 (mg/L)/yr with 6 increasing trends in the northern part of the study unit. Of the 17 total-phosphorus trends found in the study unit, 10 were found at sites where the median concentration exceeded the USEPA guideline. At these 10 sites, 4 sites had increasing trends with slopes ranging from less than 0.01 to 0.07 (mg/L)/yr, 5 sites had decreasing trends with slopes ranging from -0.01 to -0.24 (mg/L)/yr, and one site showed a seasonal concentration trend. Median nutrient concentrations were significantly different among the four land resource provinces: Southern Piedmont, Southern Coastal Plain, Coastal Flatwoods, and Central Florida Ridge. As a result, nutrient concentrations among basins with similar nutrient inputs but located within different land resource provinces are not expected to be the same due to differences in the combination of factors such as soil permeability, runoff rates, and stream channel slopes. This concept is an important consideration in designing a surface-water quality network within the study area. For the most part, the Coastal Flatwoods showed the lowest median nutrient concentrations and the Southern Coastal Plain had the highest median nutrient concentrations. Lower median nitrate concentrations in surface-water basins were associated with the forest/wetland land-use category and higher median concentrations of nitrate and ammonia with the urban category when land-use percentages were classified into four land-use categories (agriculture, forest/wetland, mixed, and urban). These results were reasonable based on expected high nutrient inputs from urban areas and low inputs from forested and wetland areas. However, the lack of association between high nutrient concentrations and the agricultural land-use category was not expected since high nutrient inputs are generally needed for agriculture production.

Florida, Georgia

Stream habitat characteristics at selected sites in the Georgia-Florida coastal plain

Habitat characterization is part of a multidisciplinary approach to water-quality assessment implemented by the National Water-Quality Assessment Program. Habitat data were collected in the Georgia-Florida Coastal Plain study unit at 24 sites during 1993-95. Data were collected for habitat characteristics at three spatial scales: basin, segment, and reach. Basin data include physiography, land resource provinces, and land use, providing a description of the environmental setting at each site. Segment data include length, gradient, and sinuosity. A Kendall correlation analysis performed on segment characteristics and the log-of-basin area showed a correlation between segment gradient and the log-of-basin area and a correlation between sinuosity and segment length. Reach data consist of field-collected measurements of both instream and riparian habitats. Sand and detritus were the most common channel-bed substrates among the sampled sites. Measurements of channel width, water depth, and bank width and height were used to create cross-sectional profiles of each sampled area. Elevations of selected durations plotted on cross sections illustrated the percentage of time that the banks were inundated at each site. Sites were divided into two groups based on duration of bank inundation (less than or equal to 1 percent and greater than 1 percent). Bank woody vegetation was also sampled and a clustering algorithm known as Two-Way INdicator SPecies ANalysis (TWINSPAN) was used to analyze these data. TWINSPAN divided the sites into two groups based on their vegetation composition. A statistical comparison of the two types of site groups (duration of bank inundation and vegetation) was performed. The significant association between these groups was consistent with the hypothesis that inundation frequency affected riparian vegetation.

Florida, Georgia

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island

Exploring the science and data foundation for Federal public lands decisions

Public lands provide diverse resources, values, and services worldwide. Laws and policies typically require consideration of science in public lands decisions, and resource managers are committed to science-informed decision-making. However, it can be challenging for managers to use, and document the use of, science and data in their decisions. To better understand science and data use in Federal public lands decisions in the United States, we assessed the number, type, and age of documents cited in 70 Environmental Assessments (EAs) completed by the Bureau of Land Management (BLM) in Colorado from 2015–2019. We focused on the BLM, as they manage the largest area of public lands in the United States. We selected Colorado as our study area, as actions proposed on BLM lands in Colorado are representative of those across the nation. Fifty percent of citations were categorized as science and 23% as data. EAs contained an average of 17 citations (range 0–111), with documents analyzing effects of oil and gas development and recreation actions including the highest and lowest mean number of citations (41 and 6, respectively). Of individual resource analysis sections within EAs, 24% contained ≥1 science citation and 21% contained ≥1 data citation. Journal articles were the most cited type of document (26% of citations) followed by non-BLM inventories (13%). Forty-seven percent of citations were relatively recent (2010 or later); the oldest citation was from 1927. Commonly analyzed resources with the highest mean number of citations were socioeconomics, mineral resources, and noise. Fourteen of 33 commonly analyzed resources included <1 citation on average. Actions and resources with no or few citations represent opportunities for strengthening the transparent use of science and data in public lands decision-making.

Colorado

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S. Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

New Hampshire

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

The 3D Elevation Program—Supporting Rhode Island’s economy

Introduction High-resolution elevation data are critical to applications of landscape modeling and planning, both of which have a significant effect on Rhode Island’s economy. In these and other enterprises, program managers, while aiming to strike a balance between accuracy and cost, strive to obtain the best available elevation data to help them address a range of issues. Programs focused on climate change, environmental management, transportation design and asset management, aviation navigation and safety, riverine ecosystem management, wildlife habitat characterization and management, shellfish aquaculture, and the management and mapping of forests, parks and recreation areas, soils, wetlands, and impervious surfaces are also among the critical applications that meet the State’s management needs and depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Rhode Island. The status of available and in-progress 3DEP baseline lidar data in Rhode Island is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $178,560 in new benefits annually to the State. The top 10 Rhode Island business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Rhode Island

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts

Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama