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The quality of our Nation’s waters: Quality of water from public-supply wells in the United States, 1993–2007: Overview of major findings

Summary of Major Findings and Implications About 105 million people in the United States-more than one-third of the Nation's population-receive their drinking water from about 140,000 public water systems that use groundwater as their source. Although the quality of finished drinking water (after treatment and before distribution) from these public water systems is regulated by the U.S. Environmental Protection Agency (USEPA) under the Safe Drinking Water Act (SDWA), long-term protection and management of groundwater, a vital source of drinking water, requires an understanding of the occurrence of contaminants in untreated source water. Sources of drinking water are potentially vulnerable to a wide range of man-made and naturally occurring contaminants, including many that are not regulated in drinking water under the SDWA. In this study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS), chemical water-quality conditions were assessed in source (untreated) groundwater from 932 public-supply wells, hereafter referred to as public wells, and in source and finished water from a subset of 94 wells. The public wells are located in selected parts of 41 states and withdraw water from parts of 30 regionally extensive water-supply aquifers, which constitute about one-half of the principal aquifers in the United States. Although the wells sampled in this study represent less than 1 percent of all groundwater-supplied public water systems in the United States, they are widely distributed nationally and were randomly selected within the sampled hydrogeologic settings to represent typical aquifer conditions. All source-water samples were collected prior to any treatment or blending that potentially could alter contaminant concentrations. As a result, the sampled groundwater represents the quality of the source water and not necessarily the quality of finished water ingested by the people served by these public wells. A greater number of chemical contaminants-as many as 337-both naturally occurring and man-made, were assessed in this study than in any previous national study of public wells (Appendixes 1 and 2). Consistent with the terminology used in the SDWA, all constituents analyzed in water samples in this study are referred to as 'contaminants,' regardless of their source, concentration, or potential for health effects (see sidebar on page 3). Eighty-three percent (279) of the contaminants analyzed in this study are not regulated in drinking water under the SDWA. The USEPA uses USGS data on the occurrence of unregulated contaminants to fulfill part of the SDWA requirements for determining whether specific contaminants should be regulated in drinking water in the future. By focusing primarily on source-water quality, and by analyzing many contaminants that are not regulated in drinking water by USEPA, this study complements the extensive sampling of public water systems that is routinely conducted for the purposes of regulatory compliance monitoring by federal, state, and local drinking-water programs. The objectives of this study were to evaluate (1) the occurrence of contaminants in source water from public wells and their potential significance to human health, (2) whether contaminants that occur in source water also occur in finished water after treatment, and (3) the occurrence and characteristics of contaminant mixtures. To evaluate the potential significance of contaminant occurrence to human health, contaminant concentrations were compared to regulatory Maximum Contaminant Levels (MCLs) or non-regulatory Health-Based Screening Levels (HBSLs)-collectively referred to as human-health benchmarks in this study (see sidebars on pages 4 and 19). The major findings and implications of this study are summarized below and the results are described in greater detail in the remainder of the report. These findings build upon water-quality data from previous public-well studies and

Circular

Assessing the Vulnerability of Public-Supply Wells to Contamination: Central Valley Aquifer System near Modesto, California

This fact sheet highlights findings from the vulnerability study of a public-supply well in Modesto, California. The well selected for study pumps on average about 1,600 gallons per minute from the Central Valley aquifer system during peak summer demand. Water samples were collected at the public-supply well and at monitoring wells installed in the Modesto vicinity. Samples from the public-supply wellhead contained the undesirable constituents uranium, nitrate, arsenic, volatile organic compounds (VOCs), and pesticides, although none were present at concentrations exceeding drinking-water standards. Of these contaminants, uranium and nitrate pose the most significant water-quality risk to the public-supply well because human activities have caused concentrations in groundwater to increase over time. Overall, study findings point to four primary factors that affect the movement and (or) fate of contaminants and the vulnerability of the public-supply well in Modesto: (1) groundwater age (how long ago water entered, or recharged, the aquifer); (2) irrigation and agricultural and municipal pumping that drives contaminants downward into the primary production zone of the aquifer; (3) short-circuiting of contaminated water down the public-supply well during the low-pumping season; and (4) natural geochemical conditions of the aquifer. A local-scale computer model of groundwater flow and transport to the public-supply well was constructed to simulate long-term nitrate and uranium concentrations reaching the well. With regard to nitrate, two conflicting processes influence concentrations in the area contributing recharge to the well: (1) Beneath land that is being farmed or has recently been farmed (within the last 10 to 20 years), downward-moving irrigation waters contain elevated nitrate concentrations; yet (2) the proportion of agricultural land has decreased and the proportion of urban land has increased since 1960. Urban land use is associated with low nitrate concentrations in recharge (3.1 milligrams per liter). Results of the simulation indicate that nitrate concentrations in the public-supply well peaked in the late 1990s and will decrease slightly from the current level of 5.5 milligrams per liter during the next 100 years. A lag time of 20 to 30 years between peak nitrate concentrations in recharge and peak concentrations in the well is the result of the wide range of ages of water reaching the public-supply well combined with changing nitrogen input concentrations over time. As for uranium, simulation results show that concentrations in the public-supply well will likely approach the Maximum Contaminant Level of 30 micrograms per liter over time; however, it will take more than 100 years because of the contribution of old water at depth in the public-supply well that dilutes uranium concentrations in shallower water entering the well. This allows time to evaluate management strategies and to alter well-construction or pumping strategies to prevent uranium concentrations from exceeding the drinking-water standard.

Fact Sheet

Assessing the vulnerability of public-supply wells to contamination: Glacial aquifer system in Woodbury, Connecticut

This fact sheet highlights findings from the vulnerability study of a public-supply well in Woodbury, Connecticut. The well typically produces water at the rate of 72 gallons per minute from the glacial aquifer system in the Pomperaug River Basin. Water samples were collected at the public-supply well and at monitoring wells installed in or near the simulated zone of contribution to the supply well. Samples of untreated water from the public-supply wellhead contained several types of undesirable constituents, including 11 volatile organic compounds (VOCs), nitrate, pesticides, uranium, and radon. Most of these constituents were detected at concentrations below drinking-water standards, where such standards exist. Only concentrations of the VOC trichlorethylene exceeded the Maximum Contaminant Level (MCL) of 5 micrograms per liter (ug/L) established by U.S. Environmental Protection Agency for drinking water. Radon concentrations exceeded a proposed-but not finalized-MCL of 300 picocuries per liter (pCi/L). Overall, the study findings point to four main factors that affect the movement and fate of contaminants and the vulnerability of the public-supply well in Woodbury: (1) groundwater age (how long ago water entered, or recharged, the aquifer); (2) the percentage of recharge received through urban areas; (3) the percentage of recharge received through dry wells and their proximity to the public-supply well; and (4) natural geochemical processes occurring within the aquifer system; that is, processes that affect the amounts and distribution of chemical substances in aquifer sediments and groundwater. A computer-model simulation of groundwater flow to the public-supply well was used to estimate the age of water particles entering the well along the length of the well screen. About 90 percent of the simulated flow to the well consists of water that entered the aquifer 9 or fewer years ago. Such young water is vulnerable to contaminants resulting from human activities, as indicated by the solvents, fuel components, road salt, and septic-system leachate that were detected in the glacial aquifer system during the current study. Age-dating combined with chemical modeling suggests that less than 2 percent of water produced by the public-supply well is water from the deep bedrock that is "old" (water that recharged, or entered, the aquifer before 1952). Such a small percentage of old groundwater entering the public-supply well offers little potential for dilution of young waters containing contaminants from human activities. Shallow groundwater that originated as recharge through urban areas generally had higher median concentrations and more detections of volatile organic compounds (VOCs) than did groundwater from the deep glacial deposits or fractured bedrock that originated mainly as recharge through agricultural and undeveloped land. Shallow groundwater was also found to be affected by road salt and septic-system leachate. A chemical mixing model indicates that up to 15 percent of nitrate in water from the supply well is likely from septic-system leachate. The Connecticut Department of Public Health has identified several potential sources of contamination in the commercial area of Woodbury (several light industrial or commercial properties where hazardous materials and petroleum products are used and stored). To reduce stormwater runoff in the commercial area, water from the parking lots and pavement is channeled into dry wells-drains that shunt water directly into the aquifer system, bypassing the soil and unsaturated zones. A computer-model simulation of groundwater flow indicates that approximately 16 percent of the water produced by the public-supply well is derived from runoff captured by these drains. Traveltime for water from the dry wells to the public-supply well ranges from about 1.5 to less than 4 years. Dry wells have the potential to enhance contaminant movement to the supply well, suggesting that stormwater-control methods cannot be considered separately from groundwater quality—they are linked. Water-quality protection in this setting depends on the entire community. If residents and businesses take steps to reduce input of manmade contaminants to groundwater, a positive effect on quality of the supply-well water might begin to be seen in less than 10 years, owing to the short residence time of water in the aquifer.

Connecticut

Public-supply water use in Florida, 1990

In 1990, public supply withdrawals represented nearly 26 percent of the total freshwater withdrawn in Florida. Total water withdrawn for public supply in Florida during 1990 averaged 1,925 million gal/day. Public suppliers served 11.23 million residents, in 1990. Groundwater was the source for more than 88 percent (1,699 million gal/day) of public-supply withdrawals and was used by more than 10.0 million residents; surface water was the source of the remaining 12 percent (226 million gal/day) and was used by about 1.2 million residents. The Floridan aquifer system was the source of the majority of groundwater in 1990 (50 percent), followed by the Biscayne aquifer (34 percent). Public-supply water withdrawals peaked in May 1990 at 2,140 million gal/day, primarily because of an increase in the residential demands for lawn irrigation. During 1990, withdrawals for January were lowest (1,870 million gal/day), nearly 270 million gal/day less than in May. Public-supply per capita use for Florida in 1990 was 171 gal/day and domestic (residential) per capita use was 111 gal/day. The population of Florida increased from 9.75 million in 1980 to more than 12.94 million in 1990, and the percentage of the population served by public supply increased from 80 percent in 1980 to 87 percent in 1990. Public-supply water with- drawals in Florida increased 41 percent between 1980 and 1990 even though public supply per capita use has remained fairly consistent since 1980. Public water suppliers in Dade County withdrew the largest amount of water (326 million gal/day) for public supply in the State for 1990 and served nearly 1.88 million people. (USGS)

Open-File Report

The quality of our Nation's waters: factors affecting public-supply-well vulnerability to contamination: understanding observed water quality and anticipating future water quality

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the vulnerability of water from public-supply wells to contamination (referred to hereafter as “public-supply-well vulnerability”). The study was designed as a follow-up to earlier NAWQA studies that found mixtures of contaminants at low concentrations in groundwater near the water table in urban areas across the Nation and, less frequently, in deeper groundwater typically used for public supply. Beside the factors affecting public-supply-well vulnerability to contamination, this circular describes measures that can be used to determine which factor (or factors) plays a dominant role at an individual public-supply well. Case-study examples are used throughout to show how such information can be used to improve water quality. In general, the vulnerability of the water from public-supply wells to contamination is a function of contaminant input within the area that contributes water to a well, the mobility and persistence of a contaminant once released to the groundwater, and the ease of groundwater and contaminant movement from the point of recharge to the open interval of a well. The following measures described in this circular are particularly useful for indicating which contaminants in an aquifer might reach an individual public-supply well and when, how, and at what concentration they might arrive: * Sources of recharge—Information on the sources of recharge for a well provides insight into contaminants that might enter the aquifer with the recharge water and potentially reach the well. * Geochemical conditions—Information on the geochemical conditions encountered by groundwater traveling to a well provides insight into contaminants that might persist in the water all the way to the well. * Groundwater-age mixtures—Information on the ages of the different waters that mix in a well provides insight into the time lag between contaminant input at the water table and contaminant arrival at the well. It also provides insight into the potential for in-well dilution of contaminated water by unaffected groundwater of a different age that simultaneously enters the well. Preferential flow pathways—pathways that provide little resistance to flow—can influence how all other factors affect public-supply-well vulnerability to contamination. For example, preferential flow pathways can influence whether a contaminant source is physically linked to a well, whether contaminant concentrations are substantially altered before contaminated groundwater reaches a well, and whether contaminated groundwater can arrive at a well within a timeframe of concern to the well owner. Methods for recognizing the influence of preferential flow pathways on the quality of water from a public-supply well are presented in this circular and can provide opportunities to prevent or mitigate the deterioration of a water supply. Knowing what water-quality variables to measure, what spatial and temporal scales on which to measure them, and how to interpret the resulting data makes it possible for samples from public-supply wells to provide a broad window into a well’s past and present water quality—and possibly future water quality. Such insight can enable resource managers to prioritize actions for sustaining a high-quality groundwater source of drinking water.

Circular

Publications of the Western Earth Surface Processes Team 2002

The Western Earth Surface Processes Team (WESPT) of the U.S. Geological Survey (USGS) conducts geologic mapping and related topical earth science studies in the western United States. This work is focused on areas where modern geologic maps and associated earth-science data are needed to address key societal and environmental issues such as ground-water quality, landslides and other potential geologic hazards, and land-use decisions. Areas of primary emphasis in 2001 included southern California, the San Francisco Bay region, the Pacific Northwest, and the Las Vegas urban corridor. The team has its headquarters in Menlo Park, California, and maintains smaller field offices at several other locations in the western United States. The results of research conducted by the WESPT are released to the public as a variety of databases, maps, text reports, and abstracts, both through the internal publication system of the USGS and in diverse external publications such as scientific journals and books. This report lists publications of the WESPT released in 2002 as well as additional 1998 and 2001 publications that were not included in the previous list (USGS Open-File Report 00-215, USGS Open-File Report 01-198, and USGS Open-File Report 02-269). Most of the publications listed were authored or coauthored by WESPT staff. The list also includes some publications authored by non-USGS cooperators with the WESPT, as well as some authored by USGS staff outside the WESPT in cooperation with WESPT projects. Several of the publications listed are available on the World Wide Web; for these, URL addresses are provided. Many of these web publications are USGS open-file reports that contain large digital databases of geologic map and related information. Information on ordering USGS publications can be found on the World Wide Web or by calling 1-888-ASK-USGS. The U.S. Geological Survey’s web server for geologic information in the western United States is located at http://geology.wr.usgs.gov. More information is available about the WESPT is available on-line at the team website.

Open-File Report

Publications of the Western Earth Surfaces Processes Team 2005

Introduction The Western Earth Surface Processes Team (WESPT) of the U.S. Geological Survey (USGS) conducts geologic mapping, earth-surface process investigations, and related topical earth science studies in the western United States. This work is focused on areas where modern geologic maps and associated earth-science data are needed to address key societal and environmental issues such as ground-water quality, landslides and other potential geologic hazards, and land-use decisions. Areas of primary emphasis in 2005 included southern California, the San Francisco Bay region, the Mojave Desert, the Colorado Plateau region of northern Arizona, and the Pacific Northwest. The team has its headquarters in Menlo Park, California, and maintains smaller field offices at several other locations in the western United States. The results of research conducted by the WESPT are released to the public as a variety of databases, maps, text reports, and abstracts, both through the internal publication system of the USGS and in diverse external publications such as scientific journals and books. This report lists publications of the WESPT released in 2005 as well as additional 2002, 2003, and 2004 publications that were not included in the previous lists (USGS Open-File Reports 03-363, 2004- 1267, 2005-1362). Most of the publications listed were authored or coauthored by WESPT staff. The list also includes some publications authored by non-USGS cooperators with the WESPT, as well as some authored by USGS staff outside the WESPT in cooperation with WESPT projects. Several of the publications listed are available on the World Wide Web; for these, URL addresses are provided. Many of these web publications are USGS Open-File reports that contain large digital databases of geologic map and related information. Information on ordering USGS publications can be found on the World Wide Web at http://www.usgs.gov/pubprod/, or by calling 1-888-ASK-USGS. The U.S. Geological Survey's web server for geologic information in the western United States is located at http://geology.wr.usgs.gov/. More information is available about the WESPT is available on-line at http://geology.wr.usgs.gov/wgmt.

Open-File Report

Chemical Characteristics, Water Sources and Pathways, and Age Distribution of Ground Water in the Contributing Recharge Area of a Public-Supply Well near Tampa, Florida, 2002-05

In 2001, the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey began a series of studies on the transport of anthropogenic and natural contaminants (TANC) to public-supply wells. The main goal of the TANC program was to better understand the source, transport, and receptor factors that control contaminant movement to public-supply wells in representative aquifers of the United States. Studies were first conducted at regional scales at four of the eight TANC study areas during 2002-03 and at small (local) scales during 2003-05 in California, Nebraska, Connecticut, and Florida. In the Temple Terrace study area near Tampa, Florida, multiple chemical indicators and geochemical and ground-water flow modeling techniques were used to assess the vulnerability of a public-supply well in the karstic Upper Floridan aquifer to contamination from anthropogenic and naturally occurring contaminants. During 2003-05, water samples were collected from the public-supply well and 13 surrounding monitoring wells that all tap the Upper Floridan aquifer, and from 15 monitoring wells in the overlying surficial aquifer system and the intermediate confining unit that are located within the modeled ground-water contributing recharge area of the public-supply well. Six volatile organic compounds and four pesticides were detected in trace concentrations (well below drinking-water standards) in water from the public-supply well, which had an open interval from 36 to 53 meters below land surface. These contaminants were detected more frequently in water samples from monitoring wells in the overlying clastic surficial aquifer system than in water from monitoring wells in the Upper Floridan aquifer in the study area. Likewise, nitrate-N concentrations in the public-supply well (0.72-1.4 milligrams per liter) were more similar to median concentrations in the oxic surficial aquifer system (2.1 milligrams per liter) than to median nitrate-N concentrations in the anoxic Upper Floridan aquifer (0.06 milligram per liter) under sulfate-reducing conditions. High concentrations of radon-222 and uranium in the public-supply well compared to those in monitoring wells in the Upper Floridan aquifer appear to originate from water moving downward through sands and discontinuous clay lenses that overlie the aquifer. Water samples also were collected from three overlapping depth intervals (38-53, 43-53, and 49-53 meters below land surface) in the public-supply well. The 49- to 53-meter interval was identified as a high-flow zone during geophysical logging of the wellbore. Water samples were collected from these depth intervals at a low pumping rate by placing a low-capacity submersible pump (less than 0.02 cubic meter per minute) at the top of each interval. To represent higher pumping conditions, a large-capacity portable submersible pump (1.6 cubic meters per minute) was placed near the top of the open interval; water-chemistry samples were collected using the low-capacity submersible pump. The 49- to 53-meter depth interval had distinctly different chemistry than the other two sampled intervals. Higher concentrations of nitrate-N, atrazine, radon, trichloromethane (chloroform), and arsenic (and high arsenic (V)/arsenic (III) ratios); lower concentrations of dissolved solids, strontium, iron, manganese, and lower nitrogen and sulfur isotope ratios were found in this highly transmissive zone in the limestone than in water from the two other depth intervals. Movement of water likely occurs from the overlying sands and clays of the oxic surficial aquifer system and intermediate confining unit (that contains high radon-222 and nitrate-N concentrations) into the anoxic Upper Floridan aquifer (that contains low radon-222 and nitrate-N concentrations). Differences in arsenic concentrations in water from the various depth intervals in the public-supply well (3.2-19.0 micrograms per liter) were related to pumping conditions. The high arsenic

Scientific Investigations Report

Simulations of ground-water flow and particle pathline analysis in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California

Shallow ground water in the eastern San Joaquin Valley is affected by high nitrate and uranium concentrations and frequent detections of pesticides and volatile organic compounds (VOC), as a result of ground-water development and intensive agricultural and urban land use. A single public-supply well was selected for intensive study to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Modesto area. A network of 23 monitoring wells was installed, and water and sediment samples were collected within the approximate zone of contribution of the public-supply well, to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state local ground-water-flow and transport model was developed to evaluate the age of ground water reaching the well and to evaluate the vulnerability of the well to nonpoint source input of nitrate and uranium. Particle tracking was used to compute pathlines and advective travel times in the ground-water flow model. The simulated ages of particles reaching the public-supply well ranged from 9 to 30,000 years, with a median of 54 years. The age of the ground water contributed to the public-supply well increased with depth below the water table. Measured nitrate concentrations, derived primarily from agricultural fertilizer, were highest (17 milligrams per liter) in shallow ground water and decreased with depth to background concentrations of less than 2 milligrams per liter in the deepest wells. Because the movement of water is predominantly downward as a result of ground-water development, and because geochemical conditions are generally oxic, high nitrate concentrations in shallow ground water are expected to continue moving downward without significant attenuation. Simulated long-term nitrate concentrations indicate that concentrations have peaked and will decrease in the public-supply well during the next 100 years because of the low nitrate concentrations in recharge beneath the urban area and the increasing proportion of urban-derived ground water reaching the well. The apparent lag time between peak input concentrations and peak concentrations in the well is about 20 to 30 years. Measured uranium concentrations were also highest (45 micrograms per liter) in shallow ground water, and decreased with depth to background concentrations of about 0.5 microgram per liter. Naturally-occurring uranium adsorbed to aquifer sediments is mobilized by oxygen-rich, high-alkalinity water. Alkalinity increased in shallow ground water in response to agricultural development. As ground-water pumping increased in the 1940s and 1950s, this alkaline water moved downward through the ground-water flow system, mobilizing the uranium adsorbed to aquifer sediments. Ground water with high alkalinity and high uranium concentrations is expected to continue to move deeper in the system, resulting in increased uranium concentrations with depth in ground water. Because alkalinity (and correspondingly uranium) concentrations were high in shallow ground water beneath both the urban and the agricultural land, long-term uranium concentrations in the public-supply well are expected to increase as the proportion of uranium-affected water contributed to the well increases. Assuming that the alkalinity near the water table remains the same, the simulation of long-term alkalinity in the public-supply well indicates that uranium concentrations in the public-supply well will likely approach the maximum contaminant level; however, the time to reach this level is more than 100 years because of the significant proportion of old, unaffected water at depth that is contributed to the public-supply well.

California

Simulations of Groundwater Flow and Particle Tracking Analysis in the Area Contributing Recharge to a Public-Supply Well near Tampa, Florida, 2002-05

Shallow ground water in the north-central Tampa Bay region, Florida, is affected by elevated nitrate concentrations, the presence of volatile organic compounds, and pesticides as a result of groundwater development and intensive urban land use. The region relies primarily on groundwater for drinking-water supplies. Sustainability of groundwater quality for public supply requires monitoring and understanding of the mechanisms controlling the vulnerability of public-supply wells to contamination. A single public-supply well was selected for intensive study based on the need to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Upper Floridan aquifer in the City of Temple Terrace near Tampa, Florida, and the presence of a variety of chemical constituents in water from the well. A network of 29 monitoring wells was installed, and water and sediment samples were collected within the area contributing recharge to the selected public-supply well to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state groundwater flow model was developed to evaluate the age of groundwater reaching the well and to test hypotheses on the vulnerability of the well to nonpoint source input of nitrate. Particle tracking data were used to calculate environmental tracer concentrations of tritium and sulfur hexafluoride and to calibrate traveltimes and compute flow paths and advective travel times in the model area. The traveltime of particles reaching the selected public-supply well ranged from less than 1 day to 127.0 years, with a median of 13.1 years; nearly 45 percent of the simulated particle ages were less than about 10 years. Nitrate concentrations, derived primarily from residential/commercial fertilizer use and atmospheric deposition, were highest (2.4 and 6.11 milligrams per liter as nitrogen, median and maximum, respectively) in shallow groundwater from the surficial aquifer system and lowest (less than the detection level of 0.06 milligram per liter) in the deeper Upper Floridan aquifer. Denitrification occurred near the interface of the surficial aquifer system and the underlying intermediate confining unit, within the intermediate confining unit, and within the Upper Floridan aquifer because of reducing conditions in this part of the flow system. However, simulations indicate that the rapid movement of water from the surficial aquifer system to the selected public-supply well through karst features (sinkholes) and conduit layers that bypass the denitrifying zones (short-circuits), coupled with high pumping rates, allow nitrate to reach the selected public-supply well in concentrations that resemble those of the overlying surficial aquifer system. Water from the surficial aquifer system with elevated concentrations of nitrate and low concentrations of some volatile organic compounds and pesticides is expected to continue moving into the selected public-supply well, because calculated flux-weighted concentrations indicate the proportion of young affected water contributing to the well is likely to remain relatively stable over time. The calculated nitrate concentration in the selected public-supply well indicates a lag of 1 to 10 years between peak concentrations of nonpoint source contaminants in recharge and appearance in the well.

Scientific Investigations Report

Comparison of nitrate, pesticides, and volatile organic compounds in samples from monitoring and public-supply wells, Kirkwood-Cohansey aquifer system, southern New Jersey

The number and total concentration of volatile organic compounds (VOCs) per sample were significantly greater in water from public-supply wells than in water from shallow and moderate-depth monitoring wells in the surficial Kirkwood-Cohansey aquifer system in the Glassboro area of southern New Jersey. In contrast, concentrations of nitrate (as nitrogen) and the number and total concentration of pesticides per sample were statistically similar in samples from shallow and moderate-depth monitoring wells and those from public-supply wells. VOCs in ground water typically are derived from point sources, which commonly exist in urban areas and which result in spatially variable contaminant concentrations near the water table. Because larger volumes of water are withdrawn from public-supply wells than from monitoring wells, their contributing areas are larger and, therefore, they are more likely to intercept water flowing from VOC point sources. Additionally, public-supply wells intercept flow paths that span a large temporal interval. Public-supply wells in the Glassboro study area withdraw water flowing along short paths, which contains VOCs that recently entered the aquifer system, and water flowing along relatively long paths, which contains VOCs that originated from the degradation of parent compounds or that are associated with past land uses. Because the volume of water withdrawn from monitoring wells is small and because shallow monitoring wells are screened near the water table, they generally intercept only relatively short flow paths. Therefore, samples from these wells represent relatively recent, discrete time intervals and contain both fewer VOCs and a lower total VOC concentration than samples from public-supply wells. Nitrate and pesticides in ground water typically are derived from nonpoint sources, which commonly are found in both agricultural and urban areas and typically result in lowlevel, relatively uniform concentrations near the water table. Because nonpoint sources are diffuse and because processes such as degradation or sorption/dispersion do not occur at rates sufficient to prevent detection of these constituents in parts of the aquifer used for domestic and public supply in the study area, concentrations of nitrate and pesticides and numbers of pesticide compounds are likely to be similar in samples from shallow monitoring wells and samples from public-supply wells. Results of a comparison of (1) the general characteristics of, and water-quality data from, public-supply wells in the Glassboro study area to available data from public-supply wells screened in the Kirkwood-Cohansey aquifer system outside the study area, and (2) land-use settings, soil characteristics, and aquifer properties in and outside the study area indicate that the findings of this study likely are applicable to the entire extent of the Kirkwood- Cohansey aquifer system in southern New Jersey.

New Jersey

Quantifying the substantive influence of public comment on United States federal environmental decisions under NEPA

A citizen’s right to comment on, and criticize, government decisions makes a difference. The U.S. National Environmental Policy Act of 1969 (NEPA) institutionalized public engagement in environmental review in the belief it would lead to better decisions and more sustainable outcomes. But, 50 years later, NEPA’s public comment process has been criticized as costly and slow, while doing little to change outcomes. Data science now makes it possible to track progress and evaluate the influence of public participation. We examined 108 environmental impact statement (EIS) processes spanning 22 years. Our analysis revealed that public comments resulted in substantive decision alterations in 62% of cases, with 64% showing modifications to alternatives, 42% showing modifications to mitigation plans and 11% leading to the selection of an entirely new preferred alternative. When federal agencies changed project alternatives (78 EISs), 88% of the time (69 of the 78 EISs) they credited public comments as the reason. In 45 of the 108 EISs, agencies modified mitigation plans and credited public comments as the reason 100% of the time. Agencies only occasionally selected a new preferred alternative (21 out of 104 EISs), but when they did, they credited public comments as the reason 100% of the time. As the United States and the 190+ states and countries that have adopted NEPA’s example consider how to address environmental change, it is important to assess the role of public participation in environmental decision making. Our data say public comments matter.

Environmental Research Letters

Assessing the vulnerability of public-supply wells to contamination—High Plains Aquifer near York, Nebraska

The U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program found, in studies from 1991 to 2001, low levels of mixtures of contaminants in ground water near the water table in urban areas across the Nation. Although contaminants were detected less frequently in deeper ground water typically developed for public supply the proximity of contaminant mixtures to underlying public-water-supply sources prompted the NAWQA Program to begin, in 2001, an intensive study to assess the vulnerability of public-supply wells to contamination. As part of this study, the pathways and processes by which contaminants reach public-supply wells in nine aquifer systems across the country are being investigated. In addition to studying the processes that occur below land surface—whereby contaminants are mobilized or attenuated—scientists are also investigating how human activities can affect the vulnerability of public-supply wells to contamination. This fact sheet highlights findings from two reports on the vulnerability study of a single, representative public-supply well in York, Nebraska. The selected high-capacity well typically produces more than 720,000 gallons per day from the upper confined aquifer of the High Plains aquifer. A possible source of contamination to the well is intensive, irrigated agriculture, which can sometimes result in elevated concentrations of nitrate and pesticides in ground water. In addition, a sampling of the selected public-supply well by the USGS in 2002 found low concentrations of the solvents trichloroethylene (TCE), tetrachloroethylene (PCE), and their degradation products, which may be linked to historical chemical use in urban and residential areas of York. Uranium and arsenic (which occur naturally in the sediments that make up the aquifers in the area) also were detected in 2002 at concentrations less than drinking-water standards but still of concern. Overall, the current NAWQA study found that three primary factors affect the movement and fate of contaminants and the vulnerability of the public-supply well in York: (1) timing of water entry (recharge) to the aquifer, (2) short-circuiting of natural flow paths through inactive wells, and (3) natural geochemical conditions of the aquifer. Study findings are intended to help water managers, drinking-water suppliers, policymakers, and scientists to better understand how and why contamination of public-supply wells occurs and whether water quality may improve or degrade. Additionally, study findings may be used to evaluate various pumping, resource-development, and land-management scenarios.

Fact Sheet

Assessing the vulnerability of public-supply wells to contamination—Edwards aquifer near San Antonio, Texas

This fact sheet highlights findings from the vulnerability study of a public-supply well field in San Antonio, Texas. The well field consists of six production wells that tap the Edwards aquifer. Typically, one or two wells are pumped at a time, yielding an average total of 20-21 million gallons per day. Water samples were collected from public-supply wells in the well field and from monitoring wells installed along general directions of flow to the well field. Samples from the well field contained some constituents of concern for drinking-water quality, including nitrate; the pesticide compounds atrazine, deethylatrazine, and simazine; and the volatile organic compounds tetrachloroethene (also called perchloroethene, or PCE), chloroform, bromoform, and dibromochloromethane. These constituents were detected in untreated water at concentrations much less than established drinking-water standards, where such standards exist. Overall, the study findings point to four primary factors that affect the movement and fate of contaminants and the vulnerability of the public-supply well field in San Antonio, Texas: (1) groundwater age (how long ago water entered, or recharged, the aquifer), (2) fast pathways for flow of groundwater through features formed or enlarged by dissolution of bedrock, (3) recharge characteristics of the aquifer, and (4) natural geochemical processes within the aquifer. A computer-model simulation of groundwater flow and transport was used to estimate the traveltime (or age) of water particles entering public-supply well W4 in the well field. Modeled findings show that almost half of the water reaching the public-supply well is less than 2 years old. Such a large percentage of very young water indicates that (1) contaminants entering the aquifer may be transported rapidly to the well, (2) there is limited time for chemical reactions to occur in the aquifer that may attenuate contaminants, and (3) should recharge water become contaminated with pathogenic microorganisms (which have limited survival times in aquifers), the microorganisms may be able to persist to the well. Features formed or enlarged by dissolution of bedrock allow most of the water reaching the well field to travel rapidly from the recharge zone to the supply wells along fast pathways rather than through the aquifer matrix. Supporting evidence includes (1) geophysical logging and flowmeter measurements in public-supply well W4 and in nearby monitoring wells showing that most of the flow volume into and out of the wells occurs in three horizontal zones, thought to be dissolution-enlarged bedding planes; and (2) fluctuations in groundwater chemistry that can be correlated to individual precipitation events. Analysis of water samples collected from shallow, intermediate, and deep zones of the Edwards aquifer at public-supply well W4 and from nearby monitoring wells reveal that water in the vicinity of the selected well field is notably well mixed throughout the sampled thickness of the Edwards aquifer, showing little of the chemical variation with depth that is commonly seen in other aquifers. Contaminants were found at all depths, and they did not enter the well through a specific horizon. The well-mixed nature of the Edwards aquifer is caused by the recharge characteristics of the area combined with fast flow paths through karst features. Constituents of concern in the Edwards aquifer for the long-term sustainability of the groundwater resource include the nutrient nitrate and anthropogenic contaminants such as atrazine, PCE, and chloroform. A scenario of hypothetical contaminant loading in the aquifer recharge zone was evaluated by using results from groundwater-flow-model particle tracking to assess the response of the aquifer to potential contamination. Results indicate that the concentrations at public-supply well W4 would begin to respond to contaminant loading in the recharge zone within 1 year because of short traveltimes through fast flow paths. Within 10 years, contaminant concentrations in the public-supply well would be equal to 90 percent of the input concentration for a contaminant (such as nitrate) that does not degrade in the oxic conditions of the Edwards aquifer.

Texas

Publications of the Western Earth Surface Processes Team 2000

The Western Earth Surface Processes Team (WESP) of the U.S. Geological Survey (USGS) conducts geologic mapping and related topical earth science studies in the western United States. This work is focused on areas where modern geologic maps and associated earth-science data are needed to address key societal and environmental issues such as ground-water quality, potential geologic hazards, and land-use decisions. Areas of primary emphasis in 2000 included southern California, the San Francisco Bay region, the Pacific Northwest, the Las Vegas urban corridor, and selected National Park lands. The team has its headquarters in Menlo Park, California, and maintains smaller field offices at several other locations in the western United States. The results of research conducted by the WESPT are released to the public as a variety of databases, maps, text reports, and abstracts, both through the internal publication system of the USGS and in diverse external publications such as scientific journals and books. This report lists publications of the WESPT released in 2000 as well as additional 1999 publications that were not included in the previous list (USGS Open-file Report 00-215). Most of the publications listed were authored or coauthored by WESPT staff. The list also includes some publications authored by non-USGS cooperators with the WESPT, as well as some authored by USGS staff outside the WESPT in cooperation with WESPT projects. Several of the publications listed are available on the World Wide Web; for these, URL addresses are provided. Many of these Web publications are USGS open-file reports that contain large digital databases of geologic map and related information.

Open-File Report

Publications of Western Earth Surface Processes Team 2001

The Western Earth Surface Processes Team (WESPT) of the U.S. Geological Survey (USGS) conducts geologic mapping and related topical earth-science studies in the Western United States. This work is focused on areas where modern geologic maps and associated earth-science data are needed to address key societal and environmental issues, such as ground-water quality, landslides and other potential geologic hazards, and land-use decisions. Areas of primary emphasis in 2001 included southern California, the San Francisco Bay region, the Pacific Northwest, and the Las Vegas urban corridor. The team has its headquarters in Menlo Park, California, and maintains smaller field offices at several other locations in the Western United States. The results of research conducted by the WESPT are released to the public as a variety of databases, maps, text reports, and abstracts, both through the internal publication system of the USGS and in diverse external publications such as scientific journals and books. This report lists publications of the WESPT released in 2001, as well as additional 1999 and 2000 publications that were not included in the previous list (USGS Open-File Report 00–215 and USGS Open-File Report 01–198). Most of the publications listed were authored or coauthored by WESPT staff. The list also includes some publications authored by non-USGS cooperators with the WESPT, as well as some authored by USGS staff outside the WESPT in cooperation with WESPT projects. Several of the publications listed are available on the World Wide Web; for these, URL addresses are provided. Many of these web publications are USGS Open-File Reports that contain large digital databases of geologic map and related information.

Open-File Report

Public supply and domestic water use in the United States, 2015

Introduction The U.S. Geological Survey (USGS) National Water Use Science Project (NWUSP), part of the USGS Water Availability and Use Science Program (WAUSP), has estimated water use in the United States every 5 years since 1950. This report provides an overview of total population, public-supply use, including the population that is served by public-supply systems and the domestic deliveries to those users, and self-supplied domestic water use in the United States for 2015, continuing the task of estimating water use in the United States every 5 years. In this report, estimates for the United States include the 50 States, the District of Columbia, Puerto Rico, and the U.S. Virgin Islands (hereafter referred to as “states” for brevity). County-level data for total population, public-supply withdrawals and the population served by public-supply systems, and domestic withdrawals for 2015 were published in a data release in an effort to provide data to the public in a timely manner. Data in the current version (1.0) of Dieter and others (2017) contains county-level total withdrawals from groundwater and surface-water sources (both fresh and saline) for public-water supply, the deliveries from those suppliers to domestic users, and the quantities of water from groundwater and surface-water sources for self-supplied domestic users, and total population. Methods used to estimate the various data elements for the public-supply and domestic use categories at the county level are described by Bradley (2017). This Open-File Report is an interim report summarizing the data published in Dieter and others (2017) at the state and national level. This report includes discussions on the total population, totals for public-supply withdrawals and population served, total domestic withdrawals, and provides comparisons of the 2015 estimates to 2010 estimates (Maupin and others, 2014). Total domestic water use, as described in this report, represents the summation of deliveries from public-water supply to domestic users plus self-supplied domestic withdrawals. Values for 2010 are the best available data for 2010 from the USGS Aggregate Water-Use Data System (AWUDS). The 2010 values presented in this report may have been revised from 2010 values published in Maupin and others (2014), and therefore values for 2010 in this report may not exactly match values in Maupin and others (2014). Withdrawal and population values in this report are rounded to three significant figures. All values are rounded independently, so the sums of individually rounded numbers may not equal the totals. Percent change is calculated on unrounded data and is expressed as an integer. Differences between 2010 and 2015 values are calculated on unrounded data, then the differences are rounded.

Open-File Report

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report