USGS ScienceSearch

FIND YOUR NEXT DISCOVERY

Results for “Contributions to Mineralogy and Petrology”

Original records, connected by a shared subject.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,234 records · Page 2Linked to original sources

Distributed volcanic fields—Patterns, products, processes, and plumbing

Distributed volcanic fields—also referred to as “monogenetic fields” or simply “volcanic fields”—are found on every continent, on the seafloors, and in every tectonic setting on Earth. Yet, our understanding of what constitutes a distributed volcanic field, and our knowledge of the common products, spatiotemporal patterns in activity, and plumbing systems of these fields, are commonly poor and (or) debated. Here we provide an overview of the current understanding of distributed volcanic fields (DVFs) through review and compilation of published data, with an emphasis on understanding the characteristics of fields that are essential to prepare for future hazardous volcanic activity. Distributed fields can erupt restricted to variable magma compositions. Activity in these fields produces nearly all types of volcanoes, including scoria and spatter cones, maars, low shields, lava fields, stratovolcanoes, and calderas, but monogenetic volcanoes are the defining characteristic of DVFs. The number of vents and lifespans of DVFs vary greatly; vent numbers range from 2 to greater than 1,000, and fields can remain active for 150,000 to 10 million years. Some characteristics of DVFs appear field dependent. Although the volumes of single monogenetic eruptions within DVFs globally are variable (from less than 0.1 to a few cubic kilometers), each field may have a characteristic range in eruption volumes. Eruptions within distributed volcanic fields can have a random distribution and timing, but spatial and (or) temporal vent clustering and alignment are common, and eruptions may be time or volume predictable. Average eruption recurrence intervals in DVFs span over an order of magnitude, from less than 3 to greater than 100 thousand years. Exposures of the shallow portions of older systems reveal that many magma batches end their ascent before reaching the surface, with some dikes stopping within only meters of the surface. Petrologic insights into the deeper plumbing systems of DVF volcanoes indicate variable depths of magma crystallization and (or) stalling, and that magma transport and storage systems may be unique to a particular DVF and its underlying crustal structure. Both seismic and petrologic data for mafic DVF eruptions corroborate intrusions of magma into storage systems in the months to years before eruption, as well as variable ascent rates through the crust (days to weeks). Few distributed fields are closely monitored, as they erupt infrequently, but these observations imply that the amount of time available to install monitoring instrumentation after the first felt seismicity may be short, as precursory activity is frequently on the order of days to months for modern DVF eruptions. Satellite-based geodesy may provide useful warning in such cases. This chapter concludes with outstanding questions and areas for future research that will aid in our understanding and preparedness for future DVF eruptions.

Professional Paper

VIPER site analysis

We needed to evaluate available orbital data of NASA’s Volatiles Investigating Polar Exploration Rover (VIPER) mission area in order to derive a variety of maps to help the science team identify scientifically interesting places for the rover to visit and to provide scientific context for our mission. Some of these maps also fulfilled engineering and mission design needs to enable safe and efficient landing and roving. We incorporated data from the Lunar Reconnaissance Orbiter Camera, the Lunar Orbital Laser Altimeter, the Mini-RF instrument, the Chandrayaan-2 Orbital High Resolution Camera, the Korean Pathfinder Lunar Orbiter’s Shadowcam, the Kaguya Spectral Profiler and Multiband Imager, and the Chandrayaan-1 Moon Mineralogy Mapper. We used a variety of techniques to build these maps, including stereogrammetry, shape-from-shading, ice stability depth and surface temperature calculations, and the horizon method for solar illumination and direct-to-Earth communications maps. Altogether, these maps allowed us to survey for boulders, evaluate features in permanently shadowed regions that VIPER might explore, provide mineralogic context for what VIPER’s instruments may learn, estimate the ages and radar properties of craters in the VIPER mission area, and evaluate the potential for gravity traverses with the rover. These data and techniques provided a rich set of information from which both the VIPER science team and engineering teams were able to draw in order to plan a safe landing and to plan a VIPER surface mission that will be both scientifically valuable and robust from an operational perspective.

The Planetary Science Journal

Global pegmatite-hosted lithium, cesium, and rubidium resources: A dataset for grade and tonnage modeling

Quantitative mineral resource assessments of potential undiscovered deposits can inform future mineral supply scenarios, but their accuracy is conditional on building robust grade and tonnage models of known deposits. This study presents an up-to-date global compilation and analysis of recently discovered and original, in-situ pegmatite-hosted Li, Cs, and Rb resources prior to historic production. Our analysis yields a median tonnage of 21.2 million tons (Mt) and grade of 1.12% Li 2 O, respectively, for global Li pegmatite deposits ( n = 73). The grades and tonnages of Li pegmatite resources vary depending on the age of the bedrock host domain, pegmatite crystallization age, and primary ore mineralogy. Lithium pegmatite resources hosted in Archean to transitional Archean-Paleoproterozoic domains have the largest median tonnage (29.8 Mt; n = 38), and those hosted in Paleoproterozoic to Mesoproterozoic domains have smaller median tonnages (6.5 Mt; n = 16). Cesium deposits where pollucite is the primary ore mineral have a bimodal grade distribution, with modes of 2.40 and 0.035 wt% Cs 2 O for high- and low-grade deposits, respectively, while Rb deposits are more unimodal with a median grade of 0.247 wt% Rb 2 O. Pegmatite-hosted Cs and Rb resources have median tonnages of 7.6 and 6.3 Mt, respectively. Covariation between ore mineralogy and the degree of crustal enrichment in pegmatite-hosted deposits is diagnostic of petrogenetic differences, including melt source characteristics, magma evolution, or variable degrees of volatile solubility. The Li pegmatite compilation is suitable for fitting robust numerical models to support quantitative assessments. More well-defined Rb and Cs pegmatite resources are required for quantitative assessments, but these data provide useful information about original in-place resources for framing supply discussions.

Ore Geology Reviews

Zircon as a pathfinder to REE mineralization

Carbonatites and alkaline silicate rocks are major primary sources of the rare earth elements (REE) and other critical metals, such as Nb. Despite the economic significance of these rocks, their formation and the processes of REE enrichment are poorly understood. Here, statistical analysis of a global dataset demonstrates that zircon geochemistry is a powerful recorder of REE metallogenesis and a potential pathfinder for REE deposits. Zircons from REE and Nb fertile intrusions lack Eu anomalies and have elevated Gd/Yb and Th/Yb, indicating they crystallised from magmas that originated from deep, oxidised and enriched mantle sources. Complexes with Nb enrichment have low U/Nb, reflecting an enriched mantle source, whereas high U/Nb in REE-only fertile intrusions suggest a subduction-metasomatised mantle source. Machine learning models demonstrate high accuracy in classifying zircon from barren and fertile deposits. Classification of detrital zircons shows that REE-enriched deposits correlate with supercontinent assembly, whereas Nb fertile complexes are associated with supercontinent breakup. This approach offers a new, mineral to global scale, petrologic and exploration tool that enhances understanding of REE metallogenesis.

Geochemical Perspectives Letters

Rapid fault healing from cementation controls the dynamics of deep slow slip and tremor

Despite its status as one of the most important discoveries in geophysics, the physical mechanism(s) responsible for slow slip events (SSEs) are not well understood. Here, we synthesize observations of deep SSEs in the Cascadia Subduction Zone and argue that rapid, cohesive fault strengthening may control the dynamics of deep SSEs. Cohesive strength is frequently ignored in constitutive laws used to describe fault rheology in numerical simulations of earthquakes and SSEs alike. To demonstrate its importance, we perform and analyze a suite of petrological experiments that simulate fault healing under representative pressure and temperature conditions. We show that significant cohesive strength recovery caused by dissolution-precipitation processes occurs on timescales of just a few hours. Together, our experimental and observational results support the idea that cohesion is a key component of fault strength under SSE conditions and highlight the need for its inclusion in both future experiments and numerical models of fault slip.

British Columbia, Washington

Solution-collapse breccia pipe uranium deposits of the southern Colorado Plateau, northwestern Arizona, USA

Some of the highest-grade uranium deposits in the United States occur in breccia pipes that formed by solution and collapse of sedimentary strata, which occur in the southern portion of the Colorado Plateau in northwestern Arizona. The host breccia pipes are up to 1200 m in vertical extent, average about 90 m in diameter, and can cross-cut strata from their base in the Mississippian Redwall Limestone to as stratigraphically high on some plateaus as the Triassic Chinle Formation. These uranium-base metal deposits are up to 600 m thick and formed within the breccia pipes where they transect the Permian Coconino Sandstone, Hermit Formation, and the Esplanade Sandstone. Of the hundreds of breccia pipes identified across this region, only a small percentage are known to contain mineralization. The main uranium ore mineral is uraninite that is intergrown with at least 20 base-metal sulfide minerals, which contribute Fe, Cu, Co, As, Pb, Zn, Ni, and Ag to the deposits. This study considered regional stratigraphy, sulfur isotope systematics, mineralogy, in situ dating, and compilation and analysis of previous work on the deposits. A comprehensive deposit model has not been published for these deposits. This analysis identified new additions to update the deposit model for these unusual, possibly unique deposits. Proposed modifications to the model include: (1) the source, mechanisms, timing of the base-metal sulfide mineral assemblages, and (2) the source, mechanism, and timing of the uranium mineralization. Sulfide and uranium deposition are shown to be separate mineralization events. The study proposes the possible role of gypsum as a source of sulfur for the sulfide minerals in the deposits. Groundwaters carrying uranium encountered the preexisting sulfides in breccia pipes, reducing the uranyl ions, and precipitating U oxide (as uraninite). Analysis of the regional stratigraphy recognized that numerous beds of gypsum are in the strata that lie only tens of meters above the breccia pipe deposits. In the breccia pipe region, if these stratigraphic units (Toroweap and Kaibab Formations) do not contain gypsum layers then the underlying pipes are not mineralized; where these Permian gypsum layers do occur, breccia pipes can host mineralization. This new understanding should be useful in identifying the prospective region for mineralized pipes.

Arizona

Remote compositional analyses of space-weathered lunar maria

Visible-to-shortwave infrared (VSWIR) reflectance spectroscopy has revolutionized our understanding of planetary surface compositions. However, space-weathering processes on airless bodies complicate quantitative compositional analyses. Here, we present a framework to isolate the signatures of space weathering in VSWIR spectra of lunar maria by leveraging radiative transfer modeling under the assumptions that (i) a space-weathered target can be expressed as a mixture of fresh and fully space-weathered components and (ii) remaining signatures can be modeled by including agglutinates as an end-member component. We first validate this approach against laboratory spectra of space-weathered Apollo mare soils of known mineral compositions using a probabilistic Markov Chain Monte Carlo implementation of the Hapke radiative transfer model. Second, we illustrate how this approach can be applied to orbital Moon Mineralogy Mapper data. The proposed space-weathering correction workflow for lunar maria could be expanded to other lunar lithologies and applied to existing and future data sets.

Planetary Science Journal

Corundum discovered by SuperCam and the Perseverance rover at Jezero crater, Mars

Mars is primarily composed of mafic mineral assemblages and their alteration products, but small, scattered rocks strewn across the landscape offer clues to greater petrological diversity. While traversing the Jezero crater rim, the Perseverance rover encountered several plagioclase-rich light-toned float rocks. SuperCam identified the distinctive signature of corundum (α-Al 2 O 3 ) in these rocks using time-resolved luminescence spectroscopy. Two strong peaks (692.7 and 694.1 nm) with millisecond lifetimes, and additional supporting lines, are consistent with Cr 3+ substitution for Al 3+ in corundum. Corundum forms in Al-rich, Si-depleted environments through magmatic or metamorphic processes. Given the rocks' small size, association with plagioclase, and location on the crater rim, we interpret the most plausible formation scenario to be impact induced metamorphism at the interface of a felsic and a mafic/ultramafic member with the likely action of fluids at some stage, although other possibilities are not excluded.

Geophysical Research Letters

Case study of deep learning image segmentation for the purposes of rapid 2D petrographic analysis in volcanic rocks

Automation using deep learning methods is a useful alternative to manual methods of petrographic segmentation, but often requires user familiarity with coding and/or algorithms. We examine the Dragonfly TM program's deep learning tools for application by users with a variety of skill levels as a method for petrographic image segmentation. An image processing methodology, bimodal image stacking, was created for low-input-data, high-efficacy training of models which can then be applied to varied samples. Using backscatter electron images we show that the resulting model segmentations agree with manual segmentation total and modal crystallinity values within 5%, and calculated plagioclase crystal size distribution (CSD) values within 2σ, despite limitations in discriminating mafic phases. Model creation and training takes <24 hours, 1–3 hours of which are supervised, and the resultant model can then be applied to new uncharacterized samples in <15 minutes per image. This allows for non-experts to create and utilize deep learning models to segment images of variable brightness and texture, at low user-time cost and resulting in size and shape data which are within uncertainty of manual segmentation. While some limitations are noted (for example, sieve-textured phases may need manual correction, and different minerals with similar BSE intensity may not be resolved as separate phases), this methodology can be utilized for general application of models to wide ranges of volcanic crystalline and bubble textures, and to create a library of models for rapid petrological analysis during volcanic eruptions.

Alaska

Critical minerals in orogenic (gold) and Coeur d’Alene-type mineral systems of the United States

Orogenic and Coeur d’Alene-type mineral systems are produced by metamorphic devolatilization of thick volcanic or siliciclastic sedimentary rock sequences and the focused flow of hydrothermal fluids upwards along crustal-scale faults. Most orogenic systems are found along the Cordilleran orogen, stretching from California northwards into Alaska, whereas most Coeur d’Alene-type systems occur in the Proterozoic Belt Basin in Idaho and Montana. Although the deposit types in these systems are exploited for precious and base metals, potential exists for the production of critical minerals necessary for current (2025) societal needs in the United States. Publicly available geochemical data compiled for these mineral systems, coupled with mineralogical characteristics, indicate that several critical minerals could potentially be recovered from unmined resources and processed mine waste: arsenic, antimony, tellurium, cobalt, and tungsten from orogenic gold deposits and zinc, antimony, arsenic, and manganese from Coeur d’Alene-type systems. These critical minerals reside primarily in arsenopyrite (arsenic), scheelite (tungsten), siderite (manganese), sphalerite (zinc), tetrahedrite (antimony and arsenic), stibnite (antimony), and telluride (tellurium) minerals.

continental United States

Recycling radiogenic osmium by crustal foundering in subduction zones: Evidence from pyroxenite xenoliths in the north Andean arc

Removal of mafic-ultramafic lower crust (e.g., via delamination) is fundamental to making andesitic continental crust, yet direct evidence of this process remains elusive. A unique suite of garnet clinopyroxenite and hornblendite (arclogite) xenoliths from the northern volcanic zone of the Andes, erupted to the surface in the mid-Pleistocene, have bulk-rock geochemistry and osmium (Os) isotopic compositions that demonstrate their crustal affinity, yet have equilibration pressures and temperatures below the arc Mohorovičić discontinuity (~53 km) and some as deep as within the sub-arc mantle wedge (~105 km). Garnet websterites from the same xenolith suite, sourced from depths approaching the Wadati-Benioff zone (~140 km), have elemental and isotopic compositions indicative of a mantle origin, likely formed as products of peridotite-liquid reactions above the subducting slab. Variability in bulk-rock 143 Nd/ 144 Nd values and garnet oxygen isotope ratios ( 𝛿 18 O) for these samples is attributed to minor assimilation of subducted components and/or older crustal material, but assimilation alone cannot account for the highly radiogenic Os isotopic compositions. These results provide direct petrologic evidence for modern arclogite formation and foundering in the Andean orogen, the archetypal active continental subduction system. Elevated 187 Os/ 188 Os values of Mercaderes arclogites imply that recycling of gravitationally unstable arc cumulates during continental crust formation introduces highly radiogenic Os into the convective mantle, which has implications for mass fluxes across the crust-mantle boundary as well as the sources and evolution of mantle heterogeneity as seen in orogenic peridotite massifs and in the sources of oceanic basalts

Earth and Planetary Science Letters

Standardized method for logging drill core at the Idaho National Laboratory, Idaho

The U.S. Geological Survey’s (USGS) Lithologic Core Storage Library (CSL) at the Idaho National Laboratory stores more than 120,000 feet of drill core that is accessible to the public for research and sampling. To effectively convey the physical and descriptive properties of the drill core, USGS staff at the Idaho National Laboratory Project Office log the drill core and publish the lithologic logs as data releases. The logs provide essential data on the lithology, texture, mineralogy, alteration, and other physical properties of the core, which serve as valuable information for researchers to guide their research and sampling efforts. To ensure consistent, quality, and dependable lithologic logs, this document outlines the procedures and expectations for logging drill core at the CSL. This document describes the processes for storing, photographing, and logging core, and includes a variety of resources, reference materials, and appendixes designed to standardize and aid the logging process. Following the procedures outlined in this document will produce consistent, detailed logs that facilitate dependable observations and serve as an easy reference for researchers and other interested parties.

Idaho

Oligocene–Miocene development and evolution of the south Dome Rock Mountains basin, lower Colorado River corridor, Arizona, USA

Sedimentary basins in the Colorado River extensional corridor record large-magnitude Basin and Range extension and younger dextral shear deformation in the evolving Pacific−North America plate boundary. The south Dome Rock Mountains basin is located in west-central Arizona (USA), where the history of basin evolution, style of deformation, and timing of the transition between extension and dextral shear are not well constrained. We integrate new geologic mapping of the south Dome Rock Mountains basin with zircon U-Pb geochronology of six marker beds to characterize the timing of basin evolution and the slip history of the south Dome Rock Mountains normal fault. Structural analysis defines structures consistent with regional extension and younger dextral shear deformation. We use sedimentological and petrological analysis to interpret the depositional environments of three basin sequences. A lower basin sequence consists of fluvial strata deposited in an internally drained intermontane basin from ca. 35 Ma to 24.4 Ma. A sequence of volcanic rocks was emplaced in the basin between 24.4 Ma and 23.3 Ma, before the onset of local extensional faulting. An upper basin sequence of coarse conglomerate and sedimentary breccia was deposited on the hanging wall of a half graben structure after 23.3 Ma and through ca. 12.8 Ma, synchronous with 3−7 km of dip slip on the west-dipping, listric south Dome Rock Mountains fault. The basin was subsequently deformed by dextral shear after 12.8 Ma and before 4.8 Ma. These results document how distributed deformation related to the evolving Pacific−North America plate boundary occurred >100 km from the primary plate boundary.

Arizona, California

Geochemical evidence for the origin of late Quaternary loess, Seward Peninsula, Alaska

Loess is the most widespread surficial deposit in the state of Alaska. Although loess of last glacial age is common in mid-continental North America, records of last glacial loess in Alaska have been elusive. Here we report a record of last glacial loess on the Seward Peninsula, along with studies of a transect of loess localities also thought to date to the last glacial period. Highly diverse hypotheses on the origin of loess on the Seward Peninsula include local volcanic rocks and mountain ranges to the north and south, as well as offshore deposits. We present particle size and mineralogical and geochemical data that indicate that the most likely sources for loess in this part of eastern Beringia are glaciogenic silt particles of the Kobuk River and Noatak River, both of which drain the Brooks Range to the northeast. Northeasterly paleowinds were therefore responsible for loess on the Seward Peninsula. Such winds probably occurred during late summer or early autumn, when river discharge was at a minimum but temperatures were still above freezing. Northeasterly winds during the last glacial period are in good agreement with a recent paleoclimate model.

Alaska

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

Microtextural characteristics of adularia in banded quartz veins from the Midas low-sulfidation epithermal deposit, Nevada

High-grade ores at the Miocene Midas low-sulfidation epithermal deposit in northern Nevada are confined to crustiform quartz veins containing abundant adularia. Micro-X-ray fluorescence elemental mapping reveals that adularia is a common gangue mineral occurring in colloform bands, bands showing bladed textures, and bands with dendritic terminations. The adularia aggregates have delicate shapes and are comprised of stacked, submillimeter crystals hosted by fine-grained quartz. The textural evidence suggests that the adularia aggregates originally formed within a gel-like, noncrystalline silica matrix, which subsequently transformed into quartz. This indicates that the adularia did not precipitate in open space along the vein walls. Correlative microscopy, involving scanning electron microscopy-based automated mineralogy and optical petrography, demonstrates that bands containing abundant adularia are not the primary host to ore minerals. The ore minerals occur in different bands within the crustiform veins, implying that adularia and ore mineral precipitation did not always occur simultaneously. It is hypothesized here that fluid flow at Midas involved intermittent short-lived events of fluid flashing, causing rapid solute supersaturation in the liquid. During each flashing event, different amounts of vapor were produced along a given vein. Compositional differences between adjacent bands in the crustiform quartz veins may, therefore, be linked to variations in the amount of vapor formed during each flash event.

Nevada

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Using hydrogeologic context and water budgets to evaluate the potential for groundwater contributions to contaminants in Lake Superior

This study presents a synthesis of the hydrogeology in the U.S. Lake Superior watershed and the contribution of groundwater to the water budget of the U.S. Lake Superior basin. Much of the shoreline of Lake Superior in Minnesota and Michigan is composed of hydrogeologic units contributing very little direct groundwater discharge to the lake. Groundwater in watersheds adjacent to the lake typically flows in short, local flow systems characterized by thin glacial sediments with active groundwater flow in fractured bedrock within the top 60–90 m below land surface. The complex groundwater system in Wisconsin’s Bayfield Peninsula has the largest groundwater reservoir near the lake, characterized by thick sand and gravel glacial deposits and underlying sandstone aquifer. Although these thick sandy glacial deposits are not in direct contact with the lake at the shoreline, groundwater discharge may still be significant via subsurface exposures beyond the shoreline or flow through the underlying sandstone aquifer. Overall, most groundwater in the watershed is contributed as indirect base flow in streams around the lakeshore and comprises about 60 percent of the upland water budget. Direct groundwater flow to the shoreline contributes 2 to 9 percent of the inflow. Identifying possible contamination sources through direct sampling of groundwater would be an inefficient way to detect problems if sources are unknown, particularly for some chemicals of concern such as PFAS, pesticides, PCBs, chloride, and nutrients. Evaluating the chemical characteristics of contamination is also important to consider in evaluating how groundwater may contribute to pollution in Lake Superior.

Lake Superior