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At least 37 records · Page 2Linked to original sources
USGS2002

Solubility of NaCl and KCl in aqueous HCl from 20 to 85°C

The solubilities of NaCl and KCl in aqueous HCl solutions were determined from 20 to 85 ° C at concentrations ranging from 0 to 20 g of HCl/100 g of solution. Equations are given that describe the solubilities over the range of conditions studied. For NaCl and KCl respectively measured solubilities show an average deviation from these equations of ??0.10 and ??0.08 g/100 g of saturated solution.

Journal of Chemical and Engineering Data↗
USGS2012

Crustal resistivity structure from magnetotelluric soundings in the Colorado Plateau-Basin and Range provinces, central and western Arizona

Resistivity structure to about 25 km depth is defined from two-dimensional modeling of 29 magnetotelluric (MT) soundings (0.002–5 Hz) that traverse 280 km of the southwestern Colorado Plateau, transition zone, and Basin and Range provinces in Arizona. From the surface to 5 km depth, the MT model suggests structural relationships between low-resistivity sedimentary and volcanic rocks (50–300 ohm m) and high-resistivity granitic and gneissic basement (500–9000 ohm m). In the Basin and Range province, the MT model and a seismic reflection section show a generally consistent distribution of supracrustal rocks that have relatively low to moderate resistivity (MT) and relatively strong, locally coherent reflectivity. The supracrustal zone defined by these physical properties is inferred to be composed of upper plate rocks above a middle Tertiary detachment fault system which has been mapped in surrounding ranges. Some low-angle fault zones inferred from seismic reflections to extend into high resistivity basement below the supracrustal rocks are not resolved by the MT model. A low-resistivity zone with a conductance of 500 S or more is modeled in the crust at an average depth of about 15 km in the Basin and Range province and transition zone and may deepen below the southwestern part of the Colorado Plateau. In the Basin and Range province, the top of the low resistivity may correspond to a reflective layer with a 6-s two-way-travel time. This deep low-resistivity zone might be caused by a small fraction of connected hydrous solutions or silicic melts.

Journal of Geophysical Research↗
USGS2005

Parameter and observation importance in modelling virus transport in saturated porous media - Investigations in a homogenous system

This paper evaluates the importance of seven types of parameters to virus transport: hydraulic conductivity, porosity, dispersivity, sorption rate and distribution coefficient (representing physical-chemical filtration), and in-solution and adsorbed inactivation (representing virus inactivation). The first three parameters relate to subsurface transport in general while the last four, the sorption rate, distribution coefficient, and in-solution and adsorbed inactivation rates, represent the interaction of viruses with the porous medium and their ability to persist. The importance of four types of observations to estimate the virus-transport parameters are evaluated: hydraulic heads, flow, temporal moments of conservative-transport concentrations, and virus concentrations. The evaluations are conducted using one- and two-dimensional homogeneous simulations, designed from published field experiments, and recently developed sensitivity-analysis methods. Sensitivity to the transport-simulation time-step size is used to evaluate the importance of numerical solution difficulties. Results suggest that hydraulic conductivity, porosity, and sorption are most important to virus-transport predictions. Most observation types provide substantial information about hydraulic conductivity and porosity; only virus-concentration observations provide information about sorption and inactivation. The observations are not sufficient to estimate these important parameters uniquely. Even with all observation types, there is extreme parameter correlation between porosity and hydraulic conductivity and between the sorption rate and in-solution inactivation. Parameter estimation was accomplished by fixing values of porosity and in-solution inactivation.

Journal of Contaminant Hydrology↗
USGS2012

Implications of a magnetic model of the Long Valley caldera, California

A quantitative magnetic model of Long Valley, California, shows that the magnetic field above this caldera is dominated by intracaldera Bishop tuff, part of the ash flow tuff whose eruption precipitated the caldera collapse. We propose that about half of the 350 km 3 of intracaldera Bishop tuff, or that part beneath the resurgent dome, has been subjected to extensive hydrothermal alteration. The heat that produced this alteration is apparently associated with the residual magma chamber, and much of the formation may still be hot (>200°C). The magnetic minerals in the remaining intracaldera Bishop tuff have not been drastically altered, presumably because the tuff was not heated sufficiently. As a result, the tuff may not be very hot today. The model also reveals the existence of parts of two large precaldera mountains beneath the caldera fill. The resolving power attained in this investigation was possible because we were dealing with large, magnetically distinct lithologic units and a large amount of geological and geophysical data were available constraints to produce the solution.

California↗
USGS2020

UV identification and quantitative measurement of quinaldine residues in fish

A method for the confirmatory analysis of quinaldine residue in fish is described. The method utilizes the same extraction and cleanup procedure as the GLC method reported previously. The lower limit of sensitivity for quinaldine residue in fish muscle is 0.01 ppm. Identification is accomplished by comparing the UV spectra of the sample and a standard solution of quinaldine.

Journal of the Association of Official Analytical ↗
USGS1992

An improved method for field extraction and laboratory analysis of large, intact soil cores

Various methods have been proposed for the extraction of large, undisturbed soil cores and for subsequent analysis of fluid movement within the cores. The major problems associated with these methods are expense, cumbersome field extraction, and inadequate simulation of unsaturated flow conditions. A field and laboratory procedure is presented that is economical, convenient, and simulates unsaturated and saturated flow without interface flow problems and can be used on a variety of soil types. In the field, a stainless steel core barrel is hydraulically pressed into the soil (30-cm diam. and 38 cm high), the barrel and core are extracted from the soil, and after the barrel is removed from the core, the core is then wrapped securely with flexible sheet metal and a stainless mesh screen is attached to the bottom of the core for support. In the laboratory the soil core is set atop a porous ceramic plate over which a soil-diatomaceous earth slurry has been poured to assure good contact between plate and core. A cardboard cylinder (mold) is fastened around the core and the empty space filled with paraffin wax. Soil cores were tested under saturated and unsaturated conditions using a hanging water column for potentials ≤0. Breakthrough curves indicated that no interface flow occurred along the edge of the core. This procedure proved to be reliable for field extraction of large, intact soil cores and for laboratory analysis of solute transport.

Journal of Environmental Quality↗
USGS1974

A mineral separation procedure using hot Clerici solution

Careful boiling of Clerici solution in a Pyrex test tube in an oil bath is used to float minerals with densities up to 5.0 in order to obtain purified concentrates of monazite (density 5.1) for analysis. The "sink" and "float" fractions are trapped in solidified Clerici salts on rapid chilling, and the fractions are washed into separate filter papers with warm water. The hazardous nature of Clerici solution requires unusual care in handling.

Journal of Research of the U.S. Geological Survey↗
USGS1974

Chert derived from magadiite in a lacustrine deposit near Rome, Malheur County, Oregon

Nodules and thin beds of chert occur in the upper part of the informally named Rome beds, about 8 11 km southwest of Rome, Oreg. The chert is in green to gray mudstone, about 8 m beneath a conspicuous gray and yellow zeolitic tuff. The bedded chert contains molds of saline minerals and it grades southward and marginward into nodular chert. The nodular chert is of two varieties: relatively large lobate nodules that have greenish-brown interiors and abundant saline crystal molds, and relatively small lobate nodules that have gray interiors and a surface reticulation. The latter variety is the so-called snakeskin agate prized by lapidaries. Both nodular varieties characteristically have a thin white rind. The cherts are similar, if not identical, to cherts reported from Quaternary lacustrine deposits in eastern Africa and from Pleistocene to Jurassic lacustrine deposits in Wyoming. The Rome chert probably formed from a hydrous sodium silicate precursor such as magadiite during diagenesis. Magadiite is generally a primary precipitate from a highly alkaline lake which is capable of attaining a high concentration of silica in solution.

Oregon↗
USGS2007

Spatial and temporal geochemical trends in the hydrothermal system of Yellowstone National Park: Inferences from river solute fluxes

We present and analyze a chemical dataset that includes the concentrations and fluxes of HCO 3 − , SO 4 2− , Cl − , and F − in the major rivers draining Yellowstone National Park (YNP) for the 2002–2004 water years (1 October 2001 – 30 September 2004). The total (molar) flux in all rivers decreases in the following order, HCO 3 − > Cl − > SO 4 2− > F − , but each river is characterized by a distinct chemical composition, implying large-scale spatial heterogeneity in the inputs of the various solutes. The data also display non-uniform temporal trends; whereas solute concentrations and fluxes are nearly constant during base-flow conditions, concentrations decrease, solute fluxes increase, and HCO 3 − /Cl − , and SO 4 2− /Cl − increase during the late-spring high-flow period. HCO 3 − /SO 4 2− decreases with increasing discharge in the Madison and Falls Rivers, but increases with discharge in the Yellowstone and Snake Rivers. The non-linear relations between solute concentrations and river discharge and the change in anion ratios associated with spring runoff are explained by mixing between two components: (1) a component that is discharged during base-flow conditions and (2) a component associated with snow–melt runoff characterized by higher HCO 3 − /Cl − and SO 4 2− /Cl − . The fraction of the second component is greater in the Yellowstone and Snake Rivers, which host lakes in their drainage basins and where a large fraction of the solute flux follows thaw of ice cover in the spring months. Although the total river HCO 3 − flux is larger than the flux of other solutes (HCO 3 − /Cl − ≈ 3), the CO 2 equivalent flux is only ∼ 1% of the estimated emission of magmatic CO 2 soil emissions from Yellowstone. No anomalous solute flux in response to perturbations in the hydrothermal system was observed, possibly because gage locations are too distant from areas of disturbance, or because of the relatively low sampling frequency. In order to detect changes in river hydrothermal solute fluxes, sampling at higher frequencies with better spatial coverage would be required. Our analysis also suggests that it might be more feasible to detect large-scale heating or cooling of the hydrothermal system by tracking changes in gas and steam flux than by tracking changes in river solute flux.

Journal of Volcanology and Geothermal Research↗
USGS1972

Virucidal activity of two Iodophors to salmonid viruses

Wescodyne ® and Betadine ® , organic iodine complexes, were compared in vitro for virucidal activity against infectious hematopoietic necrosis (IHN), infectious pancreatic necrosis (IPN), and viral hemorrhagic septicemia (VHS) viruses. Both iodophors were about equally effective on all three viruses. Each iodophor completely destroyed IHN virus within 30 sec at 12 ppm iodine, and was not affected by water hardness. Virucidal activity, however, was reduced at p H levels above 8.0 and in the presence of organic matter. Wescodyne was also compared with seven disinfectants commonly used in fish hatcheries, for virucidal properties against IHN virus. Wescodyne and chlorine were the only disinfectants to completely destroy the virus. Either Wescodyne or Betadine would effectively destroy the salmonid viruses at less than 25 ppm iodine within 5 min in solutions near neutrality.

Journal of the Fisheries Research Board of Canada↗
USGS1991

Porosity trends of the Lower Cretaceous J Sandstone, Denver Basin, Colorado

This study examines relationships between porosity and time-temperature history, and the influence of rock properties upon porosity, for the Lower Cretaceous J Sandstone in the Colorado portion of the Denver basin. The J Sandstone is classified as a quartzarenite to litharenite and was deposited in nearshore-marine, deltaic, and fluvial-estuarine (valley-fill) settings. Principal elements of its paragenetic sequence include quartz cementation and pressure solution, carbonate cementation and dissolution, dissolution of feldspar and rock fragments, and formation of authigenic clays. Porosity versus vitrinite reflectance (R 0 ) regression lines of the form Phi = A(R 0 )Beta (where B is a negative number) depicting the 10th, 25th, 50th, 75th, and 90th porosity percentiles of the J Sandstone were derived from 963 core-plug measurements representing 31 wells. The data span a thermal maturity range of R 0 = 0.41%-1.14%. Porosity distributions at different locations within the basin can be estimated as a function of thermal maturity on the basis of these regression lines. Porosity trends of the J Sandstone, if considered as a function of R 0 , are similar to those of broad, composite data sets representing sandstones in general. The petrographic factors that most affect J Sandstone porosity variability at a given level of thermal maturity are carbonate cementation and clay content. Carbonate cement, where present, reduces porosity. If previously more widespread, carbonate cement could also introduce porosity heterogeneity by temporarily preserving the pore network relative to uncemented intervals. Abundant detrital and authigenic clay reduces porosity by occupying pores. Low clay content indirectly reduces porosity because the inhibiting effects of clay upon quartz cementation and pressure solution are largely absent.

Journal of Sedimentary Petrology↗
USGS1977

Enthalpies of formation of low albite (NaAlSi 3 O 8 ), gibbsite (Al(OH) 3 ), and NaAlO 2 ; revised values for Δ H ° f,298 and Δ G ° f,298 of some aluminosilicate minerals

The enthalpies of formation from the elements Δ H ° t , of low albite, analbite, NaAlSi 3 O 8 glass, gibbsite (Al(OH) 3 ), and NaAlO 2 , have been determined by hydrofluoric acid solution calorimetry from measurements of the heats of solution, Δ H ° soln , of low albite, NaAlO 2 , SiO 2 , Al(OH) 3 , Al, H 2 O, NaCl, and HC1-12.731H 2 O in 20.1 weight percent HF(aq) at temperatures between 303.15 and 348.15 K. At 298.15 K the enthalpies of formation, Δ H ° f,298 , for low albite, analbite, NaAlSi 3 O 8 glass, gibbsite ( Al(OH) 3 ), and NaAlO 2 are -3 935 115±3415, -3 924 235±3640, -3 875 455±3700, ±1293130±1190, and 1135 990±1255 J mol -1 , respectively. Our values for the enthalpies of formation of low albite, analbite, and for NaAlSi 3 O 8 glass are approximately 13 810 J mol -1 more negative than the values calculated by D. R. Waldbaum in 1968. Our value for the enthalpy of formation of gibbsite at 298.15 K is 11234 J more negative than the value of R. Barany and K. K. Kelley obtained in 1961. The standard Gibbs free energies of formation, Δ G ° f,298 for low albite, analbite, and gibbsite calculated from the above enthalpies and the appropriate entropy data are -3 711 715±3435, -3 706 500±3660, and -1154 890±1200 J mol -1 , respectively. The enthalpy of solution of Standard Reference Material 1654, α-quartz (37 to 74 μm), in 20.1 wt percent HF(aq) is -137 737±209 J mol -1 at 333.15 K. This value is approximately 1255 J less negative than the value obtained by King in 1951 and 1952 for material that has a mean particle diameter of less than 5 μm and that has been used by the U.S. Bureau of Mines in their determinations of the enthalpies of formation of many silicates. Revised values of the enthalpies and Gibbs free energies of formation are presented for some aluminosilicate minerals, based upon this new data for Δ H ° f,298 of gibbsite and the heat of solution of α-quartz.

Journal of Research of the U.S. Geological Survey↗
USGS1976

The source of hydrothermal solutions at Puerto Maunabo and its bearing on the base-metal-potassium feldspar association in Puerto Rico

A quartz oligoclase porphyry exposed near Puerto Maunabo may provide evidence to further our understanding of the base-metal-potassium feldspar association known to occur in many of the porphyry-type copper deposits of Puerto Rico. The porphyry appears to be a magmatic differentiate on the border of the San Lorenzo batholith that may represent a source of mineralizing hydrothermal solutions. The porphyry intrudes an albitized quartz diorite border phase of the batholith that contains large roof pendants of metavolcanic rock. These roof pendants are mostly metamorphosed to greenschist metamorphic facies, but in the vicinity of Puerto Maunabo south of the porphyry, they reach amphibolite metamorphic facies; north of the porphyry, similar xenolithic lenses of metavolcanic rock appear to have been converted entirely to an oligoclase quartz felsite. The layered albitized quartz felsite has the same composition and texture as irregular veinlets in the albitized quartz diorite and as the groundmass in the porphyry. The K + ions arid basic ions of Fe +2 , Cu +2 , Mg +2 apparently were mobilized during final magmatic crystallization and then escaped as hydrothermal solutions that followed open conduits within a zone of structural weakness which also permitted the emplacement of the porphyry. The volcanic rock of Cerro Piedra Hueca, in contact with the albitized quartz diorite, and generally along strike west of the porphyry, has been altered to a quartz sericite rock entirely devoid of mafic silicates. This is the southeasternmost exposure of hydrothermally altered volcanic rock in the regional zone of northwest-trending faults that contains the principal porphyry-type copper deposits of Puerto Rico. The texture, mineralogy, and geologic environment of the porphyry at Puerto Maunabo are similar to those of the ore-bearing porphyries but differ in one important aspect. Most ore-bearing porphyries contain hydrothermal potassium feldspar and reddish-brown biotite intimately associated with the base-metal sulfides. In the porphyry of Puerto Maunabo, potassium feldspar is conspicuously absent, and only a trace of biotite is present; the only sulfide present is pyrite. The physical and chemical environment required to precipitate K + ions, either as potassium feldspar or biotite, apparently is very similar to that required to precipitate base-metal sulfides. At Puerto Maunabo, these conditions evidently did not prevail, and potassium and the base metals may have been carried in solution to a more favorable environment.

Puerto Maunabo↗
USGS1977

A thermostatic water bath for experimental studies in aqueous solutions

A temperature-controlled water bath for the study of ion-pairing equilibria and mineral solubility in aqueous solutions below 100°C is described. The bath is similar to a previously described system (P. B. Hostetler and C. L. Christ, 1968, U.S. Geol. Survey Prof. Paper 600-D, p. D217-D221) but incorporates several significant improvements. Included among these are a more efficient stirring mechanism, a potentially larger solid-to-solution ratio, and improved equilibration of the gas phase with the solution.

Journal of Research of the U.S. Geological Survey↗
USGS2022

Priorities for translating goodwill between movement ecologists and conservation practitioners into effective collaboration

Addressing ongoing biodiversity loss requires collaboration between conservation scientists and practitioners. However, such collaboration has proved challenging. Despite the potential importance of tracking animal movements for conservation, reviews of the tracking literature have identified a gap between the academic discipline of movement ecology and its application to biodiversity conservation. Through structured conversations with movement ecologists and conservation practitioners, we aimed to understand whether the identified gap is also perceived in practice, and if so, what factors hamper collaboration and how these factors can be remediated. We found that both groups are motivated and willing to collaborate. However, because their motivations differ, there is potential for misunderstandings and miscommunications. In addition, external factors such as funder requirements, academic metrics, and journal scopes may limit the applicability of scientific results in a conservation setting. Potential solutions we identified included improved communication and better presentation of results, acknowledging each other's motivations and desired outputs, and adjustment of funder priorities. Addressing gaps between science and implementation can enhance collaboration and support conservation action to address the global biodiversity crisis more effectively.

Conservation Science and Practice↗
USGS2009

Effects of uranium mining discharges on water quality in the Puerco River basin, Arizona and New Mexico

From 1967 until 1986, uranium mine dewatering increased dissolved gross alpha, gross beta, uranium and radium activities and dissolved selenium and molybdenum concentrations in the Puerco River as indicated by time trends, areal patterns involving distance from the mines and stream discharge. Additionally, increased dissolved uranium concentrations were identified in groundwater under the Puerco River from where mine discharges entered the river to approximately the Arizona-New Mexico State line about 65 km downstream. Total mass of uranium and gross alpha activity released to the Puerco River by mine dewatering were estimated as 560 Mg (560 × 10 6 g) and 260 Ci, respectively. In comparison, a uranium mill tailings pond spill on 16 July 1979, released an estimated 1.5 Mg of uranium and 46 Ci of gross alpha activity. Mass balance calculations for alluvial ground water indicate that most of the uranium released did not remain in solution. Sorption of uranium on sediments and uptake of uranium by plants probably removed the uranium from solution.

Arizona, New Mexico↗