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At least 37 records · Page 2Linked to original sources
USGS1997

Day one road log: Mid-Tertiary igneous rocks and mineral deposits in the central Wasatch Mountains, Utah

Today's field trip examines late Eocene and Oligocene granitoid intrusions, cogenetic volcanic rocks (Keetley Volcanics), and associated hydrothermally altered and mineralized rocks in the central Wasatch Mountains. Because of late Cenozoic tilting related to Basin and Range extension, a continuum of mid-Tertiary paleodepths is exposed that ranges from about 11 km on the west side of the Little Cottonwood stock to the actual paleosurface on the east side of the range (Fig. 1; John, 1989a). Consequently, we will see a wide variety of textures and styles of emplacement in the intrusive rocks, and a correspondingly wide variety of hydrothermal alteration types and mineral deposits (Lawton et al., 1980; John, 1989a). Mid-Tertiary igneous rocks in the central Wasatch Mountains consist of three phaneritic stocks exposed in the western and central parts of the range (Little Cottonwood, Alta, and Clayton Peak stocks); six porphyry to fine-grained phaneritic stocks exposed in the middle and eastern parts of the range, primarily in the Park City mining district (Flagstaff, Glencoe, Mayflower, Ontario, Pine Creek, and Valeo stocks); a subvolcanic porphyry complex (Park Premier stock) exposed near the Park Premier mine which is now partly covered by water filling the Jordanelle Reservoir; and coeval volcanic rocks (Keetley Volcanics), subvolcanic intrusions, and a volcanic neck (Indian Hollow plug) are exposed on the east side of the range (Figs. 2 and 3). The intrusive rocks range from coarse-grained, coarsely porphyritic on the west to fine-grained, porphyroaphanitic on the east (John, 1989a). They form a high-K, calc-alkaline series (Vogel

Utah↗
USGS1970

Petrology of unshocked crystalline rocks and shock effects in lunar rocks and minerals

On the basis of rock modes, textures, and mineralogy, unshocked crystalline rocks are classified into a dominant ilmenite-rich suite (subdivided into intersertal, ophitic, and hornfels types) and a subordinate feldspar-rich suite (subdivided into poikilitic and granular types). Weakly to moderately shocked rocks show high strain-rate deformation and solid-state transformation of minerals to glasses; intensely shocked rocks are converted to rock glasses. Data on an unknown calcium-bearing iron metasilicate are presented.

Science↗
USGS1967

Shock effects in certain rock-forming minerals

Shock effects in quartz, plagioclase, biotite, amphibole, and some accessory minerals have been observed in rocks subjected to various degrees of meta morphism by meteoritic impact. The shock features described are unique; they are never observed in rocks from normal geologic environments. Such features are described: 1) Multiple sets of closely spaced planar microstructures occur in quartz, plagioclase, and other rock-forming minerals. Those characteristic of shock consist of alternating platelets, with a range of reduced mean index of re fraction and birefringence; they con sist of platelets that have been partially or completely transformed to an amor phous phase. 2) Quartz and plagioclase are selec tively and completely transformed to silica glass and plagioclase glass in the solid state, whereas the associated mafic minerals remained crystalline. There is no reaction between adjacent minerals. 3) High-pressure polymorphs occur, such as coesite or stishovite. Coesite oc Curs exclusively within silica glass; it has not been observed as a reaction or breakdown product. 4) Nickel-iron spherules occur in the fused glass or impactites. 5) The occurrence of droplets of ilmenite, rutile, pseudobrookite, and baddaleyite in impactites indicates a temperature of formation exceeding 150°C. 6) Dense glass occurs, similar in composition to bulk rock, in which iron oxide, such as fine particles of mag netite, is completely dissolved. All these features are characteristic of a process involving the rapid rise and fall of extremiiely high pressures and temperatures. Minerals and mineral as semblages experiencing such high strain rates and sudden changes of pressures and temperatures react and change in dependently to the bulk chemical com position, under nonequilibrium condi tions. Many aspects of shock features re quire careful study. Kink bands in biotite and deformation lamellae in quartz occur in tectonically deformed rocks. These features should be studied with great care in order to determine whether reduction in mean index of refraction and total birefringence along the planar structures have resulted from vitrification or phase transition; their presence is additional evidence in favor of a shock mechanism. Vitreous phases or glasses formed by shock also have many unique prop erties; they have not been studied by such methods as thermoluminescence, electron spin resonance, low-angle x ray diffraction, or infrared spectroscopy. Shock-fused glass of high density needs to be studied in detail in carefully con trolled laboratory conditions. Experimental shock-wave studies of the equation-of-state of single minerals and mineral assemblages, under care fully controlled conditions, must pre cede estimates of peak pressures and peak and residual temperatures of shocked natural mineral assemblages. Detailed petrographic and mineralogic studies, however, have provided useful and definitive criteria for characteriza tion of impact events. Such data should be of paramount importance in the study of samples brought back from Moon.

Science↗
USGS1995

Impedance spectra of hot, dry silicate minerals and rocks: qualitative interpretation of spectra

Impedance spectroscopy helps distinguish the contributions that grain interiors and grain boundaries make to electrical resistance of silicate minerals and rocks. Olivine, orthopyroxene, clinopyroxenes, and both natural and synthetic clinopyroxenite were measured. A network of electrical elements is presented for use in interpreting impedance spectra and conductive paths in hot or cold, wet or dry, minerals and rocks at any pressure. In dry rocks, a series network path predominates; in wet rocks, aqueous pore fluid and crystals both conduct. Finite resistance across the sample-electrode interface is evidence that electronic charge carriers are present at the surface, and presumably within, the silicate minerals and rocks measured. -from Authors

American Mineralogist↗
USGS1976

Chromium in rocks and minerals from the southern California batholith

Chromium, determined by neutron-activation analysis in a suite of rocks and minerals from the southern California batholith, shows Cr concentrated in the mafic differentiates, decreasing as the more felsic rocks are approached. This trend is evident for samples of the Woodson Mountain Granodiorite from a single differentiated stock. The distribution of Cr in the minerals from the rocks of the southern California batholith shows that Cr was depleted in the magma during the course of crystallization. The data indicate that the minerals were in equilibrium with the magma during crystallization, and the distribution coefficient (Cr in biotite/Cr in hornblende) is correlated with differentiation indices, indicating either temperature or compositional dependence. The average distribution coefficient (Cr in biotite/Cr in hornblende) is 1.18, which compares favorably with the average values found by other investigators for other suites. ?? 1976.

Chemical Geology↗
USGS1915

Analyses of rocks and minerals from the laboratory of the United States Geological Survey, 1880 to 1914

The present Geological Survey of the United States was organized in 1879. In 1880, in connection with the Colorado work, a chemical laboratory was established at Denver in charge of W. F. Hillebrand, with whom were associated Antony Guyard and, later, L. G. Eakins. In 1882 W. H. Melville was placed in charge of a second laboratory at San Francisco, and in the autumn of 1883 the central laboratory was started in Washington, with myself as chief chemist. In November, 1885, Dr. Hillebrand was transferred to Washington; early in 1888 he was followed by Mr. Eakins, and the Denver laboratory was discontinued. In the spring of 1890 Dr. Melville also was transferred to Washington, and since then the geochemical work of the Survey has been concentrated at headquarters. The special laboratories of the water-resources and technologic branches of the Survey are not included in this statement and their work is not represented in this bulletin. Up to January 1, 1914, nearly 8,000 analyses have been made in the laboratory at Washington of rocks, minerals, ores, waters, sediments, coals, metals, and other substances with which geology has to do. Some-hundreds of analyses were also made in the laboratories at Denver and San Francisco. A fair amount of research work upon mineralogical and analytical problems has also been done. In *all of this work the following chemists have been employed: E. T. Allen, R. K. Bailey, Charles Catlett, T. M. Chatard, F. W. Clarke, L. G. Eakins, J. G. Fairchild, F. A. Gooch, Antony Guyard, W. B. Hicks, W. F. Hillebrand, W. F. Hunt, W. H. Melville, H. C. McNeil, Chase Palmer, R. B. Riggs, W. T. Schaller, E. A. Schneider, George Steiger, H. N. Stokes, E. C. Sullivan, William Valentine, R. C. Wells, W. C. Wheeler, and J. E. Whitfield. At present, January 1, 1914, eight of these chemists are employed in the Survey. Other officers of the Survey have been occupied more or less with chemical questions, but the men named in this list were connected directly with the laboratory. Some work for the chemical division has also been done by chemists not regularly on the rolls of the Survey, but their analyses, with the exception of a single group to be noted later, do not fall within the scope of this paper.

Bulletin↗
USGS1979

Pliocene intrusive rocks and mineralization near Rico, Colorado

Fission-track and potassium-argon studies of intrusive rocks in the vicinity of Rico, Colorado, have shown that at least two periods of igneous activity occurred and that significant ore mineralization is associated with alaskites and latites that are 3 to 5 million years old. Discordant fission-track ages of apatite and zircon in the older rocks reveal a major heat source, centered under the mineralized rocks near the townsite of Rico, that cooled in late Miocene or early Pliocene time. This heat source may indicate the presence of a buried stock that is related to the mineralization.

Colorado↗
USGS1980

Pliocene intrusive rocks and mineralization near Rico, Colorado

Fission-track and potassium-argon studies of intrusive rocks in the vicinity of Rico, Colorado, have shown that there are at least two periods of igneous activity and that significant ore mineralization is associated with alaskites and latites that are 3 to 5 m.y. old. Discordant fission track ages of apatite and zircon in the older rocks reveal a major heat source that cooled in late Miocene or early Pliocene and is centered under the mineralized rocks near the townsite of Rico. This heating may indicate the presence of a buried stock that is related to the mineralization.

Colorado↗
USGS1983

U-Th-Pb systematics of zircon inclusions in rock-forming minerals: A study of armoring against isotopic loss using the Sherman Granite of Colorado-Wyoming, USA

Zircon inclusions were separated from the five major rock-forming minerals of the Sherman Granite of southern Wyoming, in order to evaluate the degree of discordance as a possible function of host minerals. U-Th-Pb isotopic ratios were determined for two size fractions of zircon inclusions from each mineral, plus five size fractions from the bulk rock. Isotopic data from the inclusions have more than double the spread of data on a discordia obtained from the bulk sample, thereby yielding better-resolved concordia intercepts. However, isotopic ratios and morphologic characteristics indicate that the Pb/U systematics are complicated by inherited radiogenic lead. Although the data array cannot unequivocally be explained by the armoring process, the proposed methodology has succeeded in identifying groups of zircon with different isotopic characteristics. As such, this technique can be used to decipher complex geologic/isotopic histories and may be a useful addition to routine zircon geochronology. ?? 1983 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS2003

Applied geochemistry, geology and mineralogy of the northernmost Carlin trend, Nevada

Investigations in the northernmost Carlin trend were undertaken to advance understanding of the geochemical signatures and genesis of precious metal deposits in the trend . Two fundamental geologic relationships near the trend significantly affect regional geochemical distributions: a remarkably intact lower Paleozoic stratigraphic sequence of siliceous rocks in the upper plate of the middle Paleozoic Roberts Mountains thrust, and the widespread repetition of rocks high in the upper plate during late Paleozoic thrusting that thickens the cover above mineralized rock in the lower plate. A compilation of previously published chemical analyses of 440 stream sediment samples and 115 rocks from two 7 1/2-minute quadrangles, as well as new chemical analyses of approximately 1,000 drill core samples in a 1,514 m (4,970 ft) hole through the Rodeo Creek deposit were used to construct three-dimensional element distribution models that highlight metal zonation in the mineralized systems. The Rodeo Creek deposit comprises deep Ag base-metal ± Au-mineralized rock below the Roberts Mountains thrust and contains an unusually high Ag/Au ratio greater than 30. Stacked geochemical halos related to the deposit are confined to the lower plate of the Roberts Mountains thrust and include two horizons of Hg, Cu, and Zn anomalies-as much as 180 m above the deposit-that mostly result from mercurian sphalerite. Extremely subtle indications of mineralization in the upper plate of the Roberts Mountains thrust above the deposit include arsenopyrite overgrowths on small pyrite crystals in 50- to 75-μm-wide clay-carbonate veinlets that lack alteration halos, arsenical rims on small disseminated crystal of recrystallized diagenetic pyrite, and partial replacement of diagenetic pyrite by tennantite. Some of these minerals contain anomalously high Au. However, these As-(Au)-bearing rocks most likely represent another locus of largely untested mineralized rock rather than distal halos related to either the Rodeo Creek or the nearby Dee and Storm gold deposits. Application of micromineralogic techniques helped to identify mineral assemblages that are specific to mineralization and provided an empirical foundation for interpretations of geochemical halos in the Carlin trend . District-scale geochemical patterns of several elements in stream sediments and surface rocks coincide with the northernmost Carlin trend and can be used to explore for Carlin -type deposits. Concentrations of elevated As and Sb in stream sediments (as much as 54 ppm As) have northwest-elongate lobate patterns that clearly outline the trend across a width of approximately 4 km. Arsenic contents of exposed rocks (as much as 90 ppm As) strongly correlate with As contents of derivative stream sediments, and rock contents of Sb show a somewhat lesser but nonetheless strong and similar correspondence. Factor analysis of stream-sediment data shows that those factor scores that are correlated with As, Sb, Au, and Pb also are high along the trend and suggest that mineralized rocks may be present. Although As was not detected by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) studies in heavy mineral concentrates of high-As stream sediments in the Carlin trend , X-ray absorption near-edge spectra (XANES) of selected light fractions of stream sediment samples indicate that Al-bearing phases, such as gibbsite, amorphous Al oxyhydroxides, or aluminosilicate clay minerals host most of the As(V). The best fit, visually and in terms of the lowest residual, was obtained by a model compound of As(V) sorbed to gibbsite. Thus, most As in stream sediments derived from altered rock within the Carlin trend apparently is contained in light fractions. The geochemical character of young, unconsolidated, postmineral deposits that cover mineralized rocks on the Carlin trend partly results from mineralized sources along the trend . Concentration of As in the Miocene Carlin Formation shows an exceptionally well developed progressive increase to about 30 ppm As as altered rock surrounding the trend is approached. Mineralized and/or altered rock fragments probably have been shed directly into the sedimentary basin of the Carlin Formation, and migration of As, now fixed as As(V), also may have occurred in the supergene environment after material was recycled out of the Carlin Formation and into present-day gulleys.

Nevada↗
USGS1985

ELECTROCHEMICAL PROPERTIES OF ROCKS AND MINERALS.

Many phenomena and processes in the earth sciences are a result of the electrochemical properties of rocks and minerals. Examples include formation of mineral deposits and petroleum reservoirs control of drilling muds, and success or failure of toxic waste isolation barriers. Such phenomena can be observed at a distance using geophysical techniques to measure various electrical properties of the earth.

Conference Paper↗
USGS1975

Radiochemical determination of very low concentrations of nickel in rocks and minerals

A radiochemical procedure has been developed for the determination of very low concentrations of nickel in rocks and minerals. Sensitivity is 0.01 μ g Ni. Accuracy and precision is estimated to be ±5 percent to levels as low as 0.1 μ g Ni a marked improvement over other analytical techniques. Samples are irradiated, combined with nickel carrier, and treated by a series of chemical procedures: (1) collection of nickel in a lead bead using a fire-assay technique, (2) refusion of the lead bead and precipitation of basic element hydroxides, (3) anion-exchange chromatography, and (4) precipitation of nickel dimethylglyoxime. The nickel precipitate is weighed to determine chemical yield and counted for β activity of Ni 65 along with a precipitate from irradiated nickel standard solution.

Journal of Research of the U.S. Geological Survey↗
USGS2008

Temporal variation and the effect of rainfall on metals flux from the historic Beatson mine, Prince William Sound, Alaska, USA

Several abandoned Cu mines are located along the shore of Prince William Sound, AK, where the effect of mining-related discharge upon shoreline ecosystems is unknown. To determine the magnitude of this effect at the former Beatson mine, the largest Cu mine in the region and a Besshi-type massive sulfide ore deposit, trace metal concentration and flux were measured in surface run-off from remnant, mineralized workings and waste. Samples were collected from seepage waters; a remnant glory hole which is now a pit lake; a braided stream draining an area of mineralized rock, underground mine workings, and waste piles; and a background location upstream of the mine workings and mineralized rock. In the background stream pH averaged ???7.3, specific conductivity (SC) was ???40 ??S/cm, and the aqueous components indicative of sulfide mineral weathering, SO4 and trace metals, were at detection limits or lower. In the braided stream below the mine workings and waste piles, pH usually varied from 6.7 to 7.1, SC varied from 40 to 120 ??S/cm, SO4 had maximum concentrations of 32 mg/L, and the trace metals Cu, Ni, Pb, and Zn showed maximum total acid extractable concentrations of 186, 5.9, 6.2 and 343 ??g/L, respectively. With an annual rainfall of ???340 cm (estimated from the 2006 water year) it was expected that rain water would have a large effect on the chemistry of the braided stream draining the mine site. A linear mixing model with two end members, seepage water from mineralized rock and background water, estimated that the braided stream contained 10-35% mine drainage. After rain events the braided stream showed a decrease in pH, SC, Ca + Mg, SO4, and alkalinity, due to dilution. The trace metals Ni and Zn followed this same pattern. Sodium + K and Cl did not vary between the background and braided stream, nor did they vary with rainfall. At approximately 2 and 3 mg/L, respectively, these concentrations are similar to concentrations found in rainfall on the coasts of North America. High concentrations of total acid extractable Al and Fe were found at near-neutral pH in most of the waters collected at the site. Equilibrium solubility simulations, performed with PHREEQC, show that the stream waters are saturated with respect to Al, Fe and SiO2 solid phases. Because the "dissolved" sample fractions (acid preserved and filtered to 0.45 ??m) show significant concentrations of Al and Fe it is presumed that these are present as colloids. The relationship between concentrations of Al and Fe, and rainfall was the opposite of that observed for the major ions Ca + Mg, SO4, and alkalinity, in that Al and Fe concentrations increased with increasing rainfall. Concentrations of Cu and Pb followed the same pattern. Adsorption calculations were performed with Visual MINTEQ, using the diffuse double layer electrostatic model and surface complexation constants for the ferrihydrite surface. These results suggest that 30-93% of Cu and 58-97% of Pb was adsorbed to ferrihydrite precipitates in the stream waters. Ni and Zn showed little adsorption in this pH range. Flux calculations show that the total mass of trace metals transported from the mine site, during the 60 day study period, was ranked as Zn (196 kg) > Cu (87 kg) > Pb(1.9 kg) ??? Ni(1.9 kg). Nickel and Zn were transported mostly as dissolved species while Cu and Pb were transported mostly as adsorbed species. pH control on adsorption was evident when Cu and Pb isotherms were normalized by ferrihydrite flux. Decreased stream water pH due to periods of frequent and high volume rain events would cause desorption of Cu and Pb from the ferrihydrite surface, thus changing not only their speciation in solution but also their mechanism of transport. ?? 2007 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗
USGS2007

Mineral resource of the month: phosphate rock

Phosphate rock minerals provide the only significant global resources of phosphorus, which is an essential element for plant and animal nutrition. Phosphate rock is used primarily as a principal component of nitrogen-phosphorus-potassium fertilizers, but also to produce elemental phosphorus and animal feed.

Geotimes↗
USGS1952

Carnotite resources of Outlaw Mesa, Mesa County, Colorado

The U.S. Geological Survey explored Outlaw Mesa for carnotite deposits from 1949 through 1951 with 1,302 diamond-drill holes that totaled 222,150 feet. Total production from Outlaw Mesa from 1914 through 1951 was about 30,000 short tons of carnotite ore, having an estimated grade of about 0.40 percent U3O8 and 1.7 percent V205. The known carnotite deposits are in a number of sandstone lenses in the upper part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are mainly impregnations of sandstone by carnotite and vanadium-bearing clay minerals. Commonly, the deposits are irregular tabular layers or pod-like or crescentic masses ("rolls") connected by thin layers of mineralized rock. The deposits and rolls have a dominant northeasterly trend. Useful criteria for recognizing-sandstone that might contain mineralized rock are: (1) thick, light-brown sandstone, (2) gray mudstone at the base of and in this sandstone, and (3) abundant carbonaceous material. The indicated and inferred reserves of carnotite-bearing material, and the pounds of contained U308 and V205 are summarized in table 1. Potential reserves, whose existence is based on geologic evidence alone, are estimated to total about 80,000 short tones, averaging about 0.35 percent U308 and 1.5percent V205. No further exploration by the Geological Survey is planned; however, additional drilling by private operators is recommended, particularly in ground underlain by mineralized rock.

Colorado↗