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At least 343 records · Page 19Linked to original sources

Photogrammetry of the deep seafloor from archived unmanned submersible exploration dives

Large amounts of video images have been collected for decades by scientific and governmental organizations in deep (>1000 m) water using manned and unmanned submersibles and towed cameras. The collected images were analyzed individually or were mosaiced in small areas with great effort. Here, we provide a workflow for utilizing modern photogrammetry to construct virtual geological outcrops hundreds or thousands of meters in length from these archived video images. The photogrammetry further allows quantitative measurements of these outcrops, which were previously unavailable. Although photogrammetry had been carried out in recent years in the deep sea, it had been limited to small areas with pre-defined overlapping dive paths. Here, we propose a workflow for constructing virtual outcrops from archived exploration dives, which addresses the complicating factors posed by single non-linear and variable-speed vehicle paths. These factors include poor navigation, variable lighting, differential color attenuation due to variable distance from the seafloor, and variable camera orientation with respect to the vehicle. In particular, the lack of accurate navigation necessitates reliance on image quality and the establishment of pseudo-ground-control points to build the photogrammetry model. Our workflow offers an inexpensive method for analyzing deep-sea geological environments from existing video images, particularly when coupled with rock samples.

Journal of Marine Science and Engineering↗

Influence of inner-continental shelf geologic framework on the evolution and behavior of the barrier-island system between Fire Island Inlet and Shinnecock Inlet, Long Island, New York

High-resolution, sea-floor mapping techniques, including sidescan-sonar and subbottom profiling, were used to investigate how the geologic framework of the inner-continental shelf influenced the Holocene evolution and modern behavior of the Fire Island barrier-island system, Long Island, New York. The inner-continental shelf off Long Island is divided into two physiographic provinces by a broad outcrop of Cretaceous coastal-plain strata offshore of Watch Hill; this outcrop was part of a subaerial headland during the Holocene marine transgression. Erosion of the headland during transgression furnished sediment to the inner-continental shelf downdrift to the west. The sediment was, in turn, reworked by oceanographic processes into a series of shoreface-attached sand ridges. The oldest (~1200 yr BP) and most stable part of the barrier-island system is immediately landward of the outcropping coastal-plain strata and thickest sand ridges. East of Watch Hill, Pleistocene sediment either is exposed on the inner-continental shelf or is buried by a veneer of modern reworked sediment. Here the barrier-island system has migrated landward at a faster rate than the segment west of Watch Hill and has been breached by numerous historic inlets. Because the Pleistocene sedimentary deposit is generally of uniform thickness throughout the study area and unconformably overlies the Cretaceous coastal-plain strata, both the Holocene and historical evolution of the Fire Island barrier-island system are controlled by the physiography of this regional unconformity. In particular, the shoreface-connected sand ridges appear to be a significant source of sediment to the western portion of Fire Island. Previous attempts to develop a sediment budget for this coastal system have failed to explain volumetric discrepancies, primarily because poor assumptions were made about the nature of sediment transport in the system. A more realistic sediment budget must include a significantly larger spatial scale, including sediment input from the inner-continental shelf.

New York↗

Sedimentology of Permian upper part of the Minnelusa Formation, eastern Powder River Basin, Wyoming, and a comparison to the subsurface

Describes dolomite, gypsum, and sandstone units deposited in transgressive-regressive cycles. Three depositional cycles are partly exposed. The cycles observed in outcrop were informally labelled cycle 1, cycle 2, and cycle 3 in ascending stratigraphic order. West Mellott field represents a subsurface example of the facies and facies relationships observed in outcrop. The eolian-dune sandstone of the C cycle, which was partially reworked by the transgression of the B cycle, produces oil at West Mellott. The draping of dolomite and anhydrite of the B cycle on the eolian-dune sandstone of the C cycle is analogous to the draping gypsum on dune sand in cycle 2 in outcrop. -from Authors

Mountain Geologist↗

Middle Jurassic incised valley fill (eolian/estuarine) and nearshore marine petroleum reservoirs, Powder River Basin

Paleovalleys incised into the Triassic Spearfish Formation (Chugwater equivalent) are filled with a vertical sequence of eolian, estuarine, and marine sandstones of the Middle Jurassic (Bathonian age) Canyon Springs Sandstone Member of the Sundance Formation. An outcrop exemplifying this is located at Red Canyon in the southern Black Hills, Fall River County, South Dakota. These paleovalleys locally have more than 300 ft of relief and are as much as several miles wide. Because they slope in a westerly direction, and Jurassic seas transgressed into the area from the west there was greater marine-influence and more stratigraphic complexity in the subsurface, to the west, as compared to the Black Hills outcrops. In the subsurface two distinctive reservoir sandstone beds within the Canyon Springs Sandstone Member fill the paleovalleys. These are the eolian lower Canyon Springs unit (LCS) and the estuarine upper Canyon Springs unit (UCS), separated by the marine "Limestone Marker" and estuarine "Brown Shale". The LCS and UCS contain significant proven hydrocarbon reservoirs in Wyoming (about 500 MMBO in-place in 9 fields, 188 MMBO produced through 1993) and are prospective in western South Dakota, western Nebraska and northern Colorado. Also prospective is the Callovian-age Hulett Sandstone Member which consists of multiple prograding shoreface to foreshore parasequences, as interpreted from the Red Canyon locality. Petrographic, outcrop and subsurface studies demonstrate the viability of both the Canyon Springs Sandstone and Hulett Sandstone members as superior hydrocarbon reservoirs in both stratigraphic and structural traps. Examples of fields with hydrocarbon production from the Canyon Springs in paleovalleys include Lance Creek field (56 MMBO produced) and the more recently discovered Red Bird field (300 MBO produced), both in Niobrara County, Wyoming. At Red Bird field the primary exploration target was the Pennsylvanian "Leo sands" of the Minnelusa Formation, and production from the Canyon Springs was not anticipated. Canyon Springs reservoirs are easily bypassed because they are relatively unconsolidated, underpressured, low-resistivity, and difficult to evaluate from petrophysics, drill-stem tests, or well cuttings.

Mountain Geologist↗

The crazy hollow formation (Eocene) of central Utah

The Late Eocene Crazy Hollow Formation is a fluviatile and lacustrine unit that was deposited locally in the southwest arm of Lake Uinta during and after the last stages of the lake the deposited the Green River Formation. Most exposures of the Crazy Hollow are located in Sanpete and Sevier Counties. The unit is characterized by a large variety of rock types, rapid facies changes within fairly short distances, and different lithofacies in the several areas where outcrops of the remnants of the formation are concentrated. Mudstone is dominant, volumetrically, but siltstone, shale, sandstone, conglomerate and several varieties of limestone are also present. The fine-grained rocks are mostly highly colored, especially in shades of yellow, orange and red. Sand grains, pebbles and small cobbles of well-rounded black chert are widespread, and "salt-and-pepper sandstone" is the conspicuous characteristic of the Crazy Hollow. The salt-and-pepper sandstone consists of grains of black chert, white chert, quartz and minor feldspar. The limestone beds and lenses are paludal and lacustrine in origin; some are fossiliferous, and contain the same fauna found in the Green River Formation. With trivial exceptions, the Crazy Hollow Formation lies on the upper, limestone member of the Green River Formation, and the beds of the two units are always accordant in attitude. The nature of the contact differs locally: at some sites there is gradation from the Green River to the Crazy Hollow; at others, rocks typical of the two units intertongue; elsewhere there is a disconformity between the two. A variety of bedrock units overlie the Crazy Hollow at different sites. In the southeasternmost districts it is overlain by the late Eocene formation of Aurora; in western Sevier County it is overlain by the Miocene-Pliocene Sevier River Formation; in northernmost Sanpete County it is overlain by the Oligocene volcanics of the Moroni Formation. At many sites bordering Sanpete and Sevier Valleys the Crazy Hollow beds dip beneath Quaternary sediments that fill the two valleys. The Crazy Hollow Formation ranges from 0 to 1,307 feet (0-398 m) thick in the region, but is usually much thinner than the maximum value. At most outcrops it is only a few scores of feet (12-50 m) thick. Its age is middle Eocene, for it is only a little younger than the underlying Green River Formation. The unit developed by the washing of detritus into the basin of the southwest arm of Lake Uinta from the various source rocks in the highlands surrounding the basin. The limestone beds and lenses formed in ponds and small lakes that developed in the basin from time to time during and following the draining and evaporation of Lake Uinta. The qualities of the Crazy Hollow Formation are described in detail for 10 different areas of outcrops in the Sanpete and Sevier Valleys and vicinity.

Brigham Young University Geology Studies↗

Migrated hydrocarbons in exposure of Maastrichtian nonmarine strata near Saddle Mountain, lower Cook Inlet, Alaska

Magoon and others (1980) described an 83-meter- (272-foot-) thick succession of Maastrichtian (Upper Cretaceous) conglomerate, sandstone, mudstone, and coal exposed on the south side of an unnamed drainage, approximately 3 kilometers (1.8 miles) east of Saddle Mountain in lower Cook Inlet (figs. 1 and 2). The initial significance of this exposure was that it was the first reported occurrence of nonmarine rocks of this age in outcrop in lower Cook Inlet, which helped constrain the Late Cretaceous paleogeography of the area and provided important information on the composition of latest Mesozoic sandstones in the basin. The Saddle Mountain section is thought to be an outcrop analog for Upper Cretaceous nonmarine strata penetrated in the OCS Y-0097 #1 (Raven) well, located approximately 40 kilometers (25 miles) to the south–southeast in Federal waters (fig. 1). Atlantic Richfield Company (ARCO) drilled the Raven well in 1980 and encountered oil-stained rocks and moveable liquid hydrocarbons between the depths of 1,760 and 3,700 feet. Completion reports on file with the Bureau of Ocean Energy Management (BOEM; formerly Bureau of Ocean Energy Management, Regulation and Enforcement, and prior to 2010, U.S. Minerals Management Service) either show flow rates of zero or do not mention flow rates. A fluid analysis report on file with BOEM suggests that a wireline tool sampled some oil beneath a 2,010-foot diesel cushion during the fl ow test of the 3,145–3,175 foot interval, but the recorded fl ow rate was still zero (Kirk Sherwood, written commun., January 9, 2012). Further delineation and evaluation of the apparent accumulation was never performed and the well was plugged and abandoned. As part of a 5-year comprehensive evaluation of the geology and petroleum systems of the Cook Inlet forearc basin, the Alaska Division of Geological & Geophysical Surveys obtained a research permit from the National Park Service to access the relatively poorly understood ‘Saddle Mountain exposure’ that is located in the Lake Clark National Park and Preserve. This work was done in cooperation with the Alaska Division of Oil & Gas and U.S. Geological Survey (USGS) research geologists. This report expands on Magoon and others’ (1980) description of the exposure, presents new data on sandstone composition and reservoir quality, presents new geochemical data on petroleum extracted from the outcropping sandstone, and describes oil-bearing correlative strata penetrated by the Raven well. Although the exposure is more than a kilometer (0.6 mile) east of Saddle Mountain (fig. 2), in this report we variously refer to it as the Saddle Mountain succession, Saddle Mountain section, or the rocks at Saddle Mountain underlain by Upper Jurassic strata of the Naknek Formation.

Alaska↗

Hydrogeology, simulation of regional ground-water flow, and saltwater intrusion, Potomac-Raritan-Magothy Aquifer System, Northern Coastal Plain of New Jersey

The Potomac-Raritan-Magothy aquifer system in Middlesex and Monmouth Counties in the northern Coastal Plain of New Jersey consists primarily of unconsolidated Cretaceous sediments, which are divided into the upper and middle aquifers and confining units. These units, which strike northeastsouthwest along the Fall Line, dip and thicken to the southeast. The upper aquifer consists primarily of the Old Bridge Sand Member of the Magothy Formation, which is composed of coarse-grained sands, localized thin clay beds, and younger surficial sands and gravels in and near the outcrop. Transmissivity ranges from 1,760 to 19,400 ft 2 /d (feet squared per day) and tends to be higher in updip areas. Estimated withdrawals from the upper aquifer in the northern Coastal Plain were approximately 42 Mgal/d (million gallons per day) in 1986. Cones of depression whose centers range from 36 to 42 ft (feet) below sea level have developed as a result of these withdrawals. The upper aquifer is confined throughout most of the northern New Jersey Coastal Plain by clays and silts of the Cretaceous Woodbury Clay and Merchantville Formation and younger sediments of the Magothy Formation. This confining unit generally is greater than 200 ft thick. The simulated vertical hydraulic conductivity for the confining unit ranges from 8.4 x 10 -5 to 5.6 x 10 -3 feet per day; interpreted vertical hydraulic conductivities generally are lower except in southwestern Middlesex County, where the vertical hydraulic conductivities of the confining unit are higher. The middle aquifer consists primarily of the Farrington Sand Member of the Cretaceous Raritan Formation and surficial Holocene and Miocene sands and gravels in its outcrop area. It also can include the uppermost sands of the Cretaceous Potomac Group in parts of Monmouth County. The middle aquifer is composed of fine to coarse sand that contains some lignite and pyrite, and, locally, some clay beds. It pinches out in the northern part of Sayreville Township, near Raritan River. The transmissivity of the aquifer ranges from 2,140 to 13,800 ft 2/ d and tends to decrease in the northern part of the northern Coastal Plain of New Jersey where the aquifer thins. A poorly permeable confining unit composed mostly of clays and silts of the Woodbridge Clay Member of the Raritan Formation overlies the aquifer in most of this area. The confining unit generally is greater than 100 ft thick, although it thins and is sandy in the southwestern part of Middlesex County, where a good hydraulic connection exists between the middle and upper aquifers. Estimated withdrawals from the middle aquifer in the northern Coastal Plain were about 22 Mgal/d in 1986. These withdrawals have caused cones of depression whose centers range from 77 to 93 ft below sea level. A finite-difference, quasi-three-dimensional ground-water flow model was developed to simulate ground-water flow in the aquifer system. The confined and unconfined areas of the upper and middle aquifers were modeled as separate layers. The model was calibrated primarily by adjusting vertical hydraulic conductivity in the confining units and horizontal hydraulic conductivity in the aquifers, then matching simulated and measured groundwater levels for the period 1896-1986 and simulated and interpreted potentiometric surfaces under predevelopment conditions and in 1984. For the predevelopment period, the total flow into and out of the upper and middle aquifers is 35 and 21 Mgal/d, respectively. Recharge to the aquifer system is from direct recharge in the unconfined areas and from vertical leakage through overlying confining units. The main recharge areas are the topographically high areas in southwestern Middlesex County for both aquifers, in the eastern Sayreville area for the upper aquifer, and north of the Raritan River for the middle aquifer. Most ground water discharges to low-lying regional surface-water drains (streams), which flow into the South River. For 1984 transient conditions, the total ground-water flow into and out of the upper and middle aquifers is 61 and 34 Mgal/d, respectively. The largest amount of recharge is from direct recharge in the unconfined areas, but some recharge also is derived from vertical leakage through the Merchantville-Woodbury confining unit, captured ground-water discharge to streams, and induced inflow at artificial-recharge facilities. Regional flow is from recharge areas toward major cones of depression. Sensitivity analysis showed that the model was useful for representing flow in the system, especially in the confined-aquifer areas. Model representation of lateral and vertical boundary conditions was judged acceptable. Simulation results were less sensitive to changes in aquifer properties in the unconfined areas of the aquifers and to changes in storage in the confining units. Sensitivity analysis and calibration of hydraulic parameters and conditions showed that the distribution of hydraulic head was sensitive to changes in horizontal hydraulic conductivity in the aquifers, vertical hydraulic conductivity in the confining units, magnitudes of ground-water withdrawals, and initial hydraulic head in aquifer outcrop areas. Two scenarios were simulated to determine the effects of ground-water withdrawals from 1986 through 2019. For the scenario in which ground-water withdrawals increase to about 69 Mgal/d in the upper aquifer and 37 Mgal/d in the middle aquifer, centers of cones of depression are as deep as 100 ft below sea level in the upper aquifer and 170 ft below sea level in the middle aquifer. For this scenario, most of the additional water comes from captured surface-water discharge, induced cross-formational flow from overlying aquifers, and increases in induced flow from artificial-recharge areas. Induced flow from Raritan Bay also increases. For the scenario in which ground water withdrawals are reduced to 42.5 Mgal/d in the upper aquifer and 15 Mgal/d in the middle aquifer, water levels recover to above sea level nearly everywhere. In each aquifer, ground-water discharge to streams increases and induced flow through the confining units and from the overlying sediments decreases, and discharge of ground water to Raritan Bay in the upper aquifer exceeds the induced recharge from Raritan Bay. Reversal of ground-water gradients has caused saltwater intrusion in the two aquifers. Chloride concentrations in water from the upper aquifer in Keyport and Union Beach Boroughs were as high as 2,100 mg/L (milligrams per liter) in 1986. The intrusion has not increased significantly since well fields in the area were closed in the late 1970's. Elevated chloride concentrations also were measured in Keanesburg Borough in 1986. In both of these areas, saltwater has entered the upper aquifer from the Bay because of movement of the freshwater-saltwater interface in response to increasing ground-water withdrawals. Chloride concentrations in well-water samples from the middle aquifer were as high as 6,000 mg/L in Sayreville Borough in 1987; concentrations in samples from drive-point wells from the same aquifer near the Washington Canal, the main source of saltwater, were as high as 7,100 mg/L. The migration of the saltwater front at about 470 feet per year to the southeast is influenced mainly by a thinning of the middle aquifer, which constrains flow, and by the locations of regional cones of depression caused by groundwater withdrawals.

New Jersey↗

Analysis of the age and paleomagnetic orientation of the Broadwell Mesa Basalt, Bristol Mountains, CA

To add to the regional paleomagnetic data documenting block rotation in eastern California, we determined the age and paleomagnetic rotation of the Broadwell Mesa basalt, a basalt in the Bristol Mountains, CA as part of an effort to constrain the timing and rotation of blocks adjacent to the fault. The east-striking sinistral Broadwell Mesa fault cuts and separates the basalt into two outcrops. An 40Ar/39Ar date from the northern outcrop yields an age of 5.46 ± 0.04 Ma. Two sites consisting of 40 paleomagnetic cores from the basalt indicate the basalt is reversely magnetized and that there has been no significant rotation (< 11º) between the two basalt outcrops.

California↗

Geoarchaeology at Gilman Falls: An Archaic Quarry and Manufacturing Site in Central Maine, U.S.A

Interdisciplinary investigations at the Milford Reservoir, central Maine, resulted in excavation and analysis of a Middle Archaic quarry and manufacturing site at Gilman Falls, dated to between 7300 and 6300 yr B.P. Lithological analysis indicates that the majority of the artifacts came from very local outcrops, providing low-grade metamorphic rocks. Native Americans used a specialized technique to reduce the granofels and other rocks to long rods, artifacts commonly placed in local cemeteries. The Gilman Falls site was largely abandoned once these artifacts were no longer in vogue. Therefore, access to particular bedrock outcrops seems to have played an important role in site selection. Gilman Falls and other early to middle Holocene sites are preserved where bedrock sill dams ponded water that deposited fine sand. Early site sedimentation history is paralleled by a drainage change in the headwaters of the Penobscot River. Evidence for lower mid-Holocene lake levels and a period of higher temperatures and lower precipitation may correlate with the sedimentation history. ?? 2001 John Wiley & Sons, Inc.

Geoarchaeology - An International Journal↗

Trench infiltration for managed aquifer recharge to permeable bedrock

Managed aquifer recharge to permeable bedrock is increasingly being utilized to enhance resources and maintain sustainable groundwater development practices. One such target is the Navajo Sandstone, an extensive regional aquifer located throughout the Colorado Plateau of the western United States. Spreading-basin and bank-filtration projects along the sandstone outcrop's western edge in southwestern Utah have recently been implemented to meet growth-related water demands. This paper reports on a new cost-effective surface-infiltration technique utilizing trenches for enhancing managed aquifer recharge to permeable bedrock. A 48-day infiltration trench experiment on outcropping Navajo Sandstone was conducted to evaluate this alternative surface-spreading artificial recharge method. Final infiltration rates through the bottom of the trench were about 0.5 m/day. These infiltration rates were an order of magnitude higher than rates from a previous surface-spreading experiment at the same site. The higher rates were likely caused by a combination of factors including the removal of lower permeability soil and surficial caliche deposits, access to open vertical sandstone fractures, a reduction in physical clogging associated with silt and biofilm layers, minimizing viscosity effects by maintaining isothermal conditions, minimizing chemical clogging caused by carbonate mineral precipitation associated with algal photosynthesis, and diminished gas clogging associated with trapped air and biogenic gases. This pilot study illustrates the viability of trench infiltration for enhancing surface spreading of managed aquifer recharge to permeable bedrock. ?? 2010.

Hydrological Processes↗

A palynological biozonation for the Maastrichtian Stage (Upper Cretaceous) of South Carolina, USA

Three palynological biozones are proposed for the Maastrichtian Stage of South Carolina. In ascending stratigraphic order, the biozones are the Carolinapollis triangularis (Ct) Interval Biozone, the Holkopollenites chemardensis (Hc) Interval Biozone, and the Sparganiaceaepollenites uniformis (Su) Interval Biozone. Integration of the biostratigraphy with lithologic and geophysical log data suggests that within the study area, the upper and lower boundaries of each zone are bounded by regional unconformities, and that a three-fold subdivision of the Maastrichtian Stage is warranted. The biozonation is based on the analysis of 114 samples from 24 subsurface and three outcrop sections from the Coastal Plain of South Carolina; samples from an additional seven subsurface and 18 outcrop sections from North Carolina and Georgia were examined to evaluate the geographic extent of the biozones. One new genus and five new species of pollen are described, and emendations are presented for two genera and one species of pollen. ?? 2003 Published by Elsevier Science Ltd.

Cretaceous Research↗

Is Obsidian Hydration Dating Affected by Relative Humidity?

Experiments carried out under temperatures and relative humidities that approximate ambient conditions show that the rate of hydration of obsidian is a function of the relative humidity, as well as of previously established variables of temperature and obsidian chemical composition. Measurements of the relative humidity of soil at 25 sites and at depths of between 0.01 and 2 m below ground show that in most soil environments, at depths below about 0.25 m, the relative humidity is constant at 100%. We have found that the thickness of the hydrated layer developed on obsidian outcrops exposed to the sun and to relative humidities of 30-90% is similar to that formed on other portions of the outcrop that were shielded from the sun and exposed to a relative humidity of approximately 100%. Surface samples of obsidian exposed to solar heating should hydrate more rapidly than samples buried in the ground. However, the effect of the lower mean relative humidity experiences by surface samples tends to compensate for the elevated temperature, which may explain why obsidian hydration ages of surface samples usually approximate those derived from buried samples.

Quaternary Research↗

The information content of high-frequency seismograms and the near-surface geologic structure of "hard rock" recording sites

Due to hardware developments in the last decade, the high-frequency end of the frequency band of seismic waves analyzed for source mechanisms has been extended into the audio-frequency range (>20 Hz). In principle, the short wavelengths corresponding to these frequencies can provide information about the details of seismic sources, but in fact, much of the "signal" is the site response of the nearsurface. Several examples of waveform data recorded at "hard rock" sites, which are generally assumed to have a "flat" transfer function, are presented to demonstrate the severe signal distortions, including fmax, produced by near-surface structures. Analysis of the geology of a number of sites indicates that the overall attenuation of high-frequency (>1 Hz) seismic waves is controlled by the whole-path-Q between source and receiver but the presence of distinct fmax site resonance peaks is controlled by the nature of the surface layer and the underlying near-surface structure. Models of vertical decoupling of the surface and nearsurface and horizontal decoupling of adjacent sites on hard rock outcrops are proposed and their behaviour is compared to the observations of hard rock site response. The upper bound to the frequency band of the seismic waves that contain significant source information which can be deconvolved from a site response or an array response is discussed in terms of fmax and the correlation of waveform distortion with the outcrop-scale geologic structure of hard rock sites. It is concluded that although the velocity structures of hard rock sites, unlike those of alluvium sites, allow some audio-frequency seismic energy to propagate to the surface, the resulting signals are a highly distorted, limited subset of the source spectra. ?? 1988 Birkha??user Verlag.

Pure and Applied Geophysics PAGEOPH↗

Degassing during magma ascent in the Mule Creek vent (USA)

The structures and textures of the rhyolite in the Mule Creek vent (New Mexico, USA) indicate mechanisms by which volatiles escape from silicic magma during eruption. The vent outcrop is a 300-m-high canyon wall comprising a section through the top of a feeder conduit, vent and the base of an extrusive lava dome. Field relations show that eruption began with an explosive phase and ended with lava extrusion. Analyses of glass inclusions in quartz phenocrysts from the lava indicate that the magma had a pre-eruptive dissolved water content of 2.5-3.0 wt% and, during eruption, the magma would have been water-saturated over the vertical extent of the present outcrop. However, the vesicularity of the rhyolite is substantially lower than that predicted from closed-system models of vesiculation under equilibrium conditions. At a given elevation in the vent, the volume fraction of primary vesicles in the rhyolite increases from zero close to the vent margin to values of 20-40 vol.% in the central part. In the centre the vesicularity increases upward from approximately 20 vol.% at 300 m below the canyon rim to approximately 40 vol.% at 200 m, above which it shows little increase. To account for the discrepancy between observed vesicularity and measured water content, we conclude that gas escaped during ascent, probably beginning at depths greater than exposed, by flow through the vesicular magma. Gas escape was most efficient near the vent margin, and we postulate that this is due both to the slow ascent of magma there, giving the most time for gas to escape, and to shear, favouring bubble coalescence. Such shear-related permeability in erupting magma is supported by the preserved distribution of textures and vesicularity in the rhyolite: Vesicles are flattened and overlapping near the dense margins and become progressively more isolated and less deformed toward the porous centre. Local zones have textures which suggest the coalescence of bubbles to form permeable, collapsing foams, implying the former existence of channels for gas migration. Local channelling of gas into the country rocks is suggested by the presence of sub-horizontal syn-eruptive rhyolitic tuffisite veins which depart from the vent margin and invade the adjacent country rock. In the central part of the vent, similar local channelling of gas is indicated by steep syn-eruption tuffisite veins which cut the rhyolite itself. We conclude that the suppression of explosive eruption resulted from gas separation from the ascending magma and vent structure by shear-related porous flow and channelling of gas through tuffisite veins. These mechanisms of gas loss may be responsible for the commonly observed transition from explosive to effusive behaviour during the eruption of silicic magma.

Arizona, New Mexico↗

Inland fields of dispersed cobbles and boulders as evidence for a tsunami on Anegada, British Virgin Islands

Marine overwash from the north a few centuries ago transported hundreds of angular cobbles and boulders tens to hundreds of meters southward from limestone outcrops in the interior of Anegada, 140 km east–northeast of Puerto Rico. We examined two of several cobble and boulder fields as part of an effort to interpret whether the overwash resulted from a tsunami or a storm in a location where both events are known to occur. One of the cobble and boulder field extends 200 m southward from limestone outcrops that are 300 m inland from the island’s north shore. The other field extends 100 m southward from a limestone knoll located 800 m from the nearest shore. In the two fields, we measured the size, orientation, and spatial distribution of a total of 161 clasts and determined their stratigraphic positions with respect to an overwash sand and shell sheet deposit. In both fields, we found the spacing between clasts increased southward and that clast long-axis orientations are consistent with a transport trending north–south. Almost half the clasts are partially buried in a landward thinning and fining overwash sand and none were found embedded in the shelly mud of a pre-overwash marine pond. The two cobble and boulder fields resemble modern tsunami deposits in which dispersed clasts extend inland as a single layer. The fields contrast with coarse clast storm deposits that often form wedge-shaped shore-parallel ridges. These comparisons suggest that the overwash resulted from a tsunami and not from a storm.

Natural Hazards↗

Processes affecting geochemistry and contaminant movement in the middle Claiborne aquifer of the Mississippi embayment aquifer system

Groundwater chemistry and tracer-based age data were used to assess contaminant movement and geochemical processes in the middle Claiborne aquifer (MCA) of the Mississippi embayment aquifer system. Water samples were collected from 30 drinking-water wells (mostly domestic and public supply) and analyzed for nutrients, major ions, pesticides, volatile organic compounds (VOCs), and transient age tracers (chlorofluorocarbons, tritium and helium-3, and sulfur hexafluoride). Redox conditions are highly variable throughout the MCA. However, mostly oxic groundwater with low dissolved solids is more vulnerable to nitrate contamination in the outcrop areas east of the Mississippi River in Mississippi and west Tennessee than in mostly anoxic groundwater in downgradient areas in western parts of the study area. Groundwater in the outcrop area was relatively young (apparent age of less than 40 years) with significantly ( p < 0.05) higher dissolved oxygen and nitrate&ndash;N concentrations and higher detections of pesticides and VOCs compared to water samples from wells in downgradient areas. Oxygen reduction and denitrification rates were low compared to other aquifers in the United States (zero order rate constants for oxygen reduction and denitrification were 4.7 and 5&ndash;10 &mu;mol/L/year, respectively). Elevated concentrations of nitrate&ndash;N, and detections of pesticides and VOCs in some deep public supply wells (>50 m depth) indicated contaminant movement from shallow parts of the aquifer into deeper oxic zones. Given the persistence of nitrate in young oxic groundwater that was recharged several decades ago, and the lack of a confining unit, the downward movement of young contaminated water may result in higher nitrate concentrations over time in deeper parts of the aquifer containing older oxic water.

Claiborne Aquifer;Mississippi Embayment↗

Geochemistry and hydrodynamics of the Paradox Basin region, Utah, Colorado and New Mexico

The Paradox Basin region is approximately bounded by the south flank of the Uinta Basin to the north, the Uncompahgre uplift and San Juan Mountains to the east, the Four Corners structural platform to the southeast, the north rim of the Black Mesa Basin and the Grand Canyon to the south and southwest, and the Wasatch Plateau and Hurricane fault system to the west. Some of these geologic features are areas of ground-water recharge or discharge whereas others such as the Four Corners platform do not directly influence fluid movement. The aquifer systems studied were: (1) Mississippian rocks; (2) Pinkerton Trail Limestone of Wengerd and Strickland, 1954; (3) Paradox Member of the Hermosa Formation; (4) Honaker Trail Formation of Wengerd and Matheny, 1958; (5) Permian rocks. Recharge in the Paradox Basin occurs on the west flank of the San Juan Mountains and along the west side of the Uncompahgre uplift. The direction of ground-water movement in each analyzed unit is principally southwest-ward toward the topographically low outcrop areas along the Colorado River in Arizona. However, at any point in the basin, flow may be in some other direction owing to the influence of intrabasin recharge areas or local obstructions to flow, such as faults or dikes. A series of potentiometric surface maps was prepared for the five systems studied. Material used in construction of the maps included outcrop altitudes of springs and streams, drill-stem tests, water-well records, and an electric analog model of the entire basin. Many structurally and topographically high areas within the basin are above the regional potentiometric surface; recharge in these areas will drain rapidly off the high areas and adjust to the regional water level. With a few exceptions, most wells in formations above the Pennsylvanian contain fresh (< 1,000 mg/l T.D.S. 2 ) to moderately saline (< 10,000 mg/l T.D.S.) water. In only a few cases are true brines (> 35,000 mg/l T.D.S.) reported. Most water samples from strata below the Permian are brines of the sodium chloride type but with large amounts of calcium sulfate or calcium chloride type water commonly occurring. Because evaporite facies occur in the Paradox Member, this unit has brines with as much as 400,000 mg/l dissolved solids content. Previous analysis of the San Juan Basin has indicated the presence of an osmotic membrane system. The highly permeable Jurassic formations were postulated to be the outflow side of the membrane. It is also possible that the Upper Paleozoic units with known brines and with an otherwise inexplicably high potentiometric surface in the Four Corners area of New Mexico could be the outflow receptors of the San Juan membrane system.

Colorado, New Mexico, Utah↗

Mechanisms controlling Cu, Fe, Mn, and Co profiles in peat of the Filson Creek Fen, northeastern Minnesota

Filson Creek Fen, located in northeastern Minnesota, overlies a Cu-Ni sulfide deposit. A site in the fen was studied to evaluate the hydrogeochemical mechanisms governing the development of Fe, Mn, Co, and Cu profiles in the peat. At the study site, surface peat approximately 1 m thick is separated from the underlying mineralized bedrock by a 6–12 m thickness of lake and glaciofluvial sediments and till. Concentrations of Fe, Mn, Co, and Cu in peat and major elements in pore water delineate a shallow, relatively oxidized, Cu-rich zone overlying a deeper, reduced, Fe-, Mn-, and Co-rich zone within the peat. Sequential metal extractions from peat samples reveal that 40–55% of the Cu in the shallow zone is associated with organic material, whereas the remaining Cu is distributed between iron-oxide, sulfide, and residual fractions. Sixty to seventy percent of the Fe, Mn, and Co concentrated in the deeper zone occur in the residual phase. The metal profiles and associations probably result from non-steady-state input of metals and detritus into the fen during formation of the peat column. The enrichment of organic-associated Cu in the upper, oxidized zone represents a combination of Cu transported into the fen with detrital plant fragments and soluble Cu, derived from weathering of outcrop and subcrop of the mineral deposit, transported into the fen, and fixed onto organic matter in the peat. The variable stratigraphy of the peat indicates that weathering processes and surface vegetation have changed through time in the fen. The Fe, Mn, and Co maxima at the base of the peat are associated with a maximum in detrital matter content of the peat resulting from a transition between the underlying inorganic sedimentary environment to an organic sedimentary environment. The chemistry of sediments and ground water collected beneath the peat indicate that mobilization of metals from sulfide minerals in the buried mineral deposit or glacial deposits is minimal. Therefore, the primary source of Cu to the peat at the study site is outcrops and shallow subcrops of the mineral deposit adjacent to the fen.

Geochimica et Cosmochimica Acta↗