USGS ScienceSearch

SEARCH · USGS Science

Results for “Avian Conservation and Ecology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,656 records · Page 18Linked to original sources

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming

Estimated average annualized losses from potential building damage and fatalities due to earthquake-generated tsunamis in the United States

Earthquake-generated tsunamis represent substantial economic threats to states and territories in the United States (U.S.), but we are unaware of any effort to quantify potential impacts at the national level. This gap is partially due to the lack of nationally consistent data on tsunamigenic sources and associated return periods. This study addresses this issue and provides estimates of average annualized losses (AAL) for potential residential fatalities and capital stock losses associated with building damage (i.e., structural, non-structural, contents, and inventory damage) in the U.S. by curating tsunami-hazard information based on deterministic scenarios and probabilistic approaches, calculating potential losses, and estimating return periods where necessary. This assessment was done for the U.S. West Coast, Alaska, Hawaii, U.S. Pacific Territories, and U.S. Atlantic Territories. We estimate that earthquake-generated tsunamis that could affect these states and territories collectively represent $1 billion in potential AAL with 79 % of losses due to residential fatalities and 21 % of losses due to capital stock losses from building damage. We identify AAL variations based on county and county equivalents, states and territories, geographic regions, return periods, and departure-delay assumptions for evacuating residents. Results include high AAL values for potential fatalities in Puerto Rico and the U.S. Pacific Northwest region, high AAL values for potential building-related damage in Hawaii and California, and high building- and population-loss ratios for county equivalents in Alaska and U.S. territories.

International Journal of Disaster Risk Reduction

Continental-scale prediction of hydrologic signatures and processes

Understanding how dominant hydrologic processes and their drivers vary across diverse continental-scale landscapes is critical for hydrologic modeling and water management applications. Our research addresses this question by synthesizing large-sample watershed datasets, Caravan and GAGES-II, and developing random forest models to identify patterns in hydrologic function. We assessed dominant processes by examining hydrologic signatures – summary indicators of watershed function derived from hydroclimatic time series and random forest models across 14 146 gauged United States watersheds. The results reveal clear continental-scale gradients in hydrologic processes, including baseflow, overland flow, storage, and water balance losses. Our map of dominant processes highlights, for example, the transition from baseflow to fast responses and back to baseflow along the elevation gradient from the Appalachian spine, through the Piedmont, to the Eastern Coastal Plain; a distinct outer ring around the Great Lakes region; and sharp contrasts between coastal and inland processes in the West. Variable importance analysis from random forest models show that processes in the western U.S. are primarily controlled by climate, whereas in the eastern U.S., soil, geology, and topography play larger roles, with distinct human influences apparent in urban areas. Our approach of estimating dominant processes and their drivers facilitates extending process knowledge from research watersheds to the continental scale, assessing current hydrological understanding, and evaluating hydrological model structures.

conterminous United States

Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Arkansas, Kansas, Missouri, Oklahoma

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana

A roadmap for identifying and interpreting physical processes and national water model prediction bias associated with baseflow index regimes across the contiguous United States

Understanding how groundwater–surface water interactions shape streamflow variability is critical for diagnosing low flow behavior and prediction bias in continental scale hydrologic models. We present a process informed framework that links observed baseflow (BF) dynamics, watershed attributes, and National Water Model (NWM) performance across the contiguous United States. Using daily observed streamflow from 797 reference quality streamgages, we developed monthly baseflow index (BFI) signatures using a streamgage specific, calibrated digital filter. Hierarchical clustering of these signatures identified seven distinct BFI regimes capturing regional and seasonal variability. We evaluated NWM v3.0 retrospective streamflow performance within each regime using multiple hydrograph and flow duration curve-based metrics. Model skill varied systematically across regimes: mixed flow systems were simulated most accurately, while predominantly BF dominated and quickflow dominated regimes exhibited substantially poorer performance. Across nearly all regimes, the NWM underestimated observed BFI magnitude and frequently failed to reproduce seasonal BF patterns, indicating systematic biases in simulated low flow contributions. To relate these regimes to potential process controls, we trained a Random Forest classifier using static watershed attributes and applied Shapley Additive Explanations to identify features most strongly associated with each regime. Results highlight regionally varying influences, including the dominant role of snow fraction and seasonal runoff timing in snow dominated basins and the importance of evapotranspiration and aridity in quickflow dominated systems. Collectively, these findings demonstrate how hydrologic signatures combined with interpretable machine learning can diagnose regime specific model biases and generate process-based hypotheses about limitations in large scale hydrologic prediction systems.

contiguous United States

Updating and recalibrating the integrated Santa Rosa Plain Hydrologic Model to assess stream depletion and to simulate future climate and management scenarios in Santa Rosa, Sonoma County, California

The Santa Rosa Plain Hydrologic Model (SRPHM) was developed and published in 2014 through a collaboration between the U.S. Geological Survey (USGS) and Sonoma Water to analyze the hydrologic system in the Santa Rosa Plain watershed, help meet the increasing demand for fresh water, and prepare for future uncertainties in water resources. The original model simulated hydrological conditions and water use from water years 1975 to 2010. Recently (2023), the USGS, in cooperation with Sonoma Water and the California State Water Resources Control Board, updated the SRPHM model to extend its simulation period to the end of the 2018 calendar year, incorporate new estimates of rural and agricultural water use, and use efficient input format for climate variables. The updated model was recalibrated, and evaluation of the new model calibration is included in this report. This report presents the results of comparing the hydraulic heads, streamflow, and groundwater budget simulated by the updated model with those generated by the original model and observed data. The main difference in the simulated budget between the original and updated SRPHM is the estimates of agricultural pumping, rural domestic pumping, and return flow generated from rural water use that was not simulated in the original model. The revised agricultural pumping is simulated using the agricultural package, which constrains pumping to available groundwater. The use of the agricultural package leads to a more realistic estimation of agricultural water use, with revised agricultural pumping being one-third less than that in the original model. The revised rural pumping is about half of the pumping in the original model because of using detailed parcel data to estimate population density in rural areas instead of coarse census tracts. Overall, average total inflows for water years 2006–10 simulated by the updated model were about 2 percent less than the original model, and the average total updated outflows were nearly 5 percent less than the original model. The updated model was then used to generate stream depletion maps, simulate climate change scenarios during 2019–99, and simulate water rights allocation using the Model for Decision Support in Integrated River Basin Management (MODSIM). The results from simulating eight future climate scenarios indicated either an increase in groundwater storage or no significant change in the next 80 years, along with an increase in recharge, an increase in actual evapotranspiration in six out of eight climate projections, and an increase in surface runoff. The increases in the simulated future groundwater storage, recharge, evapotranspiration, and runoff in most climate projections are mainly driven by the projected increase in precipitation in most of the future climate scenarios. The updated model also was used to test a pilot case study demonstrating water-resource allocation among different users with different water rights using the integrated MODSIM-Groundwater and Surface-Water Flow Model (GSFLOW) platform. The updated SRPHM serves as a valuable tool for analyzing historical and future hydrologic conditions in the Santa Rosa Plain watershed and preparing for future uncertainties.

California

Lunar grid systems, coordinate systems, and map projections for the Artemis missions and lunar surface navigation

Foreward This document contains design specifications of a navigational standard for the Moon, including a Lunar Transverse Mercator system, a Lunar Polar Stereographic system, a Lunar Grid Reference System, and a unique coordinate structure, Artemis Condensed Coordinates, for Artemis mission navigation and lunar surface science. The National Aeronautics and Space Administration (NASA) Artemis campaign seeks to place humans on the Moon for the first time since the Apollo missions. Early Artemis missions are heavily focused on the lunar south pole, which promises to return valuable data on the Moon’s geologic record, amongst other mission objectives. Coordinate systems in use today for the lunar south pole provides crew members on the surface neither an efficient nor intuitive means to communicate their position and orientation. A novel grid coordinate system, the Lunar Grid Reference System, is proposed to address these concerns for use in real-time extravehicular activity operations on the lunar surface. The many stakeholders involved in the Artemis missions will need a common system to communicate position and orientation while astronauts are operating on the lunar surface. To that end, Artemis crew members will need that system to be efficient and intuitive to promote efficient extravehicular activity timelines and reduce confusion. In the context of this document, these characteristics are addressed on the design of lunar coordinate systems: Efficient.—The number of characters required to communicate a location within a desired precision level in both local and global contexts, and how many steps are required for a recipient or sender to interpret a location. Intuitive.—How well the system aligns with human perceptual abilities, and whether the system yields distances that have the same relationship to actual lunar surface distance in all directions from the point where a person is located. Technological systems are currently being investigated to supplement the crew members’ ability to locate and orient themselves and other assets on the lunar surface; however, it is unlikely that those systems will be fully operational for the first few landed missions. Even with future positional aids, crew members will still need an efficient and intuitive means to communicate position and orientation. In addition, if technological systems fail, the crews will require land navigation skills and have maps available, thus providing further motivation for a crew-centric coordinate system. The contents of this U.S. Geological Survey (USGS) document detail a comprehensive framework for standardizing lunar crewed surface navigation within NASA and outlines the protocols, methods, and designs necessary for achieving consistency and interoperability across relevant space mission teams and lunar surface navigators. Key components of this document include designs of map projections, projected coordinate reference systems (Lunar Transverse Mercator and Lunar Polar Stereographic systems), and a grid system (Lunar Grid Reference System and Artemis Condensed Coordinates) for the Moon. The work proposed in this document seeks to accomplish something similar to the National Geospatial-Intelligence Agency (NGA) document SIG 0012 (NGA, 2014a), but for using grid systems for the Moon. This report incorporates initial feedback and input from NASA’s Artemis Geospatial Data Team, NASA’s Flight Operations Directorate, National Geodetic Survey, USGS Astrogeology Science Center, and NGA and is intended to serve as a resource for all involved with the Artemis missions, as well as for engineers designing and operating lunar infrastructure.

Techniques and Methods

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research

Afterslip and creep in the rate-dependent framework: Joint inversion of borehole strain and GNSS displacements for the Mw 7.1 Ridgecrest earthquake

The elusive transition toward afterslip following an earthquake is challenging to capture with typical data resolution limits. A dense geodetic network recorded the Mw 7.1 Ridgecrest earthquake, including 16 Global Navigation Satellite System (GNSS) stations and 3 borehole strainmeters (BSM). The sub-nanostrain precision and sub-second sampling rate of BSMs bridges a gap between conventional seismologic and geodetic methods, exemplified by atypical postseismic shear strain reversals observed at nearfield (<2 km) station B921 that remain unexplained. We jointly invert GNSS displacements and BSM strains for coseismic and postseismic slip spanning hours to months over 7 independent periods. Cosiesmically, our model resolves the largest slip magnitudes of up to 6.6 m on the mainshock rupture plane, with similar patterns to other inferred slip distributions. The foreshock fault appears to slip coincidently with mainshock, revealing potential asperities activated during the preceding Mw 6.4 event. Postseismically, the best-fitting models adhere to mechanical rate-and-state expectations of logarithmically decaying slip adjacent to the coseismic rupture terminus, and where deep rheologic conditions favor creep. Most spatial variation occurs in the early postseismic timeframe (<1–2 weeks), with evidence for regional rheologic control and static stress dependence. Triggered creep on the neighboring Garlock Fault unexpectedly persists for >178 days—further highlighting the importance of fault networks in postseismic stress redistribution, critical to assessing future hazard.

Journal of Geophysics Research

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Analysis of information on nutrients, suspended sediment, and suspended solids, 1970-92

Water-quality data collected during water years 1970-90 (October 1 to September 30) for 83 surface-water sites and during 1970-92 for 395 ground-water sites in the 48,000 square mile Ozark Plateaus study unit of the National Water Quality Assessment Program were analyzed using selected descriptive and statistical methods. The water- quality data include nutrient (nitrogen and phosphorus), suspended sediment, and suspended- solids data, and ancillary information such as fertilizer use, animal waste, sewage treatment plant, and land use. Statistically significant differences exist in surface-water quality that can be attributed to physiography, land use, and other effects. The sites that were considered to be substantially affected by sewage treatment plants had the largest concentrations of nutrients. Nutrient concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. Statistically significant differences existed in the quality of ground water that can be attributed to hydrogeologic and land-use effects. Nutrient concentrations generally were largest where the water source is indicated to be shallow in origin and where parts of the hydrogeologic units are in agricultural land-use areas. Water quality has changed at several surface-water sites since 1970. Nutrient concentrations appear to have increased at some sites and decreased at other sites. Causes of these apparent trends are not known, but many of the sites with apparent trends are in agricultural areas. Surface-water loads of nutrients and suspended sediment were affected by several factors including streamflow, climate, drainage area, reservoir operation, and inputs from point and nonpoint sources. Annual loads were largest in large basins, with large inputs of nutrients or sediment during periods of high streamflows at locations where reservoir operation effects are not substantial.

Arkansas, Kansas, Missouri, Oklahoma

Comparisons of shoreline positions from satellite-derived and traditional field- and remote-sensing techniques

Satellite-derived shorelines (SDS) have the potential to help researchers answer critical coastal science questions and support work to predict coastal change by filling in the spatial and temporal gaps present in current field-based and remote-sensing data collection methods. The U.S. Geological Survey conducted comparison analyses of traditionally sourced shorelines and SDS in diverse coastal landscapes to determine how SDS could be used in ongoing and future work across varied coastal environments and provided some initial findings that could be used for implementation. Using CoastSeg, a browser-based program for SDS detection and mapping, SDS for the period 1984–2023 for multiple locations across the United States were compared to shoreline positions from traditionally sourced shoreline data. In this report, the authors present these comparisons alongside lessons learned and challenges encountered when building SDS workflows in different coastal locations. Results show that individual SDS have larger uncertainty and yet produced similar linear trends to sparser, traditionally sourced shoreline data; because SDS methods provide orders of magnitude more data than traditional shoreline-detection methods, they can be used to evaluate shoreline behaviors. Refining average scalar slopes used in tidal corrections did not result in substantial decreases in uncertainty. Using lessons from this work to outline needs for regional implementation, initial setup time would be considerable, being on the order of weeks. However, once complete, shoreline detections and analyses are fast (on the order of minutes to hours) and achievable using a desktop computer.

Alaska, Florida, Massachusetts, Washington