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Problems of snowmelt runoff modelling for a variety of physiographic and climatic conditions

Problems include: a) definition of the spatial and temporal distribution of model input; b) measurement or estimation of snow accumulation, snowmelt, and runoff process parameters for a range of applications and scales; and c) development of accurate short term and long term snowmelt runoff forecasts. Procedures being investigated to solve these problems include: a) integrating conventional and remote-sensing data to improve estimates of input data; b) developing snowmelt process algorithms which have parameters that are closely related to measurable basin and climatic characteristics; and c) updating model paramters and components using measured data or knowledge of past uncertainty. -from Author

Hydrological Sciences Journal

Effects of uranium mining discharges on water quality in the Puerco River basin, Arizona and New Mexico

From 1967 until 1986, uranium mine dewatering increased dissolved gross alpha, gross beta, uranium and radium activities and dissolved selenium and molybdenum concentrations in the Puerco River as indicated by time trends, areal patterns involving distance from the mines and stream discharge. Additionally, increased dissolved uranium concentrations were identified in groundwater under the Puerco River from where mine discharges entered the river to approximately the Arizona-New Mexico State line about 65 km downstream. Total mass of uranium and gross alpha activity released to the Puerco River by mine dewatering were estimated as 560 Mg (560 × 10 6 g) and 260 Ci, respectively. In comparison, a uranium mill tailings pond spill on 16 July 1979, released an estimated 1.5 Mg of uranium and 46 Ci of gross alpha activity. Mass balance calculations for alluvial ground water indicate that most of the uranium released did not remain in solution. Sorption of uranium on sediments and uptake of uranium by plants probably removed the uranium from solution.

Arizona, New Mexico

Evapotranspiration estimation using a normalized difference vegetation index transformation of satellite data

Evapotranspiration of irrigated crops on two irrigation service areas along the lower Colorado River was estimated using a normalized difference vegetation index of satellite data. A procedure was developed which equated the index to crop coefficients. Evapotranspiration estimates for fields for three dates of thematic mapper data were highly correlated with ground estimates. Service area estimates using thematic mapper and Advanced Very High Resolution Radiometer data agreed well with estimates based on US Geological Survey gauging station data.

Hydrological Sciences Journal

Mechanisms of Devils Lake’s responses to recent climatic wetting: Insights from a physically based hydrologic model

Study region Devils Lake Basin of the Northern Great Plains (NGP) region, North Dakota, USA Study focus Understanding the mechanism of Devils Lake’s responses and basin-wide hydrologic change under a wet-climatic regime using a process-based and cold region hydrologic model. New hydrologic insights Model results illustrate that three distinct hydroclimatic periods occurred during the study: Water Years 2002–05, 2006–11, and 2012–18. Following a brief time of contraction and growth, the latter two periods provide a complete picture of a wetting to drying cycle during an overall wetting regime. From 2006–2011, Devils Lake (DL) grew primarily due to lateral inflow, driven by strong precipitation and high frozen soil content leading up to the 2011 floods. In addition, during wet years, the snowmelt streamflow from the eastern and central parts of the DL Basin contributes significantly to lake growth compared to the western part. By contrast, from 2012 to 18, DL entered a contraction period, dominated by evaporation losses and anthropogenic flood control operations. Contributors to upstream drying included low precipitation, minimal snowpack accumulation, slightly lower frozen soil ratios, and minimal snowmelt runoff.

North Dakota

Processes regulating watershed chemical export during snowmelt, fraser experimental forest, Colorado

In the Central Rocky Mountains, snowfall dominates precipitation. Airborne contaminants retained in the snowpack can affect high elevation surface water chemistry during snowmelt. At the Fraser Experimental Forest (FEF), located west of the Continental Divide in Central Colorado, snowmelt dominates the annual hydrograph, and accounts for >95% of annual stream water discharge. During the winters of 1989-1993, we measured precipitation inputs, snowpack water equivalent (SWE) and ion content, and stream water chemistry every 7-10 days along a 3150-3500 m elevation gradient in the subalpine and alpine Lexen Creek watershed. The study objectives were to (1) quantify the distribution of SWE and snowpack chemical content with elevation and aspect, (2) quantify snowmelt rates, temperature of soil, snowpack, and air with elevation and aspect, and (3) use change in upstream-downstream water chemistry during snowmelt to better define alpine and subalpine flowpaths. The SWE increased with elevation (P < 0.001) and was greater on NE aspects (P < 0.05). Subalpine soils were unfrozen. Snowmelt occurred throughout winter at low elevation (3150 m), SE aspect stations. By snowpack peak water equivalent (PWE), the snowpack lost about a third (0.24 m) of its moisture. The subalpine snowpack had warm (> - 3??C) temperatures throughout winter which resulted in significant snowpack ion loss. By snowpack PWE in mid May, the snowpack had lost almost half the cumulative precipitation H+, NH4+, and SO42- inputs and a third of the NO3- input. Windborne soil particulate inputs late in winter increased snowpack base cation content. Variation in subalpine SWE and snowpack ion content with elevation and aspect, and wind redistribution of snowfall in the alpine resulted in large year-to-year differences in the timing and magnitude of SWE, PWE, and snowpack ion content. The alpine stream water ion concentrations changed little during snowmelt indicating meltwater passed quickly through surface porous soils and was well mixed before entering the stream. Conversely, subalpine stream water chemistry was diluted during snowmelt suggesting much melt water moved to the stream as shallow subsurface lateral flow. Published by Elsevier Science B.V.

Journal of Hydrology

Seasonal and event-scale variations in solute chemistry for four Sierra Nevada catchments

Hydrobiogeochemical processes controlling stream water chemistry were examined in four small (<5 km2) catchments having contrasting bedrock lithologies in the western Sierra Nevada foothills of California. The Mediterranean climate with its cool/wet and hot/dry cycle produces strong seasonal patterns in hydrological, biological and geochemical processes. Stream water solutes fall into three general groups according to seasonal fluctuation in concentration: Strong, rainy season minimum-dry season maximum (Cl-, SO42-, base cations); weak, rainy season minimum-dry season maximum (Si); and rainy season maximum-dry season minimum (NO3- and K+). Solute dynamics in soil solutions and stream water suggest that mixing of drainage waters from bedrock and soil sources regulate stream water solute concentrations. Patterns are further altered by the leaching of solutes accumulated in the soil over the summer period of desiccation and the temporal discoupling of nutrient cycles that occurs due to differences in the timing between vegetation growth (late spring) and leaching (early winter). Solute concentrations are remarkably similar between watersheds with varying bedrock types, with the exception of nitrate, sulfate and bicarbonate. Three watersheds have nitrogen-bearing metasedimentary bedrock that contributes to elevated nitrate concentrations in stream waters. Watersheds whose bedrock includes mineralized veins of sulfide and carbonate minerals similarly have greater sulfate and bicarbonate concentrations in stream water. Hydrobiogeochemical processes are highly dynamic at the seasonal and storm-event temporal scales and spatially complex at the watershed scale making management of stream water chemical composition, such as nitrate concentrations, very challenging. ?? 2001 Elsevier Science B.V.

Journal of Hydrology

Effect of canopy removal on snowpack quantity and quality, fraser experimental forest, Colorado

Snowpack peak water equivalent (PWE), ion concentration, content, and spatial distribution of ion load data from spring 1987-1996 in a 1 ha clearcut and adjacent forested plots vegetated by mature Picea engelmannii and Abies lasiocarpa in the Fraser experimental forest (FEF), Colorado are presented. Our objectives were: (1) to see if a forest opening might redistribute snowfall, snowpack moisture, and snowpack chemical content, and (2) to examine the importance of canopy interception on snowpack quantity and chemistry. On an average, the canopy intercepted 36% of snowfall. Interception was correlated with snowfall amount, snowpack PWE beneath the canopy, and air temperature. Canopy removal increased snowpack PWE to >90% cumulative snowfall inputs. Snowpack K-, H-, and NH4+ concentrations on the clearcut were lower and NO3- higher than in the snowpack beneath the forested plots. Cu mulative snowfall K+ input was less than in the clearcut snowpack; H+ inputs were greater in snowfall than in the snowpack of any plot; and inorganic N (NO3- and NH4+) inputs from snowfall to the clearcut were greater than to the forested plots. Processes accounting for the differences between snowfall inputs and snowpack ion content were leaching of organic debris in the snowpack, differential elution of the snowpack, and canopy retention. There were significant trends by year in snowpack ion content at PWE without similar trends in snowfall inputs. This finding coupled with snowpack ion elution bring into question the use of snowpack chemistry as an indicator of winter atmospheric inputs in short-term studies. ?? 2001 Elsevier Science B.V.

Journal of Hydrology

Improving the analysis of slug tests

This paper examines several techniques that have the potential to improve the quality of slug test analysis. These techniques are applicable in the range from low hydraulic conductivities with overdamped responses to high hydraulic conductivities with nonlinear oscillatory responses. Four techniques for improving slug test analysis will be discussed: use of an extended capability nonlinear model, sensitivity analysis, correction for acceleration and velocity effects, and use of multiple slug tests. The four-parameter nonlinear slug test model used in this work is shown to allow accurate analysis of slug tests with widely differing character. The parameter ?? represents a correction to the water column length caused primarily by radius variations in the wellbore and is most useful in matching the oscillation frequency and amplitude. The water column velocity at slug initiation (V0) is an additional model parameter, which would ideally be zero but may not be due to the initiation mechanism. The remaining two model parameters are A (parameter for nonlinear effects) and K (hydraulic conductivity). Sensitivity analysis shows that in general ?? and V0 have the lowest sensitivity and K usually has the highest. However, for very high K values the sensitivity to A may surpass the sensitivity to K. Oscillatory slug tests involve higher accelerations and velocities of the water column; thus, the pressure transducer responses are affected by these factors and the model response must be corrected to allow maximum accuracy for the analysis. The performance of multiple slug tests will allow some statistical measure of the experimental accuracy and of the reliability of the resulting aquifer parameters. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Analysis of aquifer mineralization by paleodrainage channels

Mineralization of groundwater resources is a problem in south-central Kansas, due to the penetration of saline water from Permian bedrock formations into the overlying alluvial aquifer. One of the mechanisms involved in the mineralization involves small bedrock features of high permeability located in places occupied by streams and rivers in past geological eras. These geological features are termed 'paleodrainage channels'. The permeability of the overlying aquifer can be significantly smaller than that of the channel fill material. The comparatively fast migration of saline water through these channels of high permeability is associated with the transfer of minerals into the overlying freshwater aquifer. This study applies a set of boundary layer approaches to quantify the process of mineral transfer from the channels into the aquifer. The methods used in the present study provide quick estimation and evaluation of the dilution of the channel flow, as well as mineral concentration profile changes in the mineralized zone created in the overlying aquifer. More generally, the method can also be useful for the analysis and evaluation of various types of groundwater contamination in heterogeneous aquifers. The application of the method is exemplified by a complete set of calculations characterizing the possible mineralization process at a specific channel in south central Kansas. Sensitivity analyses are performed and provide information about the importance of the various parameters that affect the mineralization process. Some possible scenarios for the aquifer mineralization phenomena are described and evaluated. It is shown that the channel mineralization may create either several stream tubes of the aquifer with high mineral concentration, or many stream tubes mineralized to a lesser extent. Characteristics of these two patterns of aquifer mineralization are quantified and discussed. ?? 2003 Published by Elsevier Science B.V.

Journal of Hydrology

Data-based comparisons of moments estimators using historical and paleoflood data

This paper presents the first systematic comparison, using historical and paleoflood data, of moments-based flood frequency methods. Peak flow estimates were compiled from streamflow-gaging stations with historical and/or paleoflood data at 36 sites located in the United States, Argentina, United Kingdom and China, covering a diverse range of hydrologic conditions. The Expected Moments Algorithm (EMA) and the Bulletin 17B historical weighting procedure (B17H) were compared in terms of goodness of fit using 25 of the data sets. Results from this comparison indicate that EMA is a viable alternative to current B17H procedures from an operational perspective, and performed equal to or better than B17H for the data analyzed. We demonstrate satisfactory EMA performance for the remaining 11 sites with multiple thresholds and binomial censoring, which B17H cannot accommodate. It is shown that the EMA estimator readily incorporates these types of information and the LP-III distribution provided an adequate fit to the data in most cases. The results shown here are consistent with Monte Carlo simulation studies, and demonstrate that EMA is preferred overall to B17H. The Bulletin 17B document could be revised to include an option for EMA as an alternative to the existing historical weighting approach. These results are of practical relevance to hydrologists and water resources managers for applications in floodplain management, design of hydraulic structures, and risk analysis for dams. ?? 2003 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Linking the pacific decadal oscillation to seasonal stream discharge patterns in Southeast Alaska

This study identified and examined differences in Southeast Alaskan streamflow patterns between the two most recent modes of the Pacific decadal oscillation (PDO). Identifying relationships between the PDO and specific regional phenomena is important for understanding climate variability, interpreting historical hydrological variability, and improving water-resources forecasting. Stream discharge data from six watersheds in Southeast Alaska were divided into cold-PDO (1947-1976) and warm-PDO (1977-1998) subsets. For all watersheds, the average annual streamflows during cold-PDO years were not significantly different from warm-PDO years. Monthly and seasonal discharges, however, did differ significantly between the two subsets, with the warm-PDO winter flows being typically higher than the cold-PDO winter flows and the warm-PDO summer flows being typically lower than the cold-PDO flows. These results were consistent with and driven by observed temperature and snowfall patterns for the region. During warm-PDO winters, precipitation fell as rain and ran-off immediately, causing higher than normal winter streamflow. During cold-PDO winters, precipitation was stored as snow and ran off during the summer snowmelt, creating greater summer streamflows. The Mendenhall River was unique in that it experienced higher flows for all seasons during the warm-PDO relative to the cold-PDO. The large amount of Mendenhall River discharge caused by glacial melt during warm-PDO summers offset any flow reduction caused by lack of snow accumulation during warm-PDO winters. The effect of the PDO on Southeast Alaskan watersheds differs from other regions of the Pacific Coast of North America in that monthly/seasonal discharge patterns changed dramatically with the switch in PDO modes but annual discharge did not. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Lag times of bank filtration at a well field, Cincinnati, Ohio, USA

Wells placed next to surface-water bodies to induce infiltration have come under scrutiny because of the presence of the potential pathogens in surface water. Removal of pathogens and other contaminants by bank filtration is assumed, but regulatory agencies question the effectiveness of this process. To investigate transport processes of biological constituents, advective groundwater traveltimes to production wells under the influence of surface water need to be established first to determine appropriate water-quality sampling schedules. This paper presents the results of a study of bank filtration at a well field in southwestern Ohio. Field parameters such as water level, specific conductance, and water temperature were measured at least hourly at a streamflow gaging station and at five monitoring wells each at two separate sites, corresponding to two nearby production wells. Water-quality samples also were collected in all wells and the streamflow gaging station. Specific conductance is directly related to concentration of chloride, a chemically conservative constituent. Cross-correlation methods were used to determine the average traveltime from the river to the monitoring wells. Traveltimes based on specific conductance ranged from approximately 20 h to 10 days at one site and 5 days to 3 months at the other site. Calculated groundwater flow velocities ranged from 2.1 ?? 10-3 to 6.0 ?? 10-3 cm/s and 3.5 ?? 10-4 to 7.1 ?? 10-4 cm/s at the two sites. Data collected when a production well is continuously pumping reveal shorter and more consistent traveltimes than when the same well is pumped intermittently. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Effect of flood-induced chemical load on filtrate quality at bank filtration sites

Riparian municipal wells, that are located on riverbanks, are specifically designed to capture a portion of the river water through induced infiltration. Runoff from agricultural watersheds is found to carry enormous amounts of pesticides and nitrate. While the risk of contamination for a vast majority of sites with small-capacity vertical wells is low, potential exists for medium to large capacity collector wells to capture a fraction of the surface water contaminants during flood. Prior monitoring and current modeling results indicate that a small-capacity (peak pumpage 0.0315 m3/s) vertical bank filtration well may not be affected by river water nitrate and atrazine even during flood periods. For a medium capacity (0.0875-0.175 m3/s) hypothetical collector well at the same site, potential exists for a portion of the river water nitrate and atrazine to enter the well during flood periods. Various combinations of hydraulic conductivity of the riverbed or bank material were used. For nitrate, it was assumed either no denitrification occurred during the period of simulation or a half-life of 2 years. Equilibrium controlled sorption (organic carbon partition coefficient of 52 ml/g) and a half-life of between 7.5 and 15 weeks were considered for atrazine. Combinations of these parameters were used in various simulations. Peak concentrations of atrazine or nitrate in pumped water could vary from less than 1% to as high as 90% of that in the river. It was found that a combination of river stage, pumping rates, hydraulic properties of the riverbed and bank, and soil/pesticide properties could affect contaminant entry from river water to any of these wells. If the hydraulic conductivity of the bed and bank material were low, atrazine would not reach the pumping well with or without sorption and degradation. However, for moderately low permeable bank and bed materials, some atrazine from river water could enter a hypothetical collector well while pumping at 0.0875 m3/s. It was interesting to note that doubling the pumpage of this collector well would bring in more ground water from the aquifer (with no atrazine) and thus have a lower concentration of atrazine in the filtrate. For highly conductive banks, it is possible to find some atrazine at a vertical well for a sustained pumpage rate of 0.0125 m3/s if the effect of sorption is neglected. However, with equilibrium sorption, the concentration would be below the detection limit. On the other hand, if a collector well of capacity 0.0875 m3/s is used at the place of the vertical well with highly conductive banks, atrazine concentration in the filtrate would be about 80% of river water even assuming equilibrium sorption and a half-life of 7.5 weeks. Remediation of river water contamination of the aquifer using 'scavenger' wells between the river and the pumping well(s) was not a feasible option due to the contact of the aquifer with a highly conductive bank at the site. However, moving the existing pumping well(s) 100 m upstream would have negligible impact from the bank-stored water. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Chemical analyses of pore water from boreholes USW SD-6 and USW WT-24, Yucca Mountain, Nevada

Analyses of pore water extracted from cores of boreholes USW SD-6 in the central part and USW WT-24 in the northern part of Yucca Mountain, Nevada, show significant vertical and lateral variations in dissolved-ion concentrations. Analyses of samples of only a few milliliters of pore water extracted by uniaxial or triaxial compression and by ultracentrifugation methods from adjacent core samples are generally in agreement, within the analytical error of 10% to 15%. However, the values of silica for water obtained by ultracentrifugation are consistently lower than values for water obtained by compression. The larger concentrations probably are due to localized pressure solution of silicate minerals during compression. The shallower water from core in borehole USW SD-6 was extracted from nonwelded units collectively referred to as the Paintbrush Tuff nonwelded (PTn). The deeper water was from core in both boreholes USW SD-6 and USW WT-24 in the nonwelded units referred to as the Calico Hills nonwelded (CHn). Significant differences in mean dissolved-ion concentrations in pore water between the PTn and CHn are (1) decreases in Ca, Mg, SO4, and NO3 and (2) increases in HCO3 and (Na+K)/(Ca+Mg) ratios. The decrease in NO3 and the increase in HCO3 could be the result of denitrification through the oxidation of organic matter. The decrease in Ca and associated increase in (Na+K)/(Ca+Mg) is the result of ion exchange with zeolites in the CHn in borehole USW WT-24. This effect is not nearly as pronounced in borehole USW SD-6, probably reflecting a smaller amount of zeolitization of the CHn in USW SD-6. Geochemical calculations using the PHREEQC code indicate that the pore water from both boreholes USW SD-6 and USW WT-24 is uniformly undersaturated in anhydrite, gypsum, and amorphous silica, but supersaturated in quartz and chalcedony. The saturation of calcite, aragonite, sepiolite, and dolomite is more variable from sample to sample. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology

Modeling radium and radon transport through soil and vegetation

A one-dimensional flow and transport model was developed to describe the movement of two fluid phases, gas and water, within a porous medium and the transport of 226Ra and 222Rn within and between these two phases. Included in this model is the vegetative uptake of water and aqueous 226Ra and 222Rn that can be extracted from the soil via the transpiration stream. The mathematical model is formulated through a set of phase balance equations and a set of species balance equations. Mass exchange, sink terms and the dependence of physical properties upon phase composition couple the two sets of equations. Numerical solution of each set, with iteration between the sets, is carried out leading to a set-iterative compositional model. The Petrov-Galerkin finite element approach is used to allow for upstream weighting if required for a given simulation. Mass lumping improves solution convergence and stability behavior. The resulting numerical model was applied to four problems and was found to produce accurate, mass conservative solutions when compared to published experimental and numerical results and theoretical column experiments. Preliminary results suggest that the model can be used as an investigative tool to determine the feasibility of phytoremediating radium and radon-contaminated soil. ?? 2003 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology

Can basin-scale recharge be estimated reasonably with water-balance models?

We examine in-place recharge as an example of the complex, basin-scale hydrologic processes that are being represented with simplified numerical models. The rate and distribution of recharge depend on local meteorological conditions and hydrogeologic properties. The pattern of recharge is defined predominantly by the distribution of net precipitation (precipitation less evapotranspiration), but different pedotransfer functions (PTFs) predict different fractions of precipitation that become in-place recharge at a given location. At any single location, these differences can often be explained on the basis of the PTF characteristics, but because of the complex averaging that occurs across a basin, the combined effects of meteorological variation and soil textural variation on the basin-wide recharge rates cannot be predicted on the basis of the characteristics of different PTFs. In fact, we show that the same basin-scale numerical model, using identical inputs and modeling options, can produce almost an order of magnitude variation in predicted basin total recharge depending on the choice of PTF. This suggests that sensitivity analyses should be performed on the choice of constitutive relationship (e.g., PTF) when assessing the predictive capability of basin-scale hydrologic models. ?? Soil Science Society of America.

Vadose Zone Journal

Transport of suspended solids from a karstic to an alluvial aquifer: The role of the karst/alluvium interface

This study focuses on the coupled transport of dissolved constituents and particulates, from their infiltration on a karst plateau to their discharge from a karst spring and their arrival at a well in an alluvial plain. Particulate markers were identified and the transport of solids was characterised in situ in porous and karstic media, based on particle size analyses, SEM, and traces. Transport from the sinkhole to the spring appeared to be dominated by flow through karst: particulate transport was apparently conservative between the two sites, and there was little difference in the overall character of the particle size distribution of the particulates infiltrating the sinkhole and of those discharging from the spring. Qualitatively, the mineralogy of the infiltrating and discharging material was similar, although at the spring an autochthonous contribution from the aquifer was noted (chalk particles eroded from the parent rock by weathering). In contrast, transport between the spring and the well appears to be affected by the overlying alluvium: particles in the water from the well, showed evidence of considerable size-sorting. Additionally, SEM images of the well samples showed the presence of particles originating from the overlying alluvial system; these particles were not found in samples from the sinkhole or the spring. The differences between the particulates discharging from the spring and the well indicate that the water pumped from the alluvial plain is coming from the karst aquifer via the very transmissive, complex geologic interface between the underlying chalk formation and the gravel at the base of the overlying alluvial system. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

The FORE-SCE model: a practical approach for projecting land cover change using scenario-based modeling

A wide variety of ecological applications require spatially explicit, historic, current, and projected land use and land cover data. The U.S. Land Cover Trends project is analyzing contemporary (1973&ndash;2000) land-cover change in the conterminous United States. The newly developed FORE-SCE model used Land Cover Trends data and theoretical, statistical, and deterministic modeling techniques to project future land cover change through 2020 for multiple plausible scenarios. Projected proportions of future land use were initially developed, and then sited on the lands with the highest potential for supporting that land use and land cover using a statistically based stochastic allocation procedure. Three scenarios of 2020 land cover were mapped for the western Great Plains in the US. The model provided realistic, high-resolution, scenario-based land-cover products suitable for multiple applications, including studies of climate and weather variability, carbon dynamics, and regional hydrology.

Journal of Land Use Science