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An entropic explanation for Gutenberg-Richter scaling

We develop a simple explanation for Gutenberg-Richter (G-R) size scaling of earthquakes on a single fault. We discretize the fault and consider all possible contiguous ruptures at that level of discretization. In this static model, we assume that slip scales with rupture length, and that the rupture rates at each point along the fault are consistent with an a priori long-term slip rate. These simple assumptions define an (under-determined) non-negative least-squares inverse problem. Each solution to this inverse problem is a set of earthquake rates that matches the slip-rate constraint. We use a Markov Chain Monte Carlo (MCMC) algorithm to uniformly sample the solution space assuming constant slip rates along the fault. At finer discretizations, deviations from G-R behavior decrease, which is consistent with an entropic pressure towards G-R solutions. When the fault is discretized into 10 or more segments, random solutions found by the MCMC algorithm have G-R size scaling, even though there are trivial solutions that, for example, have earthquakes of only one size. This is because there are simply far more solutions that have G-R scaling; as the problem size increases, the strong degeneracy of GR solutions results in other solutions becoming improbably rare. Also, the entropically favored G-R distribution has a b -value of approximately 1, which agrees with measured b -values in real earthquake catalogs.

JGR Solid Earth

Field-trip guide to Mount Hood, Oregon, highlighting eruptive history and hazards

This guidebook describes stops of interest for a geological field trip around Mount Hood volcano. It was developed for the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon. The intent of this guidebook and accompanying contributions is to provide an overview of Mount Hood, including its chief geologic processes, magmatic system, eruptive history, local tectonics, and hazards, by visiting a variety of readily accessible localities. We also describe coeval, largely monogenetic, volcanoes in the region. Accompanying the field-trip guidebook are separately authored contributions that discuss in detail the Mount Hood magmatic system and its products and behavior (Kent and Koleszar, this volume); Mount Hood earthquakes and their relation to regional tectonics and the volcanic system (Thelen and Moran, this volume); and young surface faults cutting the broader Mount Hood area whose extent has come to light after acquisition of regional light detection and ranging coverage (Madin and others, this volume). The trip makes an approximately 175-mile (280-kilometer) clockwise loop around Mount Hood, starting and ending in Portland. The route heads east on Interstate 84 through the Columbia River Gorge National Scenic Area. The guidebook points out only a few conspicuous features of note in the gorge, but many other guides to the gorge are available. The route continues south on the Mount Hood National Scenic Byway on Oregon Route 35 following Hood River, and returns to Portland on U.S. Highway 26 following Sandy River. The route traverses rocks as old as the early Miocene Eagle Creek Formation and overlying Columbia River Basalt Group of middle Miocene age, but chiefly lava flows and clastic products of arc volcanism of late Miocene to Holocene age.

Oregon

PFAS mixture composition and internal exposure profiles shape biological responses under field-realistic exposure

Per- and polyfluoroalkyl substances (PFAS) occur as complex mixtures, yet mixture-dependent biological effects under environmentally realistic exposure conditions remain poorly understood. We conducted multiyear (2018, 2019, 2021) continuous-flow, field-based exposures of male fathead minnows ( Pimephales promelas ) using a low-PFAS reference well (REF; sum of measured PFAS (∑PFAS) 0.1–0.2 μg L –1 ) and PFAS-contaminated groundwater from a fire-training area (FTA) at Joint Base Cape Cod, Massachusetts. Dilution treatments enabled separation of concentration and mixture effects. Groundwater from well FTA1 was perfluorooctanesulfonate (PFOS) dominated (∑PFAS 10–31 μg L –1 ), whereas groundwater from well FTA2 had higher concentrations and was enriched in perfluorooctanoate (PFOA) and diverse precursors (∑PFAS ∼ 80 μg L –1 ). Despite comparable plasma ∑PFAS and PFOS in FTA1–100% and FTA2–50% on day-7, cumulative mortality reached approximately 35% in FTA2–50% and 17% in FTA2–100%, and secondary sex trait expression was reduced by approximately 65–80% relative to REF, whereas sperm motility effects were mixture- and time-dependent. Plasma PFAS profiles were dominated by perfluorohexanesulfonate (PFHxS), PFOS, and sulfonamide precursors. Liver transcriptomics from REF-acclimated fish revealed robust disruption of metabolic, mitochondrial, and endocrine pathways that link PFAS mixture chemistry and internal exposure profiles to organismal outcomes, and testis transcriptomics provided complementary insight into reproductive impairment. These results indicate that PFAS mixture composition and internal exposure profiles, including precursor-associated differences, are important determinants of ecotoxicological outcomes under field-realistic conditions.

Massachusetts

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Dendroseismological investigation of redwood trees along the North Coast section of the San Andreas Fault

Sequoia sempervirens (coast redwood) tree rings have the potential to annually resolve late-Holocene earthquakes on the northern San Andreas Fault based on direct (e.g., physical damage) and indirect (e.g., co-seismic environmental change) impacts, but scarcity of suitable samples and challenges crossdating this long-lived species have limited progress. More precise dating of the pre-1906 (penultimate) earthquake can improve hazard assessment and understanding of rupture segmentation. We target old trees (maximum >815 yr) along the North Coast section of the fault (increment cores via rope-climbing, 11 living trees; plunge cuts, 23 stumps) and employ complementary disturbance detection methods including radial-growth averaging (tree- and series-level), cataloging anatomical indicators (e.g., traumatic resin ducts, TRD), and dating structural components (e.g., reiterated trunks, leans). Multi-centennial ring-width chronologies at Fort Ross (1569−2023) and Gualala (1397−2023) promote continued study with incomplete crossdating limiting utilization of some series. Growth pulses (reductions, releases) and TRD dispersed across the record reflect dynamic environments that obfuscate detection of earthquake signals. The 1906 earthquake did not leave strong signatures on most trees, and when it did, within-tree response varied from normal presentation to discoloration, TRD, and missing rings. Synchrony of indicators at both locations identified 1678−1680 (6 of 15 trees) and 1698−1700 (8 of 16 trees) as the strongest disturbances among dated rings in the time range of the penultimate earthquake, peaking at 1698 (15.7 % of possible growth and anatomical indicators), but the triggering mechanisms for these events are unknown.

California

“Leaky weirs” capture alluvial deposition and enhance seasonal mountain-front recharge in dryland streams

“Leaky weirs” are rock structures installed in dryland streams, which are anchored into exposed bedrock, loosely cemented, and designed to allow water to slowly pass through. They are being tested at a ranch in southeastern Arizona, USA, to restore and conserve the historic range and desert wetlands. Data are collected to assess how leaky weirs impact surface water, subsurface water, and groundwater recharge—including stream discharge, timing, and depth of infiltration, and groundwater elevations. Three adjacent watersheds, two with outlets just below leaky weirs and one with leaky weirs farther upstream, were instrumented with water-level loggers, wildlife cameras, and crest stage instruments with temperature sensors in the soil. As most groundwater recharge is assumed to be focused along the mountain fronts in this region, mountain-block recharge is also evaluated to differentiate between the two using isotope analyses. Finally, a single, late-season flood event is scrutinized to consider the leaky weir effect on all monitored components in the water budget. Results indicated groundwater flow is primarily from the mountains to the east via older, regional mountain-block recharge. However, the development of shallow alluvial aquifers is supported by the leaky weirs, that slow flows, capture permeable sediments, and allow infiltration, thus enhancing mountain-front recharge. In turn, these new pockets of water help support the restoration of historic wetlands. Sediment accumulates where leaky weirs are installed, reducing flashy peak flows, and resulting in a series of infiltration ponds along the channel that support vegetation during growing seasons and recharge the shallow aquifer during non-growing seasons.

Arizona

High resolution identification and quantification of diffuse deep groundwater discharge in mountain rivers using continuous boat-mounted helium measurements

Discharge of deeply sourced groundwater to streams is difficult to locate and quantify, particularly where both discrete and diffuse discharge points exist, but diffuse discharge is one of the primary controls on solute budgets in mountainous watersheds. The noble gas helium is a unique identifier of deep groundwater discharge because groundwater with long residence times is commonly enriched in helium. In this study, a portable mass spectrometer was used to measure longitudinal variation in dissolved helium concentrations in two mountainous rivers at high spatial resolution not feasible with traditional sampling techniques. Helium profiles were then simulated using a mass-balance model to quantify longitudinal variation in groundwater discharge to the receiving rivers. Results indicate helium concentrations were enriched by multiple orders of magnitude above atmospheric equilibrium in both rivers and that this persisted for up to 18 km below observed pulse inputs in the Colorado River. Helium mass-balance models match observed longitudinal patterns with the exception of sharp initial increases in helium observed in the rivers. Increased longitudinal groundwater discharge rates correspond to mapped geologic structures in both watersheds that likely transport deep geothermal water. Models show variable sensitivity to spatial assignment of input variables representing the groundwater source, illustrating the importance of collecting data from discrete groundwater discharges where possible. The methodology shows promise for field experiments designed to assess air–water exchange rates and to quantify total groundwater discharge from a combination of discrete and diffuse sources.

Colorado, Utah

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

Nodal seismic deployment on Mauna Loa volcano, Hawaii: Dataset and preliminary insights

Mauna Loa is the largest active volcano on Earth, comprising ∼51% of the Island of Hawai‘i’s landmass and posing significant risks to the island’s communities, infrastructure, and natural environment. Historical eruptions have produced lava flows that have reached the ocean in as little as 3 hr. The timing and location of such lava flows in the past 200 yr underscore how critical determination of the location and geometry of magma storage and structure is for volcanic hazard assessment and eruption forecasting. Now, after nearly 38 yr of volcanic quiescence, Mauna Loa has erupted again. On 27 November 2022, fissures initiated within the summit caldera and then migrated to the northeast rift zone, where they generated a large lava flow that threatened a major highway. To improve our understanding of the geometry of this magma system, we deployed a temporary nodal array on Mauna Loa in the summer of 2024. This increased our seismic coverage sufficiently to image this magmatic system. This nodal array consists of 33 seismometers distributed on and around the volcano and was deployed for over three months to record seismic signals. The primary objective of this project is to resolve the high‐resolution seismic velocity structure and characterize seismic features associated with magma storage and ascent pathways. In this article, we present an overview of the deployment, evaluate the quality of the data, and show example recordings to evaluate the suitability of the data set for future seismic investigations, including earthquake relocation, seismic tomography, and receiver function analysis. Comparisons with nearby permanent broadband and short‐period seismic stations demonstrate that the nodal array recorded high‐quality waveforms, making it a valuable resource for constraining the magmatic system beneath Mauna Loa at multiple scales.

Hawaii

Multi-lithofacies alluvial characterization via airborne electromagnetic-borehole fusion using ordinary interval kriging and geologic constraints

Airborne electromagnetic (AEM) survey provides extensive spatial coverage and detailed resolution at the near surface and can be used to develop hydrogeological models. However, utilization of AEM data is not straightforward because AEM resistivity is an indirect measurement for inferring sediment types. This study develops an ordinary interval kriging (OIK) algorithm and a resistivity-to-multi-lithofacies (R2ML) data fusion workflow for multi-lithofacies alluvial characterization. OIK utilizes irregular interval data to construct three-dimensional (3D) resistivity fields from one-dimensional inverted AEM resistivity models. The R2ML workflow maps the resistivity field generated from OIK into a multi-facies lithological model, incorporating geologic constraints derived from well logs and geological observations. The numerical and real-world cases demonstrate that OIK is computationally efficient, accounts for 3D anisotropy, and minimizes the smoothing effect, thereby preserving resistivity contrasts and reducing interpolation uncertainty. The methodology is applied to lithologic characterization of the Mississippi River Valley alluvial aquifer (MRVA) in the Shellmound area, Mississippi, U.S. A frequency-domain AEM survey was conducted to support groundwater studies for the managed aquifer recharge (MAR) to the MRVA. The resulting lithological model, including four types of lithofacies—clay, very fine sand, fine-medium sands, and graveliferous sands, illustrates the geomorphological processes of the MRVA and implies potential MAR. The alignment between the lithological model and existing geological and hydrogeological investigations demonstrates that OIK and R2ML workflow effectively capture the subsurface architecture of the MRVA. The methods have broad applicability for characterizing alluvial aquifers through AEM-borehole data fusion, supporting sustainable groundwater management.

Mississippi

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington

Exploring the dynamic interactions between the Southern San Andreas Fault and a normal fault under the Salton Sea

We investigate the dynamic interactions between the Southern San Andreas Fault (SSAF) and a proximal normal fault (NF) beneath the Salton Sea in southern California. The NF, positioned near the SSAF terminus at Bombay Beach, exhibits 11–15 displacement events across 14 stratigraphic sequences, with a range of 0.2–1.4 m of vertical offset since ∼2–3 ka. Notably, four of these events may align temporally with SSAF earthquakes, raising questions about the possible interplay between the two faults. Utilizing dynamic rupture models, we analyze the coseismic interactions between the SSAF and NF, addressing under what conditions the SSAF induces slip on the NF. Our findings reveal that a suite of SSAF ruptures, particularly those propagating from north to south, can trigger slip on the normal fault and replicate observed vertical offsets. If the SSAF extends beneath the Salton Sea, earthquakes originating south of the NF intersection are less likely to trigger normal fault slip, although we cannot exclude this possibility. Some SSAF ruptures do not trigger discernible slip on the NF, rendering such events undetectable in the stratigraphic record. Our research contributes toward discussions regarding the seismic hazard in southern California, shedding light on the interplay between the SSAF and NF.

California

Legacy of the fumigant 1,2-dibromo-3-chloropropane (DBCP) in California groundwater

The fumigant pesticide 1,2-dibromo-3-chloropropane (DBCP) was widely used in California agriculture during the 1960s and 1970s before being banned in 1979. Despite this ban, DBCP continues to contaminate groundwater due to its persistence and mobility. This study evaluates the distribution, historical trends, and projected persistence of DBCP in California using data from over 13,000 public supply wells and additional domestic, irrigation, and observation wells (1980-2022). Since 2010, DBCP has been detected in 9% of public supply wells statewide, with higher frequencies in the San Joaquin Valley (21%) and upper Santa Ana River watershed (13%), where DBCP use was most prevalent. Approximately 70% of wells had decreasing concentration trends, whereas increases were more common in deeper wells, indicating downward vertical migration of the DBCP front. Groundwater age estimates show that recharge timing aligns with the 1960s–1970s loading period, enabling reconstruction of peak inputs and providing a basis for age based modeling. To estimate future persistence, we applied a one dimensional advection–dispersion model that simulates long term declines in peak concentrations based on groundwater age, historical loading, and a 38 year degradation half life. Model projections suggest that concentrations above the maximum contaminant level may persist in a declining number of wells until approximately 2080 (range: 2048–2109), with longer persistence in the San Joaquin Valley. The simplified modeling framework, based on age distributions typical of wells capturing peak concentrations, can provide practical regional scale assessment of non-point source contaminants where long-term monitoring exists. This study highlights how the legacy of DBCP contamination will likely affect California's groundwater resources throughout the 21st century.

California

Potential impacts of groundwater pumping on stream temperature are greatest in streams with substantial cold groundwater inflows

Groundwater pumping-induced reductions in streamflow (known as ‘streamflow depletion’) have been documented worldwide, but potential impacts of streamflow depletion on stream temperature are not well understood. Here, we use two types of models to identify potential impacts of pumping on stream temperature across the conterminous United States (CONUS) to determine which aspects of a stream's annual thermograph (thermal signatures) can be used to monitor and manage streamflow depletion impacts on stream temperature. We used long-term streamflow and stream temperature data from 30 streamgages across CONUS and surrogate models of streamflow depletion to analyse potential stream temperature impacts at each site. We compared two different stream temperature modelling approaches: (i) a process-based energy balance model and (ii) statistical regression models based on air temperature and stream discharge. We calculated a suite of thermal signatures under depleted and non-depleted conditions for each stream and found that maximum annual 7-day temperature and annual temperature range are potentially the most sensitive to streamflow depletion, with potential changes of at least 2°C at > 70% of the sites when using the process-based model. We also found that the regression-based models predicted much less sensitivity of stream temperature to streamflow depletion than the process-based model. This work provides an initial evaluation and sensitivity analysis of the potential impacts of streamflow depletion on stream temperature. We demonstrate that stream temperature may be most sensitive to pumping in streams with a high proportion of flow sourced from relatively cold groundwater inputs, and that regression-based stream temperature models may underpredict stream temperature changes caused by streamflow depletion.

conterminous United States

Critical review of mercury methylation and methylmercury demethylation rate constants in aquatic sediments for biogeochemical modeling

Mercury is a toxin that causes neurological impairments in adults, is particularly harmful for fetuses and children, and is deadly in severe cases, making it a worldwide health concern. Methylmercury (MeHg) is the environmentally relevant form of mercury (Hg) because it biomagnifies along the food chain. Methylmercury is mainly produced in aquatic sediments via methylation of inorganic Hg (Hg(II)) and transformed back via demethylation. Because transformation rates determine MeHg concentrations, quantification of methylation and demethylation rates is needed to inform management of MeHg. Published rate constants for Hg(II) methylation ( 𝑘 𝑚 ) and MeHg demethylation ( 𝑘 𝑑 ) vary greatly, stemming partly from differences in experimental methods. We conducted a comprehensive review of rate laws, evaluated published rate constants, and performed biogeochemical simulations to assess variability in reported 𝑘 𝑚 and 𝑘 𝑑 . Based on selected studies employing the same pseudo-first-order rate law and similar experimental methods, we found that 𝑘 𝑚 = 0.04 ± 0.03 d −1 is a reasonable range for wetland sediments. Over a number of environments, maximum 𝑘 𝑑 was smaller at sites without Hg source ( 𝑘 𝑑 = 0.5 d −1 ) than at sites with identified Hg source ( 𝑘 𝑑 = 1.8 d −1 ). Larger variability and higher uncertainty in 𝑘 𝑑 compared to 𝑘 𝑚 highlight the need for more research on MeHg demethylation rates. This critical review: (a) aids the design of future experimental studies of 𝑘 𝑚 and 𝑘 𝑑 ; (b) provides guidance for comparing rate constants from different studies; (c) presents a biogeochemical reaction model to assess rate constants; and (d) informs selection of 𝑘 𝑚 and 𝑘 𝑑 values from the literature for use in model simulations.

Critical Reviews in Environmental Science and Tech