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At least 343 records · Page 19Linked to original sources

Sperm quality biomarkers complement reproductive and endocrine parameters in investigating environmental contaminants in common carp (Cyprinus carpio) from the Lake Mead National Recreation Area

Lake Mead National Recreational Area (LMNRA) serves as critical habitat for several federally listed species and supplies water for municipal, domestic, and agricultural use in the Southwestern U.S. Contaminant sources and concentrations vary among the sub-basins within LMNRA. To investigate whether exposure to environmental contaminants is associated with alterations in male common carp ( Cyprinus carpio ) gamete quality and endocrine- and reproductive parameters, data were collected among sub-basins over 7 years (1999–2006). Endpoints included sperm quality parameters of motility , viability, mitochondrial membrane potential, count, morphology, and DNA fragmentation; plasma components were vitellogenin (VTG), 17ß-estradiol, 11-keto-testosterone, triiodothyronine, and thyroxine. Fish condition factor, gonadosomatic index, and gonadal histology parameters were also measured. Diminished biomarker effects were noted in 2006, and sub-basin differences were indicated by the irregular occurrences of contaminants and by several associations between chemicals (e.g., polychlorinated biphenyls, hexachlorobenzene , galaxolide, and methyl triclosan) and biomarkers (e.g., plasma thyroxine, sperm motility and DNA fragmentation). By 2006, sex steroid hormone and VTG levels decreased with subsequent reduced endocrine disrupting effects. The sperm quality bioassays developed and applied with carp complemented endocrine and reproductive data, and can be adapted for use with other species.

Lake Mead National Recreation Area↗

Assessing the value of removing earthquake-hazard-related epistemic uncertainties, exemplified using average annual loss in California

To aid in setting scientific research priorities, we assess the potential value of removing each of the epistemic uncertainties currently represented in the US Geological Survey California seismic-hazard model, using average annual loss (AAL) as the risk metric of interest. Given all the uncertainties, represented with logic-tree branches, we find a mean AAL of $3.94 billion. The modal value is 17.5% lower than the mean, and there is a 78% chance that the true AAL value is more than 10% away from the mean, and a 5% chance that it is a factor 2.1 greater or lower than the mean. We quantify the extent to which resolving each uncertainty improves the AAL estimate. The most influential branch is one that adds additional epistemic uncertainty to ground motion models, but others are found to be influential as well, such as the rate of M ≥ 5 events throughout the region. We discuss the broader implications of our findings, and note that the time dependence caused by spatiotemporal clustering can be much more influential on AAL than the epistemic uncertainties explored here.

California↗

Assessment of lake sturgeon ( Acipenser fulvescens ) spawning efforts in the lower St. Clair River, Michigan

One of the most threatened remaining populations of lake sturgeon in the Great Lakes is found in the connecting channels between Lake Huron and Lake Erie. Only two spawning grounds are presently known to be active in this region, and both are in the St. Clair River. The spawning reef in the St. Clair River delta has been recently colonized by round gobies ( Neogobius melanostomus ) in densities up to 25/m 2 , raising concerns regarding predation on the benthic-oriented eggs and larvae of the sturgeon. Investigations in 1998&ndash;1999 showed that while round goby predation does occur, a number of other factors may be equally affecting sturgeon spawning success, including few spawning adults (< 60), suspected poaching pressure, low retention rate of eggs on the reef, low hatch rate (~0.5%), the presence of organic contaminants, and predation from native and exotic invertebrates and fish. Overall, we estimate that less than 1% of the eggs deposited during a spawning run survive to hatch. We were able to increase the egg hatch rate to 16% by placing eggs in predator-exclusion chambers on the reef. The fate of the larvae is uncertain. Two weeks after hatching, no larvae were found on the reef. We were unable to find them anywhere else in the river, nor was predation on larvae noted in either year. There were factors other than predation affecting larval survival in 1999. There was a higher silt load on the reef than in 1998 and large numbers of dead larvae were found. Recruitment success from this site could be improved by utilizing techniques to increase the number of eggs on the reef, such as reducing the illegal take of adult fish and by placing eggs in predator-exclusion chambers to increase hatch rate.

Michigan↗

A note on the comparative turbidity of some estuaries of the Americas

Field data from 27 estuaries of the Americas are used to show that, in broad terms, there is a large difference in turbidity between the analyzed east and west-coast estuaries and that tidal range and tidal length have an important influence on that turbidity. Generic, numerical sediment-transport modeling is used to illustrate this influence, which exists over a range of space scales from, e.g., the Rogue River Estuary (few km, few mg l-1) to the Bay of Fundy (hundreds of km, few g l-1). The difference in Pacific and Atlantic seaboard estuarine turbidity for the analyzed estuaries is ultimately related to the broad-scale geomorphology of the two continents.

Journal of Coastal Research↗

Symbiotic nitrogen fixation does not stimulate soil phosphatase activity under temperate and tropical trees

Symbiotic nitrogen (N)-fixing plants can enrich ecosystems with N, which can alter the cycling and demand for other nutrients. Researchers have hypothesized that fixed N could be used by plants and soil microbes to produce extracellular phosphatase enzymes, which release P from organic matter. Consistent with this speculation, the presence of N-fixing plants is often associated with high phosphatase activity, either in the soil or on root surfaces, although other studies have not found this association, and the connection between phosphatase and rates of N fixation—the mechanistic part of the argument—is tenuous. Here, we measured soil phosphatase activity under N-fixing trees and non-fixing trees transplanted and grown in tropical and temperate sites in the USA: two sites in Hawaii, and one each in New York and Oregon. This provides a rare example of phosphatase activity measured in a multi-site field experiment with rigorously quantified rates of N fixation. We found no difference in soil phosphatase activity under N-fixing vs. non-fixing trees nor across rates of N fixation, though we note that no sites were P limited and only one was N limited. Our results add to the literature showing no connection between N fixation rates and phosphatase activity.

Oecologia↗

Anticoagulant rodenticide toxicity to non-target wildlife under controlled exposure conditions

Much of our understanding of anticoagulant rodenticide toxicity to non-target wildlife has been derived from molecular through whole animal research and registration studies in domesticated birds and mammals, and to a lesser degree from trials with captive wildlife. Using these data, an adverse outcome pathway identifying molecular initiating and anchoring events (inhibition of vitamin K epoxide reductase, failure to activate clotting factors), and established and plausible linkages (coagulopathy, hemorrhage, anemia, reduced fitness) associated with toxicity, is presented. Controlled exposure studies have demonstrated that second-generation anticoagulant rodenticides (e.g., brodifacoum) are more toxic than first- and intermediate-generation compounds (e.g., warfarin, diphacinone), however the difference in potency is diminished when first- and intermediate-generation compounds are administered on multiple days. Differences in species sensitivity are inconsistent among compounds. Numerous studies have compared mortality rate of predators fed prey or tissue containing anticoagulant rodenticides. In secondary exposure studies in birds, brodifacoum appears to pose the greatest risk, with bromadiolone, difenacoum, flocoumafen and difethialone being less hazardous than brodifacoum, and warfarin, coumatetralyl, coumafuryl, chlorophacinone and diphacinone being even less hazardous. In contrast, substantial mortality was noted in secondary exposure studies in mammals ingesting prey or tissue diets containing either second- or intermediate-generation compounds. Sublethal responses (e.g., prolonged clotting time, reduced hematocrit and anemia) have been used to study the sequelae of anticoagulant intoxication, and to some degree in the establishment of toxicity thresholds or toxicity reference values. Surprisingly few studies have undertaken histopathological evaluations to identify cellular lesions and hemorrhage associated with anticoagulant rodenticide exposure in non-target wildlife. Ecological risk assessments of anticoagulant rodenticides would be improved with additional data on (i) interspecific differences in sensitivity, particularly for understudied taxa, (ii) sublethal effects unrelated to coagulopathy, (iii) responses to mixtures and sequential exposures, and (iv) the role of vitamin K status on toxicity, and significance of inclusion of supplemental vitamin K or menadione (provitamin) in the diet of test organisms. A more complete understanding of the toxicity of anticoagulant rodenticides in non-target wildlife would enable regulators and natural resource managers to better predict and even mitigate risk.

Book chapter↗

Analyses of rocks and minerals from the laboratory of the United States Geological Survey, 1880 to 1914

The present Geological Survey of the United States was organized in 1879. In 1880, in connection with the Colorado work, a chemical laboratory was established at Denver in charge of W. F. Hillebrand, with whom were associated Antony Guyard and, later, L. G. Eakins. In 1882 W. H. Melville was placed in charge of a second laboratory at San Francisco, and in the autumn of 1883 the central laboratory was started in Washington, with myself as chief chemist. In November, 1885, Dr. Hillebrand was transferred to Washington; early in 1888 he was followed by Mr. Eakins, and the Denver laboratory was discontinued. In the spring of 1890 Dr. Melville also was transferred to Washington, and since then the geochemical work of the Survey has been concentrated at headquarters. The special laboratories of the water-resources and technologic branches of the Survey are not included in this statement and their work is not represented in this bulletin. Up to January 1, 1914, nearly 8,000 analyses have been made in the laboratory at Washington of rocks, minerals, ores, waters, sediments, coals, metals, and other substances with which geology has to do. Some-hundreds of analyses were also made in the laboratories at Denver and San Francisco. A fair amount of research work upon mineralogical and analytical problems has also been done. In *all of this work the following chemists have been employed: E. T. Allen, R. K. Bailey, Charles Catlett, T. M. Chatard, F. W. Clarke, L. G. Eakins, J. G. Fairchild, F. A. Gooch, Antony Guyard, W. B. Hicks, W. F. Hillebrand, W. F. Hunt, W. H. Melville, H. C. McNeil, Chase Palmer, R. B. Riggs, W. T. Schaller, E. A. Schneider, George Steiger, H. N. Stokes, E. C. Sullivan, William Valentine, R. C. Wells, W. C. Wheeler, and J. E. Whitfield. At present, January 1, 1914, eight of these chemists are employed in the Survey. Other officers of the Survey have been occupied more or less with chemical questions, but the men named in this list were connected directly with the laboratory. Some work for the chemical division has also been done by chemists not regularly on the rolls of the Survey, but their analyses, with the exception of a single group to be noted later, do not fall within the scope of this paper.

Bulletin↗

Factors affecting long-term trends in surface-water quality in the Gwynns Falls watershed, Baltimore City and County, Maryland, 1998–2016

Factors affecting water-quality trends in urban streams are not well understood, despite current regulatory requirements and considerable ongoing investments in gray and green infrastructure. To address this gap, long-term water-quality trends and factors affecting these trends were examined in the Gwynns Falls, Maryland, watershed during 1998–2016 in cooperation with Blue Water Baltimore. Data on water-quality constituents and potential factors of influence were obtained from multiple sources and compiled for analysis, with a focus on data collected as part of the National Science Foundation funded Long-Term Ecological Research project, the Baltimore Ecosystem Study. Variability in climate (specifically, precipitation) and land cover can overwhelm actions taken to improve water quality and can present challenges for meeting regulatory goals. Analysis of land cover during 2001–11 in the Gwynns Falls watershed indicated minimal change during the study time frame; therefore, land-cover change is likely not a factor affecting trends in water quality. However, a modest increase in annual precipitation and a significant increase in winter precipitation were apparent in the region. A higher proportion of runoff producing storms was observed in the winter and a lower proportion in the summer, indicating that climate change may affect water quality in the watershed. The increase in precipitation was not reflected in annual or seasonal trends of streamflow in the watershed. Nonetheless, these precipitation changes may exacerbate the inflow and infiltration of water to gray infrastructure and reduce the effectiveness of green infrastructure. For streamflow and most water-quality constituents examined, no discernable trends were noted over the timeframe examined. Despite the increases in precipitation, no trends were observed for annual or seasonal discharge at the various sites within the study area. In some locations, nitrate, phosphate, and total nitrogen show downward trends, and total phosphorus and chloride show upward trends. Sanitary sewer overflows (gray infrastructure) and best management practices (green infrastructure) were identified as factors affecting water-quality change. The duration of sanitary sewer overflows was positively correlated with annual loads of nutrients and bacteria, and the drainage area of best management practices was negatively correlated with annual loads of phosphate and sulfate. Results of the study indicate that continued investments in gray and green infrastructure are necessary for urban water-quality improvement. Although this outcome is not unexpected, long-term datasets such as the one used in this study, allow the effects of gray and green infrastructures to be quantified. Results of this study have implications for the Gwynns Falls watershed and its residents and Baltimore City and County managers. Moreover, outcomes are relevant to other watersheds in the metropolitan region that do not have the same long-term dataset. Further, this study has established a framework for ongoing statistical analysis of primary factors affecting urban water-quality trends as regulatory programs mature.

Maryland↗

Developing a topographic model to predict the northern hardwood forest type within Carolina northern flying squirrel ( Glaucomys sabrinus coloratus ) recovery areas of the southern Appalachians

The northern hardwood forest type is an important habitat component for the endangered Carolina northern flying squirrel (CNFS; Glaucomys sabrinus coloratus ) for den sites and corridor habitats between boreo-montane conifer patches foraging areas. Our study related terrain data to presence of northern hardwood forest type in the recovery areas of CNFS in the southern Appalachian Mountains of western North Carolina, eastern Tennessee, and southwestern Virginia. We recorded overstory species composition and terrain variables at 338 points, to construct a robust, spatially predictive model. Terrain variables analyzed included elevation, aspect, slope gradient, site curvature, and topographic exposure. We used an information-theoretic approach to assess seven models based on associations noted in existing literature as well as an inclusive global model. Our results indicate that, on a regional scale, elevation, aspect, and topographic exposure index (TEI) are significant predictors of the presence of the northern hardwood forest type in the southern Appalachians. Our elevation + TEI model was the best approximating model (the lowest AICc score) for predicting northern hardwood forest type correctly classifying approximately 78% of our sample points. We then used these data to create region-wide predictive maps of the distribution of the northern hardwood forest type within CNFS recovery areas.

North Carolina, Tennessee, Virginia↗

Occurrence of fecal-indicator bacteria and protocols for identification of fecal-contamination sources in selected reaches of the West Branch Brandywine Creek, Chester County, Pennsylvania

The presence of fecal-indicator bacteria indicates the potential presence of pathogens originating from the fecal matter of warm-blooded animals. These pathogens are responsible for numerous human diseases ranging from common diarrhea to meningitis and polio. The detection of fecal-indicator bacteria and interpretation of the resultant data are, therefore, of great importance to water-resource managers. Current (2005) techniques used to assess fecal contamination within the fluvial environment primarily assess samples collected from the water column, either as grab samples or as depth- and (or) width-integrated samples. However, current research indicates approximately 99 percent of all bacteria within nature exist as attached, or sessile, bacteria. Because of this condition, most current techniques for the detection of fecal contamination, which utilize bacteria, assess only about 1 percent of the total bacteria within the fluvial system and are, therefore, problematic. Evaluation of the environmental factors affecting the occurrence and distribution of bacteria within the fluvial system, as well as the evaluation and modification of alternative approaches that effectively quantify the larger population of sessile bacteria within fluvial sediments, will present water-resource managers with more effective tools to assess, prevent, and (or) eliminate sources of fecal contamination within pristine and impaired watersheds. Two stream reaches on the West Branch Brandywine Creek in the Coatesville, Pa., region were studied between September 2002 and August 2003. The effects of sediment particle size, climatic conditions, aquatic growth, environmental chemistry, impervious surfaces, sediment and soil filtration, and dams on observed bacteria concentrations were evaluated. Alternative approaches were assessed to better detect geographic sources of fecal contamination including the use of turbidity as a surrogate for bacteria, the modification and implementation of sandbag bacteria samplers, and the use of optical brighteners. For the purposes of this report, sources of bacteria were defined as geographic locations where elevated concentrations of bacteria are observed within, or expected to enter, the main branch of the West Branch Brandywine Creek. Biologic sources (for example, waterfowl) were noted where applicable; however, no specific study of biologic sources (such as bacterial source tracking) was conducted. Data indicated that specific bacterial populations within fluvial sediments could be related to specific particle-size ranges. This relation is likely the result of the reduced porosity and permeability associated with finer sediments and the ability of specific bacteria to tolerate particular environments. Escherichia coli (E. coli) showed a higher median concentration (2,160 colonies per gram of saturated sediment) in the 0.125 to 0.5-millimeter size range of natural sediments than in other ranges, and enterococcus bacteria showed a higher median concentration (61,830 colonies per gram of saturated sediment) in the 0.062 to 0.25-millimeter size range of natural sediments than in other ranges. There were insufficient data to assess the particle-size relation to fecal coliform bacteria and (or) fecal streptococcus bacteria. Climatic conditions were shown to affect bacteria concentrations in both the water column and fluvial sediments. Drought conditions in 2002 resulted in lower overall bacteria concentrations than the more typically wet year of 2003. E. coli concentrations in fluvial sediment along the Coatesville study reach in 2002 had a median concentration of 92 colonies per gram of saturated sediment; in 2003, the median concentration had risen to 4,752 colonies per gram of saturated sediment. Symbiotic relations between bacteria and aquatic growth were likely responsible for increased bacteria concentrations observed within an impoundment area on the Coatesville study reach. This reach showed evidence of elevated aquatic growth and sharp increases in E. coli concentrations from upstream to downstream through the impoundment area in both 2002 and 2003. In 2003, E. coli concentrations within the waters column increased from 940 colonies per 100 milliliters upstream to 6,000 colonies per 100 milliliters at the dam crest. Given that these bacteria likely resulted from natural bacterial regrowth, the use of E. coli as an indicator of fecal contamination was severely impaired. Variable environmental conditions along the West Branch Brandywine Creek made the common field-chemical parameters of specific conductance, temperature, pH, and dissolved oxygen ineffective and (or) impossible to use for the determination of inputs of fecal contamination. Extreme variations in chemical gradients commonly were related to the urban/industrial signature of the watershed. For example, during base-flow sampling in 2002, specific-conductance values exceeding 1,000 microsiemens per centimeter observed in effluent from a local steel mill. This effluent raised the specific conductance within the West Branch Brandywine from just above 200 microsiemens per centimeter upstream from the outfall to just below 500 microsiemens per centimeter downstream from the outfall. These chemical gradients also, likely, had an effect on the initial colonization of bacteria, the formation of biofilms, and the persistence of certain types of bacteria along the study reach. Data collected in 2003 indicated that nutrients increased during both base-flow and stormflow conditions along the Coatesville study reach. For example, during base-flow sampling in 2003, 20 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. The largest contributors to this base-flow nutrient load were likely two wastewater-treatment facilities adjacent to the study reach. During stormflow sampling in 2003, 480 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. Data, along with other research, indicated the largest contributor to this stormflow nutrient load was likely remobilized sediment originating from a large dam impoundment. These elevated nutrient concentrations were considered sufficient to promote accelerated aquatic growth along the reach. Data collected in 2003 showed that wastewater constituents entered the West Branch Brandywine Creek largely from urban storm-sewer systems. Samples from the primary storm sewer for the city of Coatesville had detections for 20 of 69 wastewater constituents. These constituents included both strong and weak indicators of fecal contamination and generally indicated the storm-sewer system along the Coatesville study reach was a likely source of fecal-indicator bacteria and fecal contamination under base-flow conditions. By comparison, 5 constituents were detected in samples from the upstream end of the reach, and 10 constituents were detected in samples from the downstream end of the reach. During stormflow, numbers of detections were similar along the entire length of the study reach-five in samples from the upstream end, eight in samples from the center of the reach, and seven in samples from the downstream end of the reach. These data indicate that point sources (such as culverts and pipes, septic systems, and wastewater-treatment facilities) are not likely the origin of bacteria contamination during stormflow. The bacteria concentrations observed during stormflow events probably result from remobilized sessile bacteria stored within fluvial sediments. In this case, these bacteria should not be considered indicators of current fecal contamination. Impervious surfaces were found to increase bacteria concentrations along the West Branch Brandywine Creek because contaminated runoff from impervious areas generally flows into, and is concentrated within, the confines of the local storm-sewer system. During 2002, storm-sewer outfalls draining impervious areas were associated with all major locations of elevated bacterial concentrations (greater than 1,200 colonies per gram of saturated sediment) in fluvial sediments. During 2003, wetter conditions and overall bacteria concentrations higher than in 2002 resulted in point sources of bacterial contamination becoming less pronounced; however, the storm-sewer system, draining adjacent impervious areas, was still observed to be the primary source of bacteria along the reach. Where stormwater and (or) other runoff from these areas was allowed to infiltrate and (or) flow through wetland and riparian buffers, bacteria concentrations were not observed to be elevated above background levels commonly observed throughout similar areas of the same reach. Two run-of-the-river dams along the Coatesville study reach were evaluated for their effects on observed bacterial concentrations. These dams were shown to have greater or lesser effects on bacterial concentrations depending on the size of the structure and the capacity of the structure to impede flows. The smaller upstream dam had an approximate height of 3 feet and showed little observed effect on measured turbidity values; these data indicated that the dam did not effectively impede the flow of water or sediment within the West Branch Brandywine Creek. Consequently, this small dam did not show any observed effect on bacterial concentrations either upstream or downstream of the structure. The larger dam, near the middle of the reach, had an approximate height of 20 feet and showed greater effects on both turbidity and bacteria concentrations. The capacity of the larger dam to impede flows, combined with nutrients entering the reach, resulted in increased biologic activity throughout the impoundment area. Within this larger impoundment, enterococcus bacteria populations were observed to decrease sharply and E. coli bacteria populations were observed to increase sharply as flow approached the dam crest. All bacteria levels were then observed to drop to background levels, in both the water column and fluvial sediment, immediately downstream from the dam crest. Additional study is required to determine the cause for this rapid die off. Turbidity was assessed as a potential surrogate for E. coli bacteria. Regression analysis indicated higher turbidity levels usually can indicate higher concentrations of bacteria (R2 = 0.67), but the relation was too sporadic on the West Branch Brandywine Creek to use turbidity as a surrogate for estimated bacteria concentrations. Evaluation of data from individual base-flow and stormflow events resulted in variable and generally poor statistical relations between E. coli bacteria and turbidity (R2 values ranged from 0.02 to 0.94). Sandbag samplers were used in 2003 to determine their suitability for the assessment of fecal contamination. Sandbag samplers rely on the ability of bacteria to attach to surfaces and use the larger sessile bacteria populations instead of the more commonly used planktonic bacteria populations. E. coli bacteria concentrations observed in the sandbag samplers, after 1 week in place, were similar to those found within natural sediments collected concurrently. Enterococcus bacteria concentrations within the same sandbag samplers were not similar, and were generally lower, than those observed within the natural sediments. This discrepancy was likely because sand within the samplers was sieved to a size that was likely too coarse for enterococcus bacteria to persist. Optical-brightener samplers were installed along with each sandbag sampler. Optical brighteners are additives used in common household detergents; therefore, detection of optical brighteners, along with elevated fecal-indicator bacteria concentrations, strongly indicates a link to humans. Positive results for optical brighteners were detected only at the outfalls of two sewage-treatment facilities; because of treatment of the effluent from these facilities, these samples did not have elevated bacteria concentrations. The lack of additional positive results was largely because this method is not sensitive to low concentrations of optical brighteners.

Pennsylvania↗

Age dating of shallow groundwater with chlorofluorocarbons, tritium/helium: 3, and flow path analysis, southern New Jersey coastal plain

Groundwater age dating through the combination of transient tracer methods (chlorofluorocarbons (CFCs) and tritium/helium 3 ( 3 H/ 3 He)) and groundwater flow path analysis is useful for investigating groundwater travel times, flow patterns, and recharge rates, as demonstrated by this study of the homogeneous shallow, unconfined Kirkwood-Cohansey aquifer system in the southern New Jersey coastal plain. Water samples for age dating were collected from three sets of nested observation wells (10 wells) with 1.5-m-long screens located near groundwater divides. Three steady state finite difference groundwater flow models were calibrated by adjusting horizontal and vertical hydraulic conductivities to match measured heads and head differences (range, 0.002–0.23 m) among the nested wells, with a uniform recharge rate of 0.46 m per year and porosities of 0.35 (sand) and 0.45 (silt) that were assumed constant for all model simulations and travel time calculations. The simulated groundwater travel times increase with depth in the aquifer, ranging from about 1.5 to 6.5 years for the shallow wells (screen bottoms 3–4 m below the water table), from about 10 to 25 years for the medium-depth wells (screen bottoms 8–19 m below the water table), and from about 30 to more than 40 years for the deep wells (screen bottoms 24–26 m below the water table). Apparent groundwater ages based on CFC- and 3 H/ 3 He-dating techniques and model-based travel times could not be statistically differentiated, and all were strongly correlated with depth. Confinement of 3He was high because of the rapid vertical flow velocity (of the order of 1 m/yr), resulting in clear delineation of groundwater travel times based on the 3 H/ 3 He-dating technique. The correspondence between the 3 H/ 3 He and CFC ages indicates that dispersion has had a minimal effect on the tracer-based ages of water in this aquifer. Differences between the tracer-based apparent ages for seven of the 10 samples were smaller than the error values. A slight bias toward older apparent ages, found not to be statistically significant, was noted for the 3 H/ 3 He-dating technique relative to the CFC-dating technique. This result may be caused by enrichment of local air in CFC-Il and CFC-12 from urban and industrial sources in the northeastern United States and minor contamination from sampling equipment. The demonstrated validity of the combined tracer-dating techniques to determine the age of water in the Kirkwood-Cohansey aquifer system indicates that groundwater flow models can be refined when apparent ages based on 3 H/ 3 He- and CFC- dating are used as calibration targets.

New Jersey↗

Overview of developmental, reproductive, and behavioral/ neurological effects of mercury exposures in wildlife

We review wildlife/mercury literature and our own research findings that demonstrate the relevance of wildlife toxicity data in protecting human health. Methylmercury affects wildlife through reduced adult survival and reproduction, aberrant behavior, immune system effects, and teratogenic effects. Methylmercury can readily cross the blood-brain barrier, is excreted into eggs in birds, and is transferred to young mammals across the placenta and in milk. Its principal effect on wildlife is on neurological functions. Wild mink (Mustela vison) and otter (Lutra canadensis) have died from methylmercury poisoning, with signs of poisoning including anorexia, loss of weight, incoordination, tremors, and convulsions, which are symptoms similar to those experienced by mercury-poisoned humans. Mammals also may experience tonic and clonic convulsions and an increase in fetal anomalies, again paralleling toxic problems in people. Antibody-producing cells can be suppressed by methylmercury. Microscopically, the most notable lesions are in the cerebrum. Extensive vacuolation of hepatocytes in the liver and necrosis and other changes in the appearance of the proximal convoluted tubules of the kidneys are often noted. When harp seals (Pagophilus groenlandicus) were dosed with methylmercury chloride the number of circulating erythrocytes decreased and white blood cell counts greatly increased. The poisoned seals also suffered from uremia, hyperproteinemia, hypercholesterolemia, hyperbilirubinemia, and elevations in lactic dehydrogenase and alkaline phosphatase. In birds, signs of methylmercury poisoning included emaciation and weakness in the extremities, which progressed until the birds died. Mercury poisoning in birds and mammals can be diagnosed from a combination of the signs of poisoning if the animal is still alive, the pathological effects seen in a gross necropsy, the histopathological effects seen with a microscope, and the concentrations of mercury in various tissues. Our studies with mallards (Anas platyrhynchos) suggest that the dietary concentrations of mercury that cause toxicity are lower than those set in fish consumption advisories to protect humans. Because wild mammals and birds are so sensitive to methylmercury poisoning and cannot escape dietary exposure the way humans can, guidelines set to protect wild birds and mammals may very well provide a margin of safety for human health.

Book chapter↗

Iñupiaq knowledge of polar bears (Ursus maritimus) in the southern Beaufort Sea, Alaska

Successful wildlife management depends upon coordination and consultation with local communities. However, much of the research used to inform management is often derived solely from data collected directly from wildlife. Indigenous people living in the Arctic have a close connection to their environment, which provides unique opportunities to observe their environment and the ecology of Arctic species. Further, most northern Arctic communities occur within the range of polar bears ( nanuq , Ursus maritimus ) and have experienced significant climatic changes. Here, we used semi-structured interviews from 2017 to 2019 to document Iñupiaq knowledge of polar bears observed over four decades in four Alaskan communities in the range of the Southern Beaufort Sea polar bear subpopulation: Wainwright, Utqiaġvik, Nuiqsut, and Kaktovik. All but one of 47 participants described directional and notable changes in sea ice, including earlier ice breakup, later ice return, thinner ice, and less multiyear pack ice. These changes corresponded with observations of bears spending more time on land during the late summer and early fall in recent decades—observations consistent with scientific and Indigenous knowledge studies in Alaska, Canada, and Greenland. Participants noted that polar bear and seal body condition and local abundance either varied geographically or exhibited no patterns. However, participants described a recent phenomenon of bears being exhausted and lethargic when arriving on shore in the summer and fall after extensive swims from the pack ice. Further, several participants suggested that maternal denning is occurring more often on land than sea ice. Participants indicated that village and regional governments are increasingly challenged to obtain resources needed to keep their communities safe as polar bears spend more time on land, an issue that is likely to be exacerbated both in this region and elsewhere as sea ice loss continues.

Alaska↗

Fixed recurrence and slip models better predict earthquake behavior than the time- and slip-predictable models 1: repeating earthquakes

The behavior of individual events in repeating earthquake sequences in California, Taiwan and Japan is better predicted by a model with fixed inter-event time or fixed slip than it is by the time- and slip-predictable models for earthquake occurrence. Given that repeating earthquakes are highly regular in both inter-event time and seismic moment, the time- and slip-predictable models seem ideally suited to explain their behavior. Taken together with evidence from the companion manuscript that shows similar results for laboratory experiments we conclude that the short-term predictions of the time- and slip-predictable models should be rejected in favor of earthquake models that assume either fixed slip or fixed recurrence interval. This implies that the elastic rebound model underlying the time- and slip-predictable models offers no additional value in describing earthquake behavior in an event-to-event sense, but its value in a long-term sense cannot be determined. These models likely fail because they rely on assumptions that oversimplify the earthquake cycle. We note that the time and slip of these events is predicted quite well by fixed slip and fixed recurrence models, so in some sense they are time- and slip-predictable. While fixed recurrence and slip models better predict repeating earthquake behavior than the time- and slip-predictable models, we observe a correlation between slip and the preceding recurrence time for many repeating earthquake sequences in Parkfield, California. This correlation is not found in other regions, and the sequences with the correlative slip-predictable behavior are not distinguishable from nearby earthquake sequences that do not exhibit this behavior.

Journal of Geophysical Research B: Solid Earth↗

A review of plague persistence with special emphasis on fleas

Sylvatic plague is highly prevalent during infrequent epizootics that ravage the landscape of western North America. During these periods, plague dissemination is very efficient. Epizootics end when rodent and flea populations are decimated and vectored transmission declines. A second phase (enzootic plague) ensues when plague is difficult to detect from fleas, hosts or the environment, and presents less of a threat to public health. Recently, researchers have hypothesized that the bacterium (Yersinia pestis) responsible for plague maintains a continuous state of high virulence and thus only changes in transmission efficiency explain the shift between alternating enzootic and epizootic phases. However, if virulent transmission becomes too inefficient, strong selection might favor an alternate survival strategy. Another plausible non-exclusive hypothesis, best supported from Asian field studies, is that Y. pestis persists (locally) at foci by maintaining a more benign relationship within adapted rodents during the long expanses of time between outbreaks. From this vantage, it can revert to the epizootic (transmission efficient) form. Similarly, in the United States (US), enzootic plague persistence has been proposed to develop sequestered within New World rodent carriers. However, the absence of clear support for rodent carriers in North America has encouraged a broader search for alternative explanations. A telluric plague existence has been proposed. However, the availability of flea life stages and their hosts could critically supplement environmental plague sources, or fleas might directly represent a lowlevel plague reservoir. Here, we note a potentially pivotal role for fleas. These epizootic plague vectors should be closely studied with newer more exacting methods to determine their potential to serve as participants in or accomplices to a plague persistence reservoir.

Journal of Vector Borne Diseases↗

Lower Eastern Shore Tributary summary: A summary of trends in tidal water quality and associated factors, 1985-2023

The Lower Eastern Shore Tributary Summary outlines change over time according to a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period 1985 – 2023, and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring (March-May) and summer (July-September) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO4), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in an Appendix B. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as winddriven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submersed aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the Lower Eastern Shore. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who use tidal water quality to inform management decisions, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. The Tributary Summary documents are sources of readily available background for change over time in tidal water quality observed with monitoring data. They help answer questions related to water quality, show how landscape factors drive water-quality changes over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Maryland, Virginia↗

Age, distribution, and stratigraphic relationship of rock units in the San Joaquin Basin Province, California: Chapter 5 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

The San Joaquin Basin is a major petroleum province that forms the southern half of California’s Great Valley, a 700-km-long, asymmetrical basin that originated between a subduction zone to the west and the Sierra Nevada to the east. Sedimentary fill and tectonic structures of the San Joaquin Basin record the Mesozoic through Cenozoic geologic history of North America’s western margin. More than 25,000 feet (>7,500 meters) of sedimentary rocks overlie the basement surface and provide a nearly continuous record of sedimentation over the past ~100 m.y. Further, depositional geometries and fault structures document the tectonic evolution of the region from forearc setting to strike-slip basin to transpressional margin. Sedimentary architecture in the San Joaquin Basin is complicated because of these tectonic regimes and because of lateral changes in depositional environment and temporal changes in relative sea level. Few formations are widespread across the basin. Consequently, a careful analysis of sedimentary facies is required to unravel the basin’s depositional history on a regional scale. At least three high-quality organic source rocks formed in the San Joaquin Basin during periods of sea level transgression and anoxia. Generated on the basin’s west side, hydrocarbons migrated into nearly every facies type in the basin, from shelf and submarine fan sands to diatomite and shale to nonmarine coarse-grained rocks to schist. In 2003, the U.S. Geological Survey (USGS) completed a geologic assessment of undiscovered oil and gas resources and future additions to reserves in the San Joaquin Valley of California (USGS San Joaquin Basin Province Assessment Team, this volume, chapter 1). Several research aims supported this assessment: identifying and mapping the petroleum systems, modeling the generation, migration, and accumulation of hydrocarbons, and defining the volumes of rock to be analyzed for additional resources. To better understand the three dimensional relationships between hydrocarbon source and reservoir rocks, we compiled a database consisting of more than 13,000 well picks and of one-mile resolution seismic grids. Both the well picks and the seismic grids characterize the depths to the top of key stratigraphic units. This database formed the basis of subsequent numerical modeling efforts, including the construction of a three- dimensional geologic model (Hosford Scheirer, this volume, chapter 7) and simulation of the petroleum systems in space and time (Peters, Magoon, Lampe, and others, this volume, chapter 12). To accomplish this modeling, we synthesized the age, geographic distribution, lithology, and petroleum characteristics of hydrocarbon source and reservoir rocks in the basin. The results of that synthesis are presented in this paper in the form of new stratigraphic correlation columns for the northern, central, and southern San Joaquin Valley (fig. 5.1; note that all figures are at the back of this report, following the References Cited). The stratigraphic relationships and ages published here draw heavily on published and unpublished studies of the San Joaquin Basin. The stratigraphy presented in each of the columns necessarily idealizes the subsurface geology over a relatively large area, instead of representing the specific geology at an individual well, oil and gas field, or outcrop. In this paper we present the background rationale for defining the geographic divisions of the basin (inset map, fig. 5.1), the paleontological time scales used for assigning absolute ages to rock units (figs. 5.2 and 5.3), and the supporting maps illustrating the geographic distribution of each rock type included in the stratigraphic column (figs. 5.4 through 5.64).

California↗

Small-volume tephra deposits of the May 1924 explosions from Halemaʻumaʻu, Kīlauea volcano, and their origin

More than 50 explosive eruptions occurred from Halemaʻumaʻu at Kīlauea volcano over 17 days from May 11 to 27, 1924. Ballistics weighing as much as 14,000 kg were ejected and most landed within 2 km of the vent. Fine ash made up a major component of the tephra and was dispersed tens of kilometers downwind. Draining of the Halemaʻumaʻu lava lake occurred in late February 1924, with the crater floor eventually subsiding by a further ∼70 m (to ∼180 m below the crater rim) by the time the first explosions took place during the night of May 10–11. The largest explosions occurred on May 17–18 and smaller explosions continued until May 27, at which point Halemaʻumaʻu had more than doubled in width and depth. The explosions generated plumes reaching up to ∼10 km high with ballistics ejected up to 2 km from the crater. Almost 100 years later, we investigate and characterize the preserved tephra deposits within ∼3 km of the 1924 crater rim. Grain size and shape analyses were performed on 202 samples collected from 34 tephra profiles using dynamic image analysis, with a subset of layers from nine tephra profiles used for componentry (200 grains per layer in the 0.5–1 mm size fraction). Additionally, we characterize the average diameters (using the five largest clasts) at 216 locations and measure the average diameters of 2291 ballistics (largest per ∼100 m 2 area). Physical descriptions from fieldwork and grain size distributions were used to subdivide the tephra layers into five lithofacies: coarse homogeneous, fine homogenous, red ash, accretionary lapilli-bearing, and finely laminated. Grain size versus shape data show a range of values that demonstrate most grains are dense, smooth, and equant, in alignment with lithic clasts dominating the tephra componentry. The fine grained and accretionary lapilli-bearing nature of some of these lithofacies confirms that water influenced the style of the explosions. However, we also note juvenile clasts within many of the tephra layers, indicating that many of the layers were formed during phreatomagmatic explosions (sensu stricto), despite the eruptive mechanism being dominantly phreatic. Juvenile clasts are more abundant higher in the tephra profiles, suggesting that juvenile magma was more involved later in the explosive sequence. Thermal and hydrologic modeling indicate that groundwater inflow into a short-lived, small-diameter volcanic conduit (10-m to 120-m-diameter used for modeling) during the 78–85 days preceding the first explosion provides a physically plausible mechanism for this eruptive sequence.

Hawaii↗