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USGS2021

Sentinel-2 and WorldView-3 atmospheric correction and signal normalization based on ground-truth spectroradiometric measurements

Remote sensing satellite Earth Observing Systems (EOS) provide a variety of products for monitoring Earth surface processes at varying spatial and spectral resolutions. Combining information from high and medium spatial resolution images is valuable for monitoring ground cover and vegetation status in cropland, grassland, forests, and other natural settings. However, coupling information from different EOS requires compensating for atmospheric and view angle effects before integrating comparable surface reflectance (SR) values. The objectives of this study were i) to assess how different atmospheric constituents affect the atmospheric correction results in Sentinel-2 and WorldView-3 imagery, ii) to establish a relationship with field spectra measurements, and iii) to develop an empirical approach to ensure that SR values extracted from different EOS can be normalized for use in monitoring vegetation and land cover status. We compared surface reflectance values derived from Sentinel-2 images corrected with Sen2Cor, MODTRAN or FLAASH atmospheric correction approaches for the visible-to-near infrared regions. Additionally, this information was compared to SR values extracted from WorldView-3 imagery acquired from the same dates and location (Central Spain) and corrected with MODTRAN and FLAASH approaches. Assessment of the atmospheric correction was conducted by comparing satellite image SR with ground-truth spectra acquired with a FieldSpec hand-held spectroradiometer. The results emphasized the importance of using common atmospheric parameters collected from ancillary data sources (i.e. MODIS Atmosphere & Land products) to ensure a reliable SR comparison. When compared to field-collected spectral data, SR from corrected Sentinel-2 push-broom imagery showed a reliable match (<4% difference in the visible bands and <0.52% difference in the near infrared bands). However, SR imagery from the pointable WorldView-3 instrument showed significant deviation, likely resulting from the effects of steep off-nadir acquisition angles (24.6° to 39.1°) combined with surface anisotropy. The magnitude and sign of the deviation in SR differed depending on the vegetation type, wavelength and sun-surface-sensor geometry. Therefore, it was necessary to account for angular effects to ensure reliable comparisons of imagery from the different EOS. In this study, an empirical angular correction approach was developed based on calibrating each WorldView-3 band against the ground-truth spectra. This correction allowed for the accurate signal normalization of WorldView-3 and Sentinel-2 imagery SR in the visible-to-near infrared regions.

ISPRS Journal of Photogrammetry and Remote Sensing↗

USGS1997

Stable isotope evidence for an atmospheric origin of desert nitrate deposits in northern Chile and southern California, U.S.A.

Natural surficial accumulations of nitrate-rich salts in the Atacama Desert, northern Chile, and in the Death Valley region of the Mojave Desert, southern California, are well known, but despite many geologic and geochemical studies, the origins of the nitrates have remained controversial. N and O isotopes in nitrate, and S isotopes in coexisting soluble sulfate, were measured to determine if some proposed N sources could be supported or rejected, and to determine if the isotopic signature of these natural deposits could be used to distinguish them from various types of anthropogenic nitrate contamination that might be found in desert groundwaters. High-grade calich-a-type nitrate deposits from both localities have δ 15 N values that range from −5 to +5‰, but are mostly near 0‰. Values of δ 15 N near 0‰ are consistent with either bulk atmospheric N deposition or microbial N fixation as major sources of the N in the deposits. δ 18 O values of those desert nitrates with δ 15 N near 0‰ range from about +31 to +50‰ (V-SMOW), significantly higher than that of atmospheric O 2 (+23.5‰). Such high values of δ 18 O are considered unlikely to result entirely from nitrification of reduced N, but rather resemble those of modern atmospheric nitrate in precipitation from some other localities. Assuming that limited modern atmospheric isotope data are applicable to the deposits, and allowing for nitrification of co-deposited ammonium, it is estimated that the fraction of the nitrate in the deposits that could be, accounted for isotopically by atmospheric N deposition may be at least 20% and possibly as much as 100%. δ 34 S values are less diagnostic but could also be consistent with atmospheric components in some of the soluble sulfates associated with the deposits. The stable isotope data support the hypothesis that some high-grade caliche-type nitrate-rich salt deposits in some of the Earth's hyperarid deserts represent long-term accumulations of atmospheric deposition (possibly in the order of 104 yr for the Death Valley region, 10 7 yr for the Atacama Desert) in the relative absence of soil leaching or biologic cycling. The combined N and O isotope signature of the nitrate in these deposits is significantly different from those of many other natural and anthropogenic sources of nitrate.

Chemical Geology↗

USGS2011

Strong atmospheric chemistry feedback to climate warming from Arctic methane emissions

The magnitude and feedbacks of future methane release from the Arctic region are unknown. Despite limited documentation of potential future releases associated with thawing permafrost and degassing methane hydrates, the large potential for future methane releases calls for improved understanding of the interaction of a changing climate with processes in the Arctic and chemical feedbacks in the atmosphere. Here we apply a “state of the art” atmospheric chemistry transport model to show that large emissions of CH4 would likely have an unexpectedly large impact on the chemical composition of the atmosphere and on radiative forcing (RF). The indirect contribution to RF of additional methane emission is particularly important. It is shown that if global methane emissions were to increase by factors of 2.5 and 5.2 above current emissions, the indirect contributions to RF would be about 250% and 400%, respectively, of the RF that can be attributed to directly emitted methane alone. Assuming several hypothetical scenarios of CH4 release associated with permafrost thaw, shallow marine hydrate degassing, and submarine landslides, we find a strong positive feedback on RF through atmospheric chemistry. In particular, the impact of CH4 is enhanced through increase of its lifetime, and of atmospheric abundances of ozone, stratospheric water vapor, and CO2 as a result of atmospheric chemical processes. Despite uncertainties in emission scenarios, our results provide a better understanding of the feedbacks in the atmospheric chemistry that would amplify climate warming.

Global Biogeochemical Cycles↗

USGS2010

Response of the water level in a well to Earth tides and atmospheric loading under unconfined conditions

The response of the water level in a well to Earth tides and atmospheric loading under unconfined conditions can be explained if the water level is controlled by the aquifer response averaged over the saturated depth of the well. Because vertical averaging tends to diminish the influence of the water table, the response is qualitatively similar to the response of a well under partially confined conditions. When the influence of well bore storage can be ignored, the response to Earth tides is strongly governed by a dimensionless aquifer frequency Q ′ u . The response to atmospheric loading is strongly governed by two dimensionless vertical fluid flow parameters: a dimensionless unsaturated zone frequency, R , and a dimensionless aquifer frequency Q u . The differences between Q ′ u and Q u are generally small for aquifers which are highly sensitive to Earth tides. When Q ′ u and Q u are large, the response of the well to Earth tides and atmospheric loading approaches the static response of the aquifer under confined conditions. At small values of Q ′ u and Q u , well response to Earth tides and atmospheric loading is strongly influenced by water table drainage. When R is large relative to Q u , the response to atmospheric loading is strongly influenced by attenuation and phase shift of the pneumatic pressure signal in the unsaturated zone. The presence of partial penetration retards phase advance in well response to Earth tides and atmospheric loading. When the theoretical response of a phreatic well to Earth tides and atmospheric loading is fit to the well response inferred from cross-spectral estimation, it is possible to obtain estimates of the pneumatic diffusivity of the unsaturated zone and the vertical hydraulic conductivity of the aquifer.

Water Resources Research↗

USGS2007

Effects of the atmosphere on the detection of surface changes from Landsat multispectral scanner data

The atmospheric effects on radiometric data recorded in the Landsat multispectral scanner system (MSS) bands are compiled for cases of representative and ideal atmospheric conditions. The effects are expressed as a difference between the Earth's surface spectral reflectivity, a 0 , and the surface-atmosphere system spectral reflectivity, a s , derived from the satellite data, a s −a 0 = −a 0 [l+(l/μ 0 )](B+W) + 2a 2 0 B + g(μ 0 )B/2μ 0 where μ 0 is the cosine of the solar zenith angle, B and W are the backscattering and absorption optical thickness respectively, and the function g( μ 0 ) is the anisotropy of backscattering to the zenith from the direct beam. This formula is accurate only for an atmosphere of low optical thickness. Also, the equation applies only to large areas having a uniform reflectivity, because adjacency effects due to reflection from the terrain surrounding the object pixel and subsequent scattering by the atmosphere are not considered. It is concluded that in the quantitative monitoring of surface changes from satellites, scattering effects predominate in some applications (for example, bathy-metric mapping of coastal waters), whereas absorption effects predominate in other applications (for example, monitoring desert fringe areas). Different measurements are more appropriate for assessing the scattering effects than for assessing the absorption effects. These effects on the monitoring of surface changes by the use of Landsat MSS data are discussed in terms of departures of the actual atmosphere at the time of a satellite passage from a ‘minima’ atmosphere having no aerosols and characterized by gaseous absorption corresponding to minimal water vapour amounts.

International Journal of Remote Sensing↗

USGS1995

Pesticides in the atmosphere; distribution, trends, and governing factors

A comprehensive review of existing literature on the occurrence and distribution of pesticides in the atmosphere of the United States and adjoining Canadian provinces showed that the atmosphere is an important part of the hydrologic cycle that acts to distribute and deposit pesticides in areas far removed from their application sites. A compilation of existing data shows that pesticides have been detected in the atmosphere throughout the nation. Most of the available information on pesticides in the atmosphere is from small-scale, short-term studies that seldom lasted more than one year. Only two national-scale, multi-year studies were done since the late 1960's that analyzed for a wide variety of pesticides in air that were in current use at the time. Another large-scale study was done during 1990-91, but was limited to the midwestern and northeastern United States and only analyzed for two classes of herbicides in wet deposition. Most of the pesticides analyzed for were detected in either air or rain, and represent about 25 percent of the total number of insecticides, herbicides, and fungicides in current use. The geographical distribution of studies, and the type of sampling and analysis were highly variable with most of the historical study efforts concentrated in the Great Lakes area and California. Air and rain were the main atmospheric matrices sampled, but pesticides were also detected in fog and snow. Reported pesticide concentrations in air and rain were frequently positively correlated to their regional agricultural use. Deviations from this relation could usually be explained by non-agricultural use of pesticides, sampling and analytical difficulties, and environmental persistence. High concentrations of locally used pesticides were found to occur seasonally, usually in conjunction with spring planting of row crops and warm temperatures, but high concentrations also occurred during winter months in those areas where dormant orchards were sprayed. The environmentally more persistent pesticides were detected in the atmosphere at low concen- trations throughout the year. Deposition of airborne pesticides can have significant effects on water quality, but neither the nature of nor the magnitude of these effects can be determined with certainty on the basis of the type of data currently available. The lack of consistent, long-term regional and national monitoring and study of pesticides in atmospheric matrices severely limits assessment capability.

Open-File Report↗

USGS1984

Atmospheric deposition of selected chemicals and their effect on nonpoint-source pollution in the Twin Cities Metropolitan Area, Minnesota

Atmospheric deposition and subsequent runoff concentrations of total Kjeldahl nitrogen, dissolved nitrite-plus-nitrate nitrogen, total phosphorus, total sulfate (only for atmospheric deposition), total chloride, and total lead were studied from April 1 to October 31, 1980, in one rural and three urban watersheds in the Twin Cities Metropolitan Area, Minnesota. Seasonal patterns of wetfall and dryfall generally were similar for all constituents except chloride in both rural and urban watersheds. Similarity between constituents and between rural and urban watersheds suggested that regional air masses transported from the Gulf of Mexico by frontal storm movements influence seasonal patterns of atmospheric deposition in the metropolitan area. Local influences such as industrial, agricultural, and vehicular air pollutants were found to influence the magnitude or rate of atmospheric deposition rather than the seasonal pattern. Chloride was primarily influenced by northwest frontal storms laden with coastal chloride. Local influences such as dust from road deicing salt dust are thought to have caused an increase in atmospheric chloride during June. The atmospheric contribution to nonpoint-source-runoff pollution of nitrogen, in the form of nitrite-plus-nitrate, and lead was extremely high contributing as much as 84 percent of the runoff load. In contrast, phosphorus and chloride inputs were low averaging of 6 percent of the total runoff load. Future investigations of nonpoint-source pollution in runoff might include collection of data on atmospheric deposition of nitrite-plus-nitrate nitrogen and lead because of the importance of that source of these constituents in runoff.

Twin Cities Metropolitan Area↗

USGS1999

The sensitivity of terrestrial carbon storage to historical climate variability and atmospheric CO2 in the United States

We use the Terrestrial Ecosystem Model (TEM, Version 4.1) and the land cover data set of the international geosphere-biosphere program to investigate how increasing atmospheric CO2 concentration and climate variability during 1900-1994 affect the carbon storage of terrestrial ecosystems in the conterminous USA, and how carbon storage has been affected by land-use change. The estimates of TEM indicate that over the past 95 years a combination of increasing atmospheric CO2 with historical temperature and precipitation variability causes a 4.2% (4.3 Pg C) decrease in total carbon storage of potential vegetation in the conterminous US, with vegetation carbon decreasing by 7.2% (3.2 Pg C) and soil organic carbon decreasing by 1.9% (1.1 Pg C). Several dry periods including the 1930s and 1950s are responsible for the loss of carbon storage. Our factorial experiments indicate that precipitation variability alone decreases total carbon storage by 9.5%. Temperature variability alone does not significantly affect carbon storage. The effect of CO2 fertilization alone increases total carbon storage by 4.4%. The effects of increasing atmospheric CO2 and climate variability are not additive. Interactions among CO2, temperature and precipitation increase total carbon storage by 1.1%. Our study also shows substantial year-to-year variations in net carbon exchange between the atmosphere and terrestrial ecosystems due to climate variability. Since the 1960s, we estimate these terrestrial ecosystems have acted primarily as a sink of atmospheric CO2 as a result of wetter weather and higher atmospheric CO2 concentrations. For the 1980s, we estimate the natural terrestrial ecosystems, excluding cropland and urban areas, of the conterminous US have accumulated 78.2 Tg C yr-1 because of the combined effect of increasing atmospheric CO2 and climate variability. For the conterminous US, we estimate that the conversion of natural ecosystems to cropland and urban areas has caused a 18.2% (17.7 Pg C) reduction in total carbon storage from that estimated for potential vegetation. The carbon sink capacity of natural terrestrial ecosystems in the conterminous US is about 69% of that estimated for potential vegetation.

Tellus, Series B: Chemical and Physical Meteorolog↗

USGS2012

An assessment of the carbon balance of arctic tundra: comparisons among observations, process models, and atmospheric inversions

Although arctic tundra has been estimated to cover only 8% of the global land surface, the large and potentially labile carbon pools currently stored in tundra soils have the potential for large emissions of carbon (C) under a warming climate. These emissions as radiatively active greenhouse gases in the form of both CO 2 and CH 4 could amplify global warming. Given the potential sensitivity of these ecosystems to climate change and the expectation that the Arctic will experience appreciable warming over the next century, it is important to assess whether responses of C exchange in tundra regions are likely to enhance or mitigate warming. In this study we compared analyses of C exchange of Arctic tundra between 1990–1999 and 2000–2006 among observations, regional and global applications of process-based terrestrial biosphere models, and atmospheric inversion models. Syntheses of the compilation of flux observations and of inversion model results indicate that the annual exchange of CO 2 between arctic tundra and the atmosphere has large uncertainties that cannot be distinguished from neutral balance. The mean estimate from an ensemble of process-based model simulations suggests that arctic tundra acted as a sink for atmospheric CO 2 in recent decades, but based on the uncertainty estimates it cannot be determined with confidence whether these ecosystems represent a weak or a strong sink. Tundra was 0.6 °C warmer in the 2000s compared to the 1990s. The central estimates of the observations, process-based models, and inversion models each identify stronger sinks in the 2000s compared with the 1990s. Similarly, the observations and the applications of regional process-based models suggest that CH 4 emissions from arctic tundra have increased from the 1990s to 2000s. Based on our analyses of the estimates from observations, process-based models, and inversion models, we estimate that arctic tundra was a sink for atmospheric CO 2 of 110 Tg C yr -1 (uncertainty between a sink of 291 Tg C yr -1 and a source of 80 Tg C yr -1 ) and a source of CH 4 to the atmosphere of 19 Tg C yr -1 (uncertainty between sources of 8 and 29 Tg C yr -1 ). The suite of analyses conducted in this study indicate that it is clearly important to reduce uncertainties in the observations, process-based models, and inversions in order to better understand the degree to which Arctic tundra is influencing atmospheric CO 2 and CH 4 concentrations. The reduction of uncertainties can be accomplished through (1) the strategic placement of more CO 2 and CH 4 monitoring stations to reduce uncertainties in inversions, (2) improved observation networks of ground-based measurements of CO 2 and CH 4 exchange to understand exchange in response to disturbance and across gradients of hydrological variability, and (3) the effective transfer of information from enhanced observation networks into process-based models to improve the simulation of CO 2 and CH 4 exchange from arctic tundra to the atmosphere.

Biogeosciences↗

USGS2008

Atmospheric mercury accumulation and washoff processes on impervious urban surfaces

The deposition and transport of mercury (Hg) has been studied extensively in rural environments but is less understood in urbanized catchments, where elevated atmospheric Hg concentrations and impervious surfaces may efficiently deliver Hg to waterways in stormwater runoff. We determined the rate at which atmospheric Hg accumulates on windows, identified the importance of washoff in removing accumulated Hg, and measured atmospheric Hg concentrations to help understand the relationship between deposition and surface accumulation. The main study location was Toronto, Ontario. Similar samples were also collected from Austin, Texas for comparison of Hg accumulation between cities. Windows provided a good sampling surface because they are ubiquitous in urban environments and are easy to clean/blank allowing the assessment of contemporary Hg accumulation. Hg Accumulation rates were spatially variable ranging from 0.82 to 2.7 ng m-2 d-1 in Toronto and showed similar variability in Austin. The highest accumulation rate in Toronto was at the city center and was 5?? higher than the rural comparison site (0.58 ng m-2 d-1). The atmospheric total gaseous mercury (TGM) concentrations were less than 2?? higher between the rural and urban locations (1.7 ?? 0.3 and 2.7 ?? 1.1 ng m-3, respectively). The atmospheric particulate bound fraction (HgP), however, was more than 3?? higher between the rural and urban sites, which may have contributed to the higher urban Hg accumulation rates. Windows exposed to precipitation had 73 ?? 9% lower accumulation rates than windows sheltered from precipitation. Runoff collected from simulated rain events confirmed that most Hg accumulated on windows was easily removed and that most of the Hg in washoff was HgP. Our results indicate that the Hg flux from urban catchments will respond rapidly to changes in atmospheric concentrations due to the mobilization of the majority of the surface accumulated Hg during precipitation events. ?? 2008 Elsevier Ltd.

Atmospheric Environment↗

USGS2003

Atmospheric nitrogen deposition in the Rocky Mountains of Colorado and southern Wyoming - A review and new analysis of past study results

The Rocky Mountain region of Colorado and southern Wyoming receives as much as 7kgha-1yr-1 of atmospheric nitrogen (N) deposition, an amount that may have caused changes in aquatic and terrestrial life in otherwise pristine ecosystems. Results from published studies indicate a long-term increase in the rate of atmospheric N deposition during the 20th century, but data from the National Atmospheric Deposition Program and Clean Air Status and Trends Network show no region-wide increase during the past 2 decades. Nitrogen loads in atmospheric wet deposition have increased since the mid-1980s, however, at three high elevation (>3000m) sites east of the Continental Divide in the Front Range. Much of this increase is the result of increased ammonium (NH4+) concentrations in wet deposition. This suggests an increase in contributions from agricultural areas or from vehicles east of the Rocky Mountains and is consistent with the results of previous studies that have suggested a significant eastern source for atmospheric N deposition to the Front Range. The four sites with the highest NH4+ concentrations in wet deposition were among the six easternmost NADP sites, which is also consistent with a source to the east of the Rockies. This analysis found an increase in N loads in wet deposition at Niwot Ridge of only 0.013kgha-1yr-1, more than an order of magnitude less than previously reported for this site. This lower rate of increase results from application of the non-parametric Seasonal Kendall trend test to mean monthly data, which failed a test for normality, in contrast to linear regression, which was applied to mean annual data in a previous study. Current upward trends in population growth and energy use in Colorado and throughout the west suggest a need for continued monitoring of atmospheric deposition of N, and may reveal more widespread trends in N deposition in the future.

Atmospheric Environment↗

USGS2019

Virus-like particle production in atmospheric eubacteria isolates

Culturable eubacterial isolates were collected at various altitudes in Earth’s atmosphere to include ~1.5 m above ground in Tallahassee, Florida, USA, ~10.0 m above sea level over the mid-Atlantic ridge (~15oN), ~ 20 km above ground over the continental United States, ~20 km above sea level over the Pacific Ocean near southern California and from the atmosphere of Carlsbad Cavern, Carlsbad Cavern National Park, New Mexico, USA. Isolates were screened for the presence of inducible virus-like particles (VLP) through use of mitomycin C and epifluorescent direct counts. We determined that 92.7% of the isolates carried inducible (VLP) counts in exposed versus non-exposed culture controls and that the relationship was statistically significant. Further statistical analyses revealed that the numbers of isolates that demonstrated VLP production did not vary among collection sites. These data demonstrate a high prevalence of VLP generation in isolates collected in the lower atmosphere and at extreme altitudes. Also shows that species of eubacteria that are resistant to the rigors of atmospheric transport play a significant role in long-range atmospheric inter- and intra-continental dispersion of VLP and that long-range atmospheric transport of VLP may enhance rates of evolution at the microbial scale in receiving environments.

Atmosphere↗

USGS2005

Transmission of atmospherically derived trace elements through an undeveloped, forested Maryland watershed

The transmission of atmospherically derived trace elements (Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn) was evaluated in a small, undeveloped, forested watershed located in north-central Maryland. Atmospheric input was determined for wet-only and vegetative throughfall components. Annual throughfall fluxes were significantly enriched over incident precipitation for most elements, although some elements exhibited evidence of canopy release (Mn) or preferential uptake (As, Cr, and Se). Stream export was gauged based on systematic sampling under varied flow regimes. Particle loading appears to contribute significantly to watershed export (> 10%) for only As, Pb, and Fe, and then only during large precipitation/runoff events. The degree of watershed transmission for each trace element was evaluated based on a comparison of total, net atmospheric input (throughfall) to stream export over an annual hydrologic cycle. This comparison indicates that the atmospheric input of some elements (Al, Cd, Ni, Zn) is effectively transmitted through the watershed, but other elements (Pb, As, Se, Fe, Cr, Cu) appear to be strongly sequestered, in the respective orders noted. Results suggest that precipitation and subsequent soil pH are the primary factors that determine the mobility of sequestered trace element phases. To further resolve primary atmospheric and secondary weathering components, the geochemical model NETPATH was applied. Results indicate that minerals dissolved include chlorite, plagioclase feldspar, epidote, and potassium feldspar; phases formed were kaolinite, pyrite, and silica. The model also indicates that weathering processes contribute negligible amounts of trace elements to stream export, indicative of the unreactive orthoquartzite bedrock lithology underlying the watershed. Thus, the stream export of trace elements primarily reflects atmospheric deposition to the local watershed.

Maryland↗

USGS1989

Recharge of the early atmosphere of Mars by impact-induced release of CO2

Channels on the Martian surface suggest that Mars had an early, relatively thick atmosphere. If the atmosphere was thick enough for water to be stable at the surface, CO 2 in the atmosphere would have been fixed as carbonates on a relatively short time scale, previously estimated to be 1 bar every 10 7 years. This loss must have been offset by some replenishment mechanism to account for the numerous valley networks in the oldest surviving terrains. Impacts could have released CO 2 into the atmosphere by burial, by shock-induced release during impact events, and by addition of carbon to Mars from the impacting bolides. Depending on the relationship between the transient cavity diameter and the diameter of the resulting crater, burial rates as a result of impact gardening at the end of heavy bombardment are estimated to range from 20 to 45 m/10 6 years, on the assumption that cratering rates in Mars were similar to those of the Nectarian Period on the Moon. At these rates 0.1-0.2 bar of CO 2 could have been released every 107 years as a result of burial to depths where dissociation temperatures of carbonates were reached. Modeling of large impacts suggests that an additional 0.01 to 0.02 bar of CO 2 could have been released every 10 7 years during the actual impacts. In the unlikely event that all the impacting material was composed of carbonaceous chondrites, a further 0.3 bar of CO 2 could have been added to the atmosphere every 10 7 years by oxidation of meteoritic carbon. Even when supplemented by the volcanically induced release of CO 2 , these release rates are barely sufficient to sustain an early atmosphere if water were continuously present at the surface. The results suggest that water may have been only intermittently present on the surface early in the planet's history.

Icarus↗

USGS1992

Triton's surface-atmosphere energy balance

We explore the energetics of Triton's surface-atmosphere system using a model that includes the turbulent transfer of sensible heat as well as insolation, reradiation, and latent heat transport. The model relies on a 1° by 1° resolution hemispheric bolometric albedo map of Triton for determining the atmospheric temperature, the N 2 frost emissivity, and the temperatures of unfrosted portions of the surface consistent with a frost temperature of ≅38 K. For a physically plausible range of heat transfer coefficients, we find that the atmospheric temperature roughly 1 km above the surface is approximately 1 to 3 K hotter than the surface. Atmospheric temperatures of 48 K suggested by early analysis of radio occultation data cannot be obtained for plausible values of the heat transfer coefficients. Our calculations indicate that Triton's N 2 frosts must have an emissivity well below unity in order to have a temperature of ≅38 K, consistent with previous results. We also find that convection over small hot spots does not significantly cool them off, so they may be able to act as continous sources of buoyancy for convective plumes, but have not explored whether the convection is vigorous enough to entrain particulate matter thereby forming a dust devil. Our elevated atmospheric temperatures make geyser driven plumes with initial upward velocities ≤10 m s −1 stagnate in the lower atmosphere. These “wimpy” plumes provide a possible explanation for Triton's “wind streaks.”

Icarus↗

USGS2017

Atmospheric deposition to forests in the eastern USA

Atmospheric mercury (Hg) deposition to forests is important because half of the land cover in the eastern USA is forest. Mercury was measured in autumn litterfall and weekly precipitation samples at a total of 27 National Atmospheric Deposition Program (NADP) monitoring sites in deciduous and mixed deciduous-coniferous forests in 16 states in the eastern USA during 2007–2014. These simultaneous, uniform, repeated, annual measurements of forest Hg include the broadest area and longest time frame to date. The autumn litterfall-Hg concentrations and litterfall mass at the study sites each year were combined with annual precipitation-Hg data. Rates of litterfall-Hg deposition were higher than or equal to precipitation-Hg deposition rates in 70% of the annual data, which indicates a substantial contribution from litterfall to total atmospheric-Hg deposition. Annual litterfall-Hg deposition in this study had a median of 11.7 μg per square meter per year (μg/m 2 /yr) and ranged from 2.2 to 23.4 μg/m 2 /yr. It closely matched modeled dry-Hg deposition, based on land cover at selected NADP Hg-monitoring sites. Mean annual atmospheric-Hg deposition at forest study sites exhibited a spatial pattern partly explained by statistical differences among five forest-cover types and related to the mapped density of Hg emissions. Forest canopies apparently recorded changes in atmospheric-Hg concentrations over time because litterfall-Hg concentrations decreased year to year and litterfall-Hg concentrations were significantly higher in 2007–2009 than in 2012–2014. These findings reinforce reported decreases in Hg emissions and atmospheric elemental-Hg concentrations during this same time period. Methylmercury (MeHg) was detected in all litterfall samples at all sites, compared with MeHg detections in less than half the precipitation samples at selected sites during the study. These results indicate MeHg in litterfall is a pathway into the terrestrial food web where it can accumulate in the prey of songbirds, bats, and raptors.

Environmental Pollution↗

USGS2002

Atmospheric mercury deposition during the last 270 years: A glacial ice core record of natural and anthropogenic sources

Mercury (Hg) contamination of aquatic ecosystems and subsequent methylmercury bioaccumulation are significant environmental problems of global extent. At regional to global scales, the primary mechanism of Hg contamination is atmospheric Hg transport. Thus, a better understanding of the long-term history of atmospheric Hg cycling and quantification of the sources is critical for assessing the regional and global impact of anthropogenic Hg emissions. Ice cores collected from the Upper Fremont Glacier (UFG), Wyoming, contain a high-resolution record of total atmospheric Hg deposition (ca. 1720−1993). Total Hg in 97 ice-core samples was determined with trace-metal clean handling methods and low-level analytical procedures to reconstruct the first and most comprehensive atmospheric Hg deposition record of its kind yet available from North America. The record indicates major atmospheric releases of both natural and anthropogenic Hg from regional and global sources. Integrated over the past 270-year ice-core history, anthropogenic inputs contributed 52%, volcanic events 6%, and background sources 42%. More significantly, during the last 100 years, anthropogenic sources contributed 70% of the total Hg input. Unlike the 2−7-fold increase observed from preindustrial times (before 1840) to the mid-1980s in sediment-core records, the UFG record indicates a 20-fold increase for the same period. The sediment-core records, however, are in agreement with the last 10 years of this ice-core record, indicating declines in atmospheric Hg deposition.

Environmental Science & Technology↗

USGS1999

Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater

The atmosphere as a source of volatile organic compounds (VOCs) in shallow groundwater was evaluated over an area in southern New Jersey. Chloroform, methyl tertbutyl ether (MTBE), 1,1,1‐trichloroethane, tetrachloroethylene (PCE), and carbon disulfide (not a VOC) were detected frequently at low‐level concentrations in a network of 78 shallow wells in the surficial Kirkwood‐Cohansey aquifer system. The atmosphere was sampled for these compounds and only MTBE concentrations were high enough to potentially explain frequent detection in shallow groundwater. A mathematical model of reactive transport through the unsaturated zone is presented to explain how variations in unsaturated properties across the study area could explain differences in MTBE concentrations in shallow groundwater given the atmosphere as the source. Even when concentrations of VOCs in groundwater are low compared to regulatory concentration limits, it is critical to know the source. If the VOCs originate from a point source((), concentrations in groundwater could potentially increase over time to levels of concern as groundwater plumes evolve, whereas if the atmosphere is the source, then groundwater concentrations would be expected to remain at low‐level concentrations not exceeding those in equilibrium with atmospheric concentrations. This is the first analysis of VOC occurrence in shallow groundwater involving colocated atmosphere data.

Water Resources Research↗