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At least 37 records · Page 2Linked to original sources
USGS1997

The forms of trace metals in an Illinois basin coal by x-ray absorption fine structure spectroscopy

Utilities burning Illinois coals currently do not consider trace elements in their flue gas emissions. After the US EPA completes an investigation on trace elements, however, this may change and flue gas emission standards may be established. The mode of occurrence of a trace element may determine its cleanability and Hue gas emission potential. X-ray Absorption Fine Structure (XAFS) is a spectroscopic technique that can differentiate the mode of occurrence of an element, even at the low concentrations that trace elements are found in coal. This is principally accomplished by comparing the XAFS spectra of a coal to a database of reference sample spectra. This study evaluated the technique as a potential tool to examine six trace elements in an Illinois #6 coal. For the elements As and Zn, the present database provides a definitive interpretation on their mode of occurrence. For the elements Ti, V, Cr, and Mn the database of XAFS spectra of trace elements in coal was still too limited to allow a definitive interpretation. The data obtained on these elements, however, was sufficient to rule out several of the mineralogical possibilities that have been suggested previously. The results indicate that XAFS is a promising technique for the study of trace elements in coal.

ACS Division of Fuel Chemistry, Preprints↗
USGS2025

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts↗
USGS1955

Geologic investigations of radioactive deposits, semiannual progress report for June 1 to November 30, 1955

This report is a statement of progress during the six-months period from June 1 to November 30, 1955 on investigations of radioactive materials in the United States and Alaska, undertaken by the U.S. Geological Survey under the sponsorship of the U.S. Atomic Energy Commission. During the period the Geological Survey's program has been directed to an increasing extent toward the understanding of geologic conditions favorable for the concentration of uranium, rather than the search for minable deposits as such. This shift in emphasis is reflected in the decreased amount of exploration drilling during the period, and the accompanying increase in geologic programs of a long-range nature. The program is now directed toward a comprehensive understanding of the many factors involved in uranium geology, and the publication of reports that will make available information on all phases of the uranium program. Many investigations have progressed to the point where final reports are in preparation for future publication with the permission of the Atomic Energy Commission; for other investigations of a continuing nature it will be several years before final reports can be prepared. Formal publications (as distinguished from administrative Trace Elements Reports) published during the period include 10 Geological Survey Bulletins or Bulletin Chapters; 116 Geological Survey maps; 15 reports published in scientific journals; seven Trace Elements Reports sent to the Technical Information Service of the Atomic Energy Commission for distribution and sale to the public; and four Trace Elements reports placed on open file. In addition, a large number •of papers by geologists in the program were presented before scientific societies, and the 61 papers prepared for the United Nations International Conference .on the Peaceful Uses of Atomic Energy during the preceding report period were published by the United Nations.

Trace Elements Investigations↗
USGS1950

Tin, copper, and uranium at Majuba Hill, Nevada

Uranium minerals occur with ores of copper, tin, and silver at Majuba Hill, Nevada. During World War I, the Majuba Hill mine produced about 4,000 tons of 12 percent copper ore, and during World War II about 23,000 tons of ore containing 2 to 4 percent copper and enough tin ore to furnish from 10 to 15 tons of metallic tin. No uranium has been produced. The bedrock geology of Majuba Hill consists of a complex; volcanic neck or plug composed of rhyolite porphyry, porphyritic rhyolite, quartz feldspar porphyry, breccia dikes, and irregular breccia masses. This plug intruded Triassic (?) sedimentary rocks, chiefly shale. The principal loci of ore deposition were (l) parts of the breccia bodies, particularly where they were porous and where they were silicified and tourmalinized, and (2) a few small pre-mineral fractures adjacent to the breccia masses, Intense hydrothermal alteration resulted in the formation of sericite, quartz, and tourmaline in the wall rocks. This was accompanied or followed by deposition of arsenopyrite, pyrite, cassiterite, fluorite, and several primary sulfide minerals of copper. All of the ore bodies exposed in the mine are highly oxidized, and a profusion of secondary minerals of copper and iron have been found. The only uranium minerals detected are the phosphates torbernite and matatorbernite and the arsenate zeunerite. These are widely disseminated throughout the mine in small amounts associated with the secondary minerals of copper and iron along minor fault surfaces, bedding planes in the shale, and in porous parts of the breccia. A primary uranium mineral has not been found. The secondary uranium minerals appear to be most abundant where copper ore is highest grade. Although unoxidized uranium ore has not been found, it is inferred from this relation that the deposition of the original uranium minerals favored those areas where primary copper mineralization was most intense. There may have been an intimate association of uranium with silver in the ore, but this has not been established. The U 3 O 8 content of samples of copper ore ranges from .0.002 to 0.30 percent. Because the bottom of the oxidized ore has not been reached in mining or exploration, the downward extensions of the known ore bodies of secondary minerals would appear to be worthy of investigation to determine the grade and extent of the primary ore.

Nevada↗