USGS Science⌕ Search

SEARCH · USGS Science

Results for “Carbon”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2Linked to original sources
USGS2023

The Coastal Carbon Library and Atlas: Open source soil data and tools supporting blue carbon research and policy

Quantifying carbon fluxes into and out of coastal soils is critical to meeting greenhouse gas reduction and coastal resiliency goals. Numerous ‘blue carbon’ studies have generated, or benefitted from, synthetic datasets. However, the community those efforts inspired does not have a centralized, standardized database of disaggregated data used to estimate carbon stocks and fluxes. In this paper, we describe a data structure designed to standardize data reporting, maximize reuse, and maintain a chain of credit from synthesis to original source. We introduce version 1.0.0. of the Coastal Carbon Library, a global database of 6723 soil profiles representing blue carbon-storing systems including marshes, mangroves, tidal freshwater forests, and seagrasses. We also present the Coastal Carbon Atlas, an R-shiny application that can be used to visualize, query, and download portions of the Coastal Carbon Library. The majority (4815) of entries in the database can be used for carbon stock assessments without the need for interpolating missing soil variables, 533 are available for estimating carbon burial rate, and 326 are useful for fitting dynamic soil formation models. Organic matter density significantly varied by habitat with tidal freshwater forests having the highest density, and seagrasses having the lowest. Future work could involve expansion of the synthesis to include more deep stock assessments, increasing the representation of data outside of the U.S., and increasing the amount of data available for mangroves and seagrasses, especially carbon burial rate data. We present proposed best practices for blue carbon data including an emphasis on disaggregation, data publication, dataset documentation, and use of standardized vocabulary and templates whenever appropriate. To conclude, the Coastal Carbon Library and Atlas serve as a general example of a grassroots F.A.I.R. (Findable, Accessible, Interoperable, and Reusable) data effort demonstrating how data producers can coordinate to develop tools relevant to policy and decision-making.

Global Change Biology↗
USGS2009

Ocean carbon and biogeochemistry scoping workshop on terrestrial and coastal carbon fluxes in the Gulf of Mexico, St. Petersburg, FL, May 6-8, 2008

Despite their relatively small surface area, ocean margins may have a significant impact on global biogeochemical cycles and, potentially, the global air-sea fluxes of carbon dioxide. Margins are characterized by intense geochemical and biological processing of carbon and other elements and exchange large amounts of matter and energy with the open ocean. The area-specific rates of productivity, biogeochemical cycling, and organic/inorganic matter sequestration are high in coastal margins, with as much as half of the global integrated new production occurring over the continental shelves and slopes (Walsh, 1991; Doney and Hood, 2002; Jahnke, in press). However, the current lack of knowledge and understanding of biogeochemical processes occurring at the ocean margins has left them largely ignored in most of the previous global assessments of the oceanic carbon cycle (Doney and Hood, 2002). A major source of North American and global uncertainty is the Gulf of Mexico, a large semi-enclosed subtropical basin bordered by the United States, Mexico, and Cuba. Like many of the marginal oceans worldwide, the Gulf of Mexico remains largely unsampled and poorly characterized in terms of its air-sea exchange of carbon dioxide and other carbon fluxes. In May 2008, the Ocean Carbon and Biogeochemistry Scoping Workshop on Terrestrial and Coastal Carbon Fluxes in the Gulf of Mexico was held in St. Petersburg, FL, to address the information gaps of carbon fluxes associated with the Gulf of Mexico and to offer recommendations to guide future research. The meeting was attended by over 90 participants from over 50 U.S. and Mexican institutions and agencies. The Ocean Carbon and Biogeochemistry program (OCB; http://www.us-ocb.org/) sponsored this workshop with support from the National Science Foundation, the National Oceanic and Atmospheric Administration, the National Aeronautics and Space Administration, the U.S. Geological Survey, and the University of South Florida. The goal of the workshop was to bring together researchers from multiple disciplines studying terrestrial, aquatic, and marine ecosystems to discuss the state of knowledge in carbon fluxes in the Gulf of Mexico, data gaps, and overarching questions in the Gulf of Mexico system. The discussions at the workshop were intended to stimulate integrated studies of marine and terrestrial biogeochemical cycles and associated ecosystems that will help to establish the role of the Gulf of Mexico in the carbon cycle and how it might evolve in the face of environmental change. The information derived from the plenary sessions, questions, and recommendations formulated by the participants will drive future research projects. Further discussion of carbon dynamics is needed to address scales of variability, the infrastructure required for study, and the modeling framework for cross-system integration. During the workshop, participants discussed and provided a number of priorities and recommendations, which are listed on p. 2 of the report. Participants recognized that the key to understanding the Gulf of Mexico system requires international collaboration with scientists from countries adjacent to the Gulf of Mexico. Improved collaboration across existing research community boundaries will be critical and should be encouraged by the funding agencies.

Open-File Report↗
USGS2006

Belowground carbon balance and carbon accumulation rate in the successional series of monsoon evergreen broad-leaved forest

The balance, accumulation rate and temporal dynamics of belowground carbon in the successional series of monsoon evergreen broadleaved forest are obtained in this paper, based on long-term observations to the soil organic matter, input and standing biomass of litter and coarse woody debris, and dissolved organic carbon carried in the hydrological process of subtropical climax forest ecosystem—monsoon evergreen broad-leaved forest, and its two successional forests of natural restoration—coniferous and broad-leaved mixed forest and Pinus massoniana forest, as well as data of root biomass obtained once every five years and respiration measurement of soil, litter and coarse woody debris respiration for 1 year. The major results include: the belowground carbon pools of monsoon evergreen broad-leaved forest, coniferous and broad-leaved mixed forest, and Pinus massoniana forest are 23191 ± 2538 g · m −2 , 16889 ± 1936 g · m −2 and 12680 ± 1854 g · m −2 , respectively, in 2002. Mean annual carbon accumulation rates of the three forest types during the 24a from 1978 to 2002 are 383 ± 97 g · m −2 · a −1 , 193 ± 85 g · m −2 · a −1 and 213 ± 86 g · m −2 · a −1 , respectively. The belowground carbon pools in the three forest types keep increasing during the observation period, suggesting that belowground carbon pools are carbon sinks to the atmosphere. There are seasonal variations, namely, they are strong carbon sources from April to June, weak carbon sources from July to September; while they are strong carbon sinks from October to November, weak carbon sinks from December to March.

Science in China, Series D: Earth Sciences↗
USGS2010

Public review draft: A method for assessing carbon stocks, carbon sequestration, and greenhouse-gas fluxes in ecosystems of the United States under present conditions and future scenarios

The Energy Independence and Security Act of 2007 (EISA), Section 712, authorizes the U.S. Department of the Interior to develop a methodology and conduct an assessment of the Nation's ecosystems focusing on carbon stocks, carbon sequestration, and emissions of three greenhouse gases (GHGs): carbon dioxide, methane, and nitrous oxide. The major requirements include (1) an assessment of all ecosystems (terrestrial systems, such as forests, croplands, wetlands, shrub and grasslands; and aquatic ecosystems, such as rivers, lakes, and estuaries), (2) an estimation of annual potential capacities of ecosystems to increase carbon sequestration and reduce net GHG emissions in the context of mitigation strategies (including management and restoration activities), and (3) an evaluation of the effects of controlling processes, such as climate change, land use and land cover, and wildlfires. The purpose of this draft methodology for public review is to propose a technical plan to conduct the assessment. Within the methodology, the concepts of ecosystems, carbon pools, and GHG fluxes used for the assessment follow conventional definitions in use by major national and international assessment or inventory efforts. In order to estimate current ecosystem carbon stocks and GHG fluxes and to understand the potential capacity and effects of mitigation strategies, the method will use two time periods for the assessment: 2001 through 2010, which establishes a current ecosystem GHG baseline and will be used to validate the models; and 2011 through 2050, which will be used to assess future potential conditions based on a set of projected scenarios. The scenario framework is constructed using storylines of the Intergovernmental Panel on Climate Change (IPCC) Special Report Emission Scenarios (SRES), along with initial reference land-use and land-cover (LULC) and land-management scenarios. An additional three LULC and land-management mitigation scenarios will be constructed for each storyline to enhance carbon sequestration and reduce GHG fluxes in ecosystems. Input from regional experts and stakeholders will be solicited to construct realistic and meaningful scenarios. The methods for mapping the current LULC and ecosystem disturbances will require the extensive use of both remote-sensing data and in-situ (for example, forest inventory data) to capture and characterize landscape-change events. For future potential LULC and ecosystem disturbances, key drivers such as socioeconomic, policy, and climate assumptions will be used in addition to biophysical data. The product of these analyses will be a series of maps for each future year for each scenario. These annual maps will form the basis for estimating carbon storage and GHG emissions. For terrestrial ecosystems, carbon storage, carbon-sequestration capacities, and GHG emissions under the current and projected future conditions will be assessed using the LULC and ecosystem-disturbance estimates in map format with a spatially explicit biogeochemical ensemble modeling system that incorporates properties of management activities (such as tillage or harvesting) and properties of individual ecosystems (such as elevation, vegetation characteristics, and soil attributes). For aquatic ecosystems, carbon burial in sediments and GHG fluxes are functions of the current and projected future stream flow and sediment transports, and therefore will be assessed using empirical modeling methods. Validation and uncertainty analysis methods described in the methodology will follow established guidelines to assess the quality of the assessment results. The U.S. Environmental Protection Agency's Level II ecoregions map (which delineates 24 ecoregions for the Nation) will be the practical instrument for developing and delivering assessment results. Consequently, the ecoregion will be the reporting unit of the assessment because the mitigation scenarios, assessment results, validation, and uncertainty analysis will be

Open-File Report↗
USGS1978

Distribution of organic carbon and petroleum source rock potential of Cretaceous and lower Tertiary carbonates, south Florida basin: Preliminary results

Analyses of 134 core samples from the South Florida Basin show that the carbonates of Comanchean age are relatively richer in average organic carbon (0.41 percent) than those of Coahuilan age (0.28 percent), Gulfian age (0.18 percent) and Paleocene age (0.20 percent). They are also nearly twice as rich as the average world, wide carbonate (average 0.24 percent). The majority of carbonates have organic carbons less than 0.30 percent but the presence of many relatively organic rich beds composed of highly bituminous, argillaceous, highly stylolitic, and algal-bearing limestones and dolomites accounts for the higher percentage of organic carbon in some of the stratigraphic units. Carbonate rocks that contain greater than 0.4 percent organic carbon and that might be considered as possible petroleum sources were noted in almost each subdivision of the Coahuilan and Comanchean Series but particularly the units of Fredericksburg 'B', Trinity 'A', Trinity 'F', and Upper Sunniland. Possible source rocks have been ascribed by others to the Lower Sunniland, but lack of sufficient samples precluded any firm assessment in this initial report. In the shallower section of the basin, organic-rich carbonates containing as much as 3.2 percent organic carbon were observed in the lowermost part of the Gulfian Series and carbonate rocks with oil staining or 'dead' and 'live oil' were noted by others in the uppermost Gulfian and upper Cedar Keys Formation. It is questionable whether these shallower rocks are of sufficient thermal maturity to have generated commercial oil. The South Florida basin is still sparsely drilled and produces only from the Sunniland Limestone at an average depth of 11,500 feet (3500 m). Because the Sunniland contains good reservoir rocks and apparently adequate source rocks, and because the success rate of new oil field discoveries has increased in recent years, the chances of finding additional oil reserves in the Sunniland are promising. Furthermore, the presence of possible source rocks in many of the other stratigraphic units, in particular, the Fredericksburg, should give further impetus to exploring for other productive horizons.

Florida↗
USGS2009

The stable carbon isotope biogeochemistry of acetate and other dissolved carbon species in deep subseafloor sediments at the northern Cascadia Margin

Ocean drilling has revealed the existence of vast microbial populations in the deep subseafloor, but to date little is known about their metabolic activities. To better understand the biogeochemical processes in the deep biosphere, we investigate the stable carbon isotope chemistry of acetate and other carbon-bearing metabolites in sediment pore-waters. Acetate is a key metabolite in the cycling of carbon in anoxic sediments. Its stable carbon isotopic composition provides information on the metabolic processes dominating acetate turnover in situ. This study reports our findings for a methane-rich site at the northern Cascadia Margin (NE Pacific) where Expedition 311 of the Integrated Ocean Drilling Program (IODP) sampled the upper 190 m of sediment. At Site U1329, δ 13 C values of acetate span a wide range from −46.0‰ to −11.0‰ vs. VPDB and change systematically with sediment depth. In contrast, δ 13 C values of both the bulk dissolved organic carbon (DOC) (−21.6 ± 1.3‰ vs. VPDB) and the low-molecular-weight compound lactate (−20.9 ± 1.8‰ vs. VPDB) show little variability. These species are interpreted to represent the carbon isotopic composition of fermentation products. Relative to DOC, acetate is up to 23.1‰ depleted and up to 9.1‰ enriched in 13 C. Broadly, 13 C-depletions of acetate relative to DOC indicate flux of carbon from acetogenesis into the acetate pool while 13 C-enrichments of pore-water acetate relative to DOC suggest consumption of acetate by acetoclastic methanogenesis. Isotopic relationships between acetate and lactate or DOC provide new information on the carbon flow and the presence and activity of specific functional microbial communities in distinct biogeochemical horizons of the sediment. In particular, they suggest that acetogenic CO 2 -reduction can coexist with methanogenic CO 2 -reduction, a notion contrary to the hypothesis that hydrogen levels are controlled by the thermodynamically most favorable electron-accepting process. Further, the isotopic relationship suggests a relative increase in acetate flow to acetoclastic methanogenesis with depth although its contribution to total methanogenesis is probably small. Our study demonstrates how the stable carbon isotope biogeochemistry of acetate can be used to identify pathways of microbial carbon turnover in subsurface environments. Our observations also raise new questions regarding the factors controlling acetate turnover in marine sediments.

Geochimica et Cosmochimica Acta↗
USGS2018

The North American carbon budget: Past, present, and future

This chapter nicely summarizes and synthesizes the latest scientific information on the North American carbon budget by incorporating terrestrial, anthropogenic, aquatic, and coastal margin CO 2 and CH 4 dynamics. Starting with a historical context, the chapter summarizes current understanding of the magnitudes and trends of carbon stocks and fluxes at the continental scale. It also provides a regional context by stratifying the continent to countries and climate assessment regions and discusses the societal drivers, impacts, and carbon management decisions. Knowledge gaps and research needs are also identified. This chapter is well-written and clearly organized, and provides a broad context beyond individual chapters. Some of the main ways the chapter can be improved include the following: some work is needed on the Key Findings (discussed below); the goals and objectives should be explicitly described; critical content areas missing from the chapter are interannual variability of carbon fluxes and impacts of severe and extended droughts; indicators and feedbacks are missing from Section 2.4; consistent use of units is recommended; numbers with 3-4 significant digits over-state the confidence the reader should have, and all numbers should include uncertainties. And one broader concern to note: This chapter follows the global overview in Chapter 1, where “sinks” are sinks in the cycle perturbed by anthropogenic CO 2 and CH 4 , and the assumption is that globally, the net unperturbed background sinks are zero summed across all reservoirs. Yet in this chapter, “sinks” are net fluxes out of the atmosphere, background + perturbation. For the coastal ocean, inland waters, etc.—where lateral transport is significant—these sources and sinks include background/pre-industrial fluxes that are balanced by fluxes elsewhere. These distinctions must be made clear so that the reader is not given an impression of a greater or lesser sink for anthropogenic CO 2 than is there (e.g., P74, lines 4-6).

Book chapter↗
USGS2025

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts↗
USGS2022

Transforming Palmyra Atoll to native-tree dominance will increase net carbon storage and reduce dissolved organic carbon reef runoff

Native forests on tropical islands have been displaced by non-native species, leading to calls for their transformation. Simultaneously, there is increasing recognition that tropical forests can help sequester carbon that would otherwise enter the atmosphere. However, it is unclear if native forests sequester more or less carbon than human-altered landscapes. At Palmyra Atoll, efforts are underway to transform the rainforest composition from coconut palm ( Cocos nucifera ) dominated to native mixed-species. To better understand how this landscape-level change will alter the atoll’s carbon dynamics, we used field sampling, remote sensing, and parameter estimates from the literature to model the total carbon accumulation potential of Palmyra’s forest before and after transformation. The model predicted that replacing the C . nucifera plantation with native species would reduce aboveground biomass from 692.6 to 433.3 Mg C. However, expansion of the native Pisonia grandis and Heliotropium foertherianum forest community projected an increase in soil carbon to at least 13,590.8 Mg C, thereby increasing the atoll’s overall terrestrial carbon storage potential by 11.6%. Nearshore sites adjacent to C . nucifera canopy had a higher dissolved organic carbon (DOC) concentration (110.0 μMC) than sites adjacent to native forest (81.5 μMC), suggesting that, in conjunction with an increase in terrestrial carbon storage, replacing C . nucifera with native forest will reduce the DOC exported from the forest into in nearshore marine habitats. Lower DOC levels have potential benefits for corals and coral dependent communities. For tropical islands like Palmyra, reverting from C . nucifera dominance to native tree dominance could buffer projected climate change impacts by increasing carbon storage and reducing coral disease.

PLoS ONE↗
USGS2013

USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗
USGS2013

USGS Arctic Ocean carbon cruise 2011: field activity H-01-11-AR to collect carbon data in the Arctic Ocean, August - September 2011

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗
USGS1985

Cyclic variations in calcium carbonate and organic carbon in Miocene to Holocene sediments, Walvis Ridge, South Atlantic Ocean

The entire upper Miocene to Holocene sedimentary sequence recovered in a hydraulic piston core at DSDP Site 532 on Walvis Ridge shows distinct cycles in amount of CaCO sub(3) that correlate with dark and light cycles of sediment color. The average periodicities of the carbonate cycles for the Quaternary, upper Pliocene, and lower Pliocene are about 35, 46, and 28 ky, respectively, with an overall average of about 36 ky for the last 5 my. Most minima in carbonate abundance correspond to dark parts of the color cycles, and most maxmia in carbonate abundance correspond to dark parts of color cycles, The darker parts of the color cycle usually contain higher concentrations of organic carbon, but organic carbon does not follow the color cycles in detail. Organic carbon cycles were analyzed only for the last 2.5 my, and for this interval they have an average periodicity of about 34 ky. The carbonate and color cycles persist through more than 5my during which major changes in relative proportions of siliceous-biogenic, calcareous- biogenic and terrigenous- clastic components occurent in response to climate change and to the waxing and waning of the Benguela Current upwelling systems off southwest Africa. The cyclic nature of these sediments probably is the result of dilution by terrigrnous clastic material and not dissolution of carbonate. We believe that the forcing mechanisms that produced the cycliclity was external to the area of site 532. Because of the similarity among the periodicities of the Walvis Ridge cycles and those of carbonate cycles in the northeastern Atlantic, Caribbean and eastern equatorial Pacific, these cycles probably are responses to global events. We conclude that fluctuations om global sea level with an average period of about 36 ky during the last 5 my caused variations in influx of terrigenous clastic materials from the Africans continental margin

Book chapter↗
USGS2006

North American prairie wetlands are important nonforested land-based carbon storage sites

We evaluated the potential of prairie wetlands in North America as carbon sinks. Agricultural conversion has resulted in the average loss of 10.1 Mg ha- 1 of soil organic carbon on over 16 million ha of wetlands in this region. Wetland restoration has potential to sequester 378 Tg of organic carbon over a 10-year period. Wetlands can sequester over twice the organic carbon as no-till cropland on only about 17% of the total land area in the region. We estimate that wetland restoration has potential to offset 2.4% of the annual fossil CO2 emission reported for North America in 1990. ?? 2005 Elsevier B.V. All rights reserved.

Science of the Total Environment↗
USGS1998

Terrestrial sedimentation and the carbon cycle: Coupling weathering and erosion to carbon burial

This paper examines the linkages between the carbon cycle and sedimentary processes on land. Available data suggest that sedimentation on land can bury vast quantities of organic carbon, roughly 10 15 g C yr −1 . To evaluate the relative roles of various classes of processes in the burial of carbon on land, terrestrial sedimentation was modeled as a series of 864 scenarios. Each scenario represents a unique choice of intensities for seven classes of processes and two different global wetland distributions. Comparison was made with presumed preagricultural conditions. The classes of processes were divided into two major component parts: clastic sedimentation of soil-derived carbon and organic sedimentation of autochthonous carbon. For clastic sedimentation, masses of sediment were considered for burial as reservoir sediment, lake sediment, and combined colluvium, alluvium, and aeolian deposits. When the ensemble of models is examined, the human-induced burial of 0.6-1.5·10 15 g yr −1 of carbon on land is entirely plausible. This sink reaches its maximum strength between 30° and 50° N. Paddy lands stand out as a type of land use that warrants future study, but the many faces of rice agriculture limit generalization. In an extreme scenario, paddy lands alone could be made to bury about 1·10 15 g C yr −1 . Arguing that terrestrial sedimentation processes could be much of the sink for the so called “missing carbon” is reasonable. Such a hypothesis, however, requires major redesign of how the carbon cycle is modeled. Unlike ecosystem processes that are amenable to satellite monitoring and parallel modeling, many aspects of terrestrial sedimentation are hidden from space.

Global Biogeochemical Cycles↗
USGS2005

Mississippian carbonate buildups and development of cool-waterlike carbonate platforms in the Illinois Basin, Midcontinent U.S.A.

Numerous biohermal buildups occur in Mississippian (Lower Carboniferous) strata in the Illinois Basin and adjacent regions. They developed as mud mounds, biodetrital calcisiltite mounds, and bryozoan frame thickets (fenestrate-frame coquina or rudstone) during the Kinderhookian and early Meramecian (Tournaisian and early Visean), and as microbial mud mounds, microbial- serpulidbryozoanboundstones, and solenoporoid (red algal) boundstones during the Chesterian (late Visean and Serpukhovian). True Waulsortian mounds did not develop in the Illinois Basin, but echinoderm (primarily crinoids)-bryozoan carbonate banks and bryozoan frame thickets generally occupied the same niche during the Kinderhookian-early Meramecian. Nutrient availability and the resulting increase in the productivity of echinoderms and bryozoans were apparently detrimental to Waulsortian mound development. Deposition of crinoidal-bryozoan carbonates during the Kinderhookian-Osagean initially occurred on a ramp setting that later evolved into a platform with a relatively steep margin through sediment aggradation and progradation. By mid-Osagean-early Meramecian, two such platforms, namely the Burlington Shelf and the Ullin Platform, developed adjacent to a deep, initially starved basin. Sedimentologic and petrographic characteristics of the Kinderhookian-earliest Meramecian carbonates resemble the modern cool-water Heterozoan Association. This is in contrast with post-earliest Meramecian carbonates, which are typically oolitic and peloidal with common peri tidal facies. The post-earliest Meramecian carbonates, therefore, resemble those of the warm-water Photozoan Association. The prevalence of Heterozoan carbonates in the Illinois Basin correlates with a rapid increase in the rate of subsidence and a major second-order eustatic sea-level rise that resulted in deep-water starved basins at this time. In the starved Illinois Basin, deposition was initially limited to a thin phosphatic shale that was followed later by deposition of up to 200 m of siliceous, spiculitic, and radiolarianbearing limestone. The starved basin was connected to the deep open ocean through a bathymetric depression, which was centered over the failed late Precambrian-Early Cambrian Reelfoot Rift, which extended from the deep-water Ouachita Trough in central Arkansas to southern Illinois, approximately parallel to the trend of the modern Mississippi River. We believe that upwelling of cool, nutrient- and silica-rich deep oceanic water, which entered the basin through this bathymetric depression, resulted in proliferation of pelmatozoans and bryozoans. The subsequent change from cool-water-like carbonates to warm-water-like carbonates appears to be related to decreased subsidence and gradual shallowing of the basin.

Illinois↗
USGS2013

Inorganic carbon loading as a primary driver of dissolved carbon dioxide concentrations in the lakes and reservoirs of the contiguous United States

Accurate quantification of CO 2 flux across the air-water interface and identification of the mechanisms driving CO 2 concentrations in lakes and reservoirs is critical to integrating aquatic systems into large-scale carbon budgets, and to predicting the response of these systems to changes in climate or terrestrial carbon cycling. Large-scale estimates of the role of lakes and reservoirs in the carbon cycle, however, typically must rely on aggregation of spatially and temporally inconsistent data from disparate sources. We performed a spatially comprehensive analysis of CO 2 concentration and air-water fluxes in lakes and reservoirs of the contiguous United States using large, consistent data sets, and modeled the relative contribution of inorganic and organic carbon loading to vertical CO 2 fluxes. Approximately 70% of lakes and reservoirs are supersaturated with respect to the atmosphere during the summer (June–September). Although there is considerable interregional and intraregional variability, lakes and reservoirs represent a net source of CO 2 to the atmosphere of approximately 40 Gg C d –1 during the summer. While in-lake CO 2 concentrations correlate with indicators of in-lake net ecosystem productivity, virtually no relationship exists between dissolved organic carbon and p CO 2,aq . Modeling suggests that hydrologic dissolved inorganic carbon supports p CO 2,aq in most supersaturated systems (to the extent that 12% of supersaturated systems simultaneously exhibit positive net ecosystem productivity), and also supports primary production in most CO 2 -undersaturated systems. Dissolved inorganic carbon loading appears to be an important determinant of CO 2 concentrations and fluxes across the air-water interface in the majority of lakes and reservoirs in the contiguous United States.

Global Biogeochemical Cycles↗
USGS2017

Stable C, O and clumped isotope systematics and 14C geochronology of carbonates from the Quaternary Chewaucan closed-basin lake system, Great Basin, USA: Implications for paleoenvironmental reconstructions using carbonates

Isotopic compositions of lacustrine carbonates are commonly used for dating and paleoenvironmental reconstructions. Here we use carbonate δ13C and δ18O, clumped (Δ47), and 14C compositions to better understand the carbonate isotope system in closed-basin lakes and trace the paleohydrologic and temperature evolution in the Chewaucan closed-basin lake system, northern Great Basin, USA, over the Last Glacial/Holocene transition. We focus on shorezone tufas to establish that they form in isotopic equilibrium with lake water and DIC, they can be dated reliably using 14C, and their clumped isotope composition can be used to reconstruct past lake temperature. Calculations of the DIC budget and reservoir age for the lake indicate residence time is short, and dominated by exchange with atmospheric CO2 at all past lake levels. Modern lake DIC and shorezone tufas yield δ13C and 14C values consistent with isotopic equilibrium with recent fossil fuel and bomb-influenced atmospheric CO2, supporting these calculations. δ13C values of fossil tufas are also consistent with isotopic equilibrium with pre-industrial atmospheric CO2 at all shoreline elevations. This indicates that the 14C reservoir effect for this material is negligible. Clumped isotope (Δ47) results indicate shorezone tufas record mean annual lake temperature. Modern (average 13 ± 2 °C) and 18 ka BP-age tufas (average 6 ± 2 °C) have significantly different temperatures consistent with mean annual temperature lowering of 7 ± 3 °C (1 SE) under full glacial conditions. For shorezone tufas and other lake carbonates, including spring mounds, mollusk shells, and ostracod tests, overall δ13C and δ18O values co-vary according to the relative contribution of spring and lacustrine end member DIC and water compositions in the drainage system, but specific isotope values depend strongly upon sample context and are not well correlated with past lake depth. This contrasts with the interpretation that carbonate isotopes in closed-basin lake systems reflect changes in DIC and water budgets connected to higher or lower lake volumes. Instead, a small overlapping range of isotope compositions characterize multiple lake levels, so that none can be identified uniquely by isotope composition alone. Relative to other lake carbonates, δ13C and δ18O values for ostracods in Ana River Canyon deposits are very strongly influenced by Ana River water, suggesting low lake level and volume characterized Summer Lake for most of the past 100,000 years. Coupled with sedimentologic observations, the Ana River deposits thus suggest dry conditions like today are close to the mean climate state in the northern Great Basin. By contrast, basin-integrating highstands such as that dating to ∼14 ka BP, during the last glacial termination, are hydrologically unique and short-lived. Overall, our results indicate carbonate isotope records must account for the specific geochemical and hydrologic characteristics of lake system in order to provide robust paleoenvironmental reconstructions.

Great Basin↗
USGS1967

Carbon-13-rich diagenetic carbonates in miocene formations of California and Oregon

Carbon unusually rich in C 13 (δC 13 = +5.4 to +19.0 per mil relative to the Peedee belemnite carbonate standard of the University of Chicago) is characteristic of certain diagenetic limestones and dolomites in the Miocene Monterey Shale of California and the Nye Mudstone of Oregon. This heavy carbon may have originated through low-temperature equilibration between CO 3 - - and CO 2 in migrating carbonated waters or between CH 4 and CO 2 in natural gas. Light carbon (δC 13 = -5.6 to -18.2 per mil) derived through nonequilibrium oxidation of organic matter also occurs in the carbonate of Monterey Shale in some localities, but at most places it is much less common than heavy carbon.

California, Oregon↗