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Uranium analysis of single drops of natural waters using the fission-track technique

The fission-track technique has been applied to uranium analysis of natural waters using a single drop of water. Samples may be collected in the field by evaporating a drop of water on a detector, and samples may then be analyzed by returning the detector to the laboratory. A sample collecting kit has been assembled, which facilitates the designed sampling method. Some unique advantages of this technique are picogram sensitivity (10 -12 g) for uranium on single drops of water, maintenance of sample integrity during transport and storage, and the ability to discern whether the uranium is in solution or in the suspended material. Counting the tracks is the most time-consuming part of the analysis, but it can be reduced by using automatic counting systems. The analytical error is generally ± 10 percent over the entire range of concentrations.

Open-File Report

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Three-dimensional hydrogeologic framework model of the Russian River watershed, California

The Russian River watershed is in northern Sonoma County and southern Mendocino County, California, in the northern part of the California Coast Ranges. The Russian River serves as a supply for agricultural irrigation and for municipal, domestic, and commercial uses. Through a cooperative agreement with the California State Water Resources Control Board and Sonoma County Water Agency, the U.S. Geological Survey has completed studies to better understand the hydrogeologic system and develop numerical hydrologic modeling tools to evaluate and aid in managing groundwater resources. This report focuses on the development of a digital three-dimensional hydrogeologic framework model of the Russian River watershed for use in groundwater resource assessment and numerical models. The digital three-dimensional hydrogeologic framework model of the Russian River watershed portrays the altitude, thickness, and extent of five hydrogeologic units. These five hydrogeologic units include (1) a basement unit, (2) the Sonoma Volcanics, (3) a consolidated sedimentary rock unit, (4) an unconsolidated sediment unit, and (5) channel alluvium. Model input data were compiled from published geologic maps, interpreted well data, and a model of the top of basement derived from gravity data. These data were used to construct surfaces that represent the upper and lower subsurface boundaries of each hydrogeologic unit. Top surfaces were created for the five hydrogeologic units and then stacked in three dimensions to create a solid-volume digital model. The digital three-dimensional hydrogeologic framework model described in this report and the corresponding data represent the generalized geometry of the subsurface geologic units; the model reproduces the input geologic data with reasonable accuracy and is consistent with previously published subsurface conceptualizations of the region. The model indicates the overall geometry of the basement within the watershed and the spatial extent, altitude, and thickness of the basin-filling units. The hydrogeologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

California

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado

Summary of selenium in the lower Gunnison River Basin, Colorado—Information and data gaps

The Cretaceous Mancos Shale is a geologic source of selenium in the lower Gunnison River Basin. Natural weathering processes and human activity mobilize selenium from the Mancos Shale and derived materials, and surface water, groundwater, and sediment all affect the transport of selenium from source areas to receiving streams and biota. Selenium accumulates through the aquatic food chain, and its toxic effects can result in invertebrate mortality and mortality, decreased reproduction, and deformities to fish and birds. The Bureau of Reclamation, in cooperation with the State of Colorado and Gunnison River Basin water users, is implementing a Selenium Management Program to reduce selenium concentrations in the lower Gunnison River Basin of Colorado. Goals of the Selenium Management Program are to (1) achieve compliance with the State of Colorado chronic aquatic-life standard for dissolved selenium (4.6 micrograms per liter) in the Gunnison River near Grand Junction, Colorado; (2) sufficiently improve water-quality conditions to assist in the recovery of endangered species in the Gunnison and Colorado Rivers by reducing selenium concentrations; and (3) support continued water uses in the basin. Many previous studies have contributed to the understanding of selenium in the environment; however, monitoring and research data gaps exist in the lower Gunnison River Basin. The purpose of this report is to summarize information regarding selenium in the lower Gunnison River Basin and describe strategies for scientific research and monitoring to potentially improve understanding of selenium sources; processes affecting the mobilization, transport, and fate of selenium; and the effects of selenium-mitigation projects in the lower Gunnison River Basin. Monitoring and research data gaps discussed in this report include geologic mapping and geochemical source characterization, long-term and ongoing monitoring of the surface-water and groundwater networks, developing and refining statistical models, characterizing selenium on suspended sediment, modeling selenium in the food web, evaluating best management practices, and more.

Colorado

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration

The saline groundwater legacy of a large buried coastal paleo-estuary

Elevated groundwater salinity in coastal regions threatens the beneficial use of fresh groundwater. Coastal groundwater management typically focuses on preventing intrusion from modern sources of seawater; however, past geological processes can also leave a legacy of saline groundwater now hidden in the subsurface. Here, multiple extensive airborne electromagnetic surveys provide detailed evidence of residual salinity from a paleo-estuary filling a late Pleistocene incised valley impacting more than 10,000 km 2 that is now hidden beneath coastal Louisiana’s deltaic plain. Our results show that the three-dimensional pattern of saline groundwater beneath Louisiana mimics that of near-surface aquifers surrounding the modern Delaware Bay estuary, fingerprinting the signature of the past drowning of a large, incised valley of the Mississippi River following post-glacial sea-level rise. These findings demonstrate a new framework for understanding legacy sources of saltwater critical for managing stressed water resources along global coastlines.

Louisiana

Permafrost–wildfire interactions: active layer thickness estimates for paired burned and unburned sites in northern high latitudes

As the northern high-latitude permafrost zone experiences accelerated warming, permafrost has become vulnerable to widespread thaw. Simultaneously, wildfire activity across northern boreal forest and Arctic/subarctic tundra regions impacts permafrost stability through the combustion of insulating organic matter, vegetation, and post-fire changes in albedo. Efforts to synthesis the impacts of wildfire on permafrost are limited and are typically reliant on antecedent pre-fire conditions. To address this, we created the FireALT dataset by soliciting data contributions that included thaw depth measurements, site conditions, and fire event details with paired measurements at environmentally comparable burned and unburned sites. The solicitation resulted in 52 466 thaw depth measurements from 18 contributors across North America and Russia. Because thaw depths were taken at various times throughout the thawing season, we also estimated end-of-season active layer thickness (ALT) for each measurement using a modified version of the Stefan equation. Here, we describe our methods for collecting and quality-checking the data, estimating ALT, the data structure, strengths and limitations, and future research opportunities. The final dataset includes 48 669 ALT estimates with 32 attributes across 9446 plots and 157 burned–unburned pairs spanning Canada, Russia, and the United States. The data span fire events from 1900 to 2022 with measurements collected from 2001 to 2023. The time since fire ranges from 0 to 114 years. The FireALT dataset addresses a key challenge: the ability to assess impacts of wildfire on ALT when measurements are taken at various times throughout the thaw season depending on the time of field campaigns (typically June through August) by estimating ALT at the end-of-season maximum. This dataset can be used to address understudied research areas, particularly algorithm development, calibration, and validation for evolving process-based models as well as extrapolating across space and time, which could elucidate permafrost–wildfire interactions under accelerated warming across the high-northern-latitude permafrost zone. The FireALT dataset is available through the Arctic Data Center ( https://doi.org/10.18739/A2RN3092P , Talucci et al., 2024).

Arctic

Multi-scale predictors of Northern Long-eared Bat (Myotis septentrionalis) occupancy in the United States

Historically, Myotis septentrionalis (Northern Long eared Bat) was among the most common forest-interior species in North America. Largely due to high mortality from white-nose syndrome, this species has experienced severe population declines across its range. To create an updated species distribution map representing summer occupancy probabilities from 2017 to 2022, we integrated stationary acoustic data with live-capture data from the database of the North American Bat Monitoring Program into a multi-scale, multi-method occupancy modeling framework. Our results provide data-driven predictions with quantified uncertainty for summer occupancy probabilities for Northern Long-eared Bats at 2 spatial scales across the range of the species, while also accounting for inherent observation biases (e.g., imperfect detection).

Journal of North American Bat Research

Evolution of arsenic speciation during thermal treatment simulating wildfire heating in arsenic-rich sediments

Understanding arsenic transformations during wildfires can help better constrain the environmental impacts of increased wildfire intensity, frequency, and burned area. Previous studies have monitored the evolution of metal(loid) speciation at specific time/temperature endpoints, hampering the comprehension of the dynamic transformations of metal(loid)s during wildfires. Here, a novel approach, namely in situ time-resolved X-ray absorption near edge structure (TR-XANES) spectroscopy, was used for the first time to monitor the heat-induced redox transformations of arsenic (As) in two As-rich sediments with different characteristics. No arsenic transformations were observed in either sediment at room temperature or when the sediments were heated to a maximum temperature of 400 ºC. When heated to a maximum temperature of 600 or 700 ºC, As underwent complex, dynamic, and partially reversible redox transformations, the extent of which varied with sediment properties, initial As speciation, and heating temperature and duration. In the case of sediments initially containing As(V) and a low sulfide/sulfate ratio, the As(V) was reduced to As(III) over a short period of time, followed by immediate reoxidation of As(III) to As(V). The extent of the transient As reduction increased with increasing maximum temperature. The final As speciation at the end of the heating experiment was not substantially different from that at the beginning of the experiment. In contrast, in sediments that were best described by a more complex combination of reference compounds (As(V) coprecipitated with or adsorbed on iron oxide, arseniosiderite, arsenopyrite) with a high sulfide/sulfate ratio, As(V) phases were reduced to As(III) and As(III) was further reduced to As(-I) (at 700 ºC, only), followed by delayed reoxidation of As(-I) to As(III) (at 700 ºC, only) and reoxidation of As(III) to As(V). Approximately 9% and 26% of all As remained as As(III) ( i.e., was not reoxidized to As(V)) at the end of the experiment when heated to a maximum temperature of 600 and 700 ºC, respectively, which is higher than the relative abundance of As(III) in the native sediment. These fire-induced As transformations can potentially enhance As mobilization to surface water and groundwater, posing risks to environmental and human health.

California

Using the horizontal-to-vertical spectral ratio method to estimate thickness of the Barry Arm landslide, Prince William Sound, Alaska

Conducting detailed investigations of large landslides is difficult, especially in the subsurface, largely due to environmental factors such as steep slopes, difficult access, and numerous objective hazards. These factors have made it challenging to accurately estimate the depth to the failure surface of the Barry Arm landslide, a large (roughly 10 8 cubic meters), deep-seated bedrock landslide in Prince William Sound, Alaska, recognized in 2019. The landslide has exhibited accelerated movement in recent years and poses a potential tsunamigenic hazard if rapid failure occurs. Failure surface depth, equivalent to landslide thickness, is a necessary metric for landslide-volume calculations and associated tsunami wave models. In this report, we used seismic noise recorded by a seismometer located on the Barry Arm landslide in Alaska to calculate the horizontal-to-vertical spectral ratio (HVSR) to investigate the site fundamental frequency ( f 0 ) and depth of the failure surface. To ensure that observed peak frequencies in the spectral ratio were related to the underlying stratigraphy (and not caused by other noise sources like nearby glaciers, topographic resonance, weather, or human activities), we also calculated HVSRs using earthquake signals, HVSRs at other seismic stations within a 2.5-kilometer radius, and a standard spectral ratio between the landslide station and other sites. We observed multiple peaks in the landslide HVSR curves at 1.5 hertz (Hz), 4–5 Hz, and 7–11 Hz. The frequencies of these peaks were consistent at the landslide site through time and across methods and were dissimilar to those identified at other seismic stations in the area, making it unlikely the peaks were caused by local noise. Directional HVSRs calculated at 15-degree intervals showed amplification of the higher frequency peaks in the direction parallel to slip, indicating two-dimensional site effects. We used the distinct frequency peaks in the seismic record to develop a 4-layer conceptual model of the landslide wherein the top of the deepest layer represents the primary failure surface, or the boundary between damaged (mobile) and undamaged material. We inverted Rayleigh wave ellipticity curves within this 4-layer configuration with constraints on S-wave velocity and layer thickness based on analogous material properties identified in the literature. This was necessary absent any site-specific subsurface S-wave velocity data. The best-fitting models indicate a mean slope-normal depth to the failure surface of 188 (±9) meters (m), with additional stratigraphic boundaries at 4 and 20 m below ground surface, potentially representing layered motion. These results agree with and improve upon ranges estimated by previous studies and can support future modeling and assessment efforts at Barry Arm.

Alaska

Peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. This work is part of that reexamination. The stationarity assumption is a concern because flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done to assess potential nonstationarity in peak flows in the north-central United States. This report summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Scientific Investigations Report

The role of bedrock circulation depth and porosity in mountain streamflow response to prolonged drought

Quantitative understanding is lacking on how the depth of active groundwater circulation in bedrock affects mountain streamflow response to a multi‐year drought. We use an integrated hydrological model to explore the sensitivity of a variety of streamflow metrics to bedrock circulation depth and porosity under a plausible extreme drought scenario lasting up to 5 years. Endmember depth versus hydraulic conductivity relationships and porosity values for fractured crystalline rock are simulated. With drought, a deeper circulation system with higher drainable porosity more effectively buffers minimum flow and significantly limits perennial stream loss in comparison to a shallow circulation system. Streamflow buffering is accomplished through extensive groundwater storage loss. However, deeper circulation systems experience prolonged recovery from drought in comparison to storage‐limited shallow systems. Research highlights the importance of characterizing the deeper bedrock hydrogeology in mountainous watersheds to better understand and predict drought impacts on stream ecosystem health and water resource sustainability.

Colorado

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California

Declining groundwater storage expected to amplify mountain streamflow reductions in a warmer world

Groundwater interactions with mountain streams are often simplified in model projections, potentially leading to inaccurate estimates of streamflow response to climate change. Here, using a high-resolution, integrated hydrological model extending 400 m into the subsurface, we find groundwater an important and stable source of historical streamflow in a mountainous watershed of the Colorado River. In a warmer climate, increased forest water use is predicted to reduce groundwater recharge resulting in groundwater storage loss. Losses are expected to be most severe during dry years and cannot recover to historical levels even during simulated wet periods. Groundwater depletion substantially reduces annual streamflow with intermittent conditions predicted when precipitation is low. Expanding results across the region suggests groundwater declines will be highest in the Colorado Headwater and Gunnison basins. Our research highlights the tight coupling of vegetation and groundwater dynamics and that excluding explicit groundwater response to warming may underestimate future reductions in mountain streamflow.

Nature Water

Reservoir evolution, downstream sediment transport, downstream channel change, and synthesis of geomorphic responses of Fall Creek and Middle Fork Willamette River to water years 2012–18 streambed drawdowns at Fall Creek Lake, Oregon

Executive Summary Chapter A. Introduction Fall Creek Dam impounds Fall Creek Lake, a 10-kilometer-long reservoir in western Oregon and is operated by the U.S. Army Corps of Engineers (USACE) primarily for flood-risk management (or flood control) in late autumn through early spring months, as well as for water quality, irrigation, recreation, and habitat in late spring through early autumn. Since 2011 (water year [WY] 2012), Fall Creek Lake has been temporarily drawn down each year to facilitate downstream passage of juvenile spring Chinook salmon ( Oncorhynchus tshawytscha ) through the 55-meter (m) high dam. This annual dam operation is temporary, typically lasting about 1–2 weeks from WY 2012 through 2020 (drawdown operations in WY 2022–24 have increased to more than 6 weeks). Drawdown of the reservoir results in lake levels being lowered to the elevation near the historical, pre-dam streambed. The annual streambed drawdowns of WY 2012–18 have improved fish passage and led the USACE to formally adopt streambed drawdowns as part of annual operations at Fall Creek Dam. However, temporarily lowering the lake to streambed creates free-flowing conditions in the reservoir that result in the erosion and episodic export of predominantly sand and finer-grained sediments (less than 2 millimeters [mm]) to the lower gravel-bed reaches of Fall Creek and the Middle Fork Willamette River. The introduction of large volumes of sand and finer-grain sediment into the dam-regulated reaches downstream from Fall Creek Dam prompted questions about the geomorphic responses to annual streambed drawdowns within Fall Creek Lake and downstream reaches along Fall Creek and the Middle Fork Willamette River. The U.S. Geological Survey (USGS) in partnership with USACE initiated a comprehensive geomorphic and sediment transport investigation to assess the coupled processes of reservoir erosion, sediment evacuation from Fall Creek Lake, and patterns of sediment transport and deposition in reaches downstream from the Fall Creek Dam that have resulted from annual streambed drawdowns. The purpose of this report is to systematically describe the processes of sediment erosion, transport, and deposition at Fall Creek Lake and geomorphic interactions between reaches upstream and downstream from Fall Creek Dam that relate to dam operations. Specifically, this report focuses on evaluating geomorphic responses to streambed drawdowns from WY 2012 through 2018 and placing drawdown-induced geomorphic responses within the broader context of physiographic and historical conditions and dam operations of Fall Creek and Middle Fork Willamette Rivers. Key objectives for this study were to characterize changes in reservoir morphology and substrate at Fall Creek Lake, describe the character and temporal pattern of sediment transport downstream from Fall Creek Dam, characterize geomorphic changes in channel reaches downstream from the Fall Creek Dam, and relate these data to the annual streambed drawdowns of WY 2012–18. This study uses multiple independent monitoring and measurement approaches to assess site, reach, and river-scale geomorphic responses to drawdowns to inform dam and reservoir management. Patterns and processes of reservoir evolution were assessed with geomorphic mapping and volumetric analyses of topography through comparison of multiple digital surface models (DSMs). Just downstream from Fall Creek Dam, analyses of sediment export from the reservoir focused on suspended sediment but also incorporated bedload analyses to assess sediment sizes. Geomorphic assessments downstream from the dam used reach-scale and site-scale approaches to document changes in channel morphology and substrate, including site measurements of sand and finer-grained sediment deposition and in-channel bed-material, volumetric change analyses from comparison of digital elevation models (DEMs), and repeat geomorphic mapping. Findings from this study inform river management and dam operations by providing an understanding of (1) coupled upstream-downstream geomorphic responses to the Fall Creek Lake streambed drawdowns, (2) geomorphic responses of Fall Creek Lake streambed drawdowns in comparison to drawdowns at other large dams, (3) controls on reservoir erosion and downstream geomorphic responses, and (4) implications for future hydrogeomorphic changes that may result from continued drawdowns and monitoring activities to assess those changes. Chapter B. Reservoir Morphology and Evolution Related to Dam Operations at Fall Creek Lake To understand the volume and distribution of sediment accumulation in Fall Creek Lake since dam closure in 1965, decadal-scale sedimentation patterns (spanning approximately 1965–2016) are evaluated using a combination of storage curve analyses and geomorphic mapping. Short-term (drawdown event-scale) patterns of erosion, sedimentation, and sediment export downstream are evaluated using a combination of geomorphic mapping and change detection analyses that quantify the distribution and total volume of sediment erosion and deposition within Fall Creek Lake. Geomorphic mapping of reservoir topography and analyses of historical datasets reveals four categories of landforms and sediment processes within Fall Creek Lake related to lake level operations: lacustrine sedimentation expressed in the reservoir floor, fluvial erosion and deposition within historical stream channels during streambed drawdowns, channel-like features created by erosion within the reservoir floor during streambed drawdowns, and erosion on reservoir hillslopes. Where the reservoir floor is mapped for this study as pelagic (deep water), deposition up to 3 meters (m) thick by lacustrine processes and burial of pre-dam topography with deposits thinning toward the edges of the valley floor and upstream areas of reservoir are observed. Despite over 50 years of sediment accumulation since dam construction, the main stream channels of Fall and Winberry Creeks (or reservoir thalwegs) through the reservoir are well defined, though their distinct morphology is likely influenced by a long history of recurring historical drawdowns to or near streambed since dam construction. Unregulated streamflow and sediment transport through the reservoir primarily are confined to these channels during the streambed drawdown periods. Erosional channel-like features created by drawdowns are carved through underlying, unconsolidated reservoir floor sediments and are most prominent in the lower reservoir below minimum conservation pool (the low pool elevation during winter flood season); sediment generated from the formation of these drawdown channels is more likely to be transported through and out of the reservoir than sediment deposits along the reservoir hillslopes at the valley margins that are separated from main channels by areas of low-gradient reservoir floor. Morphologic changes in the lower reservoir topography between January 2012 and November 2016 indicate overall net erosion of about 129,500 cubic meters (m 3 ). The most prominent geomorphic changes occurred along the main channels of Fall and Winberry Creeks near the Fall Creek Dam where incision, lateral migration, and slumping banks resulted in vertical and lateral adjustments to channel position, whereas most changes fell below the detectable limit on higher-elevation reservoir floor surfaces except where erosion occurred along features mapped as drawdown channels. Chapter C. Sediment Delivery from Fall Creek Lake and Transport through Downstream Reaches USGS implemented a sediment monitoring program in WY 2013–18 to evaluate the quantity and character of reservoir sediment exported from Fall Creek Lake during streambed drawdowns. Turbidity and suspended sediments were monitored annually autumn through spring to span the WY 2013–18 streambed drawdowns; however, unequal monitoring timeframes each year reduced the ability to compare results and factors affecting sediment export from the reservoir difficult between years. These data were originally measured to develop regressions and compute suspended-sediment loads (SSL). Bedload sediment monitoring from a cableway at the Fall Creek streamgage was completed in the autumn-winter of WY 2013 and 2017. The limited number of samples and presumed variability in sediment supply from the reservoir precluded construction of streamflow and bedload discharge relations to compute more than instantaneous bedload. Sand and finer-grained silts and clays were transported from the reservoir in suspension, though some coarser grains (up to 32 mm) were also mobilized and transported downstream from the dam as bedload. Observations of increased sediment transport downstream from Fall Creek Dam coincided with lake levels approaching about 3 m (10 feet [ft] or elevation 690 ft) above the streambed regulating outlets. Suspended-sediment loads computed for the full monitoring periods WY 2013–18 at the Fall Creek streamgage, located 1.4 kilometers (km) downstream from Fall Creek Dam, range from 54,700 metric tons (t) in WY 2013 to 13,900 t in WY 2018. Although the total annual SSL varied from year to year, the overall seasonal patterns of suspended sediment transport throughout each year were similar during monitoring in WY 2013-18. Suspended-sediment loads were low prior to the drawdown, then increased rapidly as lake levels lowered and approached the streambed. In the weeks following the drawdown period, as pool levels were increased, SSL remained slightly elevated above pre-drawdown levels but generally declined through the following winter and spring except during streamflow-driven pulses of suspended-sediment transport. WY 2013 had the greatest total computed SSL for each streambed drawdown and partial-year monitoring period. SSL computed for the partial-year period have generally decreased since WY 2013 and have varied by about 6,800 t with the exception of WY 2014. WY 2014 SSL reflects anomalously low sediment export due to low streamflows and freezing conditions that stabilized reservoir floor deposits. Bedload measurements in the short 1.4-km reach between Fall Creek Dam and the Fall Creek streamgage showed an inverse correlation between bedload transport rates and discharge, which probably reflects diminishing supply of coarse-sized sediment. Sand was more abundant (60–100 percent) than gravel in bedload samples confirming sand and finer-grained sediment dominated sediment evacuated from the reservoir during streambed drawdowns at Fall Creek Lake. Chapter D. Geomorphic Responses to Fall Creek Lake Streambed Drawdowns Downstream from Fall Creek Dam In the days, weeks, and months following streambed drawdown operations at Fall Creek Dam through WY 2018, sites downstream from the dam displayed a variety of geomorphic responses to reservoir sediment delivery within the main channel and overbank areas. Evaluation of streambed elevations at two streamgages located 1.4 km downstream from the dam on Fall Creek and 16.3 km downstream from the dam on the Middle Fork Willamette River indicated the effects of drawdown sediment on bed elevations were modest and transient. Repeat particle size measurements (October 2015 and September 2016) at five sites along Fall Creek and the Middle Fork Willamette River showed similar grain-sized distributions that do not reveal substantial deposition of fine-grained sediment related to the WY 2016 streambed drawdown. Altogether, these findings indicate that transport capacity in the main, low-flow channels of Fall Creek and Middle Fork Willamette River during WY 2012–18 was sufficient to mobilize and evacuate reservoir sediments from streambed drawdowns or other bank material and tributary sources. However, other monitoring for this study indicate low-velocity zones in off-channel areas are prime locations for sand and finer-grain sediment deposition. Patterns of overbank sediment accumulation indicate that the magnitude and timing of overbank deposition on bars and low-elevation floodplain varies with proximity to the dam, geomorphic setting, streamflows, and other factors. Sand and finer-grained reservoir sediments carried as suspended-sediment load in the reaches downstream from Fall Creek Dam were deposited in overbank areas as observed with clay-horizon markers during WY 2016–17. Overbank deposition quantified with Geomorphic Change Detection (GCD) software evaluated landform-scale patterns of erosion and deposition using repeat light detection and ranging (lidar) surveys at two sites in the Upper Fall Creek reach and one site in the Jasper reach for 3 years (2012–15) and one site in the Clearwater reach for 6 years (2009–15). Deposition thickness and spatial patterns from the GCD analysis were variable; some sites had dispersed but measurable deposition while at others, deposition was highly localized and exceeded 1 m in depth. Patterns of overbank deposition illustrate interactions among bar morphology, local hydraulics, and suspended-sediment transport dynamics that can create patches of highly localized deposition. The measured deposition at the two Fall Creek GCD sites likely resulted from reservoir sediments released from Fall Creek Lake during streambed drawdowns in WY 2016 and 2017 because the limited sediment inputs from bank material (geomorphically laterally stable reach) or tributaries (no significant tributaries) provided few other sediment sources. On the Middle Fork Willamette River, observed patterns of overbank deposition could reflect sediment sourced from upstream tributaries, bank erosion, or Fall Creek Lake streambed drawdown operations. Despite the introduction of several thousand tons of reservoir sediment delivered from the Fall Creek Lake streambed drawdowns to below-dam river corridors, reach-scale mapping of channel features downstream from Fall Creek Dam shows minimal evidence of changes in channel planform or landforms that can be attributed to a drawdowns in WY 2012–16. On Upper Fall Creek reach, widespread increases in gravel bars or other in-channel sediment did not result from the five streambed drawdowns. The main changes attributable to sediment releases from Fall Creek Lake were localized increases in vegetated bar area, particularly on channel margin areas where sand and finer-grain sediment was deposited and rapidly colonized by vegetation. The area of mapped secondary water features decreased between 2005 and 2016, but that may be due to lower discharges depicted in the 2016 aerial photographs and less mapped area of inundation. Primary changes along the Lower Fall Creek reach include a 6.4 percent decrease in area of secondary water features between 2011 and 2016, and a nearly twofold increase in the area of unvegetated bars. Immediately downstream from the Fall Creek confluence, there were negligible changes in the location and areas of vegetated bars and the main wetted channel between 2005 and 2016, and local increases in bar area cannot be attributed solely to deposition of reservoir sediments from Fall Creek Lake because (1) areas along the Middle Fork Willamette River just upstream from the Fall Creek confluence display similar type and magnitude of changes and (2) some of the increases at the confluence area pre-date the drawdowns. The cumulative effect of sediment releases from Fall Creek Lake streambed drawdowns from WY 2012 to 2016 on downstream channel planform and landforms are modest compared to the river-scale transformations and planform changes that occurred in the decades following dam construction. Chapter E. Discussion of Geomorphic Responses of Fall Creek and Middle Fork Willamette River to Streambed Drawdowns at Fall Creek Lake Multiple aspects of Fall Creek Dam infrastructure and operations exert first-order controls on the magnitudes of reservoir erosion that occur during the streambed drawdowns and ultimately determine the sediment delivery to downstream reaches. Key aspects of the dam and its operations that are most relevant to assessing geomorphic responses to streambed drawdowns include the (1) dam infrastructure, including configuration and size of regulating outlets and their proximity to the streambed which dictates the capacity and competence of the river to deliver sediment to downstream reaches and mode of sediment transport as suspended-sediment load or bedload; (2) frequency of historical drawdowns and long-term, year-round dam operations and lake level management, which partly dictate reservoir morphology and locations and magnitudes of readily erodible materials; (3) dam operations and hydroclimatic conditions during the streambed drawdown (including length of the drawdown and streamflows entering the reservoir), which directly control the timing, duration and magnitude of reservoir erosion and sediment evacuation; and (4) dam operations following the streambed drawdown operation that regulate streamflows (and thereby sediment transport conditions) downstream of Fall Creek Dam which primarily reflect interactions between hydroclimatic conditions and flood control operations. Patterns of sediment erosion and evacuation observed in this study at Fall Creek Lake from WY 2012–18 suggest that reservoir erosion during annual streambed drawdowns may remain similar or decrease in future years assuming (1) annual streambed drawdown operations are implemented in similar manner as the WY 2012–18 drawdowns (in terms of duration, late autumn or early winter implementation, rate of pool-level lowering to reach streambed, and other factors), (2) streambed drawdowns coincide with similar conditions as were observed WY 2012–18 (similar sediment yield into reservoir, low reservoir inflows, limited precipitation, moderate air temperature), and (3) no major geomorphic changes in the main reservoir channels of Fall and Winberry Creeks occur (for example, channel avulsion). Under such conditions, it is hypothesized that the stream channel within the reservoir would achieve a quasi-equilibrium state with respect to annual influx and export of sediment and aided by the substantial amount of in-channel bedrock, will remain laterally stable without erosion across reservoir deposits. Patterns of sediment transport measured at the Fall Creek streamgage downstream from Fall Creek Dam provide insight into the potential effects of future streambed drawdowns at Fall Creek Lake. Analyses of suspended sediment measured in WY 2013–18 show a major reduction in suspended-sediment loads between WY 2013 and later years, indicating streamflows transporting sediment through the reservoir to downstream reaches during streambed drawdowns have become supply limited. The 6-year suspended-sediment monitoring and sampling program is insufficient to make predictions about future sediment transport conditions because of uneven monitoring periods and varying controls on reservoir sediment erosion. It is likely that future suspended-sediment loads will be variable but similar to those observed in WY 2015–18 if operational, climatic, and geomorphological factors remain similar to those monitored WY 2015–18. Suspended-sediment loads downstream from Fall Creek Lake will likely remain highest when regulating outlets are fully open and Fall Creek is free flowing with the reservoir fully drained with little to no residual pool. Over time, it is possible that the suspended-sediment loads would reflect mobilization of reservoir sediment deposited in the previous year rather than erosion of sediment deposited years or decades earlier. Bedload is likely to remain a small fraction of the total sediment load evacuated from the reservoir and is relatively modest compared with pre-dam bedload transport rates because most coarse sediment remains trapped by the dam. If sediment releases from Fall Creek Lake and ensuing streamflow conditions follow a similar pattern in the future as was assessed in this study spanning WY 2012–18, near-term geomorphic adjustments downstream of the dam are expected to be modest. Barring major operational, climatic, and geomorphological changes, local site-scale deposition on bars, overbank areas, or off-channel features that persists several months after the streambed drawdown will likely continue to be highly variable, ranging from negligible to several centimeters of deposition. At the landform-scale, low velocity areas nearest to Fall Creek Dam will likely continue to undergo rapid deposition immediately during and after a streambed drawdown event, similar to patterns observed for WY 2012–18. Some of the sediment entering these off-channel features and margin areas may be temporarily stored, then later remobilized and dispersed farther downstream. But if newly deposited sediment persists through the following spring, there is a greater likelihood that local vegetation will establish, reinforce deposited material, and trap sediment during later drawdowns. The reach-scale geomorphic changes may become more apparent if (1) streambed drawdowns continued for several decades, and geomorphic changes were measured at decadal scales or (2) the amount of sediment introduced to downstream reaches substantially increased and (or) sediment transport capacity decreased. The continued streamflow regulation of Fall Creek Dam after sediment releases provides an opportunity to strategically manage streamflows during and after the streambed drawdowns to minimize downstream sediment impacts and ensure other operational thresholds are satisfied. This study provides a comprehensive foundation of datasets and geomorphic analyses to inform dam operations at Fall Creek Lake, monitor sediment transport downstream, and consider operational schemes for future drawdowns. The datasets from this study also provide baselines of sediment transport and geomorphic conditions to assess future changes in reservoir and downstream environments. Future monitoring could be tailored to address specific questions regarding the long-term geomorphic effects of streambed drawdowns on fluvial habitats, flood hazards, cultural resources, or downstream water quality. Future monitoring activities could focus on the relevant geomorphic processes and spatial domains within the three categories used for this study: (1) reservoir erosion and net sediment evacuation, (2) sediment delivery to downstream reaches, including magnitude and temporal pattern of sediment transport, and (3) geomorphic responses of downstream reaches to sediment delivery. Specifically, high priority future monitoring activities could include: Repeat topographic or photographic surveys in the reservoir to characterize changes occurring within individual drawdowns, to quantify sediment export, to determine temporal changes in reservoir storage, and to identify locations of erosion and deposition. Continuous, year-round turbidity monitoring supplemented with suspended-sediment measurements at a streamflow-gaging station immediately downstream from the dam to quantify sediment export. Repeat geomorphic monitoring, mapping, or modeling in downstream reaches to track changes in channel and over bank features using a combination of site- and reach-scale monitoring approaches. This could support assessments of sediment deposition and ensuing vegetation encroachment on flood hazards and habitats and examine how sediment transport and depositional processes may be affected by different sediment supply, streamflow, or dam management scenarios.

Oregon

3-D mapping of the conterminous U.S. within the USGS National Cooperative Geologic Mapping Program: Progress and future prospects

The U.S. Geological Survey (USGS) National Cooperative Mapping Program (NCGMP) is bringing together subsurface and three-dimensional information at multiple scales for the conterminous United States from data produced throughout the USGS and by federal and state partners. Components of this work include data inventory and catalog development, data integration and database development, and construction of subregional and basin-scale three-dimensional (3-D) geologic models. At small scales, the NCGMP is compiling subsurface data to create a limited number of subsurface layers that map the majority of the lower 48 States. At larger scales, 3-D models of stratigraphic units are intended to be the subsurface analog and extension of the surface geologic maps made within the Program. The Mapping Program is developing methods of storing, visualizing, and distributing 3-D models and subsurface data from multiple sources in easily shareable, queryable, non-proprietary format(s). We report on progress in 3-D mapping of the conterminous U.S. and on future prospects.

conterminous United States

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota