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Effects of highway deicing chemicals on shallow unconsolidated aquifers in Ohio — Final report

As a result of concerns about salt intrusion into drinking water aquifers, the effects of highway deicing chemicals on shallow aquifers were studied at eight locations in Ohio from 1988 through 2002. The study was done by the U.S. Geological Survey, in cooperation with the Ohio Department of Transportation and the Federal Highway Administration. Sites were selected along major undivided highways where drainage is by open ditches and ground-water flow is approximately perpendicular to the highway. Records of deicer application rates were kept, and apparent movement of deicing chemicals through shallow, unconsolidated aquifers was monitored by means of periodic measurements of specific conductance and concentrations of dissolved sodium, calcium, and chloride. The State routes monitored were the following: State Route (SR) 3 in Ashland County, SR 84 in Ashtabula County, SR 29 in Champaign County, SR 4 in Clark County, SR 2 in Lucas County, SR 104 in Pickaway County, SR 14 in Portage County, and SR 97 in Richland County. The study began in 1988 with background data collection, extensive literature review, and site selection. This process, including drilling of wells at numerous test sites and the eight selected sites, lasted 3 years. Routine groundwater sampling at 4- to 6-week intervals began in January 1991 and continued through September 1999. A multilevel, passive flow ground-water sampling device was constructed and used. Other conditions monitored on a regular basis included ground-water level (monitored continuously), specific conductance, air and soil temperature, precipitation,chloride concentration in soil samples, and deicing-chemical application times and rates. Evidence from water analysis, specific-conductance measurements, and surface-geophysical measurements indicates that three of the eight sites (Ashtabula County, Lucas County, and Portage County sites) were affected by direct application of deicing chemicals. Climatic data collected during the study show that cold weather, and therefore deicing-chemical application rates, varied from south to north across the State. As a consequence, only minor traces of dissolved chloride (mean, 24–43 mg/L (milligrams per liter)) above background concentrations (mean, 13–23 mg/L) were determined in ground-water samples from the southernmost sites (approximately 3930' to 40 N latitude—Champaign County, Clark County, and Pickaway County). At the Ashland and Richland County sites (approximately 4030' N latitude), dissolved-chloride concentrations increased above background concentrations only intermittently (mean background concentrations 4–41 mg/L, rising to a mean of 40–56 mg/L in downgradient wells). At the northernmost sites (41 30' to 42 N latitude—Lucas County, Portage County, and Ashtabula County), deicing-chemical application was consistent throughout the winter, and downgradient dissolved-chloride concentrations (mean, 124–345 mg/L) rarely returned to background concentrations (mean, 7–37 mg/L) throughout the study period. Other factors than application rate that may affect the movement of deicing chemicals through an aquifer were precipitation amounts, the types of subsurface materials, ground-water velocity and gradient, hydraulic conductivity, soil type, land use, and Ohio Department of Transportation deicing priority.

Ohio

Baseline water quality of an area undergoing shale-gas development in the Muskingum River watershed, Ohio, 2015–16

In 2015–16, the U.S. Geological Survey, in cooperation with the Muskingum Watershed Conservancy District, led a study to assess baseline (2015–16) surface-water quality in six lake drainage basins within the Muskingum River watershed that are in the early years of shale-gas development. In 2015, 9 of the 10 most active counties in Ohio for oil and gas development were wholly or partially within the Muskingum River watershed. In addition to shale gas development, the area has a history of conventional oil and gas development and coal mining. In all, 30 surface-water sites were sampled: 20 in tributaries flowing to the lakes, 4 in lakes themselves, and 6 downstream of the lakes. At each of the 30 sites, 6 samples were collected to characterize surface-water chemistry throughout a range of hydrologic conditions. The sampling generally occurred during low flows (periods of greater groundwater contribution) rather than during runoff events (periods of high stream stage). Trilinear diagrams of major ion chemistry revealed three main types of water in the study area―sulfate-dominated waters, bicarbonate-dominated waters, and waters with mixed bicarbonate and chloride anions. Most sites produced samples of bicarbonate-dominated water, and 11 sites produced samples with sulfate-type waters. Mixed bicarbonate and chloride waters were found in samples from two of the six lake drainage basins studied. The baseline (2015–16) assessment of surface-water quality in the study area indicated that few water-chemistry constituents and properties occurred at concentrations or levels that would adversely affect aquatic organisms. Chemical-specific, aquatic life use criteria were not met in only three instances: two were for total dissolved solids at sites likely impacted by coal mining in their drainage basins (hereafter referred to as “mine-impacted sites”), and one was for dissolved oxygen. Mine drainage from historical coal mining in the region likely affected the quality of about one-third of the streams sampled. To simplify interpretation of water-chemistry results, 11 sites with sulfate-type water were identified as mine-impacted sites based on water-quality criteria established by Ohio Department of Natural Resources, Division of Mineral Resources Management, and separated out for subsequent statistical analysis. Concentrations or levels of bicarbonate, boron, calcium, carbonate, total dissolved solids, fluoride, magnesium, lithium, pH, potassium, sodium, specific conductance, strontium, sulfate, and suspended sediment in water were higher (significance level of 0.05) at mine-impacted stream sites than at non-mine-impacted stream sites. An accidental release of oil- and gas-related brines could increase salinity (sodium and chloride), the concentration of total dissolved solids in shallow groundwater and streams, and specific conductance. For this study, chloride concentrations in the study area ranged from 2.12 to 76.1 milligrams per liter. Sources of chloride in water samples were evaluated using binary mixing curves and ratios of chloride to bromide. These ratios indicated that 13 samples from 3 sites in the drainage basin that contained the highest density of conventional oil and gas wells in the study, as well as 4 samples collected from other drainage basins, likely contained a component of brine. Concentrations or levels of barium, bromide, chloride, iron, lithium, manganese, and sodium were significantly higher (alpha = 0.05) in samples with a component of brine than in samples without a component of brine. Benzene, toluene, ethylbenzene and xylene (BTEX), compounds that occur naturally in crude oil, made up 24 of the 45 detections (53 percent) of volatile organic compounds in the study area. The BTEX detections were not associated with sites containing a component of brine. The only volatile organic compound detected in any of the 17 samples that contained a component of brine was acetone, detected in 3 (18 percent) of these samples and in 11 percent of samples not containing a component of brine. Considering that BTEX are gasoline hydrocarbons and that most of the detections occurred during warmer months in and around the lakes, the BTEX detections likely are associated with increases in outdoor activities such as automobile and boating traffic. Radium-226 and radium-228 were included in the list of analytes for this study because production water from shale-gas drilling can contain these naturally occurring radioactive materials. Concentrations of radium-226 exceeded background levels in only two surface-water samples. Concentrations of radium-228 exceeded background levels in one surface-water sample. A brine signature potentially indicative of oil and gas contamination was detected in samples collected at two sites that contained active or plugged waste injection wells, or both. Results from the study indicated significant differences in the median concentrations of bromide, chloride, lithium, manganese, sodium, and total dissolved nitrogen between sites with and without injection wells in their drainage areas. Median concentrations of bromide, chloride, lithium, and sodium, which are common oil- and gas-related contaminants, were higher at sites with injection wells in their drainage areas compared to sites without injection wells. Historical (1960s, 1970s, and 1980s) chloride concentrations and streamflow data at or near five of the six sampling sites downstream from each lake dam were compared to current (2015–16) values. An analysis of covariance was done to test the effects of streamflow, time (decade), and the combined effects (cross product) of streamflow and time on chloride concentrations. Those analyses indicated that streamflow was not significant in explaining the variation in chloride concentration, likely because streamflow in those locations is controlled by dam operations; therefore, association between runoff-generating events and streamflow is less direct than in unregulated streams. From the 1980s to the study period (2015–16), data for three of the five lakes indicated an increase in chloride concentrations. The comparison of historical and current (2015–16) study data from samples collected at another lake indicated that chloride concentrations increased from the 1960s to the 1970s, but concentrations in the 1970s and 2015–16 were similar even though 13 samples from this lake drainage basin were classified as having a component of brine. Median chloride concentrations for the fifth lake, however, seemed to decrease from the 1980s to 2015–16.

Ohio

Completion summary for boreholes USGS 140 and USGS 141 near the Advanced Test Reactor Complex, Idaho National Laboratory, Idaho

In 2013, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, drilled and constructed boreholes USGS 140 and USGS 141 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory in southeast Idaho. Borehole USGS 140 initially was cored to collect continuous geologic data, and then re-drilled to complete construction as a monitor well. Borehole USGS 141 was drilled and constructed as a monitor well without coring. Boreholes USGS 140 and USGS 141 are separated by about 375 feet (ft) and have similar geologic layers and hydrologic characteristics based on geophysical and aquifer test data collected. The final construction for boreholes USGS 140 and USGS 141 required 6-inch (in.) diameter carbon-steel well casing and 5-in. diameter stainless-steel well screen; the screened monitoring interval was completed about 50 ft into the eastern Snake River Plain aquifer, between 496 and 546 ft below land surface (BLS) at both sites. Following construction and data collection, dedicated pumps and water-level access lines were placed to allow for aquifer testing, for collecting periodic water samples, and for measuring water levels. Borehole USGS 140 was cored continuously, starting from land surface to a depth of 543 ft BLS. Excluding surface sediment, recovery of basalt and sediment core at borehole USGS 140 was about 98 and 65 percent, respectively. Based on visual inspection of core and geophysical data, about 32 basalt flows and 4 sediment layers were collected from borehole USGS 140 between 34 and 543 ft BLS. Basalt texture for borehole USGS 140 generally was described as aphanitic, phaneritic, and porphyritic; rubble zones and flow mold structure also were described in recovered core material. Sediment layers, starting near 163 ft BLS, generally were composed of fine-grained sand and silt with a lesser amount of clay; however, between 223 and 228 ft BLS, silt with gravel was described. Basalt flows generally ranged in thickness from 3 to 76 ft (average of 14 ft) and varied from highly fractured to dense with high to low vesiculation. Geophysical and borehole video logs were collected during certain stages of the drilling and construction process at boreholes USGS 140 and USGS 141. Geophysical logs were examined synergistically with the core material for borehole USGS 140; additionally, geophysical data were examined to confirm geologic and hydrologic similarities between boreholes USGS 140 and USGS 141 because core was not collected for borehole USGS 141. Geophysical data suggest the occurrence of fractured and (or) vesiculated basalt, dense basalt, and sediment layering in both the saturated and unsaturated zones in borehole USGS 141. Omni-directional density measurements were used to assess the completeness of the grout annular seal behind 6-in. diameter well casing. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement at all depths in boreholes USGS 140 and USGS 141. Single-well aquifer tests were done following construction at wells USGS 140 and USGS 141 and data examined after the tests were used to provide estimates of specific-capacity, transmissivity, and hydraulic conductivity. The specific capacity, transmissivity, and hydraulic conductivity for well USGS 140 were estimated at 2,370 gallons per minute per foot [(gal/min)/ft)], 4.06 × 105 feet squared per day (ft 2 /d), and 740 feet per day (ft/d), respectively. The specific capacity, transmissivity, and hydraulic conductivity for well USGS 141 were estimated at 470 (gal/min)/ft, 5.95 × 104 ft 2 /d, and 110 ft/d, respectively. Measured flow rates remained relatively constant in well USGS 140 with averages of 23.9 and 23.7 gal/min during the first and second aquifer tests, respectively, and in well USGS 141 with an average of 23.4 gal/min. Water samples were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples from both wells indicated that concentrations of tritium, sulfate, and chromium were affected by wastewater disposal practices at the Advanced Test Reactor Complex. Most constituents in water from wells USGS 140 and USGS 141 had concentrations similar to concentrations in well USGS 136, which is upgradient from wells USGS 140 and USGS 141.

Idaho

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

Water resources of the Iroquois National Wildlife Refuge, Genesee and Orleans counties, New York 2008-2010

A 2-year study of the water resources of the Iroquois National Wildlife Refuge (Refuge) in western New York was carried out in 2009-2010 in cooperation with the U.S. Fish and Wildlife Service to assist the Refuge in the development of a 15-year Comprehensive Conservtion plan. The study focused on Oak Orchard Creek, which flows through the Refuge, the groundwater resources that underlie the Refuge, and the possible changes to these resources related to the potential development of a bedrock quarry along the northern side of the Refuge. Oak Orchard Creek was monitored seasonally for flow and water quality; four tributary streams, which flowed only during early spring, also were monitored. A continuous streamgage was operated on Oak Orchard Creek, just north of the Refuge at Harrison Road. Four bedrock wells were drilled within the Refuge to determine the type and thickness of unconsolidated glacial sediments and to characterize the thickness and type of bedrock units beneath the Refuge, primarily the Lockport Dolomite. Water levels were monitored in 17 wells within and adjacent to the Refuge and water-quality samples were collected from 11 wells and 6 springs and analyzed for physical properties, nutrients, major ions, and trace metals. Flow in Oak Orchard Creek is from two different sources. During spring runoff, flow from the Onondaga Limestone Escarpment, several miles south of the Refuge, supplements surface-water runoff and groundwater discharge from the Salina Group to the south and east of the Refuge. Flow to Oak Orchard Creek also comes from surface-water runoff from the Lockport Dolomite Escarpment, north of the Refuge, and from groundwater discharging from the Lockport Dolomite and unconsolidated deposits that overlie the Lockport Dolomite. During the summer and fall low-flow period, only small quantities of groundwater flow from the Salina shales and Lockport Dolomite bedrock and the unconsolidated sediments that overlie them; most of this flow is lost to wetland evapotranspiration, and the remainder enters Oak Orchard Creek. Water quality in the Oak Orchard Creek is affected not only by these groundwater sources but also by surface runoff from agricultural areas and the New York State Wildlife Management Area east of the Refuge. Based on the results of the drilling program, the Lockport Dolomite underlies nearly all the Refuge. The Refuge wetlands lie within a bedrock trough between the Lockport Dolomite and Onondaga Limestone Escarpments, to the north and south, respectively. This bedrock trough was filled with mostly fine-grained sediments when Glacial Lake Tonawanda was present following the last period of glaciation. These fine-grained sediments became the substrate on which the wetlands were formed along Oak Orchard Creek and nearby Tonawanda Creek, to the south and west. Water quality in the unconsolidated and bedrock aquifers is variable; poor quality water (sulfide-rich "black water") generally is present south of Oak Orchard Creek and better quality water to the north where the Lockport Dolomite is close to the land surface. A set of springs, the Oak Orchard Acid Springs, is present within the Refuge; the springs are considered unique in New York State because of their naturally low pH (approximately 2.0) and their continual discharge of natural gas. The potential development of a bedrock quarry in the Lockport Dolomite bedrock along the northern border of the Refuge may affect the nearby Refuge wetlands. The extent of drawdown needed to actively quarry the bedrock could change the local hydrology and affect groundwater-flow directions and rates, primarily in the Lockport Dolomite bedrock and possibly the Oak Orchard Acid Springs area, farther to the south. The effect on the volume of flow in Oak Orchard Creek would probably be minimal as a result of the poor interaction between the surface-water and the groundwater systems. Of greater potential effect will be the possible change in the quality of water flowing into the Refuge from the discharge of groundwater during dewatering operations at the quarry; this discharge will flow into the northern part of the Refuge and affect the quantity and quality of wetland areas downstream from the quarry discharge. These changes may affect wetland management activities because of the potential for poorquality water to affect the ecology of the wetlands and the wildlife that use these wetlands.

New York

Compilation of geologic, hydrologic, and ground-water flow modeling information for the Spokane Valley-Rathdrum Prairie aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington Department of Ecology compiled and described geologic, hydrologic, and ground-water flow modeling information about the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, ground- and surface-water interactions, computer flow models, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho and the Spokane valley and Hillyard Trough, Washington, was designated a Sole Source Aquifer by the U.S. Environmental Protection Agency in 1978. Continued growth, water management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer is composed of sand, gravel, cobbles, and boulders primarily deposited by a series of catastrophic glacial outburst floods from ancient Glacial Lake Missoula. The material deposited in this high-energy environment is coarser-grained than is typical for most basin-fill deposits, resulting in an unusually productive aquifer with well yields as high as 40,000 gallons per minute. In most places, the aquifer is bounded laterally by bedrock composed of granite, metasedimentary rocks, or basalt. The lower boundary of the aquifer is largely unknown except along the margins or in shallower parts of the aquifer where wells have penetrated its entire thickness and reached bedrock or silt and clay deposits. Based on surface geophysics, the thickness of the aquifer is about 500 ft near the Washington-Idaho state line, but more than 600 feet within the Rathdrum Prairie and more than 700 feet in the Hillyard trough based on drilling records. Depth to water in the aquifer is greatest in the northern Rathdrum Prairie (about 500 feet) and least near the city of Spokane along the Spokane River (less than about 50 feet). Ground-water flow is south from near the southern end of Lake Pend Oreille and Hoodoo Valley, through the Rathdrum Prairie, then west toward Spokane. In Spokane, the aquifer splits and water moves north through the Hillyard Trough as well as west through the Trinity Trough. From the Trinity Trough water flows north along the western arm of the aquifer. The aquifer's discharge area is along the Little Spokane River and near Long Lake, Washington. A compilation of estimates of water-budget components, including recharge (precipitation, irrigation, canal leakage, septic tank effluent, inflow from tributary basins, and flow from the Spokane River) and discharge (withdrawals from wells, flow to the Spokane and Little Spokane Rivers, evapotranspiration, and underflow to Long Lake) illustrates that these estimated values should be compared with caution due to several variables including the area and time period of interest as well as methods employed in making the estimates. Numerous studies have documented the dynamic ground-water and surface-water interaction between the SVRP aquifer and the Spokane and Little Spokane Rivers. Gains and losses vary throughout the year, as well as the locations of gains and losses. September 2004 streamflow measurements indicated that the upper reach of the Spokane River between Post Falls and downstream at Flora Road lost 321 cubic feet per second. A gain of 736 cubic feet per second was measured between the Flora Road site and downstream at Green Street Bridge. A loss of 124 cubic feet per second was measured for the reach between the Green Street Bridge and the Spokane River at Spokane gaging station. The river gained about 87 cubic feet per second between the Spokane River at Spokane gaging station and the TJ Meenach Bridge. Overall, the Spokane River gained about 284 cubic feet per second between the Post Falls,

Scientific Investigations Report

Tectonic setting and metallogenesis of volcanogenic massive sulfide deposits in the Bonnifield Mining District, Northern Alaska Range: Chapter B in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

This paper summarizes the results of field and laboratory investigations, including whole-rock geochemistry and radiogenic isotopes, of outcrop and drill core samples from volcanogenic massive sulfide (VMS) deposits and associated metaigneous rocks in the Wood River area of the Bonnifield mining district, northern Alaska Range (see fig. 1 of Editors’ Preface and Overview). U-Pb zircon igneous crystallization ages from felsic rocks indicate a prolonged period of Late Devonian to Early Mississippian (373±3 to 357±4 million years before present, or Ma) magmatism. This magmatism occurred in a basinal setting along the ancient Pacific margin of North America. The siliceous and carbonaceous compositions of metasedimentary rocks, Precambrian model ages based on U-Pb dating of zircon and neodymium ages, and for some units, radiogenic neodymium isotopic compositions and whole-rock trace-element ratios similar to those of continental crust are evidence for this setting. Red Mountain (also known as Dry Creek) and WTF, two of the largest VMS deposits, are hosted in peralkaline metarhyolite of the Mystic Creek Member of the Totatlanika Schist. The Mystic Creek Member is distinctive in having high concentrations of high-field-strength elements (HFSE) and rare-earth elements (REE), indicative of formation in a within-plate (extensional) setting. Mystic Creek metarhyolite is associated with alkalic, within-plate basalt of the Chute Creek Member; neodymium isotopic data indicate an enriched mantle component for both members of this bimodal (rhyolite-basalt) suite. Anderson Mountain, the other significant VMS deposit, is hosted by the Wood River assemblage. Metaigneous rocks in the Wood River assemblage span a wide compositional range, including andesitic rocks, which are characteristic of arc volcanism. Our data suggest that the Mystic Creek Member likely formed in an extensional, back-arc basin that was associated with an outboard continental-margin volcanic arc that included rocks of the Wood River assemblage. We suggest that elevated HFSE and REE trace-element contents of metavolcanic rocks, whose major-element composition may have been altered, are an important prospecting tool for rocks of VMS deposit potential in east-central Alaska.

Alaska;Yukon

Conceptual model to assess water use associated with the life cycle of unconventional oil and gas development

As the demand for energy increases in the United States, so does the demand for water used to produce many forms of that energy. Technological advances, limited access to conventional oil and gas accumulations, and the rise of oil and gas prices resulted in increased development of unconventional oil and gas (UOG) accumulations. Unconventional oil and gas is developed using a method that combines directional drilling and hydraulic fracturing techniques, allowing for greater oil and gas production from previously unrecoverable reservoirs. Quantification of the water resources required for UOG development and production is difficult because of disparate data sources, variable reporting requirements across boundaries (local, State, and national), and incomplete or proprietary datasets. A topical study was started in 2015 under the U.S. Geological Survey’s Water Availability and Use Science Program, as part of the directive in the Secure Water Act for the U.S. Geological Survey to conduct a National Water Census, to better understand the relation between production of UOG resources for energy and the amount of water needed to produce and sustain this type of energy development in the United States. The Water Availability and Use Science Program goal for this topical study is to develop and apply a statistical model to better estimate the water use associated with UOG development, regardless of the location and target geologic formation. As a first step, a conceptual model has been developed to characterize the life cycle of water use in areas of UOG development. Categories of water use and the way water-use data are collected might change over time; therefore, a generic approach was used in developing the conceptual model to allow for greater flexibility in adapting to future changes or newly available data. UOG development can be summarized into four stages: predrilling construction, drilling, hydraulic fracturing, and ongoing production. The water used in UOG production can be categorized further as direct, indirect, or ancillary water use. Direct water use is defined as the water used for drilling and hydraulic fracturing a well and for maintaining the well during ongoing production. Indirect water use is defined as the water used at or near a well pad. The water used for dust abatement also is considered an indirect use but may be applied away from the well pad. Ancillary water use is defined as the additional local or regional water use resulting from a change (for example, population) directly related to UOG development throughout the life cycle that is not used directly in the well or indirectly for any other purpose at the well pad. The conceptual model presented in this report consists of five elements: (1) input data, (2) processes, (3) decisions, (4) output data, and (5) outcomes. The input data requirements for estimating water use associated with UOG development are somewhat onerous, and obtaining suitable datasets can be challenging because local, State, and Federal agencies do not collect data similarly. The quality of a water-use assessment that uses the conceptual model presented in this report is dependent on the quality and quantity of data that are available for a UOG play. The conceptual model can be used for an assessment with sparse data; however, having sparse data likely will result in greater uncertainty in the water-use estimates. The conceptual model presented in this report is designed to be robust to characterize and simulate the data processing to estimate water use associated with UOG development. Although the results of an analysis that includes missing data have greater uncertainty, the analysis still can be insightful because it can establish a baseline estimate of UOG water use that may be refined further as more data become available. Analysis of models that include missing data also could aid in identifying the data most needed for future water-use estimates. Characterizing individual model limitations is important because the conceptual model can be used in future water-use studies to facilitate data compiling, data processing, estimating, and assessing UOG activities regardless of location.

Scientific Investigations Report

Hydrogeology of the West Branch Delaware River basin, Delaware County, New York

In 2009, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, began a study of the hydrogeology of the West Branch Delaware River (Cannonsville Reservoir) watershed. There has been recent interest by energy companies in developing the natural gas reserves that are trapped within the Marcellus Shale, which is part of the Hamilton Group of Devonian age that underlies all the West Branch Delaware River Basin. Knowing the extent and thickness of stratified-drift (sand and gravel) aquifers within this basin can help State and Federal regulatory agencies evaluate any effects on these aquifers that gas-well drilling might produce. This report describes the hydrogeology of the 455-square-mile basin in the southwestern Catskill Mountain region of southeastern New York and includes a detailed surficial geologic map of the basin. Analysis of surficial geologic data indicates that the most widespread surficial geologic unit within the basin is till, which is present as deposits of ablation till in major stream valleys and as thick deposits of lodgment till that fill upland basins. Till and colluvium (remobilized till) cover about 89 percent of the West Branch Delaware River Basin, whereas stratified drift (outwash and ice-contact deposits) and alluvium account for 8.9 percent. The Cannonsville Reservoir occupies about 1.9 percent of the basin area. Large areas of outwash and ice-contact deposits occupy the West Branch Delaware River valley along its entire length. These deposits form a stratified-drift aquifer that ranges in thickness from 40 to 50 feet (ft) in the upper West Branch Delaware River valley, from 70 to 140 ft in the middle West Branch Delaware River valley, and from 60 to 70 ft in the lower West Branch Delaware River valley. The gas-bearing Marcellus Shale underlies the entire West Branch Delaware River Basin and ranges in thickness from 600 to 650 ft along the northern divide of the basin to 750 ft thick along the southern divide. The depth to the top of the Marcellus Shale ranges from 3,240 ft along the northern basin divide to 4,150 ft along the southern basin divide. Yields of wells completed in the aquifer are as high as 500 gallons per minute (gal/min). Springs from fractured sandstone bedrock are an important source of domestic and small municipal water supplies in the West Branch Delaware River Basin and elsewhere in Delaware County. The average yield of 178 springs in Delaware County is 8.5 gal/min with a median yield of 3 gal/min. An analysis of two low-flow statistics indicates that groundwater contributions from fractured bedrock compose a significant part of the base flow of the West Branch Delaware River and its tributaries.

New York

Lithostratigraphic, geophysical, and hydrogeologic observations from a boring drilled to bedrock in glacial sediments near Nantucket Sound in East Falmouth, Massachusetts

In spring 2016, a 310-foot-deep boring (named MA–FSW 750) was drilled by the U.S. Geological Survey near Nantucket Sound in East Falmouth, Massachusetts, to investigate the hydrogeology of the southern coast of western Cape Cod. Few borings that are drilled to bedrock exist in the area, and the study area was selected to fill a gap between comprehensive geologic datasets inland to the north and marine geophysical data from beneath Nantucket Sound to the south. A permanent monitoring well (MA–FSW 750–0100) was installed in the boring upon the completion of the drilling and core collection. Observations from sediment cores and surface and borehole geophysical measurements were used to delineate three zones relevant to understanding groundwater flow at the study location. Shallow sands and gravels (0–107 feet [ft] below land surface [bls]) underlain by silt-rich fine and very fine sand (107–175 ft bls) form a zone of high permeability underlain by a zone of relatively lower permeability, referred to as the “shallow high-permeability” and “low-permeability” zones, respectively. A sharp lithological contact separating the shallow high-permeability and low-permeability zones may affect vertical flow of groundwater. Fine to coarse sand with intervals of clay and silt from 175 to 300 ft bls represent a deep zone of relatively high permeability, referred to as the “deep high-permeability” zone. A compacted, nonsorted unit (identified as basal till) and the bedrock surface were encountered at 300 and 305 ft bls, respectively. Hydraulic conductivity estimates from nuclear magnetic resonance logs and sediment grain-size distribution analyses indicated that the shallow high-permeability zone contributes substantially to the capacity of the aquifer to transmit groundwater at the study location. Results from geophysical surveys indicate a gradual transition from fresh to saline groundwater in the interval from 105 to 160 ft bls. Freshwater at the study site is present in the saturated unconsolidated sediments only in the 75 ft between 30 ft (the water table) and 105 ft bls in the shallow high-permeability zone. Sediments shallower than 175 ft bls closely resemble the downward fining post-Wisconsinan age deltaic and lacustrine deposits present in many parts of western Cape Cod; sediments deeper than 175 ft appear to be the product of earlier depositional processes more local to the southern coast of western Cape Cod. This study highlights how high-resolution observations of cored material coupled with a multitool geophysical approach can characterize a single boring to help better understand regional glacial history and hydrogeology.

Massachusetts

Transmissivity of the Upper Floridan aquifer in Florida and parts of Georgia, South Carolina, and Alabama

The Floridan aquifer system (FAS) covers an area of approximately 100,000 square miles in Florida and parts of Georgia, South Carolina, Alabama, and Mississippi. Groundwater wells for water supply were first drilled in the late 1800s and by the year 2000, the FAS was the primary source of drinking water for about 10 million people. One of the methods for assessing groundwater availability is the development of regional or subregional groundwater flow models of the aquifer system that can be used to develop water budgets spatially and temporally, as well as evaluate the groundwater resource change over time. Understanding the distribution of transmissivity within the FAS is critical to the development of groundwater flow models. The map presented herein differs from previously published maps of the FAS in that it is based on interpolation of 1,487 values of transmissivity. The transmissivity values in the dataset range from 8 to 9,000,000 feet squared per day (ft 2 /d) with the majority of the values ranging from 10,000 to 100,000 ft 2 /d. The wide range in transmissivity (6 orders of magnitude) is typical of carbonate rock aquifers, which are characterized by a wide range in karstification. Commonly, the range in transmissivity is greatest in areas where groundwater flow creates conduits in facies that dissolve more readily or areas of high porosity units that have interconnected vugs, with diameters greater than 0.1 foot. These are also areas where transmissivity is largest. Additionally, first magnitude springsheds and springs are shown because in these springshed areas, the estimates of transmissivity from interpolation may underestimate the actual range in transmissivity. Also shown is an area within the Gulf Trough in Georgia where high yielding wells are unlikely to be developed in the Upper Floridan aquifer. The interpolated transmissivity ranges shown on this map reflect the geologic structure and karstified areas. Transmissivity is large in the areas where the system is unconfined, such as west-central Florida and southwest Georgia just northwest of the Gulf Trough. Transmissivity is small along the Gulf Trough and Southwest Georgia Embayment (referred to as Apalachicola Embayment in some reports). Transmissivity is also small in the thin, updip part of the system near its northern boundary. Another area of large transmissivity coincides with the Southeast Georgia Embayment.

Alabama, Florida, Georgia, South Carolina

Private Domestic-Well Characteristics and the Distribution of Domestic Withdrawals among Aquifers in the Virginia Coastal Plain

A comprehensive analysis of private domestic wells and self-supplied domestic ground-water withdrawals in the Coastal Plain Physiographic Province of Virginia indicates that the magnitudes of these withdrawals and their effects on local and regional ground-water flow are larger and more important than previous reports have stated. Self-supplied ground-water withdrawals for domestic use in the Virginia Coastal Plain are estimated to be approximately 40 million gallons per day, or about 28 percent of all ground-water withdrawals in the area. Contrary to widely held assumptions, only 22 percent of domestic wells in the Virginia Coastal Plain are completed in the shallow, unconfined surficial aquifer to which the water is returned directly by home septic systems. Fifty-three percent of the wells are completed in six deeper confined aquifers, and the remaining 25 percent are completed in the Potomac aquifer and confining zone, the deepest units in the confined system. Assuming an equal rate of withdrawal per well, 78 percent of domestic ground-water withdrawal, or about 30 million gallons per day, is removed from the regional confined ground-water system. Domestic ground-water withdrawal from an estimated 200,000 private wells supplies more than 15 percent of the population of the area and provides almost the entire source of water in some rural counties. The geographic distribution of these withdrawals is dependent on the self-supplied population and is highly variable. Domestic-well characteristics vary spatially as well, primarily because of geographic differences in depths to particular aquifers, but also because of well-drilling practices that are influenced by geographic, regulatory, and socioeconomic factors. Domestic ground-water withdrawals in the Virginia Coastal Plain were characterized as part of a larger study to analyze the regional ground-water flow system. Characterizing the withdrawals required differentiation of the withdrawals among the aquifers in the area in addition to determination of the geographic distribution of the withdrawals. Because of a lack of comprehensive data on private-well construction and distribution, a sample of private domestic-well records was used to estimate well characteristics and approximate the proportion of wells and withdrawals associated with each aquifer. Construction data on 2,846 private domestic wells were collected from 29 counties and independent cities (localities) having appreciable self-supplied populations and representing private domestic withdrawals of about 31 million gallons per day. Within each locality, geographically stratified random sampling of well records by tax plat characterized details of well construction for the population of domestic wells. Because neither specific location data nor aquifer elevations were available for individual wells, the primary aquifer in which each well is completed was estimated by cross-referencing the screen elevation estimated from the well record with a generalized configuration of hydrogeologic units underlying the locality in which the well is located. For each locality, summarizing the results of this process allowed the determination of the proportion of wells and withdrawals associated with each aquifer. Additional evaluation of spatial data was used to apply the domestic withdrawal rates developed for each aquifer in each locality to a detailed ground-water study of the portion of the Virginia Coastal Plain east of the Chesapeake Bay, which is known as the Eastern Shore Peninsula. Because domestic withdrawal estimates are based on the self-supplied population, the geographic distribution of withdrawals within each of the Eastern Shore counties was estimated by using population data from the 2000 U.S. Census at the resolution of census block groups and further refining the distribution based on road density. The allocation of withdrawals among aquifers was then determined by cross-referencing the spatial distribut

Scientific Investigations Report

Geophysical log analysis of selected test and residential wells at the Shenandoah Road National Superfund Site, East Fishkill, Dutchess County, New York

The U.S. Geological Survey collected and analyzed geophysical logs from 20 test wells and 23 residential wells at the Shenandoah Road National Superfund Site in East Fishkill, New York, from 2006 through 2010 as part of an Interagency Agreement to provide hydrogeologic technical support to the U.S. Environmental Protection Agency, Region 2. The geophysical logs collected include caliper, gamma, acoustic and optical televiewer, deviation, electromagnetic-induction, magnetic-susceptibility, fluid-property, and flow under ambient and pumped conditions. The geophysical logs were analyzed along with single-well aquifer test data and drilling logs to characterize the lithology, fabric, fractures, and flow zones penetrated by the wells. The results of the geophysical log analysis were used as part of the hydrogeologic characterization of the site and in the design of discrete-zone monitoring installations in the test wells and selected residential wells. Most of the logged test and residential wells penetrated gneiss of the Hudson Highlands Complex or dolostones in the Wappinger Group, and some wells penetrated both the dolostone and gneiss. The bedrock fabric reflects the regional northeast-southwest structural trend, as well as localized folding, and includes foliation in the gneiss and bedding in the dolostone. Many fractures were oriented along the bedrock fabric, whereas others were orthogonal to the fabric. Total wellbore transmissivity of the wells was estimated from short-term, single-well aquifer test data through the use of the Cooper-Jacob analytical solution. An empirical relation was established to estimate total wellbore transmissivity from specific-capacity data for wells with insufficient transient drawdown measurements. Wellbore transmissivity estimates ranged from 0.36 to 370 feet squared per day (ft 2 /d), whereas specific capacities ranged from 0.03 to 2.1 gallons per minute per foot ((gal/min)/ft). Transmissivity and hydraulic heads of individual fracture zones were estimated from the total wellbore transmissivity and flow logs through use of an analytical model based on the Thiem equation. The model-estimated transmissivity of 95 fracture zones delineated in the 43 wells ranged from 0.25 to 340 ft 2 /d, with a median value of 6.7 ft 2 /d. The difference between model-estimated fracture-zone heads and the composite heads in each well ranged from less 0.01 to more than 10 feet (ft). Flow-log analysis generally provided an order of magnitude estimate for the fracture-zone hydraulic-head difference on the basis of a comparison of estimated and measured values. The geophysical logs and their analyses are available for display and download from the U.S. Geological Survey, New York Water Science Center, online geophysical log archive ( http://ny.water.usgs.gov/maps/geologs/ ) in LAS (Log ASCII Standard), PDF, and WellCad formats.

New York

Distribution of selected hydrogeologic characteristics of the upper glacial and Magothy aquifers, Long Island, New York

The Pleistocene- and Cretaceous-age sediments underlying Long Island, New York, compose an important sole-source aquifer system that is nearly 2,000 feet thick in some areas. Sediment characteristics of importance for water supply include water-transmitting properties—horizontal and vertical hydraulic conductivity—and the distribution of lignite, which provides an important control on oxygen-reduction (redox) conditions and water quality, in Cretaceous-age aquifers. Several decades of urbanization and the associated need to meet water demand have generated abundant data on the lithology of the aquifer sediments and the potential for an improved regional-scale understanding of this aquifer system. There is a range in the source and quality of the information, but large amounts of data, even of lesser quality, can yield insight into important aquifer characteristics. The distribution of the horizontal and vertical hydraulic conductivity and the probability of occurrence of lignite and clay in the aquifer were developed for this study from a database of drilling records and geophysical logs. Lithologic descriptions were categorized into a set of standardized codes, which in turn, were aggregated into a set of general codes for the Pleistocene-age upper glacial and Cretaceous-age Magothy aquifers. General values of hydraulic conductivity were assigned to each code from published estimates on Long Island and analogous hydrogeologic environments on Cape Cod, Massachusetts. A binary value of 1 or 0 was assigned to each coded interval to indicate the presence or absence of lignite or based on keywords in the lithologic descriptions. This information was assembled into a geographic information system database that was queried sequentially and used to develop gridded values of each aquifer characteristic by use of ordinary kriging for a set of grids, each representing 10-foot-thick planar slices for the entire vertical thickness of each aquifer. These sets of grids, taken as a whole, represent a quasi-three-dimensional representation of each aquifer characteristic in both the upper glacial and Magothy aquifers. The analysis of hydraulic conductivity shows patterns that generally reflect known depositional features of each unit and are consistent with the current understanding of the geology of the aquifers. Spatial patterns in the upper glacial aquifer show contrasts in estimated hydraulic conductivity: lower values occur in inland areas and likely are associated with glacial moraines; higher values generally occur to the south in association with glacial outwash. Higher values of hydraulic conductivity in the Magothy aquifer, which resulted from deltaic deposition, generally occur in the basal parts of the unit, are associated with channel-lag deposits and are found in parts of the aquifer known for large well yields. Lower values of hydraulic conductivity generally occur in middle parts of the aquifer associated with deposition in overbank and wetland environments. The probability of lignite occurrence is highest in this same vertical zone of the Magothy aquifer, consistent with deposition in wetland environments. The probability of lignite occurrence generally is highest along the southern shore of the island. Lignite occurrence generally is consistent with water-quality patterns; water quality in these same areas indicate chemically reducing conditions and redox-related iron biofouling commonly occurs.

New York

Surface infiltration and unsaturated zone characterization in support of managed aquifer recharge in Bedell Flat, Washoe County, Nevada

Aquifer storage and recovery (ASR) expands the portfolio of public water supply and improves resiliency to drought and future water demand. This study investigated the feasibility of ASR in the Bedell Flat Hydrographic Area using land-based methods including in-channel managed aquifer recharge (MAR) and rapid infiltration basins (RIB). Bedell Flat, one of two flow-through groundwater basins near Reno, Nevada, was a likely candidate for ASR because of its deep basin fill, proximity to supplemental water sources and infrastructure, and lack of development. In-channel MAR feasibility was determined from seepage losses along the Bird Springs ephemeral channel measured using Parshall flumes and heat-as-a-tracer inverse modeling. The feasibility of RIB was evaluated by characterizing vadose zone boreholes installed with roto-sonic drilling to water table. Field characterization of sediment and lithologic descriptions was accomplished at 1-foot (ft) increments. Bulk sediment samples were collected every 5 ft and cores from a split spoon were sampled at 10, 20, 30, 40, 60 and 100 ft below land surface (bls). Collected samples were analyzed for texture, moisture content, and geochemistry. Infiltration rates in Bird Springs channel increased downgradient with the hydraulic conductivity of the upper reaches ranging from 0.002 to 0.14 meter per hour (m/h) and the lower reaches from 0.5 to 1.5 m/h. Differences in discharge measurements indicate that seepage losses also increase down channel. When normalized to 1 ft of channel stage, modeled seepage loss rates ranged from 0.02 to 5.34 cubic feet per second (ft 3 /s) per mile (mi). Perched zones of soil moisture residing on top of dry fine-textured, clay-rich layers were prevalent in the Bird Springs drainage, indicating complicated flow paths for any supplement recharge water. Characterization of boreholes in Bird Springs drainage indicates low permeability clay layers 1–10 ft thick interbedded within extensive, grussy sands of high permeability. The presence of low permeability clay layers (1–10 ft thick) prompted a shift in analysis to the adjacent Sand Hills drainage where four additional boreholes indicated fewer perched water zones and at greater depths. Nitrates in the sediment pore-water (a condition that would discourage ASR) were integrated with depth to the aquifer 180 ft bls. Wells BF-MW-04 (Bird Springs) and BF-MW-07 (Sand Hills) contained 4,270 and 2,436 kilograms per hectare of nitrogen, respectively, which could potentially load excessive nitrogen to a receiving aquifer. An economically viable ASR project requires a minimum input of 2 million gallons per day (approximately 3 ft 3 /s), which either channel appears to have the sufficient capacity to infiltrate such a volume before reaching the valley bottom of Bedell Flat. However, the trajectory of the infiltrated water is complicated by the lithology and lateral transmissivity of the underlying sediments. There is also concern that this volume of infiltrated water may cause undesirable groundwater levels at the outflow in less than 5 years.

Nevada

Sediment lithology and borehole erosion testing, American and Sacramento Rivers, California

Executive Summary A field investigation intended to measure the potential for erosion of sediments beside the American and Sacramento Rivers near Sacramento, California, is described. The study featured two primary components: (1) drilling and soil sampling to reveal lithology, down to depths matching the local river thalweg, where possible, and (2) borehole erosion tests (BETs) as described by Briaud and others (2017) at many of the same locations. The latter test involved drilling a vertical hole, measuring its diameter profile, inserting a hollow drilling rod to almost the bottom of the hole, and pumping fluid through the drilling rod at a known discharge for a chosen time interval. The hole was then resurveyed to establish an erosion rate (change in borehole radius divided by duration of flow event) as a function of depth, and the test was repeated. This test was performed with water as the erosive fluid at 12 locations, with 1 test repeated with drilling mud. Lithology holes were drilled at these same locations and an additional five locations. Drilling operations took place on river left and river right on the American River and river left (left bank, when looking downstream) on the Sacramento River. The drilling to acquire sediment samples and reveal lithology involved the use of a mobile drilling rig equipped with a 6-inch (in.) auger, a 140-pound pneumatic hammer to drive split spoon and Calmod samplers, and a piston to push Shelby tube samplers to obtain samples of clayey material. Blow count (hammer blows per 6-in. sampler advance) was recorded while sampling, and the process was logged using standard U.S. Army Corps of Engineers (USACE), Sacramento District procedures. Sediment samples were identified and described in the field per ASTM D2488 and then delivered to a USACE laboratory and to Texas A&M University for additional laboratory analysis. The BETs were performed with the same drilling rig that performed the drilling for definition of lithology. In most instances, tests were limited to regions above the water table, to avoid slumping of the borehole and heaving sands pushing into the hole. Most of the tests featured sediments that were primarily silty sand or sandy silt. The testing procedure involved comparing borehole profiles before and after passing an assumed constant discharge through a drilling rod to the bottom of the drilled hole. Discharge and water losses were logged during the testing procedure, and water losses into the walls of the drilled hole were typically less than 5 percent of the introduced volume. For the tests performed with water, the coefficient of variation of the discharge ranged from 4.5 to 28 percent, with a mean of 13 percent, but the mean discharge appeared to be reasonably steady over the typical test duration of 10–30 minutes. It was thus assumed that discharge was constant and water losses during the tests were neglected. Coefficients of variation of the discharge for the three tests performed with drilling mud were much higher (20–50 percent), but erosion rates were much smaller. Resolution of the borehole caliper-reported diameter was 0.1 in. and several of the tests lasted for 10 minutes. With boreholes measured twice, before and after each test, and averaged, these numbers correspond to an apparent erosion rate (radius change divided by test duration) of 0.3 inches per hour (in/hr), which is a theoretical lower bound on what could be measured with this approach and equipment. In practice, 0.5 in/hr appears to be a more realistic lower bound on the detectable erosion rate, based on inspection of computed changes and erosion rates. Three flow speeds (5, 8, and 12 feet per second; ft/s) were targeted for the tests. Because of equipment limitations, it was not possible in the field to reach an average of 12 ft/s throughout any given borehole, although much higher flow speeds were reached locally in some cases. Most tests featured at least two different flow rates, and the borehole was typically surveyed at least twice for each condition, to allow averaging to reduce the influence of random diameter measurement errors. Errors arising from out-of-round boreholes appeared to be uncommon. Briaud and others (2017) recommend stepped increases in the flow rate during a borehole test. This approach was taken during initial testing but proved to be problematic. The drilled hole would be enlarged by the first (smaller) discharge, and then it would be difficult to reach the desired higher flow speed because of the larger annulus between the drilled hole and the drilling rod that supplied the water for testing. This was largely solved by starting with a high discharge and, in many cases, maintaining it for subsequent tests with the average flow speed decreasing as the hole enlarged. Several different measures of erosion rate were computed and investigated by comparison to lithological profiles. The vertically averaged erosion rate for each hole was computed, but this result does not reveal vertical variability of erodibility; and the mean flow speed within the hole is not a good representation of the speed when attempting to determine a relationship between erosion rate and flow speed. Instead, for each 6-inch layer within the hole, vertically averaged erosion rates and local flow speeds were computed and plotted. Where possible, the soil type for each layer was identified. For later laboratory analysis, project protocol dictated collection of Shelby tube samples whenever clay was encountered. Plots of erosion rate versus flow speed displayed scatter that indicate that several other factors influence the erosion potential of the soil. Blow count was not a good predictor variable; it is better correlated with soil type than erodibility. Soils were classified as sand, silt, or clay, depending on which soil type dominated within a sample. In general, those classified as sand and silt did not reveal clear patterns allowing erosion rate to be computed directly from flow speed, but the test results define the range and bounds on the erosion rate. Results for clay were slightly clearer with the erosion rate increasing with flow speed, once a threshold had been reached. In this case, the erosion rate appeared to change near a speed of 7 ft/s; above this threshold, erosion rates jumped from less than 2 in/hr to greater than 3 in/hr. Even for soils with similar classifications, large differences in erodibility were observed between sites and in different layers within an individual hole. One potential means of dealing with this problem would be to perform more tests at each site to allow establishment of relationships between flow speed and erodibility for individual layers within a borehole. The maximum number of tests performed at a site in this study was four, but in some cases, results are available for only one or two flow events. Comparison of data to a set of Erosion Function Apparatus tests that provide better resolution of the vertical variation in the erosion rate versus flow speed relationship would allow further investigation of this idea. It was hypothesized that drilling mud could expand the utility of the test in soft sands by reducing the likelihood of slumping that would be interpreted as erosion. The one test that was performed with drilling mud indicated that it greatly reduced the erosion rate of the soils encountered. It yielded very different results from the test performed at the same site with water. Erosion rate is often expressed as a function of shear stress applied to a soil. In order to compute shear stress on the walls of the drilled hole, one must assume a form for the relationship between flow speed and shear stress and select a friction factor that is often estimated empirically from head loss, observed water-surface profiles, surface roughness, or other data not available in this report. One methodology for computing shear stress from flow speed is discussed in this report, but the test results have been presented in terms of erosion rate versus flow speed to avoid assuming values that are not verifiable via the field data collected in this study. Erosion rate was computed from directly measured values (sequential borehole profiles) and flow speed was computed directly from measured quantities (discharge and borehole geometry). The BET has seen limited application, primarily in clayey soils, whereas most of the soils encountered in this study were primarily sand or silt. The objective of the BET is to determine the erodibility of in situ soil below the ground or riverbed surface. The BET is simple in principle and has the advantage of revealing erodibility of in situ sediments below the ground or riverbed surface; it appears to be very useful in clayey soils, based on previously published work, but is more difficult to apply in sandy soils where slumping and water losses within the hole during testing are more likely to occur. The BET did reveal a large variation in the results both laterally and vertically, even for the same soil-type classification. It is thus recommended that the results be applied considering these spatial variations rather than attempting to universally assign an erosion-rate relationship to a particular soil type. Results have been provided showing the results by site and by sediment classification (sand, silt, and clay), to allow either approach. Where possible, it is important to rely on site-specific results because the erosion-rate relationship for a given soil type varied by site. Data collected during this project have been made publicly available online via the U.S. Geological Survey (USGS) Sciencebase database. The measured borehole profiles, discharge, lithology log sheets, and photos are available in the data release that accompanies this report (see Work and Livsey (2019) in the “Selected References” section for the appropriate link).

California

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin — Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

As part of a national analysis of the effects of land use on ground-water quality for the National Water-Quality Assessment Program, the U.S. Geological Survey sampled wells along a flow system in surficial glacial aquifers in the northwestern part of the Twin Cities metropolitan area during 1997 and 1998. In addition, a reconnaissance steady-state ground-water model was developed to estimate flowpaths and dates of ground-water recharge using a particle-tracking routine. Sediment samples collected during drilling had high horizontal hydraulic conductivities (ranging from about 3.1 to about 190 feet per day, based on sediment-size analysis of well cuttings), small organic carbon concentrations (ranging from less than 0.2 to 160 grams per kilogram), and pH values that were mostly alkaline (ranging from 4.9 to 8.2). Water samples were analyzed for physical properties, major ions, iron, manganese, nutrients, organic carbon, radon, pesticides, volatile organic compounds (VOCs), chlorofluorocarbons, tritium, and isotopes of nitrogen, hydrogen, and oxygen. Most of the water samples had small dissolved-oxygen concentrations (less than 1 milligram per liter). Calcium, magnesium, sodium, bicarbonate, sulfate, and chloride were the primary dissolved constituents in water samples. Nitrite plus nitrate as nitrogen (nitrate) concentrations were less than the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level of 10 mg/L. Nitrogen isotope ratios indicated that the sources of nitrate primarily were soils, animal waste, or denitrification that increased nitrogen isotope ratios in nitrate. Small concentrations of pesticides were detected in the shallow parts of the aquifer. The herbicide prometon was the most frequently detected pesticide. Herbicides applied to control grasses and weeds in corn (atrazine, simazine, and metolachlor) also were frequently detected in water samples. All pesticide and VOCs detected were below USEPA Maximum Contaminant Levels or Health Advisory Limits. Chlorofluorocarbon compounds and tritium concentrations were used to estimate dates of recharge of ground-water samples. In general, shallower ground-water samples were more recently recharged although most water sampled from the aquifer was recharged after 1955. Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Minnesota

Completion summary for monitor wells NRF-17 and NRF-18 at the Naval Reactors Facility, Idaho National Laboratory, Idaho

The U.S. Geological Survey (USGS)—in cooperation with the U.S. Department of Energy (DOE) for the Naval Reactors Laboratory Field Office that supports operations for the Naval Reactors Facility (NRF) located at the Idaho National Laboratory (INL)—drilled and constructed well NRF-17 (formerly borehole USGS 151) and well NRF-18 (formerly borehole USGS 152) for stratigraphic framework analyses and water-quality monitoring at the Idaho National Laboratory (INL) near the NRF, in southeastern Idaho. Borehole USGS 151 was continuously cored from about 48 to 1,070 feet (ft) below land surface (BLS); rotary drilled from approximately 1,070 to 1,720 ft BLS; and re-drilled to complete construction as a monitor well NRF-17, completed to 461 ft BLS. Borehole USGS 152 was continuously cored from approximately 19 to 1,259 ft BLS; rotary drilled from approximately 1,259 to 1,630 ft BLS; and re-drilled to complete construction as a monitor well NRF-18, completed to 450 ft BLS. Geophysical data were examined with photographed core material to record lithologic descriptions and to suggest zones where groundwater flow was anticipated. Basalt flows varied from highly fractured to dense, with high-to-low vesiculation. Well NRF-17 generally was constructed in mostly dense basalt (greater than 75 percent), and well NRF-18 was constructed in primarily fractured and (or) vesicular basalt. In well NRF-17, the well capacity is directly affected by the limited amount of fractured basalt, which serves as the primary pathway for groundwater. This effect was observed during the pumping test conducted after the well's final construction. Single-well aquifer tests were done at wells NRF-17 and NRF-18 to provide estimates of transmissivity and hydraulic conductivity after final well construction and initial well development. Estimated values of transmissivity and hydraulic conductivity for well NRF-17 were 8.81 feet squared per day (ft 2 /d) and 1.04×10 -2 feet per day (ft/d), respectively. Estimated values of transmissivity and hydraulic conductivity for well NRF-18 were 4.77×10 3 ft 2 /d and 5.61 ft/d, respectively. The NRF-17 pump test resulted in 19.41 ft of measured drawdown at a sustained average pumping rate of 3.3 gallons per minute (gal/min). The NRF-18 pump test resulted in 0.55 ft of measured drawdown at a sustained average pumping rate of 31.0 gal/min. Water-quality samples collected from the two wells were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for select inorganic constituents showed concentrations consistent with signatures from tributary valley groundwater with influences from ephemeral surface-water recharge from the Big Lost River. Water-quality samples analyzed for stable isotopes of oxygen and hydrogen are consistent with signatures from tributary valley groundwater and surface-water recharge inputs to the aquifer. No measured water-quality results were greater than their respective maximum contaminant levels for public drinking-water supplies. Inorganic and nutrient water-quality results for well NRF-17 and well NRF-18 suggest the groundwater in this area is potentially affected by industrial wastewater disposal.

Idaho