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At least 343 records · Page 19Linked to original sources

USGS2006

Detrital zircon provenance of the Late Triassic Songpan-Ganzi complex: Sedimentary record of collision of the North and South China blocks

Using detrital zircon geochronology, turbidite deposystems fed from distinct sediment sources can be distinguished within the Songpan-Ganzi complex, a collapsed Middle to Late Triassic turbidite basin of central China. A southern Songpan-Ganzi deposystem initially was sourced solely by erosion of the Qinling-Dabie orogen during early Late Triassic time, then by Qinling-Dabie orogen, North China block, and South China block sources during middle to late Late Triassic time. A northern Songpan-Ganzi system was sourced by erosion of the Qinling-Dabie orogen and the North China block throughout its deposition. These separate deposystems were later tectonically amalgamated to form one complex and then uplifted as the eastern Tibet Plateau. ?? 2006 Geological Society of America.

Geology↗

USGS2013

Previously unrecognized regional structure of the Coastal Belt of the Franciscan Complex, northern California, revealed by magnetic data

Magnetic anomalies provide surprising structural detail within the previously undivided Coastal Belt, the westernmost, youngest, and least-metamorphosed part of the Franciscan Complex of northern California. Although the Coastal Belt consists almost entirely of arkosic graywacke and shale of mainly Eocene age, new detailed aeromagnetic data show that it is pervasively marked by long, narrow, and regularly spaced anomalies. These anomalies arise from relatively simple tabular bodies composed principally of magnetic basalt or graywacke confi ned mainly to the top couple of kilometers, even though metamorphic grade indicates that these rocks have been more deeply buried, at depths of 5–8 km. If true, this implies surprisingly uniform uplift of these rocks. The basalt (and associated Cretaceous limestone) occurs largely in the northern part of the Coastal Belt; the graywacke is recognized only in the southern Coastal Belt and is magnetic because it contains andesitic grains. The magnetic grains were not derived from the basalt, and thus require a separate source. The anomalies defi ne simple patterns that can be related to folding and faulting within the Coastal Belt. This apparent simplicity belies complex structure mapped at outcrop scale, which can be explained if the relatively simple tabular bodies are internally deformed, fault-bounded slabs. One mechanism that can explain the widespread lateral extent of the thin layers of basalt is peeling up of the uppermost part of the oceanic crust into the accretionary prism, controlled by porosity and permeability contrasts caused by alteration in the upper part of the subducting slab. It is not clear, however, how this mechanism might generate fault-bounded layers containing magnetic graywacke. We propose that structural domains defined by anomaly trend, wavelength, and source reflect imbrication and folding during the accretion process and local plate interactions as the Mendocino triple junction migrated north, a hypothesis that should be tested by more detailed structural studies.

California↗

USGS1993

Extension and contraction within an evolving divergent strike-slip fault complex: The San Andreas and San Jacinto fault zones at their convergence in southern California

A variety of extensional and contractional structures is produced by strike slip faulting. The variety and extent of the structures are directly related to the kind and extent of geometric complexities of the fault zone or system. The area of convergence of the San Andreas fault zone and the much younger San Jacinto fault zone in the eastern Transverse Ranges is exquisitely complex. We propose that the San Jacinto fault zone formed in response to a structural knot in San Gorgonio Pass probably within the past 1.5 Ma. In the area of their convergence we propose that slip is transferred both east and west from the San Jacinto fault zone northward to the San Andreas fault zone over a 60-to 70-km band that extends northwestward from the south end of the San Bernardino basin to the east end of the San Gabriel Mountains. We further propose several structural adjustments as a consequence of onset or acceleration of lateral movement on the San Jacinto fault zone: accelerated uplift of the eastern San Gabriel Mountains, development or accentuation of an arcuate schuppen-like structure in the eastern San Gabriel Mountains, inception of the San Bernardino basin, cessation of deposition in the present-day San Timoteo badlands area, inception of the San Jacinto basin, and an increase in compression and uplift in the San Gorgonio Pass area. We interpret the uplift and compression in San Gorgonio Pass to result from two formerly disparate structural blocks—the eastern San Bernardino and San Jacinto blocks—becoming a relatively coherent block, and the San Gorgonio Pass area constituting a left step between the San Andreas fault zone in the Coachella Valley area and the San Jacinto fault zone in the San Jacinto Valley area. The compression and uplift led to the formation of the San Gorgonio Pass thrust faults and disruption of any through-going San Andreas strands, at least at the surface. In partitioning slip between the San Andreas and San Jacinto fault zones, consideration should be given to the bandwidth over which horizontal strain has accumulated. The average slip rate of the northern part of the San Jacinto fault zone during the past 1.5 m.y. may have been about 20 mm/yr and about 15 mm/yr on the San Andreas. South of the San Bernardino basin, current strain accumulation based on repeated geodetic surveys is nearly equally divided between the San Jacinto and San Andreas fault zones.

California↗

USGS2023

Incorporating wave climate complexity into modeling lower shoreface morphology and transport

The lower shoreface, a transitional subaqueous region extending from the seaward limit of the surf zone to beyond the closure depth, serves as a sediment reservoir and pathway in sandy beach environments over annual to millennial time scales. Despite the important role this region plays in shoreline dynamics, the morphodynamics of the lower shoreface remain poorly quantified and understood. To better understand controls on shoreface morphology, here we combine energetics-based suspended sediment transport formulae (Ortiz & Aston 2016) with empirical wave climate data to incorporate temporal complexity in modeled equilibrium profiles and sediment flux rates. The equilibrium shoreface shape computed using a full wave climate is steeper in shallower water and less steep in the deeper reaches compared to profiles computed using single wave characteristics. Using a full wave climate to simulate steady-state morphology will yield steeper profiles in shallow water. Suspended sediment transport rates also vary in direction and magnitude at different equilibrium profile depths and can potentially inform the location of morphodynamic boundaries in the shoreface. Our results reveal how infrequent storm waves affect shoreface slopes, with large events tending to drive sediment onshore in the deeper portions of the profile. This work explores a few ways to add complexity to simple energetics-based frameworks to reproduce empirical bathymetric data more accurately and provides insight toward refining coastal source-to-sink models.

Conference Paper↗

USGS2009

Arc-continent collision and the formation of continental crust: A new geochemical and isotopic record from the Ordovician Tyrone Igneous Complex, Ireland

Collisions between oceanic island-arc terranes and passive continental margins are thought to have been important in the formation of continental crust throughout much of Earth's history. Magmatic evolution during this stage of the plate-tectonic cycle is evident in several areas of the Ordovician Grampian-Taconic orogen, as we demonstrate in the first detailed geochemical study of the Tyrone Igneous Complex, Ireland. New U-Pb zircon dating yields ages of 493 2 Ma from a primitive mafic intrusion, indicating intra-oceanic subduction in Tremadoc time, and 475 10 Ma from a light rare earth element (LREE)-enriched tonalite intrusion that incorporated Laurentian continental material by early Arenig time (Early Ordovician, Stage 2) during arc-continent collision. Notably, LREE enrichment in volcanism and silicic intrusions of the Tyrone Igneous Complex exceeds that of average Dalradian (Laurentian) continental material that would have been thrust under the colliding forearc and potentially recycled into arc magmatism. This implies that crystal fractionation, in addition to magmatic mixing and assimilation, was important to the formation of new crust in the Grampian-Taconic orogeny. Because similar super-enrichment of orogenic melts occurred elsewhere in the Caledonides in the British Isles and Newfoundland, the addition of new, highly enriched melt to this accreted arc terrane was apparently widespread spatially and temporally. Such super-enrichment of magmatism, especially if accompanied by loss of corresponding lower crustal residues, supports the theory that arc-continent collision plays an important role in altering bulk crustal composition toward typical values for ancient continental crust. ?? 2009 Geological Society of London.

Journal of the Geological Society↗

USGS2018

Subsurface controls on the development of the Cape Fear Slide Complex, central US Atlantic Margin

The Cape Fear Slide is one of the largest (>25 000 km 3 ) submarine slope failure complexes on the US Atlantic margin. Here we use a combination of new high-resolution multichannel seismic data (MCS) from the National Science Foundation Geodynamic Processes at Rifting and Subducting Margins (NSF GeoPRISMS) Community Seismic Experiment and legacy industry MCS to derive detailed stratigraphy of this slide and constrain the conditions that lead to slope instability. Limited outer-shelf and upper-slope accommodation space during the Neogene, combined with lowstand fluvial inputs and northwards Gulf Stream sediment transport, appears to have contributed to thick Miocene and Pliocene deposits that onlapped the lower slope. This resulted in burial of an upper-slope bypass zone developed from earlier erosional truncation of Paleogene strata. These deposits created a broad ramp that allowed accumulation of thick Quaternary strata across a low-gradient (<3.5°) upper slope. Upslope of one of the larger headwalls, undulating Quaternary strata appear to downlap onto a buried failure plane. Many of the nested headwalls of the upper-slope portion of slide complex are underlain by deformed strata, which may be the result of fluid migration associated with localized subsidence from salt migration. These new data and observations suggest that antecedent margin physiography, sediment loading and substrate fluid flow were key factors in preconditioning the Cape Fear slope for failure.

Geological Society of London Special Publications↗

USGS2016

Spatial and temporal variation in positioning probability of acoustic telemetry arrays: Fine-scale variability and complex interactions

Background As popularity of positional acoustic telemetry systems increases, so does the need to better understand how they perform in real-world applications, where variation in performance can bias study conclusions. Studies assessing variability in positional telemetry system performance have focused primarily on position accuracy, or comparing performance inside and outside the array. Here, we explored spatial and temporal variation in positioning probability within a 140-receiver Vemco Positioning System (VPS) array used to monitor lake trout, Salvelinus namaycush , spawning behavior over 23 km 2 in Lake Huron, North America. Methods Variability in VPS positioning probability was assessed between August and November from 2012 to 2014 using 43 stationary transmitters distributed throughout the array. Various analyses were used to relate positioning probability to number of fish transmitters in the array, wave height, and thermal stratification. We also assessed the prevalence of ‘close proximity detection interference’ (CPDI) in our array by analyzing detection probability of 35 transmitters on collocated receivers. Results Positioning probability of the VPS array varied greatly over time and space. Number of fish transmitters present in the array was a significant driver of reduced positioning probability, especially during lake trout spawning period when the fish were aggregated. Relationships between positioning probability and environmental variables were complex and varied over small spatial and temporal scales. One possible confounding variable was the large range of water depth over which receivers were deployed. Another confounding factor was the high prevalence of CPDI, which decreased exponentially with water depth and was less evident when wave heights were higher than normal. Conclusions Some variables that negatively influenced positioning can be minimized through careful planning (e.g., number of tagged fish released, transmitter power level). However, results suggested that the acoustic environment was highly variable over small spatial and temporal scales in response to complex interactions between many variables. Therefore, models that predict positioning or detection efficiencies as a function of environmental variables may not be attainable in most systems. The best defense against biased study conclusions is incorporation of in situ measures of system performance that allow for retrospective analysis of array performance after a study is completed. Keywords Vemco Positioning System Positional telemetry Performance Detection probability Close proximity detection interference Thermal stratification Wave height Signal code collision

Animal Biotelemetry↗

USGS2014

Geophysical interpretation of U, Th, and rare earth element mineralization of the Bokan Mountain peralkaline granite complex, Prince of Wales Island, southeast Alaska

A prospectivity map for rare earth element (REE) mineralization at the Bokan Mountain peralkaline granite complex, Prince of Wales Island, southeastern Alaska, was calculated from high-resolution airborne gamma-ray data. The map displays areas with similar radioelement concentrations as those over the Dotson REE-vein-dike system, which is characterized by moderately high %K, eU, and eTh (%K, percent potassium; eU, equivalent parts per million uranium; and eTh, equivalent parts per million thorium). Gamma-ray concentrations of rocks that share a similar range as those over the Dotson zone are inferred to locate high concentrations of REE-bearing minerals. An approximately 1300-m-long prospective tract corresponds to shallowly exposed locations of the Dotson zone. Prospective areas of REE mineralization also occur in continuous swaths along the outer edge of the pluton, over known but undeveloped REE occurrences, and within discrete regions in the older Paleozoic country rocks. Detailed mineralogical examinations of samples from the Dotson zone provide a means to understand the possible causes of the airborne Th and U anomalies and their relation to REE minerals. Thorium is sited primarily in thorite. Uranium also occurs in thorite and in a complex suite of ± Ti ± Nb ± Y oxide minerals, which include fergusonite, polycrase, and aeschynite. These oxides, along with Y-silicates, are the chief heavy REE (HREE)-bearing minerals. Hence, the eU anomalies, in particular, may indicate other occurrences of similar HREE-enrichment. Uranium and Th chemistry along the Dotson zone showed elevated U and total REEs east of the Camp Creek fault, which suggested the potential for increased HREEs based on their association with U-oxide minerals. A uranium prospectivity map, based on signatures present over the Ross-Adams mine area, was characterized by extremely high radioelement values. Known uranium deposits were identified in the U-prospectivity map, but the largest tract occurs over a radioelement-rich granite phase within the pluton that is likely not related to mineralization. Neither mineralization type displays a well-defined airborne magnetic signature.

Alaska↗

USGS2022

The role of hydraulic and geomorphic complexity in predicting invasive carp spawning potential: St. Croix River, Minnesota and Wisconsin, United States

Since they were first introduced to the United States more than 50 years ago, invasive carp have rapidly colonized rivers of the Mississippi River Basin, with detrimental effects on native aquatic species. Their continued range expansion, and potential for subsequent invasion of the Great Lakes, has led to increased concern for the susceptibility of as-yet uncompromised lotic and lentic systems in the central United States. Because invasive carp eggs and larvae must drift in the river current for the first several days following spawning, numerical drift modeling has emerged as a useful technique for determining whether certain river systems and reaches have the potential to support suspension-to-hatching survival of invasive carp eggs, a critical first step in recruitment. Here we use one such numerical modeling approach, the Fluvial Egg Drift Simulator (FluEgg), to estimate bighead carp ( Hypophthalmichthys nobilis ) egg hatching success and larval retention in a 47.8-kilometer (km) reach of the multi-thread St. Croix River, Minnesota and Wisconsin, United States. We explore three approaches for obtaining the hydraulic data required by FluEgg, parameterizing the model with either (a) field hydraulic data collected within the main channel during a high-flow event, or hydraulic data output from a one-dimensional hydrodynamic model with both (b) steady, and (c) unsteady flows. We find that the three approaches, along with the range of water temperatures and discharge used in simulations, produce vastly different predictions of streamwise transport and in-river egg hatching probability (0% for field data, 0 to 96% for steady-state hydraulic modeling, and 1.8 to 65% for unsteady modeling). However, all FluEgg simulations, regardless of the source of hydraulic data, predicted that no larvae reach the gas bladder inflation stage within the study reach where nursery habitat is abundant. Overall, these results indicate that the lower St. Croix River is suitable for invasive carp spawning and egg suspension until hatching for a range of discharge and water temperatures. These results highlight the role of complex channel hydraulics and morphology, particularly multi-thread reaches, and their inclusion in ecohydraulic-suitability modeling to determine susceptibility of river systems for invasive carp reproduction. Our work also emphasizes the scientific value of multi-dimensional hydrodynamic models that can capture the spatial heterogeneity of flow fields in geomorphically complex rivers. This work may help to guide management efforts based on the targeted monitoring and control and improve invasive carp egg and larvae sampling efficiency.

Minnesota, Wisconsin↗

USGS2009

Hepatic pathologies in the brackish water catfish (Chrysichthys nigrodigitatus) from contaminated locations of the Lagos lagoon complex

Several toxicological studies into the effects of aquatic pollutants on the liver of teleost fish exist in literature. The focus on the liver in these studies is predicated on its central nature in the scheme of biotransformation and excretion of xenobiotics following exposure in polluted water bodies. As a consequence of the latter primary role of the liver in these processes it is regarded as a predilective site for the sub lethal effects of xenobiotics on the organism usually detectable at histological level. Hepatic histopathology recorded in livers from feral populations of the brackish water catfish Chrysichthys nigrodigitatus from locations on the Lagos lagoon complex with significant anthropogenic inputs from denizen populations and industries are presented. Liver sections from sixty specimens from two locations on the Lagos lagoon complex (Badagry lagoon: 6°24'N, 2°56'E; and Lagos lagoon: 6°29'N, 3°22'E) were analysed. Observed pathologies included hydropic degeneration (58%), portal / sinusoidal congestion (33%), hepatic necrosis (26%), hemosiderosis (12%) and foci of cellular alterations (FCA's). No obvious oncologic features were observed; the presence of the hydropic Vacuolation lesion was taken as prelude to the development of neoplasms and discussed as such.

Badagry Lagoon, Lagos Lagoon↗

USGS2020

Amphibian population declines: 30 Years of progress in confronting a complex problem

In 1989, it dawned on participants at the First World Congress of Herpetology that observed declines in amphibian populations might actually be global in scope and unprecedented in severity. Three decades of research since then has produced an enormous increase in our knowledge of amphibian ecology and appreciation of the complexity of possible causes for amphibian population declines. In September 2019, 30 yr after the First World Congress ended, a day-long, international symposium on amphibian population declines was held at the Redpath Museum of McGill University in Montreal, Canada. Symposium participants drew upon the knowledge gained over three decades of study to look ahead with fresh ideas to address this vital aspect of the global decline of biodiversity. Despite tremendous progress over the past three decades there is still much about amphibian ecology, population biology, and pathology that remains unknown. Amphibian declines have turned out to be more complex than originally expected and the result of multiple possible causes acting across landscapes, among taxa, or between populations in ways that are not at all uniform. The papers in this special issue of Herpetologica , which stem from the symposium, explore much of our current understanding of amphibian declines and their causes.

Herpetologica↗

USGS2010

Longitudinal differences in habitat complexity and fish assemblage structure of a great plains river

We investigated the spatial variation in the Kansas River (USA) fish assemblage to determine how fish community structure changes with habitat complexity in a large river. Fishes were collected at ten sites throughout the Kansas River for assessing assemblage structure in summer 2007. Aerial imagery indicated riparian land use within 200 m from the river edge was dominated by agriculture in the upper river reaches (>35) and tended to increase in urban land use in the lower reaches (>58). Instream habitat complexity (number of braided channels, islands) also decreased with increased urban area (<25). Canonical correspondence analysis indicated that species that prefer high-velocity flows and sandy substrate (e.g., blue sucker Cycleptus elongatus and shovelnose sturgeon Scaphirhynchus platorynchus) were associated with the upper river reaches. Abundance of omnivorous and planktivorous fish species were also higher in the lower river. The presence of fluvial dependent and fluvial specialist species was associated with sites with higher water flows, more sand bars, and log jams. Our results suggest that conserving intolerant, native species in the Kansas River may require maintaining suitable habitat for these species and restoration of impacted areas of the river.

American Midland Naturalist↗

USGS2019

The Santa Cruz Basin submarine landslide complex, southern California: Repeated failure of uplifted basin sediment

The Santa Cruz Basin (SCB) is one of several fault-bounded basins within the California Continental Borderland that has drawn interest over the years for its role in the tectonic evolution of the region, but also because it contains a record of a variety of modes of sedimentary mass transport (i.e., open slope vs. canyon-confined systems). Here, we present a suite of new high-resolution marine geophysical data that demonstrate the extent and significance of the SCB submarine landslide complex in terms of late Miocene to present basin evolution and regional geohazard assessment. The new data reveal that submarine landslides cover an area of ~160 km2 along the eastern flank of the Santa Rosa–Cortes Ridge and have emplaced a minimum of 9 to 16 km3 of mass transport deposits along the floor of the SCB during the Quaternary. The failures occur along an onlapping wedge of Pliocene sediment that was uplifted and tilted during the later stages of basin development. The uplifted and steepened Pliocene strata were preconditioned for failure so that parts of the section failed episodically throughout the Quaternary—most likely during large earthquakes. Once failed, the material initially translated as a block glide along a defined failure surface. As transport continued several kilometers across a steep section of the lower slope, the material separated into distinctive proximal and distal components. The failed masses mobilized into debris flows that show evidence for dynamic separation into less and more mobile components that disturbed and eroded underlying stratigraphy in areas most proximal to the source area. The most highly mobilized components and those with the lowest viscosity and yield strength produced flows that blanket the underlying stratigraphy along the distal reaches of deposition. The estimated volumes of individual landslides within the complex (0.1–2.6 km3), the runout distance measured from the headwalls (>20 km), and evidence for relatively high velocity during initial mobilization all suggest that slides in the SCB may have been tsunamigenic. Because many slopes in the California Continental Borderland are either sediment starved or have experienced sediment bypass during the Quaternary, we propose that uplift and rotation of Pliocene deposits are important preconditioning factors for slope failure that need to be systematically evaluated as potential tsunami initiators.

California↗

USGS2012

A major light rare-earth element (LREE) resource in the Khanneshin carbonatite complex, southern Afghanistan

The rapid rise in world demand for the rare-earth elements (REEs) has expanded the search for new REE resources. We document two types of light rare-earth element (LREE)-enriched rocks in the Khanneshin carbonatite complex of southern Afghanistan: type 1 concordant seams of khanneshite-(Ce), synchysite-(Ce), and parisite-(Ce) within banded barite-strontianite alvikite, and type 2 igneous dikes of coarse-grained carbonatite, enriched in fluorine or phosphorus, containing idiomorphic crystals of khanneshite-(Ce) or carbocernaite. Type 1 mineralized barite-strontianite alvikite averages 22.25 wt % BaO, 4.27 wt % SrO, and 3.25 wt % ∑ LREE 2 O 3 (sum of La, Ce, Pr, and Nd oxides). Type 2 igneous dikes average 14.51 wt % BaO, 5.96 wt % SrO, and 3.77 wt % ∑ LREE 2 O 3 . A magmatic origin is clearly indicated for the type 2 LREE-enriched dikes, and type 1 LREE mineralization probably formed in the presence of LREE-rich hydrothermal fluid. Both types of LREE mineralization may be penecontemporaneous, having formed in a carbonate-rich magma in the marginal zone of the central vent, highly charged with volatile constituents (i.e., CO 2 , F, P 2 O 5 ), and strongly enriched in Ba, Sr, and the LREE. Based on several assumptions, and employing simple geometry for the zone of LREE enrichment, we estimate that at least 1.29 Mt (million metric tonnes) of LREE2O3 is present in this part of the Khanneshin carbonatite complex.

Economic Geology↗

USGS1986

Palladium, platinum, and rhodium contents of rocks near the lower margin of the Stillwater complex, Montana

S Palladium, platinum, and rhodium concentrations are reported for rocks belonging to the Peridotite zone of the Ultramafic series and the Basal series of the late Archcan Stillwater Complex, a suite of Stillwater-associated sills and dikes, and the metamorphic rocks lying within the contact aureole of the complex. Mean values do not exceed 20 ppb for any rock unit and the tenth percentile rarely exceeds 200 ppb. The concentration of Pd is greater than Pt for most rock groups; both of these elements have higher concentrations than Rh.A large part of the variability in the data appears to be related to rock types containing different proportions of sulfide. It is also notable that sulfur does not correlate with the platinum-group element concentrations for many lithologies, and when it does, it commonly is not a useful predictor of platinum-group element content. Further, calculated values of R, the mass ratio of silicate liquid which has equilibrated with sulfide liquid, are low (1 to 320). Analysis of this information suggests that the immiscible sulfide liquids, from which the sulfides formed, did not completely equilibrate with the silicate liquids with respect to their platinum-group element contents and that the silicate liquids were characterized by different concentrations and ratios of platinum-group elements.

Economic Geology↗

USGS1993

Geochronology of the Sleeper deposit, Humboldt County, Nevada: Epithermal gold-silver mineralization following emplacement of a silicic flow-dome complex

The high-grade gold-silver deposits at the Sleeper mine are low sulfidation, quartz-adularia-type epithermal deposits, formed during the final stages of igneous hydrothermal activity of a small middle Miocene silicic flow-dome complex in north-central Nevada. Potassiumargon and 40 Ar/ 39 Ar ages of alkali feldspar indicate that the rhyolitic flow-dome complex was emplaced before about 16.5 Ma; hydrothermal alteration and mineralization followed, lasting from about 16.2 to 14+ Ma based on ages of adularia associated with electrum. There were multiple pulses of alteration and mineralization but all occurred within a period of less than 2 m.y. Later supergene alteration formed opal and alunite about 5.4 Ma but produced no Au or Ag mineralization other than some remobilization to produce locally rich pockets of secondary Au and Ag enrichment and is unrelated to the older magmatic hydrothermal system. The Sleeper deposit in the northern part of the Great Basin is genetically related to bimodal volcanism that followed a long period of arc-related andesitic volcanism in the same general region.

Economic Geology↗

USGS1998

The ichnologic record of the continental invertebrate invasion; evolutionary trends in environmental expansion, ecospace utilization, and behavioral complexity

The combined study of continental trace fossils and associated sedimentary facies provides valuable evidence of colonization trends and events throughout the Phanerozoic. Colonization of continental environments was linked to the exploitation of empty or under-utilized ecospace. Although the nonmarine trace fossil record probably begins during the Late Ordovician, significant invasion of nonmarine biotopes began close to the Silurian-Devonian transition with the establishment of a mobile arthropod epifauna (Diplichnites ichnoguild) in coastal marine to alluvial plain settings. Additionally, the presence of vertical burrows in Devonian high-energy fluvial deposits reflects the establishment of a stationary, deep suspension-feeding infauna of the Skolithos ichnoguild. The earliest evidence of plant-arthropod interaction occurred close to the Silurian-Devonian boundary, but widespread and varied feeding patterns are known from the Carboniferous. During the Carboniferous, permanent subaqueous lacustrine settings were colonized by a diverse, mobile detritus-feeding epifauna of the Mermia ichnoguild, which reflects a significant palaeoenvironmental expansion of trace fossils. Paleozoic ichnologic evidence supports direct routes to the land from marginal marine environments, and migration to lakes from land settings. All nonmarine sedimentary environments were colonized by the Carboniferous, and subsequent patterns indicate an increase in ecospace utilization within already colonized depositional settings. During the Permian, back-filled traces of the Scoyenia ichnoguild record the establishment of a mobile, intermediate-depth, deposit-feeding in-fauna in alluvial and transitional alluvial-lacustrine sediment. Diversification of land plants and the establishment of ecologically diverse plant communities through time provided new niches to be exploited by arthropods. Nevertheless, most ot the evolutionary feeding innovations took place relatively early, during the Late Palaeozoic or early Mesozoic. A stationary deep unfauna, the Camborygma ichnoguild, was developed in Triassic transitional alluvial-lacustrinbe deposits. Terrestrial environments hosted the rise of complex social behavioral patterns, as suggested by the probable presence of hymenopteran and isopteran nests in Triassic paleosols. An increase in diversity of trace fossils is detected in Triassic-Jurassic eolian deposits, where the ichnofauna displays more varied behavioral patterns than their Paleozoic counterparts. Also, a mobile, intermediate-depth, deposit-feeding infauna, the Vagorichnus ichnoguild, was established in deep lake environments during the Jurassic. In contrast to Paleozoic permanent subaqueous assemblages typified by surface trails, Jurassic ichnocoenoses are dominated by infaunal burrows. High density of infaunal deposit-feeding traces of the Planolites ichnoguild caused major disruption of lacustrine sedimentary fabrics during the Cretaceous. Most insect mouthpart classes, functional feeding groups, and dietary guilds were established by the end of the Cretaceous. Diversification of modern insects is recorded by the abundance and complexity of structures produced by wasps, bees, dung-beetles, and termites in Cretaceous-Tertiary paleosols. The increase in bioturbation migrated from fluvial and lake-margin settings to permanent subaqueous lacustrine environments through time.

Palaios↗

USGS2005

A universal surface complexation framework for modeling proton binding onto bacterial surfaces in geologic settings

Adsorption onto bacterial cell walls can significantly affect the speciation and mobility of aqueous metal cations in many geologic settings. However, a unified thermodynamic framework for describing bacterial adsorption reactions does not exist. This problem originates from the numerous approaches that have been chosen for modeling bacterial surface protonation reactions. In this study, we compile all currently available potentiometric titration datasets for individual bacterial species, bacterial consortia, and bacterial cell wall components. Using a consistent, four discrete site, non-electrostatic surface complexation model, we determine total functional group site densities for all suitable datasets, and present an averaged set of 'universal' thermodynamic proton binding and site density parameters for modeling bacterial adsorption reactions in geologic systems. Modeling results demonstrate that the total concentrations of proton-active functional group sites for the 36 bacterial species and consortia tested are remarkably similar, averaging 3.2 ?? 1.0 (1??) ?? 10-4 moles/wet gram. Examination of the uncertainties involved in the development of proton-binding modeling parameters suggests that ignoring factors such as bacterial species, ionic strength, temperature, and growth conditions introduces relatively small error compared to the unavoidable uncertainty associated with the determination of cell abundances in realistic geologic systems. Hence, we propose that reasonable estimates of the extent of bacterial cell wall deprotonation can be made using averaged thermodynamic modeling parameters from all of the experiments that are considered in this study, regardless of bacterial species used, ionic strength, temperature, or growth condition of the experiment. The average site densities for the four discrete sites are 1.1 ?? 0.7 ?? 10-4, 9.1 ?? 3.8 ?? 10-5, 5.3 ?? 2.1 ?? 10-5, and 6.6 ?? 3.0 ?? 10-5 moles/wet gram bacteria for the sites with pKa values of 3.1, 4.7, 6.6, and 9.0, respectively. It is our hope that this thermodynamic framework for modeling bacteria-proton binding reactions will also provide the basis for the development of an internally consistent set of bacteria-metal binding constants. 'Universal' constants for bacteria-metal binding reactions can then be used in conjunction with equilibrium constants for other important metal adsorption and complexation reactions to calculate the overall distribution of metals in realistic geologic systems.

American Journal of Science↗