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USGS2002

Tectonics and distribution of gold deposits in China - An overview

Gold exploration in China has expanded rapidly during the last two decades since a modern approach to economic development has become a national priority. China currently produces 180 tonnes (t) of gold annually, which is still significantly less than South Africa, USA, and Australia. However, China is now recognized as possessing significant gold resources in a wide range of mineral deposit types. Present estimates of gold resources in China exceed 4,500 t, which comprise 60% in gold-only deposits, more than 25% in base metal-rich skarn, porphyry, and vein deposits, and more than 10% in placer accumulations. The major gold provinces in China formed during the main episodes of Phanerozoic tectonism. Such tectonism involved interaction of China's three major Precambrian cratons, North China, Tarim, and Yangtze (or South China when combined with Cathaysia block), with the Angara (or Siberian), Kazakhstan–Kyrgyzstan, and Indian cratons. Resulting collisions included deformation of accreted oceanic sequences between the cratonic blocks. The most important ore-forming orogenies were (1) the late Paleozoic Variscan (405–270 Ma), which led to amalgamation of the Angara, North China and Yangtze cratons, (2) the Indosinian (270–208 Ma), which led to the collision of North China and South China cratons, (3) the Yanshanian (208–90 Ma), which was largely influenced by the subduction of the Izanagi–Pacific plates beneath eastern China, and (4) the Himalayan (<90 Ma) indentation of the Indian continent into Eurasia. No important Precambrian gold systems are recognized in China, mainly because of reworking of exposed Precambrian rocks by these younger orogenies, but there are a few Caledonian (600–405 Ma) gold-bearing systems in northern Xinjiang. Most of China's orogenic, epithermal, and Carlin-like gold deposits are in the reworked margins of major cratonic blocks and in metasedimentary rock-dominated fold belts adjacent to these margins. Accordingly, the major gold provinces are present along the northern, southeastern and southern margins of the North China craton, along the southwestern and northwestern margins of the Yangtze craton, in the Tianshan and Altayshan orogenic belts in northern Xinjiang, and throughout the southeastern China fold belt. Gold-placer deposits derived from these primary deposits are concentrated in the northernmost part of northeastern China and along the northwestern margin of the Yangtze craton. The major provinces with significant gold in porphyry-related copper systems and base metal skarns are present in the Yangtze River area along the northeastern and southeastern margin of the Yangtze craton, in the fold belt in southwestern China, and scattered through northern China. Three-quarters of the Chinese gold-only deposits occur within the North China craton margins. Half are located in the uplifted Precambrian metamorphic rocks and most of the remainder are hosted in the Phanerozoic granitoids that intruded the reworked Precambrian terranes. The abundance of granite-hosted gold contrasts the North China craton with other Precambrian cratons, such as those in Western Australia, central Canada, and Zimbabwe, where gold is mainly hosted in the Archean greenstone belts. This difference may be explained by the multiple episodes of Phanerozoic tectonism along the North China craton margins resulting from the collision of the Angara, North China, and South China cratons, and from subduction of the Izanagi–Pacific oceanic plates underneath the eastern China continent.

Mineralium Deposita↗

USGS2005

Seasonality of diel cycles of dissolved trace-metal concentrations in a Rocky Mountain stream

Substantial diel (24-h) cycles in dissolved (0.1-μm filtration) metal concentrations were observed during summer low flow, winter low flow, and snowmelt runoff in Prickly Pear Creek, Montana. During seven diel sampling episodes lasting 34–61.5 h, dissolved Mn and Zn concentrations increased from afternoon minimum values to maximum values shortly after sunrise. Dissolved As concentrations exhibited the inverse timing. The magnitude of diel concentration increases varied in the range 17–152% for Mn and 70–500% for Zn. Diel increases of As concentrations (17–55%) were less variable. The timing of minimum and maximum values of diel streamflow cycles was inconsistent among sampling episodes and had little relation to the timing of metal concentration cycles, suggesting that geochemical rather than hydrological processes are the primary control of diel metal cycles. Diel cycles of dissolved metal concentrations should be assumed to occur at any time of year in any stream with dissolved metals and neutral to alkaline pH.

Environmental Geology↗

USGS2002

Emplacement of the most recent lava flows on Hualālai Volcano, Hawai'i

A detailed field and petrologic study of the ca. 1800 a.d. flows at Hualālai Volcano documents at least two eruptive episodes, the Hu‘ehu‘e flow field ending in 1801, and the Ka‘ūpūlehu flow several decades earlier. The morphology and stratigraphy of the Ka‘ūpūlehu flow require an emplacement duration of several days to weeks. Based on a comparison with recent eruptive activity at Mauna Loa volcano, the eruption cannot have occurred at the anomalously high rate (10 4 –10 5 m 3 /s) proposed by previous workers. The hummocky flow surface of the later phase of the Hu‘ehu‘e eruption suggests a duration of months, based on a comparison with recent eruptive activity at Kīlauea Volcano. Although none of the ca. 1800 flows show evidence for extraordinarily fast emplacement or unusual fluid rheologies, both flows show unusual features. The abundant xenoliths for which the Ka‘ūpūlehu flow is famous were transported in numerous episodes of deposition and remobilization, during which they eroded the channel systems through which they traveled. Lava transport in proximal and medial regions of both flow fields was probably through lava tubes, as evidenced by preserved tubes and by the prevalence of pāhoehoe-lined channels that require thermally efficient transport of lava over great distances. Both flows also show abundant evidence for re-occupation of older cones and lava tubes, a characteristic that may typify infrequent eruptions of older volcanic systems. Although lava flows from Hualālai Volcano do not show anomalous eruptive behavior, they pose a substantial hazard for coastal communities of Kona.

Bulletin of Volcanology↗

USGS2002

Long-period events and tremor at Popocatepetl volcano (1994–2000) and their broadband characteristics

Following an initial phreatic eruption on 21 December 1994, activity at Popocatepetl has been dominated by fumarolic emissions interspersed with more energetic emissions of ashes and gases. A phase of repetitive dome-building and dome-destroying episodes began in March 1996 and is still ongoing at present. We describe the long-period (LP) seismicity accompanying eruptive activity at Popocatepetl from December 1994 through May 2000, using data from a three-component broadband seismometer located 5 km from the summit crater. The broadband records display a variety of signals, with periods ranging in the band 0.04–90 s. Long-period events and tremor with typical dominant periods in the range 0.3–2.0 s are the most characteristic signals observed at Popocatepetl. These signals appear to reflect volumetric sources driven by pressure fluctuations associated with the unsteady transport of gases beneath the crater. Very-long-period (VLP) signals are also observed in association with LP events and tremor. The VLP signals which accompany LP events display Ricker-like wavelets with periods near 36 s, whereas VLP signals associated with tremor waveforms typically show sustained oscillations at periods ranging up to 90 s. The spectra and particle motion patterns remain similar from event to event for the majority of LP and tremor signals analyzed during the time span of this study, suggesting a repeated, non-destructive activation of a common source. Hypocenters determined by phase pick analyses of selected LP events recorded by the seven-station, permanent Popocatepetl short-period network suggest that the majority of these events are confined to a source region in the top 1.5 km below the crater floor. The repetitive occurrences of VLP signals with closely matched waveform characteristics are consistent with a non-destructive reactivation of at least two sources. One source appears to coincide with the main source region of LP seismicity, whereas the second is a deeper source whose activity appears to be intimately linked with episodes of monochromatic tremor.

Bulletin of Volcanology↗

USGS2010

Lava tube shatter rings and their correlation with lava flux increases at Kīlauea Volcano, Hawai‘i

Shatter rings are circular to elliptical volcanic features, typically tens of meters in diameter, which form over active lava tubes. They are typified by an upraised rim of blocky rubble and a central depression. Prior to this study, shatter rings had not been observed forming, and, thus, were interpreted in many ways. This paper describes the process of formation for shatter rings observed at Kīlauea Volcano during November 2005–July 2006. During this period, tilt data, time-lapse images, and field observations showed that episodic tilt changes at the nearby Pu‘u ‘Ō‘ō cone, the shallow magmatic source reservoir, were directly related to fluctuations in the level of lava in the active lava tube, with periods of deflation at Pu‘u ‘Ō‘ō correlating with increases in the level of the lava stream surface. Increases in lava level are interpreted as increases in lava flux, and were coincident with lava breakouts from shatter rings constructed over the lava tube. The repetitive behavior of the lava flux changes, inferred from the nearly continuous tilt oscillations, suggests that shatter rings form from the repeated rise and fall of a portion of a lava tube roof. The locations of shatter rings along the active lava tube suggest that they form where there is an abrupt decrease in flow velocity through the tube, e.g., large increase in tube width, abrupt decrease in tube slope, and (or) sudden change in tube direction. To conserve volume, this necessitates an abrupt increase in lava stream depth and causes over-pressurization of the tube. More than a hundred shatter rings have been identified on volcanoes on Hawai‘i and Maui, and dozens have been reported from basaltic lava fields in Iceland, Australia, Italy, Samoa, and the mainland United States. A quick study of other basaltic lava fields worldwide, using freely available satellite imagery, suggests that they might be even more common than previously thought. If so, this confirms that episodic fluctuation in lava effusion rate is a relatively common process at basaltic volcanoes, and that the presence of shatter rings in prehistoric lava flow fields can be used as evidence that such fluctuations have occurred.

Hawai'i↗

USGS2011

Shallow degassing events as a trigger for very-long-period seismicity at Kilauea Volcano, Hawaii

The first eruptive activity at Kīlauea Volcano’s summit in 25 years began in March 2008 with the opening of a 35-m-wide vent in Halema‘uma‘u crater. The new activity has produced prominent very-long-period (VLP) signals corresponding with two new behaviors: episodic tremor bursts and small explosive events, both of which represent degassing events from the top of the lava column. Previous work has shown that VLP seismicity has long been present at Kīlauea’s summit, and is sourced approximately 1 km below Halema‘uma‘u. By integrating video observations, infrasound and seismic data, we show that the onset of the large VLP signals occurs within several seconds of the onset of the degassing events. This timing indicates that the VLP is caused by forces—sourced at or very near the lava free surface due to degassing—transmitted down the magma column and coupling to the surrounding rock at 1 km depth.

Hawaii↗

USGS2019

Total grain size distribution of an intense Hawaiian fountaining event: Case study of the1959 Kīlauea Iki eruption

The 1959 eruption of Kīlauea Iki on the Island of Hawai’i is a principal example of powerful Hawaiian fountaining. Over 36 days (including repose periods), 16 fountaining episodes created a small cone, a downwind tephra blanket of approximately 0.003 km 3 and a lava lake of about 0.04 km 3 volume. During the explosive activity, the maximum fountain heights reached 600 m. Based on a dataset of more than 450 tephra grain size samples, we present both a total grain size distribution (TGSD) of the entire downwind tephra deposit, and also TGSDs for two eruptive subunits (the opening and the closing stages). The opening stage was characterized by persistent fountaining over a period of 8 days with fountain heights averaging ∼ 100 m; in contrast, the closing stage was characterized by two short (hours-long) but powerful fountaining episodes (up to 600 m). The significantly different fountaining intensities are reflected in the characteristics of the TGSDs. For the closing stages, we link bimodality of TGSDs to periods of simultaneous deposition of ballistics and fallout from the convective cloud, both of which are a function of the maximum fountain height. The 1959 Kīlauea Iki case study presents a well-constrained set of TGSD data linked with Hawaiian-style fountaining of two contrasting intensities and can be used as a valuable reference point for eruption source parameters in future modeling of pyroclast dispersal during Hawaiian fountaining eruptions.

Hawaii↗

USGS2024

Tracking magma pathways and surface faulting in the Southwest Rift Zone and the Koaʻe fault system (Kīlauea volcano, Hawai ‘i) using photogrammetry and structural observations

Volcanic islands are often subject to flank instability, resulting from a combination of magmatic intrusions along rift zones and gravitational spreading causing extensional faulting at the surface. Here, we study the Koaʻe fault system (KFS), located south of the summit caldera of Kīlauea volcano in Hawaiʻi, one of the most active volcanoes on Earth, prone to active faulting, episodic dike intrusions, and flank instability. Two rift zones and the KFS are major structures controlling volcanic flank instability and magma propagation. Although several magmatic intrusions occurred over the KFS, the link between these faults, two nearby rift zones and the flank instability, is still poorly studied. To better characterize the KFS and its structural linkage with the surrounding fault and rift zones, we performed a detailed structural analysis of the extensional fault system, coupled with a helicopter photogrammetric survey, covering part of the south flank of Kīlauea. We generated a high-resolution DEM (~ 8 cm) and orthomosaic (~ 4 cm) to map the fracture field in detail. We also collected ~ 1000 ground structural measurements of extensional fractures during our three field missions (2019, 2022, and 2023). We observed many small, interconnected grabens, monoclines, rollover structures, and en-echelon fractures that were in part previously undocumented. We estimate the cumulative displacement rate across the KFS during the last 600 ~ 700 years and found a decrease toward the west of the horizontal component from 2 to 6 cm per year, consistent with GNSS data. Integrating morphology observations, fault mapping, and kinematic measurements, we propose a new kinematic model of the upper part of the Kīlauea’s south flank, suggesting a clockwise rotation and a translation of a triangular wedge. This wedge is bordered by the extensional structures (ERZ, SWRZ, and the KFS), largely influenced by gravitational spreading. These findings illustrate a structural linkage between the two rift zones and the KFS, the latter being episodically affected by dike intrusions.

Hawaii↗

USGS2019

Landscape evolution of a fluvial sediment-rich Avicennia marina mangrove forest: Insights from seasonal and inter-annual surface-elevation dynamics

Mangrove forests are vulnerable to accelerated sea-level rise associated with climate warming because they occupy a relatively narrow zone on the mid-to-upper-intertidal flats. The fate of these ecosystems largely depends on their capacity to accrete sediment at a rate sufficient to maintain their elevation relative to sea level. We investigated the role of biophysical processes and feedbacks controlling surface-elevation dynamics in a fluvial sediment-rich Avicennia marina mangrove forest (New Zealand) at seasonal-to-inter-annual timescales (over 9 years) using the Rod Surface Elevation Table method. We found that sediment accretion in the forest was not measurably enhanced by episodic and short-lived storm discharges from rivers nor by elevated sea levels during storms. Critically, the coupling of frequent onshore winds and resulting resuspension of intertidal muds, with the fortnightly cycle of spring tide inundation, controlled sediment delivery and resulting accretion rates of 13 to 47 mm y −1 . In turn, net surface-elevation trends of 0 to 28 mm y −1 were dominated by the physical processes of sediment accretion and shallow subsidence due to seasonal desiccation and resulting compaction of the infrequently inundated forest platform (4 to 16 mm y −1 ). Our data suggest that monthly and seasonal variation in tidally controlled hydroperiod and sediment delivery rather than episodic storm events are important for the maintenance of mangrove elevation within the intertidal zone.

Firth of Thames↗

USGS2023

Detection and quantification of preferential flow using artificial rainfall with multiple experimental approaches

Preferential flow in the unsaturated zone strongly influences important hydrologic processes, such as infiltration, contaminant transport, and aquifer recharge. Because it entails various combinations of physical processes arising from the interactions of water, air, and solid particles in a porous medium, preferential flow is highly complex. Major research is needed to improve the ability to understand, quantify, model, and predict preferential flow. Toward a solution, a combination of diverse experimental measurements at multiple scales, from laboratory scale to mesoscale, has been implemented to detect and quantify preferential paths in carbonate and karstic unsaturated zones. This involves integration of information from (1) core samples, by means of mercury intrusion porosimeter, evaporation, quasi-steady centrifuge and dewpoint potentiometer laboratory methods, to investigate the effect of pore-size distribution on hydraulic characteristics and the potential activation of preferential flow, (2) field plot experiments with artificial sprinkling, to visualize preferential pathways related to secondary porosity, through use of geophysical measurements, and (3) mesoscale evaluation of field data through episodic master recession modeling of episodic recharge. This study demonstrates that preferential flow processes operate from core scale to two different field scales and impact on the qualitative and quantitative groundwater status, by entailing fast flow with subsequent effects on recharge rate and contaminant mobilizing. The presented results represent a rare example of preferential flow detection and numerical modeling by reducing underestimation of the recharge and contamination risks.

Bari↗

USGS2006

Solute sources in stream water during consecutive fall storms in a northern hardwood forest watershed: A combined hydrological, chemical and isotopic approach

Understanding the effects of climate change including precipitation patterns has important implications for evaluating the biogeochemical responses of watersheds. We focused on four storms in late summer and early fall that occurred after an exceptionally dry period in 2002. We analyzed not only the influence of these storms on episodic chemistry and the role of different water sources in affecting surface water chemistry, but also the relative contributions of these storms to annual biogeochemical mass balances. The study site was a well studied 135-ha watershed in the Adirondack Park of New York State (USA). Our analyses integrated measurements on hydrology, solute chemistry and the isotopic composition of NO 3 − (δ 15 N and δ 18 O) and SO 4 2− (δ 34 S and δ 18 O) to evaluate how these storms affected surface water chemistry. Precipitation amounts varied among the storms (Storm 1: Sept. 14–18, 18.5 mm; Storm 2: Sept. 21–24, 33 mm; Storm 3: Sept. 27–29, 42.9 mm; Storm 4: Oct. 16–21, 67.6 mm). Among the four storms, there was an increase in water yields from 2 to 14%. These water yields were much less than in studies of storms in previous years at this same watershed when antecedent moisture conditions were higher. In the current study, early storms resulted in relatively small changes in water chemistry. With progressive storms the changes in water chemistry became more marked with particularly major changes in C b (sum of base cations), Si, NO 3 − , and SO 4 2− , DOC and pH. Analyses of the relationships between Si, DOC, discharge and water table height clearly indicated that there was a decrease in ground water contributions (i.e., lower Si concentrations and higher DOC concentrations) as the watershed wetness increased with storm succession. The marked changes in chemistry were also reflected in changes in the isotopic composition of SO 4 2− and NO 3 − . There was a strong inverse relationship between SO 4 2− concentrations and δ 34 S values suggesting the importance of S biogeochemical redox processes in contributing to SO 4 2− export. The isotopic composition of NO 3 − in stream water indicated that this N had been microbially processed. Linkages between SO 4 2− and DOC concentrations suggest that wetlands were major sources of these solutes to drainage waters while the chemical and isotopic response of NO 3 − suggested that upland sources were more important. Although these late summer and fall storms did not play a major role in the overall annual mass balances of solutes for this watershed, these events had distinctive chemistry including depressed pH and therefore have important consequences to watershed processes such as episodic acidification, and the linkage of these processes to climate change.

Biogeochemistry↗

USGS1980

U-Pb ages of uraniferous opals and implications for the history of beryllium, fluorine, and uranium mineralization at Spor Mountain, Utah

The U-Pb isotope systematics of uraniferous opals from Spor Mountain, Utah, were investigated to determine the suitability of such material for geochronologic purposes, and to estimate the timing of uranium and associated beryllium and fluorine mineralization. The results indicate that uraniferous opals can approximate a closed system for uranium and uranium daughters, so that dating samples as young as ∼1 m.y. should be possible. In addition, the expected lack of initial 230 Th and 231 Pa in opals permits valuable information on the initial 234 U/ 238 U to be obtained on suitable samples of ≲10 m.y. age. The oldest 207 Pb/ 235 U apparent age observed, 20.8 ± 1m.y., was that of the opal-fluorite core of a nodule from a beryllium deposit in the Spor Mountain Formation. This age is indistinguishable from that of fission-track and K-Ar ages from the host rhyolite, and links the mineralization to the first episode of alkali rhyolite magmatism and related hydrothermal activity at Spor Mountain. Successively younger ages of 13 m.y. and 8–9 m.y. on concentric outer zones of the same nodule indicate that opal formed either episodically or continuously for over 10 m.y. Several samples of both fracture-filling and massive-nodule opal associated with beryllium deposits gave 207 Pb/ 235 U apparent ages of 13–16 m.y., which may reflect a restricted period of mineralization or perhaps an averaging of 21−and<13−m.y. periods of opal growth. Several samples of fracture-filling opal in volcanic rocks as young as 6 m.y. gave 207 Pb/ 235 U ages of 3.4–4.8 m.y. These ages may reflect hot-spring activity after the last major eruption of alkali rhyolite.

Utah↗

USGS1987

15N/14N variations in Cretaceous Atlantic sedimentary sequences: Implication for past changes in marine nitrogen biogeochemistry

At two locations in the Atlantic Ocean (DSDP Sites 367 and 530) early to middle Cretaceous organic-carbon-rich beds (“black shales”) were found to have significantly lower δ 15 N values (lower 15 N/ 14 N ratios) than adjacent organic-carbon-poor beds (white limestones or green claystones). While these lithologies are of marine origin, the black strata in particular have ° 15 N values that are significantly lower than those previously found in the marine sediment record and most contemporary marine nitrogen pools. In contrast, black, organic-carbon-rich beds at a third site (DSDP Site 603) contain predominantly terrestrial organic matter and have C- and N-isotopic compositions similar to organic matter of modern terrestrial origin. The recurring 15 N depletion in the marine-derived Cretaceous sequences prove that the nitrogen they contain is the end result of an episodic and atypical biogeochemistry. Existing isotopic and other data indicate that the low 15 N relative abundance is the consequence of pelagic rather than post-depositional processes. Reduced ocean circulation, increased denitrification, and, hence, reduced euphotic zone nitrate availability may have led to Cretaceous phytoplankton assemblages that were periodically dominated by N 2 -fixing blue-green algae, a possible source of this sediment 15 N-depletion. Lack of parallel isotopic shifts in Cretaceous terrestrially-derived nitrogen (Site 603) argues that the above change in nitrogen cycling during this period did not extend beyond the marine environment.

Earth and Planetary Science Letters↗

USGS1984

Pegmatite/wallrock interactions, Black Hills, South Dakota: Progressive boron metasomatism adjacent to the Tip Top pegmatite

Interaction between country rock and fluids derived from the Tip Top pegmatite has resulted in a series of boron enriched assemblages. Between unaltered quartz-mica schist to the pegmatite contact is a succession of four mineral assemblages: 1. (1) Quartz-Biotite-Potassium Feldspar assemblage (Q-B-K), which consists essentially of the original metamorphic silicate assemblage plus anomalously high amounts of modal tourmaline 2. (2) Quartz-Biotite-Tourmaline assemblage (Q-B-T) 3. (3) Tourmaline-Quartz-Muscovite assemblage (T-Q-M) 4. (4) Tourmaline-Quartz assemblage (T-Q). Alkali elements (Cs, Rb, K, Li), SiO 2 , and Ba show a decrease from the Q-B-K assemblage to the T-Q assemblage. A1 2 O 3 , Ga, B, total Fe and Zn increase moderately from the Q-B-K assemblage to the T-Q assemblage. The mineral chemistries also change considerably. The Mg/(Mg + Fe 2+ ) ratios in biotites range from 0.54 to 0.50 in samples from the Q-B-K assemblage to 0.39 in the (Q-B-T) assemblage. The range in tourmaline end-member components from the Q-B-K assemblage to the T-Q assemblage is as follows: Q-B-K: Dravite .63 Schorl .23 Elbaite .05 Buergerite .09 T-Q: Dravite .23 Schorl .37 Elbaite .17 Buergerite .23 . Observed variations in mineral assemblage and whole rock chemistry within the alteration zone appear to a first approximation to be a function of μB 2 O 3 (boron metasomatism) and μK 2 O (alkali leaching). The breakdown of feldspar and biotite may be approximated by reactions: 2HCl + 2(K, Na)AlSi 3 O 8 /ai 2(K, Na)Cl + Al 2 SiO 5 + 5SiO 2 + H 2 O and 2 Annite + SiO 2 + 5Al 2 SiO 5 + 2NaCl + 6H 3 BO 3 /ai 2 Tourmaline + 2KCl + 7H 2 O. The alteration zone may represent either a single episode (B-, Cs-, Li-, Rb-enriched fluid) or multiple episodes (B, Zn, Mn fluid and Cs, Li, Rb fluid) of pegmatite fluid-schist interactions. In both situations, B in the aqueous fluid from the pegmatite reacts with the schist breaking down sheet silicate “traps” for Cs, Rb, Li, and K and forming tourmaline-rich assemblages.

Geochimica et Cosmochimica Acta↗

USGS1993

Thermochronology of the Cornubian batholith in southwest England: Implications for pluton emplacement and protracted hydrothermal mineralization

The metalliferous ore deposits of southwest England are associated with biotite-muscovite granites that intruded upper Paleozoic sediments and volcanic rocks at the end of the Hercynian Orogeny. The hydrothermal mineralization can be subdivided into four stages: 1. exoskarns 2. high-temperature tin and tungsten oxide-bearing sheeted greisen bordered veins and Sn-bearing tourmaline veins and breccias 3. polymetallic quartz-tourmaline-chlorite-sulfide-fluorite-bearing fissure veins, which represent the main episode of economic mineralization 4. late-stage, low-temperature polymetallic fluorite veins. U-Pb dating of monazite and xenotime and 40 Ar 39 Ar "> 40 Ar 39 Ar dating of muscovite were used to determine emplacement ages and cooling times for individual plutons within the Cornubian batholith, as well as separate intrusive phases within the plutons. In addition, 40 Ar 39 Ar "> 40 Ar 39 Ar ages from hornblende and secondary muscovite and Sm-Nd isochron ages from fluorite were employed to determine the relationship between pluton emplacement and different stages of mineralization. The U-Pb ages indicate that granite magmatism was protracted from ~300 Ma down to ~275 Ma with no evidence of a major hiatus. There is no systematic relation between the age of a pluton and its location within the batholith. The U-Pb ages for separate granite phases within a single pluton are resolvable and indicate that magma emplacement within individual plutons occurred over periods of as much as 4.5 myrs. Felsic porphyry dike emplacement was coeval with plutonism, but continued to ~270 Ma. The geochronologic data suggest that the Cornubian batholith originated from repeated melting events over 30 myrs and was formed by a series of small coalescing granitic bodies. Cooling rates of the main plutons are unrelated to emplacement age, but decrease from the southwest to the northeast from ~210°C myr −1 to ~60°C myr −1 with a mean of 100°C myr −1 . These slow cooling rates appear to reflect the addition of heat from multiple intrusive episodes. The mineralization history is distinct for each pluton and ranges from coeval with, to up to 40 myrs younger than the cooling age for the host pluton. Stage 2 mineralization is broadly synchronous with the emplacement of granite magmas, is dominated by fluids expelled during crystallization, and may be repeated by the emplacement of younger magmas within the same pluton. Sm-Nd isochrons for fluorite from stage 3 polymetallic mineralization give ages of 259 ± 7, 266 ± 3 and 267 ± 12 Ma, postdating stage 2 mineralization by up to 25 myrs within the same deposit. The similarity in age of the main polymetallic mineralization hosted by the oldest and youngest plutons, suggests that this stage of mineralization is unlikely to be related to hydrothermal circulation driven by the emplacement and cooling of the host granite. The mineralization is more likely the product of regional hydrothermal circulation driven by heat from the emplacement and crystallization of younger buried pulses of magma.

Cornubian Batholith↗

USGS1993

Composition of steam in the system NaCl-KCl-H 2 O-quartz at 600°C

In the system NaCl-KCl-H2O, with and without ??-quartz present, steam was equilibrated in a large-volume reaction vessel with brine and/or precipitated salt at 600??C and pressures ranging from about 100 to 0.4 MPa. Episodically, steam was extracted for chemical analysis, accompanied by a decrease in pressure within the reaction vessel. In the absence of precipitated salt, within the analytical uncertainty stoichiometric quantities of Cl and total alkali, metals (Na + K) dissolve in steam coexisting with chloriderich brine. In contrast, in the presence of precipitated salt (in our experiments halite with some KCl in solid solution), significant excess chloride as associated hydrogen chloride (HCl0??) dissolves in steam. The HCl0 is generated by the reaction of steam with solid NaCl(s), producing solid NaOH(s) that diffuses into halite, forming a solid solution. In our quasistatic experiments, compared to dynamic flow-through experiments of others, higher initial ratios of H2O/NaCl have apparently resulted in higher model fractions of NaOH(s) in solid solution in halite. This, in turn, resulted in incrementally higher concentrations of associated NaOHo dissolved in steam. Addition of quartz to the system NaCl + KC1 + H2O resulted in an order of magnitude increase in the concentration of HCl0 dissolved in steam, apparently as a consequence of the formation of sodium disilicate by reaction of silica with NaOH(s). The measured dissolved silica in steam saturated with alkali halides at 600??C in the pressure range 7-70 MPa agrees nicely with calculated values of the solubility of ??-quartz obtained using the equation of Fournier and Potter (1982), corrected for dissolved salt by the method of fournier (1983). Na K ratios in steam at 600??C tend to be slightly greater than in coexisting brine. When precipitated halite is present, larger mole fractions of NaOH(s) in solid solution in that halite apparently result in even larger Na K ratios in coexisting steam. Precipitation of more halite as a consequence of repeated depressurization episodes results in decreased Na K ratios in both the brine and coexisting steam phases, indicating that the lower pressures begin to favor K over Na in the vapor. When steam is in contact with precipitated salts in the absence of brine, the Na K ratio in the steam is less than that of the bulk composition of the salt-H2O system. ?? 1993.

Geochimica et Cosmochimica Acta↗

USGS1990

D/H on Mars: Effects of floods, volcanism, impacts, and polar processes

Water in the Martian atmosphere is 5.1 times more enriched in deuterium than terrestial water. The enrichment has been previously attributed to either a massive loss of water early in the planet's history or the presence of only a very small reservoir of water that has exchanged with the atmosphere over geologic time. Both these interpretations appear inconsistent with geologic evidence of large floods and sustained volcanism. Large floods are believed to have episodically introduced large amounts of water onto the surface. During a large flood roughly 10 17 g of water would almost immediately sublime into the atmospher and be frozen out on polar terrain, to form a new layer several centimeters thick. The long-term effect of a flood would depend on where the water pooled after the flood. If the water pooled at low latitudes, all the water would slowly sublime into the atmosphers and ultimately be frozen out at the poles, thereby adding several meters to the polar deposits for each flood. If the water pooled at high latitude, it would form a permanent ice deposit, largely isolated from further interchange with the atmosphere. Volcanism has also episodically introduced water into the atmosphere. Most of this water has become incorporated into the polar deposits. That released over the last 3.5 Ga could have added a few kilometers to the polar deposits, depending on the amount of dust incorporated along with the ice. Large cometary impacts would have introduced additional large amounts of water into the atmosphere. The long-term evolution of D/H in the atmosphere depends on the rate of exchange of water between the atmosphere and the polar deposits. If exchange is active, then loss rates of hydrogen from the upper atmosphere are substantially higher than those estimated by Y. L. Yung, J. Wen, J. P. Pinto, M. Allen, K. K. Pierce, and S. Paulsen [ Icarus 76, 146–159 (1988)]. More plausibly, exchange of water between the atmosphere and the polar deposits is limited, so that after eruptions, floods, and cometary impacts, the atmosphere soon becomes enriched in deuterium. According to this scenario, the atmospheric D/H is different from the bulk of the planet's water and so reveals little about the amount of water outgassed. The scenario implies, however, that the polar deposits are older and more stable than formerly thought.

Icarus↗

USGS1989

Seepage through a hazardous-waste trench cover

Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216 mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.

Illinois↗