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Data compilation of benthic invertebrates from tributary streams in Yampa and North Platte River Basins, northwestern Colorado

Benthic invertebrates were collected from Trout Creek, Fish Creek, and the Williams Fork (tributaries of the Yampa River in Routt and Moffat Counties), and Little Grizzly and Grizzly Creeks (tributaries of the North Platte River in Jackson County). Stream-sampling sites were upstream and downstream from potential, existing, or historical coal-mining areas. Field water-quality measurements of water temperature, specific conductance, pH, and dissolved oxygen were also made to aid in assessing stream water-quality conditions. The purpose of the study was to describe and quantify the benthic invertebrate communities in selected streams in coal-mining areas. Sampling was conducted on a near bimonthly basis throughout the growing season, beginning in April and May 1980, and continuing through September 1981. This report describes the methods of data collection and presents qualitative and quantitative results of benthic invertebrates and associated water-quality data. (USGS)

Open-File Report

Cost effectiveness of the stream-gaging program in Ohio

This report documents the results of the cost effectiveness of the stream-gaging program in Ohio. Data uses and funding sources were identified for 107 continuous stream gages currently being operated by the U.S. Geological Survey in Ohio with a budget of $682,000; this budget includes field work for other projects and excludes stations jointly operated with the Miami Conservancy District. No stream gage were identified as having insufficient reason to continue their operation; nor were any station identified as having uses specifically only for short-term studies. All 107 station should be maintained in the program for the foreseeable future. The average standard error of estimation of stream flow records is 29.2 percent at its present level of funding. A minimum budget of $679,000 is required to operate the 107-gage program; a budget less than this does no permit proper service and maintenance of the gages and recorders. At the minimum budget, the average standard error is 31.1 percent The maximum budget analyzed was $1,282,000, which resulted in an average standard error of 11.1 percent. A need for additional gages has been identified by the other agencies that cooperate in the program. It is suggested that these gage be installed as funds can be made available.

Water-Resources Investigations Report

Progress report of southeastern monazite exploration, 1952

Reconnaissance of placer monazite during the field season of 1952 covered 6,600 square miles drained by streams in the western Piedmont of Virginia 5 North Carolina, South Carolina,, and Georgia. Emphasis during this investigation was placed on the area between the Savannah River at the border of South Carolina and Georgia and the Catawba River in North Carolina because it contains most of the placers formerly mined for monaziteo Four other areas along the strike of the monazite-bearing crystalline rocks were also studied, They center around Mt. Airy, N.C., Athens, Ga. Griffin, Ga. and LaGrange, Ga. In the Savannah River Catawba River district, studies indicate that even the highest grade stream deposits of more than 10 million cubic yards of alluvium contain less than 1 pound of monazite per cubic yard. The average grade of the better deposits is about 0 0 5 pound of monazite per cubic yard. Only trace amounts of niobium, tantalum, and tin have been detected in the placers. Tungsten is absent. Locally gold adds a few cents per cubic yard to the value of placer ground. The best deposits range in size from 1 to 5 million cubic yards and contain 1 to 2 pounds of monazite to the cubic yard. Hundreds of placers smaller than 1 million cubic yards exceed 2 pounds of monazite to the cubic yard and locally attain an average of 10 pounds Monazite deposits around Athens, Ga., are similar to the smaller deposits in the central part of the Savannah River - Catawba River district. A few small very low-grade monazite placers were found near Mt. Airy, N.C., Griffin, Ga., and LaGrange Ga., but they are of no economic value. The larger the flood plain and the farther it lies from the source of the stream, the lower is the monazite content of the sediment. Monazite cannot be profitably mined .from the crystalline rocks in the five areas. The alluvial placers are in stream sediments of post-Wisconsin age. Some pre-Wisconsin terrace gravel of small areal extent is exposed but it contains only a small amount of monazite Pre-Wisconsin to early post-Wisconsin colluvial sediments locally contain 2 pounds of monazite to the cubic yard. Mode of presentation of reports covering field work during the seasons of 1951 - 52 is given. No further reconnaissance will be undertaken, in the western monazite belt.

Georgia;North Carolina;South Carolina;Virginia

Compilation of selected hydrologic data, through water year 1992, Black Hills Hydrology Study, western South Dakota

This report presents water-level, water-quailty, and springflow data that have been collected or compiled, through water year 1992, for the Black Hills Hydrology Study. This study is a long-term cooperative effort between the U.S. Geological Survey, the South Dakota Department of Environmental and Natural Resources, and the West Dakota Water Development District (which represents various local and county cooperators). Water-level data are presented for 32 observation wells and 2 cave sites in the Black Hills area of western South Dakota. The wells are part of a network of observation wells maintained by the South Dakota Department of Environment and Natural Resources and are completed in various bedrock formations that are utilized as aquifers in the Black Hills area. Both cave sites are located within outcrops of the Madison Limestone. Data presented include site descriptions, hydrographs, and tabular data. Water- quality data are presented for 12 surface-water sites and 5 ground-water sites. Data presented include field parameters, bacteria counts, and concentrations of common ions, solids, nutrients, trace elements, radiometrics, cyanide, phenols, dissolved organic carbon, and suspended sediment. Spring data are presented for 83 springs and 21 stream reaches with significant springflow components. Data presented include site information, discharge, and field water-quality parameters including temperature, specific conductance, dissolved oxygen, and pH.

Open-File Report

Effects of ground-water withdrawals on the Rock River and associated valley aquifer, eastern Rock County, Minnesota

A better understanding of the ground-water and surface-water resources of the Rock River Valley in southwestern Minnesota was needed due to concerns surrounding future reliable sources of water for public supply. The Rock River Valley aquifer consists of a surficial sand and gravel unit that underlies the entire Rock River Valley and a buried sand and gravel unit that is present only in the vicinity of the Luverne Municipal and Airport well fields. The surficial and buried units of the aquifer are separated by a clay and till layer ranging in thickness from 1 to 38 feet. The combined maximum saturated thickness of the aquifer is 52 feet, with a median of 22 feet. The thickness of the buried unit ranges from 3 to 17 feet. Recharge to the Rock River Valley aquifer occurs primarily by infiltration of precipitation to the saturated zone (areal recharge) and by induced infiltration from the Rock River due to withdrawals from supply wells near the river. Discharge from the aquifer occurs primarily as leakage to streams and ground-water evapotranspiration. The water budget for the calibrated steady-state simulation indicated that areal recharge accounts for 38 percent of the sources of water to the Rock River Valley aquifer and leakage from streams contributes 58.7 percent. The largest discharge from the aquifer is leakage to streams, (71.1 percent). The net stream-aquifer leakage is approximately 5 cubic feet per second from the aquifer to the streams. The simulated contributing areas for the wells in the three well fields generally extend to the aquifer boundaries on the west and are generally truncated at the Rock River. The simulated transient water budget for 1996 indicated that the principal sources of water to the aquifer were as follows: (1) winter, spring, and late summer stress periods— leakage from streams and water released from storage and (2) early summer and fall stress periods—areal recharge and leakage from streams. The principal discharges from the aquifer were leakage to streams for all stress periods, ground-water evapotranspiration for the early and late summer stress periods, and addition to storage for the early summer and fall stress periods. The herbicides atrazine, alachlor, metolachlor, acetachlor, and cyanazine, and metabolites of these herbicides, occurred in concentrations of 0.05 to 11.5 micrograms per liter in the Rock River at Luverne during major runoff events following application of herbicides in the spring. Atrazine and metabolites, alachlor ESA (a metabolite of alachlor), metolachlor and metabolites, metolachlor ESA and metolachlor OA, and acetochlor metabolites acetochlor ESA and acetochlor OA, were detected at concentrations of 0.05 to 2.8 micrograms per liter in municipal supply wells less than 500 feet from the river during November 1995 through August 1997. The Rock River is the major source of the herbicides and metabolites. However, concentrations of atrazine and metabolites, alachlor ESA, metolachlor ESA, and metolachlor OA in supply wells may also reflect sources of these herbicides and metabolites in the ground-water contributing areas to the supply wells. Nitrite plus nitrate nitrogen concentrations in supply wells and in the ground-water contributing area to the Luverne Municipal well field were generally less than 1.5 milligrams per liter. Nitrite plus nitrate nitrogen concentrations of 2.4 to 8.5 milligrams per liter in the Rock River in the Rock County Rural Water well field and 14 to 18 milligrams per liter in the ground-water contributing area to the Rock County Rural Water supply wells are not having a substantial affect on nitrite plus nitrate nitrogen concentrations in most supply wells. Isotopic mixing calculations indicate that proportions of river water withdrawn from supply wells less than 500 feet from the river range from 5 to 60 percent of total withdrawals. The Rock River is a gaining stream in most reaches, but is losing water to the aquifer in the vicinity of the Luverne Municipal and Rock County Rural Water well fields, located 150 to 1,500 feet from the river. Simulated streamflow losses due to ground-water withdrawals in the well fields were approximately 2.1 cubic feet per second. Because an average of about 1.5 cubic feet per second of the water pumped by Luverne is returned to the Rock River as wastewater discharge, the net steady-state simulated streamflow loss for the study area is 0.6 cubic feet per second. The streamflow losses as a result of ground-water withdrawals are insignificant in comparison to typical streamflow, and are likely to have a measurable effect on streamflow only during low-flow conditions of less than approximately 10 cubic feet per second. Model results indicate that the additional water withdrawn by wells due to anticipated increased ground-water withdrawals was derived from a decrease in net leakage of ground water from the aquifer to the streams. The simulations indicated that the increased ground-water withdrawals and normal precipitation resulted in an increase in induced infiltration from the Rock River of 0.1 cubic feet per second for the Luverne Municipal well field and 0.3 cubic feet per second for the Rock County Rural Water well field. Maximum drawdowns ranged from 0.5 to 1.4 feet near the three well fields. For drought conditions, the simulated streamflow losses constituted approximately 30 percent and nearly 65 percent of the flows in the Rock River for the Luverne Municipal and Rock County Rural Water well fields, respectively. Maximum drawdowns ranged from 3.8 to 7.0 feet near the three well fields. Transient simulations with anticipated increased ground-water withdrawals and drought conditions indicated declines in hydraulic heads ranging from 0.2 to 0.4 feet per year in the vicinity of the three well fields, except for near the Rock River.

Minnesota

Survival, transport, and sources of fecal bacteria in streams and survival in land-applied poultry litter in the upper Shoal Creek basin, southwestern Missouri, 2001–2002

Densities of fecal coliform bacteria along a 5.7-mi (mile) reach of Shoal Creek extending upstream from State Highway 97 (site 3) to State Highway W (site 2) and in two tributaries along this reach exceeded the Missouri Department of Natural Resources (MDNR) standard of 200 col/100 mL (colonies per 100 milliliters) for whole-body contact recreation. A combination of techniques was used in this report to provide information on the source, transport, and survival of fecal bacteria along this reach of Shoal Creek. Results of water-quality samples collected during dye-trace and seepage studies indicated that at summer low base-flow conditions, pastured cattle likely were a substantial source of fecal bacteria in Shoal Creek at the MDNR monitoring site (site 3) at State Highway 97. Using repeat element Polymerase Chain Reaction (rep-PCR), cattle were the presumptive source of about 50 percent of the Escherichia coli ( E. coli ) isolates in water samples from site 3. Cattle, horses, and humans were the most common presumptive source of E. coli isolates at sites further upstream. Poultry was identified by rep-PCR as a major source of E. coli in Pogue Creek, a tributary in the upper part of the study area. Results of the rep-PCR were in general agreement with the detection and distribution of trace concentrations of organic compounds commonly associated with human wastewater, such as caffeine, the antimicrobial agent triclosan, and the pharmaceutical compounds acetaminophen and thiabendazole (a common cattle anthelmintic). Significant inputs of fecal bacteria to Shoal Creek occurred along a 1.6-mi reach of Shoal Creek immediately upstream from site 3. During a 36-hour period in July 2001, average densities of fecal coliform and E. coli bacteria increased from less than or equal to 500 col/100 mL upstream from this stream reach (sample site 2c) to 2,100 and 1,400 col/100 mL, respectively, at the MDNR sampling site. Fecal bacteria densities exhibited diurnal variability at all five sampling sites along the 5.7-mi study reach of Shoal Creek, but the trends at successive downstream sites were out of phase and could not be explained by simple advection and dispersion. At base-flow conditions, the travel time of bacteria in Shoal Creek along the 5.7-mi reach between State Highway W (site 2) and the MDNR sampling site (site 3) was about 26 hours. Substantial dispersion and dilution occurs along the upper 4.1 mi of this reach because of inflows from a number of springs and tributaries and the presence of several long pools and channel meanders. Minimal dispersion and dilution occurs along the 1.6-mi reach immediately upstream from the MDNR sampling site. Measurements of fecal bacteria decay in Shoal Creek during July 2001 indicated that about 8 percent of fecal coliform and E. coli bacteria decay each hour with an average first-order decay constant of 0.084 h -1 (per hour). Results of field test plots indicated that substantial numbers of fecal bacteria present in poul try litter can survive in fields for as much as 8 weeks after the application of the litter to the land surface. Median densities of fecal coliform and E. coli in slurry-water samples collected from fields increased from less than 60 col/100 mL before the application of turkey and broiler litter, to as large as 420,000 and 290,000 col/100 mL after the application of litter. Bacteria densities in the test plots generally decreased in a exponential manner over time with decay rates ranging from 0.085 to 0.185 d -1 (per day) for fecal coliform to between 0.100 and 0.250 d -1 for E. coli . The apparent survival of significant numbers of fecal bacteria on fields where poultry litter has been applied indicates that runoff from these fields is a potential source of fecal bacteria to vicinity streams for many weeks following litter application.

Water-Resources Investigations Report

Recharge characteristics of a watercourse aquifer system at Springfield, Ohio

An investigation was made of infiltration conditions in the alluvial-filled Mad River valley in the vicinity of the Springfield municipal wells. The study shows that most recharge to the 100-foot thick sand and gravel aquifer is from induced infiltration from the Mad River. Local precipitation and natural, down-valley underflow also are important in sustaining the 14 mgd (million gallons per day) pumping rate. The investigation was designed to learn more about rates of streambed infiltration. Gaging stations were established at points above and below the well field in the expectation that infiltration losses could be measured directly. The attempt was unsuccessful because infiltration losses proved too small to measure accurately by ordinary stream gaging methods. The investigation has, nevertheless, provided much new data about this important watercourse aquifer system. Observation-well records covering the 4-year period 1965 through 1968 show that ground-water levels follow an annual cycle, typically rising in the period February through June, when recharge exceeds depletion, and falling during the remainder of the year. The rate of induced stream infiltration is not sufficient to prevent perennial dewatering of the aquifer beneath the streambed. The water table beneath the center of the losing reach ranges in depth from about 17 feet in January to about 6 feet in June in the average year. Bedrock highs beneath the stream, which result in local thinning of the aquifer upstream and downstream from the well field, essentially limit infiltration to a reach about 2½ miles long having an area of approximately 24 acres. During the 7-month depletion period average infiltration is estimated at 9 mgd and during the 5-month accretion period estimated infiltration is 12 mgd. On the basis of these estimates the infiltration rate for the respective periods is 0.37 and 0.50 mgd per acre, or about 0.35 mgd per acre per foot of depth.

Ohio

Geohydrology and simulated ground-water flow in northwestern Elkhart County, Indiana

In 1994, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Elkhart, developed a ground-water model of the Elkhart, Indiana, area to determine the avail-ability and source of water at potential new well fields. The modeled area covered 190 square miles of northwestern Elkhart County and a small part of southern Michigan. Three Superfund sites and several other sites in this area are undergoing environmental cleanup. The model would be used to guide the location of well fields so that Superfund sites and environmental cleanup areas would not be within recharge areas for the well fields. The City of Elkhart obtains its water supply from two aquifers separated by a generally continuous confining unit. The upper aquifer is composed primarily of sand and gravel of glacial origin. Thickness of the upper aquifer ranges from 0 to 116 feet and averages 47 feet. The lower aquifer is composed of sand and gravel with interbedded lenses of silt and clay. Thickness of the lower aquifer ranges from 1 to 335 feet and averages 35 feet. The intervening confining unit is composed of silt and clay with interbedded sand and gravel; the confining unit ranges from 0 to 177 feet, with an average thickness of 27 feet. Flow through the aquifers is generally horizontal vertically downward from the upper aquifer, through the confining unit, and into the lower aquifer, except where flow is vertically upward at the St. Joseph River and other large streams. The hydraulic characteristics of the aquifers and confining unit were estimated by analyzing aquifer-test data from well drillers? logs and by calibration of the model. The horizontal hydraulic conductivity of the upper aquifer is 170 feet per day within about 1 mile of the St. Joseph and Elkhart Rivers and 370 feet per day at distances greater than about 1 mile. The horizontal hydraulic conductivity of the lower aquifer is 370 feet per day throughout the modeled area, with the exception of an area near the center of the modeled area where the horizontal hydraulic conductivity is 170 feet per day. Transmissivity of the lower aquifer increases generally from southwest to northeast; transmissivity values range from near 0 where the lower aquifer is absent to 57,000 square feet per day and average about 8,100 square feet per day. The vertical hydraulic conductivity of the confining unit is 0.07 feet per day; the vertical conductivity of the streambeds commonly is 1.0 foot per day and ranges from 0.05 foot per day to 50 feet per day. The areal recharge rate to the outwash deposits was determined by a base-flow separation technique to be 16 inches per year, and the areal recharge rate to the till was assumed to be 4 inches per year. A two-layer digital model was used to simulate flow in the ground-water system. The model was calibrated on the basis of historical water-use data, water-level records, and gain/loss data for streams during May and June 1979. The model was recalibrated with water-use data and water-level records from 1988. For 1979 data, 49 percent of the inflow to the model area is from precipitation and 46 percent is ground-water inflow across the model boundaries. Most of the ground-water inflow across the model boundary is from the north and east, which corresponds to high values of transmissivity?as high as 57,000 feet squared per day?in the model layers in the northern and eastern areas. Eighty-two percent of the ground-water discharge is to the streams; 5 percent of the ground-water discharge is to wells. Source areas and flow paths to the City of Elkhart public well fields are affected by the location of streams and the geology in the area. Flow to the North Well Field originates north-west of the well field, forms relatively straight flow paths, and moves southeast toward the well field and the St. Joseph River. Flow to the South Well Field begins mostly in the out-wash along Yellow Creek south of the well field, moves northward, and t

Indiana

A tube seepage meter for in situ measurement of seepage rate and groundwater sampling

We designed and evaluated a “tube seepage meter” for point measurements of vertical seepage rates ( q ), collecting groundwater samples, and estimating vertical hydraulic conductivity ( K ) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy-bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K , and that it can also be configured as a self-purging groundwater-sampling device.

Groundwater

Effect of Drought on Streamflow and Stream-Water Quality in Colorado, July through September 2002

During 2002, Colorado experienced the State's worst drought since 1977. In 2003, the U.S. Geological Survey entered into cooperative agreement with the Colorado Department of Public Health and Environment to evaluate the general effects of drought on the water quality of streams in Colorado during summer 2002 by analyzing a water-quality data set obtained during summer 2002 in cooperation with a variety of State and local governments. Water samples were collected at 148 stream sites in Colorado and were measured or analyzed for field properties, major ions, nutrients, organic carbon, bacteria, and dissolved and total recoverable metals. Mean annual streamflow was analyzed at 134 sites in Colorado, and mean summer (July-September) streamflow for 2002 was determined for 146 sites for water years 1978-2002. Mean annual streamflow for 2002 had an average percentile of 29.4 and mean summer streamflow for 2002 had an average percentile of 7.6 relative to 1978-2002. These results indicate that streamflow in Colorado was substantially less than median streamflow for the period and that the effect of drought on streamflow was greater during summer 2002 than during water year 2002 (October 1, 2001, through September 30, 2002). Few measured constituent concentrations or values were elevated or depressed on a widespread basis during summer 2002. Specific conductance was elevated (in the upper quartile relative to historical data) in five of the seven basins that had sufficient data for characterization, indicating that specific conductance likely was affected by drought in those basins. Chloride concentrations were elevated in three of five basins with sufficient data and indicate that chloride concentration generally was affected by drought in those basins. Sulfate concentration was elevated in four of six basins with sufficient data. The widespread elevation of specific conductance and concentrations of chloride and sulfate indicates that salinity generally was affected by drought in Colorado streams during July-September 2002, likely because streamflow at most sites was dominated by base flow of ground water, which usually has substantially greater salinity compared to runoff from precipitation. Total-recoverable iron and manganese concentrations were depressed (in the lower quartile of historical data) in the Arkansas River Basin, which likely was due to reduced land-surface washoff of sediment containing oxyhydroxides of these metals. Of the 246 water samples collected at 148 sites during the summer of 2002, constituents in 115 exceeded Colorado water-quality standards. Constituents that exceeded water-quality standards were pH (all 9.0 standard unit exceedances; 9 samples), chloride (1 sample), sulfate (9 samples), dissolved ammonia (10 samples), dissolved nitrite nitrogen (3 samples), E. coli (Escherichia coli) bacteria (34 samples, 20 in Arkansas River Basin), fecal-coliform bacteria (18 samples, all in Arkansas River Basin), dissolved copper (1 sample), dissolved iron (3 samples), total-recoverable iron (3 samples), dissolved manganese (13 samples), dissolved selenium (10 samples), and dissolved zinc (1 sample). Of these 115 exceedances, historical data were sufficient to conclude that 21 probably were affected by drought, that 39 probably were not affected by drought, and that 55 were of indeterminate nature. Specific conductance indicates that the San Juan River Basin (average percentile 95.2) experienced the greatest effects of drought on water quality during summer 2002 compared to other basins in Colorado, followed by the Upper Colorado (90.0) and Dolores River (85.7) Basins. The South Platte River Basin (70.9) experienced the least effect of drought, and the Yampa and White River Basin group (73.7) had the second smallest effect. The Gunnison River (82.1) and Arkansas River (81.2) Basins had intermediate drought effects. The Rio Grande had insufficient data to rank the relative effect of drought on salinity.

Scientific Investigations Report

The effects of unpaved roads on instream sediment: Patterns and challenges for monitoring

Despite > 700,000 km of unpaved roads in the western United States, our knowledge of how roads impact instream sediment is unclear. We combined two studies, including (1) a regional analysis linking stream habitat data from a large-scale monitoring program with road density data to identify generalizable relationships between roads and streambed sediment distributions and (2) a targeted field study to evaluate the responses of streambed and suspended sediment collected at locations above and below road–stream connection points to better understand the consistency of responses. Regional analyses indicated a significant positive relationship between road density and fine sediment in pool tails and a significant negative relationship between road density and median particle size. We also found significant relationships between landscape, climate, and local covariates and streambed sediment metrics, where most of the parameter estimates of the covariates were equal to or stronger than those for road density. Field studies suggested higher suspended sediment levels across the seasonal hydrologic regime where roads were open to travel year-round. However, sediment responses to road–stream connection points varied by metric and site. Together, our results indicated negative relationships between increasing road densities and sediment size distributions, but detecting road effects at site scales will be challenging given the effects of covariates that can overwhelm sediment signals.

Montana

Assessing effects of nonnative crayfish on mosquito survival

Introductions of nonnative predators often reduce biodiversity and affect natural predator–prey relationships and may increase the abundance of potential disease vectors (e.g., mosquitoes) indirectly through competition or predation cascades. The Santa Monica Mountains (California, U.S.A.), situated in a global biodiversity hotspot, is an area of conservation concern due to climate change, urbanization, and the introduction of nonnative species. We examined the effect of nonnative crayfish (Procambarus clarkii) on an existing native predator, dragonfly nymphs (Aeshna sp.), and their mosquito larvae (Anopheles sp.) prey. We used laboratory experiments to compare the predation efficiency of both predators, separately and together, and field data on counts of dragonfly nymphs and mosquito larvae sampled from 13 local streams. We predicted a lower predation efficiency of crayfish compared with native dragonfly nymphs and a reduced predation efficiency of dragonfly nymphs in the presence of crayfish. Dragonfly nymphs were an order of magnitude more efficient predators than crayfish, and dragonfly nymph predation efficiency was reduced in the presence of crayfish. Field count data showed that populations of dragonfly nymphs and mosquito larvae were strongly correlated with crayfish presence in streams, such that sites with crayfish tended to have fewer dragonfly nymphs and more mosquito larvae. Under natural conditions, it is likely that crayfish reduce the abundance of dragonfly nymphs and their predation efficiency and thereby, directly and indirectly, lead to higher mosquito populations and a loss of ecosystem services related to disease vector control.

California

Hydrogeology and groundwater quality of the glaciated valleys of Bradford, Tioga, and Potter Counties, Pennsylvania

The most important sources of groundwater in Bradford, Tioga, and Potter Counties are the stratified-drift aquifers. Saturated sand and gravel primarily of outwash origin forms extensive unconfined aquifers in the valleys. Outwash is underlain in most major valleys by silt, clay, and very fine sand of lacustrine origin that comprise extensive confining units. The lacustrine confining units locally exceed 100 feet in thickness. Confined aquifers of ice-contact sand and gravel are buried locally beneath the lacustrine deposits. Bedrock and till are the basal confining units of the stratifies-drift aquifer systems. Recharge to the stratified-drift aquifers if by direct infiltration of precipitation, tributary-stream infiltration, infiltration of unchanneled runoff at the valley walls, and groundwater inflow from the bedrock and till uplands. Valley areas underlain by superficial sand and gravel contribute about 1 million gallons per day per square mile of water from precipitation to the aquifers. Tributary streams provide recharge of nearly 590 gallons per day per foot of stream reach. Water is added at the rate of 1 million gallons per day per square mile of bordering uplands not drained by tributary streams to the stratified-drift aquifers from unchanneled runoff and groundwater inflow. Induced infiltration can be a major source of recharge to well fields completed in unconfined stratified-drift aquifers that are in good hydraulic connection with surface water. The well fields of an industrial site in North Towanda, a public-water supplier at Tioga Point, and the U.S. Fish and Wildlife Service at Asaph accounted for 75 percent of the 10.8 million gallons per day pf groundwater withdrawn by public suppliers and other selected users in 1985. The well fields tap stratified-drift aquifers that are substantially recharged by induced infiltration or tributary-stream infiltration. Specific-capacity data from 95 wells indicate that most wells completed in stratified-drift aquifers have specific capacities an order of magnitude greater than those completed in till and bedrock, Wells completed in unconfined stratified-drift aquifers and in bedrock aquifers have the highest and lowest median specific capacities -- 24 and 0.80 gallons per minute per foot of drawdown, respectively. Wells completed in confined stratified-drift aquifers and in till have median specific capacties of 11 and 0.87 gallons per minute per foot of drawdown, respectively. The results of 223 groundwater-quality analyses indicate two major hydrogeochemical zones: (1) a zone of unrestricted groundwater flow that contains water of the calcium bicarbonate type (this zone is found in almost all of the stratified-drift aquifers, till, and shallow bedrock systems); and (2) a zone of restricted groundwater slow that contains water of the sodium chloride type (this zone is found in the bedrock, and, in some areas, in till and confined stratified-drift aquifers). Samples pumped from wells that penetrate restricted-flow zones have median concentrations of total dissolved solids, dissolved chloride, and dissolved barium of 840 and 350 milligrams per liter, and 2,100 micrograms per liter, respectively. Excessive concentrations of iron and manganese are common in the groundwater of the study area; about 50 percent of the wells sampled contain water that has iron and manganese concentrations that exceed the U.S. Environmental Protection Agency secondary maximum contaminant levels of 300 and 50 micrograms per liter, respectively. Only water in the unconfined stratified-drift aquifers and the Catskill Formation has median concentrations lower than these limits.

Pennsylvania

Selenium in ecosystems within the mountaintop coal mining and valley-fill region of southern West Virginia-assessment and ecosystem-scale modeling

Coal and associated waste rock are among environmental selenium (Se) sources that have the potential to affect reproduction in fish and aquatic birds. Ecosystems of southern West Virginia that are affected by drainage from mountaintop coal mines and valleys filled with waste rock in the Coal, Gauley, and Lower Guyandotte watersheds were assessed during 2010 and 2011. Sampling data from earlier studies in these watersheds (for example, Upper Mud River Reservoir) and other mining-affected watersheds also are included to assess additional hydrologic settings and food webs for comparison. Basin schematics give a comprehensive view of sampled species and Se concentration data specific to location and date. Food-web diagrams document the progression of Se trophic transfer across suspended particulate material, invertebrates, and fish for each site to serve as the basis for developing an ecosystem-scale model to predict Se exposure within the hydrologic conditions and food webs of southern West Virginia. This approach integrates a site-specific predator’s dietary exposure pathway into modeling to ensure an adequate link to Se toxicity and, thus, to species vulnerability. Site-specific fish abundance and richness data in streams documented various species of chub, shiner, dace, darters, bass, minnow, sunfish, sucker, catfish, and central stoneroller (Campostoma anomalum), mottled sculpin (Cottus bairdii), and least brook lamprey (Lampetra aepyptera). However, Se assessment species for streams, and hence, model species for streams, were limited to creek chub (Semotilus atromaculatus) and central stoneroller. Both of these species of fish are generally considered to have a high tolerance for environmental stress based on traditional comparative fish community assessment, with creek chub being present at all sites. Aquatic insects (mayfly, caddisfly, stonefly, dobsonfly, chironomid) were the main invertebrates sampled in streams. Collection of suspended particulate material acted as an integrator of organic-rich, fine-grained biomass present in streams. The base-case food web modeled for streams was suspended particulate material to aquatic insect to creek chub, with comparative modeling of a direct particulate-to-stoneroller food web. Model species for a reservoir setting were based on an earlier study of bluegill sunfish (Lepomis macrochirus), green sunfish (Lepomis cyanellus), and largemouth bass (Micropterus salmoides). Several reservoir food webs were considered based on a variety of invertebrates (insect, snail, clam). For stream and reservoir settings, predicted Se concentrations in exposure scenarios showed a high degree of correlation (r 2 = 0.91 for invertebrates and 0.75 for fish) with field observations of Se concentrations when modeling was initiated from suspended-particulate-material Se concentrations and model transfer parameters defined previously in the literature were used. These strong correlations validate the derived site-specific model and establish sufficient confidence that the predictions from the developed model can be quantitatively applied to the ecosystems in southern West Virginia. An application of modeling used a metric describing the partitioning of Se between particulate material and dissolved phases (K d ) to allow determination of a dissolved Se concentration that would be necessary to attain a site-specific Se fish body burden. The operationally defined K d quantifies the complex process of transformation at the base of a food web on a site-specific basis. The magnitude of this metric is known to vary with such factors as Se speciation, particulate-material type, and hydrology. This application (1) ties dissolved Se concentrations to fish tissue concentrations; (2) allows consideration of different choices for intervening site-specific exposure steps that set Se bioaccumulation, partitioning, and bioavailability; and (3) generates implications for management decisions that define protection through different regulatory pathways and guidelines. The range of model outcomes accounts for critical sources of variability and establishes whether site and food-web characterization were adequate to represent the dynamics of the system with certainty. This is especially true in terms of particulate-material phases at the base of the food web and utilization of K d in different hydrologic settings. For streams, a range of field-derived K d ds were applied to food-web exposure scenarios within a framework of locational and hydrologic variables (area of stream basin; stream gradient and discharge) that may affect the magnitude of K d . Overlaying even a coarse temporal scale that acknowledges variability in stream dissolved Se and Se speciation, such as through seasonal derivation of K d , can substantially narrow model uncertainty. Modeling that constrains the place and time of greatest ecosystem Se sensitivity within a specified food web gives insight into Se risk and identifies controlling management alternatives within a watershed or stream basin. If there is a range of hydrologic settings, specificity is needed to establish a hierarchy of in-stream and off-stream habitats for a watershed approach that takes into account Se-enriched water moving through different K d and food web environments. If there is a range of predator vulnerabilities (measured as a combination of food-web Se biodynamics and response in Se toxicity tests) within the site-specific community of fish species to be protected, then choice of fish species is critical to protection because it determines the food web and, hence, the magnitude of biotransfer through which Se is modeled. Whether creek chub is representative of the vulnerability to Se of all fish species encountered within the study-site ecosystems will require additional species-specific data and analysis. A range of site-specific scenarios illustrated here set model outcomes, but the final quantitative evaluation of alternatives and their implications will be those generated through choices and guidance formulated by state and other agencies in their decisionmaking processes. Proposed additions and refinements to the ecosystem-scale site-specific approach developed here include consideration of: measurement of temporally matched pairs of dissolved and suspended-particulate-material Se concentrations across a broader range of stream sites to expand the stream K d database and to test the representativeness of a suspended-particulate-material sample within a stream; characterization of different phases of particulate material across seasons to better define the base of the food web and connect to invertebrate feeding; refinement of model assumptions concerning dietary preferences and composition for fish to develop additional trophic transfer factors (TTFs) (for example, calculation of TTFinvertebrate composite for mixed diets); expansion of modeling of fish species and their food webs to include Se-vulnerable species; temporal characterization of a predator’s life cycle and habitat use as additional model layers to integrate with Se biodynamics in streams; investigation of the effect of stream gradient on K d based on a finer scale than presented here in terms of such variables as residence time, watershed dilution, and physical habitat attributes (for example, amount of ponding versus run or riffle within a stream); and linkage to discharge through use of stream gaging to record variability and enable model organization within water-year types and discharge seasons. Investigating the presence and variability of prey and predator species in demographically open systems such as streams also is key to model outcomes given the overall environmental stressors (for example, general landscape change, food-web disruption, recolonization potential) imposed on the composition of biological communities in coal mining and valley-fill affected watersheds

West Virginia

Hyporheic zone denitrification: controls on effective reaction depth and contribution to whole-stream mass balance

Stream denitrification is thought to be enhanced by hyporheic transport but there is little direct evidence from the field. To demonstrate at a field site, we injected 15 NO 3 − , Br (conservative tracer), and SF 6 (gas exchange tracer) and compared measured whole-stream denitrification with in situ hyporheic denitrification in shallow and deeper flow paths of contrasting geomorphic units. Hyporheic denitrification accounted for between 1 and 200% of whole-stream denitrification. The reaction rate constant was positively related to hyporheic exchange rate (greater substrate delivery), concentrations of substrates DOC and nitrate, microbial denitrifier abundance (nirS), and measures of granular surface area and presence of anoxic microzones. The dimensionless product of the reaction rate constant and hyporheic residence time, λ hz τ hz define a Damköhler number, Da den-hz that was optimal in the subset of hyporheic flow paths where Da den-hz ≈ 1. Optimal conditions exclude inefficient deep pathways transport where substrates are used up and also exclude inefficient shallow pathways that require repeated hyporheic entries and exits to complete the reaction. The whole-stream reaction significance, R s (dimensionless), was quantified by multiplying Da den-hz by the proportion of stream discharge passing through the hyporheic zone. Together these two dimensionless metrics, one flow-path scale and the other reach-scale, quantify the whole-stream significance of hyporheic denitrification. One consequence is that the effective zone of significant denitrification often differs from the full depth of the hyporheic zone, which is one reason why whole-stream denitrification rates have not previously been explained based on total hyporheic-zone metrics such as hyporheic-zone size or residence time.

Indiana

Accounting for temporal variability of streamflow in estimates of travel time

Retention, processing, and transport of solutes and particulates in stream corridors are influenced by the travel time of streamflow through stream channels, which varies dynamically with discharge. The effects of streamflow variability across sites and over time cannot be addressed by time-averaged models if parameters are based solely on the characteristics of mean streamflow. We develop methods to account for the effects of streamflow variability on travel time and compare our estimates to flow-weighted (“effective”) travel time at 100 streams in the southeastern United States. Velocity time series were generated for each stream from multiple-year (median 15.5 years), high-frequency (15 min interval) records of instantaneous streamflow and field measurements of velocity and inverted to produce time series of specific travel time [T/L]. The effective travel times for streams are 60–90% of the specific travel time of mean streamflow because a large fraction of the total streamflow volume is discharged during higher flows with higher velocities. We find that adjusting the specific travel time of mean streamflow at a site by a factor of 0.81 generally accounts for the effect of a skewed streamflow distribution, but at-site estimates of the coefficient of variation of streamflow are necessary to resolve differences in streamflow variability between streams or changes in variability over time. For example, the effective travel time of urban streams is less than the effective travel of forested streams in the southeastern United States as a result of increased streamflow variability in urban streams. Effective travel time accounts for both the variation in velocity with streamflow and the large fraction of streamflow discharged during high flows in most streams and provides time-averaged models with limited capability to account for effects of streamflow variability that otherwise they lack. This capability is needed for continental-scale modeling where streamflow variability is not uniform because of heterogeneous surficial geology, hydro-climatology, and vegetation and for applications where streamflow variability is not stationary as a response to climate change or hydrologic alteration.

Alabama, Georgia, North Carolina, Virginia, South

Water quality of the Swatara Creek Basin, PA

The Swatara Creek of the Susquehanna River Basin is the farthest downstream sub-basin that drains acid water (pH of 4.5 or less) from anthracite coal mines. The Swatara Creek drainage area includes 567 square miles of parts of Schuylkill, Berks, Lebanon, and Dauphin Counties in Pennsylvania. To learn what environmental factors and dissolved constituents in water were influencing the quality of Swatara Creek, a reconnaissance of the basin was begun during the summer of 1958. Most of the surface streams and the wells adjacent to the principal tributaries of the Creek were sampled for chemical analysis. Effluents from aquifers underlying the basin were chemically analyzed because ground water is the basic source of supply to surface streams in the Swatara Creek basin. When there is little runoff during droughts, ground water has a dominating influence on the quality of surface water. Field tests showed that all ground water in the basin was non-acidic. However, several streams were acidic. Sources of acidity in these streams were traced to the overflow of impounded water in unworked coal mines. Acidic mine effluents and washings from coal breakers were detected downstream in Swatara Creek as far as Harper Tavern, although the pH at Harper Tavern infrequently went below 6.0. Suspended-sediment sampling at this location showed the mean daily concentration ranged from 2 to 500 ppm. The concentration of suspended sediment is influenced by runoff and land use, and at Harper Tavern it consisted of natural sediments and coal wastes. The average daily suspended-sediment discharge there during the period May 8 to September 30, 1959, was 109 tons per day, and the computed annual suspended-sediment load, 450 tons per square mile. Only moderate treatment would be required to restore the quality of Swatara Creek at Harper Tavern for many uses. Above Ravine, however, the quality of the Creek is generally acidic and, therefore, of limited usefulness to public supplies, industries and recreation. In general, the quality of Swatara Creek improves after it mixes with water from the Upper Little and Lower Little Swatara Creeks, which converge with the main stream near Pine Grove. Jonestown is the first downstream location where Swatara Creek contains bicarbonate ion most of the time, and for the remaining downstream length of the stream, the concentration of bicarbonate progressively increases. Before the stream enters the Susquehanna River, chemical and diluting processes contributed by tributaries change the acidic calcium sulfate water, which characterizes the upper Swatara, to a calcium bicarbonate water. A major tributary to Swatara Creek is Quittapahilla Creek, which drains a limestone region and has alkaline characteristics. Effluents from a sewage treatment plant are discharged into this stream west of Lebanon. Adjacent to the Creek are limestone quarries and during the recovery of limestone, ground water seeps into the mining areas. This water is pumped to upper levels and flows over the land surface into Quittapahilla Creek. As compared with the 1940's, the quality of Swatara Creek is better today, and the water is suitable for more uses. In large part, this improvement is due to curtailment of anthracite coal mining and because of the controls imposed on new mines, stripping mines, and the related coal mining operations, by the Pennsylvania Sanitary Water Board. Thus, today (1962) smaller amounts of coal mine wastes are more effectively flushed and scoured away with each successive runoff during storms that affect the drainage basin. Natural processes neutralizing acid water in the stream by infiltration of alkaline ground water through springs and through the streambed are also indicated.

Pennsylvania

Clearing the waters: Evaluating the need for site-specific field fluorescence corrections based on turbidity measurements

In situ fluorescent dissolved organic matter (fDOM) measurements have gained increasing popularity as a proxy for dissolved organic carbon (DOC) concentrations in streams. One challenge to accurate fDOM measurements in many streams is light attenuation due to suspended particles. Downing et al. (2012) evaluated the need for corrections to compensate for particle interference on fDOM measurements using a single sediment standard in a laboratory study. The application of those results to a large river improved unfiltered field fDOM accuracy. We tested the same correction equation in a headwater tropical stream and found that it overcompensated fDOM when turbidity exceeded ∼300 formazin nephelometric units (FNU). Therefore, we developed a site-specific, field-based fDOM correction equation through paired in situ fDOM measurements of filtered and unfiltered streamwater. The site-specific correction increased fDOM accuracy up to a turbidity as high as 700 FNU, the maximum observed in this study. The difference in performance between the laboratory-based correction equation of Downing et al. (2012) and our site-specific, field-based correction equation likely arises from differences in particle size distribution between the sediment standard used in the lab (silt) and that observed in our study (fine to medium sand), particularly during high flows. Therefore, a particle interference correction equation based on a single sediment type may not be ideal when field sediment size is significantly different. Given that field fDOM corrections for particle interference under turbid conditions are a critical component in generating accurate DOC estimates, we describe a way to develop site-specific corrections.

Limnology and Oceanography: Methods