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Mineral resources of Antarctica

Although the existence of mineral deposits in Antarctica is highly probable, the chances of finding them are quite small. Minerals have been found there in great variety but only as occurrences. Manganese nodules, water (as ice), geothermal energy, coal, petroleum, and natural gas are potential resources that could perhaps be exploited in the future. On the basis of known mineral occurrences in Antarctica and relationships between geologic provinces of Antarctica and those of neighboring Gondwana continents, the best discovery probability for a base-metal deposit in any part of Antarctica is in the Andean orogen; it is estimated to be 0.075 (75 chances in 1,000).

Circular↗

Playa-lake sedimentation and organic matter accumulation in an Andean piggyback basin: The recent record from the Cuenca de Pozuelos, NW Argentina

Expansive playa‐lake systems situated in high‐altitude piggyback basins are important and conspicuous components of both modern and ancient cordilleran orogenic systems. Extant playa lakes provide vital habitat for numerous endemic species, whereas sediments from these deposystems may record signals of climate change or develop natural resources over geological time. Laguna de los Pozuelos (North‐west Argentina) provides the opportunity for an actualistic sedimentological and geochemical assessment of a piggyback basin playa lake in an area of critical interest for understanding Quaternary palaeoclimate dynamics. Silty clays and diatom ooze are the dominant playa‐lake centre microfacies, with concentrations of total organic carbon and biogenic silica commonly exceeding 1·5 wt% in this sub‐environment. Elemental and stable isotopic analyses point to a mixed organic matter composition in the playa‐lake centre, with substantial contributions from algae and transported aquatic macrophytes. Bulk sediment and organic mass accumulation rates in the southern playa‐lake centre approach 0.22g cm −2 year −1 and 2.89 mg cm −2 year −1 , respectively, indicating moderately rapid deposition with negligible deflation over historic time. Playa margin facies contain higher percentages of fragmented biogenic carbonate (ostracods and charophytes) and inorganically precipitated aragonite crusts due to seasonal pumping and evaporation of ground water. Organic matter accumulation is limited along these heavily bioturbated wet and dry mud flats. Fluvial–lacustrine transitional environments, which are key waterbird habitats, are either silty terminal splay (northern axis) or sandy deltas (southern axis) containing highly oxidized and partially allochthonous organic matter. Modern analogue data from Laguna de los Pozuelos provide key insights for: (i) environmental reconstructions of ancient lake sequences; and (ii) improving facies models for piggyback basins.

Cuenca de Pozuelos↗

The history of a continent from U-Pb ages of zircons from Orinoco River sand and Sm-Nd isotopes in Orinoco basin river sediments

We report SHRIMP U-Pb ages of 49 zircons from a sand sample from the lower Orinoco River, Venezuela, and Nd model ages of the fine sediment load from the main river and tributaries. The U-Pb ages reflect individual magmatic or metamorphic events, the Sm-Nd model ages reflect average crustal-residence ages of the sediment sources. Together they allow delineation of the crust-formation history of the basement precursors of the sediments. The U-Pb ages range from 2.83 to 0.15 Ga, and most are concordant or nearly so. Discrete age groupings occur at ??? 2.8, ??? 2.1, and ??? 1.1 Ga. The oldest group contains only three samples but is isolated from its closest neighbors by a ??? 600 Ma age gap. Larger age groupings at ??? 2.1 and ??? 1.1 Ga make up about a third and a quarter of the total number of analyses, respectively. The remaining analyses scatter along concordia, and most are younger than 1.6 Ga. The ??? 2.8 and ??? 2.1 Ga ages correspond to periods of crust formation of the Imataca and Trans-Amazonian provinces of the Guyana Shield, respectively, and record intervals of short but intensive continental growth. These ages coincide with ??? 2.9 and ??? 2.1 Ga Nd model ages of sediments from tributaries draining the Archean and Proterozoic provinces of the Guyana Shield, respectively, indicating that the U-Pb ages record the geological history of the crystalline basement of the Orinoco basin. Zircons with ages corresponding to the major orogenies of the North Atlantic continents (the Superior at ??? 2.7 Ga and Hudsonian at 1.7-1.9 Ga) were not found in the Orinoco sample. The age distribution may indicate that South and North America were separated throughout their history. Nd model ages of sediments from the lower Orinoco River and Andean tributaries are ??? 1.9 Ga, broadly within the range displayed by major rivers and dusts. This age does not coincide with known thermal events in the region and reflects mixing of sources with different crust-formation ages. The igneous and metamorphic history of these sources, as recorded by the detrital zircons, is that of the Orinoco basin basement. This implies that, despite evidence of fast sedimentary recycling, global similarities in Nd crustal-residence ages, and the probability of cross-continent mixing through continental drift, the sedimentary material carried by individual rivers is mainly derived from the crystalline basement in the basin. The global semblance in Nd isotope ratios in major river sediments and atmospheric dusts results from the averaging effect of large-scale sampling of the continents, which are heterogeneous in age on smaller regional scales. A large portion of the continental crust in the Orinoco basin formed during the Trans-Amazonian orogeny at 2.0-2.1 Ga, and smaller portions formed both earlier, at ??? 2.8 Ga, and later, after 1.6 Ga. These observations, which are consistent with the relative sizes of crustal age provinces in the Orinoco basin, indicate that sediments from the lower Orinoco and Andean tributaries contain 25-35% of material added to the crust since Trans-Amazonian times. Nd model ages of these sediments underestimate the average crust-formation age of the basement of the Orinoco basin by only about 10%. If this relationship holds in other river basins, then Nd model ages of major rivers and wind blown particulates indicate that the mean age of the continental crust is ??? 1.9-2 Ga. ?? 1997 Elsevier Science B.V.

Chemical Geology↗

Volcanism and erosion during the past 930 k.y. at the Tatara-San Pedro complex, Chilean Andes

Geologic mapping, together with 73 new K-Ar and 40 Ar/ 39 Ar age determinations of 45 samples from 17 different volcanic units, plus paleomagnetic orientations, geochemical compositions, and terrestrial photogrammetry are used to define the chronostratigraphy of the Tatara–San Pedro complex, an eruptive center at 36°S on the volcanic front of the Andean southern volcanic zone. The Tatara–San Pedro complex preserves ≈55 km 3 of lavas that erupted from at least three central vent regions. Remnant, unconformity-bound sequences of lavas are separated by lacunae that include significant periods of erosion. Quaternary volcanism commenced ca. 930 ka with eruption of voluminous dacitic magma, followed 100 k.y. later by the only major rhyolitic eruption. From 780 ka onward, more than 80% of the preserved volume is basaltic andesite (52%–57% SiO 2 ), but petrographically and geochemically diverse dacitic magmas (63%–69% SiO 2 ) erupted sporadically throughout this younger, dominantly mafic phase of activity. A few basaltic lavas (49%–52% SiO 2 ) are present, mainly in portions of the complex older than 230 ka. The number of vents, the petrologic and geochemical diversity, and the temporal distribution of mafic and silicic lavas are consistent with emplacement of many separate batches of mafic magma into the shallow crust beneath the Tatara–San Pedro complex over the past million years.

Geological Society of America Bulletin↗

Porphyry copper deposit density

Estimating numbers of undiscovered mineral deposits has been a source of unease among economic geologists yet is a fundamental task in considering future supplies of resources. Estimates can be based on frequencies of deposits per unit of permissive area in control areas around the world in the same way that grade and tonnage frequencies are models of sizes and qualities of undiscovered deposits. To prevent biased estimates it is critical that, for a particular deposit type, these deposit density models be internally consistent with descriptive and grade and tonnage models of the same type. In this analysis only deposits and prospects that are likely to be included in future grade and tonnage models are employed, and deposits that have mineralization or alteration separated by less than an arbitrary but consistent distance—2 km for porphyry copper deposits—are combined into one deposit. Only 286 deposits and prospects that have more than half of the deposit not covered by postmineral rocks, sediments, or ice were counted. Nineteen control areas were selected and outlined along borders of hosting magmatic arc terranes based on three main features: (1) extensive exploration for porphyry copper deposits, (2) definable geologic settings of the porphyry copper deposits in island and continental volcanic-arc subduction-boundary zones, and (3) diversity of epochs of porphyry copper deposit formation. Porphyry copper deposit densities vary from 2 to 128 deposits per 100,000 km 2 of exposed permissive rock, and the density histogram is skewed to high values. Ninety percent of the control areas have densities of four or more deposits, 50 percent have densities of 15 or more deposits, and 10 percent have densities of 35 or more deposits per 100,000 km 2 . Deposit density is not related to age or depth of emplacement. Porphyry copper deposit density is inversely related to the exposed area of permissive rock. The linear regression line and confidence limits constructed with the 19 control areas can be used to estimate the number of undiscovered deposits, given the size of a permissive area. In an example of the use of the equations, we estimate a 90 percent chance of at least four, a 50 percent chance of at least 11, and a 10 percent chance of at least 34 undiscovered porphyry copper deposits in the exposed parts of the Andean belt of Antarctica, which has no known deposits in a permissive area of about 76,000 km 2 . Measures of densities of deposits presented here allow rather simple yet robust estimation of the number of undiscovered porphyry copper deposits in exposed or covered permissive terranes.

Economic Geology↗

Fire in Mediterranean climate ecosystems-A comparative overview

Four regions of the world share a similar climate and structurally similar plant communities with the Mediterranean Basin. These five areas, known collectively as "mediterranean-type climate (MTC) regions", are dominated by evergreen sclerophyllous-leaved shrublands, semi-deciduous scrub, and woodlands, all of which are prone to widespread crown fires. Summer droughts produce an annual fire hazard that contributes to a highly predictable fire regime. Fire has been an important factor driving the convergence of these systems and is reflected in plant traits such as lignotubers in resprouting shrubs and delayed reproduction that restricts recruitment to a postfire pulse of seedlings. On fertile soils where postfire resprouting is very rapid, opportunities for postfire seedling recruitment are limited and thus these woody taxa have not opted for delaying reproduction. Such fire-independent recruitment is widespread in the floras of MTC regions of the Mediterranean Basin and California and postfire seeding tends to dominate at the more arid end of the gradient. Due to very different geological histories in South Africa and Western Australia, substrates are nutrient poor and thus postfire resprouters do not pose a similar competitive challenge to seedlings and thus postfire seeding is very widespread in these floras. Although circumstantial evidence suggests that the MTC region of Chile had fire-prone landscapes in the Tertiary, these were lost with the late Miocene completion of the Andean uplift, which now blocks summer lightning storms from moving into the region. Today these five regions pose a significant fire management challenge due to the annual fire hazard and metropolitan centers juxtaposed with highly flammable vegetation. This challenge varies across the five MTC landscapes as a function of differences in regional fuel loads and population density.

Israel Journal of Ecology and Evolution↗

Detrital zircon evidence for progressive underthrusting in Franciscan metagraywackes, west-central California

We present new U/Pb ages for detrital zircons separated from six quartzose metagraywackes collected from different Franciscan Complex imbricate nappes around San Francisco Bay. All six rocks contain a broad spread of Late Jurassic-Cretaceous grains originating from the Klamath-Sierra Nevada volcanic-plutonic arc. Units young structurally downward, consistent with models of progressive underplating and offscraping within a subduction complex. The youngest specimen is from the structurally lowest San Bruno Mountain sheet; at 52 Ma, it evidently was deposited during the Eocene. None of the other metagraywackes yielded zircon ages younger than 83 Ma. Zircons from both El Cerrito units are dominated by ca. 100-160 Ma grains; the upper El Cerrito also contains several grains in the 1200-1800 Ma interval. These samples are nearly identical to 97 Ma metasedimentary rock from the Hunters Point shear zone. Zircon ages from this m??lange block exhibit a broad distribution, ranging from 97 to 200 Ma, with only a single pre-Mesozoic age. The Albany Hill specimen has a distribution of pre-Mesozoic grains from 1300 to 1800 Ma, generally similar to that of the upper El Cerrito sheet; however, it contains zircons as young as 83 Ma, suggesting that it is significantly younger than the upper El Cerrito unit. The Skaggs Spring Schist is the oldest studied unit; its youngest analyzed grains were ca. 144 Ma, and it is the only investigated specimen to display a significant Paleozoic detrital component. Sedimentation and subduction-accretion of this tract of the trench complex took place along the continental margin during Early to early-Late Cretaceous time, and perhaps into Eocene time. Franciscan and Great Valley deposition attests to erosion of an Andean arc that was active over the entire span from ca. 145 to 80 Ma, with an associated accretionary prism built by progressive underthrusting. We use these new data to demonstrate that the eastern Franciscan Complex in the northern and central Coast Ranges is a classic accretionary prism, where younger, structurally lower allochthons are exposed on the west, and older, structurally higher allochthons occur to the east, in the heavily studied San Francisco Bay area. ?? 2009 Geological Society of America.

Geological Society of America Bulletin↗

An Appalachian isochron: A kaolinized Carboniferous air-fall volcanic-ash deposit (tonstein)

The Fire Clay tonstein is a kaolinized, airfall volcanic ash bed that was deposited in a widespread late Carboniferous peat-forming mire. Eleven samples from Kentucky and West Virginia, spanning a distance of 200 km, and two samples from Tennessee and Virginia indicate a characteristic mineralogical signature, as compared with other Appalachian tonsteins, consisting of well-crystallized kaolinite, beta-quartz crystal paramorphs, sanidine, ilmenite, zircon, and brookite. Detrital illite and quartz are rarely present or are in very small amounts, which indicates rapid deposition in a mire. Several normal graded cycles in this tonstein suggest repeated episodes of pyroclastic activity that produced a composite ash layer. A high-silica alkalic rhyolitic source is suggested by the geochemistry of immobile elements and by electron-probe analyses of glass inclusions in volcanic quartz from the Fire Clay tonstein. The rare-earth-element plots (chondrite normalized) of the tonstein show a pronounced negative Eu anomaly and relatively high concentrations of Zr and Th, which are both indicative of a rhyolitic source. Probe analyses of the Fire Clay glass inclusions from four states indicate a chemically identical high-silica rhyolite with peraluminous affinities. 40 Ar/ 39 Ar sanidine plateau dating indicates an age of 312 ± 1 Ma for the Fire Clay tonstein, which is consistent with previous 40 Ar/ 39 Ar dates for this tonstein. This age is in agreement with a late Westphalian B age in the European Carboniferous chronostratigraphy on the basis of an age of 311 Ma for the Westphalian B/C boundary. A new isopachous map of the Fire Clay ash-fall deposit indicates an area of 37,000 km 2 and a probable source to the present-day southwest. The deposit has a minimum preserved compacted volume of 2.8 km 3 , which corresponds to an original uncompacted volume of about 20 km 3 . This preserved volume indicates an ultraplinian volcanic explosion. Pindell and Dewey (1982) proposed an Andean-type arc in this block during the late Carboniferous, prior to South American-North American plate collision. We hypothesize an associated back-arc caldera system in the Yucatan block to explain the high-silica, potassic rhyolitic ash that gave rise to the Fire Clay tonstein.

Geological Society of America Bulletin↗

Evidence for primitive magma storage and eruption following prolonged equilibration in thickened crust

In continental arcs, the exposure of primitive eruptive products at the surface is typically a result of rapid magmatic transfer through the crust. As a result, the initially primitive magma experiences minimal crustal residence and thus insignificant differentiation towards more evolved products. This rapid transfer of primitive magma through thickened crust is commonly recorded from smaller, monogenetic cinder cones. Manantial Pelado (35.5° S) is a long-lived stratocone in the Southern Andean Volcanic Zone (SVZ) overlying thick continental crust (45–50 km) that produces almost exclusively mafic material. As Manantial Pelado is surrounded by extensive silicic volcanism, the study of its mafic exposure as a stratocone can be used to further understand magmatic origins of long-lived volcanic systems. Our study uses textural, geochemical, and geochronological data from lavas collected from Manantial Pelado to characterize its magmatic petrogenesis, assess the primitive nature, and explain processes in the crust within the SVZ. A geologic description of the volcano reveals a mostly monotonous eruptive history of basaltic andesites that are now accessible through glacially carved valleys. New 40 Ar/ 39 Ar dating constrains most of the volcano’s cone constructing phase to last from ~ 220 to 190 ka. At ~ 30 ka, small-volume activity and different petrography of more intermediate magmas were present reflecting a change in the volcano’s character. A combination of the whole-rock and mineral-scale data reveals that basaltic andesites at Manantial Pelado are among the most primitive magmas in the thickened crust of the SVZ. Evidence for this primitive signature consists of textural and zonation patterns in olivine, the presence of Cr-spinel in olivine cores, and elevated Fo and Ni content within olivine cores. This data combined with elemental diffusion modeling provides evidence for a primitive signature for these lavas. Intermediate Fo olivines with uniform core compositions (Fo 80–84 ) suggest that basaltic andesites reside in the crust in quasi-closed system environments for extended storage prior to eruption (~ 25–6000 years). Diffusive equilibration in those intermediate Fo olivines masks the primitive nature of the magmas. These results suggest that mafic magmas can have a protracted storage history in the crust that does not significantly alter their primitive bulk composition before reaching the surface. We argue that these are important processes in understanding the magmatic origin of long-lived systems and the presence of compositionally homogenous olivines at intermediate Fo content may represent cryptic evidence for recharge with primitive magmas that experienced prolonged crustal storage.

Manantial Pelado↗

Tectonic controls of Mississippi Valley-type lead-zinc mineralization in orogenic forelands

Most of the world's Mississippi Valley-type (MVT) zinc-lead deposits occur in orogenic forelands. We examine tectonic aspects of foreland evolution as part of a broader study of why some forelands are rich in MVT deposits, whereas others are barren. The type of orogenic foreland (collisional versus Andean-type versus inversion-type) is not a first-order control, because each has MVT deposits (e.g., Northern Arkansas, Pine Point, and Cevennes, respectively). In some MVT districts (e.g., Tri-State and Central Tennessee), mineralization took place atop an orogenic forebulge, a low-amplitude (a few hundred meters), long-wavelength (100-200 km) swell formed by vertical loading of the foreland plate. In the foreland of the active Banda Arc collision zone, a discontinuous forebulge reveals some of the physiographic and geologic complexities of the forebulge environment, and the importance of sea level in determining whether or not a forebulge will emerge and thus be subject to erosion. In addition to those on extant forebulges, some MVT deposits occur immediately below unconformities that originated at a forebulge, only to be subsequently carried toward the orogen by the plate-tectonic conveyor (e.g., Daniel's Harbour and East Tennessee). Likewise, some deposits are located along syn-collisional, flexure-induced normal and strike-slip faults in collisional forelands (e.g., Northern Arkansas, Daniel's Harbour, and Tri-State districts). These findings reveal the importance of lithospheric flexure, and suggest a conceptual tectonic model that accounts for an important subset of MVT deposits-those in the forelands of collisional orogens. The MVT deposits occur both in flat-lying and in thrust-faulted strata; in the latter group, mineralization postdated thrusting in some instances (e.g., Picos de Europa) but may have predated thrusting in other cases (e.g., East Tennessee).

Mineralium Deposita↗

Ordovician K-bentonites in the Argentine Precordillera: Relations to Gondwana margin evolution

Ordovician K-bentonites have now been recorded from >20 localities in the vicinity of the Argentine Precordillera. Most occur in the eastern thrust belts, in the San Juan Limestone and the overlying the Gualcamayo Formation, but a few ash beds are known also from the central thrust belts. The oldest occur in the middle Arenig I. victoriae lunatus graptolite ( Oe. evae conodont) Zone, and the youngest in the middle Llanvirn P. elegans ( P. suecicus ) Zone. Mineralogical characteristics, typical of other Ordovician K-bentonites, include a matrix of illite/smectite mixed-layer clay and a typical felsic volcanic phenocryst assemblage: biotite, beta-form quartz, alkali and plagioclase feldspar, apatite, and zircon, with lesser amounts of hornblende, clinopyroxene, titanite and Fe-Ti oxides. The proportions of the mineral phases and variations in their crystal chemistry are commonly unique to individual (or small groups of) K-bentonite beds. Glass melt inclusions preserved in quartz are rhyolitic in composition. The sequence is unique in its abundance of K-bentonite beds, but a close association between the Precordillera and other Ordovician sedimentary basins cannot be established. The ash distribution is most consistent with palaeogeographical reconstructions in which early Ordovician drifting of the Precordillera occurred in proximity to one or more volcanic arcs, and with eventual collision along the Andean margin of Gondwana during the mid-Ordovician Ocloyic event of the Famatinian orogeny. The Puna-Famatina terrane northeast of the Precordillera might have served as the source of the K-bentonite ashes, possibly in concert with active arc magmatism on the Gondwana plate itself.

Geological Society Special Publication↗

Plutonic rocks of Jurassic age in the Alaska-Aleutian Range batholith: Ghemical variation and polarity

Plutonic rocks of Jurassic age exposed on the eastern, or Pacific, side of the Alaska–Aleutian Range batholith represent the roots of a magmatic arc generally considered to have been generated in response to northwest-directed subduction. These rocks form a compositionally continuous calc-alkaline suite that ranges from hornblende gabbro through quartz monzonite. Tonalite and quartz diorite are the dominant rock types. Trend-surface analysis was used to examine the geographic variation of major oxides and a few simple oxide ratios for 102 samples from widely separated localities. Statistical tests indicate that most of the trends, although weak, are real. The direction of slope of the trends is approximately normal to the Jurassic magmatic arc K 2 O and SiO 2 increase toward the east-southeast; the other oxides increase toward the west-northwest. The K 2 O trend accounts for about 19% of the variance in the data and is significant at > 99.9% level of confidence. If the chemical trends reflect the approximate geometry of a paleosubduction zone, the polarity of the Jurassic magmatic arc is to the northwest. That is, the paleosubduction zone was on the northwest side of the arc, and subduction was directed toward the southeast. The paleosubduction zone is on the opposite side of the arc from the position that has generally been assumed, indicating that the Jurassic plutonic rocks were not generated in response to classical Andean-type convergent plate margins. The magmatic arc may have formed in an intra-ocean environment, and subsequently has been rafted northward and accreted to this part of the northern Pacific rim during the late Mesozoic. Middle and Upper Jurassic clastic sediments underlying Cook Inlet to the southeast, and derived from the magmatic arc, are classified as backarc deposits, rather than as an arc-trench gap sequence.

Geological Society of America Bulletin↗

Pre- and post-eruptive geochemical and isotopic fingerprints of rhyolites parental to volcano-sedimentary lithium brine and clay resources in the western USA & central Andes

Lithium is a high-demand, critical element used not only in lightweight rechargeable lithium-ion batteries, but also in nuclear applications and industries producing ceramics, aluminum, and medical products. It is extracted primarily from pegmatites and volcano-sedimentary brines and clays in arid, closed lacustrine or caldera basins. Lithium brines of the central Andean salars in the AltiplanoPuna Plateau contain around ~70% of the world’s lithium resources. In contrast, Clayton Valley, Nevada is the only current producer of lithium brines in the United States and accounts for ~6% of current global lithium production. Clayton Valley hosts a newly defined Li-clay resource where locally exposed rhyolite tuffs have been proposed as a lithium source. Identifying magma evolution processes and determining the importance of syn- and post-eruptive processes on the source, mobility, and distribution of lithium is an ongoing area of research. These two regions illustrate distinctive magmatic-tectonic regimes for volcano-sedimentary lithium enrichment and therefore represent ideal regions to explore the key geological processes critical to the enrichment of lithium resources.

Clayton Valley, Puna Plateau↗

Origin and tectonic evolution of the Maclaren and Wrangellia terranes, eastern Alaska Range, Alaska

Major portions of the eastern Alaska Range, south of the Denali fault, in the McCarthy, Nabesna, Mount Hayes, and eastern Healy quadrangles, consist predominantly of the Maclaren and Wrangellia tectono-stratigraphic terranes. The Maclaren terrane consists of the Maclaren Glacier metamorphic belt and the regionally deformed and metamorphosed East Susitna batholith. The Maclaren Glacier metamorphic belt is composed of argillite, metagraywacke, and sparse andesite flows that are progressively regionally metamorphosed from lower greenschist facies to middle amphibolite facies near the East Susitna batholith. The East Susitna batholith is composed of gabbro, quartz diorite, granodiorite, and sparse quartz monzonite. Isotopic ages are as old as a K-Ar hornblende age of 87.5 m.y., possibly reset, and a U-Pb zircon age of 70 m.y. The batholith is intensely deformed and regionally metamorphosed under conditions of the middle amphibolite facies. The Wrangellia terrane is divided into two subterranes: (1) the Slana River subterrane, composed of late Paleozoic andesite to dacite flows, tuff, limestone, and argillite, unconformably overlying massive basalt flows of the Triassic Nikolai Greenstone, Late Triassic limestone, and younger Mesozoic flysch; and (2) the Tangle subterrane, a deeper-water equivalent of the Slana River subterrane, composed of late Paleozoic and Early Triassic aquagene tuff, chert, minor andesite tuff and flows, limestone, unconformably overlying pillow basalt and massive basalt flows of the Triassic Nikolai Greenstone, and Late Triassic limestone. Both subterranes are intruded by locally extensive gabbro and diabase dikes and by cumulate mafic and ultramafic sills. Less extensive terranes (two) are the Clearwater terrane, a sequence of intensely deformed chlorite schist, muscovite schist, marble, and greenstone of Late Triassic age; and an unnamed terrane of ultramafic and associated rocks of presumable Paleozoic or Mesozoic age. Each terrane or subterrane generally has (1) a distinctive time-stratigraphic sequence reflecting a unique geologic history; (2) a missing provenance for bedded sedimentary or volcanic rocks; and (3) bounding thrust or strike-slip faults, interpreted as accretionary sutures. The Maclaren and Wrangellia terranes are juxtaposed along the Broxson Gulch thrust, which consists of an imbricate series of north-dipping thrust faults. Paralleling the Broxson Gulch thrust, a few kilometres to the south, is the north-dipping Eureka Creek thrust, along which are juxtaposed the Slana River and Tangle subterranes. The Maclaren terrane is correlated with the Kluane Schist and the Ruby Range batholith in the southern Yukon Territory, which represent the northward extension of the Taku and Tracy Arm terranes. If correct, this correlation defines a minimum displacement of the Maclaren terrane along the Denali fault of ∼400 km. The Maclaren terrane is interpreted to have formed in a synorogenic Andean-type arc setting on the west margin of Mesozoic North America in the middle to late Mesozoic and early Cenozoic. The Wrangellia terrane is interpreted to have initially formed in an island-arc setting during the late Paleozoic. Subsequently in the Late Triassic, the Wrangellia terrane underwent rifting near the paleoequator, with formation of the Nikolai Greenstone and associated mafic and ultra-mafic igneous rocks. In the middle and late Mesozoic, Wrangellia migrated toward, and was accreted during, the middle Cretaceous to the Maclaren terrane along the Broxson Gulch thrust. Subsequent dispersion of both the Maclaren and Wrangellia terranes along the Denali fault and the Broxson Gulch thrust commenced during the early Tertiary and continues through the present.

Alaska↗

U-Pb isotopic evidence for the accretion of a continental microplate in the Zalm region of the Saudi Arabian Shield.

This area includes three of the main tectonic units of the Arabian Shield: the Afif continental terrain, the Nabitah suture with its associated mobile belt, and the Asir ensimatic arc terrain. U/Pb zircon data from a pelitic garnet-sillimanite gneiss show that the Kabib formation in the S of the Afif terrain may be as old as 1770 m.y. Pb and Rb/Sr isotopic data in the Zalm region reveal a change in the nature of the underlying crust, from continental basement in the NE to less radiogenic marginal arc rocks in the SW. Miogeosynclinal continental shelf facies of the Siham group lie unconformably over the Kabid formation. U/Pb zircon age determinations show that this 'Andean' continental margin developed before approx 720 m.y. and the emplacement of calc-alkaline plutonic rocks continued until approx 690 m.y. During the period 685-640 m.y. the continental Afif microplate collided with the Asir terrain as part of the Nabitah orogeny. At approx 640 m.y. age the Najd strike-slip faulting commenced, with a dextral phase that controlled emplacement of granite plutons as well as the development of large pull-apart grabens. Some of the latter were floored by new oceanic crust and filled with volcanosedimentary rocks of the Bani Ghayy group.-R.A.H.

Journal of the Geological Society↗

Geologic signature of early Tertiary ridge subduction in Alaska

A mid-Paleocene to early Eocene encounter between an oceanic spreading center and a subduction zone produced a wide range of geologic features in Alaska. The most striking effects are seen in the accretionary prism (Chugach–Prince William terrane), where 61 to 50 Ma near-trench granitic to gabbroic plutons were intruded into accreted trench sediments that had been deposited only a few million years earlier. This short time interval also saw the genesis of ophiolites, some of which contain syngenetic massive sulfide deposits; the rapid burial of these ophiolites beneath trench turbidites, followed immediately by obduction; anomalous high-T, low-P, near-trench metamorphism; intense ductile deformation; motion on transverse strike-slip and normal faults; gold mineralization; and uplift of the accretionary prism above sea level. The magmatic arc experienced a brief flare-up followed by quiescence. In the Alaskan interior, 100 to 600 km landward of the paleotrench, several Paleocene to Eocene sedimentary basins underwent episodes of extensional subsidence, accompanied by bimodal volcanism. Even as far as 1000 km inboard of the paleotrench, the ancestral Brooks Range and its foreland basin experienced a pulse of uplift that followed about 40 million years of quiescence. All of these events - but most especially those in the accretionary prism - can be attributed with varying degrees of confidence to the subduction of an oceanic spreading center. In this model, the ophiolites and allied ore deposits were produced at the soon-to-be subducted ridge. Near-trench magmatism, metamorphism, deformation, and gold mineralization took place in the accretionary prism above a slab window, where hot asthenosphere welled up into the gap between the two subducted, but still diverging, plates. Deformation took place as the critically tapered accretionary prism adjusted its shape to changes in the bathymetry of the incoming plate, changes in the convergence direction before and after ridge subduction, and changes in the strength of the prism as it was heated and then cooled. In this model, events in the Alaskan interior would have taken place above more distal, deeper parts of the slab window. Extensional (or transtensional) basin subsidence was driven by the two subducting plates that each exerted different tractions on the upper plate. The magmatic lull along the arc presumably marks a time when hydrated lithosphere was not being subducted beneath the arc axis. The absence of a subducting slab also may explain uplift of the Brooks Range and North Slope: Geodynamic models predict that longwavelength uplift of this magnitude will take place far inboard from Andean-type margins when a subducting slab is absent. Precise correlations between events in the accretionary prism and the Alaskan interior are hampered, however, by palinspastic problems. During and since the early Tertiary, margin-parallel strike-slip faulting has offset the near-trench plutonic belt - i.e., the very basis for locating the triple junction and slab window - from its backstop, by an amount that remains controversial. Near-trench magmatism began at 61 Ma at Sanak Island in the west but not until 51 Ma at Baranof Island, 2200 km to the east. A west-to-east age progression suggests migration of a trench-ridge-trench triple junction, which we term the Sanak-Baranof triple junction. Most workers have held that the subducted ridge separated the Kula and Farallon plates. As a possible alternative, we suggest that the ridge may have separated the Kula plate from another oceanic plate to the east, which we have termed the Resurrection plate.

Alaska↗

The Zn–Pb mineralization of Florida Canyon, an evaporite-related Mississippi Valley-type deposit in Bongará district, northern Peru

The Florida Canyon evaporite-related Zn–Pb sulfide deposit, in northern Peru, is one of the largest Mississippi Valley-type (MVT) deposits in South America. Triassic carbonate and former evaporite-bearing rocks of the Pucará Group host the ore bodies that comprise two different styles: (i) predominantly stratabound ore associated with hydrocarbon-rich porous dolostones and evaporite dissolution breccias; and (ii) high-grade ore associated with evaporite breccias representing diapiric injections along faults. A dome structure that controls the location of the ore deposit was defined by drillhole spatial data; the dome likely resulted from halokinetic processes during Andean deformation. NNE-trending steeply dipping secondary faults linked to major NW structures appear to control the distribution of ore grades in the deposit. Mineralization post-dated hydrocarbon migration and accumulation. Strontium, carbon, and oxygen data isotopic signatures allow distinction between pre-and syn-mineralization carbonate stages. The sulfur isotopic composition of sulfides in the deposit suggests they precipitated as the result of mixing of a metal-rich fluid with resident hydrogen sulfide in the dome. Local thermochemical sulfate reduction (TSR) may have contributed to the reduced sulfur budget during mineralization.

Economic Geology↗

U-Pb isotopic evidence for accretion of a continental microplate in the Zalm region of the Saudi Arabian Shield

The region covered by this work includes three of the main tectonic units of the Arabian Shield: the Afif continental terrane, the Nabitah suture with its associated mobile belt, and the Asir ensimatic arc terrane. The geology of the area is well understood, and this geochronologic and isotopic study confirms that the Afif terrane was a continental microplate in the late Proterozoic. The study also provides a time frame for the crustal evolution of this part of the Shield. U-Pb zircon age data from a pelitic garnet-sillimanite gneiss of the Kabid formation shows that this part of the continental basement in the Afif terrane may be as old as 1830 Ma. Isotope data indicate that lead from the Kabid gneiss resided in the upper continental crust for a long period before 1830 Ma, and require that Archean rocks exist at depth beneath the Afif terrane. Lead isotope data reveal a change in the nature of the underlying crust, from continental basement in the northeast, to less radiogenic, marginal arc rocks in the southwest. This change is coincident with both aeromagnetic data, and a fades change within a pre-collision marginal basin. Miogeosynclinal continental shelf fades of the Siham group lie unconcormably over the Kabid formation, and are in the area of continental lead signatures. Eugeosynclinal deep water sediments and volcanics, in association with ultramafic rocks, occur in the area of marginal arc signatures. U-Pb zircon age determinations show that this "Andean" continental margin developed before about 720 Ma, and emplacement of calc-alkaline plutonic rocks continued until about 690 Ma. During the period 690-640 Ma, the continental Afif microplate collided with the Asir terrane as part of the Nabitah orogeny. At approximately 640 Ma ago, the Najd strike-slip orogen commenced with a dextral phase that controlled the emplacement of granitic plutons as well as the development of a series of large pull-apart grabens. Some of these grabens were floored by new oceanic crust and were filled with volcano-sedimentary rocks of the Bani Ghayy group. Subsequently, the Najd fault system changed to sinistral strike slip motion at about 620 Ma ago.

Open-File Report↗