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Overstorey mortality promotes juvenile piñon pine growth during favourable weather at cooler, wetter sites

Hotter droughts have resulted in widespread tree die-off events globally, frequently leading to regeneration failure. Dry forest recovery often depends on the growth and survival of extant juvenile trees. However, it is unclear how microenvironmental changes following overstorey tree die-off affect juvenile trees, particularly in dryland systems where tree recruitment is typically limited by water availability and heat stress. We simulated an overstorey tree die-off event by girdling trees in piñon-juniper woodlands across the south-western United States. We sampled juvenile piñon pine growth from live and dead overstorey treatments across six study sites spanning a regional latitudinal gradient and local elevational gradients. We examined how juvenile branch and needle growth differed between live and dead overstorey treatments, and whether responses varied with weather conditions and juvenile tree size following overstorey mortality. We found greater juvenile branch and needle growth under dead compared with live overstorey trees for 2 years following overstorey mortality at mid- and high-elevation sites which are typically cooler and wetter than the other sites. These observed growth releases were contingent on favourable post-mortality weather conditions. Higher growth under dead overstorey occurred at sites experiencing near-average climatic water deficits compared with sites experiencing above-average climatic water deficits. Growth at all sites increased from the first to second year after overstorey mortality. Across sites, growth was unrelated to juvenile tree size. Synthesis . Our results underscore differentiation in juvenile responses to overstorey tree die-off driven by local site conditions and weather across the range of Pinus edulis . Overstorey mortality resulted in consistently higher juvenile growth only at climatically favourable sites and during favourable weather, while unmeasured microsite differences could help account for variation observed at the hottest and driest site. Results from less climatically favourable sites suggest that overstorey trees neither directly limit nor facilitate juvenile growth, though further study over longer timeframes is needed to resolve the pace and magnitude of potential recovery or decline. Overall, juvenile vigour may be promoted following overstorey mortality only in a narrow spatial (site) and temporal (weather) environmental context, suggesting additional vulnerabilities for piñon populations under more arid conditions.

Arizona, Colorado

Geochemistry and Soils of the Big Smoky Valley Fens, Nevada

Fens are groundwater-fed wetlands that can provide habitat for plants and animals. Due to anthropogenic activities and climate change, many fens around the world are at risk. This paper presents the results of a study of the hydrology and geochemistry of fens in Big Smoky Valley, central Nevada to support the Bureau of Land Management’s activities in the area. A water sample from the largest fen in the study area was analyzed for its water chemistry and compared to a nearby alluvial aquifer and hot spring. The high SiO 2 concentration of the fen sample implies that the fen water may originate from geothermal water. A soil core was taken to analyze radiocarbon age and soil type. A majority of the core was composed of silt and clay interlayered with water-filled voids. Changes in the character of the clay with depth suggest that there may have been changes in the depositional environment over time. Radiocarbon dating of Ruppia seeds showed longevity of the fen, with the minimum 14 C age of the core as 4,375±40 years. This paper provides reconnaissance-level information on the Big Smoky Valley fens, but further information would be needed to better understand the source of water to the fens or how the fen environment has changed over time with climate.

Nevada

Evaluation of submersible pressure transducers for streamflow monitoring in small streams

Compact streamgages requiring minimal infrastructure and equipped with submersible pressure transducers (PTs) are increasingly used to monitor small streams, yet disparate implementations obscure their accuracy under real-world conditions. This study isolated instrumentation-derived uncertainty in stage monitoring by co-locating various combinations of commercial vented and unvented PTs with seven U.S. Geological Survey (USGS) reference streamgages on small streams. Multi-year PT stage records from compact streamgages, collected and corrected following USGS protocols, were compared to concurrent reference observations. Vented PTs demonstrated an average measurement uncertainty of ±0.005 m and mean absolute percent error (MAPE) of ±0.2%. Unvented PTs exhibited higher uncertainty, averaging ±0.009 m and ±0.4% MAPE. Although both sensor types had stage errors up to ±0.3 m, 95% of vented PT and unvented PT observations were within 0.01 and 0.02 m of reference stage, respectively. Analysis of additional unvented PTs revealed stage errors of up to ±1.2% when using barometric sensors within 15 km of the in-water sensor. Propagation of stage error to discharge using reference rating models resulted in cumulative discharge MAPEs of ±4.5% for vented and ±5.5% for unvented PTs. These findings highlight PTs as practical alternatives to reference instrumentation when deployed with standardized procedures, potentially expanding access to reliable streamflow data.

conterminous United States

Decadal-scale characteristics of natural and anthropogenic dune morphology along North Carolina Barrier Islands (SE Atlantic Coast)

Dunes offer protection to coastal communities from storms, yet quantitative research characterizing human influences on dune systems across decades and 10–100 km spatial scales constitutes a known data gap. This study analyzed a multidecadal archive of dune crest elevations and positions to map mesoscale spatiotemporal trends in foredune morphology across the barrier island coastline of North Carolina, SE Atlantic coast. Results are summarized within four categories of coastline representing a range of coastal management intensities, integrating beach width and dune lateral accommodation space to assess the comparative influence of differing intensities of anthropogenic intervention on dune morphology. These categories account for the presence of structures, roads, and alongshore connectivity to anthropogenic sediment sources (beach nourishment). These categories show distinct dune and beach system characteristics. Dunes are largest in the areas with the longest legacy of coastal management. As categories decrease in development intensity, dune and beach system characteristics generally depart from the large, static dunes and narrow beaches consistent with hold-the-line management. Where small or transgressive dunes exist on heavily developed coasts, they coincide with relatively strong hydrodynamic forcing or sediment-limiting geology. There is evidence of indirect coastal management influence on undeveloped barrier islands with alongshore connectivity to developed barriers. While this analysis was conducted at the mesoscale, the results provide researchers with the framework to make insights at smaller scales than those demonstrated in this study.

North Carolina

Evaluating the U.S. Geological Survey’s earthquake shaking hazard forecasts and their implications on seismic risk

We analyze the last six update cycles of the long-term probabilistic earthquake shaking hazard forecast from the U.S. Geological Survey (USGS) and discuss the changes in hazard estimates from the 1996 to the latest 2023 update of the National Seismic Hazard Model (NSHM) for the conterminous U.S. We summarize how our understanding of earthquake hazards has evolved over the last two decades and quantify the implications of changing hazards on people, buildings, and lifeline infrastructure. The net effect of changes in hazard estimates, with reference to the mean hazard from the 2023 NSHM update that has 2% probability of exceedance in 50 years, suggests an overall increase in total geographic areas facing very strong shaking levels (modified Mercalli Intensity (MMI) of VII or more) when compared with any of the previous cycles. This increase puts ~159.2 million people (an increase from 111.8 million when using the 2018 NSHM), ~47.3 million residential buildings (an increase from 32.5 million with the 2018 NSHM), and ~$25.6 trillion of economic exposure of all buildings (an increase from $17.4 trillion when using the 2018 NSHM) at risk from earthquakes. We demonstrate that small changes in hazard estimates do not necessarily imply small changes in risk estimates. Therefore, changes in risk estimates can be used to highlight key USGS NSHM updates for improving risk mitigation efforts.

Earthquake Spectra Journal

Hydrologic variability and groundwater age of springs in eastern Oregon and northern Nevada, USA

The ecological importance of springs in semiarid regions is far greater than their small size and sparse distribution, yet little is known about the hydrologic functioning of these systems. During 2016–22, 261 springs were visited in the volcanic terrane of eastern Oregon and northern Nevada. When conditions were suitable, measurements of discharge, water temperature, and specific conductance were made, and samples for the analysis of carbon-14, tritium, and water stable isotopes (WSI) were collected. A subset of 60 springs was revisited during different seasons in the same year and during the dry season in multiple years to evaluate variability in discharge, chemistry, and groundwater age. Specific conductance and WSI varied considerably among springs across the study area but were unexpectedly stable across seasons and years at individual springs. Seasonal and interannual variability in spring discharge was related to the residence time of the discharging groundwater. Springs discharging older groundwater (10 3 –10 4 years) had significantly less variability in their discharge compared to springs discharging younger groundwater (10 0 –10 1 years). Variability among springs discharging younger groundwater included cessation of late-summer discharge at 18 % of the repeat-visit springs. A logistic regression model predicted the age of discharging spring water with 89 % accuracy using only the spring latitude, longitude, elevation, and δ 2 H value. This study framework provides a simple, inexpensive, and robust method to provisionally assess the hydrologic behavior of springs having little or no prior information in understudied, semiarid regions across the globe.

Nevada, Oregon

Per- and polyfluoroalkyl substances (PFAS) mass flux and mass balance at an aqueous film-forming foam release site in semiarid eastern New Mexico, USA

Passive flux meters (PFMs) directly measure groundwater chemistry mass flux and Darcy flux, providing insight into contaminant source-zone architecture and transport properties. This study uses PFMs to characterize PFAS flux in groundwater at a semiarid site with a thick (greater than 90-m) unsaturated zone where groundwater has been contaminated with per - and polyfluoroalkyl substances (PFAS) related to the use of aqueous film-forming foam (AFFF) for fire training and fire suppression. PFAS mass discharge (PFAS mass flux integrated over a control plane) in groundwater downgradient from several PFAS release areas is calculated using PFM results. In groundwater downgradient from fire-training areas, total PFAS mass discharge (summed across 14 compounds) was estimated to be between 6.0 and 31 g per day in 2020 and between 5.9 and 23 g per day in 2021. Site-specific documentation, generic information on AFFF properties, and literature values of PFAS concentration in AFFF are used to estimate site-specific PFAS-application rates at fire-training areas. These PFAS-application rates are compared to groundwater PFAS-discharge rates. Results suggest that transformation processes (exact pathways unknown) have led to increased discharge of measured PFAS in groundwater relative to initial AFFF formulations. The mass balance approach has broad applicability as a high-level approach that can provide insight into PFAS transport at AFFF sites.

New Mexico

Evaluating the effects of a multi-modal deterrent on upstream passage by invasive carp and native species

Invasive carp, including Silver Carp ( Hypophthalmichthys molitrix ) and Grass Carp ( Ctenopharyngodon idella ), are increasing their range within the Mississippi River Basin, threatening native fishes and ecosystem function. We conducted a 3-year field test of a multi-modal deterrent that uses sound, bubbles, and light to test its ability to impede upstream passage by invasive carp. The test was performed at a lock and dam on the Cumberland River, Kentucky, USA, using acoustic telemetry to track the movements of Silver Carp, Grass Carp, and several native fish species. When the deterrent was operating, the estimated probability of upstream lock passage was 53% lower (95% CI: 41%–63%) for Silver Carp but 74% higher (95% CI: 3%–190%) for Grass Carp compared to times when the deterrent was not operating. Paddlefish ( Polyodon spathula ) passage was reduced by 43% (95% CI: 71% reduction to 9% increase), although this was not statistically significant. We detected no significant effects on Freshwater Drum ( Aplodinotus grunniens ) or Smallmouth Buffalo ( Ictiobus bubalus ). However, sample sizes were small for these native species, limiting our ability to identify effects. Water temperature, tailwater elevation, and vessel lockages affected passage rates, although this varied among species.

Kentucky

Constraining mean landslide occurrence rates for non-temporal landslide inventories using high-resolution elevation data

Constraining landslide occurrence rates can help to generate landslide hazard models that predict the spatial and temporal occurrence of landslides. However, most landslide inventories do not include any temporal data due to the difficulties of dating landslide deposits. Here we introduce a method for estimating the mean landslide occurrence rate of deep-seated rotational and translational slides derived solely from high-resolution (≤3 m) elevation data and globally available estimates of the diffusion coefficient for sediment flux. The method applies a linear diffusion model to the roughest landslide deposits until they reach a representative non-landslide roughness distribution. This estimates the time for a landslide deposit to be unrecognizable in high-resolution digital elevation data, which we term the mean lifetime of the landslide. Using the mean lifetime and number of landslides within an area of interest, we can estimate the mean occurrence rate of landslides over that domain. We validate this approach using a comprehensive temporal inventory of landslides in western Oregon created using age-roughness curves that are calibrated with high-resolution elevation data and radiocarbon data. We find good agreement between our diffusion method and the existing age-roughness-derived estimates, producing mean lifetimes of 4500 and 5200 years (4% difference), respectively. Hazard maps produced using the two methodologies generally agree, with the maximum differences in landslide probability reaching 0.1. Due to the relative abundance of high-resolution elevation data compared with age-dated landslides, our method could help constrain landslide occurrence rates in areas previously considered unfeasible.

Oregon

Egg thiamine concentrations reflect dietary differences between four hatchery strains, including two morphotypes, of Lake Trout in Lake Ontario

Objective Test whether dietary differences among hatchery strains of Lake Trout Salvelinus namaycush were associated with variation in egg thiamine concentrations and assess the potential for using strain-specific traits to mitigate thiamine deficiency complex (TDC) in Lake Ontario restoration efforts. Methods Stomach content analysis and stable isotope mixing models were used to compare diets among four hatchery strains of Lake Trout, representing lean and humper morphotypes. Egg thiamine concentrations were measured to test whether dietary differences correlated with susceptibility to TDC. Results Significant differences in diet and egg thiamine concentrations were observed among Lake Trout strains. A humper-like morphotype strain exhibited elevated thiamine levels, which were associated with reduced consumption of prey known to degrade thiamine levels when consumed, Alewife Alosa pseudoharengus and Rainbow Smelt Osmerus mordax , and increased reliance on Round Goby Neogobius melanostomus or sculpin species (Slimy Sculpin Cottus cognatus and Deepwater Sculpin Myoxocephalus thompsonii ). These findings support the link between the consumption of Alewife and Rainbow Smelt and thiamine deficiency. Conclusions Our findings support a link between strain-specific dietary preferences and susceptibility to TDC in Lake Trout. Preferential stocking of strains less prone to TDC, such as the strain derived from a humper morph from Lake Superior, could enhance restoration success in Lake Ontario. This strategy may be especially effective given the continued dominance of Alewife in the lake's prey base and the current management priorities supporting fisheries for Pacific salmon Oncorhynchus spp.

North American Journal of Fisheries Management

Manipulation of the Symbiodiniaceae microbiome confers multigenerational impacts on symbioses and reproductive ecology of its Exaiptasia diaphana host

Symbiodiniaceae-associated microbiota strongly influence cnidarian symbioses. We systematically reduced the bacterial and fungal communities associated with Symbiodiniaceae to study potential effects on the cnidarian holobiont Exaiptasia diaphana (Aiptasia). Clonal anemones were inoculated with xenic Breviolum minutum (SSB01) and microbiome-manipulated cultures after antibacterial or antifungal treatment. The asexual reproduction of pedal laceration allowed for three generations of clonal aposymbiotic Aiptasia to be utilised in this study, from the initial adult generation (G0), to the first (G1), and second (G2) generation. We inoculated small and large G1 Aiptasia with SSB01 algae and monitored onset of symbiosis, rate of algal proliferation, and holobiont characteristics. Sequencing the 16S and 18S rRNA gene regions identified significant differences in the bacterial and fungal communities of the G0 and G1 generations, alongside differences between the size classes of small and large G1 anemones. The microbiome of larger G1 individuals was distinct to the smaller G1 anemones, suggesting a microbiome maturation process. Control Breviolum minutum cultures exhibited a significantly greater proliferation rate in large G1 anemones when compared to antibacterial or antifungal treated cultures, whereas the opposite trend was documented in the small G1 anemones. Although no differences were observed between algal photochemical parameters, or the growth and polyp activity of G1 juveniles, we observed a significant influence in the production of G2 clones between treatments. Overall, we provide strong ecological implications of manipulating Symbiodiniaceae microbiome, not for the algae themselves, but for the maturation of the host Aiptasia, as well as for the cnidarian holobiont over multiple generations.

The ISME Journal

Applying U-Th disequilbrium for dating siliceous sinters

Continental hydrothermal systems are critical avenues for the crustal transport of heat and mass captured for geothermal energy and mineral exploration. Thus, understanding their temporal evolution and longevity is important for resource characterization. Deposits of microlaminated siliceous sinter, common surface expressions of high temperature reservoirs (> 170 °C), have the potential to trace hydrothermal histories. Geothermal reservoirs are often located within uranium-bearing silicic volcanic rock where subsurface fluid-rock interactions extract U into hydrothermal fluids. U incorporated in the surface sinter deposit has the potential to provide a U— Th disequilibrium dating option. We focus on samples from El Tatio geyser field in the Altiplano of northern Chile, the largest geothermal system in the Andes. Our resulting 230 Th/U ages, along with the water and deposit elemental compositions, suggest concentrations of U and Th vary predictably along the sinter apron. While distal facies containing the highest U concentrations (> 50 μg/g) are least affected by detrital Th corrections, they can display suspected open-system behavior. In contrast, more medial facies, where bacterial mats and other porous textures are co mmonly concentrated, have only trace amounts of U (< 0.1 μg/g), which leads to unreliable or geologically improbable dates. Proximal facies tend to date most consistently. By comparing existing 14 C ages with 230 Th/U results, 230 Th/U ages tend to be younger than the 14 C ages, supporting the presence of a 14 C-dead carbon influence. New data confirm that the onset of geothermal activity at El Tatio goes back to the late Pleistocene.

Altiplano, El Tatio geyser field

Exploring the uncertainty of machine learning models and geostatistical mapping of rare earth element potential in Indiana coals, USA

Rare earth elements and yttrium (REEs) have a wide range of applications in high- and low-carbon technologies. The strategic significance of REEs has grown due to their expanding applications in manufacturing industries and the constrained availability of these essential resources. This research explores the applicability of machine learning models and their uncertainty for assessing the REE potential in coal beds using various coal parameters as inputs. The work focuses on developing a predictive model based on geological variables, excluding considerations related to potential shifts in the commodities market. The Indiana Coal Quality Database was used as the data source. The promising and unpromising indicators derived from the outlook coefficient of samples from the database were used as the REE potential indicator for machine learning classification models. The filter-based approach with bootstrap was used to evaluate the importance of the coal parameters and their prediction uncertainties. Four machine learning methods (linear discriminant analysis (LDA), random forest (RF), support vector machine (SVM), and artificial neural networks (ANN), a data balancing and augmentation approach (Synthetic Minority Over-sampling Technique), and bootstrap resampling techniques were used for building the models and evaluating their prediction capabilities under uncertainty. It was determined that the SVM bootstrap model with ten-times balanced and augmented data provided superior results compared with other models. Finally, stochastic spatial maps of the REE potential within the coal basin were generated using sequential indicator simulation. The spatial maps of the REE potential showed that a 29% area of the Indiana section of the Illinois coal basin has economic potential of REEs, with 90% confidence.

Indiana

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California

Re-examining the growing degree day minimum for grass carp spawning initiation in Lake Erie: Have we missed the mark?

Understanding the timing of life history processes of invasive fish species, such as adult aggregations during spawning, allows natural resource managers to optimize targeted population control efforts. Temperature-based estimates of the timing of spawning initiation for grass carp ( Ctenopharyngodon idella ) exist from its native range, but have not previously been developed for grass carp reproduction in its invaded range in the Laurentian Great Lakes of North America. We accounted for differences among methods across studies and calculated cumulative growing degree days (GDD) for the dates of grass carp egg capture in Lake Erie tributaries (Sandusky, Maumee, and Huron rivers) during 2015–2024 and compared these values to the existing GDD base 15°C requirement estimate from the native range (633 GDD–15°C). The earliest egg detection in Lake Erie (Sandusky River) was 19 GDD–15°C or 361 GDD–5°C (latest egg detection was 2285 GDD–5°C from the Sandusky River), indicating that spawning was initiated up to 25 days earlier than would be predicted by the native range GDD. Moreover, spawning in Lake Erie tributaries occurred earlier than predicted for 58% of spawning events examined based on the native range GDD. The GDD values for spawning initiation in Lake Erie tributaries can be used to refine the timing of control efforts targeting pre-spawn and spawning adult fish, inform the timing of egg sampling, and provide linkages to existing early life stage models to infer the length of the growing season available for age-0 fish to reassess tributary suitability.

Lake Erie, Maumee, River, Sandusky river

Detrital zircons and the magmatic history of Viti Levu, Fiji

We integrate the existing detrital zircon data from multiple modern river sediment samples on Viti Levu, Fiji, with the most current available geological and topographic mapping of the respective river drainage basins to compare detrital populations with potential bedrock sources. The temporal and spatial variations in zircon geochemistry supplement what is known from igneous rocks and confirm the petrological differences between plutonic and volcanic rocks from the Eocene to early Oligocene (Yavuna age, >30 Ma), middle Oligocene to middle Miocene (Wainimala age, 30–12.5 Ma), late Miocene (Colo age, 12.5–6.5 Ma) and latest Miocene (Namosi age, 6.5–5 Ma). The >30 Ma Yavuna-age zircons are restricted to areas that drain the previously mapped Yavuna Group. The 30–12.5 Ma zircons are found across central Viti Levu from west to east, and the 30–15 Ma zircons have distinctively low U/Yb and high Dy/Yb ratios. They are the best radiometric evidence of widespread early to middle Miocene arc magmatism in Fiji that was relatively U-poor. Peak deconvolution of the Colo age zircons from individual basins suggests the following ages for undated or poorly dated plutons from central Viti Levu. The large Mavuvu pluton is probably composed of multiple intrusions in the 12–10 Ma range, the Waiqa pluton is probably ca 10 Ma, and the Noikoro pluton is probably ca 9 Ma. There are zircons from unknown plutonic or volcanic sources between 8 and 7 Ma in western Viti Levu that have distinct Eu/Eu* ratios. We attribute the highest U/Yb ratios in some Colo age zircons to crustal anatexis. Namosi-age zircons are abundant in the Medrausucu Group and can be found scattered across Viti Levu.

Viti Levu

The petrogenesis of Þingmúli volcano, East Fjords, Iceland

In this work we revisit Þingmúli volcano (Þ = Th), a classic locality known as an example of a complete tholeiitic differentiation. Þingmúli is a ~ 9.5 Ma extinct central volcano located in the East Fjords of Iceland, in which the whole compositional spectrum from basalt to rhyolites have erupted. These volcanic products have been previously considered as petrogenetically related by an ideal fractionation trend, regardless any temporal relationship or volumetric considerations. Here we report new whole-rock geochemistry, mineral chemistry, isotope analyses, estimation of residence times of the different eruptive deposits, and an update of the original petrogenetic model. Our results highlight that an enriched source, likely spinel lherzolites, generated transitional-alkaline basaltic melts after 15–20% of partial melting at depths of 40–45 km. Many of these basaltic melts erupted at various stages of the volcano's history, while others remained longer in the volcanic plumbing system. These evolved by fractional crystallisation into basaltic andesite magmas with a residence time of ~5 years based on the crystal size distribution of the plagioclase population. Isotopic differences between the basalts/basaltic andesites ( 87 Sr/ 86 Sr ~ 0.7034; 143 Nd/ 144 Nd ~ 0.51315) and the erupted rhyolites ( 87 Sr/ 86 Sr ~ 0.7037; 143 Nd/ 144 Nd ~ 0.51304) indicate that the latter are not petrogenetically related to the former. Therefore, instead of a fractional crystallisation mechanism to generate the rhyolites, we propose the partial melting of ignimbrite layers located beneath the volcano. The broad range of trace element concentrations in andesites and dacites and their different isotopic values compared to the basalts strongly suggest that these magmas have been generated by magma mixing between basaltic and rhyolitic melts, similar to modern day Icelandic volcanoes such as Hekla. These results highlight the need to revisit previously studied Icelandic classic localities and reassess their traditionally proposed petrogenetic models.

Þingmúli volcano, East Fjords

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas