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At least 307 records · Page 17Linked to original sources

USGS2013

Hydrothermal contamination of public supply wells in Napa and Sonoma Valleys, California

Groundwater chemistry and isotope data from 44 public supply wells in the Napa and Sonoma Valleys, California were determined to investigate mixing of relatively shallow groundwater with deeper hydrothermal fluids. Multivariate analyses including Cluster Analyses, Multidimensional Scaling (MDS), Principal Components Analyses (PCA), Analysis of Similarities (ANOSIM), and Similarity Percentage Analyses (SIMPER) were used to elucidate constituent distribution patterns, determine which constituents are significantly associated with these hydrothermal systems, and investigate hydrothermal contamination of local groundwater used for drinking water. Multivariate statistical analyses were essential to this study because traditional methods, such as mixing tests involving single species (e.g. Cl or SiO 2 ) were incapable of quantifying component proportions due to mixing of multiple water types. Based on these analyses, water samples collected from the wells were broadly classified as fresh groundwater, saline waters, hydrothermal fluids, or mixed hydrothermal fluids/meteoric water wells. The Multivariate Mixing and Mass-balance (M3) model was applied in order to determine the proportion of hydrothermal fluids, saline water, and fresh groundwater in each sample. Major ions, isotopes, and physical parameters of the waters were used to characterize the hydrothermal fluids as Na–Cl type, with significant enrichment in the trace elements As, B, F and Li. Five of the wells from this study were classified as hydrothermal, 28 as fresh groundwater, two as saline water, and nine as mixed hydrothermal fluids/meteoric water wells. The M3 mixing-model results indicated that the nine mixed wells contained between 14% and 30% hydrothermal fluids. Further, the chemical analyses show that several of these mixed-water wells have concentrations of As, F and B that exceed drinking-water standards or notification levels due to contamination by hydrothermal fluids.

California↗

USGS2018

Radium mobility and the age of groundwater in public-drinking-water supplies from the Cambrian-Ordovician aquifer system, north-central USA

High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers ( 3 H, 3 He trit , SF 6 , 14 C and 4 He rad ) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (<50 yr) in upgradient, regionally unconfined areas to ancient (>1 Myr) in the most downgradient, confined portions of the potable system. More than 80 and 40 percent of mean groundwater ages were older than 1000 and 50,000 yr, respectively. Anoxic, Fe-reducing conditions and increased mineralization develop with time in the aquifer system and mobilize Ra into solution resulting in the frequent occurrence of combined Ra (Ra c = 226 Ra + 228 Ra) at concentrations exceeding the USEPA MCL of 185 mBq/L (5 pCi/L). The distribution of the three Ra isotopes comprising total Ra (Ra t = 224 Ra + 226 Ra + 228 Ra) differed across the aquifer system. The concentrations of 224 Ra and 228 Ra were strongly correlated and comprised a larger proportion of the Ra t concentration in samples from the regionally unconfined area, where arkosic sandstones provide an enhanced source for progeny from the 232 Th decay series. 226 Ra comprised a larger proportion of the Ra t concentration in samples from downgradient confined regions. Concentrations of Ra t were significantly greater in samples from the regionally confined area of the aquifer system because of the increase in 226 Ra concentrations there as compared to the regionally unconfined area. 226 Ra distribution coefficients decreased substantially with anoxic conditions and increasing ionic strength of groundwater (mineralization), indicating that Ra is mobilized to solution from solid phases of the aquifer as adsorption capacity is diminished. The amount of 226 Ra released from solid phases by alpha-recoil mechanisms and retained in solution increases relative to the amount of Ra sequestered by adsorption processes or co-precipitation with barite as adsorption capacity and the concentration of Ba decreases. Although 226 Ra occurred at concentrations greater than 224 Ra or 228 Ra, the ingestion exposure risk was greater for 228 Ra owing to its greater toxicity. In addition, 224 Ra added substantial alpha-particle radioactivity to potable samples from the C-O aquifer system. Thus, monitoring for Ra isotopes and gross-alpha-activity (GAA) is important in upgradient, regionally unconfined areas as downgradient, and GAA measurements made within 72 h of sample collection would best capture alpha-particle radiation from the short-lived 224 Ra.

Applied Geochemistry↗

USGS2019

Grounding simulation models with qualitative case studies: Toward a holistic framework to make climate science usable for US public land management

Policies directing agencies and public land managers to incorporate climate change into management face several barriers. These stem, in part, from a disconnect between the information that is produced and the information needs of local resource managers. A disproportionate focus on the natural and physical sciences in climate vulnerability and adaptation assessment obscure understandings of complex social systems and the interactions and feedbacks in social-ecological systems. We use a qualitative case study of bison management on Department of the Interior-managed and tribal lands to explore how a social-science driven Determinants and Analogue Vulnerability Assessment (DAVA) can inform ecological response models, specifically simulation models that account for multiple drivers of change. First, we illustrate how a DAVA approach can help to: 1) identify key processes, entities, and interactions across scales; 2) document local impacts, indicators, and monitoring efforts of drought and climate; and 3) identify major tradeoffs and uncertainties. We then demonstrate how qualitative narratives can inform simulation models by: 1) prioritizing model components included in modeling efforts; 2) framing joint management and climate scenarios; and 3) parameterizing and evaluating model performance. We do this by presenting a conceptual joint agent-based/state-and-transition simulation modeling framework. Simulation models can represent multiple interacting variables and can identify surprising, emergent outcomes that might not be evident from qualitative analysis alone, and we argue that qualitative case studies can ground simulation models in local contexts and help make them more structurally realistic and useful. Together, these can provide a step toward developing actionable climate change adaptation strategies.

Climate Risk Management↗

USGS2009

Afraid to Start Because the Outcome is Uncertain?: Social Site Characterization as a Tool for Informing Public Engagement Efforts

This paper introduces the concept of social site characterization as a parallel effort to technical site characterization to be used in evaluating and planning carbon dioxides capture and storage (CCS) projects. Social site characterization, much like technical site characterization, relies on a series of iterative investigations into public attitudes towards a CCS project and the factors that will shape those views. This paper also suggests ways it can be used to design approaches for actively engaging stakeholders and communities in the deployment of CCS projects. This work is informed by observing the site selection process for FutureGen and the implementation of research projects under the Regional Carbon Sequestration Partnership Program. ?? 2009 Elsevier Ltd. All rights reserved.

Conference Paper↗

USGS2026

Cumulative effects analysis to inform public land management in the United States: Key characteristics and legal challenges

Considering potential cumulative effects of proposed actions is fundamental to environmental impact analysis. However, cumulative effects analyses historically are not robust, especially for site-specific decisions. We sought to identify opportunities to strengthen cumulative effects analysis in a large United States public land management agency, the Bureau of Land Management (BLM). We asked 1) how cumulative effects analyses were legally challenged, 2) how site-specific cumulative effects analyses aligned with policy and compared to the broader-scale analyses to which they tiered, and 3) whether characteristics of cumulative effects analyses varied with category of proposed action, type of resource, or agency office. We used thematic analysis to assess litigation and appeals case documents finalized from 2010 to 2020 and a set of document analysis questions to assess National Environmental Policy Act (NEPA) analyses for BLM decisions completed prior to 2020 in Alaska and Colorado. We found that legal challenges related to cumulative effects focused on absence of cumulative effects analysis. In NEPA analyses, cumulative effects were frequently considered, but elements recommended in policy, such as citations, methods, and scope, were rarely included. These elements were present more often in the broader analyses to which site-specific analyses tiered. Many elements of cumulative effects analyses varied by proposed action and BLM office, and analyses of potential cumulative effects on air quality were consistently more detailed than for other resources. Our results suggest that many problems that historically plagued cumulative effects analysis persist. Advances in methods, training, and guidance could strengthen the defensibility of NEPA analyses.

Alaska, Colorado↗

USGS2017

Breeding birds in managed forests on public conservation lands in the Mississippi Alluvial Valley

Managers of public conservation lands in the Mississippi Alluvial Valley have implemented forest management strategies to improve bottomland hardwood habitat for target wildlife species. Through implementation of various silvicultural practices, forest managers have sought to attain forest structural conditions (e.g., canopy cover, basal area, etc.) within values postulated to benefit wildlife. We evaluated data from point count surveys of breeding birds on 180 silviculturally treated stands (1049 counts) that ranged from 1 to 20 years post-treatment and 134 control stands (676 counts) that had not been harvested for >20 years. Birds detected during 10-min counts were recorded within four distance classes and three time intervals. Avian diversity was greater on treated stands than on unharvested stands. Of 42 commonly detected species, six species including Prothonotary Warbler ( Prothonotaria citrea ) and Acadian Flycatcher ( Empidonax virescens ) were indicative of control stands. Similarly, six species including Indigo Bunting ( Passerina cyanea ) and Yellow-breasted Chat ( Icteria virens ) were indicative of treated stands. Using a removal model to assess probability of detection, we evaluated occupancy of bottomland forests at two spatial scales (stands and points within occupied stands). Wildlife-forestry treatment improved predictive models of species occupancy for 18 species. We found years post treatment (range = 1–20), total basal area, and overstory canopy were important species-specific predictors of occupancy, whereas variability in basal area was not. In addition, we used a removal model to estimate species-specific probability of availability for detection, and a distance model to estimate effective detection radius. We used these two estimated parameters to derive species densities and 95% confidence intervals for treated and unharvested stands. Avian densities differed between treated and control stands for 16 species, but only Common Yellowthroat ( Geothlypis trichas ) and Yellow-breasted Chat had greater densities on treated stands.

Mississippi Alluvial Valley↗

USGS2017

Relative abundance of deformed wing virus, Varroa destructor virus 1, and their recombinants in honey bees (Apis mellifera) assessed by kmer analysis of public RNA-Seq data

Deformed wing virus (DWV) is a major pathogen of concern to apiculture, and recent reports have indicated the local predominance and potential virulence of recombinants between DWV and a related virus, Varroa destructor virus 1 (VDV). However, little is known about the frequency and titer of VDV and recombinants relative to DWV generally. In this study, I assessed the relative occurrence and titer of DWV and VDV in public RNA-seq accessions of honey bee using a rapid, kmer-based approach. Three recombinant types were detectable graphically and corroborated by de novo assembly. Recombination breakpoints did not disrupt the capsid-encoding region, consistent with previous reports, and both VDV- and DWV-derived capsids were observed in recombinant backgrounds. High abundance of VDV kmers was largely restricted to recombinant forms. Non-metric multidimensional scaling identified genotypic clusters among DWV isolates, which was corroborated by read mapping and consensus generation. The recently described DWV-C lineage was not detected in the searched accessions. The data further highlight the utility of high-throughput sequencing to monitor viral polymorphisms and statistically test biological predictors of titer, and point to the need for consistent methodologies and sampling schemes.

Journal of Invertebrate Pathology↗

USGS2016

An assessment of mercury in estuarine sediment and tissue in Southern New Jersey using public domain data

Mercury (Hg) is considered a contaminant of global concern for coastal environments due to its toxicity, widespread occurrence in sediment, and bioaccumulation in tissue. Coastal New Jersey, USA, is characterized by shallow bays and wetlands that provide critical habitat for wildlife but share space with expanding urban landscapes. This study was designed as an assessment of the magnitude and distribution of Hg in coastal New Jersey sediments and critical species using publicly available data to highlight potential data gaps. Mercury concentrations in estuary sediments can exceed 2 μg/g and correlate with concentrations of other metals. Based on existing data, the concentrations of Hg in mussels in southern New Jersey are comparable to those observed in other urbanized Atlantic Coast estuaries. Lack of methylmercury data for sediments, other media, and tissues are data gaps needing to be filled for a clearer understanding of the impacts of Hg inputs to the ecosystem.

New Jersey↗

USGS2017

Seventy-five years of vegetation treatments on public rangelands in the Great Basin of North America

On the Ground Land treatments occurring over millions of hectares of public rangelands in the Great Basin over the last 75 years represent one of the largest vegetation manipulation and restoration efforts in the world. The ability to use legacy data from land treatments in adaptive management and ecological research has improved with the creation of the Land Treatment Digital Library (LTDL), a spatially explicit database of land treatments conducted by the U.S. Bureau of Land Management. The LTDL contains information on over 9,000 confirmed land treatments in the Great Basin, composed of seedings (58%), vegetation control treatments (24%), and other types of vegetation or soil manipulations (18%). The potential application of land treatment legacy data for adaptive management or as natural experiments for retrospective analyses of effects of land management actions on physical, hydrologic, and ecologic patterns and processes is considerable and just beginning to be realized.

California, Idaho, Nevada, Oregon, Utah↗

USGS2021

Oil and gas reclamation on US public lands: How it works and improving the process with land potential concepts

• There are three general stages of a well's life on US public land: 1) the permitting process to drill, 2) active extraction of fossil fuel resource, and 3) plugging and abandonment of well. • There is no national standard for oil and gas reclamation in the United States similar to mining and therefore current reclamation practices and standards fail to achieve long-term effectiveness across the western United States. • A reclaimed well pad's land potential is determined by 3 properties: static (e.g., climate), dynamic (e.g., soil stability), and process (e.g., water retention). • Understanding a reclaimed well pad's land potential enables federal land agencies to outline surface reclamation goals and requirements consistently and clearly. • Monitoring for land potential increases the capacity of the private industry to practice adaptive management by enabling companies to respond to plant community changes while maintaining long-term progress toward recovery.

Rangelands↗

USGS2011

Occurrence and concentrations of pharmaceutical compounds in groundwater used for public drinking-water supply in California

Pharmaceutical compounds were detected at low concentrations in 2.3% of 1231 samples of groundwater (median depth to top of screened interval in wells = 61 m) used for public drinking-water supply in California. Samples were collected statewide for the California State Water Resources Control Board's Groundwater Ambient Monitoring and Assessment (GAMA) Program. Of 14 pharmaceutical compounds analyzed, 7 were detected at concentrations greater than or equal to method detection limits: acetaminophen (used as an analgesic, detection frequency 0.32%, maximum concentration 1.89 μg/L), caffeine (stimulant, 0.24%, 0.29 μg/L), carbamazepine (mood stabilizer, 1.5%, 0.42 μg/L), codeine (opioid analgesic, 0.16%, 0.214 μg/L), p -xanthine (caffeine metabolite, 0.08%, 0.12 μg/L), sulfamethoxazole (antibiotic, 0.41%, 0.17 μg/L), and trimethoprim (antibiotic, 0.08%, 0.018 μg/L). Detection frequencies of pesticides (33%), volatile organic compounds not including trihalomethanes (23%), and trihalomethanes (28%) in the same 1231 samples were significantly higher. Median detected concentration of pharmaceutical compounds was similar to those of volatile organic compounds, and higher than that of pesticides. Pharmaceutical compounds were detected in 3.3% of the 855 samples containing modern groundwater (tritium activity > 0.2 TU). Pharmaceutical detections were significantly positively correlated with detections of urban-use herbicides and insecticides, detections of volatile organic compounds, and percentage of urban land use around wells. Groundwater from the Los Angeles metropolitan area had higher detection frequencies of pharmaceuticals and other anthropogenic compounds than groundwater from other areas of the state with similar proportions of urban land use. The higher detection frequencies may reflect that groundwater flow systems in Los Angeles area basins are dominated by engineered recharge and intensive groundwater pumping.

California↗

USGS2013

Trends in concentrations of nitrate and total dissolved solids in public supply wells of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins, San Bernardino County, California: Influence of legacy land use

Concentrations and temporal changes in concentrations of nitrate and total dissolved solids (TDS) in groundwater of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins of the Upper Santa Ana Valley Groundwater Basin were evaluated to identify trends and factors that may be affecting trends. One hundred, thirty-one public-supply wells were selected for analysis based on the availability of data spanning at least 11 years between the late 1980s and the 2000s. Forty-one of the 131 wells (31%) had a significant (p < 0.10) increase in nitrate and 14 wells (11%) had a significant decrease in nitrate. For TDS, 46 wells (35%) had a significant increase and 8 wells (6%) had a significant decrease. Slopes for the observed significant trends ranged from − 0.44 to 0.91 mg/L/yr for nitrate (as N) and − 8 to 13 mg/L/yr for TDS. Increasing nitrate trends were associated with greater well depth, higher percentage of agricultural land use, and being closer to the distal end of the flow system. Decreasing nitrate trends were associated with the occurrence of volatile organic compounds (VOCs); VOC occurrence decreases with increasing depth. The relations of nitrate trends to depth, lateral position, and VOCs imply that increasing nitrate concentrations are associated with nitrate loading from historical agricultural land use and that more recent urban land use is generally associated with lower nitrate concentrations and greater VOC occurrence. Increasing TDS trends were associated with relatively greater current nitrate concentrations and relatively greater amounts of urban land. Decreasing TDS trends were associated with relatively greater amounts of natural land use. Trends in TDS concentrations were not related to depth, lateral position, or VOC occurrence, reflecting more complex factors affecting TDS than nitrate in the study area.

California↗

USGS2022

Predicting regional fluoride concentrations at public and domestic supply depths in basin-fill aquifers of the western United States using a random forest model

A random forest regression (RFR) model was applied to over 12,000 wells with measured fluoride (F) concentrations in untreated groundwater to predict F concentrations at depths used for domestic and public supply in basin-fill aquifers of the western United States. The model relied on twenty-two regional-scale environmental and surficial predictor variables selected to represent factors known to control F concentrations in groundwater. The testing model fit R 2 and RMSE were 0.52 and 0.78 mg/L. Comparisons of measured to predicted proportions of four F-concentrations categories (<0.7 mg/L, 0.7–2 mg/L, >2 mg/L – 4 mg/L, and > 4 mg/L) indicate that the model performed well at making regional-scale predictions. Differences between measured and predicted proportions indicate underprediction of measured F at values by between 4 and 20 mg/L, representing less than 1% of the regional scale predicted values. These residuals most often map to geographic regions where local-scale processes including evaporative discharge in closed basins or intermittent streams concentrate fluoride in shallow groundwater. Despite this, the RFR model provides spatially continuous F predictions across the basin-fill aquifers where discrete samples are missing. Further, the predictions capture documented areas that exceed the F maximum contaminant level for drinking water of 4 mg/L and areas that are below the oral-health benchmark of 0.7 mg/L. These predictions can be used to estimate fluoride concentrations in unmonitored areas and to aid in identifying geographic areas that may require further investigation at localized scales.

Arizona, California, Colorado, New Mexico, Nevada,↗

USGS2004

Zoonotic protozoa in the marine environment: a threat to aquatic mammals and public health

This collection of abstracts provides an account of four presentations at the 19th International Conference of the World Association for the Advancement of Veterinary Parasitology (WAAVP) (held in New Orleans, LA, USA from 10–14 August 2003) in a symposium session on zoonotic protozoan parasites found in the marine environment and chaired by Ronald Fayer and David Lindsay. The focus was on three genera of parasites of veterinary and public health concern - Toxoplasma , Giardia , and Cryptosporidium with emphasis on their epidemiology in the marine environment.

Veterinary Parasitology↗

USGS2020

Viral, bacterial, and protozoan pathogens and fecal markers in wells supplying groundwater to public water systems in Minnesota, USA

Drinking water supply wells can be contaminated by a broad range of waterborne pathogens. However, groundwater assessments frequently measure microbial indicators or a single pathogen type, which provides a limited characterization of potential health risk. This study assessed contamination of wells by testing for viral, bacterial, and protozoan pathogens and fecal markers. Wells supplying groundwater to community and noncommunity public water systems in Minnesota, USA (n = 145) were sampled every other month over one or two years and tested using 23 qPCR assays. Eighteen genetic targets were detected at least once, and microbiological contamination was widespread (96% of 145 wells, 58% of 964 samples). The sewage-associated microbial indicators HF183 and pepper mild mottle virus were detected frequently. Human or zoonotic pathogens were detected in 70% of wells and 21% of samples by qPCR, with Salmonella and Cryptosporidium detected more often than viruses. Samples positive by qPCR for adenovirus (HAdV), enterovirus, or Salmonella were analyzed by culture and for genotype or serotype. qPCR-positive Giardia and Cryptosporidium samples were analyzed by immunofluorescent assay (IFA), and IFA and qPCR concentrations were correlated. Comparisons of indicator and pathogen occurrence at the time of sampling showed that total coliforms, HF183, and Bacteroidales -like HumM2 had high specificity and negative predictive values but generally low sensitivity and positive predictive values. Pathogen-HF183 ratios in sewage have been used to estimate health risks from HF183 concentrations in surface water, but in our groundwater samples Cryptosporidium oocyst:HF183 and HAdV:HF183 ratios were approximately 10,000 times higher than ratios reported for sewage. qPCR measurements provided a robust characterization of microbiological water quality, but interpretation of qPCR data in a regulatory context is challenging because few studies link qPCR measurements to health risk.

Minnesota↗

USGS2002

Changes in concentrations of triazine and acetamide herbicides by bank filtration, ozonation, and chlorination in a public water supply

The changes in triazine and acetamide concentrations in water during natural and artificial treatment by bank filtration, ozonation, filtration, and chlorination were measured at the well field and drinking water treatment plant of Lincoln, Nebraska, USA. The city's groundwater supply is affected by induced infiltration and transport of triazines and acetamide herbicides from the Platte River in late spring and early summer. The objective of the study was to evaluate the effect of infiltration and treatment on the presence of triazines and acetamides in drinking water. Samples of river water, well water, and public supply water at various stages of water treatment were collected from 1997-1999 during spring-runoff when the presence of herbicides in the Platte River is largest. In 1999, parent compounds were reduced by 76% of the concentration present in river water (33% by bank filtration, 41% by ozonation, and 1.5% by chlorination). Metabolites of herbicides for which analytical techniques existed were reduced by 21% (plus 26% by bank filtration, minus 23% by ozonation, and minus 24% by chlorination). However, increases in concentrations of specific metabolite compounds were identified after bank filtration and ozonation. After bank filtration, increases in cyanazine amide, cyanazine acid, and deethylcyanazine acid were identified. After ozonation, concentrations of deisopropylatrazine, deethylatrazine, didealkylatrazine, atrazine amide-I, hydroxydeethylatrazine, hydroxydeisopopylatrazine, deethylcyanazine acid, and deethylcyanazine increased. Concentrations of cyanazine acid and ethanesulfonic and oxanilic acids of acetamides decreased during ozonation. Our findings suggest that bank filtration and ozonation of water in part can shift the assessment of risk to human health associated with the consumption of the water from the parent compounds to their degradation products.

Journal of Hydrology↗

USGS2020

Occurrence and geochemistry of lead-210 and polonium-210 radionuclides in public-drinking-water supplies from principal aquifers of the United States

On the basis of lifetime cancer risks, lead-210 ( 210 Pb) and polonium-210 ( 210 Po) ≥ 1.0 and 0.7 pCi/L (picocuries per liter), respectively, in drinking-water supplies may pose human-health concerns. 210 Pb and 210 Po were detected at concentrations greater than these thresholds at 3.7 and 1.5%, respectively, of filtered untreated groundwater samples from 1263 public-supply wells in 19 principal aquifers across the United States. Nationally, 72% of samples with radon-222 ( 222 Rn) concentrations > 4000 pCi/L had 210 Pb ≥ 1.0 pCi/L. 210 Pb is mobilized by alpha recoil associated with the decay of 222 Rn and short-lived progeny. 210 Pb concentrations ≥ 1.0 pCi/L occurred most frequently where acidic groundwaters inhibited 210 Pb readsorption (felsic-crystalline rocks) and where reducing alkaline conditions favored dissolution of iron–manganese- (Fe–Mn-) oxyhydroxides (which adsorb 210 Pb) and formation of lead–carbonate complexes (enhancing lead (Pb) mobility). 210 Po concentrations ≥ 0.7 pCi/L occurred almost exclusively in confined Coastal Plain aquifers where old (low percent-modern carbon-14) groundwaters were reducing, with high pH (>7.5) and high sodium/chloride (Na/Cl) ratios resulting from cation exchange. In high-pH environments, aqueous polonium (Po) is poorly sorbed, occurring as dihydrogen polonate (H 2 PoO 3 (aq)) or, under strongly reducing conditions, as a hydrogen-polonide anion (HPo – ). Fe–Mn- and sulfate-reduction and cation-exchange processes may mobilize polonium from mineral surfaces. Po 2+ occurrence in low-to-neutral-pH waters is attenuated by adsorption.

Environmental Science Technology↗

USGS2020

Pesticides and pesticide degradates in groundwater used for public supply across the United States: Occurrence and human-health context

This is the first assessment of groundwater from public-supply wells across the United States to analyze for >100 pesticide degradates and to provide human-health context for degradates without benchmarks. Samples from 1204 wells in aquifers representing 70% of the volume pumped for drinking supply were analyzed for 109 pesticides (active ingredients) and 116 degradates. Among the 41% of wells where pesticide compounds were detected, nearly two-thirds contained compound mixtures and three-quarters contained degradates. Atrazine, hexazinone, prometon, tebuthiuron, four atrazine degradates, and one metolachlor degradate were each detected in >5% of wells. Detection frequencies were largest for aquifers with more shallow, unconfined wells producing modern-age groundwater. To screen for potential human-health concerns, benchmark quotients (BQs) were calculated by dividing concentrations by the human-health benchmark, when available. For degradates without benchmarks, estimated values (estimated benchmark quotients (BQE)) were first calculated by assuming equimolar toxicity to the most toxic parent; final analysis excluded degradates with likely overestimated toxicity. Six pesticide compounds and 1.6% of wells had concentrations approaching levels of potential concern (individual or summed BQ or BQE values >0.1), and none exceeded these levels (values >1). Therefore, although pesticide compounds occurred frequently, concentrations were low, even accounting for mixtures and degradates without benchmarks.

Continental United States↗