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At least 343 records · Page 19Linked to original sources

Equilibrium shoreline response of a high wave energy beach

Four years of beach elevation surveys at Ocean Beach, San Francisco, California, are used to extend an existing equilibrium shoreline change model, previously calibrated with fine sand and moderate energy waves, to medium sand and higher-energy waves. The shoreline, characterized as the cross-shore location of the mean high water contour, varied seasonally by between 30 and 60 m, depending on the alongshore location. The equilibrium shoreline change model relates the rate of horizontal shoreline displacement to the hourly wave energy E and the wave energy disequilibrium, the difference between E and the equilibrium wave energy that would cause no change in the present shoreline location. Values for the model shoreline response coefficients are tuned to fit the observations in 500 m alongshore segments and averaged over segments where the model has good skill and the estimated effects of neglected alongshore sediment transport are relatively small. Using these representative response coefficients for 0.3 mm sand from Ocean Beach and driving the model with much lower-energy winter waves observed at San Onofre Beach (also 0.3 mm sand) in southern California, qualitatively reproduces the small seasonal shoreline fluctuations at San Onofre. This consistency suggests that the shoreline model response coefficients depend on grain size and may be constant, and thus transportable, between sites with similar grain size and different wave climates. The calibrated model response coefficients predict that for equal fluctuations in wave energy, changes in shoreline location on a medium-grained (0.3 mm) beach are much smaller than on a previously studied fine-grained (0.2 mm) beach. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

InSAR observations of aseismic slip associated with an earthquake swarm in the Columbia River flood basalts

In 2009 a swarm of small shallow earthquakes occurred within the basalt flows of the Columbia River Basalt Group (CRBG). The swarm occurred within a dense seismic network in the U.S. Department of Energys Hanford Site. Data from the seismic network along with interferometric synthetic aperture radar (InSAR) data from the European Space Agencys (ESA) ENVISAT satellite provide insight into the nature of the swarm. By modeling the InSAR deformation data we constructed a model that consists of a shallow thrust fault and a near horizontal fault. We suggest that the near horizontal lying fault is a bedding-plane fault located between basalt flows. The geodetic moment of the modeled fault system is about eight times the cumulative seismic moment of the swarm. Precise location estimates of the swarm earthquakes indicate that the area of highest slip on the thrust fault, ???70mm of slip less than ???0.5km depth, was not located within the swarm cluster. Most of the slip on the faults appears to have progressed aseismically and we suggest that interbed sediments play a central role in the slip process. Copyright 2011 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Bora event variability and the role of air-sea feedback

A two-way interacting high resolution numerical simulation of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM) and Coupled Ocean/ Atmosphere Mesoscale Prediction System (COAMPS??) was conducted to improve forecast momentum and heat flux fields, and to evaluate surface flux field differences for two consecutive bora events during February 2003. (COAMPS?? is a registered trademark of the Naval Research Laboratory.) The strength, mean positions and extensions of the bora jets, and the atmospheric conditions driving them varied considerably between the two events. Bora 1 had 62% stronger heat flux and 51% larger momentum flux than bora 2. The latter displayed much greater diurnal variability characterized by inertial oscillations and the early morning strengthening of a west Adriatic barrier jet, beneath which a stronger west Adriatic ocean current developed. Elsewhere, surface ocean current differences between the two events were directly related to differences in wind stress curl generated by the position and strength of the individual bora jets. The mean heat flux bias was reduced by 72%, and heat flux RMSE reduced by 30% on average at four instrumented over-water sites in the two-way coupled simulation relative to the uncoupled control. Largest reductions in wind stress were found in the bora jets, while the biggest reductions in heat flux were found along the north and west coasts of the Adriatic. In bora 2, SST gradients impacted the wind stress curl along the north and west coasts, and in bora 1 wind stress curl was sensitive to the Istrian front position and strength. The two-way coupled simulation produced diminished surface current speeds of ???12% over the northern Adriatic during both bora compared with a one-way coupled simulation. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Sediment dispersal in the northwestern Adriatic Sea

Sediment dispersal in the Adriatic Sea was evaluated using coupled three-dimensional circulation and sediment transport models, representing conditions from autumn 2002 through spring 2003. The calculations accounted for fluvial sources, resuspension by waves and currents, and suspended transport. Sediment fluxes peaked during southwestward Bora wind conditions that produced energetic waves and strengthened the Western Adriatic Coastal Current. Transport along the western Adriatic continental shelf was nearly always to the south, except during brief periods when northward Sirocco winds reduced the coastal current. Much of the modeled fluvial sediment deposition was near river mouths, such as the Po subaqueous delta. Nearly all Po sediment remained in the northern Adriatic. Material from rivers that drain the Apennine Mountains traveled farther before deposition than Po sediment, because it was modeled with a lower settling velocity. Fluvial sediment delivered to areas with high average bed shear stress was more highly dispersed than material delivered to more quiescent areas. Modeled depositional patterns were similar to observed patterns that have developed over longer timescales. Specifically, modeled Po sediment accumulation was thickest near the river mouth with a very thin deposit extending to the northeast, consistent with patterns of modern sediment texture in the northern Adriatic. Sediment resuspended from the bed and delivered by Apennine Rivers was preferentially deposited on the northern side of the Gargano Peninsula, in the location of thick Holocene accumulation. Deposition here was highest during Bora winds when convergences in current velocities and off-shelf flux enhanced delivery of material to the midshelf. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Quantity-activity relationship of denitrifying bacteria and environmental scaling in streams of a forested watershed

The spatial variability of subreach denitrification rates in streams was evaluated with respect to controlling environmental conditions, molecular examination of denitrifying bacteria, and dimensional analysis. Denitrification activities ranged from 0 and 800 ng-N gsed-1 d-1 with large variations observed within short distances (<50 m) along stream reaches. A log-normal probability distribution described the range in denitrification activities and was used to define low (16% of the probability distributibn), medium (68%), and high (16%) denitrification potential groups. Denitrifying bacteria were quantified using a competitive polymerase chain reaction (cPCR) technique that amplified the nirK gene that encodes for nitrite reductase. Results showed a range of nirK quantities from 103 to 107 gene-copy-number gsed.-1 A nonparametric statistical test showed no significant difference in nirK quantifies among stream reaches, but revealed that samples with a high denitrification potential had significantly higher nirK quantities. Denitrification activity was positively correlated with nirK quantities with scatter in the data that can be attributed to varying environmental conditions along stream reaches. Dimensional analysis was used to evaluate denitrification activities according to environmental variables that describe fluid-flow properties, nitrate and organic material quantities, and dissolved oxygen flux. Buckingham's pi theorem was used to generate dimensionless groupings and field data were used to determine scaling parameters. The resulting expressions between dimensionless NO3- flux and dimensionless groupings of environmental variables showed consistent scaling, which indicates that the subreach variability in denitrification rates can be predicted by the controlling physical, chemical, and microbiological conditions. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Biogeochemical legacy of prescribed fire in a giant sequoia - Mixed conifer forest: A 16-year record of watershed balances

The effects of prescription burning on watershed balances of major ions in mixed conifer forest were examined in a 16-year paired catchment study in Sequoia National Park, California. The objective was to determine whether fire-related changes in watershed balances persist as long as estimated low-end natural fire-return intervals (???10 years), and whether cumulative net export caused by fire could deplete nutrient stocks between successive fires. Inputs (wet + dry deposition) and outputs (stream export) of N, S, Cl-, HCO3-, Ca2+, Mg2+, Na+, K+, H+, and SiO2 were measured for 7 years preceding, and 9 years following, a prescribed burn of one of the catchments. After fire, runoff coefficients increased by 7% (in dry years) to 35% (in wet years). Inorganic N was elevated in stream water for 3 years after fire. Increased export of water, SO42-, Cl-,SiO2, and base cations continued through the end of the study. Pools and processes attributed to fire led to the cumulative loss, per hectare, of 1.2 kg N, 16 kg S, 25 kg Cl-, 130 kg Ca2+, 19 kg Mg2+, 71 kg Na+, 29 kg K+ and 192 kg Si, above that predicted by prefire regression equations relating export in the paired catchments. This additional export equaled <1% of the N, up to one-third of the Ca and Mg, and up to three-fourths of the K, contained in the forest floor prior to combustion. Changes in watershed balances indicated that low-end natural fire-return intervals may prevent complete reaccumulation of several elements between fires. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Variational analysis of drifter positions and model outputs for the reconstruction of surface currents in the central Adriatic during fall 2002

In this paper we present an application of a variational method for the reconstruction of the velocity field in a coastal flow in the central Adriatic Sea, using in situ data from surface drifters and outputs from the ROMS circulation model. The variational approach, previously developed and tested for mesoscale open ocean flows, has been improved and adapted to account for inhomogeneities on boundary current dynamics over complex bathymetry and coastline and for weak Lagrangian persistence in coastal flows. The velocity reconstruction is performed using nine drifter trajectories over 45 d, and a hierarchy of indirect tests is introduced to evaluate the results as the real ocean state is not known. For internal consistency and impact of the analysis, three diagnostics characterizing the particle prediction and transport, in terms of residence times in various zones and export rates from the boundary current toward the interior, show that the reconstruction is quite effective. A qualitative comparison with sea color data from the MODIS satellite images shows that the reconstruction significantly improves the description of the boundary current with respect to the ROMS model first guess, capturing its main features and its exchanges with the interior when sampled by the drifters. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Compositional trends in aeolian dust along a transect across the southwestern United States

Aeolian dust strongly influences ecology and landscape geochemistry over large areas that span several desert ecosystems of the southwestern United States. This study evaluates spatial and temporal variations and trends of the physical and chemical properties of dust in the southwestern United States by examining dust deposited in natural depressions on high isolated surfaces along a transect from the Mojave Desert to the central Colorado Plateau. Aeolian dust is recognized in these depressions on the basis of textural, chemical, isotopic, and mineralogical characteristics and comparisons of those characteristics to the underlying bedrock units. Spatial and temporal trends suggest that although local dust sources are important to the accumulated material in these depressions, Mojave Desert dust sources may also contribute. Depth trends in the depressions suggest that Mojave sources may have contributed more dust to the Colorado Plateau recently than in the past. These interpretations point to the important roles of far-traveled aeolian dust for landscape geochemistry and imply future changes to soil geochemistry under changing conditions in far-distant dust source areas. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

Sediment and nutrient delivery from thermokarst features in the foothills of the North Slope, Alaska: Potential impacts on headwater stream ecosystems

Permafrost is a defining characteristic of the Arctic environment. However, climate warming is thawing permafrost in many areas leading to failures in soil structure called thermokarst. An extensive survey of a 600 km2 area in and around the Toolik Lake Natural Research Area (TLNRA) revealed at least 34 thermokarst features, two thirds of which were new since ???1980 when a high resolution aerial survey of the area was done. Most of these thermokarst features were associated with headwater streams or lakes. We have measured significantly increased sediment and nutrient loading from thermokarst features to streams in two well-studied locations near the TLNRA. One small thermokarst gully that formed in 2003 on the Toolik River in a 0.9 km2 subcatchment delivered more sediment to the river than is normally delivered in 18 years from 132 km2 in the adjacent upper Kuparuk River basin (a long-term monitoring reference site). Ammonium, nitrate, and phosphate concentrations downstream from a thermokarst feature on Imnavait Creek increased significantly compared to upstream reference concentrations and the increased concentrations persisted over the period of sampling (1999-2005). The downstream concentrations were similar to those we have used in a long-term experimental manipulation of the Kuparuk River and that have significantly altered the structure and function of that river. A subsampling of other thermokarst features from the extensive regional survey showed that concentrations of ammonium, nitrate, and phosphate were always higher downstream of the thermokarst features. Our previous research has shown that even minor increases in nutrient loading stimulate primary and secondary production. However, increased sediment loading could interfere with benthic communities and change the responses to increased nutrient delivery. Although the terrestrial area impacted by thermokarsts is limited, the aquatic habitat altered by these failures can be extensive. If warming in the Arctic foothills accelerates thermokarst formation, there may be substantial and wide-spread impacts on arctic stream ecosystems that are currently poorly understood. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Changes in the soil C cycle at the arid-hyperarid transition in the Atacama Desert

We examined soil organic C (OC) turnover and transport across the rainfall transition from a biotic, arid site to a largely abiotic, hyperarid site. With this transition, OC concentrations decrease, and C cycling slows precipitously, both in surface horizons and below ground. The concentration and isotopic character of soil OC across this transition reflect decreasing rates of inputs, decomposition, and downward transport. OC concentrations in the arid soil increase slightly with depth in the upper meter, but are generally low and variable (???0.05%; total inventory of 1.82 kg m-2); OC-??14C values decrease from modern (+7???) to very 14C-depleted (-966???) with depth; and OC-??13C values are variable (-23.7??? to -14.1???). Using a transport model, we show that these trends reflect relatively rapid cycling in the upper few centimeters, and spatially variable preservation of belowground OC from root inputs, possibly during a previous, wetter climate supporting higher soil OC concentrations. In the driest soil, the OC inventory is the lowest among the sites (0.19 kg m-2), and radiocarbon values are 14C-depleted (-365??? to -696???) but show no trend with depth, indicating belowground OC inputs and long OC residence times throughout the upper meter (104 y). A distinct depth trend in ??13C values and OC/ON values within the upper 40 cm at the driest site may reflect photochemical alteration of organic matter at the soil surface, combined with limited subsurface decomposition and downward transport. We argue that while root inputs are preserved at the wetter sites, C cycling in the most hyperarid soil occurs through infrequent, rapid dissolved transport of highly photodegraded organic matter during rare rain events, each followed by a pulse of decomposition and subsequent prolonged drought. These belowground inputs are likely a primary control on the character, activity, and depth distribution of small microbial populations. While the lack of water is the dominant control on C cycling, very low C/N ratios of organic matter suggest that when rainfall occurs, hyperarid soils are effectively C limited. The preservation of fossil root fragments in the sediment beneath the driest soil indicates that wetter climate conditions preceded formation of this soil, and that vadose zone microbial activity has been extremely limited for the past 2 My. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Sulfur species behavior in soil organic matter during decomposition

Soil organic matter (SOM) is a primary re??servoir of terrestrial sulfur (S), but its role in the global S cycle remains poorly understood. We examine S speciation by X-ray absorption near-edge structure (XANES) spectroscopy to describe S species behavior during SOM decomposition. Sulfur species in SOM were best represented by organic sulfide, sulfoxide, sulfonate, and sulfate. The highest fraction of S in litter was organic sulfide, but as decomposition progressed, relative fractions of sulfonate and sulfate generally increased. Over 6-month laboratory incubations, organic sulfide was most reactive, suggesting that a fraction of this species was associated with a highly labile pool of SOM. During humification, relative concentrations of sulfoxide consistently decreased, demonstrating the importance of sulfoxide as a reactive S phase in soil. Sulfonate fractional abundance increased during humification irrespective of litter type, illustrating its relative stability in soils. The proportion of S species did not differ systematically by litter type, but organic sulfide became less abundant in conifer SOM during decomposition, while sulfate fractional abundance increased. Conversely, deciduous SOM exhibited lesser or nonexistent shifts in organic sulfide and sulfate fractions during decomposition, possibly suggesting that S reactivity in deciduous litter is coupled to rapid C mineralization and independent of S speciation. All trends were consistent in soils across study sites. We conclude that S reactivity is related to spqciation in SOM, particularly in conifer forests, and S species fractions in SOM change, during decomposition. Our data highlight the importance of intermediate valence species (sulfoxide and sulfonate) in the pedochemical cycling of organic bound S. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Hydrologic support of carbon dioxide flux revealed by whole-lake carbon budgets

Freshwater lakes are an important component of the global carbon cycle through both organic carbon (OC) sequestration and carbon dioxide (CO 2 ) emission. Most lakes have a net annual loss of CO 2 to the atmosphere and substantial current evidence suggests that biologic mineralization of allochthonous OC maintains this flux. Because net CO 2 flux to the atmosphere implies net mineralization of OC within the lake ecosystem, it is also commonly assumed that net annual CO 2 emission indicates negative net ecosystem production (NEP). We explored the relationship between atmospheric CO 2 emission and NEP in two lakes known to have contrasting hydrologie characteristics and net CO 2 emission. We calculated NEP for calendar year 2004 using whole-lake OC and inorganic carbon (IC) budgets, NEP oc and NEP IC , respectively, and compared the resulting values to measured annual CO 2 flux from the lakes. In both lakes, NEP Ic and NEP Ic were positive, indicating net autotrophy. Therefore CO 2 emission from these lakes was apparently not supported by mineralization of allochthonous organic material. In both lakes, hydrologie CO 2 inputs, as well as CO 2 evolved from netcalcite precipitation, could account for the net CO 2 emission. NEP calculated from diel CO 2 measurements was also affected by hydrologie inputs of CO 2 . These results indicate that CO 2 emission and positive NEP may coincide in lakes, especially in carbonate terrain, and that all potential geologic, biogeochemical, and hydrologie sources of CO 2 need to be accounted for when using CO 2 concentrations to infer lake NEP. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Aeolian dunes as ground truth for atmospheric modeling on Mars

Martian aeolian dunes preserve a record of atmosphere/surface interaction on a variety of scales, serving as ground truth for both Global Climate Models (GCMs) and mesoscale climate models, such as the Mars Regional Atmospheric Modeling System (MRAMS). We hypothesize that the location of dune fields, expressed globally by geographic distribution and locally by dune centroid azimuth (DCA), may record the long-term integration of atmospheric activity across a broad area, preserving GCM-scale atmospheric trends. In contrast, individual dune morphology, as expressed in slipface orientation (SF), may be more sensitive to localized variations in circulation, preserving topographically controlled mesoscale trends. We test this hypothesis by comparing the geographic distribution, DCA, and SF of dunes with output from the Ames Mars GCM and, at a local study site, with output from MRAMS. When compared to the GCM: 1) dunes generally lie adjacent to areas with strongest winds, 2) DCA agrees fairly well with GCM modeled wind directions in smooth-floored craters, and 3) SF does not agree well with GCM modeled wind directions. When compared to MRAMS modeled winds at our study site: 1) DCA generally coincides with the part of the crater where modeled mean winds are weak, and 2) SFs are consistent with some weak, topographically influenced modeled winds. We conclude that: 1) geographic distribution may be valuable as ground truth for GCMs, 2) DCA may be useful as ground truth for both GCM and mesoscale models, and 3) SF may be useful as ground truth for mesoscale models. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Crustal deformation measurements in Guerrero, Mexico

GPS measurements of crustal deformation in Guerrero, southern Mexico, include surveys collected between 1992 and 2001 as well as continuous GPS measurements at a few sites. These geodetic observations are used to calculate interseismic deformation rates and assess the presence and possible location of transient deformation during the period encompassing 1992.25 to 2001.75. The data are used to examine transient deformation in 1998 previously described from data at a single site by Lowry et al. [2001]. Survey measurements and continuous data from a site near Popocate??petl volcano confirm the 1998 transient, and survey data also suggest another transient occurred following the 14 September 1995 (Mw = 7.3) Copala earthquake. All of the available GPS position estimates have been inverted for a combined model of slip during each event plus the steady state slip on the plate interface. Modeling of the steady state deformation rates confirms that the Guerrero seismic gap is partially frictionally locked at depths shallower than about 25 km and accumulating strain that may eventually be released in a great earthquake. The data also suggest that there is frictional coupling to much greater (>40 km) depths, which releases more frequently in aseismic slip events. The locations and sizes of the transient events are only partially constrained by the available data. However, the transient models which best fit the GPS coordinate time series suggest that aseismic slip was centered downdip of the seismogenic portion of the plate-bounding thrust in both events, and the moment release had equivalent magnitudes Mw = 7.1 + 1.3/-1.0 in 1995-1996 and 7.1 + 0.4/-0.1 in 1998. Copyright 2004 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Hydrogeologic controls on nitrate transport in a small agricultural catchment, Iowa

Effects of subsurface deposits on nitrate loss in stream riparian zones are recognized, but little attention has been focused on similar processes occurring in upland agricultural settings. In this paper, we evaluated hydrogeologic controls on nitrate transport processes occurring in a small 7.6 ha Iowa catchment. Subsurface deposits in the catchment consisted of upland areas of loess overlying weathered pre-Illinoian till, drained by two ephemeral drainageways that consisted of Holocene-age silty and organic rich alluvium. Water tables in upland areas fluctuated more than 4 m per year compared to less than 0.3 m in the drainageway. Water quality patterns showed a distinct spatial pattern, with groundwater in the drainageways having lower nitrate concentrations (<0.5 mg L-1 compared to upland areas (>10 mg L-1) as wells as lower pH, dissolved oxygen and redox, and higher ammonium and dissolved organic carbon levels. Several lines of evidence suggested that conditions are conducive for denitrification of groundwater flowing from uplands through the drainageways. Field-measured nitrate decay rates in the drainageways (???0.02 day-1) were consistent with other laboratory studies and regional patterns. Results from MODFLOW and MT3DMS simulations indicated that soils in the ephemeral drainageways could process all upland groundwater nitrate flowing through them. However, model-simulated tile drainage increased both water flux and nitrate loss from the upland catchment. Study results suggest that ephemeral drainageways can provide a natural nitrate treatment system in our upland glaciated catchments, offering management opportunities to reduce nitrate delivery to streams. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Can lava flow like water? Assessing applications of critical flow theory to channelized basaltic lava flows

Flowing lava and water have dramatically different physical properties but can form similar hydraulic structures, including undular hydraulic jumps, or standing wave trains. In water flows, undular hydraulic jumps are evidence of critical flow (Froude number ∼1) and open-channel hydraulic theory provides a powerful tool for estimating flow depth and velocity. Monitoring these parameters in an active lava channel is inherently challenging, but essential for calculating lava discharge (effusion rate), a primary control on the rate of flow front advance and ultimate flow runout distance. We analyze undular hydraulic jumps in both water and lava flows to assess the conditions under which they form and, by extension, the potential use of critical flow theory to estimate, in real time, lava flow velocity, depth, and discharge. Experimental data for water flows show that these structures mark the transition from supercritical to subcritical flow. Undular hydraulic jumps in the near-vent lava channel of the 2018 lower East Rift Zone eruption of Kīlauea, Hawaiʻi also reflect critical flow conditions; their wavelengths scale with flow depth and velocity, consistent with hydraulic theory. Calculated lava effusion rates are similar to estimates made using more traditional approaches (Jeffreys', 1925, https://doi.org/10.1080/14786442508634662 , equation based on lava viscosity, density, and channel slope) and with lava volumes derived from topographic-change mapping. From this we conclude that critical flow phenomena show great potential to track flow dynamics and inform hazard assessment for a wide range of geophysical fluids.

Journal of Geophysical Research - Earth Surface↗

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: applications to the physics and chemistry of the lower mantle

The electronic structure of magnesiowustite is investigated using self-consistent field X α scattered wave (SCF- X α-SW) molecular orbital calculations on (FeO 6 ) 10− and (FeMg 12 O 14 ) 2− clusters. Calculated one-electron transition energies are used to interpret the optical spectrum of (Mg, Fe)O. The results are applied to the electrical and thermal conductivity of the lower mantle. The spin pairing of Fe 2+ and the effect of pressure on bonding in magnesiowustite, with some inferences regarding the incorporation of oxygen in the outer core, is also addressed. The approach used here appears to give a reliable description of the energy and pressure dependence of the spin-allowed 5 T 2 g → 5 E g ligand field transition and the spin-pairing transition of Fe 2+ in (Mg, Fe)O. However, the oxygen to metal charge transfer transitions in (Mg, Fe)O are not as reliably determined insofar as the p - d band gap varies with cluster size and the energies of the charge transfer states cannot be found without including configurational interaction. Nevertheless, it is argued that the charge transfer transitions that are intrinsic to (Fe, Mg)O are of a sufficiently high energy to be irrelevant to the electrical and thermal conductivity of the lower mantle. This is especially true if Fe 2+ adopts the low-spin configuration. The geophysically significant properties of (Fe, Mg)O probably result from defect Fe 3+ .

Journal of Geophysical Research↗

Implications of a magnetic model of the Long Valley caldera, California

A quantitative magnetic model of Long Valley, California, shows that the magnetic field above this caldera is dominated by intracaldera Bishop tuff, part of the ash flow tuff whose eruption precipitated the caldera collapse. We propose that about half of the 350 km 3 of intracaldera Bishop tuff, or that part beneath the resurgent dome, has been subjected to extensive hydrothermal alteration. The heat that produced this alteration is apparently associated with the residual magma chamber, and much of the formation may still be hot (>200°C). The magnetic minerals in the remaining intracaldera Bishop tuff have not been drastically altered, presumably because the tuff was not heated sufficiently. As a result, the tuff may not be very hot today. The model also reveals the existence of parts of two large precaldera mountains beneath the caldera fill. The resolving power attained in this investigation was possible because we were dealing with large, magnetically distinct lithologic units and a large amount of geological and geophysical data were available constraints to produce the solution.

California↗