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At least 325 records · Page 18Linked to original sources

USGS1991

Resetting of RbSr ages of volcanic rocks by low-grade burial metamorphism

We report a nine-point RbSr whole-rock isochron age of 70±3 Ma (MSWD 3.97) for Mid-Jurassic volcanic rocks. The same rocks have also been dated by the UThPb method on zircon, giving a crystallization age of 166 ± 11 Ma, over twice as old as the RbSr age. The data demonstrate that whole-rock RbSr ages of volcanic rocks, even lava flows with SiO 2 content as low as 57 wt.%, are susceptible to complete resetting. The rocks range in composition from rhyodacite tuffs to andesite lavas. The complete breakdown of all major minerals that contain Rb and Sr resulted in an alteration mineral assemblage consisting of phengite, albite, secondary quartz, and minor amounts of chlorite and epidote. Phengite is the K-bearing product of the breakdown of biotite and K-feldspar. Pressure during low-grade metamorphism of the volcanic rocks, estimated from phengite composition to have been in the range of 4 to 6 kbar, points to thrust-related burial as the main cause of resetting. Consequently, such reset isochrons may date large-scale events such as regional thrusting and metamorphism. The coherent resetting of the RbSr isochron suggests large-scale pervasive fluid movement during thrust-related burial metamorphism.

Chemical Geology: Isotope Geoscience Section↗

USGS2012

Occurrence model for volcanogenic beryllium deposits

Current global and domestic mineral resources of beryllium (Be) for industrial uses are dominated by ores produced from deposits of the volcanogenic Be type. Beryllium deposits of this type can form where hydrothermal fluids interact with fluorine and lithophile-element (uranium, thorium, rubidium, lithium, beryllium, cesium, tantalum, rare earth elements, and tin) enriched volcanic rocks that contain a highly reactive lithic component, such as carbonate clasts. Volcanic and hypabyssal high-silica biotite-bearing topaz rhyolite constitutes the most well-recognized igneous suite associated with such Be deposits. The exemplar setting is an extensional tectonic environment, such as that characterized by the Basin and Range Province, where younger topaz-bearing igneous rock sequences overlie older dolomite, quartzite, shale, and limestone sequences. Mined deposits and related mineralized rocks at Spor Mountain, Utah, make up a unique economic deposit of volcanogenic Be having extensive production and proven and probable reserves. Proven reserves in Utah, as reported by the U.S. Geological Survey National Mineral Information Center, total about 15,900 tons of Be that are present in the mineral bertrandite (Be 4 Si 2 O 7 (OH) 2 ). At the type locality for volcanogenic Be, Spor Mountain, the tuffaceous breccias and stratified tuffs that host the Be ore formed as a result of explosive volcanism that brought carbonate and other lithic fragments to the surface through vent structures that cut the underlying dolomitic Paleozoic sedimentary rock sequences. The tuffaceous sediments and lithic clasts are thought to make up phreatomagmatic base surge deposits. Hydrothermal fluids leached Be from volcanic glass in the tuff and redeposited the Be as bertrandite upon reaction of the hydrothermal fluid with carbonate clasts in lithic-rich sections of tuff. The localization of the deposits in tuff above fluorite-mineralized faults in carbonate rocks, together with isotopic evidence for the involvement of magmatic water in an otherwise meteoric water-dominated hydrothermal system, indicate that magmatic volatiles contributed to mineralization. At the type locality, hydrothermal alteration of dolomite clasts formed layered nodules of calcite, opal, fluorite, and bertrandite, the latter occurring finely intergrown with fluorite. Alteration assemblages and elemental enrichments in the tuff and surrounding volcanic rocks include regional diagenetic clays and potassium feldspar and distinctive hydrothermal halos of anomalous fluorine, lithium, molybdenum, niobium, tin, and tantalum, and intense potassium feldspathization with sericite and lithium-smectite in the immediate vicinity of Be ore. Formation of volcanogenic Be deposits is due to the coincidence of multiple factors that include an appropriate Be-bearing source rock, a subjacent pluton that supplied volatiles and heat to drive convection of meteoric groundwater, a depositional site characterized by the intersection of normal faults with permeable tuff below a less permeable cap rock, a fluorine-rich ore fluid that facilitated Be transport (for example, BeF 4 2- complex), and the existence of a chemical trap that caused fluorite and bertrandite to precipitate at the former site of carbonate lithic clasts in the tuff.

Scientific Investigations Report↗

USGS2014

Regional mapping of hydrothermally altered igneous rocks along the Urumieh-Dokhtar, Chagai, and Alborz Belts of western Asia using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operators: a tool for porphyry copper exploration and assessment

Regional maps of phyllic and argillic hydrothermal alteration were compiled using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and logical operator algorithms. The area mapped extends from northwestern Iran to southeastern Pakistan and includes volcanic and magmatic arcs that make up the Urumieh-Dokhtar volcanic belt (UDVB), the Chagai volcanic belt (CVB), and the central part of the Alborz magmatic belt (AMB). The volcanic belts span the Zagros-Makran transform zone and the present day Baluchistan (Makran) volcanic arc. ASTER visible near infrared (VNIR) data contain three bands between 0.52 and 0.86 micrometers (μm) and the short-wave infrared (SWIR) data consist of six bands spanning 1.6 to 2.43 μm with 15-meter (m), and 30-m resolution, respectively. During the 8-year project, three different calibration methods were used to correct ASTER SWIR anomalies and produce ASTER calibrated reflectance data, which were then used to map hydrothermally altered rocks. Logical operators, used to map hydrothermally altered rocks, perform multiple band ratios and thresholds that can be applied to multiple ASTER scenes using a single algorithm, thus eliminating separate production and application of vegetation and dark pixel masks. Argillic and phyllic band ratio logical operators use band ratios that define the 2.17- and 2.20-μm absorption features to map kaolinite and alunite, typical in argillized rocks, and muscovite, which is a common mineral in phyllic alteration. Band thresholds for ratios in argillic and phyllic logical operator algorithms were determined by mapping known argillic and phyllic rocks at a calibration test site in Cuprite, Nevada, in the United States. The regional argillic and phyllic hydrothermal alteration map and geologic and deposit maps of the study area illustrate that distinct patterns of altered rocks are typically associated with certain types of mineral deposits. The central part of the UDVB contains numerous circular to elliptical patterns (1 to 5 kilometers in diameter) of mapped phyllic- and argillic-altered rocks associated with Eocene to Miocene intrusive igneous rocks, some of which host known porphyry copper deposits such as at Meiduk, Sar Cheshmeh, and Seridune in Iran. The Zagros-Makran transform zone and areas adjacent to the Saindak porphyry deposit and Taftan Volcano contain primarily phyllic-altered rocks that form linear patterns associated with extensive faulting and fractures indicative of epithermal and (or) polymetallic vein deposits. The ASTER alteration map and corresponding geologic maps were used to select circular to elliptical patterns of argillic- and phyllic-altered volcanic and intrusive rocks as potential porphyry copper sites. One hundred and seventy eight potential porphyry copper sites were mapped along the UDVB, and 23 sites were mapped along the CVB. The potential sites were selected to assist in further exploration and assessments of undiscovered porphyry copper deposits.

Scientific Investigations Report↗

USGS2026

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin↗

USGS1976

Serpentinization and alteration in an olivine cumulate from the Stillwater Complex, Southwestern Montana

Some of the olivine cumulates of the Ultramafic zone of the Stillwater Complex, Montana, are progressively altered to serpentine minerals and thompsonite. Lizardite and chrysotile developed in the cumulus olivine and postcumulus pyroxenes; thompsonite developed in postcumulus plagioclase. The detailed mineralogy, petrology, and chemistry indicate that olivine and plagioclase react to form the alteration products, except for H 2 O, without changes in the bulk composition of the rocks.

Montana↗

USGS1987

Evidence for Late-Paleozoic brine migration in Cambrian carbonate rocks of the central and southern Appalachians: Implications for Mississippi Valley-type sulfide mineralization

Many Lower Paleozoic limestones and dolostones in the Valley and Ridge province of the central and southern Appalachians contain 10 to 25 weight percent authigenic potassium feldspar. This was considered to be a product of early diagenesis, however, 40 Ar 39 Ar "> 40 Ar 39 Ar analyses of overgrowths on detrital K-feldspar in Cambrian carbonate rocks from Pennsylvania, Maryland, Virginia, and Tennessee yield Late Carboniferous-Early Permian ages (278–322 Ma). Simple mass balance calculations suggest that the feldspar could not have formed isochemically, but required the flux of multiple pore volumes of fluid through the rocks, reflecting regional fluid migration events during the Late-Paleozoic Alleghanian orogeny. Microthermometric measurements of fluid inclusions in overgrowths on detrital K-feldspar and quartz grains from unmineralized rocks throughout the study area indicate homogenization temperatures from 100° to 200°C and freezing point depressions of −14° to −18.5°C (18–21 wt.% NaCl equiv). The apparent similarity of these fluids to fluid inclusions in ore and gangue minerals of nearby Mississippi Valley-type (MVT) deposits suggests that the regional occurrences of authigenic K-feldspar and MVT mineralization may be genetically related. This hypothesis is supported by the discovery of authigenic K-feldspar intergrown with sphalerite in several mines of the Mascot-Jefferson City District, E. Tennessee. Regional potassic alteration in unmineralized carbonate rocks and localized occurrences of MVT mineralization are both explainable by a gravity-driven flow model, in which deep brines migrate towards the basin margin under a hydraulic gradient established during the Alleghanian orogeny. The authigenic K-feldspar may reflect the loss of K during disequilibrium cooling of the ascending brines. MVT deposits are probably localized manifestations of the same migrating fluids, occurring where the necessary physical and chemical traps are present.

Geochimica et Cosmochimica Acta↗

USGS1989

Glacimarine sedimentary processes, facies and morphology of the south-southeast Alaska shelf and fjords

High precipitation from Gulf of Alaska air masses can locally reach up to 800 cm a −1 . This precipitation on tectonically active mountains creates cool-temperate glaciation with extremely active erosion and continuously renewed resources. High basal debris loads up to 1.5 m thick of pure debris and rapid glacial flow, which can be more than 3000 m a −1 , combine to produce large volumes of siliciclastic glacimarine sediment at some of the highest sediment accumulation rates on record. At tidewater fronts of valley glaciers, sediment accumulation rates can be over 13 m a −1 and deltas commonly grow at about 10 6 m 3 a −1 . Major processes influencing glacimarine sedimentation are glacial transport and glacier-contact deposition, meltwater (subaerial and submarine) and runoff transport and deposition, iceberg rafting and gouging, sea-ice transport, wave action and storm reworking, tidal transport and deposition, alongshelf transport, sliding and slumping and gravity flows, eolian transport, and biogenic production and reworking. Processes are similar in both shelf and fjord settings; however, different intensities of some processes create different facies associations and geometries. The tectonoclimatic regime also controls morphology because bedrock structure is modified by glacial action. Major glacimarine depositional systems are all siliciclastic. They are subglacial, marginal-morainal bank and submarine outwash, and proglacial/paraglacial-fluvial/deltaic, beach, tidal flat/estuary, glacial fjord, marine outwash fjord and continental shelf. Future research should include study of long cores with extensive dating and more seismic surveys to evaluate areal and temporal extent of glacial facies and glaciation; time-series oceanographic data, sidescan sonar surveys and submersible dives to evaluate modern processes; biogenic diversity and production to evaluate paleoecological, paleobiogeographic and biofacies analysis; and detailed comparisons of exposed older rock of the Yakataga Formation to evaluate how glacial style has evolved over 6.3 Ma.

Marine Geology↗

USGS2024

Imogolite and allophane formed in saprolite of basalt on Maui, Hawaii

Inorganic gel and allophane collected from basaltic saprolite on Maul, Hawaii, and studied by Patterson in I964 were reexamined. The main constituent of the gel is imogolite, and gibbsite and allophane are the minor constituents. Electron and X-ray diffraction patterns, DTA curve, and an infrared spectrum of the gel are characteristic of imogolite. The allophane is virtually noncrystalline to X-rays but contains a small amount of imogolite in relatively short threads. High-resolution electron micrographs indicate differences in structural organization between allophane and imogolite and suggest crystallization of imogolite from allophane. The occurrence of imogolite as a weathering product has been reported in many localities from pyroclastic materials but not from massive rocks. Probably the exceptionally high rainfall, excellent subsurface permeability of the weathered material, and the low pH and high organic content of the leaching solution provide favorable conditions for formation of imogolite from basalt on Maul.

Hawaii↗

USGS1957

Effects of radon in drill holes on gamma-ray logs

Drill holes in uranium deposits in the Todilto limestone of Late Jurassic age near Grants, New Mexico, do not yield duplicate gamma-ray logs when probed at different times; some logs show equivalent uranium greatly in excess, in thickness and grade, of the chemical and laboratory radiometric analyses. Radon and its daughter products principally cause the discrepancies. Experimental work was undertaken by the writers to learn the relations of the radon to the uranium deposits and its behavior under different physical conditions. The work is based on the interpretation of about 600 gamma-ray logs, taken from 480 drill holes.Abnormally high amounts of radon, referred to here as contamination, ranged from barely detectable amounts to amounts that emitted as much radiation as ore-grade material. Most contaminated holes were in the higher-grade ore, and the contamination increased with elapsed time after drilling. Geologic conditions favorable for contamination by radon and its daughter products in drill holes are: proximity to uranium deposits and fractured or highly permeable rocks above the water table. Most drill holes can be decontaminated by blowing them out with compressed air or filling them with water. Water, however, tends to reduce the thickness-times-grade figures below the amounts determined in air.

New Mexico↗

USGS1999

An interpretation of the aeromagnetic and gravity data and derivative maps of the Craig and Dixon Entrance 1°x 3° quadrangles and the western edges of the Ketchikan and Prince Rupert quadrangles, southeastern Alaska

The U.S. Geological Survey (USGS) is required by the Alaska National Interest Lands Conservation Act (ANILCA, Public Law 96-487) to survey certain Federal lands to determine their mineral resource potential. As part of continuing studies designed to fulfill this responsibility, geochemical, geological and geophysical surveys of the Craig and Dixon Entrance (CDE) 1°x3° quadrangles in southeastern Alaska were undertaken by the USGS during the summers of 1983-85, 1989, and 1991. The geochemical data have been reported by Cathrall and others (1993) and Cathrall (1994). A simplified geologic map has been compiled especially for this report based largely on the work of Eberlein and others (1983) and Gehrels (1991, 1992). Brew (1996) also produced a compilation. This report presents available magnetic and gravity data and an interpretation thereof. In this report (released on CD-ROM in 1999) we are releasing USGS-acquired geophysical data for CDE 1:250,000-scale quadrangles of southeastern Alaska. Much of the data have never appeared before in the public domain, including a simplified geologic map, the raw gravity and magnetic data, and derivative products including depth-to-source images, various grids of the data, imaging representations, rock densities, and overlays of the data. In addition, we have added a limited interpretation of what the gravity and magnetic data indicate about the underlying geology, structures, and their relationship to known and potential hidden mineral resources. This interpretation is necessarily limited in the case of the gravity data by the general sparsity of stations. For convenience, we have also included here various representations of the digital topography.

Alaska↗

USGS2005

Ground-water hydrology of the Willamette basin, Oregon

The Willamette Basin encompasses a drainage of 12,000 square miles and is home to approximately 70 percent of Oregon's population. Agriculture and population are concentrated in the lowland, a broad, relatively flat area between the Coast and Cascade Ranges. Annual rainfall is high, with about 80 percent of precipitation falling from October through March and less than 5 percent falling in July and August, the peak growing season. Population growth and an increase in cultivation of crops needing irrigation have produced a growing seasonal demand for water. Because many streams are administratively closed to new appropriations in summer, ground water is the most likely source for meeting future water demand. This report describes the current understanding of the regional ground-water flow system, and addresses the effects of ground-water development. This study defines seven regional hydrogeologic units in the Willamette Basin. The highly permeable High Cascade unit consists of young volcanic material found at the surface along the crest of the Cascade Range. Four sedimentary hydrogeologic units fill the lowland between the Cascade and Coast Ranges. Young, highly permeable coarse-grained sediments of the upper sedimentary unit have a limited extent in the floodplains of the major streams and in part of the Portland Basin. Extending over much of the lowland where the upper sedimentary unit does not occur, silts and clays of the Willamette silt unit act as a confining unit. The middle sedimentary unit, consisting of permeable coarse-grained material, occurs beneath the Willamette silt and upper sedimentary units and at the surface as terraces in the lowland. Beneath these units is the lower sedimentary unit, which consists of predominantly fine-grained sediments. In the northern part of the basin, lavas of the Columbia River basalt unit occur at the surface in uplands and beneath the basin-fill sedimentary units. The Columbia River basalt unit contains multiple productive water-bearing zones. A basement confining unit of older marine and volcanic rocks of low permeability underlies the basin and occurs at land surface in the Coast Range and western part of the Cascade Range. Most recharge in the basin is from infiltration of precipitation, and the spatial distribution of recharge mimics the distribution of precipitation, which increases with elevation. Basinwide annual mean recharge is estimated to be 22 inches. Rain and snowmelt easily recharge into the permeable High Cascade unit and discharge within the High Cascade area. Most recharge in the Coast Range and western part of the Cascade Range follows short flowpaths through the upper part of the low permeability material and discharges to streams within the mountains. Consequently, recharge in the Coast and Ranges is not available as lateral ground-water flow into the lowland, where most ground-water use occurs. Within the lowland, annual mean recharge is 16 inches and most recharge occurs from November to April, when rainfall is large and evapotranspiration is small. From May to October recharge is negligible because precipitation is small and evapotranspiration is large. Discharge of ground water is mainly to streams. Ground-water discharge is a relatively large component of flow in streams that drain the High Cascade unit and parts of the Portland Basin where permeable units are at the surface. In streams that do not head in the High Cascade area, streamflow is generally dominated by runoff of precipitation. Ground-water in the permeable units in the lowland discharges to the major streams where there is a good hydraulic connection between aquifers and streams. Ground-water discharge to smaller streams, which flow on the less permeable Willamette silt unit, is small and mostly from the Willamette silt unit. Most ground-water withdrawals occur within the lowland. Irrigation is the largest use of ground water, accounting for 240,000 acre feet of withdrawals, or 81 p

Scientific Investigations Report↗

USGS1994

Hydrogeologic atlas of aquifers in Indiana

Aquifers in 12 water-management basins of Indiana are identified in a series of 104 hydrogeologic sections and 12 maps that show the thickness and configuration of aquifers. The vertical distribution of water-bearing units and a generalized potentiometric profile are shown along 3,500 miles of section lines that were constructed from drillers' logs of more than 4,200 wells. The horizontal scale of the sections is 1:125,000. Maps of aquifers showing the areal distribution of each aquifer type were drawn at a scale of 1:500,000. Unconsolidated aquifers are the most widely used aquifers in Indiana and include surficial, buried, and discontinuous layers of sand and gravel. Most of the surficial sand and gravel is in large outwash plains in northern Indiana and along the major rivers. Buried sand and gravel aquifers are interbedded with till deposits in much of the northern two-thirds of Indiana. Discontinuous sand and gravel deposits are present as isolated lenses, primarily in glaciated areas. The bedrock aquifers generally have lower yields than most of the sand and gravel aquifers; however, bedrock aquifers are areally widespread and are an important source of water. Bedrock aquifer types consist of carbonates; sandstones; complexly interbedded sandstones, siltstones, shales, limestones, and coals; and an upper weathered zone in low permeability rock. Carbonate aquifers underlie about one-half of Indiana and are the most productive of the bedrock aquifers. The other principal bedrock aquifer type, sandstone, underlies large areas in the southwestern one-fifth of Indiana. No aquifer is known to be present in the southeastern corner of Indiana.

Water-Resources Investigations Report↗

USGS1951

Determination of lithium in rocks: Fluorometric method

The gravimetric method in general use for the determination of lithium is tedious, and the final weighed product often contains other alkali metals. A fluorometric method was developed to shorten the time required for the analysis and to assure that the final determination is for lithium alone. This procedure is based on the complex formed between lithium and 8-hydroxyquinoline. The fluorescence is developed in a slightly alkaline solution of 95% alcohol and measurement is made on a photoelectric fluorometer. Separation from the ore is carried out by the wet method or by the distillation procedure. Sodium and potassium are removed by alcohol and ether, but complete separation is not necessary. Comparison of analyzed samples shows excellent agreement with spectrographic and gravimetric methods. The fluorometric method is more rapid than the gravimetric and produces more conclusive results. Another useful application is in the preparation of standard lithium solutions from reagent quality salts when a known standard is available. In this case no separations are necessary.

Analytical Chemistry↗

USGS2014

Mineral resource of the month: Vermiculite

Vermiculite comprises a group of hydrated, laminar magnesium-aluminum-iron silicate minerals resembling mica. They are secondary minerals, typically altered biotite, iron-rich phlogopite or other micas or clay-like minerals that are themselves sometimes alteration products of amphibole, chlorite, olivine and pyroxene. Vermiculite deposits are associated with volcanic ultramafic rocks rich in magnesium silicate minerals, and flakes of the mineral range in color from black to shades of brown and yellow. The crystal structure of vermiculite contains water molecules, a property that is critical to its processing for common uses.

Earth↗

USGS1976

Flameless atomic absorption determination of bismuth in soils and rocks

Recent advances in flameless atomic absorption allow determinations of bismuth in concentrations as small as 50 ppb in 0.2 g of rock or soil sample. The sample is fused with sodium bisulfate and the fusion product is leached with hot 2 M hydrochloric acid and treated with ammonium citrate, (ethylenedinitrilo) tetraacetic acid disodium salt, and finally with ammonium 1-pyrrolidinedithiocarbamate to form a complex which is extracted into methyl isobutyl ketone. Aliquots of the latter are pipetted into a graphite furnace and then subjected to an established and automated program of drying, charring, and atomizing. Recorded peak heights provide a measure of the amount of bismuth present.

Journal of Research of the U.S. Geological Survey↗

USGS1976

Heat flow and near-surface radioactivity in the Australian continental crust

Heat-flow data have been obtained at 44 sites in various parts of Australia. These include seven sites from the old (~ 2500 m.y.) Precambrian shield of Western Australia, seventeen from the younger (~ 600- 2000 m.y.) Precambrian rocks of South Australia, the Northern Territory, and Queensland, and twenty within the eastern Paleozoic and younger rocks. Thirty of the sites are located where no previous heat-flow data existed, and the remainder provide significant extensions or refinements of areas previously studied. Where the holes studied penetrated the crystalline basement rocks, or where the latter rocks were exposed within a few kilometers of the holes, the upper crustal radiogenic heat production has been estimated based on gamma-ray spectrometric determinations of U, Th, and K abundances. Three heat-flow provinces are recognized in Australia based on the linear relation (q = q* + DA 0 ) between heat flow q and surface radioactivity A 0 . New data from the Western Australian shield support earlier studies showing that heat flow is low to normal with values ranging from 0.7 to 1.2 hfu and with the majority of values less than 1.0 hfu, and the parameters q* = 0.63 hfu and 0 = 4.5 km determined previously were confirmed. Heat flow in the Proterozoic shield of central Australia is quite variable, with values ranging between about l and 3 hfu. This variability is attributed mainly to variations in near-surface crustal radioactivity. The parameters of the heat-flow line are q* = 0.64 hfu and 0 = 11.1 km and moderately high temperatures are predicted for the lower crust and upper mantle. Previous suggestions of a band of l ow- to - normal heat flow near the coast in eastern Australia were confirmed in some areas, but the zone is interrupted in at least one region (the Sydney Basin), where heat flow is about 2.0 hfu over a large area. The reduced heat flow, q*, in the Paleozoic intrusive rocks of eastern Australia varies from about 0.8 to 2.0 hfu . This variability might be related to thermal transients associated with Late Tertiary and younger volcanic and tectonic activity, even though the relation between heat-flow values and the age of volcanism is not a simple one. Parts of the high heat-flow area in the southeast might be exploitable for geothermal energy.

Open-File Report↗

USGS2015

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

Data Series↗

USGS2005

Arsenic in ground water of the United States: occurrence and geochemistry

Concentrations of naturally occurring arsenic in ground water vary regionally due to a combination of climate and geology. Although slightly less than half of 30,000 arsenic analyses of ground water in the United States were 1 μg/L, about 10% exceeded 10 μg/L. At a broad regional scale, arsenic concentrations exceeding 10 μg/L appear to be more frequently observed in the western United States than in the eastern half. Arsenic concentrations in ground water of the Appalachian Highlands and the Atlantic Plain generally are very low ( 1 μg/L). Concentrations are somewhat greater in the Interior Plains and the Rocky Mountain System. Investigations of ground water in New England, Michigan, Minnesota, South Dakota, Oklahoma, and Wisconsin within the last decade suggest that arsenic concentrations exceeding 10 μg/L are more widespread and common than previously recognized. Arsenic release from iron oxide appears to be the most common cause of widespread arsenic concentrations exceeding 10 μg/L in ground water. This can occur in response to different geochemical conditions, including release of arsenic to ground water through reaction of iron oxide with either natural or anthropogenic (i.e., petroleum products) organic carbon. Iron oxide also can release arsenic to alkaline ground water, such as that found in some felsic volcanic rocks and alkaline aquifers of the western United States. Sulfide minerals are both a source and sink for arsenic. Geothermal water and high evaporation rates also are associated with arsenic concentrations 10g/L in ground and surface water, particularly in the west. Arsenic release from iron oxide appears to be the most common cause of widespread arsenic concentrations exceeding 10 µg/L a ground water. This can occur in response to different geochemical conditions, including release of arsenic to ground water through reaction of iron oxide with either natural or anthropogenic (i.e., petroleum products) organic carbon. Iron oxide also can release arsenic to alkaline ground water, such as that found in some felsic volcanic rocks and alkaline aquifers of the Western United States. Sulfide minerals are both a source and sink for arsenic. Geothermal water and high evaporation rates also are associated with arsenic concentrations ≥ 10g/L in ground and surface water, particularly in the west.

Ground Water↗