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USGS2016

The distribution and composition of REE-bearing minerals in placers of the Atlantic and Gulf coastal plains, USA

Rare earth element (REE) resources are currently of great interest because of their importance as raw materials for high-technology manufacturing. The REE-phosphates monazite (light REE enriched) and xenotime (heavy REE enriched) resist weathering and can accumulate in placer deposits as part of the heavy mineral assemblage. The Atlantic and Gulf coastal plains of the southeastern United States are known to host heavy mineral deposits with economic concentrations of zircon, ilmenite and rutile. This study provides a perspective on the distribution and composition of REE phosphate minerals in the region. The elemental chemistry and mineralogy of sands and associated heavy-mineral assemblages from new and archived sediment samples across the coastal plains are examined, along with phase-specific compositions of monazite, xenotime and zircon. Both monazite and xenotime are present across the coastal plains. The phase-specific compositions allow monazite content to be estimated using La as a geochemical proxy. Similarly, both Y and Yb are geochemical proxies for xenotime, but their additional presence in zircon and monazite require a correction to prevent overestimation of xenotime content. Applying this correction, maps of monazite and xenotime content across the coastal plains were generated using sample coverage from the National Geochemical Database (NGS) and National Uranium Resource Evaluation (NURE). The NGS and NURE approach of sampling stream sediments in small watersheds links samples to nearby lithologies. The results show an approximately 40 km-wide band of primarily Cretaceous, marine sediments bordering the Piedmont province from North Carolina to Alabama in which monazite and xenotime content are relatively high (up to 4.4 wt. % in < 150 μm bulk sediment). Strong correlations between concentrations of the two phases were found, with estimated monazite:xenotime ratios ranging approximately 6:1 to 12:1 depending upon the dataset analyzed. From a resource perspective, xenotime correlation with monazite indicates a heavy REE potential in coastal plain placers, and exploration may be warranted within the identified coastal plain band along the boundary of the Piedmont region.

Journal of Geochemical Exploration↗

USGS1998

Electrogeochemical sampling with NEOCHIM - results of tests over buried gold deposits

Electrogeochemical extraction methods are based on the migration of ions in an electric field. Ions present in soil moisture are transported by an applied current into fluids contained in special electrodes placed on the soil. The fluids are then collected and analyzed. Extractions are governed by Faraday's and Ohm's laws and are modeled by the operation of a simple Hittord transference apparatus. Calculations show that the volume of soil sampled in an ideal electrogeochemical extraction can be orders of magnitude greater than the volumes used in more popular geochemical extraction methods, although this has not been verified experimentally. CHIM is a method of in-situ electrogeochemical extraction that was developed in the former Soviet Union and has been tested and applied internationally to exploration for buried mineral deposits. Tests carried out at the US Geological Survey (USGS) indicated that there were problems inherent in the use of CHIM technology. The cause of the problems was determined to be the diffusion of acid from the conventional electrode into the soil. The NEOCHIM electrode incorporates two compartments and a salt bridge in a design that inhibits diffusion of acid and enables the collection of anions or cations. Tests over a gold-enriched vein in Colorado and over buried, Carlin-type, disseminated gold deposits in northern Nevada show that there are similarities and differences between NEOCHIM results and those by partial extractions of soils which include simple extractions with water, dilute acids and solutions of salts used as collector fluids in the electrodes. Results of both differ from the results obtained by total chemical digestion. The results indicate that NEOCHIM responds to mineralized faults associated with disseminated gold deposits whereas partial and total chemical extraction methods do not. This suggests that faults are favored channels for the upward migration of metals and that NEOCHIM may be more effective in exploration for the deposits. It defines anomalies that are often narrow and intense, an observation previously made by CHIM researchers. The field tests show that NEOCHIM is less affected by surface contamination. A test over the Mike disseminated gold deposit indicates that the method may not be effective for locating deposits with impermeable cover. Faradaic extraction efficiencies of 20-30%, or more, are frequently achieved with NEOCHIM and the method generally shows good reproducibility, especially in extraction of major cations. However, ions of other metals that are useful in exploration, including Au and As, may be collected in low and temporally variable concentrations. The reason for this variability is unclear and requires further investigation.CHIM is a method of in-situ electrogeochemical extraction developed for the exploration of buried mineral deposits. However, electrode problems like diffusion of acid into the soil were encountered during the use of CHIM. The NEOCHIM electrode was developed to inhibit the diffusion of acid and enable collection of anions or cations. Tests over buried gold deposits showed that NEOCHIM responds to mineralized faults associated with disseminated gold deposits whereas partial and total chemical extraction methods do not. This suggests that faults are favored channels for the upward migration of metals and NEOCHIM may be effective in exploration for the deposits. But ions of metals may be collected in low and variable concentration.

Journal of Geochemical Exploration↗

USGS2009

Comparison of humus and till as prospecting material in areas of thick overburden and multiple ice-flow events: An example from northeastern New Brunswick

Thirty-nine elements in humus and till matrix were compared at 109 sites overlying Ag-As-Cu-Mo-Pb-Zn mineralized occurrences in northeastern New Brunswick to assess humus for anomaly identification. Humus element concentrations were not consistently correlative with maximum or minimum concentrations found in the underlying till or bedrock. The humus demonstrated significantly higher mean elemental concentrations than the till for six specific elements: 9 times greater for Mn, 6 times greater for Cd, 5 times greater for Ag and Pb, 3 times greater for Hg, and double the concentration of Zn. Spatial dispersal patterns for these elements were much larger for humus content than that exhibited by the till matrix analysis, but did not delineate a point source. For elements in till, the highest concentrations were commonly found directly overlying the underlying mineralized bedrock source or within one km down-glacier of the source. The complexity of the humus geochemical patterns is attributed to the effects of post-glacial biogenic, down-slope hydrodynamic and solifluction modification of dispersed mineralization in the underlying till, and the greater capacity of humus to adsorb cations and form complexes with some elements, relative to the till matrix. Humus sampling in areas of glaciated terrain is considered to be mostly valuable for reconnaissance exploration as elements can be spatially dispersed over a much larger area than that found in the till or underlying bedrock. ?? 2009 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

USGS1993

Reconnaissance guidelines for gold exploration in Central Alaska

Distribution of more than 300 gold-bearing samples from the Livengood (Tolovana) and parts of the Fairbanks and Rampart mining districts in central Alaska, USA, indicate that the concentration of gold in placers is spatially related both to structural features and to Late Cretaceous and (or) Tertiary felsic plutons. The regional consistency of these spatial relationships is demonstrated by proximity analysis using a Geographic Information System (GIS), and suggests a genetic association between faults, felsic plutons, and gold occurrences. The local presence of gold within several of the plutons indicates that these are the source of some of the gold. In addition, some gold occurs proximal to faults where plutons are not present, suggesting that some of the gold was also derived from the country rock. We envision a model whereby weakly mineralized solutions, thermally driven by latent plutonic heat, were enriched by circulation through clastic units that may have had a naturally elevated gold background. The resultant enriched solutions were channeled and reconcentrated along or adjacent to large-scale fault systems. Future exploration to define individual target areas should be directed toward areas where Late Cretaceous and (or) Tertiary felsic plutons occur near major faults. ?? 1993.

Journal of Geochemical Exploration↗

USGS1992

Decomposition techniques

Sample decomposition is a fundamental and integral step in the procedure of geochemical analysis. It is often the limiting factor to sample throughput, especially with the recent application of the fast and modern multi-element measurement instrumentation. The complexity of geological materials makes it necessary to choose the sample decomposition technique that is compatible with the specific objective of the analysis. When selecting a decomposition technique, consideration should be given to the chemical and mineralogical characteristics of the sample, elements to be determined, precision and accuracy requirements, sample throughput, technical capability of personnel, and time constraints. This paper addresses these concerns and discusses the attributes and limitations of many techniques of sample decomposition along with examples of their application to geochemical analysis. The chemical properties of reagents as to their function as decomposition agents are also reviewed. The section on acid dissolution techniques addresses the various inorganic acids that are used individually or in combination in both open and closed systems. Fluxes used in sample fusion are discussed. The promising microwave-oven technology and the emerging field of automation are also examined. A section on applications highlights the use of decomposition techniques for the determination of Au, platinum group elements (PGEs), Hg, U, hydride-forming elements, rare earth elements (REEs), and multi-elements in geological materials. Partial dissolution techniques used for geochemical exploration which have been treated in detail elsewhere are not discussed here; nor are fire-assaying for noble metals and decomposition techniques for X-ray fluorescence or nuclear methods be discussed.

Journal of Geochemical Exploration↗

USGS2004

Geochemistry of glacial sediments in the area of the Bend massive sulfide deposit, north-central Wisconsin

Geochemical exploration in northern Wisconsin has been problematic because of thick glacial overburden and complex stratigraphic record of glacial history. To assess till geochemical exploration in an area of thick glacial cover and complex stratigraphy samples of glacial materials were collected from cores from five rotasonic boreholes near a known massive sulfide deposit, the Bend deposit in north-central Wisconsin. Diamond drilling in the Bend area has defined a long, thin zone of mineralization at least partly intersected at the bedrock surface beneath 30-40 m of unconsolidated glacial sediments. The bedrock surface has remnant regolith and saprolite resulting from pre-Pleistocene weathering. Massive sulfide and mineralized rock collected from diamond drill core from the deposit contain high (10s to 10,000s ppm) concentrations of Ag, As, Au, Bi, Cu, Hg, Se, Te, and Tl. Geochemical properties of the glacial stratigraphic units helped clarify the sequence and source areas of several glacial ice advances preserved in the section. At least two till sheets are recognized. Over the zone of mineralization, saprolite and preglacial alluvial and lacustrine samples are preserved on the bedrock surface in a paleoriver valley. The overlying till sheet is a gray, silty carbonate till with a source hundreds of kilometers to the northwest of the study area. This gray till is overlain by red, sandy till with a source to the north in Proterozoic rocks of the Lake Superior area. The complex glacial stratigraphy confounds down-ice geochemical till exploration. The presence of remnant saprolite, preglacial sediment, and far-traveled carbonate till minimized glacial erosion of mineralized material. As a result, little evidence of down-ice glacial dispersion of lithologic or mineralogic indicators of Bend massive sulfide mineralization was found in the samples from the rotasonic cores. This study points out the importance of determining glacial stratigraphy and history, and identifying favorable lithologies required for geochemical exploration. Drift prospecting in Wisconsin and other areas near the outer limits of the Pleistocene ice sheets may not be unsuccessful, in part, because of complex stratigraphic sequences of multiple glaciations where deposition dominates over erosion. ?? 2004 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

USGS1977

Application of gold compositional analyses to mineral exploration in the United States

Native gold is a mineral composed of Au, Ag and Cu in solid solution and it usually contains one or more trace metals as lattice impurities, as mineral inclusions, in grain boundaries or in surface coatings. Alloy proportions of Au, Ag and Cu, together with certain other elements, can be thought of as constituting a gold “signature”. Gold is associated with a great variety of ore deposits and has characteristic signatures for each of several types of ore deposits. Signatures for gold derived from igneous-metamorphic, hypothermal, mesothermal and epithermal deposits reflect conditions of ore formation by their content of Ag, Cu and characteristic associated elements. At higher temperatures of ore formation, gold has low Ag and high Cu content, and Bi and Pb are the most abundant trace elements. But at lower temperatures of ore formation, Ag is high, Cu is low, and Pb is the most abundant trace element. The same trend in gold signatures is observable in gold mining districts, such as Central City, Colorado, where zoning as shown by mineral assemblages indicates ore deposition at progressively lower temperatures as the distance from a central high-temperature zone increases. The signatures of gold may be useful in searching for porphyry Cu deposits. Signatures from Butte (Montana), Mineral Park (Arizona) and Cala Abajo (Puerto Rico), on the basis of limited sampling, are similar and distinctive. They are characterized by a similar assemblage of trace elements and are relatively high in both Ag and Cu. Another application of gold compositional data is in tracing placer gold to its bedrock source. For example, the Ag content of placer gold in the Tarryall district of Colorado differed from that of nearly all of the bedrock sources of gold found by early prospectors. However, one lightly prospected area peripheral to the Tertiary quartz monzonite stock at Montgomery Gulch contains gold with a Ag content similar to that of the placer gold. This area is the most likely source of the gold in the productive placers and may be a potential exploration target. Gold signatures may be useful in prospecting for metals other than gold. Several metals of low crustal abundance — notably Sn, W, Mo and the Pt group metals — are detected in analyses of some gold samples and may indicate economic deposits of these metals.

Journal of Geochemical Exploration↗

USGS1976

The zonal distribution of selected elements above the Kalamazoo porphyry copper deposit, San Manuel district, Pinal County, Arizona

There may be many as-yet-undiscovered porphyry copper deposits that exist as blind deposits deep within exposed rock bodies. The Kalamazoo porphyry copper-molybdenum deposit is a blind deposit present at depths up to at least 1,000 m (about 3,200 ft) that contains zoning features common to many of the known porphyry copper deposits found in western North and South America. As the preliminary phase in a geochemical study of the Kalamazoo deposit, whole-rock samples of core and cuttings from two drill holes have been analyzed for 60 different elements. Each hole represents a different major rock unit and each has penetrated completely through all the existing alteration zones and the ore zone. Plots of concentration vs. depth for 17 selected elements show distinct high- or low-concentration zones that are spatially related to the ore zone. For most of the ore-related elements no significant correlation with the two lithologies is apparent. The spatial distribution and abundance of elements such as Co, Cu, S, Se, Mn, Tl, Rb, Zn, B, and Li may be useful in determining the direction for exploration to proceed to locate a blind deposit. Trace element studies should be valuable in evaluating areas containing extensive outcrops of rocks with disseminated pyrite. Elemental zoning should be at least as useful as alteration-mineralization zoning for evaluating rock bodies thought to contain blind deposits similar to the Kalamazoo deposit.

Journal of Geochemical Exploration↗

USGS1999

NEOCHIM: An electrochemical method for environmental application

Ion migration and electroosmosis are the principal processes underlying electrokinetic remediation of hazardous wastes from soils. These processes are a response of charged species to an applied electrical current and they are accompanied by electrolysis of water at the electrodes through which the current is applied. Electrolysis results in the formation of OH- at the cathode and H+ at the anode. The current drives the OH- and H+ thus formed from the electrodes, through the soil and to the electrode of opposite charge. Introduction of OH- and H+ into the soil being treated modifies soil chemistry and can interfere with either the collection or immobilization of hazardous waste ions. The introduction of either OH- or H+ to the soil can be problematic to electrokinetic remediation but the problem caused by OH- has been the focus of most researchers. The problem has been addressed by flushing the OH- from the soil near the cathode or treating the soil with buffers. These treatments would apply as well to soils affected by H+. With the NEOCHIM technology, developed by the U.S. Geological Survey (USGS) for use as a sampling technique in exploration for buried ore deposits, OH- and H+ are retained in the inner compartment of two-compartment electrodes and are thus prevented from reaching the soil. This enables the extraction of cations and anions, including anionic forms of toxic metals such as HAsO42-. One of the principal attributes of NEOCHIM is the large volume of soil from which ions can be extracted. It is mathematically demonstrable that NEOCHIM extraction volumes can be orders of magnitude greater than volumes typically sampled in more conventional geochemical exploration methods or for environmental sampling. The technology may also be used to introduce selected ions into the soil that affect the solubility of ceratin ions present in the soil. Although field tests for mineral exploration have shown NEOCHIM extraction efficiencies of about 25-35%, laboratory experiments suggest that significantly higher efficiencies are possible. The attributes of NEOCHIM combined with relatively low cost of electrical power, indicate that the technology may be useful for remediation and monitoring of hazardous waste sites. Of particular importance is that NEOCHIM extractions affect only dissolved and electrically charged species, hence those prone to move in groundwater.The U.S. Geological Survey (USGS) has developed a technology called NEOCHIM for use as a sampling technique in exploration for buried deposits. With this technology, OH- and H+ are retained in the inner compartment of two-compartment electrodes and are thus prevented from reaching the soil. This enables the extraction of cations and anions. Laboratory experiments suggest extraction efficiencies higher than 25-35%.

Journal of Geochemical Exploration↗

USGS1985

Adjustment of geochemical background by robust multivariate statistics

Conventional analyses of exploration geochemical data assume that the background is a constant or slowly changing value, equivalent to a plane or a smoothly curved surface. However, it is better to regard the geochemical background as a rugged surface, varying with changes in geology and environment. This rugged surface can be estimated from observed geological, geochemical and environmental properties by using multivariate statistics.

Journal of Geochemical Exploration↗

USGS1987

Geochemical studies in the Indian Pass and Picacho Peak Bureau of Land Management Wilderness study areas, imperial county, Southern California

The U.S. Geological Survey has conducted geochemical studies in the Indian Pass (CDCA-355), 124 km 2 , and Picacho Peak (CDCA-355A), 23 km 2 , Wilderness Study Areas (WSA's) as part of a program to evaluate the mineral resource potential of designated areas in the California Desert Conservation Area. These two WSA's are of particular interest because they lie within a region which has intermittently produced significant quantities of Au since the mid-1800's, and is currently the site of much exploration activity for additional Au resources. Within a 15-km radius of the WSA's, there is one actively producing gold mine, a major deposit which began production in 1986, and one recently announced discovery. In the reconnaissance geochemical surveys of the two WSA's - 177 μm (-80 mesh) stream sediments, heavy-mineral concentrates from stream sediments, and rocks were prepared and analyzed. Four areas of possible exploration interest were identified within the WSA's. The first area is characterized by anomalous W and Bi in nonmagnetic heavy-mineral concentrates, and is underlain primarily by the Mesozoic Orocopia Schist which has been intruded by monzogranite of Oligocene age. Alteration and mineralization appear to be localized near the intrusive contact. The mineralized rock at the surface contains secondary Cu and Fe minerals where the monzogranite intrudes the metabasite horizons of the Orocopia Schist and scheelite where the monzogranite intrudes marble within the Orocopia Schist.

Journal of Geochemical Exploration↗

USGS1981

The distribution of uranium and thorium in granitic rocks of the basin and range province, Western United States

Some secondary uranium deposits are thought to have formed from uranium derived by the weathering of silicic igneous rocks such as granites, rhyolites, and tuffs. A regional geochemical survey was made to determine the distribution of uranium and thorium in granitic rocks of the Basin and Range province in order to evaluate the potential for secondary uranium occurrences in the area. The resulting geochemical maps of uranium, thorium, and the Th:U ratio may be useful in locating target areas for uranium exploration. The granites were sampled according to a five-level, nested, analysis-of-variance design, permitting estimates to be made of the variance due to differences between:(1) two-degree cells; (2) one-degree cells; (3) plutons; (4) samples; and (5) analyses. The cells are areas described in units of degrees of latitude and longitude. The results show that individual plutons tend to differ in uranium and thorium concentrations, but that each pluton tends to be relatively homogeneous. Only small amounts of variance occur at the two degree and the between-analyses levels. The three geochemical maps that were prepared are based on one-degree cell means. The reproducibility of the maps is U > Th ⪢ Th:U. These geochemical maps may be used in three methods of locating target areas for uranium exploration. The first method uses the concept that plutons containing the greatest amounts of uranium may supply the greatest amounts of uranium for the formation of secondary uranium occurrences. The second method is to examine areas with high thorium contents, because thorium and uranium are initially highly correlated but much uranium could be lost by weathering. The third method is to locate areas in which the plutons have particularly high Th:U ratios. Because uranium, but not thorium, is leached by chemical weathering, high Th:U ratios suggest a possible loss of uranium and possibly a greater potential for secondary uranium occurrences to be found in the area.

Arizona, California, Nevada, Utah↗

USGS1991

Geochemistry and exploration criteria for epithermal cinnabar and stibnite vein deposits in the Kuskokwim River region, southwestern Alaska

Cinnabar- and stibnite-bearing epithermal vein deposits are found throughout the Kuskokwim River region of southwestern Alaska. A geochemical orientation survey was carried out around several of these epithermal lodes to obtain information for planning regional geochemical surveys and to develop procedures which maximize the anomaly: threshold contrast of the deposits. Stream sediment, heavy-mineral concentrate, stream water, and vegetation samples were collected in drainages surrounding the Red Devil, Cinnabar Creek, White Mountain, Rhyolite, and Mountain Top deposits. Three sediment size fractions; nonmagnetic, paramagnetic and magnetic splits of the concentrate samples; stream waters; and the vegetation samples were analyzed for multi-element suites by a number of different chemical procedures. Nonmagnetic, heavy-mineral concentrates were also examined microscopically to identify their mineralogy.

Journal of Geochemical Exploration↗

USGS1995

Sagebrush as a sampling medium for gold exploration in the Great Basin - evaluation from a greenhouse study

Seedlings (Artemisia tridentata subsp, tridentata germinated from seed collected near Preble, Nevada were grown in soils containing Carlin-type disseminated gold ore. After 4 months growth leaves, twigs and stems were combined and analyzed by INAA. Plants grown in soils containing Carlin ore did not accumulate significantly more gold than those growing in control soil. On the other hand, sagebrush grown in soils containing Carlin ores accumulated significantly more arsenic and antimony compared to those grown in control soils. Results suggest that sagebrush would be a good prospecting medium for detecting concealed Carlin-type deposits in the Great Basin if arsenic and antimony are used as the pathfinder elements. Results also suggest that true gold anomalies in sagebrush will be more difficult to separate from aeolian contamination than those for arsenic and antimony in arid environments. -from Authors

Journal of Geochemical Exploration↗

USGS1981

Jasperoid float and stream cobbles as tools in geochemical exploration for hydrothermal ore deposits

Fragments of silicified rocks that are associated with deposits of base and precious metals may be transported as cobbles and pebbles in alluvium far downstream from the source outcrop. These rocks commonly exhibit certain characteristics which distinguish them from other detrital siliceous material, and may thus serve as a useful tool in reconnaissance geochemical exploration. The predominant characteristics of jasperoid samples, classified according to genesis, type of host rock, and proximity to base and precious metal deposits have been tabulated from a large master file containing descriptive and analytical information on jasperoid samples representing more than a hundred areas in the United States. Jasperoid that is genetically and spatially associated with ore deposits is generally dark gray or brown in color, brecciated, phaneritic, and vuggy. Jasperoids associated with lead and zinc deposits exhibit extensive halos of lead and silver anomalies, and more restricted zinc and gold anomalies. Those related to copper deposits show extensive copper, silver, and gold anomalies, and more restricted bismuth and molybdenum anomalies. Jasperoid related to gold deposits tends to exhibit extensive gold and silver anomalies and more restricted titanium, barium, vanadium, molybdenum, and rare-earth element anomalies.

Journal of Geochemical Exploration↗

USGS1991

Rock chemistry and fluid inclusion studies as exploration tools for ore deposits in the Sila batholith, southern Italy

The Sila batholith is the focus of an extensive petrogenetic research program, which includes an assessment of its potential to host granite-related ore deposits. Univariate and multivariate statistical techniques were applied to major- and minor-element rock geochemical data. The analysis indicates that the highest potential for mineralization occurs in corundum-normative, peraluminous, unfoliated, relatively late-stage plutons. The plutons are enriched in Rb, Nb, Ta and U, but depleted in Fe, Mg and Sr. The K/Rb, Ba/Rb, Rb/Sr and Rb 3 /Ba·Sr·K indices and high R -factor scores of Si-K-Rb are typical of mineralized granitic rocks. A reconnaissance fluid inclusion study indicates that the sub-solidus rock was infiltrated by solutions of widely different temperatures (50–416°C) and variable salinities (0 to ∼26 wt.% NaCl equivalent). The higher-temperature solutions probably represent granite or magmatic-related Hercynian fluids, whereas the lower-temperature fluids may be either Hercynian or Alpine in age. Fluids with characteristics typical of mineralized “porphyry” systems have not been recognized.

Journal of Geochemical Exploration↗

USGS2023

Assessment of resource potential from mine tailings using geostatistical modeling for compositions: A methodology and application to Katherine Mine site, Arizona, USA

The mining industry, in most cases, targets a specific valuable commodity that is present in small quantities within large volumes of extracted material. After milling and processing, most of the extracted material and the effluents are stored as waste (tailings) in impoundments, such as dams or waste dumps, or are backfilled into underground mines. In time, tailing materials may become an issue of environmental and health concern due to the hazardous elements, ions, and oxides contained within the waste material. In addition, handling and storage of such waste in dams may pose the risk of dam failure with catastrophic consequences to nature and nearby communities. On the other hand, tailings may offer potential as secondary sources of critical elements (CEs), including rare earth elements (REEs), which may have been overlooked during primary production and processing. Therefore, treating mine tailings as a resource has economic and environmental benefits by reducing the waste from new and historical mine sites through remining. One of the critical steps for taking advantage of these benefits is to spatially quantify the resources and the pollutants, which require the application of adequate data analysis and modeling methods, often to compositional geochemical data. Utilizing adequate methods is especially important for correctly quantifying resource potential, as the quantities will often be at low concentrations. This work presents quantification of resource potential (Au, Ag, Cu, Zn, Pb) and elements of environmental concern (Hg and As) from the tailings of a historic mine site, Katherine Mine, AZ, USA. Data reported by the U.S. Bureau of Mines (USBM) after extensive field campaigns in the 1990s, including sampling from tailing impoundment and surrounding areas for geochemical characterization and geophysical surveys, were used. First, compositional data (CoDa) analysis was employed to explore associations of sampling locations, geochemical parts, and the clustering of samples. Next, sequential Gaussian simulation (SGSIM) was applied to samples that showed a genetic link to tailing material after isometric log-ratio transformation (ilr) and mix/max autocorrelation factor (MAF) transformation for spatial modeling and uncertainty evaluation. Geostatistical results revealed spatial variability of concentrations within the tailing area. Uncertainty evaluation based on realizations indicated that Cu (14.27–20.01 t), Zn (44.23–76.23 t), and Pb (22.56–38.28 t) are the most abundant elements within a 5 %–95 % interval, followed by Ag and Au (~5.3 and 0.18 t, at 50th percentile), respectively. Of the elements of health concern, As was found to be ~4.8 t (50th percentile) in the tailing area. The work also showed that ~0.51 t As, 0.005 t Hg, 0.020 t of Au, and 0.62 t of Ag were carried to Lake Mohave by an ephemeral stream called Katherine Wash, which transects the tailings.

Arizona↗

USGS1977

Uranium and coexisting element behaviour in surface waters and associated sediments with varied sampling techniques used for uranium exploration

Optimum sampling methods in surface water and associated sediments for use in uranium exploration are being studied at thirty sites in Colorado, New Mexico, Arizona and Utah. For water samples, filtering is recommended to increase sample homogeneity and reproducibility because for most elements studied water samples which were allowed to remain unfiltered until time of analysis contained higher concentrations than field-filtered samples of the same waters. Acidification of unfiltered samples resulted in still higher concentrations. This is predominantly because of leaching of the elements from the suspended fraction. U in water correlates directly with Ca, Mg, Na, K, Ba, B, Li and As. In stream sediments, U and other trace elements are concentrated in the finer size fractions. Accordingly, in prospecting, grain size fractions less than 90 μm (170 mesh) should be analyzed for U. A greater number of elements (21) show a significant positive correlation with U in stream sediments than in water. Results have revealed that anomalous concentrations of U found in water may not be detected in associated sediments and vice versa. Hence, sampling of both surface water and coexisting sediment is strongly recommended.

Journal of Geochemical Exploration↗