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At least 325 records · Page 18Linked to original sources

USGS2005

Successional trends in Sonoran Desert abandoned agricultural fields in northern Mexico

Excessive ground-water use and saline intrusion to the aquifer led, in less than three decades, to an increase in abandoned agricultural fields at La Costa de Hermosillo, within the Sonoran Desert. Using a chronosequence from years since abandonment, patterns of field succession were developed. Contrary to most desert literature, species replacement was found, both in fields with and without saline intrusion. Seasonal photosynthetic capacity as well as water and nitrogen use efficiencies were different in dominant early and late successional plant species. These ecological findings provided a framework for a general explanation of species dominance and replacement within abandoned agricultural fields in the Sonoran Desert. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Arid Environments↗

USGS2013

Phosphorus losses from agricultural watersheds in the Mississippi Delta

Phosphorus (P) loss from agricultural fields is of environmental concern because of its potential impact on water quality in streams and lakes. The Mississippi Delta has long been known for its fish productivity and recreational value, but high levels of P in fresh water can lead to algal blooms that have many detrimental effects on natural ecosystems. Algal blooms interfere with recreational and aesthetic water use. However, few studies have evaluated P losses from agricultural watersheds in the Mississippi Delta. To better understand the processes influencing P loss, rainfall, surface runoff, sediment, ortho-P (orthophosphate, PO 4 –P), and total P (TP) were measured (water years 1996–2000) for two subwatersheds (UL1 and UL2) of the Deep Hollow Lake Watershed and one subwatershed of the Beasley Lake Watershed (BL3) primarily in cotton production in the Mississippi Delta. Ortho-P concentrations ranged from 0.01 to 1.0 mg/L with a mean of 0.17 mg/L at UL1 (17.0 ha), 0.36 mg/L at UL2 (11.2 ha) and 0.12 mg/L at BL3 (7.2 ha). The TP concentrations ranged from 0.14 to 7.9 mg/L with a mean of 0.96 mg/L at UL1, 1.1 mg/L at UL2 and 1.29 mg/L at BL3. Among the three sites, UL1 and UL2 received P application in October 1998, and BL3 received P applications in the spring of 1998 and 1999. At UL1, ortho-P concentrations were 0.36, 0.25 and 0.16 for the first, second and third rainfall events after P application, respectively; At UL2, ortho-P concentrations were 1.0, 0.66 and 0.65 for the first, second and third rainfall events after P application, respectively; and at BL3, ortho-P concentrations were 0.11, 0.22 and 0.09 for the first, second and third rainfall events after P application, respectively. P fertilizer application did influence P losses, but high P concentrations observed in surface runoff were not always a direct result of P fertilizer application or high rainfall. Application of P in the fall (UL1 and UL2) resulted in more ortho-P losses, likely because high rainfall often occurred in the winter months soon after application. The mean ortho-P concentrations were higher at UL1 and UL2 than those at BL3, although BL3 received more P application during the monitoring period, because P was applied in spring at BL3. However, tillage associated with planting and incorporating applied P in the spring (BL3) may have resulted in more TP loss in sediment, thus the mean TP concentration was the highest at BL3. Ortho-P loss was correlated with surface runoff; and TP loss was correlated with sediment loss. These results indicate that applying P fertilizer in the spring may be recommended to reduce potential ortho-P loss during the fallow winter season; in addition, conservation practices may reduce potential TP loss associated with soil loss.

Mississippi↗

USGS2020

Monthly suspended-sediment apportionment for a western Lake Erie agricultural tributary

Black Creek, a headwater to the Maumee River and western Lake Erie, is an agricultural basin with a mix of cropland (66%), pasture (19%), and forest (7%) linked by a road network to the rural community. Suspended sediment was collected monthly during the 2018 water year for the main stem and two sub-basins using in-situ, passive samplers that integrated a range of streamflow conditions. Sediment fingerprinting used 44 indicators to apportion samples among five sources: cropland, pasture, forest, road dirt, and streambanks. Cropland, pasture, and streambanks had similar ranges in sediment-bound phosphorus (679-1670 ppm). Cropland contributed 21 ± 15% (monthly mean ± standard deviation; 0-46% among individual months) of suspended sediment during the year. Fall and spring peaks in cropland contribution highlight the ongoing importance of on-field management, but this small contribution of suspended sediment relative to the expanse of cropland may reflect implementation of best-management practices. Pasture contributed 0-66% (16±19%) of suspended-sediment and roads 0-26% (6±6%). Streambanks contributed 12-100% (55±25%) and was the only source identified in all sediment samples. In this basin, most cropland-adjacent streambanks are protected by a riparian setback. However, streams traversing other land-use types are not as consistently protected, and these setbacks do not protect the stream channel from discharge of water from sump pumps, road culverts, or tile drains. The contribution of sediment from other land uses combined with that from the agricultural drainage network (as streambank material) underscores the need to consider water movement in the basin as a whole.

Indiana↗

USGS2026

Sources and streambed storage of soft sediment and sediment-bound phosphorus in an agricultural Great Lakes tributary

The East River, an agricultural tributary to the Lower Fox River and Lake Michigan in Wisconsin, USA, has excessive phosphorus (P) and suspended-sediment loads that contribute to downstream eutrophication and habitat-related impairments. Spatial variations and connectivity in the sources and streambed storage of soft, fine-grained (silt and clay) sediment and related sediment-bound P (sed-P) were examined, from first-order ephemeral channels to a downstream water-monitoring station. Analysis included field inventories, a channel corridor sediment and sed-P budget applied to an extended channel network, and geochemical fingerprinting. Corridor inventories included mass wasting along valley sides, eroding streambanks, gullying along perennial and ephemeral channels, and streambed storage volumes in perennial reaches; each converted to masses. Erosion results estimate 7400 Mg/yr of fine-grained sediment, similar to the mean annual suspended sediment load of 5400 Mg/yr. Corridor erosion contributed 7200 kg/yr of sed-P, less than the mean annual particulate-P load of 10,000 kg/yr P. Soft sediment storage was 1400 Mg, with 1500 kg sed-P. Apportionment of soft sediment as streambank sourced was spatially variable, contributing ≥95 % in high order reaches with high storage and as little as 20 % in upstream reaches, where gully, crop, and forest provided the remainder. Two nearby tributaries showed similarity in the predominance of streambank-sourced material in stored soft sediment but differences in geomorphic setting affected its spatial distribution. The results of this study show the importance of including corridor erosion as a source of sediment and sed-P in agricultural basins, which can be helpful in decision-making regarding conservation practices.

Wisconsin↗

USGS2018

Adaptation with climate uncertainty: An examination of agricultural land use in the United States

This paper examines adaptation responses to climate change through adjustment of agricultural land use. The climate drivers we examine are changes in long-term climate normals (e.g., 10-year moving averages) and changes in inter-annual climate variability. Using US county level data over 1982 to 2012 from Census of Agriculture, we find that impacts of long-term climate normals are as important as that of inter-annual climate variability. Projecting into the future, we find projected climate change will lead to an expansion in crop land share across the northern and interior western United States with decreases in the south. We also find that grazing land share increases in southern regions and Inland Pacific Northwest and declines in the northern areas. However, the extent to which the adaptation potential would be is dependent on the climate model, emission scenario and time horizon under consideration.

Land Use Policy↗

USGS2011

Water- and sediment-quality effects on Pimephales promelas spawning vary along an agriculture-to-urban land-use gradient

Many streams in the U.S. are “impaired” due to anthropogenic influence. For watershed managers to achieve practical understanding of these impairments, a multitude of factors must be considered, including point and nonpoint-source influence on water quality. A spawning assay was developed in this study to evaluate water- and sediment-quality effects that influenced Pimephales promelas (fathead minnow) egg production over a gradient of urban and agricultural land use in 27 small watersheds in Eastern Wisconsin. Six pairs of reproducing fathead minnows were contained in separate mesh cartridges within one larger flow-through chamber. Water- and sediment quality were sampled for an array of parameters. Egg production was monitored for each pair providing an assessment of spawning success throughout the 21-day test periods. Incidences of low dissolved oxygen (DO) in many of these streams negatively impacted spawning success. Nine of 27 streams experienced DO less than 3.1 mg/L and 15 streams experienced DO less than 4.8 mg/L. Low DO was observed in urban and agricultural watersheds, but the upper threshold of minimum DO decreased with increasing urban development. An increase in specific conductance was related to a decrease in spawning success. In previous studies for streams in this region, specific conductance had a linear relation with chloride, suggesting the possibility that chloride could be a factor in egg production. Egg production was lower at sites with substantial urban development, but sites with low egg production were not limited to urban sites. Degradation of water- and sediment-quality parameters with increasing urban development is indicated for multiple parameters while patterns were not detected for others. Results from this study indicate that DO must be a high priority watershed management consideration for this region, specific conductance should be investigated further to determine the mechanism of the relation with egg production, and water- and sediment-quality degrade in relation to urban influence.

Science of the Total Environment↗

USGS2014

Differentiating transpiration from evaporation in seasonal agricultural wetlands and the link to advective fluxes in the root zone

The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flowrates and tracer concentrations atwetland inflows and outflows. We used two ideal reactormodel solutions, a continuous flowstirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these nonideal agricultural wetlands in which check ponds are in series. Using a fluxmodel, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment–water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemicalmechanisms affecting dissolved constituent cycling in the root zone. In addition,our understanding of internal root zone cycling of Hg and other dissolved constituents, benthic fluxes, and biological irrigation may be greatly affected.

Science of the Total Environment↗

USGS2014

Metolachlor metabolite (MESA) reveals agricultural nitrate-N fate and transport in Choptank River watershed

Over 50% of streams in the Chesapeake Bay watershed have been rated as poor or very poor based on the index of biological integrity. The Choptank River estuary, a Bay tributary on the eastern shore, is one such waterway, where corn and soybean production in upland areas of the watershed contribute significant loads of nutrients and sediment to streams. We adopted a novel approach utilizing the relationship between the concentration of nitrate-N and the stable, water-soluble herbicide degradation product MESA {2-[2-ethyl-N-(1-methoxypropan-2-yl)-6-methylanilino]-2-oxoethanesulfonic acid} to distinguish between dilution and denitrification effects on the stream concentration of nitrate-N in agricultural subwatersheds. The ratio of mean nitrate-N concentration/(mean MESA concentration * 1000) for 15 subwatersheds was examined as a function of percent cropland on hydric soil. This inverse relationship (R 2 = 0.65, p < 0.001) takes into consideration not only dilution and denitrification of nitrate-N, but also the stream sampling bias of the croplands caused by extensive drainage ditch networks. MESA was also used to track nitrate-N concentrations within the estuary of the Choptank River. The relationship between nitrate-N and MESA concentrations in samples collected over three years was linear (0.95 ≤ R 2 ≤ 0.99) for all eight sampling dates except one where R 2 = 0.90. This very strong correlation indicates that nitrate-N was conserved in much of the Choptank River estuary, that dilution alone is responsible for the changes in nitrate-N and MESA concentrations, and more importantly nitrate-N loads are not reduced in the estuary prior to entering the Chesapeake Bay. Thus, a critical need exists to minimize nutrient export from agricultural production fields and to identify specific conservation practices to address the hydrologic conditions within each subwatershed. In well drained areas, removal of residual N within the cropland is most critical, and practices such as cover crops which sequester the residual N should be strongly encouraged. In poorly drained areas where denitrification can occur, wetland restoration and controlled drained structures that minimize ditch flow should be used to maximize denitrification.

Choptank River Watershed↗

USGS2014

Long-term trends in alkalinity in large rivers of the conterminous US in relation to acidification, agriculture, and hydrologic modification

Alkalinity increases in large rivers of the conterminous US are well known, but less is understood about the processes leading to these trends as compared with headwater systems more intensively examined in conjunction with acid deposition studies. Nevertheless, large rivers are important conduits of inorganic carbon and other solutes to coastal areas and may have substantial influence on coastal calcium carbonate saturation dynamics. We examined long-term (mid-20th to early 21st century) trends in alkalinity and other weathering products in 23 rivers of the conterminous US. We used a rigorous flow-weighting technique which allowed greater focus on solute trends occurring independently of changes in flow. Increasing alkalinity concentrations and yield were widespread, occurring at 14 and 13 stations, respectively. Analysis of trends in other weathering products suggested that the causes of alkalinity trends were diverse, but at many stations alkalinity increases coincided with decreasing nitrate + sulfate and decreasing cation:alkalinity ratios, which is consistent with recovery from acidification. A positive correlation between the Sen–Thiel slopes of alkalinity increases and agricultural lime usage indicated that agricultural lime contributed to increasing solute concentration in some areas. However, several stations including the Altamaha, Upper Mississippi, and San Joaquin Rivers exhibited solute trends, such as increasing cation:alkalinity ratios and increasing nitrate + sulfate, more consistent with increasing acidity, emphasizing that multiple processes affect alkalinity trends in large rivers. This study was unique in its examination of alkalinity trends in large rivers covering a wide range of climate and land use types, but more detailed analyses will help to better elucidate temporal changes to river solutes and especially the effects they may have on coastal calcium carbonate saturation state.

Science of the Total Environment↗

USGS2015

Pesticide concentrations in frog tissue and wetland habitats in alandscape dominated by agriculture

Habitat loss and exposure to pesticides are likely primary factors contributing to amphibian decline in agricultural landscapes. Conservation efforts have attempted to restore wetlands lost through landscape modifications to reduce contaminant loads in surface waters and providing quality habitat to wildlife. The benefits of this increased wetland area, perhaps especially for amphibians, may be negated if habitat quality is insufficient to support persistent populations. We examined the presence of pesticides and nutrients in water and sediment as indicators of habitat quality and assessed the bioaccumulation of pesticides in the tissue of two native amphibian species Pseudacris maculata (chorus frogs) and Lithobates pipiens (leopard frogs) at six wetlands (3 restored and 3 reference) in Iowa, USA. Restored wetlands are positioned on the landscape to receive subsurface tile drainage water while reference wetlands receive water from overland run-off and shallow groundwater sources. Concentrations of the pesticides frequently detected in water and sediment samples were not different between wetland types. The median concentration of atrazine in surface water was 0.2 μg/L. Reproductive abnormalities in leopard frogs have been observed in other studies at these concentrations. Nutrient concentrations were higher in the restored wetlands but lower than concentrations thought lethal to frogs. Complex mixtures of pesticides including up to 8 fungicides, some previously unreported in tissue, were detected with concentrations ranging from 0.08 to 1500 μg/kg wet weight. No significant differences in pesticide concentrations were observed between species, although concentrations tended to be higher in leopard frogs compared to chorus frogs, possibly because of differences in life histories. Our results provide information on habitat quality in restored wetlands that will assist state and federal agencies, landowners, and resource managers in identifying and implementing conservation and management actions for these and similar wetlands in agriculturally dominated landscapes.

Iowa↗

USGS2019

Point sources and agricultural practices control spatial-temporal patterns of orthophosphate in tributaries to Chesapeake Bay

Orthophosphate (PO 4 ) is the most bioavailable form of phosphorus (P). Excess PO 4 may cause harmful algal blooms in aquatic ecosystems. A major restoration effort is underway for Chesapeake Bay (CB) to reduce P, nitrogen, and sediment loading to CB. Although PO 4 cycling and delivery to streams has been characterized in small-scale studies, regional drivers of PO 4 patterns remain poorly understood because most water quality trend assessment focus on total P. Moreover, these trend assessments are usually at an annual timestep. To address this research gap, we analyzed PO 4 patterns over a 9-year period at 53 monitoring stations across the CB watershed to: 1) characterize the role of PO 4 in total P fluxes and trends; 2) describe spatial and temporal patterns of PO 4 concentrations across seasons and streamflow ; and 3) explore factors explaining these patterns. Agricultural watersheds exported the most total P compared with watersheds under different land uses (e.g., urban or forest), with PO 4 comprising up to 50% of those exports. Although PO 4 exports are declining at many sites, some agricultural regions are experiencing increasing trends at a rate sufficient to drive total P trends. Regression modeling results suggest that point source load reductions are likely responsible for decreasing PO 4 concentrations observed at many sites. Watersheds with more Conservation Reserve Program enrollment had lower summer PO 4 concentrations, highlighting the effectiveness of this practice. Manure inputs strongly predicted PO 4 concentrations at high flows across all seasons. Both manure applications and conservation tillage were correlated with changes in PO 4 concentrations at high flow, suggesting these activities could contribute to increasing PO 4 concentrations. This study highlights the effectiveness of point source control for reducing PO 4 exports and underscores the need for management strategies to target sources, practices, and landscape factors determining PO 4 loss from soils where manure inputs remain high.

Delaware, Maryland, New York, Pennsylvania, Virgin↗

USGS2021

Impacts of neonicotinoid seed treatments on the wild bee community in agricultural field margins

Wild bees support global agroecosystems via pollination of agricultural crops and maintaining diverse plant communities. However, with an increased reliance on pesticides to enhance crop production, wild bee communities may inadvertently be affected through exposure to chemical residues. Laboratory and semi-field studies have demonstrated lethal and sublethal effects of neonicotinoids on limited genera (e.g., Apis , Bombus , Megachile ), yet full field studies evaluating impacts to wild bee communities remain limited. Here, we conducted a two-year field study to assess whether neonicotinoid seed treatment and presence in environmental media (e.g., soil, flowers) influenced bee nest and diet guild abundance and richness. In 2017 and 2018, we planted 23 Missouri agricultural fields to soybeans ( Glycine max) using one of three seed treatments: untreated (no insecticide), treated (imidacloprid), or previously-treated (untreated, but neonicotinoid use prior to 2017). During both years, wild bees were collected in study field margins monthly (May to September) in tandem with soil and flowers from fields and field margins that were analyzed for neonicotinoid residues. Insecticide presence in soils and flowers varied over the study with neonicotinoids infrequently detected in both years within margin flowers (0%), soybean flowers (<1%), margin soils (<8%), and field soils (~39%). Wild bee abundance and species richness were not significantly different among field treatments. In contrast, neonicotinoid presence in field soils was associated with significantly lower richness (ground- and aboveground-nesting, diet generalists) of wild bee guilds. Our findings support that soil remains an underexplored route of exposure and long-term persistence of neonicotinoids in field soils may lead to reduced diversity in regional bee communities. Future reduction or elimination of neonicotinoid seed treatment use on areas managed for wildlife may facilitate conservation goals to sustain viable, diverse wild bee populations.

Missouri↗

USGS2024

ENSO-based outlook of droughts and agricultural outcomes in Afghanistan

Drought is one of the key drivers of food insecurity in Afghanistan, which is among the most food insecure countries in the world. In this study, we build on previous research and seek to answer the central question: “What is the influence of El Niño-Southern Oscillation (ENSO) on drought outlooks and agricultural yield outcome in Afghanistan, and how do these influences vary spatially ?” We do so by utilizing multiple indicators of droughts and available wheat yield reports. We find a clear distinction in the probability of drought (defined as being in the lower tercile) in Afghanistan during La Niña compared to El Niño events since 1981. The probability of drought in Afghanistan increased during La Niña, particularly in the North, Northeast, and West regions. La Niña events are related to an increase in the probability of snow drought, particularly in parts of the Amu Darya basin. It is found that relative to El Niño events, snow water equivalent [total runoff] during La Niña events January–March (March–July total runoff) decreases between 9% and 30% (28%–42%) for the five major basins in the country. The probability of agricultural drought during La Niña events is found to be higher than 70% in the rainfed and irrigated areas of the Northeast, North, and West regions. This result is at least partly supported by reported wheat yield composites related to La Niña events that tend to be lower than for El Niño events across all regions in the case of rainfed wheat (statistically significant in Northeast, West, and South regions) and in some cases for irrigated wheat. The results of this study have direct implications for improving early warning of worsening food insecurity in Afghanistan during La Niña events, given that we now have long-lead and skillful forecasts of ENSO up to 18–24 months in advance, which could potentially be used to provide earlier warning of worsening food insecurity in Afghanistan

Weather and Climate Extremes↗

USGS2002

Effects of surface run-off on the transport of agricultural chemicals to ground water in a sandplain setting

An experiment was conducted at a depressional (lowland) and an upland site in sandy soils to evaluate the effects of surface run-off on the transport of agricultural chemicals to ground water. Approximately 16.5 cm of water was applied to both sites during the experiment, representing a natural precipitation event with a recurrence interval of approximately 100 years. Run-off was quantified at the lowland site and was not detected at the upland site during the experiment. Run-off of water to the lowland site was the most important factor affecting differences in the concentrations and fluxes of the agricultural chemicals between the two sites. Run-off of water to the lowland site appears to have played a dual role by diluting chemical concentrations in the unsaturated zone as well as increasing the concentrations at the water table, compared to the upland site. Concentrations of chloride, nitrate and atrazine plus metabolites were noticeably greater at the water table than in the unsaturated zone at both sites. The estimated mass flux of chloride and nitrate to the water table during the test were 5–2 times greater, respectively, at the lowland site compared to the upland site, whereas the flux of sulfate and atrazine plus metabolites was slightly greater at the upland site. Results indicate that matrix flow of water and chemicals was the primary process causing the observed differences between the two sites. Results of the experiment illustrate the effects of heterogeneity and the complexity of evaluating chemical transport through the unsaturated zone.

Science of the Total Environment↗

USGS2003

Baseflow and stormflow metal fluxes from two small agricultural catchments in the Coastal Plain of the Chesapeake Bay Basin, United States

Annual yields (fluxes per unit area) of Al, Mn, Fe, Ni, Cd, Pb, Zn, Cu, Cr, Co, As and Se were estimated for two small non-tidal stream catchments on the Eastern Shore of the Chesapeake Bay, United States - a poorly drained dissected-upland watershed in the Nanticoke River Basin, and a well-drained feeder tributary in the lower reaches of the Chester River Basin. Both watersheds are dominated by agriculture. A hydrograph-separation technique was used to determine the baseflow and stormflow components of metal yields, thus providing important insights into the effects of hydrology and climate on the transport of metals. Concentrations of suspended-sediment were used as a less-costly proxy of metal concentrations which are generally associated with particles. Results were compared to other studies in Chesapeake Bay and to general trends in metal concentrations across the United States. The study documented a larger than background yield of Zn and Co from the upper Nanticoke River Basin and possibly enriched concentrations of As, Cd and Se from both the upper Nanticoke River and the Chesterville Branch (a tributary of the lower Chester River). The annual yield of total Zn from the Nanticoke River Basin in 1998 was 18,000 g/km2/a, and was two to three times higher than yields reported from comparable river basins in the region. Concentrations of Cd also were high in both basins when compared to crustal concentrations and to other national data, but were within reasonable agreement with other Chesapeake Bay studies. Thus, Cd may be enriched locally either in natural materials or from agriculture.

Applied Geochemistry↗

USGS2018

Linking the agricultural landscape of the Midwest to stream health with structural equation modeling

Multiple physical and chemical stressors can simultaneously affect the biological condition of streams. To better understand the complex interactions of land-use practices, water quality, and ecological integrity of streams, the U.S. Geological Survey National Water Quality Assessment Project is conducting regional-scale assessments of stream condition across the United States. In the summer of 2013, weekly water samples were collected from 100 streams in the Midwestern United States. Employing watershed theory, we used structural equation modeling (SEM) to represent a general hypothesis for how 16 variables (previously identified to be important to stream condition) might be inter-related. Again, using SEM, we evaluated the ability of this “stressor network” to explain variations in multimetrics of algal, invertebrate, and fish community health, trimming away any environmental variables not contributing to an explanation of the ecological responses. Seven environmental variables—agricultural and urban land use, sand content of soils, basin area, percent riparian area as forest, channel erosion, and relative bed stability—were found to be important for all three-community metrics. The algal and invertebrate models included water-chemistry variables not included in the fish model. Results suggest that ecological integrity of Midwest streams are affected by both agricultural and urban land uses and by the natural geologic setting, as indicated by the sand content of soils. Chemicals related to crops (pesticides and nutrients) and residential uses (pyrethroids) were found to be more strongly related to ecological integrity than were natural factors (riparian forest, watershed soil character).

Environmental Science & Technology↗

USGS2026

Assessing pesticide application contributions of per- and polyfluoroalkyl substances (PFAS) in agricultural streams

Research has documented per-and polyfluoroalkyl substances (PFAS) to be prevalent in streams impacted by urban sources; less is known regarding PFAS contributions via pesticide applications: PFAS coming from pesticide containers and “inert” ingredients not listed on pesticide formulation labels. To better understand co-occurrence of pesticides and PFAS in agricultural streams, 10 streams were sampled in two agricultural valleys in northern California, USA during two periods of pesticide application (May and July of 2024). Water samples were analyzed for 183 pesticides and 57 PFAS. Sixty pesticides were detected: 23 herbicides, 18 insecticides, 18 fungicides, and 1 synergist. Overall detection frequencies (DF) ranged from 0 to 100%, and concentrations ranged from non-detect (ND) to 782 ng/L (fluxapyroxad). Fourteen PFAS were detected: 6 perfluoroalkyl carboxylates, 5 perfluoroalkyl sulfonates, 2 perfluoroalkyl acid precursors, and 1 perfluoroalkyl phosphinic acid with DFs ranging from 0 to 60% (PFOA) and concentrations ranging from ND to 20 ng/L (PFBA). Co-occurrence of PFAS and pesticides was observed in 80% of samples. Adopting the global definition of PFAS (includes fluorinated pesticides), pesticide applications are a likely source of instream PFAS. Examination of total organic fluorine and transformations to terminal and ultra-short PFAS could further elucidate pesticide contributions to environmental PFAS.

California↗

USGS2011

Effect of dissolved organic carbon on the transport and attachment behaviors of Cryptosporidium parvum oocysts and carboxylate-modified microspheres advected through temperate humic and tropical volcanic agricultural soil

Transport of Cryptosporidium parvum oocysts and microspheres in two disparate (a clay- and Fe-rich, volcanic and a temperate, humic) agricultural soils were studied in the presence and absence of 100 mg L –1 of sodium dodecyl benzene sulfonate (SDBS), and Suwannee River Humic Acid (SRHA) at pH 5.0–6.0. Transport of carboxylate-modified, 1.8 μm microspheres in soil columns was highly sensitive to the nature of the dissolved organic carbon (DOC), whereas oocysts transport was more affected by soil mineralogy. SDBS increased transport of microspheres from 48% to 87% through the tropical soil and from 43% to 93% in temperate soil. In contrast, SRHA reduced transport of microspheres from 48% to 28% in tropical soil and from 43% to 16% in temperate soil. SDBS also increased oocysts transport through the temperate soil 5-fold, whereas no oocyst transport was detected in tropical soil. SRHA had only a nominal effect in increasing oocysts transport in tropical soil, but caused a 6-fold increase in transport through the temperate soil. Amendments of only 4 mg L –1 SRHA and SDBS decreased oocyst hydrophobicity from 66% to 20% and from 66% to 5%, respectively. However, SDBS increased microsphere hydrophobicity from 16% to 33%. Soil fines, which includes clays, and SRHA, both caused the oocysts zeta potential (ζ) to become more negative, but caused the highly hydrophilic microspheres to become less negatively charged. The disparate behaviors of the two colloids in the presence of an ionic surfactant and natural organic matter suggest that microspheres may not be suitable surrogates for oocysts in certain types of soils. These results indicate that whether or not DOC inhibits or promotes transport of oocysts and microspheres in agricultural soils and by how much, depends not only on the surface characteristics of the colloid, but the nature of the DOC and the soil mineralogy.

Environmental Science & Technology↗