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USGS2020

Soil water availability shapes species richness in mid-latitude shrub steppe plant communities

Questions Ecological communities are controlled by multiple, interacting abiotic and biotic factors that influence the distribution, abundance, and diversity of species. These processes jointly determine resource availability, resource competition, and ultimately species richness. For many terrestrial ecosystems in dryland climates, soil water availability is the most frequent limiting resource for plant species. We used field sampling coupled with process‐based soil water balance modeling to explore the relative importance of multiple macroclimatic, ecohydrological, and biotic variables on plant species and functional type richness at the landscape scale in dryland plant communities. Location Dryland plant communities dominated by big sagebrush ( Artemisia tridentata ) that span climatic and elevational gradients in Wyoming, USA. Methods We quantified species richness at 1,000 m 2 and used multiple regression to determine whether mean climatic conditions, multiple metrics of soil moisture from a soil water balance model (SOILWAT2), soil physical and chemical properties, and shrub stand structure (biotic) variables were related to species and functional type richness. Results Species richness varied between 16 and 54 across sites. We found that species and functional type richness were related to both macroclimate and ecohydrology, but ecohydrology explained slightly more variation than climate. Biotic variables were always secondary to macroclimate and ecohydrology in our models. Variance partitioning revealed that large portions of variability in species (~54%), forb (~47%), and grass (~40%) richness were explained by ecohydrological variables. Conclusions Our results highlight the importance of the spatial and temporal distribution of soil water for dryland plant species richness and suggest that documenting the ways in which climate, vegetation, and soil properties interact to determine soil water availability is critical for understanding biodiversity patterns in dryland plant communities. This work has relevance for other mid‐latitude, shrub‐dominated dryland plant communities where soil water availability strongly influences ecosystem structure and function.

Wyoming↗

USGS2023

Photochemical mobilization of dissolved hydrocarbon oxidation products from petroleum contaminated soil into a shallow aquifer activate human nuclear receptors

Elevated non-volatile dissolved organic carbon (NVDOC) concentrations in groundwater monitoring wells under oil-contaminated hydrophobic soils originating from a pipeline rupture at the National Crude Oil Spill & Natural Attenuation Research Site near Bemidji, MN are documented.. We hypothesized the elevated NVDOC is comprised of water-soluble photooxidation products transported from the surface to the aquifer. We use field and laboratory samples in combination with complementary analytical methods to test this hypothesis and determine the biological response to these products. Observations from optical spectroscopy and ultrahigh-resolution mass spectrometry reveal a significant correlation between the chemical composition of NVDOC leached from photochemically weathered soils and groundwater monitoring wells with high NVDOC concentrations measured in the aquifer beneath the contaminated soil. Conversely, the chemical composition from the uncontaminated soil photoleachate, matches the NVDOC observed in the uncontaminated wells. Contaminated groundwater and photodissolution leachates from contaminated soil activated biological targets indicative of xenobiotic metabolism and exhibited potential for adverse effects. Newly formed hydrocarbon oxidation products (HOPs) from fresh oil could be distinguished from those downgradient. This study illustrates another pathway for dissolved HOPs to infiltrate groundwater and potentially affect human health and the environment.

Minnesota↗

USGS2024

Brittle regime slip partitioned damage and deformation mechanisms along the eastern Denali fault zone in southwestern, Yukon

Rare bedrock exposures of the eastern Denali fault zone in southwestern Yukon allow for the measurement, sampling, and analyses of brittle regime fault slip data and deformation mechanisms to explore relations to far field, oblique plate motions. Host rock lithologies and associated slip surfaces show episodic damage zone‐related deformation and calcite ± hematite ± chlorite related hydrothermal fluid flow. This regional scale network of asymmetric fault damage is spatially and kinematically linked to a discrete and narrow fault core. Fault network observations, orientations, slip data, and strain inversions document a slip partitioned strike‐slip fault system with locally and mutually overprinting strike‐, oblique‐, and dip‐slip components. Microstructural analyses reveal crystal plastic and co‐seismic brittle deformation mechanisms active in a narrow range of upper crustal temperature, pressure, fluid, and chemical conditions. The net damage related slip is not exclusively formed by a single kinematic system, but rather a fully partitioned, time integrated system likely operative for much of the fault's brittle regime evolution temporally constrained by previously published thermochronometric data. Although the fault slip data was collected from outcrop‐scale exposures at sites tens of kilometers apart, results show remarkable correlation between fault kinematics and plate motions along the ∼580 km long eastern Denali fault segment. End member, subhorizontal, northeast directed reverse and north directed dextral strike slip fault strain axes closely reflect relative plate motion interactions over at least the last 30 m.y. and act as a proxy for far‐field stresses compatible with the kinematics of the damage zone network.

Alaska↗

USGS2014

Reconnaissance of pharmaceuticals and wastewater indicators in streambed sediments of the lower Columbia River basin, Oregon and Washington

One by-product of advances in modern chemistry is the accumulation of synthetic chemicals in the natural environment. These compounds include contaminants of emerging concern (CECs), some of which are endocrine disrupting compounds (EDCs) that can have detrimental reproductive effects. The role of sediments in accumulating these types of chemicals and acting as a source of exposure for aquatic organisms is not well understood. Here we present a small-scale reconnaissance of CECs in bed sediments of the lower Columbia River and several tributaries and urban streams. Surficial bed sediment samples were collected from the Columbia River, the Willamette River, the Tualatin River, and several small urban creeks in Oregon. Thirty-nine compounds were detected at concentrations ranging from <1 to >1,000 ng [g sediment] -1 dry weight basis. Columbia River mainstem, suggesting a higher risk of exposure to aquatic life in lower order streams. Ten known or suspected EDCs were detected during the study. At least one EDC was detected at 21 of 23 sites sampled; several EDCs were detected in sediment from most sites. This study is the first to document the occurrence of a large suite of CECs in the sediments of the Columbia River basin. A better understanding of the role of sediment in the fate and effects of emerging contaminants is needed.

Oregon;Washington↗

USGS2024

Atlas of microscopic images of biochar using reflected light microscopy in biochar characterization

Derived through the thermochemical conversion of biomass, biochar is a carbon-rich substance recognized for its significance in environmental applications and sustainable agriculture. As interest in its utilization continues to rise, it becomes crucial to comprehend how the source material and pyrolysis parameters influence the properties of biochar and, consequently, to research the suitability of various analytical methods for characterizing it. Despite the current utilization of numerous physical and chemical methods, the untapped potential of reflected light microscopy warrants further exploration. While a few recent studies suggest a correlation between certain microscopic characteristics and selected physical and chemical properties of biochar, the data are limited and difficult to compare. This is primarily due to variations in the types of original biomass used and lack of information about pyrolysis conditions. Moreover, because only a limited number of photographs taken under a reflected light microscope are publicly available to-date, it is difficult to evaluate morphological differences between various biochars and other organic materials such as inertinites from coal, charcoal, etc. To address limited availability of publicly available data, this “Atlas of Microscopic Images of Biochar” presents a collection of more than 300 images contributed by researchers from Poland, the United States, Canada, Australia, Brazil, and Denmark. These photomicrographs capture optical characteristics of a diverse array of biochar, demonstrating its unique morphological and structural features. This visual documentation can serve as a valuable resource for researchers, industry professionals, educators, and enthusiasts interested in investigating the complexities of biochar forms.

Indiana Journal of Earth Sciences↗

USGS1997

Characteristics of and corrections for core shortening in unconsolidated sediments

Thinning, bypassing, and compaction of shallow unconsolidated sediments during manual coring or vibracoring operations probably cause more sediment deformation and greater stratigraphic displacement than is commonly reported in the wetland literature. We measured core shortening in open-barrel cores from fluvial wetlands, lagoonal flats, and marshes to document the magnitude and characteristics of shortening where sediments may be stiff and require extra mechanical effort to recover a sufficient length of sample for analysis. Results of those measurements indicate that thinning or non- recovery of discrete sediment intervals can range from 0 to 67 percent and cumulative core shortening can be as much as 30 percent even for cores less than one meter long. Detailed open-barrel measurements also show that core shortening is not uniformly distributed throughout the depth of penetration as is often assumed. Analytical data derived from shortened cores can only be properly interpreted if patterns of shortening are established and incorporated into the analysis. Minor artificial displacement of sediment depths can alter plots of physico-chemical parameters and can significantly influence calculated rates of sedimentation and other depth-dependent statistical relationships. This study (1) demonstrates how plots of interval shortening and cumulative shortening can be used to characterize the distribution of shortening at depth and (2) presents a simple equation for stratigraphic restoration so that core observations and analyses are corrected to their original depths.

Journal of Coastal Research↗

USGS2009

Sediment characterization and dynamics in Lake Pontchartrain, Louisiana

Lake Pontchartrain in southeastern Louisiana is the largest of several shallow estuaries that together cover over 15,000 km 2 . Wetlands, forests, and large urban areas surround the lake. Primary transport mechanisms of sediments to Lake Pontchartrain include urban runoff, major diversions of the Mississippi River, discharge from streams along the north and west shores, and tidal circulation. Sediments deposited in Lake Pontchartrain are subjected to resuspension and mixing by natural and human activities. Bioturbation and water turbulence throughout the lake are the major mixing agents, and mechanical shell dredging has reworked much of the lake bottom over the last century. Sediment characterization through direct sampling and geophysical surveys indicates that these processes continually rework the top meter of sediment. The lake receives discharge from roadways and industrial and agricultural sources. Contaminants from these sources accumulate in the lake sediments and are an important contributor to the degradation of the estuary. Decline in populations of various benthic organisms, such as shrimp and clams, has been documented in the lake. To characterize the health of this important estuary, the U.S. Geological Survey (USGS) conducted a comprehensive evaluation of the geology, geomorphology, coastal processes, and environmental condition of the Pontchartrain Basin from 1994 to 1997. This report presents an assessment of sediment distribution and quality using a multidisciplinary approach to characterize the influence of various physical and chemical parameters: nearsurface stratigraphy, major trace metal concentrations (Cu, Pb, Zn, and Ni), and short-lived radionuclides ( 210 Pb, 7 Be, and 137 Cs). The results are compared with water-circulation patterns to determine high-resolution sedimentation patterns in the lake. The data show a significant increase in trace metals in the top 1 m of lake sediments. Above this horizon, pollen analysis indicates a correlation with land clearing in the area, a proxy for increasing human development of the surrounding landscape and an increase in surface run-off. The data also show that the top meter of sediment undergoes frequent resuspension during high-energy circulation events and via circulation gyres in the lake. This regular turnover does not allow stratification of recently deposited sediments, restricting the sequestration of contaminated material that enters the lake.

Louisiana↗

USGS2025

Land application of drill waste: A scope analysis

Drilling fluid waste land application, a process where drilling wastes are spread and tilled into the land surface, has become common in some petroleum-producing states, however, the potential benefits and risks of this practice are not well studied. Drilling fluids can be water- or oil-based and can have high concentrations of total soluble salts and total petroleum hydrocarbons. Comprehensive chemical characterization of these fluids is not well documented in the literature, and the extent of land application is largely unknown. We hypothesized that the land application of drill waste would fluctuate over time due to economic factors. To begin to understand the extent of historical and potential future land application, we analyzed data from over 5,800 drilling fluid land application permits collected by the Oklahoma Corporation Commission for years 2000, 2005, 2010, and 2015–2020. During the years studied, drilling fluid wastes were applied to more than 250,000 acres in Oklahoma, with over 54,000 thousand barrels (Mbbl) of liquids and nearly 21,000 Mbbl of solids applied. Land application is widespread (occurring in 59/77 counties), however recent drilling activity, land availability, and the economics of transportation have created conditions favorable for land application specifically in the Anadarko Basin. Land application can co-occur with sensitive areas, such as important groundwater and surface-water drinking sources and agricultural fields used for subsistence or feed crop production. Our approach for quantifying the extent of land application, along with further chemical characterization studies, can aid operators and land managers who are considering this practice in assessing the associated benefits and risks.

Oklahoma↗

USGS1996

Atrazine concentrations in near-surface aquifers: A censored regression approach

In 1991, the U.S. Geological Survey (USGS) conducted a study to investigate the occurrence of atrazine (2-chloro-4-ethylamino-6- isopropylamino-s-triazine) and other agricultural chemicals in near-surface aquifers in the midcontinental USA. Because about 83% of the atrazine concentrations from the USGS study were censored, standard statistical estimation procedures could not be used. To determine factors that affect atrazine concentrations in groundwater while accommodating the high degree of data censoring. Tobit models were used (normal homoscedastic, normal heteroscedastic, lognormal homoscedastic, and lognormal heteroscedastic). Empirical results suggest that the lognormal heteroscedastic Tobit model is the model of choice for this type of study. This model determined the following factors to have the strongest effect on atrazine concentrations in groundwater: percent of pasture within 3.2 km, percent of forest within 3.2 km (2 mi), mean open interval of the well, primary water use of a well, aquifer class (unconsolidated or bedrock), aquifer type (unconfined or confined), existence of a stream within 30 m (100 ft), existence of a stream within 30 m to 0.4 km (0.25 mi), and existence of a stream within 0.4 to 3.2 km. Examining the elasticities of the continuous explanatory factors provides further insight into their effects on atrazine concentrations in groundwater. This study documents a viable statistical method that can be used to accommodate the complicating presence of censured data, a feature that commonly occurs in environmental data.

Journal of Environmental Quality↗

USGS2012

Magmatic inclusions in silicic and intermediate volcanic rocks

Fine‐grained ellipsoidal inclusions from a few millimeters to over l m in size are present in many intermediate to silicic lava flows and domes. Only recently has it become widely accepted that such inclusions are chilled blobs of magma. Their magmatic origin is manifested by vesicularity and high groundmass porosity, by ellipsoidal shapes, by mingling at contacts with the host, and by textural evidence for groundmass crystallization in an undercooled state. Groundmass textures reflect the degree of undercooling, which is a function of thermal contrast (Δ T ) between inclusions and host magmas before mingling. Compositions of inclusions are invariably more mafic than their hosts and indicate that the magmatic systems were compositionally zoned. Many inclusions were formed from hybrid magmas. Four examples are given in order to document effects of decreasing Δ C (compositional contrast) and Δ T , as hosts for mafic andesitic to andesitic inclusions vary from high‐silica rhyolite (HSR) to silicic andesite. In the HSR example from the Coso volcanic field, California, inclusions track the evolution of zonation in a long‐lived magmatic system. At the other extreme, andesitic inclusions in silicic andesite from Crater Lake, Oregon, demonstrate zonation of a system of low Δ T and Δ C and show effects of in situ differentiation by gas filter‐pressing of residual liquid. Inclusions form when a relatively small proportion of mafic magma comes into contact with a larger proportion of silicic magma. Several mechanisms by which the magmas mix have been proposed: buoyant rise of vesiculated mafic magma or convective stirring at the interface between mafic and overlying silicic magma, forcible injection of mafic magma, diking of fractured silicic magma, and mixing during ascent in a conduit. No single mechanism explains all field observations. Many inclusions in plutons are analogous to magmatic inclusions in volcanic rocks but are likely to have suffered greater chemical and textural change during comparatively slow postentrapment cooling. Magmatic inclusions are evidence of open system behavior of the differentiated parts of magma bodies, and the inclusions themselves may behave as open systems where Δ T is low.

Journal of Geophysical Research B: Solid Earth↗

USGS2003

Herbicides and herbicide degradation products in upper midwest agricultural streams during august base-flow conditions

Herbicide concentrations in streams of the U.S. Midwest have been shown to decrease through the growing season due to a variety of chemical and physical factors. The occurrence of herbicide degradation products at the end of the growing season is not well known. This study was conducted to document the occurrence of commonly used herbicides and their degradation products in Illinois, Iowa, and Minnesota streams during base-flow conditions in August 1997. Atrazine, the most frequently detected herbicide (94%), was present at relatively low concentrations (median 0.17 μg L −1 ). Metolachlor was detected in 59% and cyanazine in 37% of the samples. Seven of nine compounds detected in more than 50% of the samples were degradation products. The total concentration of the degradation products (median of 4.4 μg L −1 ) was significantly greater than the total concentration of parent compounds (median of 0.26 μg L −1 ). Atrazine compounds were present less frequently and in significantly smaller concentrations in streams draining watersheds with soils developed on less permeable tills than in watersheds with soils developed on more permeable loess. The detection and concentration of triazine compounds was negatively correlated with antecedent rainfall (April–July). In contrast, acetanalide compounds were positively correlated with antecedant rainfall in late spring and early summer that may transport the acetanalide degradates into ground water and subsequently into nearby streams. The distribution of atrazine degradation products suggests regional differences in atrazine degradation processes.

Midwest region↗

USGS1998

Recovery and validation of historical sediment quality data from coastal and estuarine areas: An integrated approach

A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1955 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray literature). Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations of Cu, Hg, and Zn of 40 to 60% over a 17-year period.A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1995 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations Cu, Hg, and Zn of 40 to 60% over a 17-year period.

Massachusetts↗

USGS2024

First documentation of grass carp spawning in Lake Erie’s Central Basin

Grass carp ( Ctenopharyngodon idella ) are non-indigenous to North America having been translocated to the United States in the 1960s as a potential non-chemical solution for nuisance aquatic vegetation. Reproductively viable grass carp now exist in many watersheds in the United States. In the Great Lakes basin, grass carp were first discovered in the 1980s with direct confirmation of successful reproduction in 2015 via collection of fertilized grass carp eggs in the Sandusky River. Early life stage monitoring also confirmed reproduction in the Maumee River in 2017. During 2018–2021, no new spawning tributaries were discovered (18 total sampling events in five Great Lakes tributaries). In 2022, fourteen eggs with characteristics similar to grass carp were identified from the Huron River which is a tributary to Lake Erie’s Central Basin. Eggs were identified to species via DNA sequencing and were determined to be grass carp eggs. The confirmation of spawning in the Huron River represents a third spawning tributary in the Lake Erie basin and expands eastward the geographic extent of known grass carp spawning locations. Presently, the ability of the Huron River to support hatching and survival of larval grass carp is unknown. Discovery of the Huron River as a grass carp spawning tributary identifies the value of continued surveillance in Great Lakes tributaries for early life stages and conducting scientific inquiries evaluating the consistency of tributary use and survival of early life stages.

Ohio↗

USGS2008

Veneers, rinds, and fracture fills: Relatively late alteration of sedimentary rocks at Meridiani Planum, Mars

Veneers and thicker rinds that coat outcrop surfaces and partially cemented fracture fills formed perpendicular to bedding document relatively late stage alteration of ancient sedimentary rocks at Meridiani Planum, Mars. The chemistry of submillimeter thick, buff-colored veneers reflects multiple processes at work since the establishment of the current plains surface. Veneer composition is dominated by the mixing of silicate-rich dust and sulfate-rich outcrop surface, but it has also been influenced by mineral precipitation, including NaCl, and possibly by limited physical or chemical weathering of sulfate minerals. Competing processes of chemical alteration (perhaps mediated by thin films of water or water vapor beneath blanketing soils) and sandblasting of exposed outcrop surfaces determine the current distribution of veneers. Dark-toned rinds several millimeters thick reflect more extensive surface alteration but also indicate combined dust admixture, halite precipitation, and possible minor sulfate removal. Cemented fracture fills that are differentially resistant to erosion occur along the margins of linear fracture systems possibly related to impact. These appear to reflect limited groundwater activity along the margins of fractures, cementing mechanically introduced fill derived principally from outcrop rocks. The limited thickness and spatial distribution of these three features suggest that aqueous activity has been rare and transient or has operated at exceedingly low rates during the protracted interval since outcropping Meridiani strata were exposed on the plains surface.

Journal of Geophysical Research E: Planets↗

USGS2014

Exposure pathways and biological receptors: baseline data for the canyon uranium mine, Coconino County, Arizona

Recent restrictions on uranium mining within the Grand Canyon watershed have drawn attention to scientific data gaps in evaluating the possible effects of ore extraction to human populations as well as wildlife communities in the area. Tissue contaminant concentrations, one of the most basic data requirements to determine exposure, are not available for biota from any historical or active uranium mines in the region. The Canyon Uranium Mine is under development, providing a unique opportunity to characterize concentrations of uranium and other trace elements, as well as radiation levels in biota, found in the vicinity of the mine before ore extraction begins. Our study objectives were to identify contaminants of potential concern and critical contaminant exposure pathways for ecological receptors; conduct biological surveys to understand the local food web and refine the list of target species (ecological receptors) for contaminant analysis; and collect target species for contaminant analysis prior to the initiation of active mining. Contaminants of potential concern were identified as arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, thallium, uranium, and zinc for chemical toxicity and uranium and associated radionuclides for radiation. The conceptual exposure model identified ingestion, inhalation, absorption, and dietary transfer (bioaccumulation or bioconcentration) as critical contaminant exposure pathways. The biological survey of plants, invertebrates, amphibians, reptiles, birds, and small mammals is the first to document and provide ecological information on .200 species in and around the mine site; this study also provides critical baseline information about the local food web. Most of the species documented at the mine are common to ponderosa pine Pinus ponderosa and pinyon–juniper Pinus–Juniperus spp. forests in northern Arizona and are not considered to have special conservation status by state or federal agencies; exceptions are the locally endemic Tusayan flameflower Phemeranthus validulus, the long-legged bat Myotis volans, and the Arizona bat Myotis occultus. The most common vertebrate species identified at the mine site included the Mexican spadefoot toad Spea multiplicata, plateau fence lizard Sceloporus tristichus, violetgreen swallow Tachycineta thalassina, pygmy nuthatch Sitta pygmaea, purple martin Progne subis, western bluebird Sialia mexicana, deermouse Peromyscus maniculatus, valley pocket gopher Thomomys bottae, cliff chipmunk Tamias dorsalis, black-tailed jackrabbit Lepus californicus, mule deer Odocoileus hemionus, and elk Cervus canadensis. A limited number of the most common species were collected for contaminant analysis to establish baseline contaminant and radiological concentrations prior to ore extraction. These empirical baseline data will help validate contaminant exposure pathways and potential threats from contaminant exposures to ecological receptors. Resource managers will also be able to use these data to determine the extent to which local species are exposed to chemical and radiation contamination once the mine is operational and producing ore. More broadly, these data could inform resource management decisions on mitigating chemical and radiation exposure of biota at high-grade uranium breccia pipes throughout the Grand Canyon watershed.

Arizona↗

USGS2025

Mercury speciation and stable isotopes in emperor penguins: First evidence for biochemical demethylation of methylmercury to mercury-dithiolate and mercury-tetraselenolate complexes

Apex marine predators, such as toothed whales and large petrels and albatrosses, ingest mercury (Hg) primarily in the form of methylmercury (MeHg) via prey consumption, which they detoxify as tiemannite (HgSe). One of the most intriguing current questions in Hg research is how more abundant lower trophic level predators detoxify MeHg, particularly in marine environments where tissue Hg burdens can be elevated. To address this need, we used high energy-resolution X-ray absorption near edge structure spectroscopy paired with nitrogen (N) and Hg stable isotopes to identify the chemical forms of Hg, Hg source, and species-specific δ 202 Hg isotopic values in emperor penguin, a mesopredator feeding primarily on Antarctic silverfish. The penguin liver contains variable proportions of MeHg and two inorganic Hg species (IHg), Hg-dithiolate (Hg(SR) 2 ) and Hg-tetraselenolate (Hg(Sec) 4 ) complexes, each characterized by a specific isotopic value (δ 202 MeHg = 0.3 ± 0.2‰, δ 202 Hg(SR) 2 = −1.6 ± 0.2‰, δ 202 Hg(Sec) 4 = −2.0 ± 0.1‰). Using δ 15 N as tracer of food source, we show that Hg(SR) 2 is not dietary but a biochemical demethylation product of MeHg metabolism. Penguin females transfer Hg to the egg as MeHg in the egg albumen, 89% MeHg and 11% IHg in the membrane, and 32% MeHg and 68% Hg(Sec) 4 in the yolk, on average (n = 15). Despite IHg species in eggs, MeHg is the main species quantitatively transferred by the mother to the chick because of the disproportionate mass of the MeHg-rich albumen compared to the yolk (n = 18). Further research is needed to elucidate the MeHg to Hg(SR) 2 demethylation pathway firmly documented here for the first time in multicellular organisms, and to understand why the thiolate ligands are not exchanged for Se ligands to form Hg(Sec) 4 , as the liver does not suffer from Se deficiency.

Adelie Land↗

USGS2015

Regional and temporal differences in nitrate trends discerned from long-term water quality monitoring data

Riverine nitrate (NO 3 ) is a well-documented driver of eutrophication and hypoxia in coastal areas. The development of the elevated river NO 3 concentration is linked to anthropogenic inputs from municipal, agricultural, and atmospheric sources. The intensity of these sources has varied regionally, through time, and in response to multiple causes such as economic drivers and policy responses. This study uses long-term water quality, land use, and other ancillary data to further describe the evolution of river NO 3 concentrations at 22 monitoring stations in the United States (U.S.). The stations were selected for long-term data availability and to represent a range of climate and land-use conditions. We examined NO 3 at the monitoring stations, using a flow-weighting scheme meant to account for interannual flow variability allowing greater focus on river chemical conditions. River NO 3 concentration increased strongly during 1945-1980 at most of the stations and have remained elevated, but stopped increasing during 1981-2008. NO 3 increased to a greater extent at monitoring stations in the Midwest U.S. and less so at those in the Eastern and Western U.S. We discuss 20th Century agricultural development in the U.S. and demonstrate that regional differences in NO 3 concentration patterns were strongly related to an agricultural index developed using principal components analysis. This unique century-scale dataset adds to our understanding of long-term NO 3 patterns in the U.S.

Journal of the American Water Resources Associatio↗

USGS2016

Methods of soil resampling to monitor changes in the chemical concentrations of forest soils

Recent soils research has shown that important chemical soil characteristics can change in less than a decade, often the result of broad environmental changes. Repeated sampling to monitor these changes in forest soils is a relatively new practice that is not well documented in the literature and has only recently been broadly embraced by the scientific community. The objective of this protocol is therefore to synthesize the latest information on methods of soil resampling in a format that can be used to design and implement a soil monitoring program. Successful monitoring of forest soils requires that a study unit be defined within an area of forested land that can be characterized with replicate sampling locations. A resampling interval of 5 years is recommended, but if monitoring is done to evaluate a specific environmental driver, the rate of change expected in that driver should be taken into consideration. Here, we show that the sampling of the profile can be done by horizon where boundaries can be clearly identified and horizons are sufficiently thick to remove soil without contamination from horizons above or below. Otherwise, sampling can be done by depth interval. Archiving of sample for future reanalysis is a key step in avoiding analytical bias and providing the opportunity for additional analyses as new questions arise.

Journal of Visualized Experiments↗